ACCELERATING THE NATURAL REMEDIATION OF TORCH LAKE A Report prepared for Senior Design (CE4905) in the Civil and Environmental Engineering Department, Michigan Technological University, Spring 2005 Submitted by: Lindsey Anderson David McCaw Amanda McKenna Kathryn Price Tim Rank Aimee Rathbun Kris Scherer Tiffany Torrance Advisor: Noel Urban April 22, 2005 Executive Summary Acknowledgements Dr. Noel Urban Bruce Peterson, District Conservationist Dick Crane, Construction Inspector NRCS Brenda Jones, EPA Joan Schumaker-Chadde André Marquette of the Chemical Engineering Department at the Louisiana State University. amarqu1@lsu.edu Dr. Stan Vitton Dr. Kris Mattila 2 TABLE OF CONTENTS 1.0 Introduction…………………………………………………………….………………….5 2.0 Project Guidelines……………………………………………………………………….. 5 3.0 Background………………………………………………………………………….........00 3.1 Mining History of Torch Lake…………………………………………………………..…….….. 00 3.2 Past Investigation and Remediation………………………………………….....................….. 00 3.3 Current Conditions and Restrictions………………………………………………………......... 00 4.0 Evaluation of Remediation Alternatives……………………………………………….. 00 5.0 Proposed Method of Remediation………………………………………………….. …. 00 5.1 Implementation………………………………………………………………………………... ….. 00 5.2 Technical Plans……………………………………………………………………………………. 00 5.2.1 Description of Phase Areas…………………………………………............... ….. 00 5.2.2 Field Investigation……………………………………………………............... ….. 00 5.2.3 Cap Design……………………………………………………………...............….. 00 5.2.4 Work Plan……………………………………………………………………..……… 00 5.2.5 Permits, Legal Issues……………………………………………………………….. 00 5.2.6 Monitoring……………………………………………………………………………. 00 5.3 Economic Analysis……………………………………………………………………………. ….. 00 5.3.1 Projected Costs…………………………………………………………………. ….. 00 5.3.2 Projected Benefits……………………………………………………..................... 00 5.3.3 Funding Sources………………………………………………………………...….. 00 5.4 Public Education…………………………………………………………………................... ….. 00 6.0 Conclusion………………………………………………………………………………… 00 7.0 References……………………………………………………………………………. …. 00 8.0 Appendices……………………………………………………………………………….. 00 3 LIST OF TABLES AND FIGURES Tables Table 1: Comparison of Observed Conditions in Torch Lake with Guidelines and Regulations…………………………………………………………………………… 00 Table 2: Contaminated Sediment and Capping Material Properties used in the Capping Model……………………………………………………………………….. 00 Table 3: Porosity and Density Values for Various Capping Materials………………….. 00 Table 4: Diameter and Dispersivity Values for Different Materials……………………… 00 Table 5: Sand Properties Used in Simulation…………………………………………….. 00 Table 6: Concentration over Time with Regulatory Concentrations for Sand at 1 Percent Organic Carbon Content…………………………………………………... 00 Table 7: Cost Estimations for Test Phase and Phase 1…………………………………. 00 Table 8: Table 9: Table 10: Figures Figure 1: Torch Lake Area, Houghton County, Michigan………………………………... 00 Figure 2: Torch Lake Mill Sites……………………………………………………………... 00 Figure 3: Torch Lake Superfund Site Operable Units Map……………………………… 00 Figure 4: Test Phase Core Sample………………………………………………………… 00 Figure 5: Red Midge Larvae………………………………………………………………… 00 Figure 6: Pore-water Concentrations at the Cap-Water Interface for a 100-year Time Period for a Cap at a Height of 40 cm (~16 inches) at One Percent Organic Carbon Content ……………………………………………………………. 00 Figure 7: Pore-Water Concentrations at the Cap-Water Interface for a 100-year Time Period for a Sand Cap at a Depth of 40 cm (~16 inches)………………….00 Figure 8: Pore-water Concentrations at the Cap-Water Interface for a 500-year Period for a Sand Cap at a Depth of 40 cm (~16 inches) at a One Percent Organic Carbon Content…………………………………………………………….. 00 Figure 9: Copper Concentration over Time with no Cap or Organic Carbon Verifying Correct and Accurate Results…………………………………………… 00 Figure 10: Figure 11: Figure 12: 4 1.0 Introduction Torch Lake is located in Houghton County, Michigan on the Keweenaw Peninsula of Michigan’s Upper Peninsula (Figure 1). Since 1868, Torch Lake and the surrounding area have been contaminated with high concentrations of copper from mining spoils. http://www.epa.gov/glnpo/aoc/trchlke.html Figure 1: Torch Lake Area, Houghton County, Michigan The area has been declared a Superfund Site by the Environmental Protection Agency (EPA) and has been researched and remediated since 1986. However, the EPA has chosen not to remediate the lake body itself, but to allow it to restore itself over time. This design group was assigned the task of developing a plan to accelerate the natural remediation of Torch Lake. The decision-making process and considerations, as well as the final decision and work plan, are described in this report. /Somewhere early in the report (right here would be appropriate), a more specific definition of the project goals/objectives is desirable. This statement could also come after the statement of the current conditions of the lake. What constitutes “acceleration”? What is the rate of “natural remediation”?/ 2.0 Project Guidelines This report details the alternatives evaluated, the approach that was selected, and the plan that was developed to enhance the rate of natural remediation of Torch Lake in Houghton County, Michigan. The lake suffers from high copper concentrations in the water and sediments as described throughout this report. The conclusions will be based on knowledge and skills acquired in earlier engineering coursework and will be focused on the process of devising a system, component or process to meet desired needs. The conclusions will be relevant to professional practice 5 and will incorporate economic, environmental, sustainability, constructability, ethical, health and safety, social and political considerations. [The requirements are only that MOST of these considerations be included. I suggest that you list only the ones included in this report.] 3.0 Background 3.1 Mining History of Torch Lake For more than a century (~120 years), copper mining was the prevalent industry of Michigan’s Keweenaw Peninsula. Discovery of two large veins of copper running through the region led to an outburst of excavating in the late-1850s. The Quincy Mining Company (Quincy) and the Calumet & Hecla Mining Company (C&H), two of the largest mining companies, constructed their mills on the shores of Torch Lake in three locations: Lake Linden, Hubbell, and Mason (Figure 2). C&H opened in 1868 and was followed soon after by Quincy. For the next century, these operations dumped approximately 200 million tons of mine spoils (tailings) into Torch Lake and along its boundaries, covering three miles of shoreline. Figure 2: Torch Lake Mill Sites Mine tailings are the residuals of excavation and extraction processes. Copper ore was crushed (also referred to as stamped) into fine particles and separated by gravitational sorting. Copper was then smelted, while crushed rock (stamp sands) was discarded into the lake. Technological advancements around 1916 enhanced extraction capabilities, 6 and previously-deposited tailings were dredged and treated with cupric ammonium carbonate to remove even more copper. The stamp sands were then returned to Torch Lake, introducing an additional contaminant. By the 1920’s, further chemical reagents were implemented to improve reclamation, and tailings were discarded along with numerous process remnants, such as lime, creosotes, and xanthates. The spoils are estimated to have had a copper concentration of 1100 µg/g [citation]. /It would be good to add a sentence about when the mills closed and all dredging activities ceased./ Through erosion and continued deposition, the tailings naturally drifted throughout the lake and settled, covering the natural sediment on the lake bottom. Benthic organisms and vegetation were thus smothered and have not yet been able to recover. The current depth of tailings is thought to be a maximum of 70 feet in some areas, and copper concentrations in the sediments reach approximately 3600 µg/g [citation]. Two large-scale chemical releases also occurred. In June of 1972 a release of 27,000 gallons of cupric ammonium carbonate leaching liquor into the north end of Torch Lake from storage vats at the Lake Linden Leaching Plant occurred. The Michigan Water Resources Commission (MWRC) reported that no detrimental effects were incurred by the lake. Their investigation actually revealed that several discharges of the compound had occurred prior to this occasion. The second event transpired during the early 1980’s when the Peninsula Copper Company dumped process water, containing 2,400 times the local sewage authority's allowable limits for copper and 100 times the limit for ammonia, into the Tamarack lagoon system. [2] 3.2 Past Investigation and Remediation Reconnaissance of the Torch Lake area commenced when several local fishermen noticed tumors on the walleye and sauger in 1973. Below is a list of events that resulted from the investigations, and following the list are further descriptions of each point [2]. 