MATERIAL SAFETY DATA SHEET 1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION Product Name: ELECTROCLEAN SOLUTION Product Code: 6911-1321 & 6911-3321 Manufacturer: Address: Automated Production Equipment Corporation 142 Peconic Avenue Medford, NY 11763, USA (631) 654-1197 (Mon-Fri, 9 am - 5 pm EST) (631) 289-4735 Telephone: Fax: Emergency Response 24-hour Telephone: CHEMTREC United States: (800) 424-9300 International: (703) 527-3887 (collect) Effective Date: Nov 4, 2002 2. COMPOSITION, INFORMATION ON INGREDIENTS RTECS # WB4900000 ZC0110000 CAS # 1310-73-2 7732-18-5 Chemical Name Sodium Hydroxide Water Wt. % 1-5 95 - 99 3. HAZARDS IDENTIFICATION EMERGENCY OVERVIEW Clear, odorless liquid. Danger! Corrosive to skin, eyes, and respiratory system. Environmental hazard. Emergency Response Guidebook Guide #154 POTENTIAL HEALTH EFFECTS TARGET ORGANS: Skin, eyes, respiratory system. PRIMARY ROUTES OF ENTRY: Skin/eye contact, inhalation, ingestion. EYE: Corrosive to the eyes and may cause severe eye damage. SKIN CONTACT: Causes skin irritation. May cause skin burns. SKIN ABSORPTION: Substance does not absorb through the skin. INHALATION: Irritating to the eyes, nose, throat, and lungs. May cause sneezing, watering of eyes, nasal discharge, coughing. INGESTION: May cause severe and permanent damage to mouth, throat, and stomach. MSDS 6911-1321 & 6911-3321 Page 1 of 6 CHRONIC EFFECTS: Prolonged or repeated exposure may cause chronic dermatitis. KNOWN OR POTENTIAL CARCINOGEN: National Toxicology Program : No I.A.R.C. Monographs : No OSHA: No ACGIH: No MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE: Preexisting skin and eye conditions; respiratory system disorders. 4. FIRST AID MEASURES First aid providers must take proper precautions for their own safety before entering contaminated areas to assist chemical accident victims and handling their contaminated clothing and equipment. Another person should immediately call the Emergency Medical Service, 911-Operator, Hospital, Physician, Ophthalmologist or Poison Control Center, as applicable. Give the following information: Location of the accident, your phone number, description of the accident, name of chemical agent and product, number and condition of casualties, what is being done for the victims. Stay on the phone until the other party hangs up! Remove victim from contaminated area to a clean, quiet, ventilated area. Calm and reassure him, keep him warm. EYES: Hold eyelids apart and flush eyes with plenty of water for at least 15 minutes. SKIN: Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Thoroughly decontaminate (or discard) clothing and shoes. INHALATION: Remove to fresh air. Lay victim down, legs raised. Loosen tight clothing, cover with a blanket. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. INGESTION: DO NOT induce vomiting, unless advised by EMS. Give victim large quantities of water or milk with 1-2 fresh eggs. Give a glass of 1/3 vinegar with 2/3 water. Never give anything by mouth to an unconscious person. 5. FIRE FIGHTING MEASURES FLAMMABLE PROPERTIES: Flash point (Method Used): Flammable Limits: Autoignition temperature: EXTINGUISHING MEDIA: MSDS 6911-1321 & 6911-3321 Material will not burn. LFL: None N.A. All UFL: None Page 2 of 6 FIRE-FIGHTING EQUIPMENT: NIOSH/MSHA approved positivepressure self-contained breathing apparatus. Structural fire fighters’ protective clothing may not provide adequate protection. FIRE AND EXPLOSION HAZARDS: Containers can build up pressure and burst if exposed to heat (fire). Water runoff can cause environmental damage. Dike area for later disposal. NFPA - 704M System: Health: 3 Flammability: 0 Reactivity 0 6. ACCIDENTAL RELEASE MEASURES IN CASE OF A SPILL: Do not touch or walk through spilled material. Isolate hazard area and keep people away. Notify your facility emergency coordinator. Eliminate all sources of ignition. Provide maximum ventilation. Do not release into soil, sewers, or natural bodies of water. Wear proper personal protective equipment (PPE). Carefully mop up or vacuum spill and triple rinse with water into suitable plastic container. Release of a reportable quantity (RQ) requires notification of proper authorities. Dispose of according to local, state, and federal regulations. NEUTRALIZING AGENT: Dilute Hydrochloric Acid (6M) 7. HANDLING AND STORAGE HANDLING: Use "buddy system" when working with chemicals. Do not get in eyes, on skin, on clothing. Do not breathe vapor, mist or gas. Use with adequate ventilation. Wash thoroughly after handling. Triple rinse container clean before discarding. Put nothing else in this container. STORAGE: Keep container tightly closed in upright position. Store at 60-90°F away from incompatible materials and physical hazards. Do not remove or deface container labels. 