Chemistry Notes for Chapters 2-4 Atoms -Elements -Compounds Compounds -Molecular (non metals and neutral) CO2, SO2 -Ionic Cl-, Na2 Atomic Theory 1. Elements are composed of extremely small particles 2. All atoms of a giver element are identical, having the same size, mass, and chemical properties 3. Compounds are composed of atoms of more than one element 4. A chemical reaction involves only the separation, combination, or rearrangement of atoms, it does not result in their creation or destruction Nomenclature Ions-either cations which are positively charged or anions which are negatively charged -examples of anions: e- +F- = flouride Chlorine atom + e- = Chloride Cl-examples of cations: Na+ + 1e- = Na Sodium atom Ionic compounds [cations][anion] -Na+ + Cl- = Sodium Chloride -K+ + S2- = K2S or Potassium sulfide Structure of the Atom Atoms-basic unit of an element Electron-Negatively charged particles Nucleus-where the positive charges are concentrated (protons) Neutron-proved to be electrically neutral particles having a mass of slightly greater than that of protons Atomic Number The number of protons in the nucleus of each atom of an element is its atomic number. In a neutral atom the number of protons is equal to the number of electrons so that atomic number also indicates the number of electrons present in the atom Mass Number Is the total number of neutrons and protons present in the nucleus of an atom of an element. Mass Number = number of protons + number of neutrons = atomic number + number of neutrons Periodic Table Periodic Table-a chart in which elements have similar chemical and physical properties are grouped together. Periods-Horizontal rows Groups-Vertical Rows Metals-good conductor of heat and electricity Non Metals-a poor conductor Metalloid-properties that are intermediate between metals and non-metals Group IA-alkali metals Group IIA-alkali earth metals Group VII A-halogens Group VIIIA-noble gases Molecules Molecules-an aggregate of at least two atoms in definite arrangement held together by chemical bonds. Diatomic molecule-contains 2 atoms Poly-atomic-contains more than 2 atoms Chemical Formulas Molecular formula-shows the exact number of atoms of each element in the smallest unit of an element Empirical formula- tells us which elements are present and the simplest whole number rations of their atoms Naming Compounds Organic Compounds-contain carbon, usually in combination with elements such as hydrogen, oxygen, nitrogen, and sulfur Ox ions ClO3- chlorate ClO4- perchlorate BrO4- perbromate Bro3- bromate NH4- ammonium Acids and Bases Acids-a substance that yields hydrogen ions when dissolved in water Formulas for acids contain one or more hydrogen atoms as well as an anion group Bases-a substance that yields hydroxide ions when dissolved in water Chapter 3 Mass Relationships in Chemical Reactions Molar Mass-defined as mass of 1 mole of units If we know the atomic mass of an element we also know its molar mass Molecular mass-sum of the atomic masses in a molecule Percent Composition-percent by mass of each element in a compound Reactions-steps to figure out a reaction 1. 2. 3. 4. balance input information given identify the goal crate a path to reach the goal Chemical Reactions- process in which substance is changed into one or more new substance Equations- uses chemical symbols to show what happens during the reaction Chapter 4 Reactions in Aqueous Solutions Solutions-a homogenous mixture of 2 or more substances Solute-substance present in smaller amounts Solvent-the substance present in larger amounts What happens when solute dissolves in water 1. Electrolytes - strong: ionic compounds - weak: acids and bases 2. Non Electrolytes - molecular compounds Electrolytes-solution that can conduct electricity, forms both positive and negatives Non electrolytes: Solution does not conduct electricity Types of Reactions 1. Precipitation Reactions 2. Acid Base Reactions Precipitate Reactions Precipitate-insoluble solid that separates from solution Acid Base Reactions Acid-have a sour taste, vinegar owes its taste to acetic acid Bases-have bitter taste, feel slippery, cause color changes in plant dyes Examples Weak Base: Ammonium Hydroxide Strong Acid: Nitric Acid Sulfuric Acid Weak Acid: Nitrous Acid Acetic Acid When you have Oxidation Reduction reactions Reduction gains electrons Oxidation loses electrons Oxidation number-the charge that atom would have in a molecule if electrons were completely transferred. 1. Free elements have an oxidation number of 0 2. In monoatomic ions the oxidation number is equal to the charge of the ion 3. Always-Group 1A metals are +1 and Group 2A metals are +2 4. Most cases H is +1 except when it is bonded to metals, and O is 2- except when it forms peroxide. 5. The sum of the oxidation number of all atoms in a molecule or ion is equal to the charge of the molecule or ion Redox Reactions 1. 2. 3. 4. 5. Combination Decompostion Combustion Disproportionation Displacement