1983: Michigan Department of Public Health (MDPH) posts Fish Consumption Advisory 1983: International Joint Commission (IJC) lists Torch Lake as a Great Lakes Area of Concern 1986: Environmental Protection Agency (EPA) lists Torch Lake and the surrounding areas as a Superfund site 1992: EPA completes assessment and formulates remediation plan 1997: Public Action Committee forms 1999-2003: Natural Resources Conservation Service remediates portions of Superfund Site Based on their own research, the Michigan Department of Public Health (MDPH) posted a fish consumption advisory in 1983. No connection between the mine tailings and fish tumors has been proven, and the consumption advisory has since been removed. 7 Current fish advisories for mercury and PCBs in fish from Torch Lake are unrelated to the mining activities in the lake. Also in 1983, the International Joint Commission (IJC) Water Quality Board listed Torch Lake as a Great Lakes Area of Concern. The IJC is responsible for the health of the waterways that connect Canada and the United States. Torch Lake was listed as an area of concern because it connects to Lake Superior through the Portage Canal. In 1984, the EPA began the process of placing the Torch Lake area on the National Priorities List (NPL). The EPA declared portions of Houghton County, including Torch Lake, a Superfund site in 1986 and divided it into three operable units (shown below in Figure 3). Torch Lake is part of Operable Unit II (OUII) and is the area of focus for this report. The stampsand deposits on the western shoreline of Torch Lake are included in Operable Unit I and are not a direct focus of this report. Also in 1986, the Torch Lake Superfund Site was placed on the EPA National Priorities List for funding under EPA Comprehensive Environmental Response, Compensation and Liability Act (CERCLA). http://www.epa.gov/glnpo/aoc/trchlke.html Figure 3: Torch Lake Superfund Site Operable Units Map In 1988, the EPA began investigating Torch Lake and the surrounding areas. These studies determined that copper was leaching from the deposited mine tailings, and documented the following impairments to the lake: Restrictions on fish and wildlife consumption 8 Degradation of benthos (sediment-dwelling organisms) Restrictions on dredging activities Restrictions on drinking water consumption Degradation of aesthetics Loss of fish and wildlife habitat Also found on the shoreline and in the water were old machinery and equipment along with other discarded metal objects, such as rusting barrels. In 1990, the EPA removed contaminated drums from the lake, as well as the soil beneath them. At this time, the remedial field work within the lake was completed. In 1992, the Remedial Investigation and Feasibility Study for Torch Lake Superfund Site Operable Unit II [1] was completed. This plan listed several alternatives for remediation of OUII. In the 1994 Record of Decision (ROD), the EPA decided that the No Action plan for OUII was the best option [3]. In this report, the “no action plan” is used synonomously with “natural remediation”. From 1999-2003, the Natural Resource Conservation Service, on behalf of the EPA, constructed a soil and vegetation cap on the stamp sands along the western shore of Torch Lake, as well as several other areas in Operable Units I and III. This capping is intended, among other things, to reduce the erosion of contaminated soils into the lake and thus to end the ongoing input of contaminants into the sediments that had caused the persistent degradation of the benthic community. From 1999-2001, Torch Lake was monitored by the EPA and the Baseline Study Report with these results was submitted in 2001. The EPA also completed a Five-Year Review in March 2003. In April 2002, Torch Lake and the Lake Linden area were partially delisted from the NPL. This delisting only includes the shoreline areas that were capped by the NRCS from 19992003. The lake body itself continues to be on the NPL. The EPA is also working on a pilot project on Gull Island, which is located in the center of Torch Lake. The EPA, NRCS, and the Michigan Department of Environmental Quality (MDEQ) planted fast-growing plants on the island to see if they could survive without the addition of soil cover. This project began in spring 2003 and is being monitored at present. [2] All of the EPA investigation reports, findings, and decisions regarding Torch Lake can be found at the Portage Lake District Library or the Lake Linden/Hubbel Public Library in the Torch Lake Superfund Site repositories [4]. 3.3 Current Conditions and Restrictions Two million tons of mine tailings currently exist on the shores and in the body of Torch Lake. Pore water percolates through these sediments into the lake and causes the copper concentrations in the water (range found in lake) to be well above the levels recommended by the EPA and the state of Michigan. The recommended level for 9 copper concentration in the lake water by the EPA is 9-13 μg/L [4a] and by the state of Michigan is 15-19 μg/L [4b]. Copper concentrations in the pore water reach 1000 μg/L, and copper concentrations in the surface sediments are in the range of 3600 μg/g /give range rather than single value/. While the EPA has not yet promulgated a sediment quality criterion for copper, the Probable Effects Level (PEL) in sediments is reported to be in the range of [give range and citation]. Approximately six centimeters of naturally formed sediment cover the mine tailings in the eastern part of the northern basin of Torch Lake. This is not thick enough to adequately prevent the copper from leaching into the lake. The western part of the northern basin, the middle basin, and the southern basin do not have any naturallyformed sediment cap over the mine tailings. The absence of a cap in these regions likely reflects the erosion of material from the above-water stamp sand piles (now capped and vegetated), the shallow water depths that allow mixing of deeper contaminated sediments with uncontaminated freshly deposited material, and the slow rate of sediment formation within this lake. Beneficial use impairments have resulted in restriction of three activities in and around the lake. Restrictions currently exist on dredging activities in Torch Lake. The EPA determined that, due to the toxicity of the sediments, dredging would release more copper into the lake waters. The restriction is enforced by the United States Army Corps of Engineers [5]. The Houghton County Health Department has also listed well permit guidelines for drinking water well depth in order to protect human health [5]. The State of Michigan continues to issue consumption advisories for pike, small mouth bass, and walleye from Torch Lake, although it is not clear that the Hg and PCBs found in the fish are of local origin [cite Michigan 2004 Fish advisory http://www.michigan.gov/documents/FishAdvisory03_67354_7.pdf] Other than the restrictions listed above, no other normal activities are banned on the lake at present. However, the EPA has recommended that boats or ships with large propellers not enter Torch Lake through the passage from Portage Canal. The reasons for this are much like the reasons for the restriction of dredging: to mitigate the resuspension of toxic particles [6]. /It would not be inappropriate to have here a section on Prognosis for Recovery in which the rate of “remediation” is discussed. How can you evaluate acceleration unless you define the existing rate of recovery? 4.0 Evaluation of Remediation Alternatives Several options are available for contaminated sediment remediation; the most effective means is, of course, dependent upon the situation. In the case of Torch Lake, the following key aspects must be considered: the sediment is contaminated with high levels of copper, large amounts of sediment are present, and access is limited. Cost and effectiveness of each method governs the action selected /This sentence seems to 10 be hanging here without context enough context. Were these the only 2 criteria used to select from among the listed alternatives?