The Department of Chemistry Times An Electronic Newsletter of the Department of Chemistry State University of New York College at Brockport Volume 2, No. 2 Brockport, NY 14420 April 2003 Undergraduate Research in Chemistry in 2002, which supported eight weeks of research under Professor Margaret E. Logan of the Department of Chemistry. This year, in addition to the President’s Citation, she is the Departmental Scholar of the Department of Biological Sciences, the Departmental Scholar of the Department of Chemistry, and the Sigma Xi Award for Research in Chemistry. She has also been on the National Dean’s List since the 19992000 academic year. Andrea Topolnycky Shares 2003 President’s Citation Award By Thomas W. Kallen For the fist time since the inception of the award in 1982, two students have been selected as the recipients of the President’s Citation Award. Andrea Topolnycky, a Chemistry and Biology double major nominated by Professor Thomas W. Kallen, Chair of the Department of Chemistry, and Allen Harvey, a Physics, Mathematics and Computer Science triple major nominated by Professor Richard V. Mancuso, Chair of the Department of Physics, were selected as corecipients of this prestigious award following interviews of the top candidates in late February. The award will be presented formally at the 2003 Honors Convocation, held at the conclusion of the Scholars’ Day presentations on April 2nd. Topolnycky, who has worked on a research project with Professor Logan for a year and a half, has presented the results of her research at the Undergraduate Science Research Conference at the University of Rochester School of Medicine and Dentistry last fall. She will also be presenting her research results at Brockport Scholars 2003, the 48th Annual Undergraduate Research Symposium of the Rochester Section of the American Chemical Society, and at the National Conference on Undergraduate Research (NCUR ’03) in Salt Lake City, UT this spring. The President’s Citation is SUNY Brockport’s highest award for a graduating senior who has demonstrated outstanding scholastic merit, a strong record of co-curricular activities, significant contributions to SUNY Brockport and community, and evidence of professional promise. Finally, Topolnycky has worked as a chemistry and biology tutor in the Center for Student Learning, has been the Treasurer of our award-winning Chemistry Club for the last two years, and has served as a volunteer worker on primary and secondary school programs such as the Science Olympiad held here last year. Topolnycky is no stranger to awards for academic achievement. She received the Outstanding Student Award of the Department of Political Science in 2000, the Freshman Chemistry Award in 2001, and the Organic Chemistry Award in 2002 and was inducted into Alpha Chi, the National Honor Society, in 2001. She was the recipient of the Collier Fellowship for Topolnycky has been tendered offers of admission into the Fall 2003 entering class of Tufts University School of Dental 1 Medicine in Boston, MA, and the SUNY at Buffalo School of Dental Medicine in Buffalo, NY. She has already decided to accept the admissions offer from SUNY at Buffalo, not only because their program is more highly rated, but because the proximity of the school to her father’s home and dental practice in Amherst, NY will allow her to continue helping him manage his practice when his medical condition requires it. Five other chemistry majors have been recipients of the School of Letters and Sciences Award: Letters and Sciences Award Recipients Chemistry Majors 2000 1998 1996 1987 1986 Diana Topolnycky (’02), Andrea’s sister, was the Departmental Scholar of the Department of Chemistry last year and will be entering the Osteopathic Medicine professional medical program of Virginia Polytechnic Institute and State University (Virginia Tech) in Blacksburg, VA, this fall. All we can think of to say at this point is “thank you for lending us your two fine daughters, Dr. and Mrs. Topolnycky.” This award, the highest in the School of Letters and Sciences (a total of seventeen member departments, including Chemistry, and two programs), is presented annually to a student who has completed a major in the School of Letters and Sciences, has earned a grade point average of at least 3.75, and has made a significant contribution to either the College or to the Department. A Short (and Somewhat Biased) History of College-wide Awards Amanda Sturdevant and Andrea Topolnycky Earn Chancellor’s Award for Student Excellence By Thomas W. Kallen Andrea Topolnycky becomes the fifth chemistry major to win the President’s Citation since its inception at the beginning of the President John E. Van de Wetering administration in 1982. Chemistry majors who have received this award are listed below: By Thomas W. Kallen Two senior Chemistry majors, Amanda