P
i
Y
Your Ref:
Ms. Elizabeth Leacy,
Environmental Protection Agency,
P.O. Box 3000,
Johnstom Castle Estate,
Co.Wexford.
Our Ref:
Date:
M672
14’ October 2004.
Dear Sir or Madam:
do not hesitate to contact me.
Co
n
se
nt
o
Should you require further in
f c Fo
op r i
yr ns
ig pe
ht ct
ow ion
ne pu
r r rp
eq os
ui es
re o
d nl
fo y.
ra
ny
ot
he
ru
se
.
Please see attachedthe MSDS sheets for the glues that we use onsite, as requested by the Agency
as part of our IPC licence review, to determine if Finsa Forest Products fklls under the Solvents
Directive (1 999/13/EC).
SAkES OFFICES
Spain
Alicante
Barcelona
Logrotio
Madrid
Muxika
Santiago
Sevilla
Valencia
3ubai
-rance
qederland
reland
taly
’oland
’ortugal
Jnited Kingdom
N
FlNSA FOREST PRODUCTS Ltd.
SCARIFF County Clare
Ireland
Tel.: + 353 / 0 61 92 10 38
Fax, + 353 / 0 61 92 1129
e-mail: ffp@finsa.es
Registered in Ireland No. 98769
Vat No IE 4736935W
Scz
IS. EN IS0 9002
Approved
System Qualify
Directors: S Garcia (Spanish],J.M. RamOS (Spanish),V. Romero (Spanish].E. Santos (Spanlshl. G. Frey (Spanish).J. lschner [Germon)
EPA Export 25-07-2013:18:56:27
\
EPA Export 25-07-2013:18:56:27
to
f c Fo
op r i
yr ns
ig pe
ht ct
ow ion
ne pu
r r rp
eq os
ui es
re o
d nl
fo y.
ra
ny
ns
en
Co
se
ru
he
ot
.
to
f c Fo
op r i
yr ns
ig pe
ht ct
ow ion
ne pu
r r rp
eq os
ui es
re o
d nl
fo y.
ra
ny
ns
en
Co
se
ru
he
ot
.
I
UREA FORMALDEHYDE
CONCENTRATE
EPA Export 25-07-2013:18:56:27
\
'.
\
EPA Export 25-07-2013:18:56:27
se
Co
n
f c Fo
op r i
yr ns
ig pe
ht ct
ow ion
ne pu
r r rp
eq os
ui es
re o
d nl
fo y.
ra
ny
nt
o
se
.
ru
he
ot
1. IDENTWICATION OF THE MATERIAL AND OF THE COMPANY/ENTERPRISE
1.1. Identification of the Material :
1.2. Identification of the Company Enterprise
...........................................
986) 540014
2. COMPOSITION / INFORMATION ABOUT COMPONENTS
Formaldehyde (CH20)
>I= 25 %
R 23125-40-43
S %-26-36137-51
se
nt
o
Substance:
Concentration (YO):
Hazard Symbol; IUS-Phrases:
Co
n
1 i
f c Fo
op r i
yr ns
ig pe
ht ct
ow ion
ne pu
r r rp
eq os
ui es
re o
d nl
fo y.
ra
ny
ot
he
ru
Emergency Phone
se
.
FORESAJndustrias Quimicas del Noroeste,S.A.
FAX+34986540855
Avda. de D o b Urraca,94
e-mail: foresa @ finsa.es
CALDAS DE REYES (Pontevedra)
3. HAZARDS IDENTIFICATION
3.1 Toxic by inhalation:
Provoking breathing diiliculties, loss of sense o f smell, palpitation (rapid heart
’ beat), headdache.
3.2 Toxic by ingestion:
Provoking nausea and vomiting, abdominal pain, diarrhea.
3.3 Toxic by skin contact:
Provoking skin burns and allergic reactions.
3.4 Eye irritate:
Provoking lacrimation, conjunctivitis and corneal burns
1
EPA Export 25-07-2013:18:56:27
. .
.
4.FIRSTAID
4.1 General twhcide:
Remove the victim from the contaminated area
4.2 Contact with skin and mucous membranes:
Wash the contaminated areas abundantly with water for at least 15 minutes, do it
under an emergency shower if available.
Contaminated clothing and shoes should be removed under shower
4.3 Eve contact:
Irrigate inmediately with large amounts of water for a mjnimun of 15 minutes
to
f c Fo
op r i
yr ns
ig pe
ht ct
ow ion
ne pu
r r rp
eq os
ui es
re o
d nl
fo y.
ra
ny
ot
he
ru
se
.
Held apart the eyelids during irrigation to insure water contact with all of tissues
of the surface of eyes and lids
The victim should be sent to a physician, preferably an eye specialist, as rapidly
as possible
4.4 Ingestion:
Do not induce vomits
Co
Calla physician
ns
en
swallow 2 gr 3 drops of water or milk
4.5 Inhalation:
Removed the exposed persons from the contaminated area, they should be kept
warm but not hot
If the victim lost concioousness put him laterally
If the victim is no breathing, an effective means of artificial respiration should
be initiated inmediately. If oxigen inhalation apparatus is available, oxygen
should be administered but only by a person authorized for such duty.
If the victim stop breathing or seems to have an heart attack, immediately start
giving him artificial ventilation and external cardiacal compression, only by a
person authorized todo it
Call a physician
2
EPA Export 25-07-2013:18:56:27
5. FlRE FIGHTING
5.1 Recommended means:
Water spray, dry chemical, carbon dioxide, foam and halon
5.2 Not advisable means:
Water jets,
5.3 Protection eauipment:
Waterproof coats, boots in PVP material, goggles and helmet
When fighting indoor fires, self-contained breathing apparatus is necessary,
of F
co or
py in
rig sp
ht ect
ow ion
ne pu
r r rp
eq os
ui es
re o
d nl
fo y.
ra
ny
ot
he
ru
se
.
5.4 Procedure on combat to fire :
Avoid product spreading
I
Xefiigerate with water the exterior parts of the tanks exposed to fire
I
\Keep away the unnecesary persons
I
Co
ns
en
t
Fire fighters should remain with the wind to their backis and apart fkom low
areas and tanks.
6. MEASURES IN CASE OF ACCIDENTAL LEAK
I
Use adequate respiratory protection, goggles, gloves and boots in PVC material
Cheek the valves bolt and cover leaks
I
Avoid the product projection over the skin, eyes respiratory system and clothes
I
Prevent the drain of the product to the sewer, water course, permeable or agriculture
lands and dwelling areas
I
Throw big quantities of pulverized water over the product
In case of small quantities, clean with a towel that should be burned after
Warn the authorities in case of serious contamination
3
I
EPA Export 25-07-2013:18:56:27
h.
7.- HANDLING AND STORAGE
7.1 Handling:
No breath of vapors
Wear protection wardrobe, goggles and gloves
When severely exposed use adequate respiratory mask
Keep vessels tiightly sealed
Workplaces and working methods must be designed to prevent driect contact
with formaldehyde solutions
ru
se
.
Emergency showers and eyes washing facilities must be available at the
workplace
f c Fo
op r i
yr ns
ig pe
ht ct
ow ion
ne pu
r r rp
eq os
ui es
re o
d nl
fo y.
ra
ny
ot
he
7.2 Storage:
Store in well ventilated places
Store in drums or tanks in a temperature range between 16 - 35 "C
Avoid contact with oxidizing and alkaline materials
Co
n
se
nt
o
Storage tanks should be adequately grounded to discharge static electricity and
to reduce other electrical hazard
Indoor storage areas should be in areas having floors pitched toward a trapped
&ah or in cubed retention areas.
8.- INDIVIDUAL EXPOSITION/PROTECTIONCONTROL
8.1 ResDiratorv urotection:
Severe exposure to formaldehyde may occur in tanks during equipment cleaning
and reapirs, when decontaminating areas following spills, or in case of failure of
piping or equipment. Employees who may be subject to such exposures should
be provided with proper respiratory protection and trained in its use and care.
Available types are described bellow:
. Sefl-contained breathing apparatus
. Positive pressure hose masks
. Air line masks
. Industrial canister type gas masks
. Chemical cartridge respirators.
