MICROSOC ________ ITEM BANK CONTENT CLASSIFICATION SYSTEM GENERAL CHEMISTRY TEST ITEM BANK #11150 ADAPTED FROM THE SOCRATES GENERAL CHEMISTRY CONTENT CLASSIFICATION SYSTEM OF SEPTEMBER, 1980 BY OLIVER SEELY, JR. CSU, DOMINGUEZ HILLS AND W. VAN WILLIS, CSU, FULLERTON MICROCOMPUTER VERSION MARCH, 1987 MAJOR SOCRATES CATEGORIES FOR CHEMISTRY ITEM BANK CATEGORY NUMBER _______________ TOPIC _____ 00000 _ 09999 RESERVED FOR 2_, AND 3_OPTION ITEMS 10000 _ 19999 INTRODUCTORY CHEMISTRY 20000 _ 29999 ATOMIC THEORY AND STRUCTURE 30000 _ 39999 CHEMICAL PERIODICITY 40000 _ 49999 STOICHIOMETRY AND THE MOLE CONCEPT 50000 _ 59999 CHEMICAL KINETICS AND CHEMICAL EQUILIBRIUM 60000 _ 69999 SOLUTION CHEMISTRY 70000 _ 79999 CHEMICAL BONDING 80000 _ 89999 CHEMICAL THERMODYNAMICS 90000 _ 99999 TOPICS IN CHEMISTRY CHEMISTRY SUBJECT AREA INVENTORY SOURCE CODES 0001 ORIGINAL KEYWORD LIST FROM SEELY AND WILLIS 0002 SORUM, HOW TO SOLVE GENERAL CHEMISTRY PROBLEMS, FOURTH ED 0003 SIENKO & PLANE, CHEMICAL PRINCIPLES AND PROPERTIES, SECOND EDITION 0004 SCHAUM AND ROSENBURG, THEORY AND PROBLEMS OF COLLEGE CHEMISTRY 0005 HARDWICK & KNOBLER, CHEMISTRY, MAN & MATTER 0006 MORTIMER, CHEMISTRY, A CONCEPTUAL APPROACH, SECOND EDITION 0007 BECKER & WENTWORTH, GENERAL CHEMISTRY 0008 CHERIM, PRELIMINARY COLLEGE CHEMISTRY 0009 MASTERTON & SLOWINKSI, CHEMICAL PRINCIPLES, THIRD EDITION 0010 HILL, CHEMISTRY FOR CHANGING TIMES 0011 WILLIAMS, EMBREC, DEBEY, INTRODUCTION TO CHEMISTRY, SECOND EDITION 0012 HEIN, FOUNDATIONS OF COLLEGE CHEMISTRY, THIRD EDITION 0013 ELBIN, THE ELEMENTS OF CHEMISTRY 0014 KUMLI, K. F., INTRODUCTORY CHEMISTRY 0015 DRAGO, R. S., PRINCIPLES OF CHEMISTRY 0016 FINE, L. W. CHEMISTRY 0017 LOEBEL, A. B., CHEMICAL PROBLEM SOLVING BY DIMENSIONAL ANALYSIS 0018 HANKINS & HANKINS, INTRODUCTORY CHEMISTRY 0019 OUELETTE, INTRODUCTORY CHEMISTRY 0020 MULER, PRINCIPLES OF COLLEGE CHEMISTRY 0021 MAHAN, COLLEGE CHEMISTRY 0022 CHICKOS, GARIN, & ROUSE, CHEMISTRY: ITS ROLE IN SOCIETY 0023 NEBERGALL, SCHMIDT, HOLTZCLAW, GENERAL CHEMISTRY, THIRD EDITION 0024 BRESCIA, MEHLMAN, PELLEGRINI, STAMBLER, CHEMISTRY: A MODERN INTRODUCTION 0025 GRISWALD, WALKER, GENERAL CHEMISTRY 0026 JONES, NETTERVILLE, JOHNS, WOOD, CHEMISTRY, MAN AND SOCIETY 0027 HEALEY, CHEMISTRY, MAN AND ENVIRONMENTAL CHANGE 0028 SEESE & DAUB, BASIC CHEMISTRY 0029 DICKERSON, GRAY & HAIGHT, CHEMICAL PRINCIPLES SECOND EDITION 0030 JONES, NETTERVILLE, JOHNSTON, & WOOD, CHEMISTRY: A BRIEF INTRODUCTION, 1969, W. B. SAUNDERS COMPANY 0031 GORDON M. BARROW, GENERAL CHEMISTRY, WADSWORTH 0032 SIDNEY W. BENSON, CHEMICAL CALCULATIONS, JOHN WILEY 0033 ROD O'CONNOR, FUNDAMENTALS OF CHEMISTRY: A LEARNING SYSTEMS APPROACH, HARPER, 1972 0034 MODERN CHEMICAL SCIENCE, (ANSWER MANUAL AND TEST BOOKLET) FERNANDEZ, J. 0035 ITEMS FROM BOB HENDERSON 0036 FOUNDATIONS OF COLLEGE CHEMISTRY, 3RD EDITION, HEIN STUDY GUIDE 0037 FOUNDATIONS OF COLLEGE CHEMISTRY, 3RD EDITION, HEIN, STUDY GUIDE 0038 GENERAL CHEMISTRY, SECRIST, POWERS, TEACHER'S MANUAL 0039 STUDY GUIDE, NORMAN E. GRISWALD 0040 CHEMISTRY: A SCIENCE FOR TODAY, SEAGER, INSTRUCTOR'S MANUAL 0041 FUNDAMENTALS OF PHYSICAL SCIENCE, 6TH EDITION, BEISER, STUDY GUIDE 0042 ITEMS FROM VAN WILLIS 0043 STUDY GUIDE TO ACCOMPANY, SIENKO & PLANE, 2ND EDITION, JOHN B. RUSSELL 0044 PITTS COMPUTER GENERATED REPEATABLE CHEMISTRY EXAM 0045 ITEMS FROM OLIVER SEELY, JR. 0046 TESTS FOR FOUNDATIONS OF CHEMISTRY BY HENDRICKSON, C. W. & JUDGE, J. A. 0047 ACS HIGH SCHOOL