/ Based on the history of Torch Lake and its contamination, the following methods of remediation were investigated: Dredging – Dredging is a process by which all contaminated sediments are dug out of the lake and removed from the site. Due to the extensive size of Torch Lake, a barge would be needed for the dredge to reach all portions of the lake. While dredging completely removes all contamination and restores the lake to its original shape and size, it also results in a large amount of turbidity in the process. This causes the copper concentrations in the water to rise dramatically. In addition, because the volume of contaminated sediment is so massive, dredging would be an especially costly approach [7]. Furthermore, disposal of the sediments would require … Capping – Geosynthetics, sands, clays, gravels, or other similar materials may be used for a cap. The area and/or amount of material needed are the driving factors for cost and effectiveness. Capping would seal the contaminated sediment and keep the copper from dissolving into the lake; however the contamination in Torch Lake covers over 2400 acres. The cost of capping this much surface area is generally high. Cap placement can be accomplished using one of many techniques, each with its own unique challenges [8]. Wetlands and Vegetation – Wetlands and vegetation require creating shallow ponds with appropriate vegetation to trap and concentrate contaminants from the sediment. Vegetation for this situation must have an affinity for copper. The plants in the shallow water absorb the contamination out of the sediment. Once the copper has bioaccumulated in the plants, harvesting is necessary to prevent the copper from re-entering the environment. This process can be costly and time consuming. It can also be difficult to begin the growing process – capping would most likely /might/ be needed [9]. What portion of the lake could be treated? Sulfide Generation – Sulfide generation is a process which uses organic matter to generate sulfides. The sulfides trap the copper in the water and the sediments, allowing benthic organisms to survive. Sulfide generation could be a very inexpensive solution as long as the necessary conditions were met. Sufficient organic matter and an emplacement method would need to be determined [10]. The alternatives listed above were evaluated in terms of cost, time, and feasibility constraints. Dredging was not selected because /list specific reasons/. Wetlands were were thought to be unlikely to have an effect on the lake as a whole because they could be created only in shallow areas (what percent of lake?); furthermore, the high maintenance costs associated with vegetation harvesting rendered this option unattractive. Sulfide generation was ?? /state clear and explicit reasons for not 11 choosing this option/ This left capping as the method of choice despite the potential for moderately high costs. /It still might be desirable to create a table listing relative costs (low, medium, high), time requirements, or other factors that would make more clear why you selected capping./ 5.0 Proposed Method of Remediation To accelerate the remediation of Torch Lake, a modified method of capping was chosen. The entire contaminated area (approximately 2,400 acres) is too large to be feasibly capped at once. Thus, it is recommended that the lake bottom be capped in phases. The Test Phase and Phase One are described below in the Description of Phase Areas. That section also illustrates how to choose additional phases if the Test Phase and Phase One prove successful. Capping was chosen for two reasons: 1) sand – the chosen material – is relatively inexpensive, and 2) the labor and machinery needed for the job are cost efficient and readily available. The capping can be completed fairly quickly for each phase, and monitoring can be done easily to determine success or failure. As shown below (where? I don’t see that this is shown anywhere), capping has proven to be the most economical and feasible method of remediation. The chosen method of In-Situ Capping (ISC) is one that has been implemented in similar scenarios by the United States Environmental Protection Agency (EPA). The EPA has created an outline for the design sequence. In compliance with the EPA, the design group addressed every cell within the flow chart shown in Appendix A. A sediment cap protects a water body from underlying contaminants via several mechanisms. First, by increasing the distance between the source of contamination and the lake, the cap retards the diffusion of pollutant into the lake. Because it would take about a year for the copper to diffuse through a 40-cm cap (as compared to < 1 week for diffusion through the existing sediments), the steady-state flux of copper into the lake would be reduced 50- to 100-fold even if no mechanism existed for copper retention in the cap. However, there are several mechanisms for retention of copper within a sediment cap that further retard its movement through the cap. The copper may sorb to organic matter within the cap, it may precipitate in various oxide, carbonate, or silicate mineral phases, or if hydrogen sulfide is generated through decomposition of organic matter within the cap, the copper may be precipitated as a sulfide mineral. The cap will utilize the naturally occurring organic matter within the capping material (sand) along with the organic sediment that has accumulated on the bottom of the lake as a catalyst for sulfide generation. 5.1 Implementation Before the proposed construction can begin, several steps need to be followed. First, the plan needs to be approved by the EPA if the site is still a Superfund site. Once 12 approval has been received, funds need to be arranged. The funding options are described in a later section of this report. After funding is received, the project will then proceed to the construction sequence. Before, during and after construction, the project team will need to communicate frequently with the local population to keep them informed. A communication plan is outlined in the Public Education section below. The construction will occur as outlined below in the Technical Plans. /I recommend that this paragraph and Table 1 be moved to the beginning of section 5.1/ The proposed remediation is to be implemented if and when the EPA’s No Action Plan is deemed to be ineffectual. Comparison of observed benthos abundance and measured copper concentrations (in the water column, sediment and pore water) with regulatory limits and guidelines (Table 1) provides the criterion for evaluating the No Action Plan as well as our proposed remediation scheme. Even after 35 years of no action since the last stamp mill closed, the lake water copper concentration has not met the EPA’s Recommended Water Quality Criterion of 9-13 mg/L. If, by 2008, sampling indicates that copper concentrations have still not reached this level and the benthos remain severely impaired, the EPA’s “No Action” Plan will have proven ineffectual, and the proposed alternative could be implemented. Table 1: Comparison of Observed Conditions in Torch Lake with Guidelines and Regulations Guidelines or Regulatory Limits 9-13c (15-19 for MI) Undefined due to sampling difficulty Category 1980’s 1990’s 2001 2004 Cu in Lake Water (μg/L) 30-50a 25-30b 27-44g not yet released Cu in Pore Water (μg/L) 200-600a 890d 2,500e Cu in Sediments (mg/kg) 1,200a 12,000e 1,000d 4,200e 635-5,850g 1,600-2,000f PEL: 108-390 Benthos Severely impaired Severely impaired Severely impaired Severely impaired Site-specific; undefined for Torch Lake not yet released a) Leddy at al. [10a] b) Cusack (1995) [10b] and Urban (unpubl.) [?] (Should I reference this to what is currently [13] Dr. Urban, or is there a report or something I need to reference it to?) Citation should be: Urban, N.R., Dept. Civil & Environmental Engineering, Mich. Tech. Univ., Houghton, MI, unpubl. data. c) U.S. EPA recommended surface water quality criteria d) Cusack (1995) [10b] e) Jeong et al. (1998) from hot spot off Lake Linden [10c] f) Surface values in sediment cores from eastern half of main lake basin (Urban unpubl.) [?] g) Baseline Study Report Torch Lake Superfund Site Houghton County, Michigan (2001) [10d] 5.2 Technical Plans 13 5.2.1 Description of Phase Areas As noted previously, capping the entire bottom of the lake is not a feasible option due to Torch Lake’s extensive size. Therefore, capping in phases is recommended as a means to make construction physically and economically