Sturdevant and Andrea Topolnycky, will be recognized as SUNY Brockport recipients of the 2003 Chancellor’s Award for Student Excellence at an award ceremony and reception to take place in the Convention Center, Empire State Plaza in Albany on April 21st. Chancellor’s awards will pre presented to a total of seven SUNY Brockport students by SUNY Chancellor King. President’s Citation Recipients Chemistry Majors 2003 2001 1997 1987 1982 Tracy L. Wiesner Walter J. Doherty III Joseph C. McNulty Joseph S. Sedita Anne M. Yawman Andrea N. Topolnycky Michael G. Nicholson Adam S. Buntzman Jordan C. Poler Marilyn J. Schneider The Chancellor’s Award for Student Excellence is a new honor, awarded for the first time in 2002 to 187 students scattered among the 56 Community Colleges, Colleges and Universities and quarter million students of the SUNY system. This award seeks to honor graduating seniors who have best demonstrated and been recognized for their integration of academic excellence with other aspects of their lives, aspects which may include leadership, athletics, community service, creative arts and performing arts, The President’s Citation is SUNY Brockport’s highest award for a graduating senior who has demonstrated outstanding scholastic merit, a strong record of co-curricular activities, significant contributions to SUNY Brockport and community, and evidence of professional promise. Marilyn J. Schneider was the very first recipient of the President’s Citation. 2 entrepreneurship, or career achievement. It is the highest student award that SUNY may bestow. Chemistry and a minor in Geology, was named co-Departmental Scholar of the Department of Earth Sciences at the 2003 Honors Convocation April 2nd. Brown also received the Sigma Xi Award for Research in Earth Science for his work under Professor Mark R. Noll of the Department of Earth Science. Topolnycky’s many awards are described in the lead article in this edition of the Times (“Andrea Topolnycky Shares President’s Citation Award,” pp. 1-2). Sturdevant, who has been a President’s Scholar throughout her four years at SUNY Brockport, was also the recipient of the Paul J. Kronthaler Memorial Prize in Chemistry, the Chemistry Achievement Award of the Rochester Section of the American Chemical Society, and the Sigma Xi Award for Research in Chemistry. Brown has accepted an offer of admission and a graduate teaching assistantship in the Environmental Engineering PhD Program of the University of Florida. It is worth noting that Chemistry majors earned recognition as Departmental Scholars in three departments, Biology, Chemistry and Earth Science! Sturdevant’s research with Professor Mark P. Heitz, supported by the Collier Fellowship for Undergraduate Research in Chemistry in the Summer 2002, has led to production of a thesis entitled “Spectroscopic Studies of DCM as a Molecular Probe for Solute-Solvent Interactions” and will lead to the award of Honors in Chemistry, as well as her graduation with Honors Program Honors. Six Chemistry Majors Present Papers at NCUR 2003 in Salt Lake City, Utah By Thomas W. Kallen Six chemistry majors traveled to Salt Lake City, UT, to present research papers at NCUR 2003, the 17th National Conference on Undergraduate Research, held at the University of Utah March 13-15. The research of each of these students had been supported by award of a Summer Research Fellowship for 2002. The name of each student presenter, her/his research advisor, the title of her/his paper, and the source of her/his research support follow: Sturdevant, the current President of the award-winning Chemistry Club, has served the department as a laboratory assistant in College Chemistry and Organic Chemistry. She also serves the College as a Campus tour guide for the Office of Admissions. Sturdevant has accepted the offer of admission and a graduate teaching assistantship in the Forensic Chemistry MS Program of Michigan State University. Jason Carr (Mentor, Markus M. Hoffmann, “CO2 Thermodynamic Phase Behavior Studies and Preliminary Evidence for the Formation of CO2/Ionic Liquid Microemulsions”) supported by a Camille and Henry Dreyfus Foundation Fellowship. The Faculty of the Department of Chemistry extends its heartiest congratulations to both students! Chemistry Major Earns Departmental Scholar Award in Earth Sciences Stacy Morrill (Mentor, Margaret E. Logan, “Progress Toward an Improved Synthetic Route to Amino-Substituted Diaryl Tellurides”) supported by an Ortho-clinical Diagnostics (Division of Johnson & Johnson) Fellowship. By Thomas W. Kallen Gordon H. Brown, a major in both Water Resources (Department of Earth Science) and 3 Amanda Sturdevant (Mentor, Mark P. Heitz, “Spectroscopic Study of DCM as Fluorescent Probe of Solute-Solvent Interactions”) supported by the Morris Fellowship from the Brockport Foundation. Biology, and one from