The Department of Chemistry Times An Electronic Newsletter of the Department of Chemistry State University of New York College at Brockport Volume 2, No. 3 Brockport, NY 14420 June 2003 of Chemists Award. His research was supported during the 2002 summer sessions by Hoffmann’s Dreyfus Foundation grant. Meet our Graduates, The Class of 2003 By Thomas W. Kallen Carr will be attending SUNY at Buffalo this fall as a graduate student in their PhD program in Chemistry. He has received a teaching assistantship and scholarship to support his graduate studies. The department will report a total of ten graduates to the American Chemical Society Committee on Professional Training this year. Nine SUNY Brockport seniors graduated with majors in chemistry in May 2003, while one graduated with a major in chemistry last August. Four students earned American Chemical Society certification of their major programs. A brief description of each of our May graduates follows: Darren R. Fry, a resident of Brockport NY, and member of Delta College, completed a major in chemistry. Michael J. Potter, a Buffalo NY resident and transfer student from the SUNY College of Technology at Alfred, completed a American Chemical Society certified major in chemistry. Gordon H. Brown, a Rochester NY resident and transfer student from SUNY Cortland, completed an earth sciences water resources major and geology minor in addition to his chemistry major. Brown, the 2003 Departmental Scholar of the Department of Earth Science and recipient of the 2003 Sigma Xi Award for Undergraduate Research in Earth Science, participated in research in geochemistry with Professor Mark R. Noll of the Department of Earth Sciences. He will be attending the University of Florida this fall as a graduate student in their MS program in Environmental Engineering and has received a research assistantship to support his graduate studies. Shawn P. Powers, a resident of Rochester NY, transferred from SUNY College of Technology at Alfred to complete an American Chemical Society certified major in chemistry while being employed full time at Eastman Kodak Company. Powers earned the 2003 Sigma Xi Award for Undergraduate Research for his research as an independent study student under Professor Thomas W. Kallen and Mr. John O. Young of Eastman Kodak. Powers returned to being “just” a full-time employee of Eastman Kodak Company, but is considering, rumor has it, part-time graduate studies at the Rochester Institute of Technology Jason B. Carr, a Rochester resident, earned a major in chemistry and minor in meteorology. Carr received the 2003 Sigma Xi Award for Undergraduate Research in Chemistry, based on his research under Professor Markus M. Hoffmann, and was selected by the faculty as the recipient of the 2003 American Institute Amanda B. Sturdevant, a resident of Clockville NY, completed an American Chemical Society certified major in chemistry and a second major in criminal justice. 1 Sturdevant, who was a President’s Scholar throughout her four years at SUNY Brockport, was also the recipient of the 2003 Paul J. Kronthaler Memorial Prize in Chemistry, the 2003 Chemistry Achievement Award of the Rochester Section of the American Chemical Society, the 2003 Sigma Xi Award for Research in Chemistry for her research under Professor Mark P. Heitz, and the 2003 SUNY Chancellor’s Award for Student Excellence. She was also the 20012002 vice president and 2002-2003 president of the Chemistry Club, a student affiliate chapter of the American Chemical Society. Topolnycky will enter the DDS program of the SUNY at Buffalo School of Dental Medicine this fall. Christopher M. Woods, a resident of Rochester NY, completed a major in chemistry. Woods received the 2003 Sigma Xi Award for Undergraduate Research for his research under Professor Markus M. Hoffmann and Mr. Jack Fox of Rochester Midland Corporation. His research activity under Hoffmann and Fox was supported by the award of the Chemistry Alumni Fellowship by the Brockport Foundation during the 2002 summer sessions and by a small grant from the Rochester Academy of Science during the 2002-2003 academic year. Sturdevant’s research with Professor