feasible. An initial Test Phase is proposed followed by capping of larger areas in successive phases. The chosen Test Phase site is an approximately 13-acre cove immediately west of the Tamarack City sewage lagoons (seen in figure XXX of appendix B) (The map of the work site will be within the appendix, I am not sure if we need to reference the locations within the report of such items or not. /It would not hurt/). This site was chosen for three primary reasons. First, this cove is somewhat isolated from the rest of the lake; this makes it an ideal “control area” for testing and monitoring. Second, the size and shape of this site require relatively simple and inexpensive construction techniques. The selected construction equipment can access all surfaces of the cove relatively easily. The final primary reason for selecting this area for the Test Phase is that the land surrounding it is publicly owned and undeveloped. This simplifies land use issues. In addition, a stream flowing into the test area will help to “seed” benthic organisms in the fresh, uncontaminated sediment cap. As the name implies, the Test Phase will be monitored to ensure that it is indeed accelerating the remediation of the cove. The procedures for such monitoring are described in the Monitoring section of this report. If the Test Phase proves successful, the design group recommends similar capping techniques for Phase One. The area suggested for Phase One is located between the mainland and Gull Island and can be seen in figure XXX of appendix B (reference above note). This area is protected from the full energy of wave action by its orientation and the orientation of Gull Island. Phase 1 covers approximately 86 acres of the lake’s surface area. The primary reasons for selecting this area are the same as those laid out for selecting the Test Phase area. The knowledge gathered from the cap placement and monitoring of the Test Phase will be used in Phase One. These selected phases allow “value-added” engineering principles to be used, and help to ensure an economical, efficient, and functional in-situ capping system. Delineation of specific areas for Phases Two and beyond is not within the scope of this remediation plan. It is the conclusion of the design group that the methods for implementation outlined in this report could be applied to any part of the lake and, provided enough money was available, to any size area. A procedure for selecting additional phase sites is as follows. When selecting a site for Phases Two and beyond, it is most important that the area is large enough to sustain itself without becoming buried under contaminated sands. Ideally the area should be located such that natural shoreline erosion will not cover the in-situ cap. Therefore any area that is chosen should be capped all the way to the nearest adjacent shoreline. It is recommended that any practical knowledge gained by the placement of the Test Phase 14 and the Phase One caps be applied to the construction technique for any and all selected future phases. The goal of any additional phases should be to cap as large a portion of the lake as possible. The design group suggests that, ultimately, the entire lower and middle basins of the lake and parts of the upper basin be capped using the aforementioned techniques. 5.2.2 Field Investigation This section seems out of place. It really interrupts the flow in your description of the technical plan. Perhaps it could be put much earlier in the report in the description of current conditions. The design group sampled the sediment at one location in the Test Phase area to determine the current conditions there. The sampling site was located near the middle of the Test Phase cove where the water depth was 3 m. Sampling was performed in winter by lowering a gravity corer and a ponar dredge through holes drilled in the ice. A 30-cm sediment core was obtained. The core (seen below in Figure 4) had a visible layer of partially decomposed organic matter and purple-tinted stamp sand mixture approximately 10 cm thick above another 20 cm of purple-tinted stamp sands. The organic material is beneficial to the benthic community; however, the continuous natural mixing with the stamp sands contaminates the new sediments and keeps the bottom surface toxic to the benthic organisms. 10 cm of organic matter and stamp sand Stamp sand Figure 4: Test Phase Core Sample 15 The sediment grab sample (0.046 m2 ponar) was sieved (0.5 mm) for benthic organisms. Late winter is an ideal time to search for benthic organisms, as there are generally more insects in the larval stage at the bottom of the lake in winter. The single organism recovered, see below in Figure 5, was a bright red midge larva; the calculated density is 22 per m2. Figure 5: Red Midge Larvae 5.2.3 Cap Design This section must be reorganized and condensed. I would suggest first writing an outline for this section to be sure that the sequence of topics is logical. Then, in writing the section, try to be certain that each paragraph is tightly organized; the first line should identify the paragraph topic, and the conclusion of the paragraph should be in either the first or last sentence. The material in this section should be understandable to every member of the class, even though not every one will understand it at the same level. In general, it is good to go from simple to greater levels of detail, and it is better to err on the side of explaining too well. One issue that is not addressed anywhere in the report is why a protective or armoring layer is not included in the cap. I think that such a layer probably is not needed, but it should be mentioned. If a marina (or other area of high boat traffic) were to be capped, such a layer would be desirable. Another topic that is not clear in this version is why pore water concentrations are used as the criterion for evaluating the cap. There are no regulations for porewater concentrations; the monitoring program will use lake copper concentrations and sediment copper concentrations as indicators of whether regulatory guidelines have been met. I wonder if a simple description of what occurs in a cap is not warranted to help understand what the model is predicting. What is meant by consolidation of the cap and underlying sediment? How long does the consolidation take? Why do copper concentrations go down over time at the top of the cap? Given that the model is assuming only one mechanism for copper retention in the cap, is the model prediction conservative or the opposite? What safety factor was incorporated into the design? To determine the cap thickness and organic carbon content, a computerized model was implemented. The model used to determine the thickness of the sediment cap was the Hazardous Substance Research Center (HSRC) Capping Model. The model used is a web-based model provided by the South and Southwest Region Hazardous Substance Research Center and was created by André Marquette of the Chemical Engineering Department at the Louisiana State University. This model is used for the determination of cap parameters and to analyze the chemical transport of contaminated pore-water 16 through the sediment and cap [11]. It assists in the design of a sediment cap by evaluating the chemical transport in pore-water. The model is based on the fundamental equations found in Appendix B of the ‘Guidance for Sub-Aqueous In-Situ Sediment Capping’ (EPA 905-B96-004) [12]. The model can be viewed online at: http://capping.hsrc.lsu.edu/ The model simulates the results by way of inputting sediment and contaminates properties. The input data is used to solve for the coefficient of the standard mass balance partial differential equation, this coefficient is the retardation factor. This model considers several different issues including Darcian groundwater flow, effects of benthic organisms, contaminant adsorption due to organic carbon, and dispersion due to sediments. An effective capping thickness was determined using the model. It is assumed that the underlying sediment remains uniformly contaminated at the concentration levels prior to cap placement [12]. Another assumption is that the capping material is spatially uniform and that pore-water is not horizontally forced through the sediment by the cap [12]. Therefore the cap thickness is determined from the initial thickness, bioturbation thickness, the consolidation thickness of the cap and the consolidation in the underlying sediment. The equation used for the effective cap thickness is