Political Science. Professor Margaret E. Logan represented the Department of Chemistry and must have had her hands full riding herd on the chemistry students. Colleen Donaldson, Grants Development Director at the College, provided the financial support for the trip; and Marsha Moss of Grants Development handled the travel arrangements, accommodations, and registration for all participants. Andrea Topolnycky (Mentor, Margaret E. Logan, “Synthesis and Evaluation of Novel Diaryl Tellurides”) supported by the Collier Fellowship from the Brockport Foundation. Jason Tubbs (Mentor, Markus M. Hoffmann, “NMR Relaxation Measurements of Ionic Liquid Systems”) supported by a Camille and Henry Dreyfus Foundation Fellowship. A Fifth Chemistry “Alum” on the Faculty of Other Colleges By Thomas W. Kallen Thanks to a chance communication with Charles Scott (’88) following the publication of the February edition of the “Times,” we have discovered a fifth Chemistry alumnus who is teaching at the college level. Jordan C. Poler (’87) is an Associate Professor on the faculty of the Department of Chemistry at the University of North Carolina at Charlotte. Christopher Woods (Mentor Markus M. Hoffmann, “Surfactant Studies Using Electron Paramagnetic Resonance”) supported by a Chemistry Alumni Fellowship from the Brockport Foundation. Sturdevant’s paper was submitted in full form to, and has been selected for inclusion in, the “Proceedings of the 17th National Conference on Undergraduate Research.” The “Proceedings” of NCUR typically accepts full papers for inclusion only after peer review. Poler, a Chemistry and Physics major and recipient of the 1987 President’s Citation while at SUNY Brockport, earned a PhD in Physical Chemistry/Materials Science from the University of North Carolina in Chapel Hill, completed a post-doctoral appointment as an NIH Fellow in the Department of Molecular Biology at Princeton University, and joined the faculty at UNCC in 1995. A total of 126 papers were presented in the Chemistry Section of the conference. SUNY Brockport chemistry students presented the largest number of papers of any school in New York with 6 papers. Colgate University followed close behind with 5 papers, while Clarkson University, the University of Rochester, and Union College lagged far behind with one paper, each. No other SUNY school presented papers in the Chemistry Section. Poler reports on his Web page, “Most of my research interests are materials related. My efforts are toward the fundamental studies of complex systems at the nanoscale with regard to applications of materials at the macroscale. Complex systems exist at surfaces, interfaces and thin films. The experimental techniques that I use to study these systems are both optically and electronically based. Scanning probe microscopies are the work-horses of my research. In particular, the scanning tunneling microscope (STM) and the newly developed scanning thermopower microscope The six chemistry majors were part of a contingent of 18 students and faculty from SUNY Brockport. This contingent included six students from Chemistry, four from Physics, two from Psychology, one from 4 (STPM) are central in my studies of surfaces and interfaces. studies he and members of his undergraduate research group, Amanda Sturdevant (’03) and Lindsay Harrington (’02), have been conducting in supercritical carbon dioxide and ionic liquids (so-called environmentally “friendly” solvents). The complex systems that are of most interest to me are in the areas of both; "hard" materials (e.g. semiconductors and metals) and "soft" materials (e.g. self-assembled monolayers, biologically interesting molecules and Langmuir films).” During his visit, Heitz also made plans for a collaborative research effort with Professor Allen focused on making static and ultra-fast Raman spectroscopic measurements in supercritical carbon dioxide. He anticipates that work on this project will begin during Summer 2003 with the assistance of a SUNY Brockport undergraduate who will accompany him to OSU to help make measurements. Poler’s research interests and recent publications are listed on his Web page at http://www.chem.uncc.edu/faculty/poler/gr ad96.htm. He is currently the Chemistry Graduate Program Director of UNCC. Poler joins Jim Knittle (’74), University of Cincinnati, Bill Stevens (’77), Southern Illinois University at Carbondale, Paul Smith (’88), University of Maryland Baltimore County, and Charles Scott (’88), Thomas Jefferson University, as Chemistry alumni who are members of other college faculties. Heitz Visits Maroncelli at Pennsylvania State University By Mark P. Heitz One of the research directions in the Heitz group focuses on the solvation characteristics of solutes in “green” solvents, including supercritical CO2 and more recently ionic liquids. Solute solvation is studied by using