4
EPA Export 25-07-2013:18:56:27
1
8.2 Hand protection:
Use gloves made of rubber or the other impervious material
8.3 Eye protection:
Cup type fi-amed goggles, equipped with the approved impact resistant glass or
plastic lenses, should be worn whenever there is danger of UF coming in contact
with the eyes
Metal or plastic rim safety spectacles with unperforated side shields with safety
lenses or suitable all plastic safety goggles may be used where continuous eye
protection in desirable, as in laboratories
f c Fo
op r i
yr ns
ig pe
ht ct
ow ion
ne pu
r r rp
eq os
ui es
re o
d nl
fo y.
ra
ny
ot
he
ru
se
.
8.4 Another Drotections:
Plastic shields with forehead protection may be worn where complete face
protection is desirable
"Hard"hats or soft-brimmed hats or caps may be worn to give protection against
filing objects or liquid leaks an splashes, respectively.
Leather or rubber or other imprevious may be worn to protect the body against
formaldehyde splashes.
Co
n
se
nt
o
Note : All the equipment of protection must be caremy kept, insppected,
cleaned and sterilized periodically.
9.- CHEMICAL AND PaYSICAL PROPERTIES
Color:
Colorless at 20 "C
Pungent and irritating
Odor:
Boiling Point:
> 100 "C
Inflammation Temperature (in closed recipiente):N.D.
Autoignition Temperature:
N.A.
Explosive Limits::
N.D.
1.20-1.30(depending on concentration
Density at 25/25 "C:
1
Solubility:
Soluble in water
EPA Export 25-07-2013:18:56:27
5
10.- STABILITYAND REACTIVITY
Concentrate of UF solutions can undergo a nonhazardous self-polymerization to form
pardormaldehyde which precipitates out of the solution
Oxigen fiom the air can oxidize concentrate of UF to formic acid, which is corrosive
Avoid contact with strong oxidizing agents, phenols, strong bases and copper, iron and
silver salts.
11.- TOXICOLOGICAL INF'OlU'VlATION
f c Fo
op r i
yr ns
ig pe
ht ct
ow ion
ne pu
r r rp
eq os
ui es
re o
d nl
fo y.
ra
ny
ot
he
ru
se
.
Acute inhalation effects:
Excesive vapor concentrations are readily attainable and may cause serious
adverse effects
Excessive exposure may cause severe irritation to upper respiratory tract and
lugs
Co
n
se
nt
o
Sings and symptoms of excessive exposure may be abdominal cramps andor
diarrhea
12.-ECOLOGICAL INFORMATION
Noxious for aquatic We
Do not drain down a sewer or surface waters
Formaldehyde can be degraded by certain bacteria in soil to carbon dioxide and
water
Bioaccumulation does not occur
13.-EL*IMINATIONSUBJET
The waste disposals resulting from this product, must be manager according to
the present legislation, specially in installations of eliminatiodvaluation
properly authorized.
I
EPA Export 25-07-2013:18:56:27
- ... - ... .. .. ... . . .
6
14.- TRANSPORT INFORMATION
Usual tanks : Stainless steel cistern with variable capacity
15.- INFORMATION ABOUT REGULATIONS
Exposure limits values : VLE - CM 1 ppm Portugese Norm NP - 1796 (1988)
16.- OTHER INF’ORMATIONS
he
ru
se
.
$6.1 Recommendations:
f c Fo
op r i
yr ns
ig pe
ht ct
ow ion
ne pu
r r rp
eq os
ui es
re o
d nl
fo y.
ra
ny
ot
The employees working in the handling, storage and shipping of formaldehyde
should be quali@and possess official licenses for such job.
16.2 Biblioeraohv:
A.- “Toxic and Hazardous - Industrial Chemicals Safety Manual” The
International Technical Information Insitute, Tokyo, Japan, 1978
-
Formaldehyde” Manufkcturing
nt
o
B.- “Chemical Safety Data Sheet SD - 1
Co
n
se
Chemists Association Inc. Washington, 1960
C.-“Product data sheet - Formalin LM 42” Perstorp Formox, Swedwn, May 22
1995
EPA Export 25-07-2013:18:56:27
.
3
-$
!'*
L 1 y
FORESA
I
ESPECIFICACIO
NES TECNICAS
Fecha:
17/01/01
Revision:
1
1de
Pa&
1
Control de
2alidad
CONCENTRADO UF-80
Parametro
Rango
Unidades
FormaIdehid0
56 = 57
OO
/
en peso
Urea
23 = 24
OO
/
en peso
se
.
(E.L.110 - 59)
to
f c Fo
op r i
yr ns
ig pe
ht ct
ow ion
ne pu
r r rp
eq os
ui es
re o
d nl
fo y.
ra
ny
ot
he
ru
(E.L.1 0 8 - 59)
Viscosidad a 25 O C
(E.L.102- 59)
1,300
CP
- 1,310
g/cm3
Co
ns
en
Densidad a 25 OC
(E.L.103- 59)
90 = 200
pH a 25 O C
6,5 = 8,O
Materia reactiva
79 = 81
Coeficiente de
expansi6n ciibica
0,0006
(E.L.104- 59)
OO
/
en peso
g/cms.oC
Observaciones:
EPA Export 25-07-2013:18:56:27
to
f c Fo
op r i
yr ns
ig pe
ht ct
ow ion
ne pu
r r rp
eq os
ui es
re o
d nl
fo y.
ra
ny
ns
en
Co
se
ru
he
ot
.
MELAMINE
EPA Export 25-07-2013:18:56:28
EPA Export 25-07-2013:18:56:28
se
Co
n
f c Fo
op r i
yr ns
ig pe
ht ct
ow ion
ne pu
r r rp
eq os
ui es
re o
d nl
fo y.
ra
ny
nt
o
se
.
ru
he
ot
Issue date: January 1 4 1996
Version: 2
Page 1 of 7
1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
Chemical product name
: Melamine
Common chemical name
: 2,4,6-triamino-1,3,5-triazine
Chemical formula
: C,H,N,
CAS no
: 108-78-1
EINECS no
: 203-615-4
se
.
Supplier's name and address
. D S M Melamine Americas, Inc D S M Melamine Limburg
P.O.Box 327
P.O. Box 43
ru
P.T. D S M Kaltim Melamine
ot
he
P.O.Box 4834 JKTM
Addis, Louisiana 707 10-0327
%
Jakarta 12510
Indonesia
(62) 21 7984261
Telefnx (62) 2'1 7984266
Telex 66075 DKM Jkt I A
6130 A A Sittard
The Netherlands
(311 46 4773854
Tslefar. (31) 46 4773049
Telex 36777
to
f c Fo
op r i
yr ns
ig pe
ht ct
ow ion
ne pu
r r rp
eq os
ui es
re o
d nl
fo y.
ra
ny
USA
(1) 504 685 3015
Telefax (1) 504 585 3003
Emergency tele'phone
8
I '
. : (3 1) 4 6 4765555
It.
ns
en
Emergency telefax
.*
: (311 46 4766440
Co
Transport emergencies for North and South America: CHEMTREC, (800) 424 9300
2. COMPOSlTlONllNFORMATION ON INGREDIENTS
~~
~~
~~
~~
~
Chemical name of substance
C A S no.
% (w/w)
2,4,6-triamino-l,3,5-triazine
108-78-1
>
Impurities contributing to the hazard:
99.8
~
Symbol
R phrases
none
none
Not applicable
3. HAZARDS IDENTIFICATION
Physicallchemical hazards
: Melamine is non-combustible and melaine dust is
weakly explosible.
Environmental hazards
: None.
Effect(s1 of (overlexposure
: Above threshold limit value of nuisance dust of 10
mg/m3,irritating to nose, throat and respiratory
tract. Mildly irritating to eyes.
8
DSM
r\
1?,
e
z
EPA Export 25-07-2013:18:56:28
Melamine
Page 2 of 7
Issue date: Januay 1 4 1996
Version: 2
Symptom(s1 of (overlexposure
I
Inhalation
: Irritating.
Ingestion
:
Skin contact
: Not irritating.
Eye contact
: Redness, pain.