Leff=L0-Lbio-ÄLcap-ÄLsed. where Leff = Effective cap thickness L0 = Initial cap thickness Lbio = Thickness of bioturbation ÄLsed = Thickness affected by short term pore water migration due to consolidation in the underlying sediment Ä Lcap = Thickness by consolidation of the cap The effective cap thickness is subjected to two different components for chemical transport. The short term consolidation of the sediment underlying the cap is considered for the advective component. Another component is the diffusive or advective-dispersive component. This component accounts for the movement of contaminate as pore-water after the cap has been stabilized. Advection and diffusion are the driving forces when estimating the effectiveness of the cap during its lifetime. These processes will help determine the loss or release of the contaminant over time by the estimation of the flux of the contaminant. The main equation used in this model is: Retard*(dc/dt) = Diff*(d2c/dt2) – Adv*(dc/dt) + Reaction. where Retard = Retardation factor Diff = Diffusion coefficient A = Advection coefficient 17 Reaction = chemical reaction that occurs The retardation factor found here is the ratio of the total concentration in the soil to that in the pore-water. This factor is used in the calculation of the effective thickness of the cap. Using the model and inserting the sediment, contaminate and capping properties the effective thickness is determined. [12] Many properties were used to develop a sediment cap. To completely evaluate the cap and use the HSRC model copper concentrations, sediment properties and capping material properties were needed. These properties for the capping model were found using a variety of different sources. A majority of the values were found from previous studies [13]. Table 1 shows the description, values, and units for the different properties used for the capping model. Table 2: Contaminated Sediment and Capping Material Properties used in the Capping Model As the model was run for different capping materials, which included sand, clay and silty sand the cap material properties changed. The properties that changed were the density, porosity and dispersivity of the material; these are seen in Table 2 and 3. Table 3: Porosity and Density Values for Various Capping Materials Mat De Por eria nsitosit l y y (kg/ m3) 18 http://www.cst.cmich.edu/users/Franc1M/esc334/lectures/physical.htm Table 4: Diameter and Dispersivity Values for Different Materials Mat Dia Dis eria met per l er sivi (m ty m) (m) Very Coarse Sand 1.5 7.50E-04 Coarse Sand 0.75 3.75E-04 Fine Sandy Loam 0.175 8.75E-05 Very Fine Sand 0.075 3.75E-05 Silt 0.02 1.00E-05 Clay 0.0015 7.50E-07 http://www.newton.dep.anl.gov/askasci/env99/env201.htm To determine the optimum cap height and organic carbon content, various properties of the capping material were changed as the model ran. Height and organic carbon content of the cap were chosen on a concentration gradient basis. These values were adjusted as the concentration over time was evaluated to determine the optimum cap height and organic carbon content. Cap height is limited to cost as organic carbon content is limited to the available for organisms at the cap-water interface. The cap depth was chosen by running the model at zero percent organic carbon content with a number of different depths. Based on these simulations, 40 cm (approximately 16 inches) was the optimum depth of the cap. On what criterion was this choice of optimum thickness based? Should a graph be shown with these results? What safety factor was applied? The organic carbon content was then varied for the 40 cm (16 in) and three different types of capping material (sand, clay, and silty sand). The organic carbon values used to evaluate the cap depth were 0, 0.05, 0.1, 0.25, 0.5, 0.75, 1, 1.5, 2 percent. For each material, nine variations of the model were run. Each variation had a different organic carbon content value input. One percent organic carbon content was found to be the optimum content. The model showed that one percent produced the fastest decrease in copper concentration with an organic carbon content that doesn’t overload the oxygen availability for the organisms. How was it judged what foc would overload the oxygen resupply capacity of the lake? Given that it states later that the sand likely has only 0.10.5 % OC, it seems as if no margin of safety is being planned. 19 Using the HSRC web-based capping model the optimum capping design was established. The optimum parameters were chosen by evaluating each of the models run for each of the materials. Figure 4 shows the concentration over a hundred years for each of the three capping materials (clay, sand and silty sand) at an organic carbon content of one percent. Of the three materials tested, sand showed the best results, the lowest decrease in concentration. Based on these results, sand is the best capping material option at one percent organic carbon content. Though sand had the best results, all three materials show the same trend: they greatly decrease the concentration of the pore-water at the cap-water interface. The concentration decreases the most rapidly within the first ten years. For the worst case material – clay – the aqueous concentration decreased from 30 μg/L to 10 μg/L. All three of the materials decrease the concentration below the recommendation pore-water concentration of 13 μg/L. Figure 6: Pore-water Concentrations at the Cap-Water Interface for a 100-year Time Period for a Cap at a Height of 40 cm (~16 inches) at One Percent Organic Carbon Content Using sand as the optimum cap material, the other model simulations were assessed more closely to see the effects of the various fractions of organic carbon in the cap. The results of these simulations can be seen in Figure 5. The summary of the simulations for clay, sand and silty sand for the different organic carbon contents can be seen in Appendix C. These simulations were run to look at the trends and to verify that one percent was the best fraction of organic carbon. Similar trends of decreasing concentration were found with the different organic carbon contents. These trends could also be seen in the clay and silty sand simulations. The concentration decreases faster as more organic carbon is added to the model. This decrease of concentration in the pore-water at the cap-water interface is due to the increasing organic carbon content and its adsorption of the copper. Figure 7: Pore-Water Concentrations at the Cap-Water Interface for a 100-year Time Period for a Sand Cap at a Depth of 40 cm (~16 inches) One percent organic carbon was found to still be the optimum level and is a relativity low amount, therefore not to affect the dissolved oxygen concentration availability to the benthic community. This low amount will guarantee the survival of biological life near the cap-water interface. The natural amount of organic carbon in sand is on the order of 0.1 to 0.5 percent. The sand properties used for this analysis can be found in Table 4. 20 Table 5: Sand Properties Used in Simulation Using a sand cap 40 cm thick with one percent organic carbon, the concentration of copper in the pore-water will decrease over time and result in a reduction below the regulatory suggestions. The EPA recommended limit is 13 μg/L. The pore-water in the capped area will decrease to this level in approximately 2 years. In five years monitoring should show that the concentration has decreased will decrease to 8μg/L Table 5 shows the decrease in pore-water concentrations beyond five years, as well as a continuous decrease in concentration. Table 6: Concentration over Time for Sand at 1 Percent Organic Carbon Content To examine the chosen cap further, the model was simulated for 500 years (see summary Table X in Appendix C). According to this simulation, the pore-water concentration will continue to decrease and will reach a steady state in approximately 300 years. The simulated model can be seen below in Figure 6. Figure 8: Pore-water Concentrations at the Cap-Water Interface for a 500-year Period for a Sand Cap at a Depth of 40 cm (~16 inches) at a One Percent Organic Carbon Content Based on the above described modeling, the optimum cap for Torch Lake is a sand cap with thickness of 40 cm (16 inches) and one percent organic carbon content. Using this cap will significantly decrease the aqueous pore-water concentration, reducing it to 5 μg/L by 14 years after the cap is placed, and reaching steady state in 300 years. The model produced very compelling