5.2 Physical Science: Physical science principles, including fundamental ideas about matter, energy, and motion, are powerful conceptual tools for making sense of phenomena in physical, living, and Earth systems science. Properties of Matter: All objects and substances in the natural world are composed of matter. Matter has two fundamental properties: matter takes up space, and matter has inertia. (5.2.12.A) Essential Questions What is the significance of the organization of the periodic table? Content Statements Enduring Understandings Electrons are the only subatomic particles responsible for chemical reactions in the universe. Cumulative Progress Indicators Electrons, protons, and neutrons are parts of the atom and have measurable properties, including mass and, in the case of protons and electrons, charge. The nuclei of atoms are composed of protons and neutrons. A kind of force that is only evident at nuclear distances holds the particles of the nucleus together against the electrical repulsion between the protons. Use atomic models to predict the behaviors of atoms in interactions. 5.2.12.A.1 Differences in the physical properties of solids, liquids, and gases are explained by the ways in which the atoms, ions, or molecules of the substances are arranged, and by the strength of the forces of attraction between the atoms, ions, or molecules. In the Periodic Table, elements are arranged according to the number of protons (the atomic number). This organization illustrates commonality and patterns of physical and chemical properties among the elements. Account for the differences in the physical properties of solids, liquids, and gases. Labs, Investigation, and Student Experiences Instruction Guidance To assist in meeting this CPI 5.2.12.A.1, Students may Predict the VSEPR structure of different compounds. Describe the progress of atomic structure from Democritus. Investigate the behavior of Cu and Cr in relation to electron configuration. Define different types of bonding. Sample Assessments 5.2.12.A.2 To show evidence of meeting this CPI, students may answer the following questions: 1. Why is gold so valuable? 2. Why are spider webs so strong and flexible? 3. Specify the types of bonds and Compounds for the following: BaCl 2, CO2, Al2O3, and PCl3. 4. Tests, quizzes and worksheets. 5. An experiment – Flame test. Resources Predict the placement of unknown elements on the Periodic Table based on their physical and chemical properties. 5.2.12.A.3 Inquiry in Action: Investigating Matter through Inquiry, 3rd edition. Permission is granted in advance for reproduction for classroom use. Please include “Reprinted with permission from Inquiry in Action, Third Edition, Copyright © 2007, American Chemical Society.” National Science Digital Library, Science Digital Literacy Maps The Physical Setting: Atoms and Molecules http://strandmaps.nsdl.org/?id=SMS-MAP-1325 National Science Digital Library, Science Refreshers 5.2.12.A 2011 In a neutral atom, the same number of negatively charged electrons surrounds the positively charged nucleus. Atoms of an element whose nuclei have different numbers of neutrons are called isotopes. Solids, liquids, and gases may dissolve to form solutions. When combining a solute and solvent to prepare a solution, exceeding a particular concentration of solute will lead to precipitation of the solute from the solution. Dynamic equilibrium occurs in saturated solutions. Concentration of solutions can be calculated in terms of molarity, molality, and percent by mass. Acids and bases are important in numerous chemical processes that occur around us, from industrial to biological processes, from the laboratory to the environment. Explain how the properties of isotopes, including half-lives, decay modes, and nuclear resonances, lead to useful applications of isotopes. 5.2.12.A.4 http://nsdl.org/refreshers/science/ Textbook, overhead projector, projector, online resources. Instruction Guidance To assist in meeting this CPI 5.2.12.A.2, Students may Describe the process by which solutes dissolve in solvents. 5.2.12.A.5 Relate the pH scale to the concentrations of various acids and bases. 5.2.12.A.6 Investigate the Melting points of a series of ionic, molecular and metallic solids in a laboratory experiment. Investigate electric conductivity of a series of ionic, and molecular compounds as solid or when molten in a laboratory experiment. Correlate physical properties of molecular and ionic compounds with their geometrical structures and Intermolecular forces. Design three-dimensional structural models to explain the observed physical properties of ionic crystals, polar and non-polar molecules. Sample Assessment 1. Which of the following compounds are soluble in water? Justify your answer. i) ii) 2. Carbon and Silicon both have 4 valance electrons, however Carbon Dioxide CO 2 is a gas at room temperature while SiO2 is solid. Explain why. 3. Camphor, C10H16O has a normal freezing point of 179.8oC and a Kf = 40.0oC/m. When 0.186 g of an unknown organic substance is dissolved in 22.01 g of camphor, the mixture’s new freezing point is 176.7oC. Find the unknown’s molar mass. 4. Draw the complete Lewis electron-dot diagram for ethyne C2H2. 5. Energy is required to boil ethanol. Consider the statement “As ethanol boils, energy 1. goes into breaking C-C bonds, C-H bonds, C-O bonds, and O-H bonds. ” Is the statement true or false? Justify your answer. 5.2.12.A 2011 Resources Inquiry in Action: Investigating Matter through Inquiry, 3rd edition. Permission is granted in advance for reproduction for classroom use. Please include “Reprinted with permission from Inquiry in Action, Third Edition, Copyright © 2007, American Chemical Society.” National Science Digital Library, Science Digital Literacy Maps The Physical Setting: Atoms and Molecules http://strandmaps.nsdl.org/?id=SMS-MAP-1325 National Science Digital Library, Science Refreshers http://nsdl.org/refreshers/science/ Science Curriculum Topic Study: Particulate Nature of Matter (Atoms and Molecules) p. 169 Chemistry and Material Discoveries http://www.nsf.gov/news/overviews/chemistry/index.jsp Exploring the material world http://www.lbl.gov/MicroWorlds/module_index.html About Microworld – Information for teachers http://www.lbl.gov/MicroWorlds/teachers/ Instructional Guidance To assist in meeting this CPI 5.2.12.A.3, students may: Learn the history of the periodic table, including the major contributors who had an impact on the current design. Investigate the concepts of atomic size, ionization energy, and electronegativity. Determine the group and periodic trends for atomic size, ionization energy, and electronegativity. Predict the location of an element based upon its properties. 