SECTION 4 HAZARDOUS WASTE MANAGEMENT U.S. TEAM Guide, March 2001 A. Applicability This section applies to facilities and activities that generate, store, transport, treat, or dispose of any type of hazardous waste. This section and its associated checklists are more complex than other sections in this volume. Not all checklist items will be applicable to a given facility or activity. Guidance is provided on the checklists to direct the assessor to the regulations concerning the type of hazardous waste activities/facilities at the facility or activity. Information on hazardous waste storage tanks is in the section titled Storage Tank Management. Assessors are required to review state and local regulations and, if applicable, the appropriate Agency Supplement, to perform a comprehensive assessment. Select portions of this section (i.e., Review of Federal Legislation, State and Local Regulations, Key Compliance Requirements, Key Terms and Definitions, Typical Records to Review, Typical Physical Features to Inspect, and the Checklist) have been reviewed by USEPA personnel from the Office of Enforcement and Compliance Assurance (OECA) and USEPA's Office of General Counsel. USEPA's comments and suggestions for changes have been incorporated in this version of the TEAM Guide. USEPA did not review all portions of this section. USEPA also did not review and comment on items pertaining to federal Executive Orders, DOT regulations, OSHA regulations or any other area outside of Title 40 of the Code of Federal Regulations. Portions which have been added or revised as a result of this review are identified as either being reviewed, revised or added in March 2000, for example [Added March 2000]. B. Federal Legislation • The Resource Conservation and Recovery Act (RCRA). RCRA of 1976, which amended the Solid Waste Disposal Act, addresses nonhazardous (Subtitle D) and hazardous (Subtitle C) waste management activities. The Hazardous and Solid Waste Amendments (HSWA) of 1984 strengthened RCRA’s waste management provisions and added Subtitle I, which governs underground storage tanks (USTs). This section addresses Subtitle C requirements. See Solid Waste Management for Subtitle D requirements and Storage Tank Management for Subtitle I requirements [Revised March 2000]. Regulations promulgated pursuant to Subtitle C of RCRA (40 CFR 260 through 299) establish a “cradle-to-grave” system governing hazardous waste from the point of generation to disposal. RCRA hazardous wastes include the specific materials listed in the regulations (commercial chemical products designated with the code "P" or "U", hazardous wastes from specific industries/sources designated with the code "K", or hazardous wastes from non-specific sources, designated with the code "F") or materials that exhibit a hazardous waste characteristic (ignitability, corrosivity, reactivity, or toxicity and designated with the code "D"). Regulated entities that generate hazardous waste are subject to waste accumulation, manifesting, and record keeping standards. Facilities generally must obtain a permit either from U.S. EPA or from a state agency that U.S. EPA has authorized to implement the permitting program if they store hazardous wastes for more than 90 days before treatment or disposal. Facilities may operate less- than-90-day tanks or containers of hazardous wastes without a permit. Subtitle C permits contain general facility standards, such as contingency plans, emergency procedures, record keeping and reporting requirements, financial assurance mechanisms, and unit-specific standards. RCRA also contains provisions (40 CFR 264, Subpart S and Section 264.101) for conducting corrective actions that govern the cleanup of releases of hazardous waste or constituents from solid waste management units at RCRA treatment, storage, and disposal facilities. 4-1 Hazardous Waste Many operations and organizations may have numerous operations that result in the generation and management of different types of solid and hazardous waste. These operations may be subject to specific parts of RCRA, depending on the type of waste generated, its management (e.g., stored, transported), and its disposal. Most RCRA requirements are not industry specific but apply to any entity that generates, transports, treats, stores, or disposes of hazardous waste. The following are some important RCRA regulatory requirements: Identification of Solid and Hazardous Wastes (40 CFR 261) delineates the procedure every generator must follow in determining whether the material in question is considered a hazardous waste or solid waste or is exempted from regulation. Standards for Generators of Hazardous Waste (40 CFR 262) establish the responsibilities of hazardous waste generators. These include obtaining a U.S. EPA identification number, preparing a manifest, ensuring proper packaging and labeling, meeting standards for waste accumulation units, and meeting record keeping and reporting requirements. Providing they meet additional requirements described in 40 CFR 262.34, generators may accumulate hazardous waste for up to 90 days (or 180 or 270 days depending on the amount of waste generated and the distance the waste will be transported). Land Disposal Restrictions (LDRs) (40 CFR 268) are regulations prohibiting the disposal of hazardous waste on land without prior treatment. Under the LDR program, materials must meet LDR treatment standards prior to placement in a RCRA land disposal unit (landfill, land treatment unit, waste pile, or surface impoundment). Generators of waste subject to the LDR must provide notification of such to the designated TSD facility to ensure proper treatment prior to disposal. Used Oil Management Standards (40 CFR 279) impose management requirements affecting the storage, transportation, burning, processing, and re-refining of the used oil. For parties that merely generate used oil, regulations establish storage standards. For a party considered a used oil processor, re-refiner, burner, or marketer (one who generates and sells off-specification used oil directly to a used oil burner), additional tracking and paperwork requirements must be satisfied. These requiremens are addressed in the section titled POL Management. Tanks and Containers, as well as any unit, used to store, treat, or dispose of hazardous waste, are regulated under RCRA. Tanks and containers used to store hazardous waste with a high volatile organic concentration must meet emission standards under RCRA. Regulations (40 CFR 264-265, Subpart CC) require generators to test the waste to determine the concentration of the waste, to satisfy tank and container emissions standards, and to inspect and monitor regulated units. These regulations apply to all facilities that store such waste, including large quantity generators accumulating waste prior to shipment off-site. Storage tanks are addressed in the section titled Storage Tank Management. Boilers and Industrial Furnaces (BIFs) that use or burn fuel containing hazardous waste must comply with design and operating standards. BIF regulations (40 CFR 266, Subpart H) address unit design, provide performance standards, require emissions monitoring, and restrict the type of waste that may be burned. • The Federal Facility Compliance Act (FFCA) of 1992. This act provides for a waiver of sovereign immunity with respect to Federal, state, and local procedural and substantive requirements relating to RCRA solid and hazardous waste laws and regulations. Additionally, it defines hazardous waste in relation to public vessels, expands the definition of mixed waste, addresses the issue of munitions, and discusses waste discharges to Federally owned treatment works (FOTWs). • Executive Order (EO) 12088, Federal Compliance with Pollution Standards. This EO, dated 13 October 1978, requires Federally owned and operated facilities to comply with applicable Federal, state, and local pollution control standards. It makes the head of each executive agency responsible for seeing to it that the agencies, 4-2 Hazardous Waste facilities, programs, and activities the agency funds meet applicable Federal, state, and local environmental requirements and for correcting situations that are not in compliance with such requirements. In addition, the EO requires that each agency ensure that sufficient funds for environmental compliance are included in the agency budget. C. State/Local Regulations For information on regulations in specific states, see the State Supplements to TEAM Guide. Most states have met the U.S. Environmental Protection Agency (USEPA) requirements in 40 CFR 271 and have been delegated USEPA authority to administer RCRA requirements. RCRA encourages states to develop their own hazardous waste statutes and to operate regulatory programs. Many states have adopted the USEPA regulations by reference or have promulgated regulations that are identical to the USEPA regulations; other states have promulgated regulations stricter than the Federal RCRA. These differences between individual state regulations and the federal program require that assessors check the status of the state’s authorization and then determine which regulations apply. Because the section checklists are based exclusively on the requirements of the Federal RCRA/ USEPA program, it is necessary to determine in what ways the applicable state program differs from the RCRA/USEPA program. D. Key Compliance Requirements • Generator Requirements - Responsibilities are based on the amount of waste being generated in 1 mo. Typical wastes include solvents, paint, contaminated antifreeze or oil, and sludges. In some states, waste oil and other substances have been classified as a hazardous waste and therefore need to be included in the total amount of waste being generated. Within Federal regulations there are three classifications: 1. A conditionally exempt small quantity generator (CESQG) produces no more than 100 kg [ 220 lb] of hazardous waste and no more than 1 kg [ 2 lb] of acute hazardous waste in any calendar month. They cannot generate more than 100 kg [ 220 lb] in one month of any residue or contaminated soil, waste, or other debris from the clean-up of a spill, into or on any land or water, of any acute hazardous wastes. They also do not accumulate onsite more than 1000 kg [ 2205 lb] of hazardous waste and no more than 1 kg [ 2 lb] of acute hazardous waste at any one time. When either the volume of waste produced in 1 mo exceeds 100 kg [ 220 lb] of nonacutely hazardous waste or more than 1 kg [ 2 lb] of acutely hazardous waste or more than 1000 kg [ 2205 lb] of waste has accumulated onsite, the CESQG is required to comply with the more stringent standards applicable to a small quantity generator (SQG) or a Generator. 2. An SQG produces between 100 [ 220 lb] and 1000 kg [ 2205 lb] of hazardous waste and no more than 1 kg [ 2 lb] acute hazardous waste in any calendar month. They cannot generate more than 100 kg [ 220 lb] in one month of any residue or contaminated soil, waste, or other debris from the clean-up of a spill, into or on any land or water, of any acute hazardous wastes. The waste cannot accumulate onsite for more than 180 days unless the waste must be transported more than 200 mi to a treatment, storage, or disposal facility (TSDF). In that situation, the waste can accumulate for 270 days. But at no time is there to be more than 6000 kg [ 13,228 lb] of waste accumulated at the SQG. When the accumulation time onsite is exceeded, or more than 6000 kg [ 13,228 lb] of waste is onsite, the SQG is required to obtain a permit and comply with the standards in 40 CFR 264 and 265. 3. A Generator produces 1000 kg [ 2205 lb] or more of hazardous waste or more than 1 kg [ 2 lb] acute hazardous waste in any calendar month. This classification is sometimes referred to as a large quantity generator. (NOTE: Using water, which weighs 8.34 lb/gal, as a basis of measurement, 100 kg [ 220 lb] would equal 27 gal and 1000 kg [ 2205 lb] would equal 265 gal.) 4-3 Hazardous Waste Whether the facility is a CESQG, an SQG, or a Generator determines the type of records they are required to keep and design standards for storage areas. Storage areas connected with a generation point are often referred to as a satellite accumulation points. Regardless of the amount of hazardous waste generated, every facility is required to test or use knowledge of materials or processes used to determine if it is a listed hazardous waste or has hazardous characteristics. Comparison of RCRA Generator Requirements Requirement CESQG SQG Generator Identify HW Quantity Limits Yes 100 kg/mo[ 220 lb/m] Acute Waste Limits Facility Receiving Waste 1 kg/mo [ 2 lb/mo] State approved or RCRA permitted Yes 100 kg/mo [ 220 lb] 1000 kg/mo [ 2205 lb] 1 kg/mo [ 2 lb/mo] RCRA permitted facility. Yes >1000 kg/mo [ 2205 lb/mo] None RCRA permitted facility. USEPA ID Number RCRA Personnel Training DOT Training Exception Report Biennial Report Onsite Accumulation Limits (without permit) Not Required Not Required Required Basic Training Required. Required Required > 60 days Not Required 6000 kg [ 13,228 lb] Hazardous waste < 1 kg [ 2 lb] of acute hazardous waste. 180 days or day (> 200 mi) Basic requirements with technical standards for containers or tanks. Required Required Yes* Yes Accumulation Time Limits (without permit) Storage Requirements Use Manifests Required Not Required Not Required 1000 kg [ 2205 lb] hazardous waste < 1 kg [ 2 lb] of acute hazardous waste. None None No Required Required > 45 days Required Any quantity. .</= 90 days + 30 days granted by USEPA Full compliance with management of containers or tanks. * Unless the waste is reclaimed under contractual agreement and properly marked and labeled. • Transport Requirements - Containers of hazardous waste shipped offsite must be labeled to identify the waste and its hazard class. Transporters of hazardous waste required to be manifested must have an USEPA identification number and must comply with manifest management requirements. • Accumulation Point Management - An accumulation point is an area where hazardous waste is accumulated or stored before being turned in for disposal. Storage in these areas is temporary, and the permissible length of time for accumulation depends on generator classification. • Satellite Accumulation Point Management - A satellite accumulation point is an area at which no more than 55 gal of a hazardous waste or 1 qt of acute hazardous waste is accumulated at or near the point of generation. The satellite accumulation point is under the control of one operator of the process generating the waste. When the 55 4-4 Hazardous Waste gal limit is reached the operator has 3 days to move the waste to a 90-day storage area or a permitted TSDF. These standards only apply to an SQG or a Generator. • Universal Wastes - These requirements apply to batteries, pesticides, and thermostats as defined in 40 CFR 273. They are alternate standards for the handling of these wastes instead of the requirements found in 40 CFR 260 through 272. Handlers can be classified as either a large quantity handler of universal waste (5000 kg [ 11,111 lb] or more in 1 yr) or a small quantity handler of universal waste (less than 5000 kg [ 11,111 lb] in 1 yr). Depending on classification, the handler has to meet requirements concerning management of the waste, marking and labeling, notifications, and transportation. Additionally, there are standards for universal waste transporters and universal waste destination facilities (40 CFR 273). These regulations are only effective upon adoption by the state RCRA program, except in those areas without an authorized program. • Permitted TSDF Requirements - The operation of a TSDF is subject to regulation and permitting under Federal and state regulations. These regulations are both administrative and technical in nature. The administrative standards require that various plans be developed to ensure that emergencies can be dealt with, waste received is properly identified, and operating personnel are adequately trained to operate the TSDF and respond to emergencies. These administrative standards also include requirements that the TSDF be inspected routinely, records of operations are compiled and maintained, and reports of both routine and contingency operations are made to the applicable regulatory agency. The administrative standards also require that a plan for ceasing operations and closing the TSDF be developed, kept on hand, and updated frequently. The technical standards that are applicable to TSDFs fall into two classes: general standards that apply to all TSDFs and specific standards that apply to various types of facilities, i.e., container storage areas, tanks, containment buildings, surface impoundments, waste piles, land treatment facilities, incinerators, landfills, thermal treatment facilities, and chemical, physical, and biological treatment facilities. Administrative and technical standards are applied to a particular facility through a RCRA permit issued to a facility. Existing TSDFs that have applied for a permit but not yet been issued a RCRA permit are considered to be in interim status if they applied for a part A and part B permit and can continue to operate if they comply with the RCRA mandated interim status standards (ISS) of 40 CFR 265 (interim status standards for owners and operators of hazardous waste TSDF). • Ordnance - Under the provisions of 40 CFR 261.23(a)(6) through 261.23(a)(8) ordnance is classified as a reactive hazardous waste. The open burning and detonation (OB/OD) of waste explosives is allowed at interim status TSDFs as long as a minimum distance is kept from the property line of the property of others. The length of this distance is based on the amount of explosive being OB/OD. For permitted TSDFs, OB/OD activities are regulated by permit to operate a miscellaneous unit. This is often referred to as a Subpart X permit. E. Key Compliance Definitions • Active Life - the period from the initial receipt of hazardous waste at the facility until the Regional Administrator receives certification of final closure (40 CFR 260.10). • Active Portion - that portion of a facility where treatment, storage, or disposal operations are being or have been conducted and which is not a closed portion (40 CFR 260.10). • Acute Hazardous Waste - any waste listed under 40 CFR 261.31 through 261.33(d) with a hazard code of H. These include USEPA Hazardous waste numbers: F020, F021, F022, F023, F026, and F027 (40 CFR 261.31 through 261.33). • Aquifer - a geologic formation or group of formations, or part of a formation capable of yielding a significant amount of groundwater to wells or springs (40 CFR 260.10). 4-5 Hazardous Waste • Average Volatile Organic (VO) Concentration - the mass-weighted average VO concentration of a hazardous waste (40 CFR 265.1081). • Battery - a device consisting of one or more electrically connected electrochemical cells which is designed to receive, store, and deliver electric energy. An electrochemical cell is a system consisting of an anode, cathode, and an electrolyte, plus such connections (electrical and mechanical) as may be needed to allow the cell to deliver or receive electrical energy. The term battery also includes an intact, unbroken battery from which the electrolyte has been removed (40 CFR 260.10 and 273.9). In relation to the concept of universal wastes, this term includes all batteries except the following (40 CFR 273.2(b)): 1. spent lead acid batteries that are managed under 40 CFR 266, Subpart G (reclamation of spent lead acid batteries that are recyclable) 2. batteries as defined above that are not yet wastes under 40 CFR 261, including those that do not meet the criteria for waste generation (see definition of Waste Battery) 3. batteries as defined above that are not hazardous waste. A battery is a hazardous waste if it exhibits one or more of the characteristics identified in 40 CFR 261, Subpart C [Revised October 1999, Reviewed March 2000]. See also the definition of waste battery. • Boiler - an enclosed device using controlled flame combustion and having the following characteristics (40 CFR 260.10): 1. the unit has physical provisions for recovering and exporting thermal energy in the form of steam, heated fluids, or heated gases 2. the unit’s combustion chamber and primary energy recovery section(s) must be of integral design 3. while in operation, the unit maintains a thermal energy recovery efficiency of at least 60 percent 4. the unit exports and utilizes at least 75 percent of the recovered energy. • Certification - a statement of professional opinion based upon knowledge and belief (40 CFR 260.10). • Characteristics of Hazardous Waste - the characteristics of ignitibility, corrosivity, reactivity, and toxicity that identify hazardous waste (40 CFR 261.20 through 261.24). • Closed Portion - the portion of a facility that has been closed in accordance with the approved closure plan and all applicable closure requirements (40 CFR 260.10). • Closure Device - a cap, hatch, lid, plug, seal, valve, or other type of fitting that blocks an opening in a cover such that when the device is secured in the closed position it prevents or reduces air pollutant emissions to the atmosphere. Closure devices include devices that are detachable from the cover (e.g., a sampling port cap), manually operated (e.g., hinged access lid or hatch), or automatically operated (e.g., a spring loaded pressure relief valve) (40 CFR 265.1081). • Consignee - the ultimate treatment, storage, or disposal facility in a receiving country to which the hazardous waste will be sent (40 CFR 262.51). • Container - any portable device in which a material is stored, transported, treated, disposed of, or otherwise handled (40 CFR 260.10). • Containment Building - a hazardous waste management unit that is used to store or treat hazardous waste under 40 CFR 264.1100 through 264.1103 and 265.1100 through 265.1103 (40 CFR 260.10). 4-6 Hazardous Waste • Contingency Plan - a document setting out an organized, planned, and coordinated course of action to be followed in case of a fire, explosion, or release of hazardous waste or hazardous waste constituents which could threaten human health or the environment (40 CFR 260.10). • Corrective Action Management Unit (CAMU) - an area within a facility that is designated by the Regional Administrator under 40 CFR 264, subpart S, for the purpose of implementing corrective action requirements under 264.101 and RCRA section 3008(h). A CAMU shall only be used for the management of remediation wastes pursuant to implementing such corrective action requirements at the facility (40 CFR 262.10). • Cover - a device that provides a continuous barrier over the hazardous waste managed in a unit to prevent or reduce air pollutant emissions to the atmosphere. A cover may have openings (such as access hatches, sampling ports, gauge wells) that are necessary for operation, inspection, maintenance, and repair of the unit on which the cover is used. A cover may be a separate piece of equipment which can be detached and removed from the unit or a cover may be formed by structural features permanently integrated into the design of the unit (40 CFR 265.1081). • Debris - solid material exceeding a 60 mm particle size that is intended for disposal and that is (40 CFR 268.2): 1. a manufactured object 2. plant or animal matter 3. natural geologic material. The following materials are not debris: 1. any material for which a specific treatment standard is provided in Subpart D, 40 CFR 268, namely lead acid batteries, cadmium batteries, and radioactive lead solids 2. process residuals such as smelter slag and residues from the treatment of waste, wastewater, sludges, or air emissions residues 3. intact containers of hazardous waste that are not ruptured and retain at least 75 percent of their original volume. • Designated Facility - a hazardous waste TSDF that is identified on a manifest as the destination of a hazardous waste shipment. The facility must have an appropriate permit, interim status, or be regulated under specific recycling requirements (40 CFR 260.10). • Destination Facility - a facility that treats, disposes of, or recycles a particular category of universal waste, except small quantity handlers of universal waste batteries and thermostats, or a large quantity handlers of universal waste batteries or thermostats. A facility at which a particular category of universal waste is only accumulated is not a destination facility for the purposes of managing that category of universal waste (40 CFR 262.10 and 273.9) [Revised October 1999, Reviewed March 2000]. • Detonation - an explosion in which chemical transformation passes through the material faster than the speed of sound (0.33 km/s at sea level) (40 CFR 265.382). • Dike - an embankment or ridge of either natural or manmade materials used to prevent the movement of liquids, sludges, solids, or other materials (40 CFR 260.10). • Discharge or Hazardous Waste Discharge - the accidental or intentional spilling, leaking, pumping, pouring, emitting, emptying, or dumping of hazardous waste into or on any land or water (40 CFR 260.10). • Disposal - the discharge, deposit, injection, dumping, spilling, leaking, or placing of any solid waste or hazardous waste into or on any land or water so that such solid waste or hazardous waste or any constituent thereof may enter the environment or be emitted into the air or discharged into any waters, including groundwaters (40 CFR 260.10). 