results for a cap at 40 cm (16 in). To verify the produced results the HSRC model was run with virtually no cap containing zero percent organic carbon. This simulated the concentration over time without the aid of a cap. With no cap and zero percent organic carbon, the concentration would not decrease over time. Without a cap and organic carbon, the pore-water is free to transfer out of the sediment and into the open water. Also, without the cap, adsorption aided by the organic carbon of the copper can not occur and therefore a decrease in concentration will not occur. The initial pore-water concentration was assumed to be around 30 μg/L, the verification model produced these same results. Therefore the model is shown to be correct as it has verified the original concentration under natural conditions with no barrier for the contaminate or adsorption process. This verification can be seen in 21 Figure 7, the summary of the verification data can be seen in (Appendix C). This shows a relatively constant concentration over time, just as it would be if there was no cap. Figure 9: Copper Concentration over Time with no Cap or Organic Carbon Verifying Correct and Accurate Results 5.2.4 Work Plan There are several methods available for capping, each used for different situations. The placement technique selected for the Test Phase is ice placement using a crane and clamshell style bucket. Ice placement means that the crane and bucket will spread the sand onto the ice of the phase area during the winter months. Due to the small scale of the Test Phase, the entire region can be reached by a crane on shore which minimizes costs and risk. It is estimated that a reach of approximately 250 feet is sufficient in length to cover any and all parts of the Test Phase cove. Moderately large cranes can readily reach out over 300 feet. The stamp sands are vulnerable to liquefaction and exhibit low shear strength [15]. Because of this, the roads that the equipment will be driving on would need to be packed down and frozen. To do this, a bulldozer will clear the haul road and stockpile area of snow. It is estimated that three times a month during the winter the snow would have to be removed from the “roads” to allow a deep freeze. Once the ground is frozen the large-scale equipment would be able to drive on the sands, and overlying topsoil, safely and non-destructively. The contracted crane operator would choose the material stockpile placement. This operator would be able to choose the most efficient locations of the material for the crane being used. The contracted dump truck operators would create the stockpiles as instructed. Silt fence would be placed around the stockpiles to prevent the capping material from spreading to the surrounding area. As described above, the material selected for this operation is sand. Sand has a natural organic matter content of approximately 0.1 to 0.5 percent. The recommended organic matter content of the material for this project is 1 percent. However, if the 0.1 to 0.5 percent organic matter plus the organic matter currently on the floor of the lake are taken into account, the total amount of organic matter will be sufficient for our purposes. This allows any mixing of additional organic matter (e.g., sludge, leaf refuse) with the sand to be eliminated from the plan. If during the monitoring of the Test Phase the organic matter content is found to be inadequate, mixing can be added to the process for Phase One and beyond. Once the crane is mobilized and the material has been stock-piled, the crane could begin placing the material atop the frozen ice. The crane operator would take care to ensure an even and complete layer no less than sixteen inches in thickness be placed 22 atop the ice. The crane operator would be responsible for keeping track of the completed placement areas. Once the test phase is completed, demobilization should occur as soon as possible to reduce the risk of the ice roads becoming weak due to warmer temperatures. When the ice melts, the sand will drift to the lake bottom, generating the cap. Table 6 below gives the quantities for the Test Phase and equipment needed in order to produce the desired cap. /This is not a paragraph/ Once the Test Phase is determined to be successful based on the monitoring techniques described later in this report, construction on Phase One will begin. Phase One of the project uses slightly more advanced techniques for placement due to the larger area. It is estimated that approximately 10% of the selected area for Phase One will be able to be completed using the same techniques described for the Test Phase. The rest of the area will be placed using what the design group refers to as “Mechanical Placement.” This method employs the same equipment as dredging techniques only in reverse. A clamshell bucket would take material from the barge and place it onto the bottom. This technique would require an experienced dredging/capping contractor to ensure even placement and complete coverage on the bottom of the lake. This placement technique is more costly than the shore-based crane placement, and it is recommended that as much as possible be capped using the crane technique. Inspection of such a technique during construction may only be possible using electronic monitoring of the dredge operations. The contacted dredge operator would assume such monitoring responsibilities. Both of the techniques for placement were determined to be feasible /What does this sentence mean? How was this determined?/. The techniques would ensure that the cap met all criteria described previously. Because Phase One is larger than the Test Phase, it will take longer to cap. Once the Test Phase and Phase One are complete and successful, it is recommended that other phases be planned and implemented until the lake can successfully heal itself in its entirety. 5.2.5 Permits, Legal Issues /This section needs to be more specific/ It is EPA policy that permits from federal and state agencies are not required for work performed at Superfund sites. However, Superfund sites do have to comply with the intent of all permits that would be required if the site were not on the NPL list [16]. Specific aspects of this project that might involve permits are accessibility to the construction location, wetland/shoreline guidelines, using a crane during construction, and erosion control standards for piles of sandy material located on or near the shore. Below is a list of permits that would need to be followed during construction [17]. Because permit requirements change with time, it will be advisable to research this issue again when the project is actually implemented. 23 /Rather than this bulleted list, I would like to see additional information included in a table. Specifically, in addition to these topic areas it would be good to list the relevant law (and section), the agency involved in issuing permits, and a web page or other contact information./ Soil Erosion and Sedimentation Control Program Inland Lakes and Streams (alterations) Permit Shorelands Protection and Management Permit Wetland Protection Permit 5.2.6 Monitoring To evaluate the successfulness of the initial capping, Test Phase monitoring and management of the lake are necessary. The parameters to be monitored include the diversity and abundance of benthic organisms, copper concentrations in the lake water above the cap, copper concentrations in the pore water (to be obtained by centrifuging or pressing sediments) within the surface (0-5 cm below surface) sediments, and copper concentrations in the solid phase of the surface sediments. There are currently thirty-eight sampling locations throughout Torch Lake. These were initiated in 1999 and 2000 for the monitoring of the remediation of the shoreline as well as of the lake. Currently there are no monitoring stations in the Test Phase area, and there is one in the proposed Phase One area. The EPA samples at these stations every five years [18]. Three monitoring stations are recommended for evaluating the success of capping of the Test Phase area. One station would be placed in the northwest section, another in the center and a third in the southeast section of the Test Phase area. At each of the sampling stations, copper concentrations in pore-water, lake water and sediments will be measured as will the abundance and type of benthic organisms. Samples will be obtained every year for the first five years to closely monitor concentrations and the benthic community response. After five