> 10 g may result in abdominal pain.
4. FIRST AID MEASURES
: Rinse mouth with plenty of water. Consult a doctor
in event of complaints.
Inhalation
: Remove victim to fresh air. Consult a doctor in event
of complaints.
to
f c Fo
op r i
yr ns
ig pe
ht ct
ow ion
ne pu
r r rp
eq os
ui es
re o
d nl
fo y.
ra
ny
ot
he
ru
se
.
Ingestion
: Wash off with water and soap.
Skin contact
: ‘Wash out with plenty of water. Consult a doctor in
event of complaints.
Eye contact
Suitable
Co
Extinguishing media
ns
en
5. FIRE FIGHTING MEASURES
: Melamine is non-combustible, use water to cool. In
case of fire in immediate vicinity: use any extinguishing agent
Unusual fire and explosion hazards
: Melamine is non-combustible. It can however
Protection of firefighters
: Self-contained breathing equipment.
decompose when exposed to fire. In case of a lack
of oxygen, ammonia and hydrogen cyanide can be
formed upon decomposition.
6. ACCIDENTAL RELEASE MEASURES
I
Personal precautions
: As mentioned under heading 8.
Environmental precautions
: Not applicable.
Methods for cleaning up
: Collect spilled material in sealable containers.
Disposal according to local, provincial and federal
regulations.
Remarks
: Prevent formation of melamine dust.
P
EPA Export 25-07-2013:18:56:28
i
I:-1
'
--
Safety Data Sheet
a
--_
- -_
Conforms to /SO 11014-?:1994 (El
?.
Melamine
11
Issue date: Januay I",1996
Version: 2
1
7. HANDLING AND STORAGE
1
I/
Page 3 of 7
Handling
Technical measures
: Provide mechanical or natural ventilation to maintain
nuisance dust concentrations within acceptable levels.
Safe handling advise
: Avoid eye contact. Avoid breathing dust.
I
Storage
: Do not stack more than two bulk-bags > 1000 kg
on top of each other because of tear risk.
Storage conditions
: Store away from highly flammable substances. Keep
in a dry place.
Incompatible products
: None.
he
ru
se
.
Technical measures
f c Fo
op r i
yr ns
ig pe
ht ct
ow ion
ne pu
r r rp
eq os
ui es
re o
d nl
fo y.
ra
ny
en
to
Packagirrg materials
ns
(I.
I
Co
I
ot
\
: Exposure to high concentrations: dust mask.
: Not applicable.
: Not applicable.
: Safety goggles.
EPA Export 25-07-2013:18:56:28
a
Safety Data Sheet
Conforms to IS0 I 1014-I: 1994 (Eland 9 7/755/EEC
Melamine
Issue date: Januay la, 1996
Version: 2
Page 4 of 7
9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance
: Crystalline powder
Colour
: White
Odour
: Odourless
Molecular weight
: 126.13
Melting point
: 354
Boiling point
: sublimes
Decomposition temperature
: 354
Density
: 1573 kg/m3 (20 OC)
oc
to
f c Fo
op r i
yr ns
ig pe
ht ct
ow ion
ne pu
r r rp
eq os
ui es
re o
d nl
fo y.
ra
ny
ot
he
ru
se
.
oc
: 3 g/l(20 O C )
Solubility in water
Vapour pressure
: 0.204 mbar (20 OC)
pH (10 % slurry in water)
1
: typically 8.4 to 8.9
:
>
280 OC
Autoignition temperature
:
>
1050 O C
Dust explosion class
according to VDI 3673
: St. 1 (weakly explosible)
Ignition energy
:
Co
ns
en
Flash point
>
8700 mJ
10. STABILITY AND REACTIVITY
Stability
: Stable under normal storage conditions.
Conditions to avoid
: Avoid temperatures above 300 OC.
Hazardous decomposition products
: Melamine is stable under normal conditions.
In addition to carbon dioxide, carbon monoxide,
nitrogen and, to a little extent, nitrogen oxides, the
following decomposition products can be formed in
case of a lack of oxygen:
above 3 5 0 OC: ammonia.
above 550 OC: hydrogen cyanide.
Hazardous reactions
: Will not occur.
EPA Export 25-07-2013:18:56:28
I
I
-
-
j
Melamine
1
-
Page 5 of 7
Issue date: Januay "I*
1996
,
Version: 2
11. TOXICOLOGICAL INFORMATION
Acute toxicity
: LD,
LD,
LD,
LD,
Oral
: Mildly irritating.
Skin irritation
: Not irritating.
Sensitization
: Not sensitizing.
Chronic toxicity
:
se
.
Eye irritation
he
ru
c:
male rat: 3,100 mg/kg
female rat: 3,800 mg/kg
male mouse: 3,300 mg/kg
female mouse: 7,000 mg/kg
ot
to
f c Fo
op r i
yr ns
ig pe
ht ct
ow ion
ne pu
r r rp
eq os
ui es
re o
d nl
fo y.
ra
ny
: Environmental Protection Agency 1988: the risk on
bladder tumour promotion, posed by melamine, is
non-existent or at worst, extremely low.
Carcinogenicity
Mutagenicity
: Not mutagenic.
ns
en
~~
No relevant chronic toxicity.
Co
12. ECOLOGICAL INFORMATION
0
Mobi f ity
: Adsorption on soil is not expected.
Persistence and degradability
: The substance
Ecotoxicity
: Melamine has been shown to have low toxicity to
aquatic life.
is not readily biodegradable. It is
however inherently biodegradable.
96 h LC,, (for fish): > 3,000 mg/l
( = solubility melamine in water)
NOEC fish chronic test: > 1,000 mg/l
48 h LC,, (for Daphnia): > 2,000 mg/l
NOEC Daphnia magna 21 days: 18 mg/l
EC60 Algae: 940 mg/l
NOEC Algae: 320 mg/l
ECG0 bacteria: > 10,000 mg/l
EPA Export 25-07-2013:18:56:28
Page 6 of 7
Issue date: Januay Id. 1996
Version: 2
13. DISPOSAL CONSIDERATIONS
Responsibility of the receiver to have knowledge of national and local regulations.
: Please comply with all local, provincial and federal
regulations
Methods of disposal
14. TRANSPORT INFORMATION
-
: Not restricted.
Inland waterways
: Not restricted.
Sea
: Not restricted.
Air
: Not restricted.
f c Fo
op r i
yr ns
ig pe
ht ct
ow ion
ne pu
r r rp
eq os
ui es
re o
d nl
fo y.
ra
ny
ot
he
ru
se
.
Land RoadlRailway
15. REGULATORY INFORMATION
Responsibility of the receiver to have knowledge of national and local regulations.
to
EC Classification
: Not classified as a dangerous substance accor
EC criteria.
Co
ns
en
Label name
Hazard symbol
Risk phrases
Safety phrases
: None.
’
: None.
: None.
.-... .
HMlS rating:
Health
Flammability
Reactivity
WHMIS class
: 1
: o
: o
: D2B
EPA Export 25-07-2013:18:56:28
to
f c Fo
op r i
yr ns
ig pe
ht ct
ow ion
ne pu
r r rp
eq os
ui es
re o
d nl
fo y.
ra
ny
ns
en
Co
se
ru
he
ot
.
UREA FORMALDEHYDE
RESIN THAT WE
PURCHASE
EPA Export 25-07-2013:18:56:28
se
Co
n
f c Fo
op r i
yr ns
ig pe
ht ct
ow ion
ne pu
r r rp
eq os
ui es
re o
d nl
fo y.
ra
ny
nt
o
se
.
ru
he
ot
..
EPA Export 25-07-2013:18:56:28
a
c, Pt/2
.
Dynea Ireland Ltd
Marino Point,
Cobh,
Co. Cork.
Telephone:
+353-21-4855100
Facsimile:
+353-21-4855156
Emergency No: +353-21-4855120
-'-
Ireland Ltd.
