Research Center in Electrochemistry and Non-conventional Materials (CCEMN) Address Research Center in Electrochemistry and Non-conventional Materials Faculty of chemistry and chemical engineering Str. Arany Janos 11, RO-400028 Cluj-Napoca ROMANIA Director: Prof. Ionel Catalin POPESCU Tel. +40-264.59.38.33/ext. 5692 E-mail: cpopescu@chem.ubbcluj.ro Vice-director: Prof. Liana MURESAN Tel. +40-264.59.38.33/ext. 5710 E-mail: limur@chem.ubbcluj.ro Accredited by “Babes-Bolyai” University in 2013 Staff Professor Professor Professor Engineer Assoc. Prof. Assoc. Prof. Engineer Assoc. Prof. Assoc. Prof. Assist. Prof. Engineer Assist. Prof. Assist. Eng. Assist. Eng. Senior Researcher II, PhD Senior Researcher III, PhD Ionel Cătălin POPESCU Liana Maria MUREŞAN Petru ILEA Iuliu Ovidiu MARIAN Graziella TURDEAN Sorin DORNEANU Sanda Andrada MAICANEANU Adrian NICOARĂ Gabriella SZABO Daniela CHELARU Szabolcs FOGARASI Virginia DANCIU Veronica COŞOVEANU cpopescu@chem.ubbcluj.ro limur@chem.ubbcluj.ro pilea@chem.ubbcluj.ro iomar@chem.ubbcluj.ro gturdean@chem.ubbcluj.ro dorneanu@chem.ubbcluj.ro andrada@chem.ubbcluj.ro anicoara@chem.ubbcluj.ro gszabo@chem.ubbcluj.ro julieta_dana@yahoo.com szfogarasi@chem.ubbcluj.ro vdanciu@chem.ubbcluj.ro vcosov@chem.ubbcluj.ro Senior Researcher III, PhD Senior Researcher III, PhD PhD student PhD student PhD student PhD student PhD student PhD student PhD student PhD student PhD student PhD student PhD student Ioana FORT Cosmin COTEŢ Nicoleta COTOLAN Raluca DEAC Roxana BOSTAN Codruta VARODI Ana-Maria SĂCARA Cosmin Gelu CATANAŞ Alina POPESCU Emilia GILCA Andrada DARGOLEA Ana Cristina VLADU Horaţiu MĂRINCAŞ iladiu@chem.ubbcluj.ro cotetcosmin@yahoo.com ncotolan@chem.ubbcluj.ro deac_raluca89@yahoo.com anamariasacara@yahoo.ro popescualina@chem.ubbcluj.ro gemilia@chem.ubbcluj.ro andrada.dragolea@yahoo.ro Ana.VLADU@ubbonline.ubbcluj.ro hmarincas@chem.ubbcluj.ro Research Topics: a) Electrode materials for electrochemical sensors /biosensors (prof. C. Popescu, prof. L. Muresan, assoc. prof. G. Turdean) Obtaining and characterization of non-conventional electrode materials, exhibiting electrocatalytic activity and selective recognition properties, for sensors or biosensors construction Electrochemical nanostructures prepared by self-assembling (on Au), electropolymerization (on carbonaceous materials) and adsorption (on conventional electrode materials) b) Non-conventional materials with (photo)catalytic properties (CS I V. Danciu, dr. C. Cotet. Dr. I. Fort) Composite materials based on polymeric matrices containing zeolites, carbon or TiO2 aerogels, graphenes, noble metal particles and redox mediators Electroactive biocomposites incorporating enzymes, cofactors and mediators c) Materials electrodeposition (theoretical and practical aspects) (prof. L. Muresan, assist. prof. A. Nicoara) Investigation of the electrodeposition mechanism of metals and composites using modern electrochemical techniques (electrochemical impedance spectroscopy, cronoamperometry, hydrodynamic voltammetry etc.) Theoretical and practical aspects of electrowinning, electrorefining and electroplating of metals d) Corrosion and anticorrosive protection (prof. L. Muresan, assist. D. Chelaru, assist prof. G. Szabo) New corrosion inhibitors Smart corrosion resistant coatings Corrosion investigation by electrochemical methods (Polarization measurements, electrochemical impedance spectroscopy etc.) e) Metals electrowinning and electrorefining (Cu, Mn, Zn, Ni, Ag, Au etc.) (prof. P.Ilea) f) Waste electric an electronic equipments (WEEE) recycling (prof. P.Ilea) g) Electrosyntesis (prof. P.Ilea) h) Waste water treatment (prof. P.Ilea, assoc. prof. S. Dorneanu) i) Design and elaboration of computer controlled electronic equipments for the investigation and control of the electrochemical processes (assoc. prof. S. Dorneanu) j) Elaboration of software applications