CubeSat DeOrbit System Final Report MAE 434W December 3rd, 2013 Students: Joshua Barham Trevor Jackson Timothy Lynch Joseph McNamara Joe Powell Troy Tarnacki Faculty Advisor: Dr. Robert Ash Table of Content Abstract................................................................................................................................ii Introduction..........................................................................................................................1 Background..........................................................................................................................2 Completed Methods.............................................................................................................2 Proposed Methods................................................................................................................5 Preliminary Results..............................................................................................................7 Discussion............................................................................................................................7 Appendices...........................................................................................................................9 References..........................................................................................................................22 List of Figures Figure 1 - CAD model of baseplate.....................................................................................9 Figure 2 - Gasket, baseplate with screws, and baseplate cap...............................................3 Figure 3 - Baseplate with membrane, gasket, and cap assembled.......................................3 Figure 4 - Cutting wire and battery......................................................................................9 Figure 5 - Enthalpy of Sublimation of Benzoic Acid vs. Temperature.............................10 Figure 6 - Necessary mass of Benzoic Acid vs. Volume of Aerobrake and Pressure inside Aerobrake...........................................................................................................................10 Figure 7 - Necessary Energy for Sublimation of Benzoic Acid vs. Volume of Aerobrake and Pressure inside Aerobrake...........................................................................................11 Figure 8 - Baseplate with deployed inflatable.....................................................................6 Table 1 - Saturation Temperature as a function of Pressure with respective Elevations...12 i Abstract There has been an urgent need expressed by the United Nations to reduce space debris. It is currently recommended that devices placed in orbit should have the ability to deorbit themselves within 25 years, however, a mandate of this recommendation may be on the horizon. This time constraint restricts CubeSats to a launch altitude of 600 km. By utilizing technology first implemented by NASA's Echo I project a deorbit system is being developed. This paper describes the apparatus that will utilize the sublimation of benzoic acid to inflate a drag device, or aerobrake, that will allow for controlled and expedited deorbit of a CubeSat. ii Introduction Debris from leftover space missions creates a hazardous environment for the International Space Station as well as expensive military and industrial satellites. The United Nations (UN) has published debris mitigation guidelines, which mandatory requirements expected in the near future. To resolve this accumulation of space debris, aerodynamics brakes (aerobrakes) are being developed for CubeSats and satellites to reduce their orbit life [1]. The use of small satellites and cube satellites (CubeSats) is increasing because of their relatively low cost to produce and lower cost to launch due to their low mass. Aerobrakes using mechanical mechanisms are currently being used, but they take up a considerable amount of volume inside the CubeSat while being stored, creating the need for an aerobrake that takes up less space when stowed. The use of benzoic acid to inflate a balloon like aerobrake has been used by the National Aeronautics and Space Administration's (NASA) Project Echo [2]. The use of benzoic acid has not been used on CubeSats for deorbit, creating the potential for a small storage volume aerobrake device. The design for a benzoic acid driven aerobrake consists of inflating a balloon-like device to create drag, which is attached to a CubeSat. The baseplate encompasses the aerobrake and is pressurized by sealing a membrane material through use of a gasket between the baseplate and cap. A high resistance heating wire is used to cut the membrane and deploy the aerobrake, which is then inflated by the sublimation of benzoic acid. The membrane is responsible for holding the aerobrake inflatable