SAFETY DATA SHEET
Liquid Urea Formaldehyde Resin
1. IDENTIFICATION OF THE PREPARATION AND THE COMPANY
SYNONYMS, TRADE NAMES:
Prefere 10F219 (L-219), Prefere 71 1485J (Urex 3485), Prefere 87 01640H
(CFL-3), Prefere 10F057 (C57), Prefere 11F311 (L-3 11) Prefere 10F58I8
SUPPLIER:
Dynea Ireland Ltd, Marino Point, Cobh, Co. Cork
TELEPHONE:
+353-(0) 21 4855100
EMERGENCY TELEPHONE:
Tel: +353 (0) 21 4855120 (24 Hours)
ot
he
ru
se
.
Liquid Urea Formaldehyde Resin
to
f c Fo
op r i
yr ns
ig pe
ht ct
ow ion
ne pu
r r rp
eq os
ui es
re o
d nl
fo y.
ra
ny
I
CHEMICAL NAME:
2. COMPOSITION/INFORMATIONON INGREDIENTS
INGREDIENT NAME:
CAS No.
CONTENTS
HEALTH
(class)
RISK (R.No.)
FORMALDEHYDE:
50-00-0
4 %
T,
23/24/25
34,40,43
60-75%
3. HAZARDS IDENTIFICATION
Co
ns
en
UREA-FORMALDEHYDE POLYMER:
Not regarded as a health hazard under current legislation.
4. FIRST AID MEASURES
i
EYES:
Promptly wash eyes with lots of water while lifting the eye lids. Contact
physician if irritation persists.
SKIN :
Remove affected person from source of contamination. Promptly wash
contaminated skin with soap or mild detergent and water. Promptly
remove clothing if soaked through and wash as above.
INHALATION:
Move the exposed person to fresh air at once.
INGESTION:
Promptly let affected person drink lots of water to dilute the swallowed
chemical. Do not induce vomiting. Get medical attention immediately.
5. FIRE FIGHTING MEASURES
EXTINGUISHING MEDIA:
This material is not flammable. Use extinguishing media appropriate for
surrounding fire.
UNUSUAL FIRE & EXPLOSION
No unusual fire or explosion hazards noted.
EPA Export 25-07-2013:18:56:28
Urea Formaldehyde Resin
Page 2 o f 4
HAZARDS:
HAZARDOUS DECOMPOSITION
PRODUCTS:
,
.
High temperatures generate Carbon Monoxide (CO) and Carbon
Dioxide (COz).
6. ACCIDENTAL RELEASE MEASURES
SPILL CLEANUP METHODS:
GENERAL:
Runoff or release to sewer, waterway or ground is forbidden.
ABSORB:
Absorb in vermiculite, dry sand or earth and place into containers.
COLLECT:
Shovel into dry containers. Cover and move the containers. Flush the area
with water.
Prior to flushing, consult Local Water Authorities.
Avoid skin and eye contact. Ventilate well, avoid breathing
vapours. Use approved respirator if air contamination is above
Accepted level.
STORAGE PRECAUTIONS:
Keep in cool, ventilated storage and closed containers.
f c Fo
op r i
yr ns
ig pe
ht ct
ow ion
ne pu
r r rp
eq os
ui es
re o
d nl
fo y.
ra
ny
ot
he
ru
se
.
USAGE PRECAUTIONS:
8. EXPOSURE CONTROLS AND PERSONAL PROTECTION
INGREDIENT NAME:
FORMALDEHYDE
CASNo. STD
LTEXP
50-00-0
2 ppm
No std.
UREA FORMALDEHYDE POLYMER:
STEXP
(10min)
2ppm
No std.
se
nt
o
PROTECTIVE EQUIPMENT:
MEL
(Shrs)
Co
n
0
7. HANDLING AND STORAGE
RESPIRATORS
No specific recommendation made, but respiratory protection must be used
if the general level exceeds the Occupational Exposure Level (OEL).
PROTECTIVE GLOVES
Chemical resistant gloves required for prolonged or repeated contact. Use
protective gloves made of rubber or plastic.
EYE PROTECTION
Wear chemical safety goggles where eye exposure is reasonably probable.
OTHER PROTECTION
Use engineering controls to reduce air contamination to permissible level.
9. PHYSICAL AND CHEMICAL PROPERTIES
COLOUR:
APPEARANCE:
ODOUIUTASTE:
SOLUBILITY DESCRIPTION:
VISCOSITY (25C):
White
Liquid.
Formaldehyde
Soluble in water
0.1-2 Pas
EPA Export 25-07-2013:18:56:28
. ' 3
3
D
Page 3 o f 4
Urea Formaldehyde Resin
*
-
'
a
pH VALUE:
10. STABILITY AND REACTIVITY
Ca. 8
STABILITY:
Avoid contact with acids.
HAZARDOUS DECOMPOSITION:
PRODUCTS:
High temperatures generate Carbon Monoxide (CO) and Carbon Dioxide
(C02).
11. TOXICOLOGICAL INFORMATION
>5000 mgkg (oral rat)
No data available
HEALTH WARNINGS:
Exposure: This chemical has good warning properties.
MEDICAL SYMPTOMS:
Irritation of eyes and mucous membranes
TOXICOLOGICAL INFORMATION:
Information relevant to formaldehyde toxicity. In the
EU formaldehyde is classified as a Category 3 carcinogen. This means that
formaldehyde is not known to be carcinogenic to man (Category l), or
regarded to be carcinogenic to man (Category 2). Although at high
concentrations, formaldehyde has been shown to cause cancer in rats, there
is no convincing evidence that the substance induces cancer in man. For
this reason formaldehyde has been placed in the lowest Category 3.
CARCINOGENICITY:
Formaldehyde is classified as a Cat.3 Carcinogen (EU)
f c Fo
op r i
yr ns
ig pe
ht ct
ow ion
ne pu
r r rp
eq os
ui es
re o
d nl
fo y.
ra
ny
ot
he
ru
se
.
a
TOXIC DOSE - LD50:
TOXIC CONC. LC50:
12.-ECOLOGICAL INFORMATION
Urea formaldehyde Polymer: Slowly, but not readily biodegradable.
TOC - removal 28 days: 61% BOD28: 0.62 mg/mg substance.
Nitrification 28 days: 0.45 mg N03-N/mg substance. Formaldehyde; No
bioconcentration. Biodegradation: BODYCOD: 0.68 (readily
biodegradable).
se
nt
o
DEGRADABILITY:
Co
n
w
ACUTE FISH TOXICITY:
a
Formaldehyde - LC50 1.OOO - 100 mg/L (96h)
Urea-Formaldehydepolymer - very IOW toxicity, no inhibition
of activated sludge at 140 mg/L suspended solids.
13. DISPOSAL CONSIDERATIONS
~~~
~~
~
When cured, the resin may be disposed on an ordinary landfill.
Dynea material must be disposed of in accordance with EPA (or other
relevant legislative) requirements. Advice, if required, on the disposal of
waste Dynea Products is available from Dynea Ireland Ltd.
DISPOSAL METHODS
14. TRANSPORT INFORMATION
LABEL FOR CONVEYANCE:
No transport warning sign required.
15. REGULATORY INFORMATION
~
LABEL FOR SUPPLY:
No classification given.
RISK PHRASES:
Not Classified
SAFETY PHRASES:
S-26
In case of contact with eyes, rinse
EPA Export 25-07-2013:18:56:28
Urea Formaldehyde Resin
Page 4 o f 4
S-36/37/39
s-44
‘S-51
Immediately with plenty of water and seek medical
advice.
Wear suitable protective clothing, gloves and
Eyelface protection.
If you feel unwell, seek medical advice (show label if
possible)
Use only in well ventilated areas.
16. OTHER INFORMATION
INFORMATION SOURCES
Dynea UK Safety Manual NO. AD2 “Handling Precautions for
Formaldehyde-based Products, Vinyl Emulsions and Hot-melt adhesives”
0
Co
ns
en
to
f c Fo
op r i
yr ns
ig pe
ht ct
ow ion
ne pu
r r rp
eq os
ui es
re o
d nl
fo y.
ra
ny
ot
he
ru
se
.
REVISION DATE: 28/01/04
EPA Export 25-07-2013:18:56:29
...
. ... .