4-7 Hazardous Waste • Disposal Facility - a facility or part of a facility at which hazardous waste is intentionally placed into or on any land or water, and at which waste will remain after closure. The term disposal facility does not include a corrective action management unit into which remediation wastes are placed (40 CFR 260.10). • Elementary Neutralization Unit - a device which (40 CFR 260.10): 1. is used for neutralizing wastes that are hazardous only because they exhibit corrosivity characteristic defined in 40 CFR 261.22, or they are listed in Subpart D of 40 CFR 261 only for this reason 2. meets the definition of tank, tank system, container, transport vehicle, or vessel in 40 CFR 261.10. • Enclosure - a structure that surrounds a tank or container, captures organic vapors emitted from the tank or container, and vents the captured vapors through a closed-vent system to a control device (40 CFR 265.1081). • EPA Acknowledgment of Consent - the cable sent to the USEPA from the U.S. Embassy in a receiving country that acknowledges the written consent of the receiving country to accept the hazardous waste and describes the terms and conditions of the receiving country’s consent to the shipment (40 CFR 262.51). • EPA Hazardous Waste Number - the number assigned by USEPA to each hazardous waste listed in 40 CFR 261, Subpart D, and to each characteristic identified in 40 CFR 261, Subpart C (40 CFR 260.10). • EPA Identification Number - the number assigned by USEPA to each generator, transporter, and TSDF (40 CFR 260.10). • Equipment - each valve, pump, compressor, pressure relief device, sampling connection system, open-ended valve or line, or flange or other connector, and any control devices or systems required by this subpart (40 CFR 264.1031) [Added April 1999]. • Exempted Hazardous Waste Containers and Surface Impoundments - containers and surface impoundments are exempt from these air emission requirements if the waste management unit is one of the following (40 CFR 264.1082(c) and 265.1083(c)) [Revised December 1997]: 1. containers and surface impoundments for which all hazardous wastes entering the unit has an average VO concentration at the point of waste origination is less than 500 ppmw. This determination is updated at least every 12 mo 2. containers and surface impoundments for which the organic content of all hazardous wastes entering the unit has been reduced by an organic destruction or removal process that achieves any of the following conditions: a. a process that removes or destroys the organics to a level such that the average VO concentration of the hazardous waste at the point of waste treatment is less than the exit concentration limit established for the process b. a process that removes or destroys the organics contained in the hazardous waste to such a level that the organic reduction efficiency for the process is equal to or greater than 95 percent, and the average VO concentration of the hazardous waste at the point of waste treatment is less than 100 ppmw c. a process that removes or destroys the organics contained in the hazardous waste to such a level that the actual organic mass removal rate for the process is greater than the required organic mass removal rate established for the process d. a biological process that destroys or degrades the organics contained in the hazardous waste such that either of the following is met: i. the organic reduction efficiency for the process is equal to or greater than 95 percent and the organic biodegradation efficiency for the process is equal to or greater than 95 percent ii. the total actual organic mass biodegradation rate for all hazardous waste treated by the process is equal to or greater than the required organic mass removal rate e. a process that removes or destroys the organics contained in the hazardous waste and meets all the following conditions: 4-8 Hazardous Waste i. from the point of waste origination through the point where the hazardous waste enters the process, the hazardous waste is continuously managed in waste management units which use air emissions controls as applicable to the waste management unit ii. from the point of waste origination through the point where the hazardous waste enters the process, any transfer of the hazardous waste is accomplished through continuous hard-piping or other closed system transfer that does not allow exposure of the waste to the atmosphere iii. the average VO concentration of the hazardous waste at the point of waste treatment is less than the lowest average VO concentration at the point of waste origination determined for each of the individual hazardous waste streams entering the process or 500 ppmw, whichever value is lower f. a process that removes or destroys the organics contained in the hazardous waste to a level such that the organic reduction efficiency for the process is equal to or greater than 95 percent the owner/operator certifies that the average VO concentration at the point of waste origination for each of the individual waste streams entering the process is less than 10,000 ppmw g. a hazardous waste incinerator for which the owner/operator has either been issued a final permit or has certified compliance h. a boiler or industrial furnace for which the owner or operator has been issued a final permit or has certified compliance. 3. a surface impoundment used for biological treatment of hazardous waste such that it degrades or destroys the organics contained in the hazardous waste such that either of the following conditions is met: a. organic reduction efficiency for the process is equal to or greater than 95 percent and the organic biodegradation efficiency for the process is equal to or greater than 95 percent b. the total actual organic mass biodegradation rate for all hazardous waste treated by the process is equal to or greater than the required organic mass removal rate 4. containers or surface impoundments for which all hazardous waste placed in the unit either: a. meets the numerical concentrations limits for organic hazardous constituents as specified in 40 CFR 280 b. has been treated by the treatment technology established by the USEPA in 40 CFR 268.42(a) or have been removed or destroyed by an equivalent method of treatment. • Exempted Hazardous Waste Management Unit - in relation to air emissions standards, this is (40 CFR 264.1080(b) and 265.1080(b)) [Revised April 1999]: 1. a waste management unit that holds hazardous waste placed in the unit before 6 December 1996, and in which no hazardous waste is added to the unit on or after 6 December 1996 2. a container that has a design capacity less than or equal to 0.1 m3 3. a tank in which an owner/operator has stopped adding hazardous waste and the owner/operator has begun implementing or completed closure pursuant to an approved closure plan 4. a surface impoundment in which an owner/operator has stopped adding hazardous waste (except to implement an approved closure plan) and the owner/operator has begun implementing or completed closure pursuant to an approved closure plan 5. a waste management unit that is used solely for onsite treatment or storage of hazardous waste that is placed in the unit as a result of implementing remedial activities required under the corrective action authorities of RCRA Sect 3004(u), 3004(v), or 3008(h); or similar Federal or state authorities 6. a waste management unit that is used solely for the management of radioactive mixed waste in accordance with all applicable regulations under the Atomic Energy Act and the Nuclear Waste Policy Act 7. a waste management unit that the owner or operator certifies is equipped with and operating air emissions controls in accordance with regulations promulgated as a result of the CAA 8. a tank that has a process vent as defined in 40 CFR 264.1031. • Existing Hazardous Waste Management (HWM) Facility or Existing Facility - a facility which was in operation or for which construction commenced on or before 19 November 1980 (40 CFR 260.10). • Existing Portion - the land surface area of an existing waste management unit, included in the original Part A permit application, on which wastes have been placed prior to the issuance of a permit (40 CFR 260.10). 4-9 Hazardous Waste • Explosives or Munitions Emergency - a situation involving the suspected or detected presence of unexploded ordnance (UXO), damaged or deteriorated explosives or munitions, an improvised explosive device (IED), other potentially explosive material or device, or other potentially harmful military chemical munitions or device, that creates an actual or potential imminent threat to human health, including safety, or the environment, including property, as determined by an explosives or munitions emergency response specialist. Such situation may require immediate and expeditious action by an explosives or munitions emergency response specialist to control, mitigate, or eliminate the threat (40 CFR 260.10). • Explosives or Munitions Emergency Response - all immediate response activities by an explosives and munitions emergency response specialist to control, mitigate, or eliminate the actual or potential threat encountered during an explosives or munitions emergency. An explosives or munitions emergency response may include in-place render safe procedures, treatment, or destruction of the explosives or munitions and/or transporting those items to another location to be rendered safe, treated, or destroyed. Any reasonable delay in the completion of an explosives or munitions emergency response caused by a necessary, unforeseen, or uncontrollable circumstance will not terminate the explosives or munitions emergency. Explosives and munitions emergency responses can occur on either public or private lands and are not limited to responses at RCRA facilities (40 CFR 260.10). • External Floating Roof - a pontoon or double-deck type floating roof that rests on the surface of a hazardous waste being managed in a tank that has no fixed roof (40 CFR 265.1081). • Facility - all contiguous land and structures, other appurtenances, and improvements on the land, used for treating, storing, or disposing of hazardous waste. A facility may consist of several treatment, storage, or disposal operational units (e.g., one or more landfills, surface impoundments, or combination of them) (40 CFR 260.10). • Federally Owned Treatment Work (FOTW) - a facility that is owned and operated by a department, agency, or instrumentality of the Federal Government treating wastewater, a majority of which is domestic sewage, prior to discharge in accordance with a permit issued under section 402 of the Federal Water Pollution Control Act (42 USC 6939e(d)). • Final Closure - the closure of all hazardous waste management units at the facility in accordance with all applicable closure requirements so that hazardous waste management activities under parts 264 and 265 are no longer conducted at the facility unless subject to the provisions of 262.34 (40 CFR 260.10). • Fixed Roof - a cover that is mounted on a unit in a stationary position and does not move with fluctuations in the level of the material managed in the unit (40 CFR 265.1081). • Floating Membrane Cover - a cover consisting of a synthetic flexible membrane material that rests upon and is supported by the hazardous waste being managed in a surface impoundment (40 CFR 265.1081). • Floating Roof - a cover consisting of a double deck, pontoon single deck, or internal floating cover which rests upon and is supported by the material being contained, and is equipped with a continuous seal (40 CFR 265.1081). • Food-Chain Crops - tobacco, crops grown for human consumption, and crops grown for feed for animals whose products are consumed by humans (40 CFR 260.10). • Free Liquids - liquids that readily separate from the solid portion of a waste under ambient temperature and pressure (40 CFR 260.10). • Generator - any person, by site, whose act or process produces hazardous waste identified or listed in 40 CFR 261, or whose act first causes a hazardous waste to become subject to regulation (40 CFR 260.10). (NOTE: This typically is used to refer to a facility producing hazardous waste in quantities greater than 1000 kg/mo [ 2205 lb/mo] or any amount of acute waste) [Reviewed March 2000]. 4 - 10 Hazardous Waste • Groundwater - water below the land surface in a zone of saturation (40 CFR 260.10). • Halogenated Organic Compounds (HOCs) - compounds having a carbon-halogen bond that are listed in Appendix III of 40 CFR 268 (40 CFR 268.2). • Hazardous Debris - debris that contains a hazardous waste listed in subpart D of 40 CFR 261, or that exhibits a characteristic of hazardous waste identified in subpart C of 40 CFR 261. Any deliberate mixing of prohibited hazardous waste with debris that changes its treatment classification (i.e., from waste to hazardous debris) is not allowed under the dilution prohibition in 40 CFR 268.3 (40 CFR 268.2) [Revised July 1999]. • Hazardous Waste - a solid waste identified as a characteristic or listed hazardous waste in 40 CFR 261.3 (40 CFR 260.10). • Hazardous Waste Constituent - a constituent that caused the hazardous waste to be listed in 40 CFR 261, Subpart D (lists of hazardous wastes from nonspecific and specific sources, and listed hazardous wastes, or a constituent listed in the table of maximum concentrations of contaminants for the toxicity characteristic) (40 CFR 260.10). • Hazardous Waste Management Unit - a contiguous area of land on or in which hazardous waste is placed, or the largest area in which there is a significant likelihood of mixing hazardous waste constituents in the same area. Examples are a surface impoundment, a waste pile, a treatment area, a landfill cell, an incinerator, a tank and its associated piping and underlying containment system, and a container storage area. A container alone does not constitute a unit; the unit includes containers and the land or pad upon which they are placed (40 CFR 260.10). • In Light Liquid Service - the piece of equipment contains or contacts a waste stream where the vapor pressure of one or more of the organic components in the stream is greater than 0.3 kPa at 20 C, the total concentration of the pure organic components having a vapor pressure greater than 0.3 kPa at 20 C is equal to or greater than 20 percent by weight, and the fluid is a liquid at operating conditions (40 CFR 264.1031) [Revised December 1997]. • In Light Material Service - the container is used to manage a material for which both of the following conditions apply (40 CFR 265.1081): 1. the vapor pressure of one or more of the organic constituents in the material is greater than 0.3 kPa at 20 C 2. the total concentration of the pure organic constituents having a vapor pressure greater than 0.3 kPa at 20 C is equal to or greater than 20 percent by weight. • Incinerator - an enclosed device that either (40 CFR 260.10): 1. uses controlled flame combustion and neither meets the criteria for classification as a boiler, sludge dryer, or carbon regeneration unit, nor is listed as an industrial furnace 2. meets the definition of infrared incinerator or plasma arc incinerator. • Incompatible Waste - a hazardous waste that is unsuitable for (40 CFR 260.10): 1. placement in a particular device or facility because it may cause corrosion or decay of containment materials (e.g., container liners or tank walls) 2. commingling with another waste or material under uncontrolled conditions because the commingling conditions produce heat or pressure, fire or explosion, violent reaction, toxic dusts, mist, fumes or gases, or flammable fumes or gases. • Individual Generation Site - the contiguous site at or on which one or more hazardous wastes are generated. An individual generation site, such as a large manufacturing plant, may have one or more sources of hazardous waste but is considered a single or individual generation site if the site or property is contiguous (40 CFR 260.10). • Industrial Furnace - any of the following enclosed devices that are integral components of manufacturing processes and that use controlled flame devices to accomplish recovery of materials or energy: cement kilns, lime kilns, aggregate kilns, phosphate kilns, coke ovens, blast furnaces, smelting, melting and refining furnaces, 4 - 11 Hazardous Waste titanium dioxide chloride process oxidation reactors, methane reforming furnaces, pulping liquor recovery furnaces, combustion devices used in the recovery of sulfur values from spent sulfuric acid, halogen acid furnaces, and other devices designated by the administrator (40 CFR 260.10). • Injection Wells - a well into which fluids are injected (40 CFR 260.10). • Inner Liner - a continuous layer of material placed inside a tank or container that protects the construction materials of the tank or container from the contained waste or reagents used to treat the waste (40 CFR 260.10). • International Shipment - the transportation of hazardous waste into or out of the jurisdiction of the United States (40 CFR 260.10). • Lamp - the bulb or tube portion of an electric lighting device. A lamp is specifically designed to produce radiant energy, most often in the ultraviolet, visible, and infrared regions of the electromagnetic spectrum. Examples of common universal waste electric lamps include, but are not limited to, fluorescent, high intensity discharge, neon, mercury vapor, high pressure sodium, and metal halide lamps (40 CFR 260.10, 273.9) [Added October 1999, Reviewed March 2000]. The following are exempted from the definition of lamp in relation to universal waste (40 CFR 273.5(b)): 1. lamps that are not yet wastes under 40 CFR 261 (see the definition of Waste Lamp) 2. lamps that are not hazardous waste. A lamp is a hazardous waste if it exhibits one or more of the characteristics identified in 40 CFR 261. See also the definition for Waste Lamp. • Land Disposal - placement in or on the land, except in a corrective action management unit, and includes, but is not limited to, placement in a landfill, surface impoundment, waste pile, injection well, land treatment facility, salt dome formation, salt bed formation, underground mine or cave, or placement in a concrete vault, or bunker intended for disposal purposes (40 CFR 268.2). • Land Treatment Facility - a facility or part of a facility at which hazardous waste is applied onto or incorporated into the soil surface; such facilities are disposal facilities if the waste will remain after closure (40 CFR 260.10). • Landfill - a disposal facility or part of a facility where hazardous waste is placed in or on land and which is not a pile, a land treatment facility, a surface impoundment, an underground injection well, a salt dome formation, a salt bed formation, an underground mine, a cave, or a corrective action management unit (40 CFR 260.10). • Landfill Cell - a discrete volume of a hazardous waste landfill that uses a liner to provide isolation of wastes from adjacent cells or wastes. Examples are trenches and pits (40 CFR 260.10). • Large Quantity Generator - see Generator. • Large Quantity Handler of Universal Waste - a universal waste handler who accumulates 5,000 kilograms or more total of universal waste (batteries, pesticides, thermostats, or lamps, calculated collectively) at any time. This designation as a large quantity handler of universal waste is retained through the end of the calendar year in which 5,000 kg [ 11,111 lb] or more total of universal waste is accumulated (40 CFR 273.9) [Revised October 1999, Reviewed March 2000]. • Leachate - any liquid, including any suspended components in the liquid, that has percolated through or drained from hazardous waste (40 CFR 260.10). • Leak Detection System - a system capable of detecting the failure of either the primary or secondary containment structure or the presence of a release of hazardous waste or accumulated liquid in the secondary structure. Such a system must employ operational controls (e.g., daily, visual inspections for releases into the secondary containment system of aboveground tanks) or consist of an interstitial monitoring device designed to detect 4 - 12 Hazardous Waste continuously and automatically the failure of the primary or secondary containment structure or the presence of a release of hazardous waste into the secondary containment structure (40 CFR 260.10). • Liner - a continuous layer of natural or manmade materials, beneath or on the sides of a surface impoundment, landfill, or landfill cell, which restricts the downward or lateral escape of hazardous waste, hazardous waste constituents, or leachate (40 CFR 260.10). • Malfunction - any sudden, infrequent, and not reasonably preventable failure or air pollution control equipment, process equipment, or a process to operate in a normal or usual manner. Failures that are caused in part by poor maintenance or careless operations are not malfunctions (40 CFR 265.1081). • Management or Hazardous Waste Management - the systematic control of the collection, source separation, storage, transportation, processing, treatment, recovery, and disposal of hazardous waste (40 CFR 260.10). • Management Practice (MP) - practices that, although not mandated by law, are encouraged to promote safe operating procedures. • Manifest - the shipping document originated and signed by the generator containing the information required by 40 CFR 262, Subpart B (40 CFR 260.10). • Manifest Document Number - the USEPA 12-digit number assigned to the generator plus a unique 5-digit number assigned to the manifest by the generator for recording and reporting purposes (40 CFR 260.10). • Military Munitions - all ammunition products and components produced or used by or for the U.S. DOD or the U.S. Armed Services for national defense and security, including military munitions under the control of the DOD, the Coast Guard, the DOE, and National Guard personnel. The term military munitions includes: confined gaseous, liquid, and solid propellants, explosives, pyrotechnics, chemical and riot control agents, smokes and incendiaries used by DOD components, including bulk explosives and chemical warfare agents, chemical munitions, rockets, guided and ballistic missiles, bombs, warheads, mortar rounds, artillery ammunition, small arms ammunition, grenades, mines, torpedoes, depth charges, cluster munitions and dispensers, demolition charges, and devices and components thereof. Military munitions do not include wholly inert items, improvised explosive devices, and nuclear weapons, nuclear devices, and nuclear components thereof. However, the term does include non-nuclear components of nuclear devices, managed under DOEs nuclear weapons program after all required sanitization operations under the Atomic Energy Act of 1954, as amended, have been completed (40 CFR 260.10). • Miscellaneous Unit - a hazardous waste management unit at which hazardous waste is treated, stored, or disposed of and that is not a container, tank, surface impoundment, pile, land treatment unit, landfill, incinerator, boiler, industrial furnace, underground injection well with appropriate technical standards under 40 CFR 146, containment building, corrective action management unit, or unit eligible for a research development and demonstration permit under 40 CFR 270.65 (40 CFR 260.10). • Movement - hazardous waste transported to a facility in an individual vehicle (40 CFR 260.10). • New Hazardous Waste Management Facility - a facility that began operation, or for which construction commenced after 21 October 1976 (40 CFR 260.10). • No Detectable Organic Emissions - no escape of organics to the atmosphere as determined by using the procedures specified in 40 CFR 265.1084(d) (40 CFR 265.1081). • Nonwastewaters - wastes that do not meet the criteria for wastewaters (40 CFR 268.2). • Onsite - the same or geographically contiguous property which may be divided by a public or private right-of-way, provided the entrance and exit between the properties is at a crossroads intersection, and access is by crossing as opposed to going along the right-of-way. Non-contiguous properties owned by the same person but connected by 4 - 13 Hazardous Waste a right-of-way which he controls and to which the public does not have access is also considered onsite property (40 CFR 260.10) [Reviewed March 2000]. • Open Burning - the combustion of any material without the following characteristics (40 CFR 260.10): 1. control of combustion air to maintain adequate temperature for efficient combustion 2. containment of the combustion-reaction in an enclosed device to provide sufficient residence time and mixing for complete combustion 3. control of emission of the gaseous combustion products. • Open-ended Valve or Line - any valve, except pressure relief valves, having one side of the valve seat in contact with hazardous waste and one side open to the atmosphere, either directly or through open piping (40 CFR 264.1031) [Added April 1999]. • Ordnance - See Waste Explosives. • Partial Closure - the closure of a hazardous waste management unit in accordance with the applicable closure requirements of 40 CFR 264 and 265 at a facility that contains other active hazardous waste management units. For example, partial closure may include the closure of a tank (including its associated piping and underlying containment systems) while other units of the same facility continue to operate (40 CFR 260.10). • Pesticides - any substance or mixture of substances intended for preventing, destroying, repelling, or mitigating any pest, or intended for use as a plant regulator, defoliant, or desiccant, other than any article that either (40 CFR 262.10 and 273.9): 1. is a new animal drug under FFDCA Section 201(w) 2. is an animal drug that has been determined by regulation of the Secretary of Human Health and Human Services not to be a new animal drug 3. is an animal feed under FFDCA section 201(x) that bears or contains any substances described by paragraph 1 or 2 of this definition. Pesticides that are regulated as universal wastes include pesticides that are either (40 CFR 273.3(a): 1. recalled pesticides that are stocks of a suspended and canceled pesticide that are a part of a voluntary or mandatory recall under FIFRA Section 19(b), including, but not limited to, those owned by the registrant responsible for conducting the recall 2. recalled pesticide that are stocks of suspended or canceled pesticides, or a pesticide that is not in compliance with FIFRA, that are part of a voluntary recall by the registrant 2. stocks of other unused pesticide products that are collected and managed as a part of a waste pesticide collection. Pesticides that are not universal wastes include (40 CFR 273.3(b): 1. the following pesticides when disposed of on a farmers own farm in a manner consistent with the label, and the container is triple rinsed: a. suspended or recalled pesticides that are a part of a voluntary or mandatory recall under FIFRA Section 19(b), including, but not limited to, those owned by the registrant responsible for conducting the recall b. stocks of suspended or canceled pesticide products that are not in compliance with FIFRA and are part of a voluntary recall by the registrant c. stocks of other unused pesticide products 2. pesticides not meeting the definition of a universal waste 3. pesticides that are not wastes under 40 CFR 261, including those who do not meet the criteria for waste generation or those that are not wastes (see the definition of Waste Pesticide) 4. pesticides that are not a hazardous waste [Revised October 1999, Reviewed March 2000]. See also the definition for Waste Pesticides. 