under pressure inside of the baseplate. Without the membrane the benzoic acid within the inflatable would sublimate prematurely, inflating the balloon in the lack of pressure in low earth orbit. A thin membrane that can be cut by a high resistance heating wire was configured to deploy the aerobrake. A Nichrome (Nickel-Chromium) wire will be subjected to electrical current raising the temperature of the wire. A sufficient power supply is needed in order to supply enough power to heat the Nichrome wire to the melting point of the membrane, cutting it and releasing the aero-brake. Once the aerobrake is released, the vacuum pressure of low earth orbit along with solar radiation energy from the sun and the earth will induce a phase change of the stored solid benzoic acid into a gas inflating the aerobrake. A comprehensive thermal analysis was conducted in order to determine how much energy input is needed to start the sublimation of benzoic acid at a given temperature and pressure. The baseplate, to encompass the entire aerobrake system, needed to be large enough to contain a folded aerobrake but optimized so that it would not take up any unnecessary amount of space and add unnecessary weight. The baseplate must also be strong enough to prohibit failure due to the internal pressure of the sealed aerobrake. Materials selection for the baseplate will be taken into consideration for cost, ease of manufacture, weight, and overall optimization of the system. The purpose of the project was to find a low mass, low volume, and low cost solution to anticipated international mandates that provides the ability to deorbit small satellites in a controlled manner. The general increase in the rate of CubeSats being placed into orbit in the past few years, due to their low cost nature, provides a need for a small and low complexity system that is easily attachable to existing CubeSat chassis Page | 1 designs. This will allow CubeSat users to continue placing small satellites into orbit while meeting the requirements for deorbit. Background The first successful launch of an inflatable satellite was performed by NASA in 1960. This satellite, known as the Echo I, was constructed to act as a radio relay station and placed into low Earth orbit for the purpose of increasing global communications. Once in orbit, the Echo I was inflated using a sublimating powder known as benzoic acid. Spherical in shape and comprised of a thin metallized polymide, the Echo project demonstrated the low mass, high volume advantages of inflatable payloads used in space operations [2]. It is this research conducted by NASA that is the basis of the Old Dominion University (ODU) CubeSat DeOrbit System. Initiated by Dr. Robert Ash, the initial deorbit design incorporated the use of small gas canisters to inflate a polymide balloon [3]. Since this initial design, previous ODU CubeSat deorbit teams have used the Echo I project as inspiration to utilize benzoic acid as the means of inflation for the aerobrake. The original design also incorporated an aluminum door to protect the aerobrake and gas tanks from any damage from the outside [3]. The design has recently been revised to include the light-weight option of a polymide membrane barrier between the aerobrake and the vacuum of space. A deployment device known as the “ODU Picosatellite Orbital Deployer” or O-POD, was designed by a previous ODU CubeSat team as a means of propelling the CubeSat away from the rocket placing it into orbit. The O-POD remains attached to the rocket and can therefore be reused in future missions. It is the task of the current ODU CubeSat team to incorporate this previous research into the development of a functional deorbit device. Completed Methods The first aerobrake capsule design focused on optimization of the volume inside the baseplate so that the maximum amount of space will be available to hold the aerobrake and accompanying components. The first baseplate was designed for testing purposes only. The aerobrake capsule design consists of a baseplate, membrane, gasket, metal cap and are assembled in that order (see Figure 1, Appendix 1). After the components are put in place screws are inserted through the cap, gasket, membrane, and screwed into the baseplate in order to form an airtight seal between the membrane and the baseplate. The main concepts that were to be tested was the ability of the design to seal the membrane and test the cutting wire. By doing this the baseplate was built overly robust, so that extra time was not needed to do a finite element analysis and the complexity of the design could be simplified so that the machine shop would not have to spend as much time machining a more complex part. The membrane is responsible for holding the aerobrake inside the baseplate under atmospheric pressure until being release by the cutting wire. The membrane must