TESTS_EXAMS, PETER BAINES, CSU, LONG BEACH 0048 INSTRUCTOR7S MANUAL FOR GENERAL CHEMISTRY INTERACTION OF MATTER, ENERGY & MAN, F. R. LONGO 0049 ITEMS FROM VAN WILLIS 0050 TEST QUESTIONS FROM EL CAMINO JUNIOR COLLEGE 0051 0052 0053 TEST PAPERS, NEW JERSEY CHEMICAL LEAGUE 0054 DAVID FRANK, CSU FRESNO 0055 CHEMISTRY VOL. 48, SEPT. 1975 0056 CHEMISTRY, VOL. 48, OCTOBER, 1975 0057 CHEMISTRY VOL. 49, 1 JAN_FEB, 1976 0058 CHEMISTRY, VOL. 49, 3, APRIL, 1976 0059 CHEMISTRY, VOL. 499, 4, MAY, 1976 0060 CHEMISTRY, VOL. 49, 5, JUNE, 1976 0061 CHEMISTRY, VOL. 49, 6, JULY_AUGUST, 1976 0062 CHEMISTRY, VOL. 48, 11, DECEMBER, 1975 0063 STUDENT'S GUIDE TO FUNDAMENTALS OF CHEMISTRY, 3RD ED., (BRESCIA, ET. AL.), BY DONALD BRACKEN SPECIAL CHARACTERISTIC CODES FOR CHEMISTRY ITEM BANK 05 TRADITIONAL 4 OR 5 OPTION MULTIPLE CHOICE. THIS IS NOT BEING USED AT THIS TIME BUT WAS EMPLOYED FOR MANY EARLY EMU AND COMBAT ITEMS. 04 2_OPTION ITEM. ETS ITEMS ONLY 06 3_OPTION ITEM. ETS ITEMS ONLY 08 4_OPTION ITEM. ETS ITEMS ONLY 09 TRUE/FALSE QUESTIONS 11_16 BLOOM'S TAXONOMY, CATEGORIES 1_6, RESPECTIVELY. ONLY THE ITEMS DONATED BY ETS ARE CODED THIS WAY. 20 MATCHING QUESTIONS 21 FILL IN THE BLANK QUESTIONS 22 MORE THAN 5_OPTION MULTIPLE CHOICE QUESTIONS 23 ESSAY OR NON_MACHINE GRADABLE PROBLEM TYPE QUESTIONS 24 DEFINITIONS 30 DERIVATIONS 30 ERRONEOUS CODE 31 ERRONEOUS CODE 40 EQUIVALENT QUESTIONS 51 COMPREHENSIVE EXAMINATION 52 ERRONEOUS CODE 90 MACRO ITEM 95 ENHANCED ITEM 01_40 CHAPTERS 1_40. (TO BE USED ONLY IN CONJUNCTION WITH A TEXTBOOK KEYWORD.) EXTRA KEYWORD NUMBERS 8001 VAN WILLIS, CSU FULLERTON 8002 OLIVER SEELY, CSC, DOMINGUEZ HILLS 8003 BOB BERNSTEIN, SAN JOSE STATE U. 8004 DAVID FRANK, CSU, FRESNO 8005 BEA PAIGE, ANTELOPE VALLEY COLLEGE 8006 JOE CASANOVA, CSU, LOS ANGELES 8007 PROF SPITZE, SAN JOSE STATE U. 8008 PROF. PYE, CAL_POLY POMONA 9001_9999 RESERVED FOR FIGURE NUMBERS (9001=FIG. 1,ETC.) TRUE_FALSE AND 3_OPTIONS ITEMS CATEGORY DESCRIPTION 01000 I. INTRODUCTORY CHEMISTRY 01100 A. DIAGNOSTIC TESTS 01110 1. CHEMISTRY CONCEPTS 01120 2. SCIENCE AND MATHEMATICS CONCEPTS 01121 (A) SCIENTIFIC NOTATION AND EXPONENTIAL NOTATION 01122 (B) SIGNIFICANT FIGURES 01123 (C) DIMENSIONAL ANALYSIS 01124 (D) METRIC SYSTEM 01125 (E) GRAPHING 01126 (F) LOGARITHMS 01200 B. HISTORICAL CONCEPTS IN CHEMISTRY 01300 C. NOMENCLATURE 01600 D. SCIENTIFIC METHOD 01700 E. PHYSICAL MEASUREMENTS 01720 1. METRIC SYSTEM 01730 (A) CONVERSION OF UNITS 01731 (B) SI UNITS 01740 2. TEMPERATURE 01760 3. HEAT 01770 4. LIGHT 01780 5. DENSITY OF SOLIDS AND LIQUIDS 01900 F. PROPERTIES OF MATTER 01920 1. STATES OF MATTER 01922 (A) GASES 01924 (B) LIQUIDS 01926 (C) SOLIDS 01930 2. SUBSTANCES AND MIXTURES 01932 (A) MIXTURES 01934 (B) ELEMENTS 01936 (C) COMPOUNDS 01950 3. PHYSICAL AND CHEMICAL CHANGES 01952 (A) DEFINITIONS AND EXAMPLES 01954 (B) EXPLANATORY ATOMIC THEORY 01960 4. CHEMICAL LAWS 01962 (A) CONSERVATION OF MASS AND ENERGY 01964 (B) DEFINITE AND MULTIPLE PROPORTIONS 01980 5. THE ELECTRICAL NATURE OF MATTER 02000 II. ATOMIC THEORY AND STRUCTURE 02100 A. ATOMIC PARTICLES; THE NUCLEUS 02111 1. ELECTRON 02111 (A) PHOTOELECTRIC EFFECT 02130 2. PROTON 02150 3. NEUTRON 02200 B. ATOMIC THEORY OF MATTER 02210 C. THE BOHR ATOM 02300 D. ATOMIC WEIGHTS 02310 1. ISOTOPES 02330 2. NATURAL ABUNDANCE 02500 E. AUFBAU PRINCIPLE; ATOMIC NUMBERS 02510 1. ELECTRON CONFIGURATIONS 02530 2. ENERGY LEVELS(ATOMIC) 02531 (A) SPECTRA 02700 F. WAVE MECHANICS; QUANTUM THEORY 