4 - 14 Hazardous Waste • Pile - any noncontainerized accumulation of solid, nonflowing hazardous waste used for treatment or storage that is not a containment building (40 CFR 260.10). • Point of Waste Treatment - the point where a hazardous waste exits a waste management unit used to destroy, degrade, or remove organics in the hazardous waste (40 CFR 265.1081). • Point Source - any discernible, confined, and discrete conveyance, including, but not limited to, any pipe, ditch, channel, tunnel, conduit, well, discrete fissure, container, rolling stock, concentrated animal feeding operation, or vessel or floating craft from which pollutants are or may be discharged. This term does not include return flows from irrigated agriculture (40 CFR 260.10). • Primary Exporter - any person who is required to originate the manifest for a shipment of hazardous waste in accordance with 40 CFR 262, Subpart B or an equivalent state provision, that specifies treatment, storage, or disposal facility in a receiving country as the facility to which the hazardous waste will be sent and any intermediate arranging for the export (40 CFR 262.51). • Publicly Owned Treatment Works (POTW) - any device or system used in the treatment (including recycling and reclamation) of municipal sewage or industrial wastes of a liquid nature that is owned by a state or municipality (as defined by section 502(4) of the CWA). This definition includes sewers, pipes, or other conveyances only if they convey wastewater to a POTW providing treatment (40 CFR 260.10). • Pump Operating Level - a liquid level proposed by the owner or operator and approved by the Regional Administrator based on pump activation level, sump dimensions, and level that avoids backup into the drainage layer and minimizes head in the sump (40 CFR 264.226(d)(3)). • Qualified Groundwater Scientist - a scientist or engineer who has received a baccalaureate or post- graduate degree in the natural sciences or engineering and has sufficient training and experience in groundwater hydrology and related fields as may be demonstrated by state registration, professional certification, or completion of accredited university courses that enable the individual to make sound professional judgments regarding groundwater monitoring and contaminant fate and transport (40 CFR 260.10). • Receiving Country - a foreign country to which a hazardous waste is sent for the purpose of treatment, storage, or disposal (except short-term storage incidental to transportation) (40 CFR 262.51). • Replacement Unit - a landfill, surface impoundment, or waste pile unit (40 CFR 260.10): 1. from which all or substantially all of the waste is removed 2. that is subsequently reused to treat, store, or dispose of hazardous waste. This does not apply to a unit from which waste is removed during closure, if the subsequent reuse solely involves the disposal of waste from that unit and other closing units or corrective action areas at the facility, in accordance with an approved closure plan or USEPA or state-approved corrective action. • Representative Sample - a sample of a universe or whole (e.g., waste pile, lagoon, groundwater) that can be expected to exhibit the average properties of the universe or whole (40 CFR 260.10). • Restricted Wastes - categories of hazardous wastes that are restricted from land disposal either by regulation or by statute, in other words, a hazardous waste that is restricted no later than the date of the deadline established in RCRA Section 3004 (40 CFR 268). • Runoff - any rainwater, leachate, or other liquid that drains over land from any part of a facility (40 CFR 260.10). • Run-On - any rainwater, leachate, or other liquid that drains over land onto any part of a facility (40 CFR 260.10). 4 - 15 Hazardous Waste • Sampling Connection System - an assembly of equipment within a process or waste management unit used during periods of representative operation to take samples of the process or waste fluid. Equipment used to take nonroutine grab samples is not considered a sampling connection system (40 CFR 264.1031) [Added April 1999]. • Sludge - any solid, semisolid, or liquid waste generated from a municipal, commercial, or industrial wastewater treatment plant, water supply treatment plant, or air pollution control facility exclusive of the treated effluent from a wastewater treatment plant (40 CFR 260.10). • Small Quantity Generator (SQG) - a generator that generates less than 1000 kg [ 2205 lb] of hazardous waste in a calendar month. (NOTE: As commonly used, an SQG generates more than 100 kg [ 220 lb] and </= 1 kg of acute waste in a calendar month) (40 CFR 260.10).) • Small Quantity Handler of Universal Waste - a universal waste handler who does not accumulate 5,000 kg [ 11,111 lb] or more total of universal waste (batteries, pesticides, thermostats, or lamps, calculated collectively) at any time (40 CFR 273.9) [Revised October 1999, Reviewed March 2000]. • Soil - unconsolidated earth material composing the superficial geologic strata (material overlying bedrock), consisting of clay, silt, sand, or gravel size particles as classified by the U.S. Natural Resources Conservation Service, or a mixture of such materials with liquids, sludges or solids which is inseparable by simple mechanical removal processes and is made up primarily of soil by volume based on visual inspection. Any deliberate mixing of prohibited hazardous waste with soil that changes its treatment classification (i.e., from waste to contaminated soil) is not allowed under the dilution prohibition in 40 CFR 268.3 (40 CFR 268.2) [Added July 1999]. • Storage - the holding of hazardous wastes for a temporary period, at the end of which the hazardous wastes are treated, disposed of, or stored elsewhere (40 CFR 260.10). • Sump - any pit or reservoir that meets the definition of tank and those troughs/trenches connected to it that serve to collect hazardous waste for transport to hazardous waste TSDFs except that as used in the landfill, surface impoundment, and waste pile rules, sump means any lined pit or reservoir that serves to collect liquids drained from a leachate collection and removal system or leak detection system for subsequent removal from the system (40 CFR 260.10). • Surface Impoundment - a facility or part of a facility that is a natural topographic depression, man-made excavation, or diked area formed primarily of earthen materials designed to hold an accumulation of liquid wastes or wastes containing free liquids and which is not an injection well (40 CFR 260.10). • Thermal Treatment - the treatment of hazardous waste in a device that uses elevated temperature as the primary means to change the chemical, physical, or biological character or composition of the hazardous waste (40 CFR 260.10). • Thermostat - a temperature control device that contains metallic mercury in an ampule attached to a bimetal sensing element, and mercury-containing ampules that have been removed from these temperature control devices in compliance with the requirements of 40 CFR 273.12(c)(2) or 273.33(c)(2) (40 CFR 262.10 and 273.9). The following are exempted from the definition of thermostat in relation to universal waste (40 CFR 273.4(b)): 1. thermostats that are not yet wastes under 40 CFR 261 (see the definition of Waste Thermostat) 2. thermostats that are not hazardous waste [Revised October 1999, Reviewed March 2000]. See also the definition for Waste Thermostat. • Totally Enclosed Treatment Facility - a facility for the treatment of hazardous waste which is directly connected to an industrial production process and which is constructed and operated in a manner which prevents the release of any hazardous waste or any constituent thereof into the environment during treatment. An example is a pipe in which waste acid is neutralized (40 CFR 260.10). 4 - 16 Hazardous Waste • Transfer Facility - any transportation-related facility including loading docks, parking areas, storage areas, and other similar areas where shipments of hazardous wastes are held during the normal course of transportation (40 CFR 260.10). • Transit Country - any foreign country, other than a receiving country, through which a hazardous waste is transported (40 CFR 262.51). • Transport Vehicle - a motor vehicle or rail car used for the transportation of cargo by any mode. Each cargocarrying body (trailer, railroad freight car, etc.) is a separate transport vehicle (40 CFR 260.10). • Transporter - a person engaged in the offsite transportation of hazardous wastes by air, rail, highway, or water (40 CFR 260.10). • Treatability Study - a study in which a hazardous waste is subjected to a treatment process to determine (40 CFR 260.10): 1. whether the waste is amenable to the treatment process 2. what pretreatment (if any) is required 3. the optimal process conditions needed to achieve the desired treatment 4. the efficiency of a treatment process for a specific waste or wastes 5. the characteristics and volumes of residuals from a particular treatment process. Also included in this definition for the purpose of the 261.4(e) and (f) exemptions are liner compatibility, corrosion, and other material compatibility studies and toxicological and health effects studies. A treatability study is not a means to commercially treat or dispose of hazardous waste. • Treatment - any method, technique, or process, including neutralization, designed to change the physical, chemical, or biological character or composition of any hazardous waste to neutralize the waste, recover energy or material resources from the waste, or render the waste nonhazardous or less hazardous; safer to transport, store, or dispose of; or amenable for recovery, amenable for storage, or reduced in volume (40 CFR 260.10). • Treatment Zone - a soil area of the unsaturated zone of a land treatment unit within which hazardous constituents are degraded, transformed, or immobilized (40 CFR 260.10). • Underground Injection - the subsurface emplacement of fluids through a bored, drilled, driven, or dug well, when the depth of the dug well is greater than the largest surface dimension (40 CFR 260.10). • Unexploded Ordnance (UXO) - military munitions that have been primed, fused, armed, or otherwise prepared for action, and have been fired, dropped, launched, projected, or placed in a such a manner as to constitute a hazard to operations, installation, personnel, or material and remain unexploded either by malfunction, design, or any other cause (40 CFR 266.201). • Unsaturated Zone or Zone of Aeration - the zone between the land surface and the water table (40 CFR 260.10). • United States - the 50 states, the District of Columbia, the Commonwealth of Puerto Rico, the U.S. Virgin Islands, Guam, American Samoa, and the Commonwealth of the Northern Mariana Islands (40 CFR 260.10). • Universal Waste - any of the following hazardous wastes that are managed under the universal waste requirements of 40 CFR 273 (40 CFR 260.10 and 273.9): 1. Batteries as described in Sec. 273.2 (see definition of Battery) 2. Pesticides as described in Sec. 273.3 (see definition of Pesticides) 3. Thermostats as described in Sec. 273.4 (see definition of Thermostat) 4. Lamps as described in Sec. 273.5 (see definition of Lamp) [Revised October 1999, Reviewed March 2000]. 4 - 17 Hazardous Waste • Universal Waste Handler - this term means either (40 CFR 262.10 and 273.9): 1. a generator of universal waste 2. the owner or operator of a facility, including all contiguous property, that receives universal waste from other universal waste handlers, accumulates universal waste, and sends universal waste to another universal waste handler, to a destination facility, or to a foreign destination. It does not mean: 1. a person who treats (except under the provisions of 40 CFR 273.13(a) or (c), or 273.33(a) or (c), disposes of, or recycles universal waste 2. a person engaged in offsite transportation of a universal waste by air, rail, highway, or water, including a universal waste transfer facility [Revised October 1999, Reviewed March 2000]. • Universal Waste Transfer Facility - any transportation related facility including loading docks, parking areas, storage areas, and other similar areas where shipments of universal waste are held during the normal course of transportation for 10 days or less (40 CFR 273.9) [Revised October 1999, Reviewed March 2000]. • Universal Waste Transporter - a person engaged in the offsite transportation of universal waste by air, rail, highway, or water (40 CFR 260.10 and 273.9) [Revised October 1999, Reviewed March 2000]. • Uppermost Aquifer - the geologic formation nearest the natural ground surface that is an aquifer, as well as lower aquifers that are hydraulically interconnected with this aquifer, within the facility’s property boundary (40 CFR 260.10). • Used Oil - any oil that has been refined from crude oil, or any synthetic oil, that has been used and as a result of such use is contaminated by physical or chemical impurities [NOTE: See also the definition of Used Oil in POL Management] (40 CFR 260.10). • Volatile Organic (VO) Concentration - the fraction by weight of the volatile organic compounds in a hazardous waste expressed in terms of ppmw as determined by direct measurement or by knowledge of the waste (40 CFR 265.1081). • Waste Battery - a used battery becomes a waste on the date that it is discarded (e.g., when sent for reclamation). An unused battery becomes a waste on the date the handler decides to discard it. See also the definition of Battery (40 CFR 273.2(c)) [Reviewed March 2000]. • Waste Explosives - waste that has the potential to detonate and bulk military propellants that cannot be safely disposed of through other modes of treatment (40 CFR 265.382). • Waste Lamp - A used lamp becomes a waste on the date it is discarded. An unused lamp becomes a waste on the date the handler decides to discard it (40 CFR 273.5(c)) [Added October 1999, Reviewed March 2000]. • Waste Military Munitions - a military munition is not a solid waste when (40 CFR 266.202): 1. used for its intended purpose, including: a. use in training military personnel or explosives and munitions emergency response specialists (including training in proper destruction of unused propellant or other munitions b. use in research, development, testing, and evaluation of military munitions, weapons, or weapon systems c. recovery collection, and on range destruction of unexploded ordnance and munitions fragments during range clearance activities at active or inactive ranges. However, “use for intended purposes” does not include the on-range disposal or burial of unexploded ordnance and contaminants when the burial is not a result of product use. 2. an unused munition, or component thereof, is being repaired, reused, recycled, reclaimed, disassembled, reconfigured, or otherwise subjected to materials recovery activities, unless such activities involve use constituting disposal or burning for energy recovery. 4 - 18 Hazardous Waste An unused military munition is a solid waste when any of the following occurs: 1. the munition is abandoned by being disposed of, burned, detonated (except during intended use), incinerated, or treated prior to disposal 2. the munition is removed from storage in a military magazine or other storage area for the purpose of being disposed of, burned, or incinerated, or treated prior to disposal; or 3. the munition is deteriorated or damaged (e.g., the integrity of the munition is compromised by cracks, leaks, or other damage) to the point that it cannot be put into serviceable condition, and cannot reasonably be recycled or used for other purposes 4. the munition has been declared a solid waste by an authorized military official. A used or fired military munition is a solid waste: 1. when transported off range or from the site of use, where the site of use is not a range, for the purpose of storage, reclamation, treatment, disposal, or treatment prior to disposal 2. if recovered, collected, and then disposed of by burial, or landfilling either on or off a range. • Waste Pesticides - this term applies as follows (40 CFR 273.3(c): 1. a recalled pesticides becomes a waste on the first date on which both of the following conditions apply: a. the generator of the recalled pesticide agrees to participate in the recall; and b. the person conducting the recall decides to discard (e.g., burn the pesticides for energy recovery) the pesticides 2. stocks of unused pesticide products that are collected and managed as part of a waste pesticide collection program becomes a waste on the day the generator decides to discard it. The following pesticides are not waste (40 CFR 273.3(d): 1. recalled pesticides providing the person conducting the recall either: a. has not made a decision to discard (e.g., burn for energy recovery) the pesticide b. has made a decision to use a management option that, under 40 CFR 261.2, does not cause the pesticide to be a solid waste (i.e., the selected option is use (other than use constituting disposal), or reuse, or reclamation) 2. unused pesticide products that are collected and managed as a part of a waste pesticide collection program if the generator of the unused pesticide product has not decided to discard (e.g., burn for energy recovery) them [Reviewed March 2000]. • Waste Stabilization Process - any physical or chemical process used to either reduce the mobility of hazardous constituents in a hazardous waste or eliminate free liquids (40 CFR 265.1081). • Waste Thermostats - A used thermostat becomes a waste on the date it is discarded (e.g., sent for reclamation). An unused thermostat becomes a waste on the date the handler decides to discard it (40 CFR 273.4(c)) [Reviewed March 2000]. • Wastewater Treatment Unit - a device that is part of a wastewater treatment facility subject to regulation under section 402 or 307(b) of the CWA and receives and treats or stores an influent wastewater that is a hazardous waste (as defined in 40 CFR 261.3), or that generates and accumulates a wastewater treatment sludge that is a hazardous waste, or treats or stores a wastewater treatment sludge, and meets the definition of tank or tank system (40 CFR 260.10). • Wastewaters - wastes that contain less than 1 percent by weight total organic compounds and less than 1 percent by weight total suspended solids (TSS) with certain exceptions (40 CFR 268.2). • Zone of Engineering Control - an area under the control of the owner/operator that, upon detection of a hazardous waste release, can be readily cleaned up before the release of hazardous waste or hazardous constituents to groundwater or surface water (40 CFR 260.10). F. Records To Review [Revised October 1998] 4 - 19 Hazardous Waste Generator (including TSDFs if they are also generators): • Notification (USEPA identification number) • Hazardous waste manifests • LDR Restriction Notification Forms • Manifest exception reports • Biennial reports • Inspection Logs (as applicable) • Delistings • Land disposal restriction certifications • Employee training documentation • Contingency plan • Notifications of hazardous waste oil fuel marketing or blending activity In addition to the above, TSDFs would require: • Permits, if issued, otherwise Part A application • Unmanifested waste reports • Waste analysis plan(s) • Operating record • Groundwater monitoring records and annual reports (where required) • Biennial reports • Closure/postclosure plans • Closure/postclosure notices (where applicable) • Location map of the TSDF • Part A permit, including: • inspection plan • training plan • closure/postclosure plans • Other documents as required by the permit • Emergency permits G. Physical Features To Inspect • • • • • • • • • • • Disposal sites Accumulations points Incinerators Vehicles used for transport Storage facilities (including drums) Surface impoundments OB/OD sites Treatment units Generation sites Satellite accumulation points Recycling sites 4 - 20 Hazardous Waste H. Guidance for Hazardous Waste Management Checklist Users REFER TO CHECKLIST ITEMS: All Federal Facilities HW.1.1.US. and HW.1.2.US. Missing Checklist Items HW.2.1.US. All Sizes of Generators HW.10.1.US. through HW.10.3.US Conditionally Exempt Small Quantity Generators (CESQGs) HW.15.1.US. through HW.15.6.US. Small Quantity Generators (SQGs) General Personnel Training Containers Satellite Accumulation Points Container Storage Areas Disposal of Restricted Wastes HW.20.1.US. through HW.20.5.US. HW.25.1.US. and HW.25.2.US. HW.30.1.US. through HW.30.6.US. HW.35.1.US. HW.40.1.US. through HW.40.3.US. HW.45.1.US. through HW.45.5.US. Generators General Personnel Training Contingency Plans and Emergency Coordinators Containers Emissions from Process Vents Air Emission Standards for Equipment Leaks Satellite Accumulation Points Container Storage Areas Containment Buildings Disposal of Restricted Waste HW.55.1.US. through HW.55.7.US. HW.60.1.US. and HW.60.2.US. HW.65.1.US. through HW.65.4.US. HW.70.1.US. through HW.70.12.US. HW.71.1.US. through HW.71.6.US. HW.72.1.US. through HW.72.10.US. HW.75.1.US. HW.80.1.US. through HW.80.4.US. HW.85.1.US. through HW.85.7.US. HW.90.1.US. through HW.90.6.US. Transportation of Hazardous Waste HW.100.1.US. through HW.100.5.US. Military Munitions HW.102.1.US. through HW.102.4.US. All TSDFs General Personnel Training Containers Container Storage Areas Containment Buildings Restricted Wastes Emissions from Process Vents Air Emissions Standards for Equipment Leaks Documentation Requirements Surface Impoundments Waste Piles Land Treatment Units Hazardous Waste Landfills HW.105.1.US. though HW.105.10.US. HW.110.1.US. and HW.110.2.US. HW.115.1.US. through HW.115.12.US. HW.120.1.US. through HW.120.3.US. HW.125.1.US. through HW.125.7.US. HW.130.1.US. through HW.130.6.US. HW.135.1.US. through HW.135.6.US. HW.140.1.US. through HW.140.10.US. HW.145.1.US. through HW.145.13.US. HW.150.1.US. through HW.150.8.US. HW.155.1.US. HW.160.1.US. HW.165.1.US. through HW.165.10.US. 4 - 21 Hazardous Waste REFER TO CHECKLIST ITEMS: Hazardous Waste Munitions and Explosives Storage Closure Additional Requirements for Permitted TSDFs General Surface Impoundments Waste Piles Land Treatment Units Hazardous Waste Landfills Incinerators Miscellaneous Units HW.167.1.US. through HW.167.5.US. HW.170.1.US. through HW.170.5.US. HW.180.1.US. through HW.180.14.US. HW.185.1.US. through HW.185.12.US. HW.190.1.US. through HW.190.5.US. HW.195.1.US. through HW.195.7.US. HW.200.1.US. through HW.200.4.US. HW.205.1.US. through HW.205.4.US. HW.210.1.US. through HW.210.3.US. Additional Requirements for Interim Status TSDFs General Surface Impoundments Waste Piles Land Treatment Units Hazardous Waste Landfills Incinerators Thermal Treatment Chemical/Physical/Biological Treatment HW.220.1.US. through HW.220.9.US. HW.225.1.US. through HW.225.5.US. HW.230.1.US. through HW.230.4.US. HW.235.1.US. through HW.235.4.US. HW.240.1.US HW.245.1.US. through HW.245.5.US. HW.250.1.US. through HW.250.3.US. HW.255.1.US. through HW.255.3.US. Export/Import of Hazardous Waste HW.265.1.US. through HW.265.8.US. Hazardous Waste on Public Vessels HW.270.1.US. Small Quantity Universal Waste Handlers General Specific Wastes Personnel Training Containers Transportation HW.280.1.US. through HW.280.4.US. HW.290.1.US. through HW.290.6.US. HW.300.1.US. HW.310.1.US. HW.330.1.US. and HW.330.2.US. Large Quantity Universal Waste Handlers General Specific Wastes Personnel Training Containers Notifications Transportation HW.370.1.US. through HW.370.4.US. HW.380.1.US. through HW.380.6.US. HW.390.1.US. HW.400.1.US. HW.410.1.US. HW.420.1.US. through HW.420.3.US. Universal Waste Transporters HW.450.1.US. through HW.450.7.US. Universal Waste Destination Facilities HW.470.1.US. through HW.470.4.US. Appendix 4-1, Hazardous Waste from Nonspecific Sources and from Specific Sources Appendix 4-2, Commercial Chemical Products or Manufacturing Chemical Intermediates 4 - 22 Hazardous Waste Identified as Toxic Wastes Appendix 4-3, Toxicity Constituents and Regulatory Levels Appendix 4-4, This appendix has been deleted Appendix 4-5, Commercial Chemical Products or Manufacturing Chemical Intermediates Identified as Acute Hazardous Waste Appendix 4-6, Hazardous Materials/Hazardous Waste Storage Incompatibility Chart Appendix 4-7, Recordkeeping, Notification, and/or Certification Requirements for 40 CFR 268. Appendix 4-8, Land Disposal Restricted Wastes and Their Effective Dates Appendix 4-8a, Schedule for Implementation of Air Emissions Standards Appendix 4-9, Treatment Standards for Hazardous Wastes Appendix 4-10, Technology Codes and Description of Technology Based Standards Appendix 4-11, Maximum Concentrations of Constituents for Groundwater Protection Appendix 4-12, Groundwater Monitoring List Appendix 4-13, Interim Primary Drinking Water Standards Select portions of this section (i.e., Review of Federal Legislation, State and Local Regulations, Key Compliance Requirements, Key Terms and Definitions, Typical Records to Review, Typical Physical Features to Inspect, and the Checklist) have been reviewed by USEPA personnel from the Office of Enforcement and Compliance Assurance (OECA) and USEPA's Office of General Counsel. USEPA's comments and suggestions for changes have been incorporated in this version of the TEAM Guide. USEPA did not review all portions of this section. USEPA also did not review and comment on items pertaining to federal Executive Orders, DOT regulations, OSHA regulations or any other area outside of Title 40 of the Code of Federal Regulations. Portions which have been added or revised as a result of this review are identified as either being reviewed, revised or added in March 2000, for example [Added March 2000]. 