Heitz, supported by the Morris Fellowship for Undergraduate Research in Chemistry in the Summer 2002, led to production of a thesis entitled “Spectroscopic Studies of DCM as a Molecular Probe for Solute-Solvent Interactions” and the award of Honors in Chemistry, as well as Honors Program Honors. David J. Wesley, a resident of Fairport NY and transfer student from Monroe Community College, completed a major in chemistry. Our lone August 2002 graduate was Larry A. Ducady Jr., a Brockport resident and transfer student from SUNY Oneonta and Texas Tech, completed both a major in biology and an ACS-certified major in chemistry. Ducady received the Susan S. Collier Fellowship for undergraduate research in 2001, was president of the Chemistry Club in 2002, was selected as the recipient of the 2002 Kronthaler Award, and earned the 2002 Sigma Xi Award for Undergraduate Research for his work under Professor Mark P. Heitz. Ducady was accepted into the Chemistry PhD program at Syracuse University with the offer a teaching assistantship last year. However, he decided to defer admission for at least a year until he is sure graduate studies are the right thing for him. He is currently employed as a laboratory technician by Tyco Healthcare in Hobart NY. Sturdevant will be attending Michigan State University as a graduate student in their Forensic Chemistry MS program. Andrea N. Topolnycky, a resident of Kenmore NY, completed majors in both chemistry and biology. Topolnycky received the Outstanding Student Award of the Department of Political Science in 2000, the Freshman Chemistry Award in 2001, and the Organic Chemistry Award in 2002. She was the recipient of the Collier Fellowship for Undergraduate Research in Chemistry in 2002, which supported her summer research under Professor Margaret E. Logan. She was the 2003 Departmental Scholar of the Department of Biological Sciences, the 2003 Departmental Scholar of the Department of Chemistry, recipient of the 2003 Sigma Xi Award for Research in Chemistry, the 2003 President’s Citation Award, and the 2003 SUNY Chancellor’s Award for Student Excellence. She was also the 2001-2002 and 2002-2003 treasurer of the Chemistry Club, a student affiliate chapter of the American Chemical Society. We wish each of our new graduates success, happiness, and good luck in the future. We hope they “phone home” to report their accomplishments regularly! 2 Jason Carr (Mentor, Markus M. Hoffmann, “CO2 Thermodynamic Phase Behavior Studies and Evidence for the Formation of CO2/Ionic Liquid Microemulsions”) supported by a Camille and Henry Dreyfus Foundation Fellowship. Professor J. E. Morris Receives Fulbright to Teach in Kenya By Thomas w. Kallen Professor J. Emory Morris has been awarded a William J. Fulbright Scholarship for 2003-2004 to teach biochemistry in Kenya, Africa. Morris will be affiliated with the Department of Biochemistry of Kenyatta University in Nairobi, Kenya. Amanda Sturdevant (Mentor, Mark P. Heitz, “Spectroscopic Study of DCM Laser Dye as Fluorescent Probe of Solute-Solvent Interactions”) supported by the Morris Fellowship from the Brockport Foundation. This will be Morris’ second tour abroad, having taught at Pahlavi University (now Shiraz University) in Shiraz, Iran as a member of the Peace Corps in 1965-1967. Morris reports that SUNY Brockport hired him, sight unseen, without an interview, while he was teaching in Iran. Andrea Topolnycky (Mentor, Margaret E. Logan, “Synthesis and Evaluation of Novel Diaryl Tellurides”) supported by the Collier Fellowship from the Brockport Foundation. Greg Garvey of the Department of SUNY Brockport’s Department of English also received a Fulbright Scholarship, to teach at Moscow University during 2003-2004. In all, 15 SUNY Brockport faculty have received Fulbright Awards since 1984. Morris is the first member of the Department of Chemistry to receive this award. Jason Tubbs (Mentor, Markus M. Hoffmann, “NMR Relaxation Measurements of Ionic Liquid Systems”) supported by a Camille and Henry Dreyfus Foundation Fellowship. Christopher Woods (Mentors Markus M. Hoffmann and Jack D. Fox (Rochester Midland Corporation), “Surfactant Studies Using