02710 1. WAVE/PARTICLE DUALITY 02730 2. HEISENBERG PRINCIPLE 02750 3. ORBITS AND ORBITALS 02770 4. QUANTUM NUMBERS 02780 5. SCHRODINGER EQUATION 02790 6. PAULI EXCLUSION PRINCIPLE 02900 G.NUCLEAR CHEMISTRY 02910 1. RADIOACTIVITY AND RADIOACTIVE DECAY 02930 2. NUCLEAR STABILITY; MASS DEFECT; THEORY OF THE NUCLEUS 02950 3. NUCLEAR REACTIONS 02970 4. COSMIC PROCESSES 02990 5. MASS_ENERGY RELATIONSHIPS 03000 III. CHEMICAL PERIODICITY 03100 A. DEFINITIONS 03110 1. HISTORY AND PURPOSE OF THE PERIODIC TABLE 03120 2. TABLE STRUCTURE 03121 (A) SERIES 03122 (B) GROUPS 03123 (C) METALS 03124 (D) NON_METALS 03200 B. IDENTIFICATION RELATIONSHIPS 03210 03220 03221 03222 03223 03230 03231 03232 03233 03234 03235 03236 03238 03240 1. PROPERTIES RELATED TO ELECTRONIC CONFIGURAGION 2. PROPERTIES RELATED TO LOCATION WITHIN PERIOD (A) SEMI_METALLIC (METALLOID) (B) METALLIC EXCLUSIVELY (C) NON_METALLIC EXCLUSIVELY 3. PROPERTIES RELATED TO GROUP MEMBERSHHIP (A) ACTIVE METALS (B) NON_METALS (C) TRANSITION METALS (D) AMPHOTERIC ELEMENTS (E) LANTHANIDES (F) TRANSURANIC ELEMENTS (G) INERT GASES 4. IDENTIFICATION OF GROUPS BY ELECTRONIC CONFIGURATION 03250 5. IDENTIFICATION OF ELEMENTS BY VALENCE AND ATOMIC NUMBER 03300 C. PERIODIC TRENDS 03310 1. ELECTRONEGATIVITY 03320 2. IONIZATION ENERGY 03330 3. ELECTRON AFFINITY 03340 4. ATOMIC RADII 03350 5. PHYSICAL PROPERTIES 03360 6. COORDINATION NUMBER 03370 7. OXIDATION STATE 03380 8. BOND TYPE 03390 9. REACTIVITY 04000 IV. STOICHIOMETRY AND THE MOLE CONCEPT 04100 A. CHEMICAL FORMULAS AND EQUATIONS 04120 1. CHEMICAL SYMBOLS 04140 2. CHEMICAL FORMULAS 04141 (A) RADICALS 04143 (B) COMPLEX SPECIES 04160 3. WRITING AND BALANCING CHEMICAL EQUATIONS 04162 (A) PREDICTING PRODUCTS 04164 (B) CALCULATIONS FROM CHEMICAL EQUATIONS 04200 B. THE MOLE CONCEPT 04220 1. AVOGADRO'S NUMBER 04240 2. CALCULATIONS YIELDING NUMBERS OF ATOMS OR NUMBERS OF MOLECULES 04260 3. ATOMIC WEIGHT SCALE 04280 4. FORMULA WEIGHTS AND MOLECULAR WEIGHTS 04282 (A) GRAM MOLECULAR WEIGHTS 04284 (B) EQUIVALENT WEIGHTS 04300 C. STOICHIOMETRY 04320 1. DETERMINATION OF WEIGHT PERCENT 04340 04342 04344 04360 04370 04390 2. DETERMINATION OF FORMULAS (A) SIMPLEST FORMULAS (B) MOLECULAR FORMULAS 3. CALCULATIONS YIELDING WEIGHTS OR VOLUMES 4. CALCULATIONS YIELDING MOLES 5. CALCULATIONS YIELDING ATOMIC AND MOLECULAR WEIGHTS 04400 D. REDOX PHENOMENA 04410 1. DEFINITIONS 04420 2. COMBUSTION 04430 3. ELECTROMOTIVE SERIES 04440 4. APPLICATIONS OF THE PERIODIC TABLE 04441 (A) ELECTRON SHELLS 04442 (B) DETERMINATION OF OXIDATION NUMBERS 04443 (C) CHEMICAL ACTIVITY 04450 5. BALANCING EQUATIONS 04470 6. APPLIED CHEMISTRY 04471 (A) METALLURGY 04472 (B) PHOTOGRAPHY 04473 (C) OXIDATION PROCESSES OF ACIDS 04474 (D) ELECTROLYSIS 04475 (E) ELECTROCHEMICAL CELLS 04476 (F) WATER PURIFICATION 05000 V. CHEMICAL KINETICS AND CHEMICAL EQUILIBRIUM 05100 A. KINETICS 05110 1. COLLISION THEORY 05130 2. TRANSITION STATE THEORY 05150 3. MECHANISMS 05170 4. REACTION ORDER AND MOLECULARITY; RATE CONSTANTS 05190 5. FACTORS INFLUENCING REACTION RATE 05191 (A) CONCENTRATION 05193 (B) TEMPERATURE; ARRHENIUS' EQUATION, CALCULATING ACTIVATION ENERGY 05195 (C) CATALYSTS 05197 (D) NATURE OF REACTANTS 05300 B. HOMOGENEOUS EQUILIBRIA 05310 1. GASEOUS EQUILIBRIA 05311 (A) LE CHATELIER'S PRINCIPLE 05313 (B) NATURE OF DYNAMIC EQUILIBRIA 05315 (C) EQUILIBRIUM CONCENTRATIONS ( K , K , K ) P C X 05317 (D) EQUILIBRIUM CONCENTRATIONS IN TERMS OF INITIAL CONCENTRATIONS 