MATERIAL SAFETY DATA SHEET
CARBON DIOXIDE
Manufacturer’s Name
Air Liqiude Australia Limited
Emergency Telephone No.
133 166 or 000
Address
Royal Domain Centre,
Other Information Calls
133 166 or
(02) 9440 9322
380 St. Kilda Road,
Melbourne Vic. 3004
Prepared By
Technical Services
Date Prepared
April 2004
Carbon Dioxide
CAS No.
124-38-9
Chemical Family
N/A
SECTION 1 - IDENTITY
Common Name (used on lable)
(Trade Name and Synonyms)
Aligal
R
2,
Lasal
Chemical Name
Carbon Dioxide
Formula
CO2
R
2
SECTION 2 - INGREDIENTS
PART A – HAZARDOUS INGREDIENTS
Pricipal Hazardous Component(s)
Wt.%
CAS No.
Carbon Dioxide
100
124-38-9
ACGIH TLV
Acute Toxicity Data
OSHA PEL 5000ppm,
Inhalation (human) LCLO
ACGIH TLV-TWA 5000ppm
ACGIH TLV-STEL 30000ppm
100,000ppm/min
PART B – OTHER INGREDIENTS
Other Component(s)
Wt.%
CAS No.
ACGIH TLV
Acute Toxicity Data
N/A
N/A
N/A
N/A
N/A
SECTION 3 – Physical & Chemical Charateristics (Fire & Explosion Data)
Boiling Point
Percent Volatile by
-78.5°
Specific Gravity (Air = 1)
N/A
1.53
Vapour Density
Volume (%)
1.873kg/m
Vapour Pressure (mm Hg)
5090kPa @15°C
Evaporation Rate
N/A
(air = 1)
(Butyl acetate =1)
Reactivity in water
NDA
Solubility in Water
1.716m3/kg
Appearance & Odour
Straw yellow clear liquid, mild sweet odour.
Flash Point
None
Flammable Limits in
N/A
Air % by Volume
Special Fire Fighting
3
Extinguisher
THIS IS AN
Media
EXTINGUISHING AGENT
Auto-Ignition Temp
N/A
None
Procedures
Unusual Fire &
Carbon Dioxide is non-flammable, but container may rupture when heated. Move cylinders from fire if safe to do so.
Explosion Hazards
Cool cylinders with water from a protected location. If unable to keep cylinders cool, evacuate area.
SECTION 4 – Physical Hazards
Stability
Unstable
Incompatibility (materials to avoid)
N/A
Hazardous Decomposition Products
None
Hazardous Polymerization
May Occur
Stable
X
Conditions to avoid
None known
Will Not Occur
X
Conditions to avoid
N/A
SECTION 5 – Health Hazards
Threshold Limit Value
OSHA PEL 5000ppm ACGIH TLV-TWA 5000ppm ACGIH TLV-STEL 30000ppm
Routes of Entry
Eye
The liquid form of this material can produce
Skin
Evaporation of liquid from skin can produce
Contact :
chilling sensations and discomfort also
Contact:
chilling sensations. Frostbite can occur.
frostbite.
Avoid carbon dioxide snow(dry ice).
1
Inhalation:
Carbon Dioxide is an asphyxiant. Effects of oxygen deficiency ; below
Ingestion:
Not a likely route of entry.
6%: convulsive movements, possible respiratory collapse and death.
Signs & Symptons – Acute
Contact can produce chilling sensations, lightheadedness, giddienss, shortness of breath, muscular
Overexposure
tremors and weakness, and acrocyanosis. Also unconsciousness or even death.
Signs & Symptons – Chronic
Prolonged exposure to an oxygen deficient atmosphere (below 18% oxygen) may affect the heart and
Overexposure
nervous system.
Medical Conditions Generally
Respiratory problems.
Aggravated by Exposure
Chemical Listed as Carcinogen or
National Toxicology Program:
No
I.A.R.C Monographs:
No
OSHA:
No
Potential
SECTION 6 – Emergency & First Aid Procedures
Eye Contact
Immediately flush eyes with plenty of water for 15 minutes whilst holding lids open. If redness, itching or burning
occurs get medical attention.
Skin Contact
Wash material off skin with copious amounts of water and soap for at least 15 minutes. If redness, itching or burning
occurs get medical attention.
Inhalation
Call Doctor. If victim is concious: move to uncontaminated area to breath fresh air. Keep warm and quiet. If victim is
unconcious: move to uncontaminated area and give assisted respiration. Continued treatment should be symptomatic
and supportive.
N.B Rescuers should not enter an oxygen deficient atmosphere without using self-contained full face positive pressure
breathing equipment.
Ingestion
N/A
SECTION 7 – Special Protection Information
Respiratory Protection
Approved self-contained full face respiratory equipment should be readily available.
(Specify Type)
Ventilation
Local Exhaust:
Recommended
Mechanical (General):
Supply sufficient replacement air to maintain
oxygen concentration above 18%.
Protective Gloves
Leather or PVC gloves.
Eye Protection
Other Protective
Safety footware. Full cover overalls.
Chemical goggles are recommended.
Clothing or Equipment
SECTION 8 – Special Precautions & Spill/Leak Procedures
Precautions to be Taken in
Store in cool ,dry well ventilated area out of direct sunlight and away from heat and ignition sources. Do
Handling & Storage
not expose any cylinder part to temperatures above 55° C. store upright on a level, fireproof floor, secure
in position and protected from damage. Full cylinders stored separately from empties.
Other Precautions
Avoid any contact with oil or grease particularly to the cylinder valve.
Steps to be Taken in Case Material
Ventilate area. Stop leak if it can be done without risk. Allow gas to dissipate into atmosphere. Carbon
is Released/Spilled
Dioxide is heavier than air and will accumulate in low points. Low level ventilation may be required.
Waste Disposal Methods
Dispose of in compliance with local, state and federal regulations.
SECTION 9 – Transport Information
Australian Dangerous Goods Code Hazard Class or Division
Class 2.2 UN Number 1013 HAZCHEM 2TE
Hazardous Material Identification System Ratings
Hazard Index
4 – Severe, 3 – Serious, 2 – Moderate, 1 – Slight, 0 – Minimal hazard, N/A –Not applicable, NDA – No Data Available, N/E –
None Established
Health
N/E
Flammability
N/A
Ansul is a registered trademark.
2
Reactivity
N/A