for the acquisition and treatment of experimental and process data (assoc. prof. S. Dorneanu) k) CFD modelling of chemical and electrochemical reactors (assoc. prof. S. Dorneanu, assist Szabolcs Fogarasi) Scientific collaborations LEOPR, University “Joseph Fourier” Grenoble, France LISE, University Pierre et Marie Curie, Paris, France Dept. of Analytical Chemistry, University of Lund, Sweden Dept. of Chemistry, Clarkson University, New York, USA Dept. of Analytical Chemistry, University Alcala de Henares, Spain University Tor Vergata, Rome, Italy Université Franche-Comté de Besançon, France University of Zagreb, Croatia Josef Stefan Institute Ljubljana, Slovenia University of Pannonia, Veszprem, Hungary Technische Universität Ilmenau, Gemany University of L’Aquila, Italy University of Technology and Economics, Faculty of Chemical Technology and Biotechnology, Budapest Universita degli Studi di Udine, Dipartimento di Chimica, Fisica e Ambiente, Italy Most representative ISI publications (2013 - 2014) E. Albert, N. Cotolan, N. Nagy, G. Sáfrán, G. Szabó, L.M. Mureşan, Z. Hórvölgyi, Mesoporous silica coatings with improved corrosion protection properties, Microporous & Mesoporous materials, 2015, 206, 102-113. I. Rotaru, S. Varvara, L. Gaina, L.M. Muresan, Antibacterial drugs as corrosion inhibitors for bronze surfaces in acidic solutions, Applied Surface Science, 2014, 32, 188–196 P. I. Nemes, M. Lekka, L. Fedrizzi, L. M. Muresan, Influence of the electrodeposition current regime on the corrosion resistance of Zn–CeO2 nanocomposite coatings, Surface & Coat. Technol. 2014, 252, 102-107. S. Varvara, R. Bostan, L. Găină, L. M. Muresan, Thiadiazole derivatives as inhibitors for acidic media corrosion of artificially patinated bronze, Materials and Corrosion, 2014, 12, 1202-1214. J. D. Chelaru, L. M. Mureşan, V. F. Soporan, O. Nemeş, L. Barbu-Tudoran, Investigation of a naturally patinated bronze artifact originating from the outdoor statuary group of Mathias Rex, J. Cult. Her., 2014, 15, 546–549 D. Blejan, L. M. Muresan, Corrosion behavior of Zn-Ni-Al2O3 nanocomposite coatings obtained by electrodeposition from alkaline electrolytes, Materials & Corrosion, 2013, 64(5), 433–438 P.I. Nemes, M. Zaharescu, L.M. Muresan, Initial corrosion behavior of composite coatings obtained by electrolytic codeposition of zinc with nanoparticles of Ti and.Ce oxides, J. Solid State Electrochem, 2013, 17, (2) (2013), 511-518 Adriana Vulcu, Camelia Grosan, Liana Maria Muresan, Stela Pruneanu, Liliana Olenic, Modified gold electrodes based on thiocytosine/guanine-gold nanoparticles for uric and ascorbic acid determination, Electrochim. Acta, 2013, 88 (2013) 839– 846 Sorin Dorneanu, Liana Maria Muresan, Ossi Horovitz and Ionel Catalin Popescu, Electrochemical and spectroelectrochemical behavior of n-methyl-phenothiazinyl meso-substituted porphyrins and their complexes with Ni(II), Cu(II) and Pd(II), J. Electroanal. Chem, 2013, 698, 17–24 Ingrid Milosev, Diana Blejan, Simona Varvara, Liana Maria Muresan, Effect of anodic oxidation on the corrosion behavior of Ti-based materials in simulated physiological solution, J. Appl. Electrochem. 2013, 43, 645-658. Simona Varvara, Roxana Bostan, Luiza Găină, Liana Maria Muresan, Thiadiazole derivatives as inhibitors for acidic media corrosion of artificially patinated bronze, Materials and Corrosion, 2013, 64, No. 9999. DOI: 10.1002/maco.201307072. Emőke Volentiru, Mária Nyári, Gabriella Szabó, Zoltán Hórvölgyi, Liana Maria Mureşan, Silica Sol – gel protective coatings against corrosion of zinc substrates, Periodica Polytechnica Chemical Engineering, 2014, 58, 61-66 Graziella L Turdean, Ionel Catalin Popescu, Self-assembled architecture based on triironsubstituted polyoxomolybdate anion and positively charged polymer, Journal of Solid State Electrochemistry, 2012, 16, 681–687, DOI 10.1007/s10008-011-1385-9. Carmen