measuring the luminescence of several highly fluorescent solute molecules and how the luminescence changes as the solute environment changes. Heitz Presents Seminar at The Ohio State University By Thomas W. Kallen In October 2001 Professor Mark P. Heitz, our 2001-2002 Seminar Director, invited Professor Heather Allen, an atmospheric chemist in the Department of Chemistry at The Ohio State University in Columbus, OH, to present a seminar in our department. Her seminar, entitled “Understanding Atmospheric Heterogeneous Chemistry: Surface Studies and Instrumentation Advances,” and her outgoing personality ended-up attracting one of our graduates, to Ohio State University for graduate studies in atmospheric chemistry. During Spring Break 2003, Professor Mark P. Heitz visited the laboratories of his postdoctoral research advisor, Professor Mark Maroncelli, at Pennsylvania State University (PSU) to measure the timeresolved fluorescence of the solutes DCM and C153 in room-temperature phosphoniumbased ionic liquids (RTPILs). Heitz used Maroncelli’s ultra-fast lasers to measure the temporal dependence of the emission spectra (TRES) of these solutes. Measurements were made using a time-correlated, single photon counting spectrometer with a time resolution of ~5 ps (that’s 5x10-12 s!). This year, Professor Heitz accepted Professor Allen’s invitation to “retaliate in kind!” Heitz presented a seminar in the Department of Chemistry at Ohio State U. on March 4, 2003, as part of their Analytical Chemistry Seminar program. In his seminar, “Characterizing Solvation in Green Solvent Systems,” Heitz summarized the recent results of fundamental Collaborative work between Heitz and Maroncelli will continue in the near future to more fully elucidate the solvation characteristics of RTPILs. 5 Mallinckrodt, in Hobart, NY. I am truly excited about finally using my degree for something other than a wall decoration. Mainly my job will be as an analytical chemist in the lab, but I will update everyone as I learn more about this job. The pay and benefits are good and the experience will put me well on my way to a bright, shiny future in chemistry. I will email everyone with more details as they become available. I hope to hear from you all soon. Let me know what you are all up to as well. Wish me luck!!! Larry.” ACS Undergraduate Research Symposium to be Held at SUNY Brockport in April By K. D. Schlecht and M. E. Logan The 48th Annual Undergraduate Research Symposium of the Rochester Section of the American Chemical Society will be held in the Seymour College Union at SUNY Brockport on Saturday, April 26, 2003. The Symposium will feature poster and oral presentations by undergraduates participating in research at Rochester area colleges. Lindsay Harrington (’02) reports that Ohio State was just not for her! She left OSU following the Winter quarter and entered the PhD Program at the SUNY College of Environmental Science and Forestry (ESF) in Syracuse, NY. In addition to the student presentations, symposium participants and guests will have the opportunity to learn about the role of chemistry in the development of new information media as Douglas Robello of the Eastman Kodak Company Research Laboratories presents the keynote lecture, "Imaging Chemistry for the New Millennium.” If you have news about yourself that you wish to have included in the “Alumni News” section of The Department of Chemistry Times, please send it by e-mail to the editor, Tom Kallen, at tkallen@brockport.edu. The Rochester Section of the American Chemical Society will provide a lunch for the student presenters and their faculty advisors following the symposium. Other symposium attendees may join them for lunch at their own expense. The organizers of this year’s symposium are Professor Margaret E. Logan and Professor Kenneth D. Schlecht of the Department of Chemistry at SUNY Brockport. Abstracts of student papers should be submitted on or before April 15, 2003. The Department of Chemistry Times is posted on the Department of Chemistry Web site at irregular intervals by Professor, Chairman and Editor Dr. Thomas W. Kallen, Department of Chemistry, SUNY College at Brockport, 350 New Campus Drive, Brockport NY 14420-2971. You may visit the Department of Chemistry Web site at www.brockport.edu/~chemistry/. E-mail messages to the Times should be addressed to Professor Kallen at tkallen@brockport.edu. Alumni News By Thomas W. Kallen Larry Ducady Jr. (’02), in a recent e-mail message writes, “Well, it's probably been a while since I've contacted many of you, so let me tell you all what is new in my life. Since graduating college in May, it's been tough for me to find a job in my field that I thought I would really like. Finally, I have found just such a job! On Monday, March 10th (tomorrow as I write this), I start as a Quality Technician II at Tyco Healthcare 6