ME 4171 – Environmentally Conscious Design and Manufacture Final Exam – March 16, 1998 Total 180 points 1 – Some General Questions (3 points each) (60 points) a) A paper towel manufacturer advertises that their product is made of 100% recycled materials. Without any further claims, what could they be hiding about their claim? b) An auto manufacturer claims that one of their cars is 90% recyclable. What might they not be telling you that weakens their seemingly strong claim? c) What is the difference between toxic waste reduction and waste minimization? d) Name five reasons why products become obsolete. e) What is ISO 14000? f) What are the trends in material use? g) What are the pros and cons of selling product utilization versus selling products per se. h) What is the difference between pre-consumer scrap and home-scrap. i) What are the EPA’s Life-Cycle Design goals? j) What are key differences between manufacturing and remanufacturing. k) Name at least three common measures of useful product life. l) In which four categories can environmental impact be organized, according to the EPA. m) Briefly discuss design strategies for reducing environmental impact. n) Why do some people argue that hydro-electric power is not environmentally friendly? o) What are the differences between pollution prevention and design for the environment? p) Name two ways that shredded copper bits can be separated from plastics (besides through manual separation by a human)? q) List two ways that reducing the weight of a product can increase the environmental friendliness of that product. r) What are the advantages/disadvantages to having a single metric (one number) that represents the complete life cycle environmental friendliness of a product? s) Why is separability a key issue in recycling? t) Name at least four drivers for why industry is pursuing Environmentally Conscious Design and Manuacture? 1 2 – Sheet Molding Compound Manufacture (30 points) Sheet Molding Compound (SMC) is a fiberglass-resin compound which is molded into products ranging from Jet-Ski hulls to valve covers and micro-wave dishes. Resining Mixing Paste Paste Combination Compaction Figure 2.1 - SMC Manufacturing Process SMC is manufactured by placing a layer of paste on a sheet of carrier film, dropping a layer of randomly oriented glass fibers one to two inches in length on this layer of paste, and adding a layer of paste on top of this (Figure 2.2). This paste-glass combination then passes through a compaction section to ensure that the fibers are "wetted out", or covered with paste. The SMC is then stored for two days to cure the plastic. At this point it is cut into charges, or shaped pieces of the sheet, and placed in a heated mold. Pressure is applied, hardening the SMC into the desired shape. Paste Fiberglass Paste Figure 2.2 - Pre-compaction SMC While the fiberglass is simply bought from a supplier in roll form, the paste is manufactured in the plant, and can have many different formulations. The paste formulations are based on liquid resins to which filler and other materials are added. These resins are manufactured elsewhere, brought to the plant, and stored in large holding tanks. These tanks are connected through pumps to a resining station. Portable tanks are brought to this station, filled with resin or with styrene, and taken elsewhere in the plant for the mixing process (Figure 2.3). 2 From Holding Tanks Screen 2 feet Portable Tank (Approx. 4 ft. diameter) Figure 2.3 - Resining Station During the mixing process fillers (such as silica) are added to the paste to increase its volume, essentially cutting the strength of the resin. After mixing, the tank is taken to a pumping station. Here the paste mixture is emptied from the tank into a pumping system that mixes the paste with a catalyst. This begins the SMC "curing" process, and the paste must quickly be laid down with fiberglass as discussed before. Styrene is a monomer that is an integral component of the resins. It is also stored in pure form in these tanks since it is used as an inert ingredient to reduce the potency of the resins. Evaporation of styrene occurs at room temperature and atmospheric pressure from the paste or resin at all stages of the SMC manufacturing process. Since the tanks are not covered, styrene escapes into the plant workers environment whenever a tank contains resin or paste. Inhalation of styrene in sufficient quantities can cause central nervous system damage, and aspiration of styrene can be fatal. Short term exposure limit for styrene exposure as set by OSHA is 100 parts per million of styrene. The highest allowable time weighted average (average exposure over an eight hour day) is 50 ppm. a) b) c) d) e) Draw a process diagram for the preceding process. (5 points) Create a mass balance for each of