withstand a vacuum pressure of 10^-4 torr without leaks. Testing consisted of an off the shelf gasket being roughly cut into the shape of the baseplate (See Figure 2). Page | 2 (Figure 2) - (Top) Gasket, (Left) Baseplate with screws, (Right) Baseplate cap The membrane is tensioned over the baseplate between the gasket and the baseplate then the cap is placed on top and screwed down tight (see Figure 3). (Figure 3) - Baseplate with membrane, gasket, and cap assembled To test the baseplate a 1 mil Kapton film and a 5 mil Mylar film were used as membranes. The Kapton and Mylar films were put on the baseplate and the gasket was Page | 3 put on top of that. The cap was placed on top of the gasket and membranes and screws were used to screw the cap into the baseplate, compressing the gasket and membrane to create a seal. The baseplate was put into the vacuum chamber and the air was pumped out. The seal held to a small vacuum but leaked out of the spaces between the membrane and baseplate as the vacuum pressure dropped below 500 millitorr. This is evident from negative pressure inside the seal. Several different membrane and gasket materials have been tested without complete sealing success. After doing a failure analysis the result of the leak can be related to the aluminum cap bending where screws are absent. The cutting wire, which melts the membrane releasing the aerobrake, has also been tested with different materials to ensure cutting of the membrane. The wire fits inbetween the membrane material and the gasket to guarantee contact. When powered the wire has been able to melt the membrane; cutting wire vacuum testing has not been completed at this time but is planned. An electrical analysis of the cutting wire was performed to determine the power required to heat the wire above the melting temperature of a given membrane (see Appendix 3). With the completion of the electrical analysis of the wire, a proof of concept was required to demonstrate the capability of the selected Nichrome (NickelChromium) cutting wire to melt through a 5 mil thickness Mylar membrane. This was accomplished by connecting the Nichrome wire to a 6 Volt, 5 Amp/hour alarm battery (Appendix 1 Figure 4). The wire was connected by soldering the ends to copper leads and manually connecting the lead ends to the positive and negative battery terminals. Immediately after connecting the wire to the battery, the wire temperature began to rise and a second team member pressed the Mylar against the wire. As expected, the wire temperature was greater than the melting temperature of the Mylar and the membrane began to melt. A thermal analysis of the system was conducted in parallel so that once the capsule system was functioning testing could begin on the inflatable system. The thermal analysis sought to describe the thermodynamic system inside the inflatable as a numerical model where parameters could be changed and the effects on the overall system could be evaluated. The aerobrake can inflate easily in the vacuum environment as long as the internal pressure after sublimation is above the external vacuum of space. Because the aerobrake causes the CubeSat to descend in elevation, internal pressure must be sufficient to maintain aerobrake shape at lower elevations (see Appendix 4). Pressure as a function of elevation can be found in Appendix 2 Table 1 using data published in the Journal of Geophysical Research [4]. Saturation temperature of benzoic acid as a function of pressure at the selected elevation was found using the Antoine equation (see Appendix 5). These values were then used to find the minimum amount of benzoic acid needed for sublimation to attain desired internal pressure at a selected elevation, through use of the Ideal Gas Law (see Appendix 6). The energy required is based on the enthalpy of sublimation for benzoic acid. A relation for the enthalpy of sublimation based on saturation temperature was derived using microcalorimetry [5] (see Appendix 7). A plot of the relation can be seen in Appendix 1 Figure 5. These values, combined with the mass of benzoic acid required, were used to find the minimum energy required (see Appendix 8). This process was then analyzed over a range of values by varying parameters and analyzing the results. Inflatable volume, desired internal pressure, mass of benzoic acid required, and energy Page | 4 required for sublimation were analyzed over a range of values (see Appendix 1 Figure 6,7). Proposed Methods A redesign of the base plate and cap were conducted and a design that optimizes the sealing of a pressure vessel will be used. The baseplate and cap will be a circular design so the stress on the cap and membrane should be evenly distributed. This design will give the best chance for positive sealing of the pressure vessel. Once the baseplate is machined the tests described above will be conducted