years, the monitoring will be performed every five years to ensure that recovery of the lake sediment is continuing and to record the increase in benthos. The criteria for evaluating the success of the capping are the same as for evaluating the current No Action Plan. Lake water Cu concentrations less than 9-13 μg/L, sediment Cu concentrations below 108-390 μg/g, and porewater Cu concentrations below the model predicted values would indicate success of the capping. A diversity and abundance of benthic organisms similar to nearby (e.g., Portage) lakes also would indicate success. It is unlikely that lake water copper concentrations will be affected by capping of the small areas in the Test and First Phase of this project; success would be indicated by the other parameters. After five years the copper concentration of the pore-water at the cap-water interface should be approximately 8 μg/L, as predicted by the aforementioned model. If these conditions are achieved, monitoring of the Test Phase will continue and construction will begin on Phase One. 24 The same monitoring schedule will be used for Phase One. There is currently one monitoring station in the Phase One area [18]. Seven more monitoring stations in this area are recommended, including three surrounding Gull Island. The criteria for evaluating the Phase One cap will be the same as for the Test Phase; if monitoring results indicate the cap was successful, then planning for additional phases could begin. As with Phase One, if successful results are shown the next phase could be implemented until the lake is fully recovered. As more area of the lake is capped there will be an increase in the benthic community as well as a decrease of copper concentration in the lake and sediment. 5.3 Economic Analysis 5.3.1 Projected Costs The projected construction costs were estimated and are displayed below in Table 8. The numbers below represent the price range for which this project could be bid in 2005. It should be used as an engineers’ estimate only and only as a reference until the job is let for bidding. Depending on how long project implementation takes, additional inflation may need to be considered. The following estimate should not be displayed to any contractor who may be involved on the project. Table 7: Cost Estimation for Test Phase and Phase One 25 The above costs for construction are reasonable and were deemed acceptable by the design group. /What does the previous sentence mean? Monitoring of the cap itself will be part of the monitoring plan discussed previously and is not included in this construction cost estimate. Presently, the DEQ is obligated to conduct and pay for the ongoing monitoring of the lake; whether they would conduct the additional monitoring described in this project is not yet known. Any large-scale maintenance deemed necessary during the monitoring period should reference the above numbers for cost estimations. Small-scale maintenance should not be completed due to the complexity and expense of mobilizing the required equipment. Because the Test Phase will be closely monitored, maintenance issues will become apparent during that phase and may play into the feasibility of continuing with Phase One. 5.3.2 Projected Benefits There are several projected benefits of this proposed project. Capping in phases will allow the lake to begin to recover from exposure to the mine wastes. As the lake recovers, better ecological conditions will begin to develop in each phase area, eventually extending throughout the entire lake. As part of these healthier ecological conditions, benthic and fish communities will increase and begin to reproduce and sustain themselves in the lake. Decreased copper concentrations in the lake water may enhance algal production and thereby promote faster rates of sediment accumulation and burial of the contaminated sediments. Increased fish populations and clean sediments will allow for increased recreation on and around Torch Lake. Natural fish reproduction may lessen the need for stocking of the lake. The fishing and swimming conditions will improve, boosting the local economy. 5.3.3 Funding Sources Funding for this remediation project would come in the form of grants from state, federal and nongovernmental sources. Groups that might manage the project and that could apply for these grants include local citizens groups such as the Torch Lake Public Action Committee (TLPAC), civic organizations (e.g., Trout Unlimited), or local government entities (e.g., Houghton County). For this type of project numerous grants are available, and some detailed information for them is given below. From a link on the EPA website many grants can be found in the Catalog of Federal Domestic Assistance (CFDA) [21]. Many of these grants are allocated on a case by case basis with a limited amount to disperse over a certain 26 geographical region, so obtaining awards for these grants may prove to be challenging depending on the environmental priority of this project. Not all grants are specifically intended for the construction process. A few may cover only monitoring costs or technical advising expenses. Also several of these funding sources require proper planning and design information to be available to insure that the project plan is in order and meets grant requirements. Again, rather than a bulleted list, I would recommend a Table. MDEQ Michigan Coastal Management Program Grants [22] o Applications are due by April 1, 2005 to get funding by the following January (applications found on MDEQ website) o $50,000 average award matched 1:1 with state and local funds MDEQ Water Quality Management Grants (monitoring only) [22] o Proposals due: April 15, 2005 o $100,000 is available for inland lake beach monitoring grants, $200,000 for local water quality monitoring grants, and $200,000 for emerging issues monitoring grants o Eligible parties: local governments and nonprofit organizations o Further detailed information found on MDEQ website Clean Water Act Section 319 Funds [22] o Use is for preventing non-point source pollution in watersheds o Applications due: April 8, 2005 o Application forms on MDEQ website o $2.9 million available in Michigan for 2005 with 40% matching o Minimum of 25% matching Targeted Watershed Grant Program [21] o Goal is to restore, preserve, & protect the nation’s watersheds o State governors apply for national assistance for respective state projects o $600,000 to $900,000 on average per award per project with a minimum 25% non-federal match o Application forms on EPA website (CFDA 66.439) Regional Environmental Monitoring & Assessment Program [21] o Applications due: March 14, 2005 o $192,000/award o additional information on the EPA website (CFDA 66.512) National Coastal Wetlands Conservation Grants [23] o Covered under the Coastal Wetlands Planning, Protection, & Restoration Act o Information found on the Fish & Wildlife Service’s website o Eligible only through the state 27 o Applications due: 1st week in June o Award ranges: $75,000 to $1,000,000 with 50% match Michigan Great Lakes Protection Fund [22] o Utilized for new research and demonstration projects to preserve, enhance, and restore the Great Lakes and its component ecosystems o Average proposal amount is $75,000 o Funding notification varies each year o Information found on the MDEQ website Superfund Technical Assistance Grants [21] o Given to qualified groups to contract with independent technical advisors to help in interpreting and commenting on Superfund site-related information and decisions o $50,000 as an initial award with a 20% match required unless waived due to financial burden o further detail can be found on the EPA website (CFDA 66.806) Another source of funding that could be researched is the remaining money from the original grant allowance of $15.2 million from the EPA for the Superfund site. Approximately $12.2 million of the original amount has been allocated to date. The remaining funds may be required further maintenance of previous work, but with coordination with the EPA this money could become available for this specific project. Grants that require some percent of matching contributions from state and local agencies will need to be anticipated in future budgets in order to acquire such funding. These actions would require further coordination with respective governmental entities. 