4 - 23 Hazardous Waste 4 - 24 Hazardous Waste COMPLIANCE CATEGORY HAZARDOUS WASTE MANAGEMENT U.S. TEAM Guide REGULATORY REQUIREMENTS HW.1 ALL FEDERAL FACILITIES REVIEWER CHECKS March 2001 (NOTE: When conducting the assessment, be aware of possible pollution prevention opportunities in this section and report them to the individual responsible for assessing pollution prevention.) HW.1.1.US. The current status of any ongoing or unresolved consent orders, compliance agreements, notices of violation (NOVs), interagency agreements, or equivalent state enforcement actions is required to be examined (a finding under this checklist item will have the enforcement action/ identifying information as the citation). Determine if noncompliance issues have been resolved by reviewing a copy of the previous report, consent orders, compliance agreements, NOVs, interagency agreements, or equivalent state enforcement actions. HW.1.2.US. Specific persons should be designated responsible for areas where hazardous waste is stored for all sizes of generators and TSDFs, and the precise nature of their responsibilities should be specified (MP). Verify that specific individuals have been designated in writing responsible for hazardous waste storage areas. Verify that the individuals designated responsible for hazardous waste storage areas are aware of the precise nature of their responsibilities. 4 - 25 Hazardous Waste 4 - 26 Hazardous Waste COMPLIANCE CATEGORY HAZARDOUS WASTE MANAGEMENT U.S. TEAM Guide REGULATORY REQUIREMENTS REVIEWER CHECKS March 2001 HW.2 MISSING CHECKLIST ITEMS HW.2.1.US. Facilities are required to comply with all applicable Federal regulatory requirements not contained in this check list (a finding under this checklist item will have the citation of the applied regulation as a basis of finding). Determine if any new regulations have been issued since the finalization of TEAM. Determine if the facility has activities or facilities that are regulated but not addressed in this checklist. Verify that the facility is in compliance with all applicable and newly issued regulations. 4 - 27 Hazardous Waste 4 - 28 Hazardous Waste COMPLIANCE CATEGORY HAZARDOUS WASTE MANAGEMENT U.S. TEAM Guide REGULATORY REQUIREMENTS REVIEWER CHECKS March 2001 HW.10 ALL SIZES OF GENERATORS HW.10.1.US. Generators of solid waste must determine if the wastes are hazardous wastes (40 CFR 261.3, 261.4(b), 261.21 through 261.24, and 262.11) [Revised January 2000]. (NOTE: Determination of whether or not a waste is a hazardous waste can be done through one of the following: knowledge of all the constituents of the waste (MSDSs) and whether it is listed in 40 CFR 261 laboratory analysis knowledge of processes and/or materials used.) (NOTE: Unidentified waste materials and spilled hazardous materials may have to be disposed of as hazardous waste depending on their constituents or characteristics.) (NOTE: Some batteries, pesticides, thermostats, and mercury lamps may be considered universal wastes instead of hazardous wastes and need to be handled according to the requirements in 40 CFR 273 (see the appropriate definitions for clarification.) Discuss with staff how wastes generated are identified and classified. Determine if USEPA criteria were followed for identifying the characteristics of hazardous waste and USEPA’s listed wastes in 40 CFR 261 (see Appendices 4-1, 4-2, 4-3, and 4-5). Determine whether the facility generates, transports, treats, stores, or disposes of any hazardous waste (see Appendices 4-1, 4-2, 4-3, and 4-5 for guidance) and the quantity. (NOTE: The following solid wastes are not considered to be hazardous wastes: household waste solid wastes that are generated by any of the following and are returned to the soils as fertilizers: growing and harvesting of agricultural crops raising of animals, including animal manures mining overburden returned to the mine site fly ash waste, bottom ash waste, and flue gas emission control waste generated primarily from the combustion of coal or other fossil fuels except for facilities that burn hazardous waste drilling fluids, produced waters, and other wastes affiliated with the explorations, development, or production of crude oil, natural gas, or geothermal energy wastes that fail the test for the toxicity characteristic because chromium is present or are listed in Subpart D because of the presence of chromium, that do not fail the test for toxicity characteristics for any other constituent or are 4 - 29 Hazardous Waste COMPLIANCE CATEGORY HAZARDOUS WASTE MANAGEMENT U.S. TEAM Guide REGULATORY REQUIREMENTS REVIEWER CHECKS March 2001 not listed due to the presence of any other constituent, and that do not fail the test for other characteristics (see 40 CFR 261.4(b) for a listing of types of industries generating this type of waste that receive exclusions) solid waste from the extraction, beneficiation, and processing of ores and minerals (including coal, phosphate rock, and overburden) from the mining of uranium ore (NOTE: There is an exception to this for facilities that burn or process hazardous waste.) cement kiln dust waste, except for facilities that burn or process hazardous waste solid waste that consists of discarded arsenic-treated wood or wood products that fail the test for toxicity characteristics for hazardous waste codes D004 through D017 and that is not a hazardous waste for any other reason if the waste is generated by persons who utilize the arsenic-treated wood and wood products for those materials’ intended end use petroleum contaminated media and debris that fail the test for toxicity characteristics (hazardous waste codes D018 through D043 only) and are required to meet the corrective action regulations under 40 CFR 280 (see the section titled Storage Tank Management) used chlorofluorocarbon refrigerants from totally enclosed heat transfer equipment, including mobile air-conditioning systems, mobile refrigeration and commercial and industrial air-conditioning and refrigeration systems that use chlorofluorocarbons as the heat transfer fluid in a refrigeration cycle, provided that the refrigerant is reclaimed for further use non-terne plated used oil filters that are not mixed with a listed hazardous waste if these oil filters have been gravity hot-drained using one of the following methods: puncturing the filter anti-drain back valve or the filter dome end and hotdraining hot-draining and crushing dismantling and hot-draining any other equivalent hot-draining method that will remove used oil used oil re-refining distillation bottoms that are used as feedstock to manufacture asphalt products leachate or gas condensate collected from landfills where certain solid wastes have been disposed, provided that: the solid wastes disposed would meet one or more of the listing descriptions for Hazardous Waste Codes K169, K170, K171, and K172 if these wastes had been generated after 8 February 1999 the solid wastes were disposed prior to the effective date of the listing the leachate or gas condensate do not exhibit any characteristic of hazardous waste nor are derived from any other listed hazardous waste discharge of the leachate or gas condensate, including leachate or gas condensate transferred from the landfill to a POTW by truck, rail, or dedicated pipe, is subject to regulation under sections 307(b) or 402 of the CWA. (NOTE: After 13 February 2001, leachate or gas condensate will no longer be 4 - 30 Hazardous Waste COMPLIANCE CATEGORY HAZARDOUS WASTE MANAGEMENT U.S. TEAM Guide REGULATORY REQUIREMENTS REVIEWER CHECKS March 2001 exempt if it is stored or managed in a surface impoundment prior to discharge. There is one exception: if the surface impoundment is used to temporarily store leachate or gas condensate in response to an emergency situation (e.g., shutdown of wastewater treatment system), provided the impoundment has a double liner, and provided the leachate or gas condensate is removed from the impoundment and continues to be managed in compliance after the emergency ends.) Verify that listed wastes are tested for reactivity, corrosivity, ignitability, and toxicity characteristics. Verify that all data used for determination, including quality assurance data, is maintained and kept available for reference or inspection. HW.10.2.US. Areas where containers of hazardous waste are stored should have secondary containment (MP). Verify that the areas where containers of hazardous waste are stored have secondary containment. HW.10.3.US. Facilities which claim that a particular material is not a solid waste or is conditionally exempt from regulation as a hazardous waste are required to provide specific documentation (40 CFR 261.2(f)) [February 1995]. Determine if the facility has any waste that are typically handled as hazardous waste that it claims are exempt. Verify that, for these wastes, the facility can demonstrate that there is a known market or disposition for the material and that they meet the terms of the exclusion or exemption. Verify that documentation is provided that indicates the material is not a waste, or is exempt from regulation. (NOTE: One example of documentation are contracts showing that a second person uses the material as an ingredient in a production process.) Verify that, if the facility is claiming to recycle material, the equipment for the recycling is actually at the facility and in working order. 4 - 31 Hazardous Waste 4 - 32 Hazardous Waste COMPLIANCE CATEGORY HAZARDOUS WASTE MANAGEMENT U.S. TEAM Guide REGULATORY REQUIREMENTS REVIEWER CHECKS March 2001 HW.15 CONDITIONALLY EXEMPT SMALL QUANTITY GENERATORS (CESQGs) HW.15.1.US. Generators of no more than 100 kg/mo [approx. 220 lb/mo] of hazardous waste may qualify as CESQGs when they meet specific requirements (40 CFR 261.5) [Revised June 1998]. Verify that the following quantity and storage limitations are met: no more than 100 kg [ 220 lb] of hazardous waste is generated in a calendar month total onsite accumulation does not exceed more than 1000 kg [ 2205 lb] of hazardous waste no more than 1 kg [ 2 lb] of acute hazardous waste (see Appendix 4-5) is generated in a calendar month no more than a total of 100 kg [ 220 lb] of any residue or contaminated soil, waste, or other debris resulting from the cleanup of any acute wastes in a calendar month is generated. (NOTE: When making quantity determinations, all hazardous waste generated must be included except hazardous waste that is: exempt from regulation under 40 CFR 261.4(c) through (f), 261.6(a)(3), 261.7(a)(1), or 261.8 managed immediately upon generation only in onsite elementary neutralization units, wastewater treatment units, or totally enclosed treatment facilities recycled, without prior storage or accumulation, in an onsite process is used oil managed under 40 CFR 261.6(a)(4) and 279 universal waste managed under 40 CFR 273.) Verify that wastes are either treated or disposed of in an onsite facility or delivered to an offsite TSDF, either of which is one of the following: permitted in interim status authorized to manage hazardous waste by a state with an approved hazardous waste management program permitted, licensed, or registered by a state to manage municipal or industrial solid waste a facility that does one of the following: beneficially uses or reuses, or legitimately recycles or reclaims, its waste treats waste prior to beneficial use or reuse, or legitimate recycling or reclamation a universal waste handler or destination facility for universal waste. (NOTE: If a hazardous waste generator meets the requirements for being a CESQG, they are not required to meet any of the standards outlined in 40 CFR 4 - 33 Hazardous Waste COMPLIANCE CATEGORY HAZARDOUS WASTE MANAGEMENT U.S. TEAM Guide REGULATORY REQUIREMENTS REVIEWER CHECKS March 2001 262 through 266, (except 262.11), 268, and 270.) (NOTE: If a CESQG mixes its waste with used oil, the mixture is subject to the requirements in Subpart G, 40 CFR 279 if the mixture is destined to be burned for energy recovery.) (NOTE: Quantities of acute hazardous waste, greater than listed amounts, are required to be handled according to the standards in 40 CFR 262 through 266, 268, 270, and 124.) (NOTE: Even though a CESQG is not legally required to use a manifest or obtain a hazardous waste identification number, many hazardous waste haulers will not transport hazardous waste from a facility without a manifest or identification number.) HW.15.2.US. CESQG personnel who handle hazardous waste should meet certain training requirements (MP). Verify that the training program is directed by a person trained in hazardous waste management procedures. Verify that the training program includes the following: response to fire or explosion response to leaks or spills waste turn-in procedures identification of hazardous wastes container use, marking, labeling, and onsite transportation. Verify that new employee training is completed within 6 mo of employment. Verify that new employee training is completed within 6 mo of employment. Verify that an annual review of initial training is provided. Verify that employees do not work unsupervised until training is completed. Verify specifically that accumulation point managers and hazardous waste handlers have been trained. HW.15.3.US. Training records must be maintained for all CESQG staff who manage hazardous waste (MP). Examine training records and verify they include the following: job title and description for each employee by name written description of how much training each position will obtain documentation of training received by name. Determine if training records are retained for 3 yr after employment terminates at 4 - 34 Hazardous Waste COMPLIANCE CATEGORY HAZARDOUS WASTE MANAGEMENT U.S. TEAM Guide REGULATORY REQUIREMENTS REVIEWER CHECKS March 2001 the facility or until closure of the facility. HW.15.4.US. Empty containers at CESQGs previously holding hazardous wastes must meet the regulatory definition of empty before they are exempted from hazardous waste requirements (40 CFR 261.7). Verify that, for containers or inner liners holding hazardous wastes: wastes are removed that can be removed using common practices and no more than 2.5 cm [1 in.] of residue remains if the container is less than or equal to 110 gal, no more than 3 percent by weight of total container capacity remains when the container is greater than 110 gal, no more than 0.3 percent by weight of the total container capacity remains. Verify that, for containers which hold a compressed gas, the pressure in the container approaches atmosphere. Verify that, for containers or inner liners which held an acute hazardous waste listed in Appendix 4-5, that one of the following is done: it is triple rinsed it is cleaned by another method identified through the literature or testing as achieving equivalent removal the inner liner is removed. HW.15.5.US. Containers at CESQGs should be managed in accordance with specific management practices (MP). Verify the following by inspecting storage areas: HW.15.6.US. Containers of hazardous waste should be kept in designated storage areas at CESQGs (MP). Verify that all hazardous waste containers are identified and stored in appropriate areas. containers are not stored more than two high and have pallets between them containers of highly flammable wastes are electrically grounded (check for clips and wires and make sure wires lead to ground rod or system) at least 3 ft of aisle space is provided between rows of containers. (NOTE: Any unidentified contents of solid waste containers and/or containers not in designated storage areas must be tested to determine if solid or hazardous waste requirements apply.) 4 - 35 Hazardous Waste 4 - 36 Hazardous Waste COMPLIANCE CATEGORY HAZARDOUS WASTE MANAGEMENT U.S. TEAM Guide REGULATORY REQUIREMENTS REVIEWER CHECKS March 2001 SMALL QUANTITY GENERATORS (SQGs) HW.20 General HW.20.1.US. Generators of more than 100 kg [approx. 220 lb] but less than 1000 kg [approx. 2204 lb] of hazardous waste per month may qualify as an SQG that can accumulate hazardous waste onsite for 180 days without a permit if specific conditions are met (40 CFR 262.34(d)(1), 262.34(d)(4), 262.34(e), and 262.34(f)). Inspect containers, storage, and records. Verify that no more than 1000 kg [approx. 2204 lb] of hazardous waste is generated in any month. Verify that the onsite accumulation time does not exceed 180 days. (NOTE: For an SQG, the accumulation start date begins when the first waste is poured/placed into the waste container, except for at satellite accumulation points.) (NOTE: The 180-day time period is extended to 270 days if the waste must be transported more than 200 mi to a TSDF. This extension does not apply if a TSDF is available within 200 mi and the SQG chooses to transport the waste to a farther away TSDF.) Verify that no more than 6000 kg [approx. 13,227 lb] is allowed to accumulate. Verify that containers are marked with the date accumulation began and the words HAZARDOUS WASTE. Verify that the containers and the areas at which containers are stored meet the requirements outlined in the subsections pertaining to SQGs. (NOTE: When an SQG exceeds the quantity generation or amount accumulation, it becomes subject to either Generator or TSDF requirements. When an SQG exceeds the storage time limitation, the SQG becomes subject to all storage facility and permitting requirements.) HW.20.2.US. SQGs that generate, transport, or handle hazardous wastes must obtain an USEPA identification number (40 CFR 262.12(a), 262.1(b), and 265.11). Examine documentation from USEPA for the generator identification number. HW.20.3.US. An SQG must not offer its hazardous waste to transporters or to TSDFs that have not received an Verify that all transporters of hazardous waste of TSDFs have an USEPA identification number by examining records pertaining to disposal contract awards. Verify that, correct identification number is used on all appropriate documentation (i.e., manifests). 4 - 37 Hazardous Waste COMPLIANCE CATEGORY HAZARDOUS WASTE MANAGEMENT U.S. TEAM Guide REGULATORY REQUIREMENTS REVIEWER CHECKS March 2001 USEPA identification number (40 CFR 262.12(c)). HW.20.4.US. SQGs of hazardous waste are required to use manifests and keep records of hazardous waste activity (40 CFR 262.20, 262.40(a), 262.40(c), 262.40(d), 262.42(b), 262.43, and 262.44). Verify that signed copies of returned manifests are kept for 3 yr. Verify that exception reports were submitted to the USEPA Regional Administrator when a signed manifest copy was not received within 60 days of the waste being accepted by the initial transporter. Verify that exception reports are kept for at least 3 yr. Verify that records of test results, waste analyses, and determinations are kept for 3 yr. (NOTE: The requirement to prepare a manifest does not apply if: the waste is reclaimed under contractual agreement and: the type of waste and frequency of shipments are specified in the agreement the vehicle used to transport the waste to the recycling facility and to deliver regenerated material back to the generator is owned and operated by the reclaimer the generator maintains a copy of the reclamation agreement for at least 3 yr after termination of the agreement.) (NOTE: Period of retention of records is extended automatically during the course of any unresolved enforcement action or as requested by the USEPA administrator.) HW.20.5.US. SQGs are required to have an emergency coordinator and emergency response planning (40 CFR 262.34(d)(5)). Verify that there is an emergency coordinator. Verify that the following emergency information is posted next to the telephone: name and telephone number of emergency coordinator location of fire extinguishers and spill control materials location of fire alarms (if present) telephone number of fire department. Verify that waste handlers are familiar with waste handling and emergency procedures. 4 - 38 Hazardous Waste COMPLIANCE CATEGORY HAZARDOUS WASTE MANAGEMENT U.S. TEAM Guide REGULATORY REQUIREMENTS REVIEWER CHECKS March 2001 SQGs HW.25 Personnel Training HW.25.1.US. SQG personnel are required to be thoroughly familiar with proper waste handling and emergency procedures (40 CFR 262.34(d)(5)(iii)) [February 1995]. Verify that personnel are thoroughly familiar with waste handling and emergency procedures relevant to their responsibilities during normal facility operation and emergencies. HW.25.2.US. Training records should be maintained for all SQG staff who manage hazardous waste (MP). Examine training records and verify that they include the following: job title and description for each employee by name written description of how much training each position will obtain documentation of training received by name. Determine if training records are retained for 3 yr after employment terminates at the SQG or until closure of the SQG. 4 - 39 Hazardous Waste 4 - 40 Hazardous Waste COMPLIANCE CATEGORY HAZARDOUS WASTE MANAGEMENT U.S. TEAM Guide REGULATORY REQUIREMENTS REVIEWER CHECKS March 2001 SQGs HW.30 Containers HW.30.1.US. Empty containers at SQGs previously holding hazardous wastes must meet the regulatory definition of empty before they are exempted from hazardous waste requirements (40 CFR 261.7). Verify that, for containers or inner liners holding hazardous waste: all wastes are removed that can be removed using common practices and no more than 2.5 cm [1 in.] of residue remains if the container is less than or equal to 110 gal, no more than 3 percent by weight of total container capacity remains when the container is greater than 110 gal, no more than 0.3 percent by weight of the total container capacity remains. Verify that, for containers which held a compressed gas, the pressure in the container approaches atmosphere. Verify that, for containers or inner liners which held an acute hazardous waste listed in Appendix 4-5, one of the following is done: it is triple rinsed it is cleaned by another method identified through the literature or testing as achieving equivalent removal the inner liner is removed. HW.30.2.US. Containers used to store hazardous waste at SQGs must be in good condition and not leaking (40 CFR 262.34(d)(2) and 265.171). Verify that containers are not leaking, bulging, rusting, damaged, or dented. HW.30.3.US. Containers used at SQGs must be made of or lined with materials compatible with the waste stored in them (40 CFR 262.34(d)(2) and 265.172). Verify that containers are compatible with waste, in particular, check that strong caustics and acids are not stored in metal drums. HW.30.4.US. Containers of hazardous waste at SQGs must be closed during storage and handled in a safe manner (40 CFR 262.34(d)(2) and Verify that containers are closed, except when it is necessary to add or remove waste (check bungs on drums). Verify that waste is transferred to a new container or managed in another appropriate manner when necessary. Verify that handling and storage practices do not cause damage to the containers 4 - 41 Hazardous Waste COMPLIANCE CATEGORY HAZARDOUS WASTE MANAGEMENT U.S. TEAM Guide REGULATORY REQUIREMENTS REVIEWER CHECKS March 2001 265.173). or cause them to leak. HW.30.5.US. The handling of incompatible wastes, or incompatible wastes and materials in containers at SQGs, must comply with safe management practices (40 CFR 262.34(d)(2) and 265.177). Verify that incompatible wastes or incompatible wastes and materials are not placed in the same containers unless it is done so that it does not: generate extreme heat or pressure, fire, or explosion, or violent reaction produce uncontrolled toxic mists, fumes, dusts, or gases in sufficient quantities to threaten human health produce uncontrolled flammable fumes or gases in sufficient quantities to pose a risk of fire or explosions damage the structural integrity of the device or facility by any other like means threaten human health. (NOTE: Incompatible wastes as listed in Appendix 4-6 should not be placed in the same drum.) Verify that hazardous wastes are not placed in an unwashed container that previously held an incompatible waste or material. Verify that containers holding hazardous wastes incompatible with wastes stored nearby in other containers, open tanks, piles, or surface impoundments are separated or protected from each other by a dike, berm, wall, or other device. HW.30.6.US. Containers of hazardous waste at SQGs should be managed in accordance with specific management practices (MP). Determine the following by inspecting containers and storage areas: containers are not stored more than two high and have pallets between them containers of ignitable wastes are electrically grounded (check for clips and wires and make sure wires lead to ground rod or system) at least 3 ft of aisle space is provided between rows of containers. 