Version A Team Copy Chemistry 100: Midterm Exam Practice Expect the exam to be a cross between: o questions like these (taken from Fall 2002 & Winter 2003 Exams), o questions on the Team Exercises, and o homework problems. Team Name: _______________________ Leader: ____________________ Worker: ____________________ Recorder: ____________________ Worker: ____________________ Spokesperson: ____________________ Worker: ____________________ 1 1 H H Atomic Number Symbol Atomic Mass Pauling’s Electronegativity 2 1.008 1.008 2.1 3 2.1 4 5 6 7 8 9 10 Li Be B C N O F Ne 6.941 9.012 10.81 12.01 14.01 16.00 19.00 20.18 1.0 11 1.5 12 2.0 13 Al 2.5 14 Si 3.0 15 P 3.5 16 S 4.0 17 Cl 26.98 28.09 30.97 32.07 35.45 1.5 1.8 2.1 2.5 3.0 He 4.003 Na Mg 22.99 24.31 0.9 19 1.2 20 K Ca 39.10 40.08 0.8 37 1.0 38 Rb Sr 85.47 87.62 0.8 55 0.9 56 Cs Ba 132.9 137.3 0.7 87 0.9 88 Fr Ra (223) 226.0 * Lanthanide Series † Actinide Series 1s 2s 2p 3s 3p 3d 4s 4p 4d 4f 5s 5p 5d 5f 21 Sc 22 Ti 23 V 24 Cr 25 Mn 26 Fe 27 Co 28 Ni 29 Cu 30 Zn 31 Ga 32 Ge 33 As 34 Se 35 Br 44.96 47.88 50.94 52.00 54.94 55.85 58.93 58.69 63.55 65.39 69.72 72.61 74.92 78.96 79.90 1.8 1.8 2.0 2.4 2.8 39 Y 88.91 40 Zr 91.22 41 Nb 42 Mo 43 Tc 44 Ru 45 Rh 46 Pd 47 Ag 48 Cd 49 In 50 Sn 51 Sb 52 Te 53 I 92.91 95.94 (99) 101.1 102.9 106.4 107.9 112.4 114.8 118.7 121.8 127.6 126.9 1.7 1.8 1.9 2.1 2.5 81 Tl 82 Pb 83 Bi 84 Po 85 At 204.4 207.2 209.0 (209) (210) 1.8 1.9 1.9 2.0 2.2 68 69 70 71 57 La 72 Hf 73 Ta 138.9 178.5 180.9 * 89 Ac † 227.0 74 75 76 77 78 W Re Os Ir Pt 183.9 186.2 190.2 192.2 195.1 197.0 200.6 107 108 109 65 66 67 104 105 Rf Db Sg Bh Hs Mt (261) (262) (263) (262) (265) (268) 60 61 62 63 64 58 59 Ce Pr 140.1 140.9 106 79 80 Au Hg Nd Pm Sm Eu Gd Tb Dy Ho 144.2 90 91 92 Th Pa U 232.0 231.0 238.0 (145) 150.4 152.0 157.3 158.9 93 94 95 96 97 162.5 Er Tm Yb Lu 164.9 167.3 168.9 173.0 175.0 100 101 102 103 98 99 Np Pu Am Cm Bk Cf Es Fm Md No Lr 237.0 (251) (252) (260) (244) HONClBrIF (243) (247) (247) (257) (258) (259) 18 Ar 39.95 36 Kr 83.80 54 Xe 131.3 86 Rn (222) Version A Team Copy 1. (10 pts) Without referring to any periodic table (including the one on the front page of this exam, write the first 3 rows of the periodic table including element symbol and atomic number. You must sign and date the statement to get credit for this problem. I certify that I did not look at any reference while solving this problem. Signed: __________________________ Date: ______________ 1 H 3 Li 11 Na 4 Be 12 Mg 5 B 13 Al 6 C 14 Si 7 N 15 P 8 O 16 S 9 F 17 Cl 2 He 10 Ne 18 Ar 2. (2 pts) Which of the following changes is/are endothermic for the underlined object? i. baking a potato ii. a person being burned by a pan iii. a wood log burning iv. a lit light bulb shining v. a person digesting food A. iii only B. iii and iv C. iii and iv D. i and iv E. i and ii 3. (2 pts) Which of the following are elements? i. KOH iv. carbon tetrachloride ii. Ne v. calcium iii. CO A. i, ii, and iii B. iv and v C. ii and iii D. ii and v E. ii, iii, and v Version A 4. (2 pts) Which of the following is not a particulate sample of matter? A. An oxygen molecule B. A human egg cell C. An electron D. E. Team Copy A nickel atom A hemoglobin molecule 5. A chemistry instructor puts some Iodine crystals (I2 (s)) in a flask. Upon warming the flask, a purple cloud appears. a. (5 pts) Write the chemical equation that describes this process. Heat I2 (s) + Heat I2 (g) or I2 (s) ----------> I2 (g) b. (5 pts) Later, an ice cube was held next to the top edge of the flask. What happened? Ice Purple Cloud Crystals formed on the edge of the glass. c. (5 pts) Write the equation for the process from (b). I2 (g) - Heat I2 (s) I2 (g) I2 (s) + Heat I2 (s) or d. (5 pts) Which of the processes was endothermic for the Iodine? Briefly describe why. I2 (s) + Heat I2 (g) heat went into the iodine 6. (2 pts) Which of the following properties is/are classified as physical? i. ii. iii. iv. v. the odor of glass cleaning solution the color of chlorine gas the electrical conductivity of copper wire the ability of milk to sour a compound does not react with bromine A. i only B. ii only C. i and ii D. E. i, ii, and iii iv and v 7. Version A (2 pts) Which of the following properties is/are classified as chemical? i. ii. iii. iv. v. the taste of honey the ability of hair to stretch the corrosive character of