5.4 Public Education In the process of remediating Torch Lake, there must be measures taken to inform the public about what is happening in their local environment. Therefore, it is necessary to have a plan of action for educating the public on what is going to happen to Torch Lake in the design and construction processes. Citizen involvement is needed on Superfund sites in order to meet community needs and to promote a successful outcome of the remediation. The process to educate the public can be quite involved with several methods of informing the local community about what is going to happen to the remediation site. /This is not a paragraph/ A first step is to have a public meeting to explain the process for the remediation of Torch Lake. In order to inform the local community about this meeting, an advertisement would need to be posted in the local newspapers at least two weeks in advance. A printed flyer with details of the meeting may also be needed, as some 28 residents do not receive the local newspaper. At the meeting a fact sheet would be distributed to each attending citizen. Graphics to aid in the explanation of the remediation process should also be included. Following the public meeting, a 30-day public comment period would be required to allow local citizens to respond to the content of the public meeting. If substantial interest is shown by the community, the amount of time for the public comment period could be extended to 60 days. A second method of maintaining contact with the community is through bi-monthly fact sheets. A fact sheet could include information encouraging citizens to write or call the Community Relations Coordinator or Remedial Project Manager with any comments or questions. It also could include a blank mailing label for citizens who are not currently on the mailing list but would like to be. Knowing the level and type of public interest is necessary for planning successful community relations activities. Another method for involving local residents is making monthly telephone calls to key local officials or citizen leaders and soliciting their input; this demonstrates to the community that their thoughts are important. Another useful method is setting up a toll-free number to provide the public with easy access to the EPA and to allow the public to inform the EPA of any problems in the community because of the project [24]. These three methods of contact should be arranged by the EPA or the group to whom they have contracted the project. Currently there are high school students in four area schools performing long-term monitoring of soil, plants, and birds on the Torch Lake Superfund Site in site areas that have already been remediated. This process began in August of 2003 and a commitment has been made by those schools to continue performing the studies through 2006 [25]. The students that are performing these monitoring tasks could be used for monitoring soil samples from the bottom of Torch Lake in our Test Phase and Phase 1 areas. The most economical method for the testing would be to take soil samples in the winter when the lake is frozen. The monitoring of the Torch Lake Superfund site is an educational experience for the students as well as a method for further educating the public about the capping method. 6.0 Conclusion This design group believes that the natural remediation of Torch Lake can and should be assisted by a 40 cm (16 inch) sand cap with an organic carbon content of one percent. This solution will benefit the benthic community of Torch Lake while remaining cost and time effective. Due to the nature of this project, its construction should be implemented as soon as possible. The EPA’s guidelines were strictly followed and every cell on the flowchart addressed. The earlier this project is begun, the sooner it will benefit the benthic 29 community. It is the recommendation of this design group that this project be implemented as soon as possible and according in accordance with this report. 30 7.0 References [1] [2] “NPL Factsheets for Michigan: Torch Lake.” Region 5 Superfund Division. United States Environmental Protection Agency. December 10, 2004. http://www.epa.gov/R5Super/npl/michigan/MID980901946.htm. Accessed March 2005. [3] “Record of Decision List: Torch Lake.” Superfund Information Systems. United States Environmental Protection Agency. January 12, 2004. http://cfpub.epa.gov/superrods/rodslist.cfm?msiteid=0503034#rodlist. Accessed March 2005. [4] Portage Lake District Library. 105 Huron Houghton, Michigan 49931 (906) 482-4570 Lake Linden/Hubbel Public Library 601 Calumet Street Lake Linden, Michigan 49945 (906) 296-0698 [4a] EPA Source for recommended surface water quality criteria (Dr. Urban) [4b] State of Michigan Source for recommended surface water quality criteria (Dr. Urban) [5] “Torch Lake Area of Concern”. United States Environmental Protection Agency. July 6, 2004. http://www.epa.gov/glnpo/aoc/trchlke.html. Accessed March 2005. [6] Beaver, Bill and Jim Gondec. Area of Concern (AOC) Torch Lake, MI. Michigan Technological University Environmental Policy Program. June 1998. http://www.ss.mtu.edu/EP/TorchLake/AOC.html. Accessed March 2005. [7] Dredging source (Kris) [8] Capping source (Kris) [9] Wetland source (Kris) [10] sulfide generation source (Kris) 31 [10a] Leddy, D.G., S.T. Bagley, T.J. Bornhorst, S.H. Bowen, W.W. Charland, L.D. Dorie, F.H. Erbisch, D.S. McDowell, W.I. Rose, and J.A. Spence. Torch Lake Study (Project Completion Report). Michigan Department of Natural Resources. 1986. [10b] Cusack, Cynthia C. Sediment Toxicity from Copper in the Torch Lake (MI) Great Lakes Area of Concern: Thesis for the degree of Master of Science. Houghton, MI: Michigan Technological University, 1995. [10c] Jeong J. N.R. Urban, and S.A. Green. Release of Copper from Mine Tailings on the Keweenaw Peninsula. Journal of Great Lakes Research: 25 (4), 721-734. 1999. [10d] Baseline Study Report Torch Lake Superfund Site Houghton County, Michigan. United States Environmental Protection Agency. August 2001. [11] Louisiana State Chemical Engineering Capping Design Model. Louisiana State University. http://capping.hsrc.lsu.edu/. Accessed March 2005. [12] Reible, Danny D. “Guidance for In-Situ Subaqueous Capping of Contaminated Sediments: Appendix B: Model for a Chemical Containment by a Cap.” United States Environmental Protection Agency. http://www.epa.gov/glnpo/sediment/iscmain/appndb.pdf. Accessed March 2005. [13] Urban, Noel PhD. [14] Chin, David A. Water Resources Engineering. Upper Saddle River, NJ: Prentice Hall, 2000. [15] Crane, Dick. Construction Inspector. State of Michigan Natural Resources Conservation Service. Personal Interview February 8, 2005 by the design team. [16] Jones, Brenda. United States Environmental Protection Agency. Division Office Chicago, Illinois. Jones.brenda@epa.gov. Personal Interview March 8, 2005 by Lindsey Anderson. [17] Environmental Permits, Licenses, and Certifications. Michigan Department of Environmental Quality. 2005. http://www.michigan.gov/deq/0,1607,7-135-683089034--,00.html. Accessed March 2005. [18] monitoring source (Tiffany) [19] Heavy Construction Data – RSMeans. 17th annual edition, 2003. Construction Publishers and Consultants. Kingston, MA. Copyright 2002. [20] Crawler Cranes. Liebherr Group. http://www.liebherr.com/cr/en/default_cr.asp. Accessed March 2005. 32 [21] The Catalog of Federal Domestic Assistance. United States Environmental Protection Agency. http://12.46.245.173/cfda/cfda.html. Accessed March 2005. [22] Michigan Department of Environmental Quality. www.michigan.gov/deq. Accessed March 2005. [23] United States Fish & Wildlife Service. www.fws.gov. Accessed March 2005. [24] Community Relations Handbook, Appendix H. United States Environmental Protection Agency. July 29, 2005. http://www.epa.gov/superfund/action/community/involvement.htm. Accessed March 2005. [25] Torch Lake: EPA Superfund Site Monitored by Michigan Students. Joan Schumaker-Chadde, Education Program Coordinator, Michigan Technological University, 2004. 33 8.0 Appendices Appendix A: Flow Chart Appendix B: Maps of Worksite Appendix C: Simulation Summary for Clay, Sand, and Silty Sand 34 DESIGN SEQUENCE FOR IN-SITU CAPPING PROJECTS DEFINE GOALS OF REMEDIATION EVALUATE CONTAMINATED SEDIMENT CHARACTERISTICS CHARACTERIZE CAPPING SITE CAPPING FEASIBLE? NO CONSIDER ALTERNATIVES NO CONSIDER ALTERNATIVES NO CONSIDER ALTERNATIVES YES DESIGN CAP COMPONENTS SELECT EQUIPMENT AND PLACEMENT TECHNIQUE NOTE: ALL BRANCHES OF THE FLOWCHART MUST BE FOLLOWED CAPPING DESIGN ACCEPTABLE? YES DEVELOP MONITORING AND MANAGEMENT PROGRAM DETERMINE CONSTRUCTION MONITORING AND MAINTENANCE COSTS COSTS ACCEPTABLE? YES IMPLEMENT 35