8. EXPOSURE CONTROLS/ PERSONAL PROTECTION ENGINEERING CONTROLS: Local exhaust ventilation is required to meet the permissible exposure limits (PEL) during the use of this product. RESPIRATORY PROTECTION: If engineering controls are not feasible, the respiratory protection program must comply with OSHA 29 CFR 1910.134. SKIN PROTECTION: Nitrile, neoprene, vinyl, latex gloves. Impervious boots, apron, protective clothing as required by job conditions. EYE PROTECTION: Face shield and safety glasses w/side shields or splash-proof chemical goggles. Do not wear contact lenses. Eye wash station, safety shower, washing facilities near work area. MSDS 6911-1321 & 6911-3321 Page 3 of 6 EXPOSURE LIMITS: Agencies OSHA Limits PEL/TWA STEL Ceiling ACGIH TLV/TWA STEL Ceiling NIOSH REL/TWA IDLH Units mg/m3 ppm mg/m3 ppm mg/m3 ppm mg/m3 ppm mg/m3 ppm mg/m3 ppm mg/m3 ppm mg/m3 ppm Hazardous Ingredients Sodium Hydroxide 2 Skin Designation 2 2 10 No 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance: Odor: pH: Specific gravity: Vapor pressure: Vapor density: Evaporation rate: Colorless liquid None 12 – 14 1.044 - 1.054 N.A. N.A. <1 (ethyl ether =1) Boiling point: Freezing/Melting point: Solubility in water: 10. >100°C; >212°F < 0°C; <32°F Complete STABILITY AND REACTIVITY Stability (Conditions to avoid): Incompatibility (Materials to avoid): Hazardous Decomposition Products: Hazardous Polymerization: MSDS 6911-1321 & 6911-3321 Stable under normal ambient conditions. Avoid contact with amphoteric metals, strong acids, anhydrides, aldehydes. Na2O Will not occur Page 4 of 6 11. TOXICOLOGICAL INFORMATION Not available 12. ECOLOGICAL INFORMATION Not available 13. DISPOSAL CONSIDERATIONS Ship to approved treatment/disposal facility. Dispose of according to local, state, and federal regulations. EPA Waste I.D. Number: D002 Follow the applicable regulations for disposal of empty containers and rinsate. The disposal information applies to the material as manufactured. Contamination may affect the disposal requirements. The responsibility for proper waste disposal is with the generator of the waste. 14. TRANSPORT INFORMATION DOT, IATA, ICAO, IMO description: Proper Shipping Name: Hazard Class: Identification Number: Packaging Group (PG) Label Requirements: Unit Container : Packaging: Reportable Quantity (RQ): ERG Guide # 15. Sodium Hydroxide Solution 8 UN 1824 II 8 - Corrosive 1, 4, 8, 20, 60 Liter Polyethylene Container Meets Performance Oriented Packaging requirements. >18,000 liters 154 REGULATORY INFORMATION U.S. FEDERAL REGULATIONS: 1. Supplier Notification about toxic Chemicals. AUTOMATED PRODUCTION EQUIPMENT CORPORATION is required to inform you, that this product contains a toxic chemical or chemicals subject to the reporting requirements of Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR Part 372, if specified annual thresholds are met or exceeded. Toxic Chemical CAS # Wt.%(Maximum) None MSDS 6911-1321 & 6911-3321 Page 5 of 6 Your other suppliers of trade name products or mixtures containing section 313 chemicals must also notify you. If you repackage or otherwise redistribute this product to industrial customers you are required to furnish similar notification to them. 2. CERCLA and EPCRA: Threshold Planning Quantity: Not Applicable (Release) Reportable Quantity: >18,000 liters Extremely Hazardous Substance: None 3. EPCRA Hazard Categories: Immediate (Acute) Health: Yes Delayed (Chronic) Health: Yes Fire: No Sudden release of Pressure: No Reactivity: No 4. TSCA Statement. All ingredients of this product are listed under the Toxic Substances Control Act (TSCA). 5. ODS Certification. This product does not contain and is not manufactured with Ozone Depleting Substances (ODS). 6. VOC Certification. This product does not contain any Volatile Organic Compounds (VOC). 7. PCB Certification. This product does not contain any polychlorinated biphenyls (PCB). STATE REGULATIONS: California Prop. 65: Not applicable INTERNATIONAL REGULATIONS: WHMIS Classification. Class D2B, Class E 16. OTHER INFORMATION The data and information presented herein has been compiled from sources considered to be dependable, and is accurate and reliable to the best of the knowledge and belief of AUTOMATED PRODUCTION EQUIPMENT CORPORATION, but not guaranteed to be so. AUTOMATED PRODUCTION EQUIPMENT CORPORATION makes no representations or warranties, expressed or implied, nor assumes legal responsibility. This information is offered solely for your consideration, investigation and verification. Customers are encouraged to conduct their own tests. MSDS 6911-1321 & 6911-3321 Page 6 of 6