4 - 42 Hazardous Waste COMPLIANCE CATEGORY HAZARDOUS WASTE MANAGEMENT U.S. TEAM Guide REGULATORY REQUIREMENTS REVIEWER CHECKS March 2001 SQGs HW.35 Satellite Accumulation Points HW.35.1.US. All SQGs may accumulate as much as 55 gal of hazardous waste or 1 qt of acutely hazardous waste in containers at or near any point of initial generation without complying with the requirements for onsite storage if specific standards are met (40 CFR 262.34(c)). (NOTE: This type of storage is often referred to as a satellite accumulation point.) Verify that the satellite accumulation point is at or near the point of generation and is under the control of the operator of the waste generating process. Verify that the containers are in good condition and are compatible with the waste stored in them and that the containers are kept closed except when waste is being added or removed. Verify that the containers are marked HAZARDOUS WASTE or other words that identify contents. (NOTE: See Appendices 4-1, 4-2, 4-3, and 4-5 for guidance on characteristic and listed hazardous wastes.) Verify that, when waste is accumulated in excess of quantity limitations, the following actions are taken by interviewing the shop managers: the excess container is marked with the date the excess amount began accumulating the excess waste is transferred to a 180-day or permitted storage area within 3 days. 4 - 43 Hazardous Waste 4 - 44 Hazardous Waste COMPLIANCE CATEGORY HAZARDOUS WASTE MANAGEMENT U.S. TEAM Guide REGULATORY REQUIREMENTS REVIEWER CHECKS March 2001 SQGs HW.40 Container Storage Areas HW.40.1.US. Containers of hazardous waste at SQGs should be kept in storage areas designated in the management plan (MP). Verify that all containers are identified and stored in appropriate areas. HW.40.2.US. SQG storage areas for hazardous waste must be designed, constructed, maintained, and operated to minimize the possibility of a fire, explosion, or any unplanned release of hazardous waste (40 CFR 262.34(d)(4) and 265.30 through 265.37). Determine if the following required equipment is easily accessible and in working condition by inspecting the SQG storage areas: (NOTE: Any unidentified contents of solid waste containers and/or containers not in designated storage areas must be tested to determine if solid or hazardous waste requirements apply.) internal communications or alarm system capable of providing immediate emergency instruction to personnel a telephone or hand-held two-way radio portable fire extinguishers and special extinguishing equipment (foam, inert gas, or dry chemicals) spill control equipment decontamination equipment fire hydrants or other source of water (reservoir, storage tank, etc.) with adequate volume and pressure, foam producing equipment, automatic sprinklers, or water spray systems. Determine if equipment is tested and maintained as necessary to ensure proper operation in an emergency. Verify that sufficient aisle space is maintained to allow unobstructed movement of personnel, fire protection equipment, spill control equipment, and decontamination equipment to any area of the operation. Verify that police, fire departments, and emergency response teams are familiar with the layout of the SQG, properties of the waste being handled, and general operations as appropriate for the type of waste and potential need for such services. Verify that the hospital is familiar with the site and the types of injuries that could result in an emergency as appropriate for the type of waste and potential need for such services. HW.40.3.US. SQGs must Verify that inspections are conducted at least weekly to look for leaking containers 4 - 45 Hazardous Waste COMPLIANCE CATEGORY HAZARDOUS WASTE MANAGEMENT U.S. TEAM Guide REGULATORY REQUIREMENTS conduct weekly inspections of container storage areas (40 CFR 262.34(d)(2) and 265.174). REVIEWER CHECKS March 2001 and signs of deterioration of containers. 4 - 46 Hazardous Waste COMPLIANCE CATEGORY HAZARDOUS WASTE MANAGEMENT U.S. TEAM Guide REGULATORY REQUIREMENTS SQGs REVIEWER CHECKS March 2001 (NOTE: See Appendix 4-7 for a summary of recordkeeping and notification requirements.) HW.45 Disposal of Restricted Wastes HW.45.1.US. SQGs must test their wastes or use process knowledge to determine if they are restricted from land disposal (40 CFR 268.7(a)(1)) [Revised June 1998]. Determine whether the SQG determines if wastes have to be treated prior to disposal. (NOTE: Determination can be made by testing the waste or using knowledge of the waste.) Determine if land disposal restricted wastes are generated by reviewing test results (see Appendix 4-8). HW.45.2.US. When an SQG is managing a waste or soil that does not meet treatment standards, a written notice must be issued to the TSDF stating the appropriate treatment standards and prohibition levels (40 CFR 268.7(a)(2), 268.7(a)(3) and 268.7(a)(10)) [Revised January 2000]. Verify that, for waste or soil that does not meet the applicable treatment standards or exceeds the applicable prohibition levels, the notice is issued and includes: the USEPA hazardous waste number waste constituents that the treater will monitor, if monitoring will not include all regulated constituents, for wastes F001 - F005, F039, D001, D002, D003, and D012 - D043 whether the waste is a nonwastewater or wastewater the subcategory of the waste for hazardous debris, the contaminants subject to treatment, and indication that the contaminants are being treated plus: the USEPA hazardous waste number waste constituents that the treater will monitor, if monitoring will not include all regulated constituents, for wastes F001 - F005, F039, D001, D002, D003, and D012 - D043 whether the waste is a nonwastewater or wastewater the subcategory of the waste a certification statement for contaminated soil. Verify that, for waste or contaminated soil that meets the treatment standard at the original point of generation, the notice includes: the USEPA hazardous waste number waste constituents that the treater will monitor, if monitoring will not include all regulated constituents, for wastes F001 - F005, F039, D001, D002, D003, and D012 - D043 whether the waste is a nonwastewater or wastewater the subcategory of the waste the manifest number associated with the shipment the waste analysis data, when available 4 - 47 Hazardous Waste COMPLIANCE CATEGORY HAZARDOUS WASTE MANAGEMENT U.S. TEAM Guide REGULATORY REQUIREMENTS REVIEWER CHECKS March 2001 the signature of an authorized representative certifying that the waste complies with the treatment standards of 40 CFR 268. Verity that, for waste or contaminated soil that meets the treatment standard at the original point of generation, if the waste changes, the generator sends a new notice and certification to the receiving facility and places a copy in their files. (NOTE: Generators of hazardous debris excluded from the definition of hazardous waste under 40 CFR 261.3(f) are not subject to the requirements for waste or contaminated soil that meets the treatment standard at the original point of generation.) Verify that, for restricted waste that is subject to an exemption from a prohibition of the type of land disposal used, the notice states that the waste is not prohibited from land disposal and includes: the USEPA hazardous waste number waste constituents that the treater will monitor, if monitoring will not include all regulated constituents, for wastes F001 - F005, F039, D001, D002, D003, and D012 - D043 whether the waste is a nonwastewater or wastewater the subcategory of the waste the manifest number associated with the shipment the waste analysis data, when available for hazardous debris, the contaminants subject to treatment, and indication that the contaminants are being treated plus: the USEPA hazardous waste number waste constituents that the treater will monitor, if monitoring will not include all regulated constituents, for wastes F001 - F005, F039, D001, D002, D003, and D012 - D043 whether the waste is a nonwastewater or wastewater the subcategory of the waste. (NOTE: SQGs with tolling agreements are required to comply with notification and certification requirements for the initial shipment of waste subject to the agreement. The SQG will retain an onsite copy of the notification and certification along with the tolling agreement for at least 3 yr after the termination or expiration of the agreement.) HW.45.3.US. SQGs that are managing hazardous wastes in tanks, containers, or containment buildings and treating the waste to meet applicable treatment standards must develop and follow a Verify that the plan describes the procedures the generator will carry out to comply with treatment standards. (NOTE: SQGs treating hazardous debris under the alternative treatment standards in Table 1 of 40 CFR 268.7(a)(4) are not required to conduct waste analysis.) 4 - 48 Hazardous Waste COMPLIANCE CATEGORY HAZARDOUS WASTE MANAGEMENT U.S. TEAM Guide REGULATORY REQUIREMENTS written waste analysis plan (40 CFR 268.7(a)(5) and 268.7(a)(10)) [Citation Revised June 1998]. REVIEWER CHECKS March 2001 Verify that the plan is kept onsite and: the plan is based on a detailed chemical and physical analysis of representative sample of the prohibited waste being treated contains all information necessary to treat the wastes in accordance with regulatory requirements, including the selected testing frequency the plan is filed with the USEPA Regional Administrator or state-authorized official at least 30 days prior to the treatment activity, with delivery verified. (NOTE: SQGs with tolling agreements are required to comply with notification and certification requirements for the initial shipment of waste subject to the agreement. The SQG will retain an onsite copy of the notification and certification along with the tolling agreement for at least 3 yr after the termination or expiration of the agreement.) HW.45.4.US. SQGs are required to keep specific documents pertaining to restricted wastes onsite (40 CFR 268.7(a)(4), 268.7(a)(6), 268.7(a)(7) and 268.7(a)(10))[Revised June 1998]. Verify that, if generator knowledge is used to determine whether a waste or contaminated soil meets land disposal restriction requirements, the supporting data used in making this determination is retained onsite in the operating files. Verify that, when it is determined whether a waste or contaminated soil is restricted using appropriate test methods, the waste analysis data are retained onsite in the files. Verify that, when managing a prohibited waste that is excluded from the definition of a hazardous waste or solid waste or exempt from RCRA Subtitle C, a one-time notice is placed in the files stating that the generated waste is excluded. Verify that a copy of all notices, certifications, demonstrations, waste analysis data, and other documentation is kept for at least 3 yr from the date the waste was last sent to onsite or offsite treatment, storage, or disposal. Verify that SQGs with a tolling agreement retain the agreement and copies of notification and certification for at least 3 yr after the agreement expires. HW.45.5.US. The storage of hazardous waste that is restricted from land disposal is not allowed unless specific conditions are met (40 CFR 268.50). Verify that land disposal restricted waste is not stored at the SQG unless the SQG is storing the wastes in tanks, containers, or containment buildings onsite only for the purpose of accumulating enough hazardous waste to facilitate proper recovery, treatment, or disposal and all appropriate standards for containers, tanks, and containment buildings are met. Verify that transporters do not store manifested shipments of land disposal restricted wastes for more than 10 days. (NOTE: The prohibition on storage does not apply to hazardous wastes that have 4 - 49 Hazardous Waste COMPLIANCE CATEGORY HAZARDOUS WASTE MANAGEMENT U.S. TEAM Guide REGULATORY REQUIREMENTS REVIEWER CHECKS March 2001 met treatment standards.) Verify that liquid hazardous wastes containing PCBs at concentrations greater than 50 ppm are stored at a site that meets the requirements of 40 CFR 761.65(b) (see the section titled Toxic Substances Management) and is removed from storage within 1 yr of the date it was first placed into storage. 4 - 50 Hazardous Waste COMPLIANCE CATEGORY HAZARDOUS WASTE MANAGEMENT U.S. TEAM Guide REGULATORY REQUIREMENTS REVIEWER CHECKS March 2001 GENERATORS HW.55 General HW.55.1.US. Generators may accumulate hazardous waste onsite for 90 days or less without a permit or interim status provided they meet certain conditions (40 CFR 262.34(a)(2), 262.34(a)(3), and 262.34(b)). Inspect each accumulation point and interview the accumulation point manager. Verify that: the recorded start date indicates no container or tank has been accumulating a hazardous waste longer than 90 days (unless granted a 30-day extension) each container and tank is labeled or marked clearly with the words HAZARDOUS WASTE or other appropriate words clearly indicating the contents the accumulation start date is indicated. (NOTE: For a Generator, the accumulation start date begins when the first waste is poured/placed into the waste container, except for at satellite accumulation points.) (NOTE: A generator who meets these standards is exempt from meeting the closure requirements outlined in 40 CFR 265.110 through 265.156, except for 265.111 and 265.114.) (NOTE: A generator who accumulates hazardous waste for more than 90 days (without an extension) is subject to all TSDF and permitting requirements.) HW.55.2.US. A generator that generates, transports, or handles hazardous wastes must obtain an USEPA identification number (40 CFR 262.12(a), 262.12(b), 264.11, and 265.11). Examine documentation from USEPA for the generator identification number. HW.55.3.US. Generators must not offer their waste to transporters or TSDFs that have not received an USEPA identification number (40 CFR 262.12(c)). Verify that all transporters of hazardous wastes or TSDFs used by the generator have an USEPA identification number by examining records pertaining to disposal contract awards. Verify that the correct identification number is used on all appropriate documentation (i.e., manifests). 4 - 51 Hazardous Waste COMPLIANCE CATEGORY HAZARDOUS WASTE MANAGEMENT U.S. TEAM Guide REGULATORY REQUIREMENTS REVIEWER CHECKS March 2001 HW.55.4.US. Generators of hazardous waste must submit a biennial report to the Regional Administrator by 1 March of even numbered years (40 CFR 262.40(b) and 262.41(a)). Verify that the biennial report (USEPA Form 8700-13A) is complete and was submitted in a timely manner. Verify that copies are kept for 3 yr. (NOTE: Reporting for exports of hazardous waste is not required.) (NOTE: This may not apply if an annual report was submitted to the state depending on the state requirements.) (NOTE: Periods of retention of records may be extended automatically during the course of any unresolved enforcement action or at the request of the USEPA administrator.) HW.55.5.US. Generators are required to use manifests, file manifest exception reports, and maintain records (40 CFR 262.40(b), 262.40(d), and 262.42(a)). Verify that manifests are used when shipping the waste offsite. Verify that exception reports are filed with the USEPA Regional Administrator if a copy of the manifest is not received within 45 days after the waste is accepted by the initial transporter. Verify that manifests and exception reports are kept for 3 yr. (NOTE: Periods of retention for records may be extended automatically during the course of any unresolved enforcement action or at the request of the USEPA administrator.) HW.55.6.US. Generators are required to keep records of waste analyses, tests, and waste determinations (40 CFR 262.40(c)). Verify that the appropriate records are kept for 3 yr from the date the waste was last sent to the onsite or offsite TSDF. HW.55.7.US. Checklist item deleted [Deleted December 1997]. Checklist item deleted because it is a duplicate of HW.80.4.US. (NOTE: Periods of retention for reports may be extended automatically during the course of any unresolved enforcement action or at the request of the USEPA administrator. 4 - 52 Hazardous Waste COMPLIANCE CATEGORY HAZARDOUS WASTE MANAGEMENT U.S. TEAM Guide REGULATORY REQUIREMENTS REVIEWER CHECKS March 2001 GENERATORS HW.60 Personnel Training HW.60.1.US. Personnel who handle hazardous waste must meet certain training requirements (40 CFR 262.34(a)(4) and 265.16(a) through 265.16(c)). Verify that the training program is directed by a person trained in hazardous waste management procedures. Verify that the training program includes the following: contingency plan implementation (emergency procedures, equipment, and systems) key parameters for automatic waste feed cut-off system procedures for using, inspecting, and repairing emergency and monitoring equipment operation of communications and alarm systems response to fire or explosion response to groundwater contamination incidents. Verify that new employee employment/assignment. training is completed within 6 mo of Verify that an annual review of initial training is provided. Verify that employees do not work unsupervised until training is completed. Verify specifically that accumulation point managers and hazardous waste handlers have been trained. HW.60.2.US. Training records must be maintained for all staff who manage hazardous waste (40 CFR 262.34(a)(4), 265.16(d), and 265.16(e)). Verify that training records include the following: job title and description for each employee by name written description of how much training each position will obtain documentation of training received by name. Determine if training records are retained for 3 yr after employment at the LQG terminates or until the closure of the site. 4 - 53 Hazardous Waste 4 - 54 Hazardous Waste COMPLIANCE CATEGORY HAZARDOUS WASTE MANAGEMENT U.S. TEAM Guide REGULATORY REQUIREMENTS REVIEWER CHECKS March 2001 GENERATORS HW.65 Contingency Plans and Emergency Coordinators HW.65.1.US. Generators must have a contingency plan (40 CFR 262.34(a)(4) and 265.50 through 265.54). (NOTE: Generating activities may be addressed in the Spill Prevention, Control, and Countermeasure SPCC) plan or other emergency plan; or, if none exists, in a separate contingency plan.) Verify that the contingency plan is designed to minimize hazards to human health or the environment from fires, explosions, or any unplanned sudden or nonsudden release of hazardous waste or hazardous waste constituents. Verify that the plan includes the following: a description of actions to be taken during an emergency a description of arrangements made with local police departments, fire departments, hospitals, contractors, and state and local emergency response teams as appropriate names, addresses, and phone numbers of all persons qualified to act as emergency coordinator a list of all emergency equipment and where this equipment is required, located, and what it looks like an evacuation plan for personnel where there is a possibility evacuation would be needed. Verify that copies of the contingency plan are maintained at the generation sites and storage areas and also have been submitted to organizations which may be called upon to provide emergency services. Verify that the contingency plan is routinely reviewed and updated, especially when a new permit is issued, the plan fails in an emergency, the emergency coordinators change, the waste being handled changes, and/or the list of emergency equipment changes. HW.65.2.US. Each generator must have an emergency coordinator on the premises or on call at all times (40 CFR 262.34(a)(4) and 265.55). Verify that, at all times, there is at least one employee on the premises or on call with responsibility for coordinating all emergency response measures. Verify that the emergency coordinator is thoroughly familiar with the LQG, the characteristics of the waste handled, and the provisions of the contingency plan. In addition, verify that the emergency coordinator has the authority to commit the resources needed to carry out the contingency plan. 4 - 55 Hazardous Waste COMPLIANCE CATEGORY HAZARDOUS WASTE MANAGEMENT U.S. TEAM Guide REGULATORY REQUIREMENTS REVIEWER CHECKS March 2001 HW.65.3.US. Emergency coordinators at generators must follow certain emergency procedures whenever there is an imminent or actual emergency situation (40 CFR 262.34(a)(4) and 265.56(a) through 265.56(i)). Verify that the emergency coordinator is required to follow these emergency procedures: HW.65.4.US. Operators must record the time, date, and details of any incident that requires implementing the contingency plan (40 CFR 262.34(a)(4) and 265.56(j)). Determine if incidents have been recorded and corrective actions taken through a review of operating records. immediately activate alarms or communication systems and notify appropriate base, state, and local response parties identify the character, exact source, amount, and a real extent of any released materials assess possible hazards to human health or the environment, including direct and indirect effects (e.g., release of gases, surface runoff from water, or chemicals used to control fire or explosions, etc.) stop processes and operations when necessary to prevent fires. explosions, or further releases collect and contain the released waste remove or isolate containers when necessary monitor for leaks, pressure buildup, gas generation, or ruptures in valves, pipes, or other equipment whenever appropriate provide for treatment, storage, or disposal of recovered waste, contaminated soil, surface water, or other material ensure that no waste which may be incompatible with the released material is treated, stored, or disposed of until cleanup is completed ensure that all emergency equipment is cleaned and fit for its intended use before operations are resumed notify the USEPA and appropriate state and local authorities that the facility is in compliance before operations resume. Verify that written reports have been submitted to the USEPA Regional Administrator within 15 days after the incident. 4 - 56 Hazardous Waste COMPLIANCE CATEGORY HAZARDOUS WASTE MANAGEMENT U.S. TEAM Guide REGULATORY REQUIREMENTS GENERATORS HW.70 Containers HW.70.1.US. Empty containers at generators previously holding hazardous wastes must meet the regulatory definition of empty before they are exempted from hazardous waste requirements (40 CFR 261.7) [May 1997]. REVIEWER CHECKS March 2001 (NOTE: See Appendix 4-8a for guidance on the schedule for implementation of air emissions standards in 40 CFR 265.1080 through 265.1090. Also, in relation to the requirements for air emissions standard, see the definitions of Exempted Hazardous Waste Containers and Surface Impoundments and Exempted Hazardous Waste Management Unit. There are documentation requirements for exempted containers.) Verify that, for containers or inner liners holding hazardous wastes, one of the following is met: wastes are removed that can be removed using common practices and no more than 2.5 cm [1 in.] of residue remains if the container is less than or equal to 110 gal, no more than 3 percent by weight of total container capacity remains when the container is greater than 110 gal, no more than 0.3 percent by weight of the total container capacity remains. Verify that, for containers which held a compressed gas, the pressure in the container approaches atmospheric. (NOTE: Some states require a treatment permit when returning compressed gas cylinders and aerosol cans to atmospheric by puncturing or physically altering the container.) Verify that, for containers or inner liners which held an acute hazardous waste listed in Appendix 4-5, one of the following is done: it is triple rinsed it is cleaned by another method identified through the literature or testing as achieving equivalent removal the inner liner is removed. Verify that the rinsate has been disposed of as necessary according to its properties. HW.70.2.US. Containers used to store hazardous waste at generators must be in good condition and not leaking (40 CFR 262.34(a)(1)(i) and 265.171). Verify that containers are not leaking, bulging, rusting, damaged, or dented. HW.70.3.US. Containers used Verify that containers are compatible with waste, in particular, check that strong Verify that waste is transferred to a new container or managed in another appropriate manner when necessary. 4 - 57 Hazardous Waste COMPLIANCE CATEGORY HAZARDOUS WASTE MANAGEMENT U.S. TEAM Guide REGULATORY REQUIREMENTS REVIEWER CHECKS March 2001 at generators must be made of or lined with materials compatible with the waste stored in them (40 CFR 262.34(a)(1)(i) and 265.172). caustics and acids are not stored in metal drums. HW.70.4.US. Containers at generators must be closed during storage and handled in a safe manner (40 CFR 262.34(a)(1)(i) and 265.173). Verify that containers are closed, except when it is necessary to add or remove waste (check bungs on drums, look for funnels). HW.70.5.US. The handling of incompatible wastes, or incompatible wastes and materials in containers at generators, must comply with safe management practices (40 CFR 262.34(a)(1)(i) and 265.177). Verify that incompatible wastes or incompatible wastes and materials are not placed in the same containers unless it is done so that it does not: Verify that handling and storage practices do not cause damage to the containers or cause them to leak. generate extreme heat or pressure, fire, or explosion, or violent reaction produce uncontrolled toxic mists, fumes, dusts, or gases in sufficient quantities to threaten human health produce uncontrolled flammable fumes or gases in sufficient quantities to pose a risk of fire or explosions damage the structural integrity of the device or facility by any other like means threaten human health or the environment. (NOTE: Incompatible wastes as listed in Appendix 4-6 should not be placed in the same drum.) Verify that hazardous wastes are not placed in an unwashed container that previously held an incompatible waste or material. Verify that containers holding hazardous wastes incompatible with wastes stored nearby in other containers, open tanks, piles, or surface impoundments are separated or protected from each other by a dike, berm, wall, or other device. HW.70.6.US. Containers used to store hazardous waste at generators should be managed in accordance with specific management practices (MP). Verify the following by inspecting container storage areas: HW.70.7.US. Containers with (NOTE: The requirements of 40 CFR 265.1087 do not apply to containers in containers are not stored more than two high and have pallets between them containers of highly flammable wastes are electrically grounded (check for clips and wires and make sure wires lead to ground rod or system) at least 3 ft of aisle space is provided between rows of containers. 4 - 58 Hazardous Waste COMPLIANCE CATEGORY HAZARDOUS WASTE MANAGEMENT U.S. TEAM Guide REGULATORY REQUIREMENTS REVIEWER CHECKS March 2001 design capacities greater than 0.1 m3 [approx. 26 gal] and less than or equal to 0.46 m3 [approx. 122 gal] into which hazardous waste is placed are required to meet specific design and operating standards (40 CFR 262.34(a)(1)(i), 265.178, 265.1087(a) through 265.1087(b)(1)(i), and 265.1087(c)) [December 1996]. which all the hazardous waste entering the container meets one of the following (40 CFR 265.1083(c) [see also the definition for exempted hazardous waste containers and surface impoundments]): the average VO concentration of the hazardous waste at the point of waste origination is less than 500 ppmw the organic content of the hazardous waste has been reduced by an organic destruction or removal process the waste meets the numerical concentration limits for organic hazardous constituents as specified in 40 CFR 268.40 or has been treated by the treatment technology established by the USEPA for the waste in 268.42(a) or an equivalent method.) (NOTE: These requirements do not apply to a container that has a design capacity less than or equal to 0.1 m3 [approx. 