again. Different gasket materials will also be used to try and optimize the most effective gasket material for sealing the pressure vessel. When proper sealing methods are achieved the cutting wire will be integrated into the test system and debug any unforeseen issues. Once the sealing method and cutting wire are proven to work and are reliable, a prototype baseplate will be designed to reduce weight while still being able to hold up to pressure differences. A thorough finite element analysis will be conducted with different materials and alloys to optimize the system. Stress and deflection in the membrane will be computed using FEA software PaTran (MSC Software, Newport Beach, CA). Now that proof of concept has been established to physically cut the membrane, it is proposed that this process be completed wirelessly in a vacuum chamber. A remote controlled circuit (Arduino Kit) will be placed within the vacuum chamber along with the battery to remotely activate the cutting wire and demonstrate the capability to cut the membrane without manual operation. This process will first be attempted by installing a membrane to the CubeSat baseplate and laying the Nichrome on top of the membrane. After the vacuum chamber reaches the lowest possible pressure (approximately 150 millitorr), the circuit will be turned on to observe how the membrane behaves after being cut under vacuum pressures. Once wireless capability has been established, it is then necessary to embed the cutting wire within the baseplate and still maintain a vacuum seal. It is proposed to layer high temperature gaskets around the membrane and cutting wire to prevent contact between the aluminum baseplate and the wire. Failure to do so will result in a shorting of the circuit and heat loss from the wire. After integrating the wire within the baseplate, it is required to again remotely activate the circuit and cut the membrane. Completion of this portion of testing will demonstrate the ability to perform integration of multiple subcomponents of the CubeSat DeOrbit System. The tether release has gone through several design iterations since the beginning of the project. Currently a thermal cutting wire wrapped around the base of the balloon (Figure 8) will initiate the separation. Further analytical work of the baseplate structure is needed before further action can occur on the release system. A finalized baseplate design will allow for an efficient placement of the release system to reduce the system weight and complexity. Page | 5 (Figure 8) - Baseplate with deployed inflatable Previous tether release systems included: a two plate system and a double ring design. After an initial design is agreed upon, analysis of the balloon separation can occur. A finite element analysis program will be used to characterize the aerobrakeCubeSat separation. Systems Tool Kit (STK) (Analytical Graphics, Inc., Exton, PA) will also be used to model the CubeSat flight characteristics. Analysis will ensure that the CubeSat separation device will not introduce abnormal flight characteristics such as tumbling due to uneven separation. After the computer based analysis, the separation system will be proven functional in a vacuum environment. After successful completion of the test, the system will be integrated onto the test structure for full scale testing. The inflatable material will be Mylar with either Polypropylene or Polyethylene coated on one side to provide reflectivity or absorptivity depending on the temperature requirements of the benzoic acid. In order to determine the drag due to the balloon the following equation will be used: Drag = Coefficient Drag * (Surface Area) * 0.5 * (Pressure) * (Velocity)^2 (Equation 1) The pressure and estimated velocity, depending on altitude and orbit, will be known. The exact surface area will need to be determined. The surface area will be estimated using the vacuum sealed volume of the balloon and the amount of space allotted for the balloon in the CubeSat capsule. Knowing the surface area, altitude, and pressure, STK will be used to model the CubeSat’s orbit. The thermal analysis now seeks to determine if energy required to sublimate the benzoic acid can be provided by solar radiation or if a heating element is necessary in the design. The inclusion of a heating element is undesired due to the addition of mass and complexity. Project Echo provided a variety of calculations pertaining to the availability of energy from solar radiation and did not require a heating element [2]. STK will be Page | 6 used to model probable orbit paths, in reference to available solar energy. The availability of energy in the simulated orbits will be compared to the Project Echo experimental data to verify accuracy. The availability of energy greatly affects the design of the CubeSat DeOrbit System, not only in reference to the possibility of necessity for