hydrochloric acid the combustibility of ethanol the softness of talc A. i and ii B. i, ii, and v C. iii only 8. iv only iii and iv i only ii only iv only D. E. i and iv i, ii, and iv (2 pts) In which of the following pairs of substances will there be a net attractive electrostatic force? A. B. C. D. E. 10. D. E. (2 pts) Which of the following substances is/are homogeneous? i. mineral oil iv. sugar ii. a plant leaf v. freshly squeezed lemonade iii. sausage A. B. C. 9. Team Copy Two positively charged table tennis balls A negatively charged piece of dust and a positively charged piece of dust A positively charged sodium ion and a positively charged potassium ion A negatively charged chloride ion and a negatively charged bromide ion Two negatively charged pith balls (2 pts) One of the main features of Dalton's atomic theory which is no longer considered valid is: All atoms of each element are identical in every respect. Which of the following is the best explanation of why this feature is no longer considered valid? A. B. C. D. The existence of isotopes Mass is conserved in a chemical change Nearly all of the mass of an atom is concentrated in the nucleus The total charge of the electrons of an atom exactly balances the positive charge of the nucleus E. The planetary model of the atom has been shown to be incorrect 11. Version A Team Copy (2 pts) Which of the three major subatomic particles has/have a charge of +1? Proton 12. 41 K (2 pts) The nuclear symbol of an isotope of potassium is 19 . Indicate the number of protons, number of neutrons, atomic number, and mass number of the isotope. Number of protons 13. Number of neutrons Atomic number Mass number A. 19 22 19 41 B. 22 19 41 19 C. 19 41 19 22 D. 41 19 22 19 E. 19 41 22 41 (2 pts) Which of the three major subatomic particles has/have a mass of approximately one amu? proton, neutron 14. (3 pts) Isotopes of an element vary in mass because of differing numbers of: neutrons 15. (5 pts) Write the elemental formula for the following elements: Element Elemental Formula i. nitrogen N2 ii. sulfur S iii. lithium Li iv. bromine Br2 v. oxygen O2 16. Version A Team Copy (3 pts). The alkali metal kalium was discovered in 1807. What is its English name and symbol? Potassium 17. (10 pts) Neatly sketch and label the apparatus/experiment that disproved the Plum Pudding model of the atom. Rutherford experiment 18. Early chemists classified the elements by their chemical properties and gave these groups of elements special names. a. (3 pts) What feature of the periodic table do these groups correspond to? columns b. (3 pts) Write the names of three of these groups. alkali metals, alkaline earths, transition metals, halogens, noble gases c. (0 pts) Choose one of the following elements and circle it. (Read d – f before making your choice!) Calcium Cobalt Chlorine d. (3 pts) Write the electronic configuration of that element: Calcium: Cobalt: Chlorine: 1s22s22p63s23p64s2 1s22s22p63s23p64s23d7 1s22s22p63s23p5 (easiest one!) e. (3 pts) Write the name of the group that the element belongs to: Calcium: Cobalt: Chlorine: alkaline earths transition metals halogens f. (2 pts) How many electrons are your element’s valence (outer shell)? Calcium: Cobalt: Chlorine: 2 2 7 19. Version A Team Copy The element bromine (name for the Greek word for stench, brômos) was discovered in 1826 by Antoine J. Balard. a. (3 pts). Write its electronic configuration. 1s22s22p63s23p64s24d104p5 On the figure below: b. (3 pts). Label the s, p, and d orbitals. c. (2 pts). Fill in electrons for Bromine in the energy level diagram. s E p d 4d 5 5s 5p 4 4s 4p 3s 3p 3d 3 Either labeling the top & side (w/ special label for 3d, 4d. or labeling each set of orbitals is ok. 2 2s 2p d. (2 pts). Bromine has two stable isotope with masses 79 and 81. Write the nuclear symbol for these isotopes. 79 Br 35 81 1 d Br 35 1s d 20. Version A Team Copy (6 pts) A dedicated Chemistry 100 student tried to repeat the paper chromatography experiment from lecture. Based on the individual results, Label each of the following samples as homogenous, heterogeneous, or undetermined. Sample: Fluid: Black Sharpie Black Marker (Permanent) Blue Overhead Pen Water Rubbing Alcohol Water Resulting Paper: Sample Type: (homogenous/ heterogeneous/ undetermined) homogenous/ or undetermined heterogeneous heterogeneous