26 gal] or to containers of any size at satellite accumulation points (40 CFR 265.1080(b)(2).) (NOTE: Standards for containers used in waste stabilization processes (40 CFR 265.1087(b)(2)) are in checklist item HW.70.9.) Verify that, for containers with a design capacity greater than 0.1 m3 [approx. 26 gal] and less than or equal to 0.46 m3 [approx. 122 gal], air emissions are controlled according to the following Container Level 1 standards: a container that meets applicable U.S. DOT regulations on the packaging of hazardous materials for transportation a container that is equipped with a cover and closure devices that form a continuous barrier over the container openings so that when the cover and closure devices are secured in the closed position there are not visible holes, gaps, or other open spaces into the interior of the container an open-top container in which an organic vapor suppressing barrier is placed on or over the hazardous waste in the container so that no hazardous waste is exposed to the atmosphere. Verify that, when a container using Level 1 standards, other than DOT approved containers, are used, they are equipped with covers and closure devices composed of suitable materials to minimize exposure of the hazardous waste to the atmosphere and to maintain the equipment integrity for as long as it is in service. Verify that, whenever waste is in a container using Level 1 controls, covers, and closure devices are installed and closure devices are secured and maintained in the closed position except as follows: opening of a closure device or cover is allowed for adding waste or other material to the container as follows: when the container is filled to the intended final level in one continuous operation, the closure devices is secured in the closed position and the covers installed at the conclusion of the filling operation when discrete batches or quantities of material are added intermittently to 4 - 59 Hazardous Waste COMPLIANCE CATEGORY HAZARDOUS WASTE MANAGEMENT U.S. TEAM Guide REGULATORY REQUIREMENTS REVIEWER CHECKS March 2001 the container over a period of time, the closure devices are secured in the closed position and covers installed upon either the container being filled to the intended final level, the completion of a batch loading after which no additional material will be added to the container within 15 min, the person performing the loading operation leaving the immediate vicinity of the container, or the shutdown of the process generating the material being added to the container, whichever condition occurs first opening of a closure device or cover is allowed for removing the hazardous waste as follows: in order to meet the requirements for an empty container when discrete quantities or batches of material are removed from the container but the container is not empty, the closure devices will promptly be returned to the closed position and the covers installed upon completion of batch removal after which no additional material will be removed within 15 min or the person performing the unloading leaves the immediate vicinity, whichever condition occurs first opening of a closure device or cover is allowed when access inside the container is needed to perform routine activities other than transfer of hazardous waste opening of a spring loaded, pressure vacuum relief valve, conservation vent, or similar type of pressure relief device which vents to the atmosphere is allowed during normal operations for the purpose of maintain internal container pressure opening of a safety device to avoid unsafe conditions. HW.70.8.US. Containers with design capacities greater than 0.46 m3 [approx. 122 gal] into which hazardous waste is placed are required to meet specific design and operating standards (40 CFR 262.34(a)(1)(i), 265.178, and 265.1087(a) through 265.1087(b)(1)(ii), 265.1087(b)(1)(iii), 265.1087(c), and 265.1087(d)) [December 1996]. (NOTE: The requirements of 40 CFR 265.1087 do not apply to containers in which all the hazardous waste entering the container meets one of the following [see also the definition for exempted hazardous waste containers and surface impoundments] (40 CFR 265.1083(c): the average VO concentration of the hazardous waste at the point of waste origination is less than 500 ppmw the organic content of the hazardous waste has been reduced by an organic destruction or removal process the waste meets the numerical concentration limits for organic hazardous constituents as specified in 40 CFR 268.40 or has been treated by the treatment technology established by the USEPA for the waste in 268.42(a) or an equivalent method.) (NOTE: These requirements do not apply to a container that has a design capacity less than or equal to 0.1 m3 [approx. 26 gal] or to containers of any size at satellite accumulation points (40 CFR 265.1080(b)(2).) (NOTE: Standards for containers used in waste stabilization processes (40 CFR 265.1087(b)(2) are in checklist item HW.70.9.) Verify that, for containers with a design capacity greater than 0.46 m3 [approx. 122 gal] that are not in light material service, air emissions are controlled 4 - 60 Hazardous Waste COMPLIANCE CATEGORY HAZARDOUS WASTE MANAGEMENT U.S. TEAM Guide REGULATORY REQUIREMENTS REVIEWER CHECKS March 2001 according to the following Container Level 1 standards: a container is used that meets applicable U.S. DOT regulations on the packaging of hazardous materials for transportation a container is used that is equipped with a cover and closure devices that form a continuous barrier over the container openings so that when the cover and closure devices are secured in the closed position there are not visible holes, gaps, or other open spaces into the interior of the container an open-top container is used in which an organic vapor suppressing barrier is placed on or over the hazardous waste in the container so that no hazardous waste is exposed to the atmosphere. Verify that, for containers with a design capacity greater than 0.46 m3 [approx. 122 gal] that are in light material service, air emissions are controlled according to the following Container Level 2 standards: a container is used that meets applicable U.S. DOT regulations on the packaging of hazardous materials for transportation a container is used that operates with no detectable organic emissions a container is used that has been demonstrated within the preceding 12 mo to be vapor tight. Verify that, when a container using Level 1 standards, other than DOT approved containers, is used it is equipped with covers and closure devices composed of suitable materials to minimize exposure of the hazardous waste to the atmosphere and to maintain the equipment integrity for as long as it is in service. Verify that, whenever waste is in a container using Level 1 or Level 2 controls, covers and closure devices are installed and closure devices are secured and maintained in the closed position except as follows: opening of a closure device or cover is allowed for adding waste or other material to the container as follows: when the container is filled to the intended final level in one continuous operation, the closure devices are secured in the closed position and the covers installed at the conclusion of the filling operation when discrete batches or quantities of material are added intermittently to the container over a period of time, the closure devices are promptly secured in the closed position and covers installed upon either: the container being filled to the intended final level the completion of a batch loading after which no additional material will be added to the container within 15 min the person performing the loading operation leaving the immediate vicinity of the container the shutdown of the process generating the material being added to the container, whichever condition occurs first opening of a closure device or cover is allowed for removing the hazardous 4 - 61 Hazardous Waste COMPLIANCE CATEGORY HAZARDOUS WASTE MANAGEMENT U.S. TEAM Guide REGULATORY REQUIREMENTS REVIEWER CHECKS March 2001 waste as follows: in order to meet the requirements for an empty container when discrete quantities or batches of material are removed from the container but the container is not empty, the closure devices are promptly secured in the closed position and the covers installed either: upon completion of batch removal after which no additional material will be removed within 15 min the person performing the unloading leaves the immediate vicinity, whichever condition occurs first opening of a closure device or cover is allowed when access inside the container is needed to perform routine activities other than transfer of hazardous waste opening of a spring loaded, pressure vacuum relief valve, conservation vent, or similar type of pressure relief device which vents to the atmosphere is allowed during normal operations for the purpose of maintaining internal container pressure opening of a safety device to avoid unsafe conditions. Verify that the transfer of hazardous waste in or out of containers meeting Container Level 2 controls is done in a manner to minimize exposure of the hazardous waste to the atmosphere (i.e., a submerged fill pipe, a vapor balancing system, a vapor recovery system, a fitted opening in the top of the container through which the hazardous waste is filled and subsequently purge the transfer line before removing it). HW.70.9.US. .Containers with design capacities greater than 0.1 m3 [approx. 26 gal] used for the treatment of a hazardous waste by a waste stabilization process are required to meet specific design and operating standards (40 CFR 262.34(a)(1)(i), 265.178, and 265.1087(a) through 265.1087(b)(2), and 265.1087(e)(1) through 265.1087(e)(3)) [December 1996]. (NOTE: The requirements of 40 CFR 265.1087 do not apply to containers in which all the hazardous waste entering the container meets one of the following [see also the definition for exempted hazardous waste containers and surface impoundments] (40 CFR 265.1083(c): the average VO concentration of the hazardous waste at the point of waste origination is less than 500 ppmw the organic content of the hazardous waste has been reduced by an organic destruction or removal process the waste meets the numerical concentration limits for organic hazardous constituents as specified in 40 CFR 268.40 or has been treated by the treatment technology established by the USEPA for the waste in 268.42(a) or an equivalent method.) (NOTE: These requirements do not apply to a container that has a design capacity less than or equal to 0.1 m3 [approx. 26 gal] or to containers of any size at satellite accumulation points (40 CFR 265.1080(b)(2)).) (NOTE: Safety devices may be installed and operated as necessary.) Verify that containers with design capacities greater than 0.1 m3 [approx. 26 gal] used for the treatment of a hazardous waste by a waste stabilization process meet 4 - 62 Hazardous Waste COMPLIANCE CATEGORY HAZARDOUS WASTE MANAGEMENT U.S. TEAM Guide REGULATORY REQUIREMENTS REVIEWER CHECKS March 2001 the following Container Level 3 standards at those times during the waste stabilization process when the hazardous waste in the container is exposed to the atmosphere: a container is vented directly through a closed vent system to a control device a container is vented inside an enclosure which is exhausted through a closed vent system to a control device. Verify that, for Level 3 containers, the following requirements are met: the container enclosure is designed and operated in accordance with the criteria for a permanent total enclosure under 40 CFR 52.741 the closed vent system and control device is designed and operated in accordance with 265.1088 (see checklist item HW.70.12). HW.70.10.US. Facilities are required to have a written plan and schedule for inspection and monitoring requirements for containers and meet specific inspection requirements (40 CFR 262.34(a)(1)(i), 265.178, 265.1087(c)(4), 265.1087(d)(4), and 265.1089) [December 1996]. (NOTE: These requirements do not apply to a container that has a design capacity less than or equal to 0.1 m3 [approx. 26 gal] or to containers of any size at satellite accumulation points (40 CFR 265.1080(b)(2)).) Verify that the facility has a written plan and schedule for performing inspections and monitoring. Verify that the plan and schedule are being met. Verify that inspections of the containers and their covers and closure devices for containers using Container Level 1 or Level 2 controls are done as follows: when a hazardous waste is already in the container when it is first accepted and the container is not emptied within 24 h after it is accepted, it is visually inspected within 24 h after acceptance for cracks, holes, gaps, or other open spaces when a container used for managing hazardous waste for 1 yr or more, it is visually inspected at least once every 12 mo for visible cracks, holes, gaps, or other open spaces when the cover and closure devices are secured in the closed position. Verify that, when a defect is detected, the first efforts at repairs are within 24 h after detection, and repair is completed as soon as possible but no later than 5 calendar days after detection. (NOTE: If repair cannot be completed within 5 calendar days, the hazardous waste must be removed from the container.) HW.70.11.US. Facilities are required to meet (NOTE: These requirements do not apply to a container that has a design capacity less than or equal to 0.1 m3 [approx. 26 gal] or to containers of any size at satellite 4 - 63 Hazardous Waste COMPLIANCE CATEGORY HAZARDOUS WASTE MANAGEMENT U.S. TEAM Guide REGULATORY REQUIREMENTS documentation requirements for containers (40 CFR 262.34(a)(1)(i), 265.178, 265.1087(c)(5), 265.1090(a), and 265.1090(d) through 265.1090(i)) [December 1996]. REVIEWER CHECKS March 2001 accumulation points (40 CFR 265.1080(b)(2)).) Verify that a copy of the procedure used to determine that containers with a capacity of 0.46 m3 [approx. 122 gal] or greater which do not meet DOT standards are not managing hazardous waste in light material service is available. Verify that if using Container Level 3 air emissions controls, the facility prepares and maintains records that: include the most recent set of calculations and measurements performed by the owner/operator to verify that the enclosure meets the criteria of a permanent total enclosure as specified in 40 CFR 52.741, Appendix B the same records as required for closed vent systems. Verify that if using a closed-vent system and control device, the following records are maintained: certification that is signed and dated by the owner/operator stating that the control device is designed to operate at the performance level documented by a design analysis or by performance tests when the container is operating at capacity or the highest level reasonably expected to occur design documents if design analysis is used, including information describing the control device design and certification that the equipment meets the applicable specification a performance test plan if performance tests are used and all test results description and date of each modification, as applicable identification of operating parameters, description of monitoring devices, and diagrams of monitoring sensor locations, as applicable semiannual records of the following for those planned routine maintenance operations that would require the control device to exceed limitations: a description of the planned routine maintenance that is anticipated to be performed for the control device during the next 6-mo period, including the type of maintenance needed, planned frequency, and lengths of maintenance periods a description of the planned routine maintenance that was performed for the control device during the previous 6-mo period, including the type of maintenance performed and the total number of hours during those 6 mo that the control device did not meet applicable requirements records of the following for those unexpected control device system malfunctions that would cause the control device to not meet specifications: the occurrence and duration of each malfunction of the control device system the duration of each period during a malfunction when gases, vapors, or fumes are vented from the waste management unit through the closed vent system to the control device while the control device is not properly functioning actions taken during periods of malfunction to restore a malfunctioning control device to its normal or usual manner of operation 4 - 64 Hazardous Waste COMPLIANCE CATEGORY HAZARDOUS WASTE MANAGEMENT U.S. TEAM Guide REGULATORY REQUIREMENTS REVIEWER CHECKS March 2001 records of the management of the carbon removed from a carbon adsorption system. Verify that, for exempted containers (see the definition of Exempted Hazardous Waste Containers and Surface Impoundments), the following records are prepared and maintained as applicable: if exempted under the hazardous waste concentration conditions, information used for the waste determination in the facility operating log and/or the date, time, and location of each waste sample if analysis results for samples are used if exempted under incineration use or process destruction use, the identification number for the incinerator, boiler, or industrial furnace in which the hazardous waste is treated. Verify that covers designated as unsafe to monitor are listed in a log kept in the facility operating record with an explanation of why they are unsafe to inspect and monitor and a plan and schedule of inspection and monitoring is recorded. Verify that, for containers not using the air emissions controls specified in 40 CFR 265.1085 through 265.1088 (see checklist items HW.70.7 through HW.70.12), the following information is maintained: a list of the individual organic peroxide compounds manufactured at the facility if it produces more than one functional family of organic peroxides or multiple organic peroxides within one functional family, and one or more of these organic peroxides could potentially undergo self-accelerating thermal decomposition at or below ambient temperatures a description of how the hazardous waste containing the organic peroxide compounds identified in the above list are managed, including: a facility identification number for the container or group of containers the purpose and placement of this container or group of containers in the management train of this hazardous waste the procedures used to ultimately dispose of the hazardous waste handled in the containers an explanations why managing these containers would be an undue safety hazard. Verify that all records, except design information records, are kept for at least 3 yr. Verify that design information records are maintained in the operating record until the air emissions control equipment is replaced or otherwise no longer in service. (NOTE: See also the recordkeeping requirements for carbon adsorption units in checklist item HW.71.3.) HW.70.12.US. Facilities are (NOTE: The requirements of 40 CFR 265.1088 do not apply to containers in 4 - 65 Hazardous Waste COMPLIANCE CATEGORY HAZARDOUS WASTE MANAGEMENT U.S. TEAM Guide REGULATORY REQUIREMENTS REVIEWER CHECKS March 2001 required to meet specific requirements for closed vent systems and control devices used to achieve compliance (40 CFR 262.34(a)(1)(i). 265.178, and 265.1088) [December 1996]. which all the hazardous waste entering the container meets one of the following (40 CFR 265.1083(c): the average VO concentration of the hazardous waste at the point of waste origination is less than 500 ppmw the organic content of the hazardous waste has been reduced by an organic destruction or removal process the waste meets the numerical concentration limits for organic hazardous constituents as specified in 40 CFR 268.40 or has been treated by the treatment technology established by the USEPA for the waste in 268.42(a) or an equivalent method.) (NOTE: These requirements do not apply to a container that has a design capacity less than or equal to 0.1 m3 [approx. 26 gal] or to containers of any size at satellite accumulation points (40 CFR 265.1080(b)(2)).) Verify that closed vent systems meet the following: it routes the gases, vapors, and fumes emitted from the hazardous waste in the waste management unit to a control device it is designed and operated in accordance with 40 CFR 265.1033(j) (see check list item HW.71.2) if it includes bypass devices that could be used to divert the gas or vapor stream to the atmosphere before entering the control device, one of the following equipment requirements is met for each type of bypass device, (NOTE: Low leg drains, high point bleeds, analyzer vents, open-ended valve or lines, spring loaded pressure relief valves, and other fittings used for safety purposes are not considered bypass devices.): a flow indicator is installed, calibrated, maintained, and operated at the inlet to the bypass line used to divert gases and vapors from the closedvent system to the atmosphere at a point upstream of the control device inlet a seal or locking device is placed on the mechanism by which the bypass device position is controlled when the bypass valve is in the closed position so that the bypass device cannot be opened without breaking the seal or removing the lock. Verify that the seal or closure mechanism is visually inspected at least once every month. Verify that one of the following control devices are used: a device designed and operated to reduce the total organic content of the inlet vapor stream vented to the control device by at least 95 percent by weight an enclosed combustion device designed and operated in accordance with 265.1033(c) (see checklist item HW.71.2) a flare designed and operated in accordance with 40 CFR 265.1033(d) (see checklist item HW.71.2). 4 - 66 Hazardous Waste COMPLIANCE CATEGORY HAZARDOUS WASTE MANAGEMENT U.S. TEAM Guide REGULATORY REQUIREMENTS REVIEWER CHECKS March 2001 Verify that, when a closed vent system and control device is used, the following are met: periods of planned routine maintenance of the control device during which the device does not meet specifications do not exceed 240 h per year control device system malfunctions are corrected as soon as practicable it is operated such that gases, vapors, and/or fumes are not actively vented to the control device during periods of planned maintenance or control device system malfunction, except in cases where it is necessary to do so in order to avoid an unsafe condition or to implement malfunction corrective actions or planned maintenance actions. Verify that, if a carbon adsorption system is used, the following requirements are met: all activated carbon is replaced with fresh carbon on a regular basis as outlined in 40 CFR 265.1033(g) and 265.1033(h) (see checklist item HW.71.2) all carbon removed from the devices is managed in a correct manner. Verify that, if a control device other than thermal vapor incinerators, flare, boiler, process heater, condenser, or carbon adsorption systems are used, the requirements in 40 CFR 265.1033(i) are met (see checklist item HW.71.2). Verify that, for control devices, it is demonstrated by either a performance test or a design analysis that the device achieves compliance except for the following: a flare boiler or process heater with a design heat input capacity of 44 MW or greater a boiler or process heater into which the vent stream is introduced with the primary fuel a boiler or process heater burning hazardous waste for which the owner or operator has been issued a final permit under 40 CFR 270 and has designed and operates the unit in accordance with the requirements of 40 CFR 266, subpart H a boiler or industrial furnace burning hazardous waste for which the owner or operator has certified compliance with the interim status requirements of 40 CFR 266, subpart H. Verify that the readings from each control device are inspected at least once each operating day to check control device operation. 