05330 2. SOLUTION EQUILIBRIA 05331 (A) ORDINARY SOLUTION EQUILIBRIA 05333 (B) DISTRIBUTION(PARTITION) COEFFICIENTS 05335 (C) COMMON ION EFFECT 05337 (D) IONIZATION CONSTANTS AND WEAK ELECTROLYTES 05339 (E) COMPLEX EQUILIBRIA 05350 3. ACID_BASE EQUILIBRIA 05351 (A) PH: STRONG ACID AND BASES 05353 (B) PH: WEAK ACIDS AND BASES 05355 (C) POLYPROTIC ACIDS 05357 (D) BUFFER SOLUTIONS 05359 (E) HYDROLYSIS 05370 4. REDOX EQUILIBRIA 05500 C. HETEROGENEOUS EQUILIBRIA 05510 1. SOLUBILITY AND K SP 05530 2. MIXING AND PRECIPITATION; COMMON ION EFFECT 05550 3. PHASE EQUILIBRIA 06000 VI. SOLUTION CHEMISTRY 06100 A. CONCENTRATION RELATIONSHIPS 06110 1. UNITS 06120 2. TITRIMETRY 06130 3. PH AND POH 06200 B. ACIDS, BASES AND SALTS 06210 1. GENERAL PROPERTIES 06211 (A) DEFINITIONS 06212 (B) ACIDS AND SALTS 06213 (C) BASES AND SALTS 06214 (D) ACIDS AND BASES 06215 (E) SALTS 06220 2. NEUTRALIZATION 06221 (A) INDICATORS 06223 (B) TITRATIONS; EQUIVALENCE POINT 06230 3. COMMON ACIDS AND BASES 06231 (A) MANUFACTURE 06232 (B) APPLICATIONS 06240 4. LEWIS ACIDS AND BASES 06300 C. SOLUTE_SOLVENT INTERACTION 06310 1. DIPOLES IN SOLUTIONS 06320 2. ATTRACTIVE FORCES IN SOLUTION 06330 3. COMMON ION EFFECT 06340 4. SOLUBILITY; HEATS OF SOLUTIONS 06350 5. DISSOCIATION 06360 6. DIVERSE ION EFFECTS 06400 D. COLLIGATIVE PROPERTIES 06410 1. BOILING POINT ELEVATION 06420 2. FREEZING POINT LOWERING 06430 3. OSMOTIC PRESSURE 06440 4. VAPOR PRESSURE LOWERING 06600 E. COLLOIDAL SUSPENSIONS 07000 VII. BONDING 07100 A. COVALENT BONDING 07110 1. QUANTUM MECHANICS 07111 (A) WAVE FUNCTIONS AND ATTRACTIVE FORCES 07113 (B) MOLECULAR ORBITALS 07120 2. VALENCE BOND THEORY 07121 (A) LEWIS DOT STRUCTURES; FORMAL CHARGES 07123 (B) MULTIPLE BONDS 07125 (C) RESONANCE 07127 (D) HYBRIDIZATION 07128 (E) ELECTRONEGATIVITY 07130 3. MOLECULAR ORBITAL THEORY 07131 (A) BONDING/ANTIBONDING/NONBONDING ORBITALS 07133 (B) ELECTRON DELOCALIZATION; MULTI_CENTERED BONDING 07135 (C) BOND ORDER; ODD ELECTRON BONDS 07137 (D) MOLECULAR ORBITAL ENERGY CORRELATION DIAGRAMS 07140 4. MOLECULAR ARCHITECTURE; PREDICTING MOLECULAR SHAPES 07141 (A) VALENCE SHELL ELECTRON PAIR REPULSION THEORY 07143 (B) MOLECULAR ORBITAL THEORY INTERPRETATIONS 07145 (C) VALENCE BOND INTERPRETATIONS 07147 (D) MOLECULAR SHAPES AND EXPERIMENTAL DATA 07148 (E) SYMMETRY 07150 5. BOND PROPERTIES 07151 (A) SPECTROSCOPIC 07153 (B) BOND ENERGIES AND REACTIVITY 07155 (C) DIPOLE MOMENT 07157 (D) PARAMAGNETISM 07158 (E) BOND LENGTHS 07160 6. TRANSITION METAL COMPLEXES 07161 (A) STRUCTURE AND ISOMERIZATION 07162 (B) LIGANDS 07163 (C) CRYSTAL FIELD THEORY 07164 (D) VALENCE BOND AND MOLECULAR ORBITAL THEORY 07165 (E) PHYSICAL PROPERTIES 07200 B. IONIC BONDING 07210 1. BONDING FORCES 07220 2. BRAGG'S LAW 07230 3. LATTICE GEOMETRY 07250 4. LATTICE ENERGY 07270 5. DULONG_PETIT LAW 07280 6. PROPERTIES OF ELECTROVALENT COMPOUNDS 07300 C. METALLIC BONDING 07310 1. METALLIC PROPERTIES (CHEMICAL AND PHYSICAL) 07330 2. BAND THEORY (SEMICONDUCTORS) 07400 D. VAN DER WAAL'S BONDING 07410 1. BONDING FORCES 07430 2. HYDROGEN BONDING 07500 E. STRUCTURE AND REACTIVITY 08000 VIII. CHEMICAL THERMODYNAMICS 08100 A. THERMODYNAMICS 08110 1. HEAT; WORK; TEMPERATURE (1ST LAW) 08111 (A) MECHANICAL 08113 (B) CHEMICAL 08115 (C) ELECTRICAL 08130 2. ENTHALPY 08131 (A) PHASE CHANGES 08132 (B) CALORIMETRY 08133 (C) HESS' LAW OF HEAT SUMMATION (INCLUDES BOND ENERGIES) 08134 (D) HEAT CAPACITIES (INCLUDES PHASE CHANGES, 3RD LAW) 08135 (E) HEATS OF CHEMICAL REACTIONS (INCLUDES COMBUSTION) 08136 (F) TEMPERATURE EFFECTS ON ENTHALPY 08137 (G) CALCULATIONS INVOLVING GASES 08150 3. GIBBS FREE ENERGY 08151 (A) SPONTANEITY AND REVERSIBILITY 08153 (B) FREE ENERGY AND EQUILIBRIUM 08155 (C) CLAUSIUS_CLAPEYRON EQUATION 08157 (D) NON_STANDARD STATE REACTIONS 08170 4. ENTROPY (2ND LAW) 08200 B. ELECTROCHEMISTRY 08210 1. CELL REACTIONS AND NOMENCLATURE 08220 2. ELECTROLYSIS AND FARADAY'S LAWS 08230 3. CELL POTENTIALS 08231 (A) STANDARD CELL POTENTIALS 08233 (B) THE NERNST EQUATION 08235 (C) ELECTROMOTIVE FORCE SERIES 08240 4. ELECTRICAL UNITS AND ELECTRICAL WORK 08250 5. STANDARD ELECTRODES 08251 (A) REFERENCE ELECTRODES 08253 (B) PH ELECTRODES 08255 (C) SPECIAL PURPOSE ELECTRODES 08260 6. ELECTROCHEMICAL CELLS 08261 (A) STORAGE CELLS AND BATTERIES 08263 (B) FUEL CELLS 09000 IX. TOPICS IN CHEMISTRY 09100 A. ORGANIC CHEMISTRY 09110 1. FORMULAS, STRUCTURE, AND NOMENCLATURE 09130 2. POLYMERS 09131 (A) SYNTHETIC 09133 (B) NATURAL (PEPTIDES, ETC.) 09135 3. ORGANIC REACTIONS 09137 09140 09150 09200 09210 09211 09220 09230 09240 09300 09310 09330 09350 09400 09410 09430 09500 09510 09530 09600 09610 09620 09630 09700 09710 09730 09750 09800 09830 09900 4. NATURAL PRODUCTS 5. PETROLEUM CHEMISTRY 6. ISOMERS B. BIOCHEMISTRY 1. FATS, CARBOHYDRATES, PROTEINS AND NUCLEIC ACIDS (A) PROTEIN SYNTHESIS: THE GENETIC CODE 2. BIOENERGETICS 3. ENZYME CATALYSIS 4. METABOLIC CHEMISTRY C. INDUSTRIAL CHEMISTRY 1. PROCESSES 2. PRODUCTS 3. CHEMICAL TECHNOLOGY D. GEOCHEMISTRY 1. MINERALS AND SILICATES 2. GEOCHEMICAL PROCESSES E. ENVIRONMENTAL CHEMISTRY 1. ENVIRONMENTAL POLLUTION 2. THE CHEMISTRY OF CONSERVATION F. LABORATORY TECHNIQUES 1. MAKING PHYSICAL MEASUREMENTS 2. LABORATORY APPARATUS AND ITS USE 2. LABORATORY SAFETY G. DESCRIPTIVE CHEMISTRY 1. MAIN GROUP ELEMENTS 2. TRANSITION METALS 3. INNER TRANSITION METALS H. ANALYTICAL CHEMISTRY 1. INSTRUMENTAL ANALYSIS I. PHYSICAL CHEMISTRY 4_ AND 5_ OPTION ITEMS 10000 I. INTRODUCTORY CHEMISTRY 11000 A. DIAGNOSTIC TESTS 11100 1. CHEMISTRY CONCEPTS 11111 FULLERTON PLACEMENT TEST 11200 2. SCIENCE AND MATHEMATICS CONCEPTS 11210 (A) SCIENTIFIC NOTATION AND EXPONENTIAL NOTATION 11212 (1) MULTIPLICATION AND DIVISION 11214 (2) ADDITION AND SUBTRACTION 11220 (B) SIGNIFICANT FIGURES 11230 (C) DIMENSIONAL ANALYSIS 11240 11250 11260 11261 11262 11280 12000 13000 16000 17000 17200 17300 17310 17320 17400 17600 17700 17800 19000 19200 19220 19222 19224 19226 19227 19228 19229 19240 19242 19244 19260 19262 19264 19300 19320 19340 19360 19380 19500 19520 19540 19600 19620 19640 19800 (D) METRIC SYSTEM (E) GRAPHING (F) LOGARITHMS (1) GETTING LOGS FROM A TABLE (2) GETTING ANTI_LOGS FROM A TABLE (G) PRECISION AND ACCURACY B. HISTORICAL CONCEPTS IN CHEMISTRY C. NOMENCLATURE D. SCIENTIFIC METHOD E. PHYSICAL MEASUREMENTS 1. METRIC SYSTEM (A) CONVERSION OF UNITS (B) SI UNITS (C) METRIC PREFIXES 2. TEMPERATURE 3. HEAT 4. LIGHT 5. DENSITY OF SOLIDS AND LIQUIDS F. PROPERTIES OF MATTER 1. STATES OF MATTER (A) GASES (1) DETERMINATION OF MOLECULAR WEIGHTS (2) DETERMINATION OF P,V,T, OR MOLES (3) DETERMINATION OF MOLE FRACTION; PARTIAL PRESSURES (4) IDEAL GAS LAW (5) KINETIC MOLECULAR THEORY (6) REAL GASES (B) LIQUIDS (1) PHYSICAL PROPERTIES (2) THEORY AND STRUCTURE (C) SOLIDS (1) PHYSICAL PROPERTIES (2) THEORY AND STRUCTURE 2. SUBSTANCES AND MIXTURES (A) MIXTURES (B) ELEMENTS (C) COMPOUNDS (D) COMMON NAMES OF COMPOUNDS 3. PHYSICAL AND