5.2.12.A 2011 Sample Assessments 1) Compare and contrast the periodic tables devised by Mendeleev and Moseley. 2) Match the periodic and group trends with the property: A. Atomic Size B. Ionization Energy 1. Increases left to right across a period and decreases down a group 2. Decreases left to right across a period and increases down a group 3) List the following elements in order of increasing ionization energy: Aluminum, Magnesium, Sulfur, Chlorine, Sodium 4) Unknown element X has a relatively high ionization energy but a short atomic radius. Describe the area of the periodic table you would expect to find element X. How did you come to this conclusion? Resources Inquiry in Action: Investigating Matter through Inquiry, 3rd edition. Permission is granted in advance for reproduction for classroom use. Please include “Reprinted with permission from Inquiry in Action, Third Edition, Copyright © 2007, American Chemical Society.” Science-Class.Net (Graphing Periodic Properties, The Periodic Table Project, Editable Periodic Tables): www.scienceclass.net/Chemistry/periodic_table.htm The Science Spot (Element Trading Cards, Periodic Table Basics): http://sciencespot.net/Pages/classchem.html Ionization Energy Activity: http://isite.lps.org/mschmid3/web/documents/IonizationEnergyActivity.p df 5.2.12.A 2011 Instructional Guidance To assist in meeting this CPI, 5.2.12.A.4, students may: Define radioactivity and the different types of radioactive decay (alpha, beta, gamma, positron, and electron capture) Write and balance equations to represent nuclear reactions Predict the type decay that occurs for a given radioisotope Calculate the amount of a radioactive nucleus remaining after a certain period of time given the half-life and the amount of time required for a certain amount of a nucleus to decay Calculate energy changes involved in nuclear reactions Use these relationships to understand and interpret phenomena in the natural world. Sample Assessments To show evidence of meeting this CPI, students may answer the following questions: To show evidence of meeting this CPI, Students may answer the following question: 1. While on your casual Sunday walk through Central Park, you and your friends uncover what appears to be an ancient artifact. You are determined to prove that this item is at least 2000 years old. Because you are very familiar with Carbon-14 dating you choose to utilize this method to complete your objective. Describe the steps you would undertake to determine a potential age for the artifact. Suggest alternative methods of analyses to correct for the carbon-14 limitations in obtaining the most accurate age. 5.2.12.A 2011 Resources Solvation of NaCl video Oil/Water demo Density Bottles Inquiry in Action: Investigating Matter through Inquiry, 3rd edition. Permission is granted in advance for reproduction for classroom use. Please include “Reprinted with permission from Inquiry in Action, Third Edition, Copyright © 2007, American Chemical Society.” National Science Digital Library, Science Digital Literacy Maps The Physical Setting: Atoms and Molecules http://strandmaps.nsdl.org/?id=SMS-MAP-1325 National Science Digital Library, Science Refreshers http://nsdl.org/refreshers/science/ Science Curriculum Topic Study: Elements and the Periodic Table p. 165 Instructional Guidance To assist in meeting this CPI, 5.2.12.A.5, students may: Design investigations and use scientific instruments to collect, analyze and evaluate evidence as part of building an explanation for classifying samples as a pure substance or a compound. Use partner talk and whole-group discussions in order to learn from other’s ideas. Given an interactive digital periodic table of elements, identify unknown substances based on their physical and chemical properties. Collaboratively evaluate and refine claims based on peers’ evidence and reasoning, 5.2.12.A 2011 Sample Assessments To show evidence of meeting this CPI, students may answer the following questions: Investigate the dissolving of various solids, liquids and gases in water, as well as factors that affect solubility. Model the process of solvation using the video ______. Calculate the concentration of a solution using molarity, molality and percent by mass using sample problems as a guide. Resources Inquiry in Action: Investigating Matter through Inquiry, 3rd edition. Permission is granted in advance for reproduction for classroom use. Please include “Reprinted with permission from Inquiry in Action, Third Edition, Copyright © 2007, American Chemical Society.” National Science Digital Library, Science Digital Literacy Maps The Physical Setting: Atoms and Molecules http://strandmaps.nsdl.org/?id=SMS-MAP-1325 National Science Digital Library, Science Refreshers http://nsdl.org/refreshers/science/ Science Curriculum Topic Study: Elements and the Periodic Table p. 165 Instructional Guidance To assist in meeting this CPI, 5.2.12.A.6 students may: Determine whether or not a particular substance is an acid or a base. Predict the action of an acid or base in a chemical reaction Identify common acids and bases in our everyday experience Explain a neutralization reaction in a buffer system 5.2.12.A 2011 Sample Assessments To show evidence of meeting this CPI, students may answer the following question: 1. In the following equation, identify the substance as being an acid, base, or Salt. NaOH + HCl HCl + HOH. 2. What does a pH number represent and how does it relate to the positions on the pH scale? 3. What factors would contribute to a substance being designated an acid or a base. Resources Inquiry in Action: Investigating Matter through Inquiry, 3rd edition. Permission is granted in advance for reproduction for classroom use. Please include “Reprinted with permission from Inquiry in Action, Third Edition, Copyright © 2007, American Chemical Society.” National Science Digital Library, Science Digital Literacy Maps The Physical Setting: Atoms and Molecules http://strandmaps.nsdl.org/?id=SMS-MAP-1325 National Science Digital Library, Science Refreshers http://nsdl.org/refreshers/science/ Science Curriculum Topic Study: Elements and the Periodic Table p. 165 5.2.12.A 2011