Electron Paramagnetic Resonance”) supported by a Chemistry Alumni Fellowship from the Brockport Foundation. Six Chemistry Majors and Two Faculty Present Papers at 2003 Brockport Scholars’ Day By Thomas W. Kallen The entire Physical Methods Laboratory class, CHM/PHS409, presented posters, each describing one of the experiments that they had done during the year, at a special, extremely well-attended, afternoon poster session. Student presenters were Gordon Brown, Jason Carr, Allen Harvey, Cameron McKinley, Mike Potter, Eric Sharpsteen, Jason Tubbs, David Wesley, and Jennifer Woodworth. Six chemistry majors presented oral research papers at Brockport Scholars’ Day 2003, held at the SUNY College at Brockport on April 2, 2003. The research of each of these students had been supported by award of a Summer Research Fellowship for 2002. The name of each student presenter, her/his research advisor, the title of her/his paper, and the source of her/his research support follow: Professor Carolyn J. Greene presented Professor Richard V. Mancuso’s annual “physics toys” show, “Toys and Physics XI,” with the assistance of undergraduate Physics major, Eli Banta, while Professor Kenneth D. Schlecht presented his annual chemistry “magic show,” “The Excitement of Gordon Brown (Mentor, Mark R. Noll (Department of Earth Sciences), “The Geochemistry of New York Finger Lakes Benthic Sediments.” 3 Chemistry.” Both presentations have been regular, well-attended features of Brockport Scholars’ Day for many years. Kenneth D. Schlecht of the SUNY College at Brockport. Research Students Co-Author Two Publications 48th Annual ACS Undergraduate Research Symposium Held at SUNY Brockport By Thomas W. Kallen Three SUNY Brockport undergraduates and one Brockport High School student, working under the direction of Professor Markus M. Hoffmann, are now co-authors of scientific journal articles! By K. D. Schlecht and M. E. Logan The 48th Annual Undergraduate Research Symposium of the Rochester Section of the American Chemical Society was held in the Seymour College Union at SUNY Brockport on Saturday, April 26, 2003. The Symposium featured 18 poster papers and 19 oral presentations by undergraduates participating in research at Rochester area colleges. Last summer, SUNY Brockport chemistry major Chris Woods and Brockport High School Junior Nicole Bushie worked to synthesize several ionic liquid compounds; and, as part of their work, developed a novel synthesis involving an ordinary household microwave oven. Their results are described in the article, “Microwave-Assisted Synthesis of 1-Ethyl-3-Methylimidazoleum Bromide” (Woods, C. M., Bushie, N. T.; Hoffmann, M. M.; Journal of Undergraduate Chemistry Research, Vol. 2, No. 2, pp. 1-4.). Student presenters represented ten different private and public, up-state colleges and universities, including Hobart and William Smith College, Nazareth College, St. John Fisher College, SUNY College at Brockport, SUNY College of Environmental Science and Forestry (ESF), SUNY College at Fredonia, SUNY College at Geneseo, SUNY College at Potsdam, Syracuse University, and the University of Rochester. Jason Carr subsequently used Woods’ and Bushie’s ionic liquid to study its phase behavior in supercritical carbon dioxide in the presence of surfactants. Jason Tubbs analyzed Carr’s samples using NMR spectroscopy. The preliminary results of this study indicated partial dissolution of the ionic liquid into the carbon dioxide phase, something that had not been observed before. Carr and Tubbs’ findings appeared in the review article, “Surfactants in Green Solvent Systems–Current and Possible Future Research Directions” (Hoffmann, M. M.; Heitz, M. P.; Carr, J. B.; Tubbs, J. D., Journal of Dispersion Science and Technology, Vol. 1, No. 2, pp. 155-171.). Five SUNY Brockport chemistry majors, Gordon Brown, Jason Carr, Amanda Sturdevant, Jason Tubbs and Chris Woods, presented oral papers on the research they had conducted in the past year. Douglas Robello of the Eastman Kodak Company Research Laboratories was the keynote speaker, offering hope for the role of chemistry in the age of modern electronic photography in his seminar, "Imaging