CHEMICAL CHANGES (A) DEFINITIONS AND EXAMPLES (B) EXPLANATORY ATOMIC THEORY 4. CHEMICAL LAWS (A) CONSERVATION OF MASS AND ENERGY (B) DEFINITE AND MULTIPLE PROPORTIONS 5. THE ELECTRICAL NATURE OF MATTER 20000 II. ATOMIC THEORY AND STRUCTURE 21000 A. ATOMIC PARTICLES; THE NUCLEUS 21110 1. ELECTRON 21110 (A) PHOTOELECTRIC EFFECT 21300 2. PROTON 21500 3. NEUTRON 22000 B. ATOMIC THEORY OF MATTER 22100 C. THE BOHR ATOM 23000 D. ATOMIC WEIGHTS 23100 1. ISOTOPES 23300 2. NATURAL ABUNDANCE 25000 E. AUFBAU PRINCIPLE; ATOMIC NUMBERS 25100 1. ELECTRON CONFIGURATIONS 25300 2. ENERGY LEVELS(ATOMIC) 25310 (A) SPECTRA 27000 F. WAVE MECHANICS; QUANTUM THEORY 27100 1. WAVE/PARTICLE DUALITY 27300 2. HEISENBERG PRINCIPLE 27500 3. ORBITS AND ORBITALS 27700 4. QUANTUM NUMBERS 27800 5. SCHRODINGER EQUATION 27900 6. PAULI EXCLUSION PRINCIPLE 29000 G.NUCLEAR CHEMISTRY 29100 1. RADIOACTIVITY AND RADIOACTIVE DECAY 29300 2. NUCLEAR STABILITY; MASS DEFECT; THEORY OF THE NUCLEUS 29500 3. NUCLEAR REACTIONS 29700 4. COSMIC PROCESSES 29900 5. MASS_ENERGY RELATIONSHIPS 30000 III. CHEMICAL PERIODICITY 31000 A. DEFINITIONS 31100 1. HISTORY AND PURPOSE OF THE PERIODIC TABLE 31200 2. TABLE STRUCTURE 31210 (A) SERIES 31220 (B) GROUPS 31230 (C) METALS 31240 (D) NON_METALS 32000 B. IDENTIFICATION RELATIONSHIPS 32100 1. PROPERTIES RELATED TO ELECTRONIC CONFIGURAGION 32200 2. PROPERTIES RELATED TO LOCATION WITHIN PERIOD 32210 (A) SEMI_METALLIC (METALLOID) 32220 (B) METALLIC EXCLUSIVELY 32230 (C) NON_METALLIC EXCLUSIVELY 32300 3. PROPERTIES RELATED TO GROUP MEMBERSHHIP 32310 (A) ACTIVE METALS 32320 (B) NON_METALS 32330 32340 32350 32360 32380 32400 (C) TRANSITION METALS (D) AMPHOTERIC ELEMENTS (E) LANTHANIDES (F) TRANSURANIC ELEMENTS (G) INERT GASES 4. IDENTIFICATION OF GROUPS BY ELECTRONIC CONFIGURATION 32500 5. IDENTIFICATION OF ELEMENTS BY VALENCE AND ATOMIC NUMBER 33000 C. PERIODIC TRENDS 33100 1. ELECTRONEGATIVITY 33200 2. IONIZATION ENERGY 33300 3. ELECTRON AFFINITY 33400 4. ATOMIC RADII 33500 5. PHYSICAL PROPERTIES 33600 6. COORDINATION NUMBER 33700 7. OXIDATION STATE 33800 8. BOND TYPE 33900 9. REACTIVITY 40000 IV. STOICHIOMETRY AND THE MOLE CONCEPT 41000 A. CHEMICAL FORMULAS AND EQUATIONS 41200 1. CHEMICAL SYMBOLS 41400 2. CHEMICAL FORMULAS 41410 (A) RADICALS 41430 (B) COMPLEX SPECIES 41600 3. WRITING AND BALANCING CHEMICAL EQUATIONS 41620 (A) PREDICTING PRODUCTS 41640 (B) CALCULATIONS FROM CHEMICAL EQUATIONS 42000 B. THE MOLE CONCEPT 42200 1. AVOGADRO'S NUMBER 42400 2. CALCULATIONS YIELDING NUMBERS OF ATOMS OR NUMBERS OF MOLECULES 42600 3. ATOMIC WEIGHT SCALE 42800 4. FORMULA WEIGHTS AND MOLECULAR WEIGHTS 42820 (A) GRAM MOLECULAR WEIGHTS 42840 (B) EQUIVALENT WEIGHTS 43000 C. STOICHIOMETRY 43200 1. DETERMINATION OF WEIGHT PERCENT 43400 2. DETERMINATION OF FORMULAS 43420 (A) SIMPLEST FORMULAS 43440 (B) MOLECULAR FORMULAS 43600 3. CALCULATIONS YIELDING WEIGHTS OR VOLUMES 43700 4. CALCULATIONS YIELDING MOLES 43900 5. CALCULATIONS YIELDING ATOMIC AND MOLECULAR WEIGHTS 44000 D. REDOX PHENOMENA 44100 1. DEFINITIONS 44200 2. COMBUSTION 44300 3. ELECTROMOTIVE SERIES 44400 4. APPLICATIONS OF THE PERIODIC TABLE 44410 (A) ELECTRON SHELLS 44420 (B) DETERMINATION OF OXIDATION NUMBERS 44430 (C) CHEMICAL ACTIVITY 44500 5. BALANCING EQUATIONS 44700 6. APPLIED CHEMISTRY 44710 (A) METALLURGY 44720 (B) PHOTOGRAPHY 44730 (C) OXIDATION PROCESSES OF ACIDS 44740 (D) ELECTROLYSIS 44750 (E) ELECTROCHEMICAL CELLS 44760 (F) WATER PURIFICATION 50000 