4 - 67 Hazardous Waste COMPLIANCE CATEGORY HAZARDOUS WASTE MANAGEMENT U.S. TEAM Guide REGULATORY REQUIREMENTS REVIEWER CHECKS March 2001 GENERATORS HW.71 Emissions From Process Vents HW.71.1.US. Generators with process vents associated with distillation, fractionation, thinfilm evaporation, solvent extraction, or air or steam stripping operations, that manage hazardous wastes with organic concentrations of at least 10 ppmw, are required to meet specific standards (40 CFR 262.34(a)(1)(i), 265.178, 265.1030(b), and 265.1032) [December 1996]. (NOTE: This applies only if the operations are conducted in one of the following: a unit that is subject to the permitting requirements of 40 CFR 270 a unit (including a hazardous waste recycling unit) that is not exempt from permitting under the provisions of 40 CFR 262.34(a) (i.e., a hazardous waste recycling unit that is not a 90-day tank or container) and that is located at a hazardous waste management facility that is otherwise subject to the permitting requirements of 40 CFR 270 a unit that is exempt from permitting under the provisions of 40 CFR 262.34(a) (i.e., a 90-day tank or container).) HW.71.2.US. When a generator uses a closed-vent system and control device to meet the standards for total organic emissions, the closedvent system and control device must meet certain minimum requirements (40 CFR 262.34(a)(1)(i), 265.178, and 265.1033(b) through 265.1033(k)) [December 1996]. (NOTE: This applies to generators with process vents associated with distillation, fractionation, thin-film evaporation, solvent extraction, or air or steam stripping operations, that manage hazardous wastes with organic concentrations of at least 10 ppmw, if the operations are conducted in one of the following: Verify that one of the following is met: total organic emissions from the process vents do not exceed 1.4 kg/h (3 lb/h) and 2.8 Mg/yr (3.1 tons/yr) total organic emissions are reduced by use of a control device from all process vents by 95 weight percent. a unit that is subject to the permitting requirements of 40 CFR 270 a unit (including a hazardous waste recycling unit) that is not exempt from permitting under the provisions of 40 CFR 262.34(a) (i.e., a hazardous waste recycling unit that is not a 90-day tank or container) and that is located at a hazardous waste management facility that is otherwise subject to the permitting requirements of 40 CFR 270 a unit that is exempt from permitting under the provisions of 40 CFR 262.34(a) (i.e., a 90-day tank or container).) Verify that control devices involving vapor recovery are designed and operated to recover the organic vapors vented to the air with an efficiency of 95 weight percent or greater, unless the total organic emission limit can be attained at an efficiency of less than 95 weight percent. Verify that, if an enclosed combustion device is used (i.e., vapor incinerator, boiler, or process heater), it is designed and operated to reduce the organic emissions vented to it by 95 weight percent or greater, to achieve a total organic compound concentration of 20 ppmv expressed as the sum of the actual 4 - 68 Hazardous Waste COMPLIANCE CATEGORY HAZARDOUS WASTE MANAGEMENT U.S. TEAM Guide REGULATORY REQUIREMENTS REVIEWER CHECKS March 2001 compounds, not carbon equivalents, on a dry basis corrected to 3 percent oxygen, or to provide a minimum residence time of 0.50 s at a minimum temperature of 760 °C [1400 °F]. Verify that, if a boiler or process heater is used as the control device, the vent stream is introduced into the flame zone of the boiler or process heater. Verify that, if flares are used: they are designed and operated with no visible emissions except for periods not in excess of 5 min during any 2 consecutive hours they are operated with a flame present at all times they are used only if the net heating value of the gas being combusted is 11.2 MJ/scm (300 Btu/scf) or greater if the flare is steam assisted or air assisted if nonassisted, the net heating value of the gas being combusted is 7.45 MJ/scm (200 Btu/scf) or greater if nonassisted or steam-assisted, have an exit velocity less than 18.3 m/s (60 ft/ s), except when the net heating value of the gas being combusted is greater than 37.3 MJ/scm (1000 Btu/scf) and the exit velocity is equal to or greater than 18.3 m/s (60 ft/s) but less than 122 m/s (400 ft/s). Verify that each monitor and control device is inspected on a routine basis. Verify that each required control device is installed, calibrated, monitored and inspected as follows: a flow indicator is installed in the vent stream at the nearest feasible point to the control device inlet, but before being combined with other streams, and provides a record of vent stream flow from each affected process vent to the control device at least once every hour a device to continuously monitor control device operations as specified: a temperature monitoring device equipped with a continuous recorder for a thermal vapor incinerator a temperature monitoring device equipped with a continuous recorder for a catalytic vapor incinerator a heat sensing monitor with a continuous recorder for flares a temperature monitoring device equipped with a continuous recorder to measure parameters that indicate good combustion operating practices are being used for a boiler or process heater having a design heat input capacity less than 44 MW for a condenser, one of the following: a monitoring device with a continuous recorder to measure the concentration level of the organic compound in the exhaust vent stream from the condenser a temperature monitoring device equipped with a continuous recorder capable of monitoring temperature in the exhaust vent stream from the condenser with an accuracy of +/- 1 percent of the temperature being monitored in Celsius or in +/- 0.5 °C, which 4 - 69 Hazardous Waste COMPLIANCE CATEGORY HAZARDOUS WASTE MANAGEMENT U.S. TEAM Guide REGULATORY REQUIREMENTS REVIEWER CHECKS March 2001 ever is greater for a carbon adsorption system such as a fixed bed carbon adsorber that regenerates the carbon bed directly in the control device, one of the following: a monitoring device equipped with a continuous recorder to measure the concentration levels of the organic compounds in the exhaust vent stream from the carbon bed a monitoring device equipped with a continuous recorder to measure a parameter that indicates the carbon bed is regenerated on a regular, predetermined time cycle. Verify that readings from monitoring devices are checked at least once a day. Verify that, if a carbon adsorption system is being used that regenerates the carbon bed directly onsite, the existing carbon in the control device is replaced with fresh carbon at a regular, predetermined time intervals. (NOTE: The predetermined time interval is based on the design analysis required under 40 CFR 265.1035(b)(4)(iii)(F).) Verify that if a carbon adsorption system is being used that does not regenerate the carbon bed directly onsite in the control device, the existing carbon in the control device is replaced on a regular basis. (NOTE: When to replace the carbon is determined by one of the following procedures: monitoring the concentration level of the organic compound in the exhaust vent stream from the carbon adsorption system daily or at an interval no greater than 20 percent of the time required to consume the total carbon working capacity, whichever is longer replace the carbon at a regular predetermined time interval that is less than the design carbon replacement interval.) Verify that closed vent systems meet one of the following: are designed and operated with no detectable emissions as indicated by an instrument reading of less than 500 ppm above background as determined by the procedures in 40 CFR 265.1034(b) and by visual inspection are designed to operate at a pressure below atmospheric pressure and are equipped with at least one pressure gauge or other pressure measurement device that can be read from a readily accessible location. HW.71.3.US. Generators are required to maintain specific records pertaining to process vent emissions (40 CFR 262.34(a)(1)(i), 265.178 and Verify that the following information is kept in the operating record: an implementation schedule up-to-date documentation of compliance the test plan if test data is used to determine the organic removal efficiency or total organic compound concentration achieved by a control device 4 - 70 Hazardous Waste COMPLIANCE CATEGORY HAZARDOUS WASTE MANAGEMENT U.S. TEAM Guide REGULATORY REQUIREMENTS 265.1035) [December 1996]. REVIEWER CHECKS March 2001 documentation of compliance with 40 CFR 265.1033, including: a list of all information references and sources used in preparing the documentation records, including the dates of required compliance tests design analysis, specifications, drawing, schematics, and piping and instrumentation diagrams if engineering calculations are used a statement signed and dated by the operator or owner certifying that the operating parameters used in the design analysis reasonably represent the conditions which exist when the hazardous waste management unit is or would be operating at the highest load or capacity level reasonably expected a statement signed and dated by the owner or operator certifying that the control device is designed to operate at an efficiency of 95 percent or greater unless the total organic concentration limit is achieved at an efficiency of less than 95 weight percent, or the total organic emissions limits for affected process vents can be attained by a control device involving vapor recovery at an efficiency less than 95 weight percent. all performance test results if used to demonstrate compliance design documentation monitoring and inspection results notations of exceedance explanation for each period of exceedance for carbon adsorption systems: when the carbon is replaced in carbon adsorption systems date and time when a control device is monitored for carbon breakthrough the date of each control device startup and shutdown. Verify that records of monitoring operations and inspection information are kept for 3 yr. HW.71.4.US. Closed vent systems are required to be monitored, inspected, and leaks repaired (40 CFR 262.34(a)(1)(i), 265.178, 265.1033(k) and 265.1033(n)) [December 1996]. (NOTE: This applies to generators with process vents associated with distillation, fractionation, thin-film evaporation, solvent extraction, or air or steam stripping operations, that manage hazardous wastes with organic concentrations of at least 10 ppmw, if the operations are conducted in one of the following: a unit that is subject to the permitting requirements of 40 CFR 270 a unit (including a hazardous waste recycling unit) that is not exempt from permitting under the provisions of 40 CFR 262.34(a) (i.e., a hazardous waste recycling unit that is not a 90-day tank or container) and that is located at a hazardous waste management facility that is otherwise subject to the permitting requirements of 40 CFR 270 a unit that is exempt from permitting under the provisions of 40 CFR 262.34(a) (i.e., a 90-day tank or container.) Verify that closed vents systems designed and operated with no detectable emissions, as indicated by an instrument reading of less than 500 ppm above background, are monitored as follows: 4 - 71 Hazardous Waste COMPLIANCE CATEGORY HAZARDOUS WASTE MANAGEMENT U.S. TEAM Guide REGULATORY REQUIREMENTS REVIEWER CHECKS March 2001 an initial leak detection monitoring of the closed vent system using the procedures specified in 40 CFR 265.1034(b) on or before the date the system become subject to this section of the CFR after initial leak detection monitoring: visual inspection at least once a year for closed vent system joints, seams, or other connections that are permanently or semi-permanently sealed (e.g., a welded joint between two sections of hard piping or a bolted and gasketed ducting flange) whenever a component is repaired or replaced monitor according to 40 CFR 265.1034(b) annually and at times required by the Regional Administrator for all other parts of the system using the procedures specified in 40 CFR 265.1034(b). Verify that closed vent systems designed to operate at no detectable emissions, as indicated by an instrument reading of less than 500 ppmv above background, are monitored as follows: annual visual inspection to check for defects that could result in air pollutant emissions initial inspection on or before the date the system becomes subject to this section of the CFR. (NOTE: For closed vent systems designed to operate at no detectable emissions, as indicated by an instrument reading of less than 500 ppmv above background, portions of the system designated as unsafe to monitor are exempt from the visual monitoring if: the components are unsafe to monitor because monitoring personnel would be exposed to an immediate danger a written plan that requires monitoring as practicable during safe to monitor periods is in place and followed.) Verify that detectable emissions, as indicated by visual inspection or by an instrument reading of greater than 500 ppmv above background, are controlled as soon as practicable but not later than 15 days after the emissions is detected. Verify that a first attempt at repair is made no later than 5 calendar days after the emission is detected. (NOTE: Delay of repair of a closed vent system for which leaks have been detected is allowed if the repair is technically infeasible without a process unit shutdown, or if it is determined that the emissions resulting from the immediate repair would be greater than the fugitive emissions likely to result from delay of repair.) HW.71.5.US. Closed vent systems and control devices (NOTE: This applies to generators with process vents associated with distillation, fractionation, thin-film evaporation, solvent extraction, or air or steam stripping 4 - 72 Hazardous Waste COMPLIANCE CATEGORY HAZARDOUS WASTE MANAGEMENT U.S. TEAM Guide REGULATORY REQUIREMENTS REVIEWER CHECKS March 2001 used to comply with the provisions of 40 CFR 265.1030 through 265.1035 are required to be operated at all times when emissions may be vented to them (40 CFR 262.34(a)(1)(i), 265.178, 265.1033(l)) [December 1996]. operations, that manage hazardous wastes with organic concentrations of at least 10 ppmw, if the operations are conducted in one of the following: a unit that is subject to the permitting requirements of 40 CFR 270 a unit (including a hazardous waste recycling unit) that is not exempt from permitting under the provisions of 40 CFR 262.34(a) (i.e., a hazardous waste recycling unit that is not a 90-day tank or container) and that is located at a hazardous waste management facility that is otherwise subject to the permitting requirements of 40 CFR 270 a unit that is exempt from permitting under the provisions of 40 CFR 262.34(a) (i.e., a 90-day tank or container).) Verify that closed vent systems and control devices are operated at all times when emissions may be vented to them. HW.71.6.US. When carbon adsorption systems are used, operators are required to manage all carbon that is a hazardous waste according to specific parameters (40 CFR 262.34(a)(1)(i), 265.178, 265.1033(m)) [December 1996]. (NOTE: This applies to generators with process vents associated with distillation, fractionation, thin-film evaporation, solvent extraction, or air or steam stripping operations, that manage hazardous wastes with organic concentrations of at least 10 ppmw, if the operations are conducted in one of the following: a unit that is subject to the permitting requirements of 40 CFR 270 a unit (including a hazardous waste recycling unit) that is not exempt from permitting under the provisions of 40 CFR 262.34(a) (i.e., a hazardous waste recycling unit that is not a 90-day tank or container) and that is located at a hazardous waste management facility that is otherwise subject to the permitting requirements of 40 CFR 270 a unit that is exempt from permitting under the provisions of 40 CFR 262.34(a) (i.e., a 90-day tank or container).) Verify that carbon removed from control devices that is a hazardous waste is managed in one of the following manners, regardless of the average VOC concentration of the carbon: regenerated or reactivated in a thermal treatment unit that meets one of the following: the unit has a final permit under 40 CFR 270 which implements the requirements of 40 CFR 264, subpart X the unit is equipped with and operating air emission controls in accordance with applicable requirements incinerated in a hazardous waste incinerator for which the operator either: has a final permit under 40 CFR 270 which implement the requirements of 40 CFR 264, subpart O has designed and operates the incinerator in accordance with the interim status required in 40 CFR 265, subpart O burned in a boiler or industrial furnace for which the operator either: has been issued a final permit under 40 CFR 270 implementing 40 CFR 266 4 - 73 Hazardous Waste COMPLIANCE CATEGORY HAZARDOUS WASTE MANAGEMENT U.S. TEAM Guide REGULATORY REQUIREMENTS REVIEWER CHECKS March 2001 has designed and operates the boiler or industrial furnace in accordance with the interim status requirements of 40 CFR 266, Subpart H. 4 - 74 Hazardous Waste 4 - 75 Hazardous Waste COMPLIANCE CATEGORY HAZARDOUS WASTE MANAGEMENT U.S. TEAM Guide REGULATORY REQUIREMENTS GENERATORS HW.72 Air Emission Standards for Equipment Leaks REVIEWER CHECKS March 2001 (NOTE: This section applies to equipment that contains or contacts hazardous waste with organic concentrations of at least 10 percent by weight that are managed in one of the following (40 CFR 265.1050(b)) [Revised December 1997]: a unit that is subject to the permitting requirements of 40 CFR 270 a unit (including a hazardous waste recycling unit) that is not exempt from permitting under the provisions of 40 CFR 262.34(a) (i.e., a hazardous waste recycling unit that is not a 90-day tank or container) and that is located at a hazardous waste management facility that is otherwise subject to the permitting requirements of 40 CFR 270 a unit that is exempt from permitting under the provisions of 40 CFR 262.34(a) (i.e., a 90-day tank or container) and is not a recycling unit under the provisions of 40 CFR 261.6.) (NOTE: This section does not apply to (40 CFR 265.1050(d) and 265.1050(e)) [Revised December 1997]: equipment that is in vacuum service and is identified as such on the required list equipment that contains or contacts hazardous waste with an organic concentration of at least 10 percent by weight for less than 300 h per calendar year and is identified as such.) HW.72.1.US. Generators with pumps in light liquid service, that contain or contact hazardous wastes with organic concentrations of at least 10 percent by weight, are required to meet specific standards (40 CFR 262.34(a)(1)(i), 265.178, and 265.1052) [December 1996]. Verify that pumps in light liquid service are monitored monthly according to designated reference methods and inspected visually weekly. (NOTE: A leak is detected if there is an instrument reading of 10,000 ppm or greater or if there is an indication of liquid dripping from the pump seal.) Verify that, when a leak is detected, the first attempt at repair is made within 5 calendar days and repair is completed within 15 calendar days. (NOTE: Pumps equipped with dual mechanical seal systems and pumps designated for no detectable emissions that meet standards outlined here do not have to be monitored monthly or visually checked weekly.) Verify that pumps equipped with a dual mechanical seal system which do not have to be monitored monthly or visually checked weekly, meet the following design and operation requirements: the dual mechanical seal system is operated with barrier fluid at a pressure that is at all times greater than the pump stuffing box, or equipped with a barrier fluid degassing reservoir that is connected by a closed-vent system to a control device, or equipped with a system that purges the barrier fluid into a hazardous waste stream with no detectable emission to the atmosphere the barrier fluid system has no hazardous waste with organic concentrations 10 percent or greater by weight the barrier fluid system is equipped with a sensor that will detect failure if the 4 - 76 Hazardous Waste COMPLIANCE CATEGORY HAZARDOUS WASTE MANAGEMENT U.S. TEAM Guide REGULATORY REQUIREMENTS REVIEWER CHECKS March 2001 seal is broken pumps are checked by visual inspection weekly sensors are checked daily or equipped with an audible alarm that is checked monthly. (NOTE: Each owner or operator must determine, based on design considerations and operating experience, a criterion that indicate failure of the seal system, the barrier fluid system, or both.) Verify that pumps designated for no detectable emissions, as indicated by an instrument reading of 500 ppm above background or less, meet the following: they are operated with no detectable emissions they are tested for compliance initially upon designation, annually, and at other times as requested by the Regional Administrator no externally actuated shaft penetrates the pump housing. (NOTE: Any pump that is equipped with a closed-vent system capable of capturing and transporting any leakage from the seal or seals to a control device is exempt from these requirements.) HW.72.2.US. Generators with compressors that contain or contact hazardous wastes with organic concentrations of at least 10 percent by weight are required to meet specific standards (40 CFR 262.34(a)(1)(i), 265.178, and 265.1053) [December 1996]. Verify that each compressor is equipped with a seal system which includes a barrier fluid system and prevents leakage of total organic emissions to the atmosphere except if: it is equipped with a closed-vent system capable of capturing and transporting any leakage from the seal to a control device it is designated for no detectable emission, and: it operates at an instrument reading of less than 500 ppm above back ground it is tested for compliance initially upon designation, annually, and at times as requested by the Regional Administrator. Verify that compressor seal systems meet one of the following: it is operated with the barrier fluid at a pressure that is at all times greater than the compressor stuffing box pressure it is equipped with a barrier fluid system that is connected to a closed-vent system or a control device it is equipped with a system that purges the barrier fluid into a hazardous waste stream with no detectable emissions to the atmosphere. Verify that the barrier fluid is not a hazardous waste with organic concentrations 10 percent or greater by weight. Verify that each barrier fluid system is equipped with a sensor which will detect 4 - 77 Hazardous Waste COMPLIANCE CATEGORY HAZARDOUS WASTE MANAGEMENT U.S. TEAM Guide REGULATORY REQUIREMENTS REVIEWER CHECKS March 2001 failure of the seal system, barrier fluid system, or both. Verify that each sensor is checked daily or it is equipped with an audible alarm that is checked monthly. (NOTE: Sensors on compressors located within the boundary of an unmanned site must be checked daily.) (NOTE: Each owner or operator must determine, based on design considerations and operating experience, a criterion that indicate failure of the seal system, the barrier fluid system, or both.) Verify that, when a leak is detected, the first attempt at repair is made within 5 calendar days and the repair is made within 15 calendar days. HW.72.3.US. Generators with pressure relief devices in gas/vapor service that contain or contact hazardous wastes with organic concentrations of at least 10 percent by weight are required to meet specific standards (40 CFR 262.34(a)(1)(i), 265.178, 265.1054) [December 1996] Verify that, except during pressure releases, each pressure relief device in gas/vapor service is operated with no detectable emissions as indicated by an instrument reading of less than 500 ppm above background. HW.72.4.US. Generators with sampling connecting systems that contain or contact hazardous wastes with organic concentrations of at least 10% by weight are required to meet specific standards (40 CFR 262.34(a)(1)(i), 265.178, and 265.1055) [December 1996]. Verify that each sampling connection system is equipped with a closed-purge, closed loop system or closed-vent system. Verify that if there is a pressure release, the device is returned to a no detectable emission status within 5 calendar days and the device is monitored to ensure compliance. (NOTE: Any pressure relief device that is equipped with a closed-vent system capable of capturing and transporting leakage from the pressure relief device to a control device is exempt from these requirements.) Verify that each system collects the sample purge for return to the processing or for routing to the appropriate treatment system. (NOTE: Gases displaced through filling of the sample container are not required to be collected or captured.) Verify that each closed-purge, closed-loop system or closed-vent system does one of the following: returns the purged process fluid directly to the process line collects and recycles the purged process fluid is designed and operated to capture and transport all the purged process fluid to a waste management unit that is in compliance or a control device that is in compliance. 4 - 78 Hazardous Waste COMPLIANCE CATEGORY HAZARDOUS WASTE MANAGEMENT U.S. TEAM Guide REGULATORY REQUIREMENTS REVIEWER CHECKS March 2001 (NOTE: In-situ sampling systems are exempt from these requirements.) HW.72.5.US. Generators with open-ended valves or lines that contain or contact hazardous wastes with organic concentrations of at least 10 percent by weight are required to meet specific operation standards (40 CFR 262.34(a)(1)(i), 265.178, 265.1056) [December 1996]. Verify that each open-ended valve or line is equipped with a cap, blind flange, plug, or a second valve. Verify that the cap, blind flange, plug, or second valve seals the open end at all times, except during operations requiring hazardous waste stream flow through the open-ended valve or line. Verify that each open-ended valve or line equipped with a second valve is operated so the valve on the hazardous waste stream end is closed before the second valve is closed. Verify that, when a double block and bleed system is being used, the bleed valve is shut or plugged except during operations that require venting the line between the block valves. HW.72.6.US. Generators with valves in gas/vapor service or light liquid service, that contain or contact hazardous wastes with organic concentrations of at least 10 percent by weight, are required to meet specific monitoring and repair standards (40 CFR 262.34(a)(1)(i), 265.178, 265.1057, and 265.1062) [Revised December 1997]. Verify that valves in gas/vapor service or light liquid service are monitored monthly to detect leaks. (NOTE: A leak is detected if an instrument reading of 10,000 ppm or greater is measured. But, if a leak is not detected for 2 consecutive months, monitoring may be cut back to quarterly until a leak is detected.) (NOTE: Valves that are designated for no detectable emissions, as indicated by an instrument reading of less than 500 ppm above background, do not have to be monitored monthly if: the valve has no external actuating mechanism in contact with the hazardous waste stream the valve is operated with emissions less than 500 ppm above background the valve is tested initially upon designation, annually, and at the request of the Regional Administrator.) (NOTE: Valves that are designated as unsafe to monitor are exempt from the requirement for monthly monitoring if: the valve is unsafe to monitor because monitoring personnel would be exposed to an immediate danger a written monitoring plan is followed that requires monitoring as often as is reasonably practicable during safe to monitor times.) (NOTE: The generator may elect to have all valves within a hazardous waste management unit comply with an alternative standard of no greater than 2 percent of the valves to leak; see checklist item HW.72.10.) 