Chemistry for the New Millennium.” Woods, our 2002 Chemistry Alumni Fellow, received support for his summer research from the Brockport Foundation and also received a $100 student research grant for chemicals and supplies from the Rochester Academy of Science. Bushie’s research was funded by a grant from the SEED Program The Rochester Section of the American Chemical Society provided a lunch for the student presenters and their faculty advisors following the symposium. The organizers of this year’s symposium were Professor Margaret E. Logan and Professor 4 of the American Chemical Society, administered by its Rochester Section. Carr and Tubbs have been working under Hoffmann, for academic credit during the academic year and for pay during the summer, for the past two years. Their summer research efforts were funded through Hoffmann’s Camille and Henry Dreyfus Foundation start-up grant for faculty at undergraduate institutions. The Brockport Foundation, thanks largely to the generosity of this year’s faculty and alumni donors and with the assistance of the Rochester Midland Corporation, was just able to fund two fellowships. Alicia Penna, this year’s Chemistry Alumni Fellow, will be working with Professor Margaret E. Logan on the “evaluation of antioxidant efficiency as measured by inhibition of linoleic acid oxidation.” Kristina Fuller, this year’s Morris Fellow, will be working with Professor Mark P. Heitz on a project entitled “Probing Solvation and Reaction in Supercritical; Fluids.” It is indeed rare that undergraduate researchers manage to get their name on a published scientific paper before they have earned their BS. It is even more rare that a student has done so before they have graduated from high school! Congratulations go out to all who were involved in these projects! Two undergraduate research fellowships were funded by the Camille and Henry Dreyfus Foundation grant of Professor Markus M. Hoffmann. Jason Tubbs and Jim Hutchings will be working with Professor Hoffmann on projects entitled “NMR Studies of Solvated Ionic Liquids” and “Binary Phase Behavior Studies of CO2 and Ionic Liquids,” respectively. Logan Presents Poster Paper at National Organic Symposium By Thomas w. Kallen Professor Margaret E. Logan traveled to Indianapolis IN June 8-12 to present a poster at the 2003 National Organic Symposium. The poster, entitled “An Improved Synthesis of Electron-Rich Diaryl Ditellurides and Diaryl Tellurides,” summarized the results obtained by members of her research group over the last two years. One undergraduate research fellowship was funded by a grant from the Rochester Midland Corporation, administered by Professor Hoffmann. Megan Bennett will be working with Professor Hoffmann and Mr. Jack Fox of Rochester Midland on a project entitled “NMR and ESR Studies on Aqueous Surfactant s.”. Three SUNY Brockport undergraduates, Elizabeth A. Gregory (’02), Stacy A. Morrill (’02), and Andrea N. Topolnycky (’03), were listed as co-authors of this poster. One student, Ahmed Yimam Nuriye, is technically on the payroll of the College’s VP for Information Technology Services. Ahmed is working with Professor Margaret E. Logan on “the efficient synthesis of novel, electron-rich diaryl ditellurides and diaryl tellurides.” Summer 2003 Research of Six Students Supported by Grants and Summer Fellowships Alumni News By Thomas w. Kallen By Thomas W. Kallen Six SUNY Brockport undergraduates will each be working full-time for eight weeks this summer on the research projects of our junior faculty. Stephen and Jacquelyne Ognibene (’99) report the birth of their second child, a girl, Alyssa Stephanie Lucia Ognibene, born at 9:57 AM on June 8, 2003. Alyssa weighed 6 lbs. 5 oz. and was 18.5 inches long ( For all 5 you fishermen, she’s a “keeper!”). Mom and Baby O. are doing fine!! his research, while actively recruiting the best and the brightest for the PhD program at Penn State. Doug Smith (’99) is a fourth-year graduate student, working with Professor Troy Wood in analytical mass spectrometry, at SUNY Buffalo. Smith is working in the area of electro-spray ionization and has designed a new source using nano