V. CHEMICAL KINETICS AND CHEMICAL EQUILIBRIUM 51000 A. KINETICS 51100 1. COLLISION THEORY 51300 2. TRANSITION STATE THEORY 51500 3. MECHANISMS 51700 4. REACTION ORDER AND MOLECULARITY; RATE CONSTANTS 51900 5. FACTORS INFLUENCING REACTION RATE 51910 (A) CONCENTRATION 51930 (B) TEMPERATURE; ARRHENIUS' EQUATION, CALCULATING ACTIVATION ENERGY 51950 (C) CATALYSTS 51970 (D) NATURE OF REACTANTS 53000 B. HOMOGENEOUS EQUILIBRIA 53100 1. GASEOUS EQUILIBRIA 53110 (A) LE CHATELIER'S PRINCIPLE 53130 (B) NATURE OF DYNAMIC EQUILIBRIA 53150 (C) EQUILIBRIUM CONCENTRATIONS ( K , K , K ) P C X 53170 (D) EQUILIBRIUM CONCENTRATIONS IN TERMS OF INITIAL CONCENTRATIONS 53300 2. SOLUTION EQUILIBRIA 53310 (A) ORDINARY SOLUTION EQUILIBRIA 53330 (B) DISTRIBUTION(PARTITION) COEFFICIENTS 53350 (C) COMMON ION EFFECT 53370 (D) IONIZATION CONSTANTS AND WEAK ELECTROLYTES 53390 (E) COMPLEX EQUILIBRIA 53391 (1) COMPLEX IONS AND STABILITY CONSTANTS 53393 (2) ASSOCIATION CONSTANTS (POLYMERIZATION) 53395 (3) SIMULTANEOUS EQUILIBRIA 53500 3. ACID_BASE EQUILIBRIA 53510 (A) PH: STRONG ACID AND BASES 53530 53550 53570 53590 53591 53593 (B) PH: WEAK ACIDS AND BASES (C) POLYPROTIC ACIDS (D) BUFFER SOLUTIONS (E) HYDROLYSIS (1) BRONSTED ACID_BASE THEORY (2) THE ION_PRODUCT CONSTANT OF WATER, K W 53700 4. REDOX EQUILIBRIA 55000 C. HETEROGENEOUS EQUILIBRIA 55100 1. SOLUBILITY AND K SP 55300 2. MIXING AND PRECIPITATION; COMMON ION EFFECT 55500 3. PHASE EQUILIBRIA 60000 VI. SOLUTION CHEMISTRY 61000 A. CONCENTRATION RELATIONSHIPS 61001 OVERFLOW OF GENERAL CONCENTRATION RELATIONSHIP QUESTIONS 61100 1. UNITS 61200 2. TITRIMETRY 61300 3. PH AND POH 62000 B. ACIDS, BASES AND SALTS 62100 1. GENERAL PROPERTIES 62110 (A) DEFINITIONS 62120 (B) ACIDS AND SALTS 62130 (C) BASES AND SALTS 62140 (D) ACIDS AND BASES 62141 (1) STRONG ACIDS (INCLUDING OXIDIZING PROPERTIES) 62142 (2) WEAK ACIDS 62143 (3) STRONG BASES 62144 (4) WEAK BASES 62145 (5) POLYPROTIC ACIDS 62150 (E) SALTS 62151 (1) ACID SALTS 62152 (2) BASIC SALTS 62153 (3) NEUTRAL SALTS 62154 (4) AMPHIPROTIC SALTS 62200 2. NEUTRALIZATION 62210 (A) INDICATORS 62230 (B) TITRATIONS; EQUIVALENCE POINT 62300 3. COMMON ACIDS AND BASES 62310 (A) MANUFACTURE 62320 (B) APPLICATIONS 62400 4. LEWIS ACIDS AND BASES 63000 C. SOLUTE_SOLVENT INTERACTION 63100 1. DIPOLES IN SOLUTIONS 63200 2. ATTRACTIVE FORCES IN SOLUTION 63300 3. COMMON ION EFFECT 63400 4. SOLUBILITY; HEATS OF SOLUTIONS 63500 5. DISSOCIATION 63600 6. DIVERSE ION EFFECTS 64000 D. COLLIGATIVE PROPERTIES 64100 1. BOILING POINT ELEVATION 64200 2. FREEZING POINT LOWERING 64300 3. OSMOTIC PRESSURE 64400 4. VAPOR PRESSURE LOWERING 65000 E. SOLUTIONS 66000 F. COLLOIDAL SUSPENSIONS 70000 VII. BONDING 71000 A. COVALENT BONDING 71100 1. QUANTUM MECHANICS 71110 (A) WAVE FUNCTIONS AND ATTRACTIVE FORCES 71130 (B) MOLECULAR ORBITALS 71200 2. VALENCE BOND THEORY 71210 (A) LEWIS DOT STRUCTURES; FORMAL CHARGES 71230 (B) MULTIPLE BONDS 71250 (C) RESONANCE 71270 (D) HYBRIDIZATION 71280 (E) ELECTRONEGATIVITY 71300 3. MOLECULAR ORBITAL THEORY 71310 (A) BONDING/ANTIBONDING/NONBONDING ORBITALS 71330 (B) ELECTRON DELOCALIZATION; MULTI_CENTERED BONDING 71350 (C) BOND ORDER; ODD ELECTRON BONDS 71370 (D) MOLECULAR ORBITAL ENERGY CORRELATION DIAGRAMS 71400 4. MOLECULAR ARCHITECTURE; PREDICTING MOLECULAR SHAPES 71410 (A) VALENCE SHELL ELECTRON PAIR REPULSION THEORY 71430 (B) MOLECULAR ORBITAL THEORY INTERPRETATIONS 71450 (C) VALENCE BOND INTERPRETATIONS 71470 (D) MOLECULAR SHAPES