Ioana Fort, Liviu Cosmin Cotet, Virginia Danciu, Graziella Liana Turdean, Ionel Catalin Popescu, Fe Doped Carbon Aerogel - New Electrode Material for Electrocatalytic Reduction of H2O2, Materials Chemistry and Physics, 2013, 138(2-3), 893898 Dan Rusu, Adrian R. Tomsa, Graziella L. Turdean, Ileana Cojocaru, Mariana Rusu, Synthesis and characterization of the copper (II)-substituted polyoxotungstate based on α-B-[BiW9O33]9units, Revue Roumaine de Chimie, 2013, 57 (4-5) , pp. 327-336 Graziella L. Turdean, Amperometric detection of glucose by electrocatalytic reduction at a copper – modified electrode, Revue Roumaine de Chimie, 2013, 589(9-10), 729-735 Graziella L. Turdean, Gabriella Szabo, Nitrite detection in meat products samples by square-wave voltammetry at a new single walled carbon naonotubes - myoglobin modified electrode, Food Chemistry, 2014, 179, 235-330 A. Killyeni, A. Nicoara, V. Canpean, A. Kun, S. Astilean, I. C. Popescu, S-acetylcalix[8]arene adsorption on polycrystalline Au surface: A kinetic study, Electrochim. Acta, 2013, 102, 225-232. Szabolcs Fogarasi, Florica Imre-Lucaci, Arpad Imre-Lucaci, Petru Ilea, Copper recovery and gold enrichment from waste printed circuit boards by mediated electrochemical oxidation, Journal of Hazardous Materials 273 (2014) 215–221 Eva Fischer-Fodor, Ana-Maria Vălean, Piroska Virag, Petru Ilea, Corina Tatomir, Florica Imre-Lucaci, Maria Perde Schrepler, Ludovic Tibor Krausz, Lucian Barbu Tudoran, Calin George Precup, Iulia Lupan, Evamarie Hey-Hawkins, Luminita SilaghiDumitrescu, Gallium phosphinoarylbisthiolato complexes counteract drug resistance of cancer cells, Metallomics, 2014, 6, 833-844 Emilia Gîlcă, Andrada Măicăneanu, Petru Ilea, Removal of zinc ions as zinc chloride complexes from strongly acidic aqueous solutions by ionic exchange, + Cent. Eur. J. Chem. 12(8) 2014 821-828 Fogarasi, S., Imre-Lucaci, F., Ilea, P., Imre-Lucaci, A., The environmental assessment of two new copper recovery processes from Waste Printed Circuit Boards, Journal of Cleaner Production 54, 264-269, 2013 Coman, V., Robotin, B. and Ilea, P., Nickel recovery/removal from industrial wastes: A review. Resources, Conservation and Recycling, 73, 229-238, 2013 B. Robotin, A. Ispas, V. Coman, A. Bund, P. Ilea, Nickel recovery from electronic waste II Electrodeposition of Ni and Ni–Fe alloys from diluted sulfate solutions, Waste Management 33 (2013) 2381–2389 F. A. Hanc-Scherer, P. Ilea, Electrochemical Reduction of CO2 on lead Electrode. I. Cyclic Voltammetry and Long Time Electrosynthesis Studies. Studia Universitatis Babes-Bolyai, Studia Universitatis Babeş Bolyai, LVIII, 3, 75, 2013 R. Rácz, P. Ilea, Electrolytic recovery ofMn3O4 and Zn fromsulphuric acid leach liquors of spent zinc–carbon–MnO2 battery powder, Hydrometallurgy 139 (2013) 116– 123 P. Macolino, A. L. Manciulea, I. De Michelis, M. S. Anton, P. Ilea, F. Veglio, Manganese recovering from alkaline spent batteries by ammonium peroxodisulfate, Acta Metallurgica Slovaca, Vol. 19, 2013, No. 3, p. 212-222 F. A. Hanc-Scherer, C. M. Sánchez-Sánchez, P. Ilea, E. Herrero, Surface-Sensitive Electrooxidation of Carbon Monoxide in Room Temperature Ionic Liquids, ACS Catalysis, 2013, 3, 2935−2938. Research equipment 1. Computer controlled potentiostats (PGStat 10, PGStat 12 Echochemie, The Netherlands; PARStat 2273, Princeton Applied Research-USA; VSP, BioLogic, France, VoltaLab 10, Radiometer Analytical, France) with impedance spectroscopy setup option. 1. Computer controlled flow injection setup (FIALab 2500, USA) 2. Rotating disk electrode and rotating ring disk electrode (Radiometer Analytical, Denmark, 10000 rpm) 3. Computer electrochemical microbalance controlled quartz (Radiometer Analytical, France) 4. Electrochemical reactor with planparallel electrodes 5. Supercritical point dryer SAMDRIPVT-3D (TOUSIMIS, USA) 6. UV photodegradation installation