STOLLER CHEMICAL COMPANY OF CANADA LIMITED 940 SHELDON COURT BURLINGTON, ONTARIO L7L 5K6 1-800-263-9114 MATERIAL SAFETY DATA SHEET SECTION I IDENTIFICATION Emergency Phone Number Chemical Family Chemical Name & Synonyms: Formula: Trade Name & Synonym: CHEM-TEL, INC. 1-800-255-3924 Organic Salt Solution N/A – Mixture Proprietary THIS COPPER 5% SECTION II PRODUCT AND COMPONENT HAZARD DATA A. CAS. REG. NO 7758-99-8 COMPONENTS Copper Sulphate APPROX. % 20% TLV 1 mg/m3 as Cu SECTION III PHYSICAL DATA Appearance and Odor: Boiling Point: Specific Gravity: Vapor Pressure: Percent Volatile by Volume: Vapor Density (Air = 1) Evaporation Rate: Solubility in Water: Brown, sweet, molasses like odor 212 F 1.25 30 mm (approx.) Proprietary >1 (Ethyl Ether = 1): <1 >99% SECTION IV FIRE AND EXPLOSION HAZARD DATA Flash Point: Flammable Limits: Extinguishing Agent: Special Fire Fighting Procedures: Unusual Fire and Explosion Hazards: Hazards: N/A N/A N/A NA May evolve SO2 if involved in fire. SECTION V REACTIVITY DATA Stability: Incompatibility: Hazardous Decomposition Products: Hazardous Polymerization: Stable Oxidizers, strong acids May evolve SO2 over 300 C. Will not occur. Page 1 of 3 STOLLER CHEMICAL COMPANY OF CANADA LIMITED 940 SHELDON COURT BURLINGTON, ONTARIO L7L 5K6 1-800-263-9114 SECTION VI TOXICITY AND HEALTH A. EXPOSURE LIMITS OSHA Permissible Exposure Limit (PEL): Threshold Limit Value (TLV): 5 mg/m3 as Mn, 1 mg/m3 as Cu B. EFFECTS OF OVEREXPOSURE 1. 2. ACUTE a. Inhalation: b. Eyes: c. Ingestion: d. Skin: CHRONIC: Irritation Irritation may cause ulceration. Irrigation, somnolence, nausea, and vomiting Irritating. Animal studies have implicated manganese as possible carcinogen. Copper compounds have shown adverse on male reproductive organs. C. EMERGENCY FIRST AID PROCEDURES Inhalation – Remove from exposure area. If irritation exists from mists, or in the event of massive inhalation, seek medical attention. Eyes – Rinse thoroughly with plenty of water for at least 15 minutes. Seek medical attention. Ingestion – Drink large quantities ( at least 2 glasses) of warm water. Seek medical attention. Skin – Wash with soap and water. Rinse thoroughly; seek medical attention if inflammation occurs. D. ANMAL TOXICITY DATA Copper Sulphate LD-50 (oral-rat) 300 mg/kg SECTION VII PERSONAL PROTECTION AND CONTROLS A. RESPIRATORY PROTECTION – As required by conditions. Use an OSHA or NIOSH approved respirator if required. B. VENTILATION: General: Use if needed for safe comfortable working conditions. Local Exhaust- Not normally required. C. SKIN AND EYE PROTECTION: Safety glasses should be worn in any type of industrial operation. Protective gloves should be worn as a good hygiene dictates. D. OTHER CONTROL MEASURES: An eye bath and washing facilities should be available. Wash thoroughly after handling. Page 2 of 3 STOLLER CHEMICAL COMPANY OF CANADA LIMITED 940 SHELDON COURT BURLINGTON, ONTARIO L7L 5K6 1-800-263-9114 SECTION VIII SPECIAL STORAGE AND HANDLING PRECAUTIONS Since emptied packages retain product residue, follow label warnings even after package is emptied. SECTION IX SPILL, LEAK AND DISPOSAL PRACTICES STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED. Collect and contain for salvage or disposal. Absorb waste on inert media and dispose of as solid waste. WASTE DISPOSAL METHOD: Landfill in compliance with all federal, state and local laws concerning health and environment. SECTION X ENVIRONMENTAL EFFECTS DATA SUMMARY: Copper compounds are quite toxic to some species of fish and mollusca. Avoid introduction into any body of water. No hazards are anticipated to warm-blooded animals from normal use dilutions. SECTION XI TRANSPORTATION Proper Shipping Name: Copper Chloride Solution DOT Hazard Classification: 8 (9.2), UN2802, P.G. III The information contained herein is furnished without warranty of any kind. Users should consider these data only as a supplement to other information gathered by them and must make independent determinations of suitability and completeness of information from all sources to assure proper use and disposal of these materials ands the safety and health of employees and customers. Page 3 of 3 January 2013