.....- -
SAFETY DATA SHEET
Liquid Urea Formaldehyde Resin
I IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND THE COMPANY
Liquid Urea Formaldehyde Resin
PRODUCT NAME:
f c Fo
op r i
yr ns
ig pe
ht ct
ow ion
ne pu
r r rp
eq os
ui es
re o
d nl
fo y.
ra
ny
ot
TEL:
ru
Dynocheni UK Ltd,
Alyn Works,
Denbigh Road,
Mold, Flintshire, CH7 1BF Wales.
(01352) 757657
SUPPLIER
he
bi
se
.
SYNONYMS, TRADE NAMES: Aerolite 300, Aerolite G, Aerolite KL,Aerolite UL 4330, Aerolite UL 5144,
Aerolite V, Resin DUL 5289, DUL 5342, DUL 5639, DUL 5678.
EMERGENCY TELEPHONE(S):
Tel: 01352 750116 (21 Hours)
2 COM POSITION/INFORMATION ON INGREDIENTS
CAS No.
nt
o
INGREDIENT NAME
50-00-0
Co
n
se
FORMALDEHYDE
UREA-FORMALDEHYDE POLYMER
' 0
CONTENTS
1-3 u/ow/w
60-75 %,\vIw
HEALTH
RISK
(CliISS)
(R No.)
23/24/25, 34, 40,
43
T
3 HAZARDS IDENTIFICATION
Irritating to eyes, respiratory system and skin.
Possible risk of irreversible effects.
May cause sensitisation by skin contact.
INHALATION:
Move the exposed person to fresh air at once.
INGESTION:
Promptly get affected personnel to drink large volumes of water to dilute the
swallowed chemical. Do not induce vomiting (induction of vomiting should
only be performed upon the advicc of qualified niedical personnel). Get medical
attention immediately. and rinse the mouth repeatedly \vith water.
SKIN:
Remove aflected person froni sourcc of contamination. Wash the skin
immediately with soap and ufater.
Safechem N o :11019
Page 1 1 5
>>>
EPA Export 25-07-2013:18:56:29
1
-
I-".
Liquid Urea Formaldehyde Resin
EYES:
'
EXTINGUISHING MEDIA:
Promptly wasI1 eyes with plenty of water while lifting the eye lids. Contact
physician if irritation persists.
This material is not flammable. Use estinguishing media appropriate for
surrounding fire.
UNUSUAL FIRE & EXPLOSION HAZARDS:
N o unusual fire or esplosion hazards noted.
6 ACCIDENTAL RELEASE MEASURES
GENEW.
Runoff or release to sewer, ivatenvay or ground is forbidden.
ABSORB.
Absorb in vermiculite, dry sand or earth and place into containers.
COLLECT.
Shovel into dry containcrs. Cover and move the containers. Flush the area with
water. Prior to flushing, consult Local Water Authorities.
USAGE PRECAUTIONS:
Avoid skin and eye contact. Ventilate well, avoid breathing vapours. Use
approved respirator if air contamination is above accepted level.
STORAGE PRECAUTIONS:
Keep in cool, dry, ventilalcd storage and closed containers.
Co
n
se
nt
o
f c Fo
op r i
yr ns
ig pe
ht ct
ow ion
ne pu
r r rp
eq os
ui es
re o
d nl
fo y.
ra
ny
ot
he
ru
se
.
SPILL CLEANUP METHODS:
I
8 EXPOSURE CONTROLS AND PERSONAL PROTECTION
INGREDIENT NAME
CAS No
STD
LT EXP
(8 hrs)
50-00-0
FORMALDEHYDE
UREA-FORMALDEHYDE POLYMER
MEL.
2 PPm
N o Std
ST EXP
(15 min)
2 PPm
No Std.
PROTECTIVE EQUIPMENT
RESPIRATORS:
N o specific recommendation made, but respiratory protection must be used if the
general level esceeds the Occupational Esposure Level (OEL).
PROTECTIVE GLOVES:
Chemical resistant gloves required for prolonged or repeated contact. Use
protective gloves made of: Rubber, neoprene or PVC.
EYE PROTECTION:
Wear approved chemical safety goggles where eye esposure is reasonably
probable.
Safechem N o :11019
Page 2 1 5
>>>
EPA Export 25-07-2013:18:56:29
.
..
-
Liquid Urea Formaldehyde Resin
OTHER PROTECTION:
Use engineering controls to reduce air contamination to permissible exposure
level.
AL AND CHEMICAL PROPERTIES
APPEARANCE:
ODOUR/TASTE:
SOLUBILITY DESCRIPTION:
pH-VALUE:
VISCOSITY:
Liquid.
Formaldehyde
Soluble in water.
8.0-8.5
1.00 11.00 Pas @ 25 OC
STABILITY:
See Technical Information
ZONDITIONS TO AVOID:
Avoid contact with acids.
COLOUR:
White.
I)H-VALUE,CONC:
-
FLASH POINT (“C):
8.5-8.8
>IO0
- Dynochem UK Ltd.
I I TOXICOLOGICAL INFORMATION
to
f c Fo
op r i
yr ns
ig pe
ht ct
ow ion
ne pu
r r rp
eq os
ui es
re o
d nl
fo y.
ra
ny
ot
he
ru
se
.
HAZARDOUS DECOMPOSITION PRODUCTS:
High temperatures generate: Carbon monoxide (CO). Carbon dioxide (C02).
Ammonia or amines.
Co
ns
en
>5000mg/kg (oral rat)
rOXIC DOSE1- LD50:
No data available.
r o x I c CONC.- L C ~ O :
rOXICOLOGICAL INFORMATION:
Information relevant to formaldehyde toxicity:’ In the EU formaldehyde is
classified as a Category 3 Carcinogen. This means that formaldehyde is not
known to be carcinogenic to man (Category I), or regarded to be carcinogenic to
man (Category 2). Although at high concentrations, formaldehyde has been
shown to cause cancer in rats, there is no convincing evidence that the substance
induces cancer in man. For this reason formaldehyde has been placed in the
lowest Category 3.’
[EALTH WARNINGS:
Exposure; This chemical has good
warning properties. Irritant of eyes and
mucous membranes.
Mild dermatitis. allergic skin rash.
ITHER HEALTH EFFECTS:
Formaldehyde is classificd as a Category 3 Carcinogen (EEC),
IEDICAL SYMPTOMS:
Irritation of eyes and mucous membranes.
2 ECOLOGICAL INFORMATION
EGRADABILITY:
Formaldehyde: No bioconcentration.
Urea formaldehyde polymers are slowly,but not .readily biodegradable.
3 DISPOSAL CONSIDERATIONS
Fechem No : I 1019
Page 3 / 5
>>>
EPA Export 25-07-2013:18:56:29
Liquid Urea Formaldehyde Resin
DISPOSAL METHODS:
Dynochem materials must be disposed of in accordance with the requirements
of 'The Special Waste Regulations 1996'. Advice if required, on the disposal of
waste Dynochem Products is available from Dynochenl UK Ltd.
LABEL FOR CONVEYANCE:
No transport warning sign required.
ROAD:
ROAD TRANSPORT NOTES:
No label required for Road Transport
RAIL
No label required for Rail Transport
SEA:
SEA TRANSPORT NOTES:
No label required for Sca Transport
AIR:
AIR TRANSPORT NOTES:
No label required for Air Transport
to
f c Fo
op r i
yr ns
ig pe
ht ct
ow ion
ne pu
r r rp
eq os
ui es
re o
d nl
fo y.
ra
ny
ot
he
ru
se
.
RAIL TRANSPORT NOTES:
Possible risk of irreversible effects.
May cause sensitisation by skin contact.
R-40
R-43
Co
RISK PHRASES:
ns
en
HARMFUL
SAFETY PHRASES:
In case of contact with eyes, rinse irnmcdialely with plenty
S-26
S-36/37/39
S-5 I
of water and seek medical advice.
Wear suitablc protective clothing, gloves and eyeiface
protection.
Use only in well ventilated areas.
UK REGULATORY REFERENCES:
T h e Control of Substances Hazardous to Health Regulations.
The Chemicals (Hazard Informalion and Packaging for Supply) Regulations.
EH40 Occupational Esposure Limits.
Carriage of Dangerous Goods (Classification, Packaging, and Label1ing)and use
of Pressure Receptacle Regulations.
