First Semester Final Exam 2013 Chemist: __________________________ Unit 2: Atomic Structure and Periodicity 1. What is the charge, location and mass of a proton? positive charge, in the nucleus, 1 amu. Determines the identity of the element. P + N = atom’s mass 2. What is the charge, location and mass of a neutron? Neutral charge, in the nucleus, 1 amu, # varies in individual atoms of the element to form isotopes, P + N = atom’s mass 3. What is the charge, location and mass of an electron? negative charge, arranged in energy levels around the nucleus, negligible mass. Determines the chemical properties of the element. The valence electrons are the electrons that are involved in bonding. 4. What is an energy level? “layers” around a nucleus where the electrons are located How can you determine how many an element has? By what row the element can be found on the periodic table. For example, Mg is on the 2nd row and it has 2 energy levels. 5. What atomic particle determines the identity of the element? Protons (if the Proton # changes it is a different element) 6. What atomic particle is active in bonding and determines the chemical properties of the atom? Electrons (the valence electrons are shared or stole/transferred in chemical bonds) 7. Define “atomic number” the # of protons in an atom 8. Where is an atom’s atomic number on the periodic table? above the symbol 9. Define “atomic mass” the # of protons + the # of neutrons in an atom. (electrons’ mass is so small it does not affect the overall mass…it’s like having long hair vs short hair; you still say you weigh the same) 10. Where is an atom’s atomic masss on the periodic table? below the symbol 11. What is the different between atomic mass and average atomic mass? The # on the periodic table is the average mass of all the isotopes of that element. An individual atom’s mass is always a whole number that represents the # of protons and neutrons that specific atom has. 12. Define “isotope” atoms of the same element that have different masses (same # of protons but different # of neutrons). Some isotope nuclei are unstable; these are radioactive isotopes and will decompose after a certain period of time (2 sec to 5000 years depending on the isotope). 13. Define “ion” a charged atom caused by the gain or loss of electrons. 14. Define “cation” a positive ion. Metals lose electrons and become positively charged ions. 15. Define “anion” a negative ion. Non-metals gain electrons and become negatively charged ions. 16. Define “period” a row in the periodic table. Atoms in the same period have the same # of shields and energy levels. 17. Define “group/family” a column in the periodic table. Atoms in the same family have the same # of valence electrons and similar chemical properties. What are the general characteristics of Group 1/Alkali Metals? Metals, 1 valence electron, highly reactive (remember the Li, Na, K and water demos?!) What are the general characteristics of Group 2/Alkaline Earth Metals? Metals, 2 valence electrons, reactive (not quite as reactive as Group 1 – remember the Ca and water demo) What are the general characteristics of Group 7/Halogens? Non-metals, 7 valence electrons, reactive, most are gases at room temperature, most are diatomic What are the general characteristics of Group 9/Nobel Gases? Non-metals, 8 valence electrons, non-reactive (inert), gases at room temperature 18. Where are the metals, transition metals, metalloids and non-metals located on the periodic table? Metals are anything to the left of the staircase. Transition metals are metals that are located in the short middle part of the periodic table. Non-metals are located to the right of the staircase 19. What are the properties of metals? Metals conduct electricity and heat, they have luster (are shiny) and are malleable (can be molded into various shapes). They have low electronegativities and ionization energies which cause them to lose electrons and become cations (positive electrons). 20. What are the properties of metalloids? Metalloids are elements that are located on both sides of the staircase that have properties of both metals and non-metals. 21. What are the properties of non-metals? Non-metals do not conduct electricity or heat, are dull and brittle if solid at room temperature. Many are gases at room temperature. They have high electronegativities and ionization energies which cause them to gain electrons and become anions (negative electrons). 22. Define “shielding” the inner energy levels that block a nucleus’s ability to pull its valence electrons and other shared electrons towards the nucleus. How does shielding change as you move across a row on the periodic table? Atoms in the same row have the same # of shields. (Elements in the 3rd row of the periodic table have 2 shields and 1 row of valence electrons.) How does shielding change as you move down a column on the periodic table? Shielding increases as you move down a column. (Elements in the 4th row of the periodic table have 3 shields and 1 row of valence electrons.) 23. Define “nuclear charge” the pull that the protons can exert on the atom’s electrons. The more protons an atom has the stronger the nuclear charge / proton pull. 24. Define “atomic radius” the distance from the center of the nucleus and the valence energy level. How does atomic radius change as you move across a row on the periodic table? decreases Why? Same # of shields but more protons as you move to the right across the table. The increased protons are able to pull the valence electrons closer to the nucleus. How does atomic radius change as you move down a column on the periodic table? increases Why? Each row of the periodic table adds an energy level to the atoms. This means that there is another shield that counters the extra protons. The valence electrons are able to move farther away from the nucleus. 25. Define “Ionization energy” the energy 1 atom needs to remove the 1st valence electron from another atom How does Ionization energy change as you move across a row on the periodic table? increases Why? As the # of protons increase they are able to pull the valence electrons towards the nucleus, thus requiring more energy to pull 1 valence electron away. How does Ionization energy change as you move down a column on the periodic table? decreases Why? As the # of shields increase the nucleus can’t pull the valence electrons as well thus requiring less energy to pull 1 valence electron away. 26. Define “Electronegativity” an atom’s ability to pull shared valence electrons towards its nucleus How does Electronegativity change as you move across a row on the periodic table? increases Why? As the # of protons increase atoms are able to pull shared electrons towards it own nucleus How does Electronegativity change as you move down a column on the periodic table? decreases Why? As the # of shields increase the nucleus can’t pull shared valence electrons as well 27. Define “Reactivity” how readily an atom will react with another What is the most reactive metal? Francium Why? Fr has the lowest Ionization energy of all metals. Makes it the quickest to lose its 1 valence electron. So reactive it is impossible to find it pure in nature – it is always bonded to another atom. What is the most reactive non-metal? Fluorine Why? F has the highest electronegativity of all non-metals. Makes it the best at pulling valence electrons in to gain 1 valence electron to complete valence energy level. 28. What are the 2 conclusions Rutherford made about the structure of the atom after his Gold Foil Experiment? When most of the + particles were able to pass through the Gold foil, Rutherford concluded that most of the atom is empty space. 1 time in 8000 the + particles were deflected. Rutherford concluded that the gold’s positive charges are clumped in a small nucleus. 29. What is the mass of the atom? 35 amu How many protons does it have? 17 protons How many neutrons does it have? 35-17=18 neutrons How many electrons does it have? No charge notated on upper right corner. Electrons = protons; 17 electrons How would the symbol change if this atom gained an electron? (17 protons, 18 electrons)