a heating element, but also in the volumetric size of the inflatable. The orbit analysis will provide necessary design criteria to ensure the final product meets the requirements to survive an orbit test inflation, which is planned to be done aboard an Orbital Sciences launch from Wallops Flight Facility. Orbit profiles will be created using STK, then emulated during testing at Langley Research Center (LaRC). The vacuum testing facilities at LaRC provide the ability to simulate orbit through use of radiative heat lamps. Calculations of availability of energy to sublimate the Benzoic Acid will be verified by the physical experiments. This will provide a high level of confidence in the calculations, with the ability to modify the calculations for different conditions then re-verify them through additional testing at LaRC. The baseplate, membrane, and cutting wire systems will also undergo final vacuum, thermal, and vibration testing in accordance with NASA’s Launch Services Program Level Poly-Picosatellite Orbital Deployer (PPOD) and CubeSat Requirements Document [6]. Preliminary Results With design of the system underway no numerical results have been found pertaining to design criteria. Membrane and cutting wire testing was conducted for an initial proof of concept. The cutting wire testing proved to be successful in heating the cutting wire and having the ability to cut through the thickest of the membrane samples. Testing is planned to further the analysis on the cutting wire until optimum wire diameter and power consumption are calculated, and will be included in future documents. Membrane and gasket testing was also conducted for an initial proof of concept. The membranes were shown to hold a seal until approximately 500 millitorr. Leaking of the gasket was displayed by negative pressure when the vacuum chamber was returned to atmospheric conditions. The problem was found to be the non-diametral bolt pattern of the baseplate. Fortunately another portion of the CubeSat DeOrbit System design team had produced a baseplate with a diametral bolt pattern which was able to hold seal under much lower vacuum pressure, proving that the direction we are moving will be successful. Future testing will now begin documenting maximum values and parameters for the abilities of the membrane, cutting wire, and inflatable aerobrake. Discussion The CubeSat deorbit system will provide a commercially available part for future CubeSat missions to comply with UN space debris regulation. The system will also incorporate a thermally actuated balloon release mechanism. This mechanism will allow scientific access to lower earth orbits which were previously cost prohibitive. The balloon inflation system will be driven by the sublimation of benzoic acid similarly to project Echo, conducted by NASA in the 1960’s. During preliminary testing several issues came up. The need arose to determine a more efficient sealing method other than what has been proposed. It was determined that the thermal cutting wire must be isolated from the base plate in order for the wire to retain its thermal energy and cut the membrane; this method of thermal isolation will also be used on the balloon release mechanism. Page | 7 The research team consists primarily of undergraduate students. This lack of practical experience results in longer deadlines for tasks. Access to resources at ODU and NASA have helped the team alleviate some of the experience gap. Currently there is a lack of testing equipment at Old Dominion. The vacuum pump used during preliminary testing does not have a pressure gauge on it. This lack of instrumentation affects the ability to conduct accurate tests outside of proof of concept tests. It is anticipated that the team will have access to a proper vacuum facility at NASA Langley to conduct preliminary flight qualification testing in the near future. Future utilization of this technology could result in regular flights to altitudes whose orbits decay in a matter of weeks to hours. The implications of conducting science experiments at these elevations cannot be projected. This viable mitigation option for space debris from CubeSats will be commercially available in the near future as a result of this work. Page | 8 Appendix 1 - Figures (Figure 1) - CAD model of baseplate (Figure 4) - Cutting wire and battery Page | 9 (Figure 5) - Enthalpy of Sublimation of Benzoic Acid vs. Temperature (Figure 6) - Necessary mass of Benzoic Acid vs. Volume of Aerobrake and Pressure inside Aerobrake (with ambient pressure held constant at 0.00136 mmHg) Page | 10 (Figure 7) - Necessary Energy for Sublimation of Benzoic Acid vs. Volume of Aerobrake and Pressure inside Aerobrake (with ambient pressure held constant at 0.00136 mmHg) Page | 11 Appendix 2 - Tables Geometric Altitude Ambient Pressure Ambient Pressure Saturation Temperature (km) (mbar) (mmHg) (˚C) 