Carriage of Dangerous Goods by Road Regulations.
Special Waste Regulations 1996 (SI 1996 NO. 972).
Health and Safety at Work Act 1971.
INFORMATION SOURCES:
Dynochem
UK Ltd Safety Manual
/
No.AD2
'Handling Precautions for Formaldehyde-based Products.Vinyl Emulsions and
Safechem No :11019
Page 4 1 5
>>>
EPA Export 25-07-2013:18:56:29
se
Co
n
f c Fo
op r i
yr ns
ig pe
ht ct
ow ion
ne pu
r r rp
eq os
ui es
re o
d nl
fo y.
ra
ny
nt
o
se
.
ru
he
ot
REVISION DATE:
Safechem No :11019
EPA Export 25-07-2013:18:56:29
EPA Export 25-07-2013:18:56:29
se
Co
n
f c Fo
op r i
yr ns
ig pe
ht ct
ow ion
ne pu
r r rp
eq os
ui es
re o
d nl
fo y.
ra
ny
nt
o
se
.
ru
he
ot
se
f c Fo
op r i
yr ns
ig pe
ht ct
ow ion
ne pu
r r rp
eq os
ui es
re o
d nl
fo y.
ra
ny
nt
o
se
.
ru
he
ot
I
Co
n
1
UREA FOFUMALDEHYDE
VENEERING RESIN
EPA Export 25-07-2013:18:56:29
f c Fo
op r i
yr ns
ig pe
ht ct
ow ion
ne pu
r r rp
eq os
ui es
re o
d nl
fo y.
ra
ny
nt
o
se
.
ru
he
ot
...
se
. .
Co
n
I
,
i
EPA Export 25-07-2013:18:56:29
1-
REVISION DATE :04-03-2004
.-
U
i
S A F E N DATA SHEET
Prefere 4752 (Aerolife
I IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND
COMPANYIUNDERTAKING
Prefere 4152 (Aerolite V)
Urea formaldehyde resin used for veneering.
SUPPLIER
Dynea UK Ltd.
Alyn Works,
Denbigh Road,
Mold, Flintshire CH7 1BF
Tel: 01352 757657
Emergency Tel: 01352 750416
f c Fo
op r i
yr ns
ig pe
ht ct
ow ion
ne pu
r r rp
eq os
ui es
re o
d nl
fo y.
ra
ny
ot
he
ru
se
.
PRODUCT NAME
APPLICATION
The Full Text for all R-Phrases are Displayed in Section 16
3 HAZARDS IDENTIFICATION
se
4 FIRST-AID MEASURES
nt
o
Limited evidence of a carcinogenic effect. May cause sensitisation by skin contact.
CLASSIFICATION
Carc 3;R40. R43.
Co
n
a
GENERAL INFORMATION
Remove victim immediately from source of exposure. Provide rest, warmth and fresh air. Get medical attention if any
discomfort continues. Keep affected person under observation. If unconcious, loosen tight clothing. Place unconscious
person on the side in the recovery position and ensure breathing can take place. Perform artificial respiration if breathing
has stopped.
INHALATION
Move the exposed person to fresh air at once. Get medical attention if any discomfort continues.
INGESTION
Rinse mouth thoroughly. DO NOT induce vomiting. Get medical attention immediately.
.\
SKIN CONTACT
Wash skin with soap and water. Remove contaminated clothing.
EYE CONTACT
Promptly wash eyes with plenty of water while lifting the eye lids. Continue to rinse for at least 15 minutes. Get medical
attention promptly if symptoms occur after washing.
5 FIRE-FIGHTING MEASURES
EXTINGUISHING MEDIA
Use fire-extinguishing media appropriate for surrounding materials.
SPECIAL FIRE FIGHTING PROCEDURES
Cool containers exposed to flames with water until well after the fire is out.
SPECIFIC HAZARDS
Fire creates: Carbon dioxide (C02). Carbon monoxide (CO). Nitrous gases (NOX).
EPA Export 25-07-2013:18:56:29
$
REVISION DATE .04-03-2004
.
Prefere 4152 (Aerolite V)
'J .!
*'
c
PROTECTIVE MEASURES IN FIRE
Self contained breathing apparatus and full protective clothing must be worn in case of fire.
I
6 ACCIDENTAL RELEASE MEASURES
PERSONAL PRECAUTIONS
Wear protective clothing as described in Section 8 of this safety data sheet.
ENVIRONMENTAL PRECAUTIONS
Product is partly soluble in water. Stop leak without risk. Do not discharge into drains, water courses or onto the ground.
SPILL CLEAN UP METHODS
Absorb in vermiculite, dry sand or earth and place into containers. Remove containers and flush area with water. Inform
Authorities if large amounts are involved. For waste disposal, see section 13.
7 HANDLING AND STORAGE
USAGE PRECAUTIONS
Avoid spilling, skin and eye contact. Provide good ventilation. Eye wash facilities should be available when handling this
product.
USAGE DESCRIPTION
Read and follow manufactureh recommendations.
STORAGE PRECAUTIONS
Keep containers tightly closed.
8 EXPOSURE CONTROLS/PERSONAL PROTECTION
OES
-
LT mg/m3
2.5 mglm3
.
SODIUM HYDROXIDE
LT-ppm
2 ppm
se
Std
MEL
ru
Name
ST - ppm
2 PPm
-
ST mgIrn3
2.5 mglm3
to
f c Fo
op r i
yr ns
ig pe
ht ct
ow ion
ne pu
r r rp
eq os
ui es
re o
d nl
fo y.
ra
ny
ot
he
-FORMALDEHYDE...%
2 mglm3
ns
en
INGREDIENT COMMENTS
MEL = Maximum Exposure Limit. OES = Occupational Exposure Standard. Sk = Skin Absorption
PROTECTIVE EQUIPMENT
Co
PROCESS CONDITIONS
Provide eyewash station.
ENGINEERING MEASURES
Provide adequate general and local exhaust ventilation.
RESPIRATORY EQUIPMENT
Respiratory protection must be used if air contamination exceeds acceptable level.
HAND PROTECTION
Chemical resistant gloves required for prolonged or repeated contact. Polyvinyl chloride (PVC). Rubber (natural, latex).
Neoprene.
EYE PROTECTION
Wear approved safety goggles.
OTHER PROTECTION
Wear appropriate clothing to prevent any possibility of skin contact.
9 PHYSICAL AND CHEMICAL PROPERTIES
APPEARANCE
Liquid
COLOUR
Colourless to White
ODOUR
Formaldehyde
SOLUBILITY
Slightly soluble in water.
BOILING POINT ("C)
pH-VALUE, CONC. SOLUTION
FLASH POINT ("C)
8-9
> 100 CC (Closed cup).
>loo
RELATIVE DENSITY
VlSCOSlN
1.28-1.31 @ 25 "C
1000-2200 mPas @ 25 "C
EPA Export 25-07-2013:18:56:29
Prefere 4452 (Aerolite
STABIL I N
Stable under normal temperature condhons. Storage at higher temperatures will give increased viscosity. This gives a
decrease in shelf-life.
HAZARDOUS DECOMPOSITION PRODUCTS
None at ambient temperatures. Fire or high temperatures may form harmful vapours (CO, C02, NOx).
f c Fo
op r i
yr ns
ig pe
ht ct
ow ion
ne pu
r r rp
eq os
ui es
re o
d nl
fo y.
ra
ny
ot
he
ru
se
.
TOXICOLOGICAL INFORMATION
LD50 (oral,rat): 800mg/kg (formaldehyde)
Formaldehydeis a category 3 carcinogen.
GENERAL INFORMATION
Irritant properties are the main hazard.
INHALATION
Vapour may irritate respiratory system or lungs. Gas or vapour is harmful on prolonged exposure or in high
concentrations.
INGESTION
May cause stomach pain or vomiting.
SKIN CONTACT
Slightly irritating. Prolonged or repeated exposure may cause severe irritation.
EYE CONTACT
Irritating to eyes. Repeated exposure may cause chronic eye irritation.
HEALTH WARNINGS
Mild dermatitis, allergic skin rash.