the production stages. (10 points) Identify pollutants. (5 points) Where would you find the exposure limits for styrene, if it was not given? (3 points) Identify equipment design options for reducing the release of styrene to the atmosphere from the process stages and discuss their pros and cons. (10 points) f) Identify and discuss options for pollution prevention specifically for this process. (10 points) 3 3 – Fork Life Cycle (25 points) Consider the simplified product life cycles (given below) of a plastic fork (made out of polypropylene (PP)) and that of a steel metal fork to be used in a restaurant. Energy 1 ore Energy 3 Energy 2 fabricate (press from sheet metal) package and ship use Metal Fork clean and reuse fork dirty water Energy 4 Energy 1 oil fabrication (injection mold) Energy 2 package and ship use Plastic Fork recycle fork The following assumptions can be made: 1. A plastic fork weights 50 grams. A metal fork is twice as heavy. 2. The packaging is the same for both forks 3. The shipping distance between the forks' factory and restaurant is 500 kilometers and the forks are shipped by truck. 4. Anything not shown in the life cycle diagrams is equal between the two options and should not be considered in comparisons. 5. 100% of plastic forks are recycled directly into new forks 6. Once a metal fork begins being used, it can be cleaned and reused indefinitely. 7. Plastic or metal forks are both acceptable in this restaurant a) According to the AAMA, what is the difference between reuse and recycling? (3 points) b) Using the Eco-Indicator tables attached to the exam, what is the difference in environmental impact in terms of milli-points for the two forks, if we ignore the impact of the cleaning and dirty water for the metal fork? Justify your assumptions made (if any). (10 points) 4 c) Which of the two options (plastic or metal forks), would the environmentally conscious restaurant owner use? Why? Consider as many factors as possible and analyze the tradeoffs. (5 points) d) Narratively, describe how you would go about quantitatively assessing the impact of the metal fork cleaning process. (4 points) e) What are two things that are unrealistic about assumption #5? Why might a “generous” assumption like that be made? (3 points) 4 – Coffee Maker Recyclability (30 points) Below is a partially filled out recyclability assessment table for an automatic coffee maker. No. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 Name Filter basket Decals Screws in filter basket holder Filter basket holder Top of tank Aquaduct Spring from pump Metal harness from pump Pump Rubber stoppers from base Screws from base Wires Base and heating plate base heating element On/off switch Power cord Screws holding heating element Heating element, gasket, clamp Outer housing Quantity 1 2 4 1 1 2 1 1 3 4 5 5 2 1 1 1 2 1 1 Material Unit Mass Total Mass R.R. S.R. Recyclable Mass PP 75.5 75.5 1 Adhesive 0.5 1 2 Steel 0.7 2.8 2 PP 24 24 1 PP 145 145 1 PP 12.5 25 1 Aluminum 4 4 1 Aluminum 6.3 6.3 1 Aluminum, plastic 4.1 12.3 1 Rubber 1.7 6.8 3 Steel 1.3 6.5 2 Copper, rubber 4.3 21.5 2 Aluminum 146 292 1 Nylon, tungsten 25 25 1 ABS 7.6 7.6 1 Copper, rubber 35 35 1 Steel 1.4 2.8 2 Mixed components 146 146 2 PP 645 645 2 1484.1 RECYCLABILITY (BY WEIGHT): a) What is the difference between the European standards for recyclability and the US Federal Trade Commission standards? (3 points) b) Fill in any blanks in the above table and calculate the current and technical feasible recyclability (by weight) using the USCAR/VRP recyclability and separability ratings (R.R. and S.R., respectively). (10 points) c) Identify a number of areas for improvement on the coffee maker. Show how implementing one of these improvements (pick one) affects the percent recyclability by weight of the coffee maker? (7 points) d) What is the main difference between a recyclability rating of 3 vesus 4? (2 points) e) What is the difference between levels 2 and 3 on the separability scale? (2 points) f) This approach for measuring the recyclability of a product relies on two rating scales that are defined by a central authority (the US Vehicle Recycling Partnership). Another approach would be for each designer to define their own scales. What are the advantages and 5 disadvantages of a unified scale? Do the advantages outweigh the disadvantages or the other way around? (6 points) 5 – Product Life (10 points) Three situations are described below: A) A t-shirt is designed that will last for 30 years without degrading in any way under normal conditions. B) A bridge is designed that lasts for 30 years without degrading in any way under normal conditions. C) A laptop computer is designed that lasts for 30 years without degrading in any way under normal conditions. In each case, the new product does not harm