1.01325E+03 7.60002E+02 249.077 0 2.26320E+02 1.69750E+02 199.896 11.019 5.47470E+01 4.10640E+01 161.815 20.063 8.67980E+00 6.51040E+00 121.417 32.162 1.10900E+00 8.31800E-01 85.1195 47.35 5.89970E-01 4.42520E-01 75.4427 52.429 1.82090E-01 1.36580E-01 58.9162 61.591 1.03760E-02 7.78270E-03 25.2572 79.994 1.64370E-03 1.23290E-03 7.46534 90 3.00700E-04 2.25500E-04 -6.87372 100 7.35270E-05 5.51500E-05 -17.5102 110 2.52090E-05 1.89080E-05 -24.9408 120 (Table 1) - Saturation Temperature as a function of Pressure with respective Elevations (ambient pressures taken from Journal of Geophysical Research [1]) Page | 12 Appendix 3 Electrical Analysis of Cutting Wire ρ0= Electrical resistivity at room temperature (Ω*m) α = Temperature coefficient of resistance (material property) T0 = Room Temperature (0C) T = Desired Temperature (0C) Electrical Resistivity varies with temperature; therefore resistivity as a function of temperature can be expressed as: ρ(T) = ρ0[1- α(T-T0)] Electrical Resistance (R) using Pouillet’s law is expressed as: R= R= L is wire length (m) and A is the cross sectional area of the wire (m2). Finally, the electrical power (W) required to heat a material to a desired temperature can be expressed using Ohm’s Law as: P= I2*R I is current in amperes. By substituting R= (ρ0[1- α(T-T0)]*L)/ A into the above equation, we have: P= The above equation defines the amount of power required to heat a given material to a desired temperature based on predetermined dimensions. Page | 13 Appendix 4 Finding desired Internal Pressure of Inflatable For purpose of this study If will be taken as 0.00136 mmHg: , then to inflate and hold shape. This means that all calculations for required mass of Benzoic Acid and energy input are the absolute minimums. Appendix 5 Finding Saturation Temperature of Benzoic Acid as a Function of Pressure Table 1 was found using the Antoine equation: Log is the logarithm based of 10 P = pressure (mmHg) T= temperature ( ) A, B, C are substance-specific coefficients (constants) A=8.57134 B=2726.2 C= 230 Manipulating equation yields: More simply: Page | 14 Appendix 6 Use of Ideal Gas Law to solve for Mass of Benzoic Acid Required Molar mass of Benzoic Acid: 122.12 g/mol Universal Gas Constant: 8.314462 J/mol K Using the Ideal Gas Law: Sample calculations for various inflatable volumes at ambient pressure of 0.1813 Pa: For 0.1 m^3: For 0.5 m^3: For 1 m^3: Appendix 7 Enthalpy of Sublimation as a function of Temperature Test limitations in document were stated as: "The lower limits of the temperature ranges of the measurements are thus determined by the recorder system sensitivity and the upper limits by the conditions of validity of Knudsen equation." [3] The value of enthalpy of sublimation has thus not been determined by measurement due to equipment restrictions. However, a function of the slope of the enthalpy of sublimation versus temperature was found using least squares treatment of the experimental data that can be used to find accurate values for enthalpy of sublimation at given saturation temperatures. The trend of the enthalpy of sublimation as a function of temperature in Kelvin given in the document [3]: Page | 15 Appendix 8 Finding Required Energy for Sublimation based on mass of Benzoic Acid Using our current saturation temperature at a pressure of 0.1813 Pa, = 281.5 K, and disregarding deviation of the function for now, the enthalpy of sublimation is: Sample calculations: For 0.1 m^3: For 0.5 m^3: For 1 m^3: Page | 16 Appendix 9 - Gantt Chart Page | 17 Appendix 10 - Budget CubeSat DeOrbit Budget Labor Student Labor Materials CubeSat Membranes Cutting wires Raw Aluminum Hardware, Misc. Thermal Gasket Vacuum Supplies Battery and Charger Benzoic Acid Temperature Gages Arduino, Xbee, Misc. Software Pro-E and Patran Facilities NASA Vacuum Chamber On Campus Vacuum Chamber Subcontractors and Consultants Baseplate at Machine Shop 3-D Printing Consultant Nathanael Miller (NASA) $24,000 Calculations $25 per hour x 6 group members x 5 hours per week x 32 weeks=$24,000 $7,500 $100 $50 $160 $25 $100 $25 $300 $30 $100 $200 $6,000 $8,000 $1,000 per hour x 8 hours=$8,000 $1,250 $50 x 25 hours=$1,250 $4,000 $1,200 $100 per hour x 40 hours=$4,000 $100 per hour x 12 hours=$1,200 $1,500 $100 per hour x 15 hours=$1,500 Page | 18 Travel None Contingency 30% of Budget TOTAL BUDGET COST Cumulative Budget Cost (CBC) Cumulative Actual Cost (CAC) Cumulative Earned Value (CEV) Cost Performance Index (CPI) Cost Variance (CV) Forecasted Cost At Completion (FCAC) TCPI (ToComplete Performance Index) $0 $16,362.0 $70,902 0.3*SUM(B4:B30) SUM(B4:B33) $21,920 (Labor + (Materials - CubeSat) + (Subcontractors Consultants 3-D printing) + (Facilities - NASA Vacuum Chamber) + Contingency)/2 + Software (Labor + (Materials - CubeSat) + (Subcontractors Consultants 3-D printing) + (Facilities - NASA Vacuum Chamber))/2 + Software $25,806 0.5*Labor + 0.45*Materials + 0.1*Subcontractors Consultants + Software + 0.41*Facilities $30,101 1.18 $3,886 $60,225 0.92 CPI = CEV/CAC CV=CEV-CAC FCAC=TBC/CPI TCPI=(TBC-CEV)/(TBC-CAC) Discussion of Budget The actual budget for the project is only for the CubeSat structure which is $1725.00. The team was awarded $1350.00 which will be going towards that structure in its entirety. Ways to gap the cost between the CubeSat structure and the amount of money awarded will be sought out in the following semester, although the CubeSat structure is not necessary for testing within our scope. The expensive nature of a total CubeSat system (approximately $7500) means that the current and future teams will be buying the CubeSat system in portions from the manufacturer. The Gantt chart and budget agree that the team is on track with our current goals. Purchase of the CubeSat structure will help provide future teams with an eventual orbital test of the CubeSat DeOrbit System, although it is not immediately necessary for the progression of research. Page | 19 Appendix 11 MATLAB Code Enthalpy of Sublimation of Benzoic Acid vs. Temperature Plot T=linspace(240,360); Hhigh=22058-(4.036*T); Hlow=21958-(4.008*T); Hmid=22008-(4.022*T); hold on plot(T,Hhigh,'r--') plot(T,Hmid) plot(T,Hlow,'r--'),title('Enthalpy of Sublimation of Benzoic Acid vs. Temperature'); xlabel('Temperature (K)'); ylabel('Enthalpy of Sublimation (cal/mol)'); Variation of Parameters Program Vinflatable=needs input; %m^3 Pinflatable=needs input; %in Pa P=needs input; %in mmHg based on elevation R=0.0680844; %J/gK Tsat=((2726.2-(8.57134-log10(P))*230)/(8.57134-log10(P)))+273.15%K mass_benzoic_req=(Pinflatable.*Vinflatable)./(R*Tsat) hig=(22008-(4.022*Tsat)) %cal/mol higunits=(hig/122.12)*4.184 %J/g E_req=mass_benzoic_req*higunits %J Example of Variation of Parameters Program using values from this study Vinflatable=1; %m^3 Pinflatable=0.1813; %in Pa P=0.00136; %in mmHg based on elevation R=0.0680844; %J/gK Tsat=((2726.2-(8.57134-log10(P))*230)/(8.57134-log10(P)))+273.15%K mass_benzoic_req=(Pinflatable*Vinflatable)/(R*Tsat) hig=(22008-(4.022*Tsat)) %cal/mol higunits=(hig/122.12)*4.184 %J/g E_req=mass_benzoic_req*higunits %J Comparison of mass of Benzoic Acid required versus aerobrake volume and desired interior pressure Vinflatable=linspace(0.5,3); %m^3 Pinflatable=linspace(0.1813,15); %in Pa P=0.00136; %in mmHg based on elevation R=0.0680844; %J/gK Tsat=((2726.2-(8.57134-log10(P))*230)/(8.57134-log10(P)))+273.15%K Page | 20 mass_benzoic_req=(Pinflatable.*Vinflatable)./(R*Tsat) hig=(22008-(4.022*Tsat)) %cal/mol higunits=(hig/122.12)*4.184 %J/g E_req=mass_benzoic_req*higunits %J plot3(Pinflatable,Vinflatable,mass_benzoic_req),title('Necessary mass of Benzoic Acid vs. Volume of Aerobrake and Pressure inside Aerobrake'); xlabel('Aerobrake desired interior pressure (Pa)'); ylabel('Volume of Aerobrake (m^3)');zlabel('Mass of Benzoic Acid required (g)') hold on grid on Comparison of Energy required for sublimation of Benzoic Acid versus aerobrake volume and desired interior pressure Vinflatable=linspace(0.5,3); %m^3 Pinflatable=linspace(0.1813,15); %in Pa P=0.00136; %in mmHg based on elevation R=0.0680844; %J/gK Tsat=((2726.2-(8.57134-log10(P))*230)/(8.57134-log10(P)))+273.15%K mass_benzoic_req=(Pinflatable.*Vinflatable)./(R*Tsat) hig=(22008-(4.022*Tsat)) %cal/mol higunits=(hig/122.12)*4.184 %J/g E_req=mass_benzoic_req*higunits %J plot3(Pinflatable,Vinflatable,E_req),title('Necessary energy for sublimation of Benzoic Acid vs. Volume of Aerobrake and Pressure inside Aerobrake'); xlabel('Aerobrake desired interior pressure (Pa)'); ylabel('Volume of Aerobrake (m^3)');zlabel('Energy required for sublimation (J)') hold on grid on Page | 21 References [1] [2] [3] [4] [5] [6] N. A. Vaios Lappas, Lourens Visagie, Juan Fernandez, Theodoros Theodorou, Wellem Steyn, Matthew Perren, "CubeSail: A low cost CubeSat based solar sail demonstration mission," Advances in Space Research, vol. 48, p. 11, June 12 2011. D. L. Clemmons and L. R. Center, The Echo I inflation system: National Aeronautics and Space Administration, 1964. E. Lokcu and R. L. Ash, "A de-orbit system design for CubeSat payloads," in 2011 5th International Conference on Recent Advances in Space Technologies (RAST), 9-11 June 2011, Piscataway, NJ, USA, 2011, pp. 470-4. N. Sissenwine, M. Dubin, and H. Wexler, "The U. S. standard atmosphere, 1962," Journal of Geophysical Research, vol. 67, pp. 3627-3630, 08/ 1962. L. Malaspina, R. Gigli, and G. Bardi, "Microcalorimetric determination of the vol. enthalpy of sublimation of benzoic acid and anthracene," Journal of Chemical Physics,59, pp. 387-94, 07/01 1973. N. A. S. Administration, "Launch Services Program Level Poly-Picosatellite Orbital Deployer(PPOD) and CubeSat Requirements Document," in A, ed. Florida: John F. Kennedy Space Center, 2011. Page | 22