Inhalation of high volume of vapour may cause: Irritation of nose and throat. Ingestionmay cause: Stomach pain.
MEDICAL SYMPTOMS
Nausea, vomiting. Sneezing. Eczematous irritation.
MEDICAL CONSIDERATIONS
Skin disorders and allergies.
Co
n
se
nt
o
EGOTOXICITY
The product is not expected to be hazardous to the environment.
MOBILITY
Partially water soluble.
BIOACCUMULATION
No bioaccumulationexpected.
DEGRADABILITY
The product is expected to be slowly biodegradable.
ACUTE FISH TOXICITY
Polymer: Low toxicity expected.
13 DISPOSAL CONSIDERATIONS
DISPOSAL METHODS
Dispose of waste and residues in accordance with local authority requirements.Confirm disposal procedures with
environmental engineer and local regulations.
ADR CLASS
Not classified for transport:
ADRIRIDIIMDGIIATAICDG
CPU
LABELLING
3 14
EPA Export 25-07-2013:18:56:29
i ’
.
Prefere 4152 (Aerolite b!l
?
F
Harmful
CONTAINS
FORMALDEHYDE ...%
RISK PHRASES
Limited evidence of a carcinogenic effect.
May cause sensitisation by skin contact.
R40
R43
SAFETY PHRASES
Wear suitable protective clothing, gloves and eyelface protection.
S36137139
This material andlor its container must be disposed of as hazardous waste.
S60
UK REGULATORY REFERENCES
EH40 Occupational Exposure Limits.
EU DIRECTIVES
Dangerous Substance Directive 67/548/EEC. Dangerous Preparations Directive 88/379/EEC. Safety data sheet directive
911155.
16 OTHER INFORMATION
04-03-2004
f c Fo
op r i
yr ns
ig pe
ht ct
ow ion
ne pu
r r rp
eq os
ui es
re o
d nl
fo y.
ra
ny
ot
he
ru
RISK PHRASES IN FULL
NC
Not classified.
Toxic by inhalation, in contact with skin and if swallowed.
ma24125
se
.
REVISION COMMENTS
Change of product name.
REVISION DATE
Causes bums.
Causes severe bums.
R37
R40
R43
Irritatingto respiratorysystem.
Limited evidence of a carcinogenic effect.
May cause sensitisationby skin contact.
Co
n
se
nt
o
R34
R35
4 14
EPA Export 25-07-2013:18:56:29
se
Co
n
f c Fo
op r i
yr ns
ig pe
ht ct
ow ion
ne pu
r r rp
eq os
ui es
re o
d nl
fo y.
ra
ny
nt
o
se
.
ru
he
ot
HOT MELT ADHESIVE
FOR EDGE BANDING
EPA Export 25-07-2013:18:56:29
EPA Export 25-07-2013:18:56:29
se
Co
n
f c Fo
op r i
yr ns
ig pe
ht ct
ow ion
ne pu
r r rp
eq os
ui es
re o
d nl
fo y.
ra
ny
nt
o
se
.
ru
he
ot
G
I
Tel.N r .:
-
05021 /a8 241
T e l . N r , : 05021/88-241
f c Fo
op r i
yr ns
ig pe
ht ct
ow ion
ne pu
r r rp
eq os
ui es
re o
d nl
fo y.
ra
ny
ot
he
ru
se
.
Information ~ r l pproduo4
Trade name: EAKOLL-SK K4/384/LV
i
Chemical cbaractmrik3t.h
Co
ns
en
to
( p reparatiom )
\
::
j
''
!
' &
I
_
-
I
FIRST x h
&bUkLES
t
!
I
mdz- d
fnformtion
!
I
kl;;sftfi hazard ,ariees from the solid BUbctance. Bpcauee
\e h i g h working temperature. the danger of burns exists.
EPA Export 25-07-2013:18:56:29
-
SAFETY DATA SHE3ET IN ACCORDANCE WITH 91/1$5/EEC
EC-Safety data sheet
W
bate p r i n t e d :
:DNR..
Amended o n :
6.10.94
13 . 0 4 . 9 4
, :
rade name:
._
RAKOLL-SIC. K4/58rnV
H,B.Fuller
4.2
OII inhalation
vapsurs a t e inhaled when working on tbe melt, provide f r e s h
air. In case of irritation of t h e respiratory system, seek
medical attentioa,
4.3
On
Page:
2
Version;
1
GmbH
Nienklurg
If
contact with the skin
Treat a s f o r burns: cm coatact with the molten p r o d u c t , cool
quickly with cold water. Do not remove solidified praduct
from the s k i h . Seek medical attention.
On contact with the eye
After contact of hot melt with the
se
.
e y e s , wash immediately
u n d e r running water for 15 minutes ahd seek medical attentioa!
he
ru
4.4
1
On s w d o w i a g
g.6
Information for the physician
f c Fo
op r i
yr ns
ig pe
ht ct
ow ion
ne pu
r r rp
eq os
ui es
re o
d nl
fo y.
ra
ny
ot
4.5
Consult a physician.
--
.-
FUWl?%GEITINGMEASURES
;. 1
Suitable extinguishers
A d a p t to fire'e surroundings: water, foam, powder, c02, sand
i. 2
Extiaguiehers unsuitable cm safety grounds
not ap plicabla
i. 3
Particular hazards aesociated with tho sabatance,
its cmmbustion products or
resulting gasea
PlIain combusfjon products: CO, 1202. acrolein and acetic acid.
i. 4
Particular pxotective equipment
Wear breathing Drotectioh which is indeaendebt of the
Co
n
se
nt
o
i
surrounding air.
-
-
-
MEASUIFLES TO
i
5.1
i.2
BE TAREN ON ACCIDENTALkELEASE
Precaut$onary m e a ~ u r e sfor humans
a r e needed far spilt granulate.
If melt leaks a u t , take precautions to avoid burns.
N o pertieuIar precautions
Precautionary m e a e u ~ e sfor the sm~iroanrent
N o gpacial precautions necessary
a
I .
3
Method for cleasing/spillagc
Cleau up any spilt granula:
'.-X-F-:
,:io= . f a k e d melt t o cool.
EPA Export 25-07-2013:18:56:29
E C - S a f e t y data aheet
Rate printed:
KDNR.
.
.
Versioa:
13 . 0 4 , 9 4
:
I
RAKOLL-SK Kq/s8mv
Trada name:
6.4
Amended on:
6.10.94
Pagar.
H.3 .Fuller
9
1
-
GmbH N i a n b u r g
Addition4 infarmation
nQ?H
I
I
I
_
7
&LING
7.1
Bandling
I
AND STORAGE
hformation
d o bandling
No special protective meaaures n e e d e d
ru
se
.
Iaformatioa o n protectian 3gaiBst fire and explosion
special precautions a e c e s m r y .
7.2
Storage
f c Fo
op r i
yr ns
ig pe
ht ct
ow ion
ne pu
r r rp
eq os
ui es
re o
d nl
fo y.
ra
ny
ot
he
No
Requiremeats for storeraoms and containers
Store d r y .
Infarmation on storage together with other subsltaaeee
net applicable
Storage temperature :
10 20 ' C
Co
n
se
nt
o
-
8
LIMITS OF EXPOSURE AND EQTJS2-T
8.1
Additiuaal informatioh 0x1 the nature cvf technical equipment
Provide adequate ventilatiozl at the workplace,
8.2
Components with workplace-relevant concentration linnits
8 3
Personal protective equipment
~
-
FOR PERSONAL PROTECTION
General protecztfon and hygiene P2888nre8
W h e n handling t h e melt, do not inhale vapoure and avoid
contact with t h e s k i n .
Breaching pretectian
Not Decessary where room is adequately ventilated.
Hand
protection
E m f - r e s i s t a n t gloves a r e t o be worn only when handling t h e
melt.
Eye protection
Fully enclosed p r o t e c t i v e glaases for hahdling the melt.
Body protection
W e a r suitable industrial c l o t h i n g .
EPA Export 25-07-2013:18:56:29
.