the environment more than the existing product in any part of the life cycle. Additionally, the cost of the new products is the same as existing products. In other words, all else is equal except for the new ability to extend the product lives to 30 years. a) Is measuring each of these product’s life in terms of years appropriate? How else can you measure product life? (5 points) b) In which of the three cases above is designing for 200 years not appropriate? Why is this so? State any assumptions clearly. (5 points) 6 – Office Seat Dismantling Financial Analysis (20 points) An entrepreneur is interested in setting up a dismantling line for office seats. He gets the seats for free and it takes 3 minutes to manually dismantle the seat and sort the materials. The capital equipment cost for the facility is $500,000. The operational costs (excl. labor) are estimated to be about $3,000 per month. Assume that there are 10 workers working 40 hours a week with a $20 per hour salary (incl. benefits). The material breakdown for the seats is given in Table 6.1. The prices for the recycled material are given in Table 6.2. Table 6.1 - Car seat material breakdown No. 1 2 3 4 5 Material Steel PP Polyester PUR ABS 6 Amount (Kg) 10.23 0.14 1.81 3.18 0.03 Table 6.2 - Car seat material prices No. 1 2 3 4 5 Material Steel PP Polyester PUR ABS Price ($/Kg) 0.12 0.11 0.33 0.55 0.73 a) Given the preceding information and assuming continuous production throughout the year, how many months will it take the entrepreneur to start making a return on his investment? (10 points) b) What are some critical uncertainties which could affect the entrepreneur's business negatively? (5 points) c) What is an alternative way to process the seats and what are the economical advantages and disadvantages? (5 points) 8 – And finally ... (5 points) Tell me how you are going to use the material from this class in a) your future classes at Tech and b) your professional career. Have a nice Springbreak! 7 ECO-INDICATOR VALUES Production of metals (in millipoints per kg) Indicator Secondary aluminium 1.8 Aluminium 18 Copper, primary 85 Copper, 60% primary 60 Secondary copper 23 Other non-ferrous metals 50-200 Stainless steel 17 Secondary steel 1.3 Steel 4.1 Sheet steel 4.3 Description made completely of secondary material containing average 20% secondary material primary electrolytic copper from relatively modern American factories normal proportion secondary and primary copper 100% secondary copper, relatively high score through heavy metal emissions estimate for zinc, brass, chromium, nickel etc.; lack of data sheet material, grade 18-8 block material made of 100% scrap block material with average 20 % scrap cold-rolled sheet with average 20% scrap Processing of steel (in millipoints) Bending steel Bending stainless steel Cutting steel Cutting stainless steel Pressing and deep-drawing Rolling (cold) Spot-welding Machining Machining Indicator 0.0021 0.0029 0.0015 0.0022 0.58 0.46 0.0074 0.42 0.0033 Description one sheet of 1 mm over width of 1 metre; straight angle one sheet of 1 mm over width of 1 metre; straight angle one sheet of 1 mm over width of 1 metre one sheet of 1 mm over width of 1 metre per kilo deformed steel, do not include non-deformed parts! per pass, per m2 per weld of 7 mm diameter, sheet thickness 2 mm per kilo machined material ! (turning, milling, boring) per cm3 machined material ! (turning, milling, boring) Hot-galvanising 17 Electrolytic galvanising 22 per m2, 10 micrometres, double-sided; data fairly unreliable per m2, 2.5 micrometres, double-sided; data fairly unreliable Electroplating (chrome) 70 per m2, 1 micrometre thick; double-sided; data fairly unreliable Processing of aluminium (in millipoints) Indicator Blanking and cutting 0.00092 Bending 0.0012 Rolling (cold) 0.28 Description one sheet of 1 mm over width of 1 metre one sheet of 1 mm over width of 1 metre per pass, per m2 Spot-welding Machining Machining 0.068 0.12 0.00033 per weld of 7 mm diameter, sheet thickness 2 mm. per kilo machined material ! (turning, milling, boring) per cm3 machined material ! (turning, milling, boring) Extrusion 2.0 per kilogram 8 Production of plastic granulate (in millipoints per kg) Indicator Description and explanation of score ABS high energy input for production, therefore high emission output 9.3 HDPE relatively simple production process 2.9 LDPE score possibly flattered by lack of CFC emission 3.8 Natural rubber ozone-layer-depleting solvents used during production 15 PA high energy input for production, therefore high emission output 13 PC high energy input for production, therefore high emission output 13 PET high energy input for production, therefore high emission output 7.1 PP relatively simple production process 3.3 PPE/PS A commonly used blend, identical to PPO/PS 