AND EXPERIMENTAL DATA 71480 (E) SYMMETRY 71500 5. BOND PROPERTIES 71510 (A) SPECTROSCOPIC 71530 (B) BOND ENERGIES AND REACTIVITY 71550 (C) DIPOLE MOMENT 71570 (D) PARAMAGNETISM 71580 (E) BOND LENGTHS 71600 6. TRANSITION METAL COMPLEXES 71610 (A) STRUCTURE AND ISOMERIZATION 71620 (B) LIGANDS 71630 (C) CRYSTAL FIELD THEORY 71640 (D) VALENCE BOND AND MOLECULAR ORBITAL THEORY 71650 (E) PHYSICAL PROPERTIES 72000 B. IONIC BONDING 72100 1. BONDING FORCES 72200 2. BRAGG'S LAW 72300 3. LATTICE GEOMETRY 72500 4. LATTICE ENERGY 72700 5. DULONG_PETIT LAW 72800 6. PROPERTIES OF ELECTROVALENT COMPOUNDS 73000 C. METALLIC BONDING 73100 1. METALLIC PROPERTIES (CHEMICAL AND PHYSICAL) 73300 2. BAND THEORY (SEMICONDUCTORS) 74000 D. VAN DER WAAL'S BONDING 74100 1. BONDING FORCES 74300 2. HYDROGEN BONDING 75000 E. STRUCTURE AND REACTIVITY 80000 VIII. CHEMICAL THERMODYNAMICS 81000 A. THERMODYNAMICS 81020 (A) PATH INDEPENDENCE 81040 (B) DIFFERENTIAL RELATIONSHIPS FOR GASES, INTERNAL ENERGY, ENTHALPY AND FREE ENERGY 81100 1. HEAT; WORK; TEMPERATURE (1ST LAW) 81110 (A) MECHANICAL 81112 ADIABATIC EXPANSIONS 81114 ISOTHERMAL EXPANSIONS 81130 (B) CHEMICAL 81150 (C) ELECTRICAL 81300 2. ENTHALPY 81310 (A) PHASE CHANGES 81320 (B) CALORIMETRY 81330 (C) HESS' LAW OF HEAT SUMMATION (INCLUDES BOND ENERGIES) 81340 (D) HEAT CAPACITIES (INCLUDES PHASE CHANGES, 3RD LAW) 81350 (E) HEATS OF CHEMICAL REACTIONS (INCLUDES COMBUSTION) 81360 (F) TEMPERATURE EFFECTS ON ENTHALPY 81370 (G) CALCULATIONS INVOLVING GASES 81500 3. GIBBS FREE ENERGY 81510 (A) SPONTANEITY AND REVERSIBILITY 81530 (B) FREE ENERGY AND EQUILIBRIUM 81531 (1) GASES 81533 (2) SOLUTIONS 81535 (3) REDOX 81537 (4) TEMPERATURE EFFECTS 81550 (C) CLAUSIUS_CLAPEYRON EQUATION 81570 (D) NON_STANDARD STATE REACTIONS 81700 4. ENTROPY (2ND LAW) 82000 B. ELECTROCHEMISTRY 82100 1. CELL REACTIONS AND NOMENCLATURE 82200 2. ELECTROLYSIS AND FARADAY'S LAWS 82300 3. CELL POTENTIALS 82310 (A) STANDARD CELL POTENTIALS 82330 (B) THE NERNST EQUATION 82350 (C) ELECTROMOTIVE FORCE SERIES 82400 4. ELECTRICAL UNITS AND ELECTRICAL WORK 82500 5. STANDARD ELECTRODES 82510 (A) REFERENCE ELECTRODES 82530 (B) PH ELECTRODES 82550 (C) SPECIAL PURPOSE ELECTRODES 82600 6. ELECTROCHEMICAL CELLS 82610 (A) STORAGE CELLS AND BATTERIES 82630 (B) FUEL CELLS 90000 IX. TOPICS IN CHEMISTRY 91000 A. ORGANIC CHEMISTRY 91100 1. FORMULAS, STRUCTURE, AND NOMENCLATURE 91300 2. POLYMERS 91310 (A) SYNTHETIC 91330 (B) NATURAL (PEPTIDES, ETC.) 91350 3. ORGANIC REACTIONS 91370 4. NATURAL PRODUCTS 91400 5. PETROLEUM CHEMISTRY 91500 6. ISOMERS 92000 B. BIOCHEMISTRY 92100 1. FATS, CARBOHYDRATES, PROTEINS AND NUCLEIC ACIDS 92110 (A) PROTEIN SYNTHESIS: THE GENETIC CODE 92200 2. BIOENERGETICS 92300 3. ENZYME CATALYSIS 92400 4. METABOLIC CHEMISTRY 93000 C. INDUSTRIAL CHEMISTRY 93100 1. PROCESSES 93300 2. PRODUCTS 93500 3. CHEMICAL TECHNOLOGY 94000 D. GEOCHEMISTRY 94100 1. MINERALS AND SILICATES 94300 2. GEOCHEMICAL PROCESSES 95000 E. ENVIRONMENTAL CHEMISTRY 95100 1. ENVIRONMENTAL POLLUTION 95300 2. THE CHEMISTRY OF CONSERVATION 96000 F. LABORATORY TECHNIQUES 96100 1. MAKING PHYSICAL MEASUREMENTS 96200 2. LABORATORY APPARATUS AND ITS USE 96300 3. LABORATORY SAFETY 96400 4. QUALITATIVE ANALYSIS 97000 G. DESCRIPTIVE CHEMISTRY 97100 1. MAIN GROUP ELEMENTS 97300 2. TRANSITION METALS 97500 3. INNER TRANSITION METALS 98000 H. ANALYTICAL CHEMISTRY 98300 1. INSTRUMENTAL ANALYSIS 98500 2. QUALITATIVE ANALYSIS 99000 I. PHYSICAL CHEMISTRY