-
EC-Safety data sheet
Page:
4
9
Appearance
Form :
granulate
B e i g e ,RAL 1001
neutral
Colour :
Odour:
Data relevant bu safety
CHANGE OF CONDITION
TEMPERATURE
ACCORbXNG TO
-
96
-
he
' C (at
81 " C
'C
to
f c Fo
op r i
yr ns
ig pe
ht ct
ow ion
ne pu
r r rp
eq os
ui es
re o
d nl
fo y.
ra
ny
Inflammability :
Ignition temper- :
approx.
Self -igniting properties :
Fire promotiag propertiee:
73
ot
.
Boiling p {range:
approx ,
Softening p , /range: a p p r u x .
Hardening p . lrange:approx.
Dropping p . / r a h g e : a p p r o x .
Melting p . /range:
approx.
Flame point:
approx.
ru
se
.
TESTED
"C
104 "C
"C
4 c
Co
9.2
ns
en
9.1
--.
Explosiolr haeard :
lowst:
EXPLOSION LUMITS
Vapour preBeure
..
...- .
density. - .
Density
Bulk
I
1,54
:
-
upper:
:
n.a.
hPa
hPa
hPa
(at
(at
(at
g/cm'
(at
kg/mJ
(at
20
'C>
HBF
Solubility
in water:
app,
g/l
[at
ia
. app.
g/l
(at
PE value;
(at
gli water) (at 25°C)
iasoluble.
-
Dia t rib 11Cion c oefficielr t E octan01/uratet
log POW
Compoaents :
Viscosity
approx.
80000 mPas 20.: ' C Brookfield
.
i
C
.--
RVT
HEF
EPA Export 25-07-2013:18:56:29
SAF'ETY DATA SHEET I
NACCORDANCE WITH 91/1$5/EEC
m
EC-Safety data sheet
Date printed:
. :
KDNrR.
.
Trade name:
6.10.94
Amended on:
Page:
Versim:
13.04.96
,
6
1
-
RAICOLL-SK K4!58ULV
H . B . F u l l e r GmbH Nienburg
INFORMATION ON ECOLOGY
12.1
Details of elimination lperslstehcs aad deconylosition)
12.2
Properties relevant to the ecology
12.3
Ecataxic effeota
12.4
Further detaile ob ecology
13
INFOEMATION ON DISPOSAL
-
ot
he
ru
se
.
12
Prodact
to
f c Fo
op r i
yr ns
ig pe
ht ct
ow ion
ne pu
r r rp
eq os
ui es
re o
d nl
fo y.
ra
ny
13.1
Waste Ire&
Waste :
Duty of ptoviding evidence:
RscommmndaWn :
- +
,Contarnipatad aackaPing
Becmunendation :
Recommendation : Empty package of all residue@ ( d r i p free,
run f r e e , scraped but). Channel. package preferab1.y into
Co
ns
en
13.2
local r e u s e / r e c y e l i a g while abserving localihational
regulations.
Reemtm- cleaning agent:
n o t applicable
14
INFORMATION ON T W S P O B T
14.1
Overland tranepdrt APR/RfD and GGVSlGGVJE
ADR/RID-QGVS/E Class
Warning notice ->
Hazard-nr :
Description af gaode :
Number/letrer:
S u b s t . -nr:
Remarks :
Not a hazardous s u b s t a n c e in terms of transport regulations.
14.2
Transport an domeelic waterways
ADNf AD N R
Clags
Warning natioe - Z
Category:
DeecripClas of goods I
Remarks :
AaN/AUNB
Nwnher/letter:
not applicable
EPA Export 25-07-2013:18:56:30
4
7/>0
'94
710 ' 9 4
B 3 5 3 1 8731952
B + 4 8 5021 88170
08:55
08:43
+++ FINSA FOREST
+++ N U IRLW
N.A.A.
B F - N I EllPORT
---F-
@001/004
@006/003
-
-1-
-
--
SAF'EW DATA SHEET IN ACGORlDANCE WITH 9Ul!j5/EEC
I :'
EC-Safety data sheet
Date printed:
. . :
Amended on:
6.10.94
13 . 0 4 , 9 4
KDNR.
T r a d e name:
Paga:
5
Version:
1
-
RAKOLL-SK K4/ssultV
H.B .Fuller GrobH Nienburg
TESTED ACCORDING-TO
. - . - .:
. . . . - . .:
Solvent separation test
Solvent content - .
Further iaformatinm
.--
AND REACTNITY
be avoided
.
COAdition8 t o
not applicable
se
STABILITY
-
10.2
to
f c Fo
op r i
yr ns
ig pe
ht ct
ow ion
ne pu
r r rp
eq os
ui es
re o
d nl
fo y.
ra
ny
ot
IO. 2
g.a,
ru
10
n.a.
46
he
9.3
%
Substances t o be avoided
not a p plicsble
10.3
Hazardous declsmpositizrn products
If severely o v e r h e a t e d , acrolein, acetic acid, carbas. monaside
and carbon dioxide can be formed,
Further information
Zinc and copper in any form accelerate t h e reaction and
t h e thermal decomposition.
1I . 1
Acute toxicity
Co
ns
en
10.4
Seasibilisatian :
Not known.
11.2
Subacute to chronic toxicity
11.3
Experience in humane :
Accordilrg t o p r e a e n t knowledge, n o damage t o health is t o he
expected when u s e d correctly.
11.4
Further information:
none
EPA Export 25-07-2013:18:56:30
SAFETY DATA SmET IN ACCORDANCE WITN 9V155/EEC
EC-Safety data sheet
Date p r i n t e d :
KDNR.. .
6.10,94
Amended on:
13 . 0 4 , 9 4
1
'.
Page:
8
Version:
1
:
TA Air
Class:
Number :
Water eontaminatioa risk class:
Proportion in %;
0
(f.liquiiis)
(self- classification
111
to
f c Fo
op r i
yr ns
ig pe
ht ct
ow ion
ne pu
r r rp
eq os
ui es
re o
d nl
fo y.
ra
ny
ot
he
.--
'This iaforznation is based an our preeent-day knowledge, but
does auk imply say assurame of product charaeterieties.
~
7
,r"
c o t applicable
- not determined
= Method of H.B.Fuller GmbH
7
ns
en
n
Co
-_.
ru
se
.
Other regulations, Iimitatioas and acta of prohibition:
Observe Berufsgenossenschaft UVV (VBG 81 1:
"Working with adheaivee"
EPA Export 25-07-2013:18:56:30
!,'lo
'94
110 ' 9 4
08:56
08:44
B 3 5 3 1 8731952
=+43
5031 881iO
+++ FINSA FOREST
N.A.A.
EBF-NI EXPORT
+lt+
fiAb IRLhND
@1ao3/004
Qooa/oos
_-,-
Amehded
6.10.94
OIL:
IMDG] GGVSee
Class
W A G ,
C o r r e c t techa. name:
Remarks :
not applicable
Air transport
1
PG :
EMS-NO.
:
Marina pollutant:
UN-No.:
:
ICAO-TI and IATA-DEB
J C A /IATA
~
Claes
C o r r e c t t e c h s . name:
Remarks :
n o t applicabie
UNlID-No.:
he
ot
to
f c Fo
op r i
yr ns
ig pe
ht ct
ow ion
ne pu
r r rp
eq os
ui es
re o
d nl
fo y.
ra
ny
Further information
Store in a d ~ p
ylace.
REGULATIONS
-
EC guidelines
ns
en
Marking according t o
PG :
Identification letter and hazard description for the product :
Labelling 3 s defined by C h e d e a l Act n o t mandatory
Co
5
Version:
.
.4
.
13,04.94
se
.
ru
Lte p r i n t e d :
3NR. :
Component(s) responsible for hazard labelling: contains :
not appliaable
Particular designation far certain preparations (accordiag to Appendix I1 of
the Guidelinee on Preparations 89/3?9/&EC 1
not applicable
National re gdationa
Additional classification according to Dangerous Goods Act Appendix II
not applicable
NOL:
Remarks :
n o t applicable
I[nformatbn om working lim.itatioB6!
n o t applicable
W a a c t i o n s Act:
not applicable
VbF Class:
Temperature clam icccoxd.
Fire class according to DIN 14011:
B
to
DIN 57165:
EPA Export 25-07-2013:18:56:30