5.8 PS rigid foam block of foam with pentane as blowing agent (causes smog) 13 PS high impact (HIPS) high-impact polystyrene 8.3 PUR ozone-layer-depleting solvents used during production 14 PVC calculated as pure PVC, without addition of stabilisers 4.2 Processing of plastics (in millipoints) Indicator Injection mould. in general 0.53 Inject. mould. PVC & PC 1.1 RIM, PUR 0.30 Extrusion blowing PE 0.72 Vacuum forming 0.23 Vacuum pressure forming 0.16 Calandering of PVC 0.43 Foil blowing PE 0.030 Description per kilo material, this figure may also be used as estimate for extrusion per kilo material, this figure may also be used as estimate for extrusion per kilo material per kilo, for bottles and such like per kilo per kilo per kilo per m2, thin foil (for bags) Ultrasonic welding Machining per metre weld length per cm3 machined material 0.0025 0.00016 Production of other materials (in millipoints per kg) Indicator Description Glass 57% secondary glass 2.1 Glass wool and glass fibre for isolation and reinforcement 2.1 Rockwool score is largely determined by carcinogenic substances 4.3 Ceramics simple applications, e.g. sanitary fittings etc. 0.47 Cellulose board this material is particularly used in dashboards 3.4 Paper chlorine-free bleaching, normal quality 3.3 Recycled paper unbleached, 100% waste paper 1.5 Wood wood from Europe, sawn into planks, without preservatives 0.74 Cardboard corrugated cardboard made of 75% waste paper. 1.4 Production of energy (in millipoints) Indicator Electricity high voltage 0.57 Electricity low voltage 0.67 Heat from gas (MJ) 0.063 Heat from oil (MJ) 0.15 Mechanical (diesel, MJ) 0.17 Description per kWh, for industrial use per kWh, for consumer use (230V) per MJ heat per MJ heat per MJ mechanical energy from a diesel engine 9 Transport (in millipoints) Truck (28 ton) Truck (75m3) Indicator 0.34 0.13 Train Container ship Aircraft 0.043 0.056 10 Fraction Description per ton kilometre, 60% loading, European average per m3 km, 60% loading, European average per ton kilometre, European average for diesel and electric traction per ton kilometre, fast ship, with relatively high fuel consumption per kg !, with continental flights the distance is not relevant Waste processing and recycling (in millipoints per kg) Indicator Notes Incineration (in modern waste incinerator with heat recovery and flue-gas treatment) Glass almost inert material on incineration 0.89 Ceramics almost inert material on incineration 0.020 Plastics (excluding PVC) plastics contain heavy metals, but also have a high energy yield 1.8 PVC PVC contains heavy metals and it has a relatively low energy yield 6.9 Paper and cardboard heavy metals (ink) are dominant, energy yield is relatively high 0.56 Steel and iron 70% is recovered from slag, particularly larger pieces 1.8 Landfill (in modern landfill site with percolation water treatment and dense base) Glass almost inert material on a landfill 0 Ceramics almost inert material on a landfill 0.027 Plastics (excluding PVC) 0.1 % of all heavy metals released 0.035 PVC 0.1 % of all heavy metals released 0.077 Paper and cardboard 10% of all heavy metals (mainly in ink) released 0.16 Steel and iron small proportion (ca. 1%) of heavy metals released 0.80 Recycling (note: these values cannot be used for recycling of secondary material) Glass less glass has to be manufactured because of glass recycling -1.5 Ceramics cannot be sensibly recycled n.a. Plastics (PP en PE) less plastic has to be manufactured because of plastic recycling -0.46 Engineering plastics the higher the indicator for production, the higher the "profit" -0.5 - -5.0 PVC less PVC has to be manufactured because of PVC recycling -1.6 Paper and cardboard less paper has to be manufactured because of paper recycling -1.8 Steel and iron less pig iron has to be manufactured because of steel recycling -2.9 Municipal waste (Processing of waste by average Dutch municipality) Glass 37% incinerated, 63% landfilled 0.35 Ceramics 37% incinerated, 63% landfilled 0.041 Plastics (excluding PVC) 37% incinerated, 63% landfilled 0.69 PVC 37% incinerated, 63% landfilled 2.6 Paper and cardboard 37% incinerated, 63% landfilled 0.33 Steel and iron 37% incinerated, from which 70% is recovered, 63% landfilled, 1.2 Household waste (Same, but with average separation by consumer (e.g. glass and paper containers)) Glass 61% separated and recycled, rest is municipal waste (see above) -0.80 Ceramics almost all processed as municipal waste 0.041 Plastics (excluding PVC) 2% separated and recycled, rest is municipal waste (see above) 0.66 PVC 2% separated and recycled, rest is municipal waste (see above) 2.5 Paper and cardboard 35% separated and recycled, rest is municipal waste (see above) -0.43 Steel and iron 36% separated and recycled, rest is municipal waste (see above) -0.28 10