electro-spray technology. He expects to finish his doctoral studies this December. Renee Becker (Earl) (’01) will complete an MS in Chemistry at SUNY Albany this August. She has accepted a job offer from Manatee Community College in Bradenton, FL and will be teaching Introduction to Chemistry and General Chemistry this fall. Earl married former SUNY Brockport chemistry major Tony Becker, who is working as an analytical chemist, in December 2002. Smith married Stephanie Reynolds, a 1997 SUNY Geneseo graduate in Geology, in 2000. Stephanie earned an MS in Geology from The Ohio State University following graduation from Geneseo. Zach Henneman (’01) is in his second year of a PhD program in Physical Chemistry at SUNY Buffalo. Henneman is working with Professor George Nancollas on the dissolution kinetics of apatite and bone, studying, in particular, in vitro bone resorption inhibitors developed by Proctor and Gamble. He plans to complete his synopsis proposal for PhD candidacy this fall and will complete his doctoral degree in two- or two-and-onehalf years. Roderick Fry ('00), now a graduate student at The Pennsylvania State University, hopes to finish work toward a PhD by the summer of 2004. During his tenure at Penn State, Rod has been very active in presenting and publishing his research. You can check out a sample of what he has been doing in "19F MAS NMR Quantification of Accessible Hydroxyl Sites on Fiberglass Surfaces," R. A. Fry, N. Tsomaia, C. G. Pantano, K. T. Mueller, Journal of the American Chemical Society, 125 (9), 2378-2379. Henneman has just become engaged to Sabrina Thoms, a University of Rochester graduate in English and Art History who is currently a graduate student in Museum Studies at SUNY Oneonta. Fry will be presenting his research at the 226th National Meeting of the American Chemical Society in NewYork city this September. His presentation is entitled "Investigation of Hydroxyl Sites in Fiberglass Materials Using Solid-State 19F MAS NMR Spectroscopy". Brian Peppers (’01) is also in his second year of a PhD program in Synthetic Organic Chemistry at SUNY Buffalo. Peppers is working with Professor Stephen Driver in the area of natural product synthesis, in particular on E-9 ring closing and olefin metathesis using a ruthenium catalyst. He plans to complete his synopsis proposal for PhD candidacy this fall and will complete his doctoral degree in two- or two-and-one-half years. Fry started a paid internship at Air Products and Chemicals Inc. this May. This internship is part of a Penn State-APCI graduate fellowship that Rod competed for and won. He will be at APCI in Allentown, PA for the summer studying supercritical inverse gas chromatography. Upon completion of the internship, Rod's stipend, research expenses and tuition will be covered by APCI for one full year while he continues his studies at Penn State. Peppers, who rooms with Zach Henneman, will be seeking a new roommate for next year for obvious reasons. Peppers, at least, has no girlfriend. He claims to be too busy (“the only curves (he) sees are on the sides of glassware!”)! He also claims that he “has an Fry hopes to return to SUNY Brockport this coming fall to give a departmental seminar on 6 implant in the back of his neck that heats-up when he should be in lab!” Peppers was this year’s graduate Chemistry Club coordinator for National Chemistry Week at SUNY Buffalo and has also done chemistry demonstrations at the Buffalo Museum of Science. Hey, move over Prof. Schlecht! You have competition! If you have news about yourself that you wish to have included in the “Alumni News” section of The Department of Chemistry Times, please send it by e-mail to the editor, Tom Kallen, at tkallen@brockport.edu. The Department of Chemistry Times is posted on the Department of Chemistry Web site at irregular intervals by Professor, Chairman and Editor Dr. Thomas W. Kallen, Department of Chemistry, SUNY College at Brockport, 350 New Campus Drive, Brockport NY 14420-2971. You may visit the Department of Chemistry Web site at www.brockport.edu/~chemistry/. E-mail messages to the Times should be addressed to Professor Kallen at tkallen@brockport.edu. 7