4 - 79 Hazardous Waste COMPLIANCE CATEGORY HAZARDOUS WASTE MANAGEMENT U.S. TEAM Guide REGULATORY REQUIREMENTS REVIEWER CHECKS March 2001 (NOTE: Valves that are designated as difficult to monitor are exempt from monthly monitoring requirements if: the valve cannot be monitored without elevating the monitoring personnel more than 2 m above a support surface the hazardous waste management unit within which the valve is located was in operation before 21 June 1990 a written monitoring plan is followed that requires the monitoring of the valve at least once per calendar year.) (NOTE: The following are alternatives to the prescribed monitoring schedule which can be used until the percentage of valves leaking is greater than 2 percent: after 2 consecutive quarterly leak detection periods with the percentage of valves leaking equal to or less than 2 percent, an owner or operator may begin to skip one of the quarterly leak detection periods for the valves subject to 40 CFR 265.1057 after 5 consecutive quarterly leak detection periods with the percentage of valves leaking equal to or less than 2 percent, an owner or operator may begin to skip three of the quarterly leak detection periods for the valves subject to 40 CFR 265.1057. Verify that the first attempt at repairing a leak is done within 5 calendar days after detection and leak repair is completed within 15 days after detection. (NOTE: First attempts at repair include, but are not limited to: tightening of bonnet bolts replacement of bonnet bolts tightening of packing gland nuts injection of lubricant into lubricated packing.) HW.72.7.US. Generators with pumps and valves in heavy liquid service, pressure relief devices in light liquid service or heavy liquid service, and other connectors that contain or contact hazardous wastes with organic concentrations of at least 10% by weight, are required to meet specific monitoring and repair standards (40 CFR 262.34(a)(1)(i), 265.178, and 265.1058) [December 1996]. Verify that pumps and valves in heavy liquid service, pressure relief devices in light liquid service or heavy liquid service, and other connectors are monitored within 5 days if evidence of a potential leak is found by visual, olfactory, audible, or other detection method. (NOTE: Any connector that is inaccessible or is ceramic or ceramic lined is exempt from the monitoring requirements.) (NOTE: A leak is detected if an instrument reading of 10,000 ppm or greater is measured.) Verify that, when a leak is detected, the first attempt at repair occurs within 5 days and repair is done within 15 days after discovery. (NOTE: First attempts at repair include, but are not limited to: tightening of bonnet bolts replacement of bonnet bolts 4 - 80 Hazardous Waste COMPLIANCE CATEGORY HAZARDOUS WASTE MANAGEMENT U.S. TEAM Guide REGULATORY REQUIREMENTS REVIEWER CHECKS March 2001 tightening of packing gland nuts injection of lubricant into lubricated packing.) HW.72.8.US. Generators are required to keep specific records pertaining to the valves, pumps, pressure relief devices, and connecting systems being monitored for leaks and submit certain reports (40 CFR 262.34(a)(1)(i), 265.178, 265.1058(e) and 265.1064) [Revised December 1997]. Verify that the following information is maintained in the generator’s operating record: equipment identification number and hazardous management unit identification approximate locations type of equipment percent-by-weight total organics in the hazardous waste stream at the equipment hazardous waste state at the equipment (gas, liquid, vapor) method of compliance implementation schedule if needed a performance plan for control devices as needed documentation of compliance documentation of repair, including: the instrument and operator identification numbers and the equipment identification number the date evidence of a potential leak was found the date the leak was detected and the date of each attempt to repair the leak repair methods applied in each attempt “Above 10,000” if the maximum instrument reading after each repair attempt is greater then 10,000 ppm “Repair Delayed” and the reason for delay if the leak is not repaired within 15 calendar days after discovery documentation supporting the delay of repair of a valve signature of the owner or operator whose decision it was that repair could not be affected without a hazardous waste management unit shutdown the expected date of successful repair of the leak when it is not repaired within 15 calendar day the date of successful repair of the leak design documentation and monitoring, operating, and inspection information for each closed vent system control device required to comply with the provisions of 40 CFR 265.1060 monitoring and inspection information indicating proper operation and maintenance of the control device for a control device other than a thermal vapor incinerator, catalytic vapor incinerator, flare, boiler, process heater, condenser, or carbon adsorption system the following information for all equipment subject to 40 CFR 265.1052 through 265.1060: a list of identification numbers for equipment (except welded fittings) a list of identification numbers for equipment that the owner or operator elects to designate for no detectable emissions a list of equipment identification numbers for pressure relief devices the dates of required compliance tests, background levels, and maximum 4 - 81 Hazardous Waste COMPLIANCE CATEGORY HAZARDOUS WASTE MANAGEMENT U.S. TEAM Guide REGULATORY REQUIREMENTS REVIEWER CHECKS March 2001 instrument reading measured during the compliance test a list of identification numbers for equipment in vacuum service identification either by list or location (area or group) of equipment that contains or contacts hazardous waste with an organic concentration of at least 10 percent by weight for less than 300 h per calendar year. Verify that the following information is kept for all valves subject to 40 CFR 265.1057(g) and (h): a list of identification numbers for valves listed as unsafe to monitor, an explanation for each valve stating why it is unsafe to monitor, and the plan for monitoring each valve a list of identification numbers for valves that are designated as difficult to monitor, an explanation for each valve stating why it is difficult to monitor, and the plan for monitoring each valve the following for all valves complying with 40 CFR 265.1062: a schedule of monitoring the percent of valves found leaking in each monitoring period. Verify that the following information is kept for use in determining exemptions: an analysis determining the design capacity of the unit a statement listing the hazardous waste influent to and effluent from each unit subject to 40 CFR 265.1052 through 265.1060 and an analysis determining whether these hazardous wastes are heavy liquids an up-to-date analysis and the supporting information and data used to determine if equipment is subject to the requirements. (NOTE: Any connector that is inaccessible or is ceramic or ceramic lined is exempt from the recordkeeping requirements.) HW.72.9.US. Each piece of equipment subject to the requirements in 40 CFR 265.1050 through 265.1064 is required to be marked so that it can be distinguished from other equipment (40 CFR 262.34(a)(1)(i), 265.178, and 265.1050(c) [December 1996]. Verify that each piece of equipment subject to the requirements in 40 CFR 265.1050 through 265.1064 (see checklist items HW.72.1 through HW.72.8) is marked so that it can be distinguished from other equipment. HW.72.10.US. generator has Determine if the owner/operator subject to 40 CFR 265.1057 (see checklist item HW.72.6) has elected to have all valves within a hazardous waste management When elected a to 4 - 82 Hazardous Waste COMPLIANCE CATEGORY HAZARDOUS WASTE MANAGEMENT U.S. TEAM Guide REGULATORY REQUIREMENTS REVIEWER CHECKS March 2001 comply with alternative standards, specific actions are required (40 CFR 262.34(a)(1)(i) and 265.1061) [May 1997]. unit comply with an alternative standard of allowing 2 percent of the valves to leak. Verify that the following actions have been taken if comply with the 2 percent alter native: the Regional Administrator has been notified of the choice to comply with the alternative standards a performance test was conducted initially upon designation, annually, and at other times as required by the Regional Administrator if a valve leak is detected, first attempt at repair is within 5 calendar days and leak repair is completed within 15 days after detection. Verify that if the owner/operator has decided to no longer comply with the 2 percent rule, they have notified the Regional Administrator. 4 - 83 Hazardous Waste COMPLIANCE CATEGORY HAZARDOUS WASTE MANAGEMENT U.S. TEAM Guide REGULATORY REQUIREMENTS REVIEWER CHECKS March 2001 GENERATORS HW.75 Satellite Accumulation Points HW.75.1.US. Generators may accumulate as much as 55 gal of hazardous waste or 1 qt of acutely hazardous waste in containers at or near any point of initial generation without complying with the requirements for onsite storage if specific standards are met (40 CFR 262.34(c)). (NOTE: This type of storage is often referred to as a satellite accumulation point.) Verify that the satellite accumulation point is at or near the point of generation and is under the control of the operator of the waste generating process. Verify that the containers are in good condition and are compatible with the waste stored in them, and that the containers are kept closed except when waste is being added or removed. Verify that the containers are marked HAZARDOUS WASTE or other words that identify the contents. (NOTE: See Appendices 4-1, 4-2, 4-3, and 4-5 for guidance on characteristic and listed hazardous wastes.) Verify that, when waste is accumulated in excess of quantity limitations, the following actions are taken: the excess container is marked with the date the excess amount began accumulating the excess waste is transferred to a 90-day or permitted storage area within 3 days. 4 - 84 Hazardous Waste 4 - 85 Hazardous Waste COMPLIANCE CATEGORY HAZARDOUS WASTE MANAGEMENT U.S. TEAM Guide REGULATORY REQUIREMENTS REVIEWER CHECKS March 2001 GENERATORS HW.80 Container Storage Areas HW.80.1.US. At generators, containers of hazardous waste should be kept in designated storage areas (MP). Verify that all containers are identified and stored in appropriate areas. HW.80.2.US. Containers holding ignitable or reactive waste must be located 15 m (50 ft) from the property line (40 CFR 262.34(a)(1)(i) and 265.176). Determine the distance from storage containers holding ignitable or reactive waste to the property line. HW.80.3.US. Generator personnel must conduct weekly inspections of container storage areas (40 CFR 262.34(a)(1)(i) and 265.174). Verify that inspections are conducted at least weekly to look for leaking containers and signs of deterioration of containers. HW.80.4.US. Generator storage areas for hazardous waste must be designed, constructed, maintained, and operated to minimize the possibility of a fire, explosion, or any unplanned release of hazardous waste (40 CFR 262.34(a)(4) and 265.30 through 265.37). Determine if the following required equipment is easily accessible and in working condition by inspecting the LQG storage areas: (NOTE: Any unidentified contents of solid waste containers and/or containers not in designated storage areas must be tested to determine if solid or hazardous waste requirements apply.) internal communications or alarm system capable of providing immediate emergency instruction to facility personnel a telephone or hand-held two way radio portable fire extinguishers and special extinguishing equipment (foam, inert gas, or dry chemicals) spill control equipment decontamination equipment fire hydrants or other source of water (reservoir, storage tank, etc.) with adequate volume and pressure, foam producing equipment, or automatic sprinklers, or water spray systems. Determine if equipment is tested and maintained as necessary to insure proper operation in an emergency. 4 - 86 Hazardous Waste COMPLIANCE CATEGORY HAZARDOUS WASTE MANAGEMENT U.S. TEAM Guide REGULATORY REQUIREMENTS REVIEWER CHECKS March 2001 Verify that sufficient aisle space is maintained to allow unobstructed movement of personnel, fire protection equipment, spill control equipment, and decontamination equipment to any area of the operation. Verify that police, fire departments, and emergency response teams are familiar with the layout of the LQG, properties of the waste being handled, and general operations as appropriate for the type of waste and potential need for such services. Verify that the hospital is familiar with the site and the types of injuries that could result in an emergency as appropriate for the type of waste and potential need for such services. 4 - 87 Hazardous Waste COMPLIANCE CATEGORY HAZARDOUS WASTE MANAGEMENT U.S. TEAM Guide REGULATORY REQUIREMENTS GENERATORS HW.85 Containment Buildings REVIEWER CHECKS March 2001 (NOTE: According to the Background Information published on page 37211 of the 18 August 1992 edition of the Federal Register, a hazardous waste containment building involves "the management of a hazardous waste inside a unit designed and operated to contain the hazardous waste within the unit". This is not a building that holds drums or tanks filled with hazardous waste but a building that holds the hazardous waste itself.) HW.85.1.US. Generators with containment buildings that are in compliance are not subject to the definition of land disposal if specific requirements are met (40 CFR 262.34(a)(1)(iv) and 265.1100). Verify that the containment building meets the following: HW.85.2.US. Containment buildings are required to be designed according to specific standards (40 CFR 262.34(a)(1)(iv), 265.1101(a)(1) through 265.1101(a)(2), and 265.1101(b)). Verify that the containment building meet the following design standards: it is a completely enclosed, self-supporting structure that is designed and constructed of manmade materials of sufficient strength and thickness to support themselves, the waste contents, and any personnel and heavy equipment that operate within the unit it is designed to prevent failure due to pressure gradients, settlement, compression or uplift, physical contact with the hazardous wastes, climatic conditions, and the stress of daily operations it has a primary barrier that is designed to be sufficiently durable to withstand the movement of personnel, wastes, and handling of equipment within the unit if the unit is used to manage liquids: there is a primary barrier designed and constructed of materials to prevent migration of hazardous constituents into the barrier there is a liquid collection system designed and constructed of materials to minimize the accumulation of liquid on the primary barrier there is a secondary containment system designed and constructed of materials to prevent migration of hazardous constituents into the barrier, with a leak detection and liquid collection system capable of detecting, collecting, and removing leaks of hazardous constituents at the earliest practicable time it has controls sufficient to prevent fugitive dust emissions it is designed and operated to ensure containment and prevent the tracking of materials from the unit by personnel and equipment. it is completely enclosed with a floor, walls, and a roof to prevent exposure to the elements and to assure containment of wastes the floor and containment walls, including any required secondary containment system, are designed and constructed of man-made materials of sufficient strength and thickness to support themselves, the waste contents, and any personnel and heavy equipment that operate within the unit it is designed to prevent failure due to pressure gradients, settlement, compression or uplift, physical contact with the hazardous wastes, climatic 4 - 88 Hazardous Waste COMPLIANCE CATEGORY HAZARDOUS WASTE MANAGEMENT U.S. TEAM Guide REGULATORY REQUIREMENTS REVIEWER CHECKS March 2001 conditions, and the stress of daily operations it has sufficient structural strength to prevent collapse or other failure all surfaces in contact with hazardous wastes are compatible with the wastes it has a primary barrier that is designed to be sufficiently durable to withstand the movement of personnel, wastes, and handling of equipment within the unit and is appropriate for the chemical and physical characteristics of the waste. Verify that, if the containment building is going to manage hazardous wastes with free liquids or be treated with free liquids, the following design requirements are also met: there is a primary barrier designed and constructed of materials to prevent migration of hazardous constituents into the barrier (e.g., a geomembrane covered by a concrete wear surface) there is a liquid collection and removal system designed and constructed of materials to minimize the accumulation of liquid on the primary barrier: the primary barrier is sloped to drain liquids to the associated collection system liquids and wastes are collected and removed to minimized hydraulic head on the containment system at the earliest practicable time there is a secondary containment system, including a secondary barrier, designed and constructed of materials to prevent migration of hazardous constituents into the barrier, with a leak detection and liquid collection system capable of detecting, collecting, and removing leaks of hazardous constituents at the earliest practicable time the leak detection component of the secondary containment system meets the following: it is constructed with a bottom slope of 1 percent or more it is constructed of a granular drainage materials with a hydraulic conductivity of 1 x 10-2 cm/s or more and a thickness of 12 in. (30.5 cm) or more, or constructed of synthetic or geonet drainage materials with a transmissivity of 3 x 10-5 m2/s or more if treatment is to be conducted in the building, the treatment area is designed to prevent the release of liquids, wet materials, or liquid aerosols to other portions of the building the secondary containment system is constructed of materials that are chemically resistant to the waste and liquids managed in the building and of sufficient strength and thickness to prevent collapse under pressure exerted by overlaying materials and by any equipment used. (NOTE: An exception to the structural strength requirement may be made for light- weight doors and windows based on the nature of the waste management operations if the following criteria are met: the doors and windows provide an effective barrier against fugitive dust emissions the unit is designed and operated in a manner that ensures the waste will not 4 - 89 Hazardous Waste COMPLIANCE CATEGORY HAZARDOUS WASTE MANAGEMENT U.S. TEAM Guide REGULATORY REQUIREMENTS REVIEWER CHECKS March 2001 come in contact with the doors or windows.) (NOTE: A containment building can serve as an external liner or a secondary containment system for tanks within the building if: it meets the requirements of 265.193(d)(1) (see Storage Tank Management) it meets the requirements of 265.193(b), 265.193(c)(1), and 265.193(c)(2) (see Storage Tank Management.) HW.85.3.US. Containment buildings are required to be operated according to specific standards (40 CFR 262.34(a)(1)(iv), 265.1101(a)(3), 265.1101(c)(1), and 265.1101(c)(4)). Verify that incompatible wastes or treatment reagents are not placed in the building or its secondary containment system if they could cause the unit or the secondary containment system to leak, corrode, or otherwise fail. Verify that the following operational procedures are done: controls and practices are used to ensure the containment of the waste within the building the primary barrier is maintained so it is free of significant cracks, gaps, corrosion, or other deterioration that could cause hazardous waste to be released from the primary barrier the level of the stored/treated hazardous waste is maintained so the height of any containment wall is not exceeded measures are implemented to prevent the tracking of hazardous waste out of the unit by personnel or equipment used in the handling of the waste there is a designated area for the decontamination of equipment and collection of rinsate any collected rinsate is managed as needed according to its constituents measures are implemented to control fugitive dust emissions so that no openings exhibit visible emissions particulate collection devices are maintained and operated according to sound air pollution control practices. Verify that data is gathered from monitoring equipment and leak detection equipment, the site is inspected at least once every 7 days, and the results are recorded in the operating record. Verify that there is a written description of procedures to ensure that waste does not remain in the building for more than 90 days. Verify that there is documentation that the waste does not remain for more than 90 days. HW.85.4.US. Containment buildings are required to be certified by a registered Verify that the building has been certified by reviewing the documentation. 4 - 90 Hazardous Waste COMPLIANCE CATEGORY HAZARDOUS WASTE MANAGEMENT U.S. TEAM Guide REGULATORY REQUIREMENTS professional engineer CFR 262.34(a)(1)(iv) 265.1101(c)(2)). REVIEWER CHECKS March 2001 (40 and HW.85.5.US. Leaks in containment buildings must be repaired and reported (40 CFR 262.34(a)(1)(iv) and 265.1101(c)(3)). Verify that, if a condition is detected which could lead to a leak or has already caused a leak, it is repaired promptly. HW.85.6.US. Containment buildings that contain both areas with and with out secondary containment must meet specific requirements (40 CFR 262.34(a)(1)(iv) and 265.1101(d)). Verify that each area is designed and operated according to the appropriate requirements. HW.85.7.US. When a containment building is closed, specific requirements must be met (40 CFR 262.34(a)(1)(iv) and 265.1102). Determine if a containment building has been closed recently. Verify that, when a leak is discovered: the discovery is recorded in the operating record the portion of the containment building that is affected is removed from service a cleanup and repair schedule is established within 7 days the Regional Administrator is notified and within 14 working days written notice is provided to the Regional Administrator the Regional Administrator is notified upon the completion of all repairs, and that certification from a registered professional engineer is also submitted. Verify that measures are taken to prevent the release of liquids or wet materials into areas without secondary containment. Verify that a written description is maintained in the operating log of operating procedures used to maintain the integrity of areas without secondary containment. Verify that, at closure, all waste residues, contaminated containment system components, contaminated subsoils, and structures and equipment contaminated with waste and leachate were removed or decontaminated. Verify that the containment building is closed in accordance with closure and postclosure requirements for TSDFs as outlined in the sections titled Closure and Documentation Requirements. Verify that, if it is found that not all contaminated subsoils can be practicably removed or decontaminated, the site is closed and landfill postclosure requirements are implemented. 4 - 91 Hazardous Waste COMPLIANCE CATEGORY HAZARDOUS WASTE MANAGEMENT U.S. TEAM Guide REGULATORY REQUIREMENTS GENERATORS REVIEWER CHECKS March 2001 (NOTE: See Appendix 4-7 for a summary of recordkeeping and notification requirements.) HW.90 Disposal of Restricted Waste HW.90.1.US. Generators must test their wastes or use process knowledge to determine if the wastes are restricted from land disposal (40 CFR 268.7(a)(1)) [Revised June 1998]. Determine whether the generator tests for restricted wastes. HW.90.2.US. When a generator is managing a waste or soil that does not meet treatment standards, a written notice must be issued to the TSDF stating the appropriate treatment standards and prohibition levels (40 CFR 268.7(a)(2), and 268.7(a)(3)) [Revised January 2000]. Verify that, for waste or soil that does not meet the applicable treatment standards or exceeds the applicable prohibition levels, the notice is issued and includes: Determine if restricted wastes are generated by reviewing test results (see Appendix 4-8). the USEPA hazardous waste number waste constituents that the treater will monitor, if monitoring will not include all regulated constituents, for wastes F001 - F005, F039, D001, D002, D003, and D012 - D043 whether the waste is a nonwastewater or wastewater the subcategory of the waste for hazardous debris, the contaminants subject to treatment, and indication that the contaminants are being treated plus: the USEPA hazardous waste number waste constituents that the treater will monitor, if monitoring will not include all regulated constituents, for wastes F001 - F005, F039, D001, D002, D003, and D012 - D043 whether the waste is a nonwastewater or wastewater the subcategory of the waste a certification statement for contaminated soil. Verify a copy of the notice is placed on file as well. Verify that, for wastes or contaminated soil that meets the treatment standard at the original point of generation, the one-time written notice is issued and includes: the USEPA hazardous waste and manifest number the waste is subject to LDRs and the constituents of concern for F001 - F005 and F039, and underlying hazardous constituents (for wastes that are not managed in a CWA or CWA-equivalent facility), unless the waste will be treated and monitored for all constituents (NOTE: If all wastes will be treated and monitored, there is no need to put them on the LDR notice.) whether the waste is a nonwastewater or wastewater and subdivision made 4 - 92 Hazardous Waste COMPLIANCE CATEGORY HAZARDOUS WASTE MANAGEMENT U.S. TEAM Guide REGULATORY REQUIREMENTS REVIEWER CHECKS March 2001 within a waste code based on waste specific criteria waste analysis data a certification statement as outlined in 40 CFR 268.7(a)(3). Verity that, for waste or contaminated soil that meets the treatment standard at the original point of generation, if the waste changes, the generator sends a new notice and certification to the receiving facility and places a copy in their files. (NOTE: Generators of hazardous debris excluded from the definition of hazardous waste under 40 CFR 261.3(f) are not subject to the requirements for waste or contaminated soil which meets the treatment standard at the original point of generation.) Verify that, for restricted waste that is subject to an exemption from a prohibition of the type of land disposal used, the notice states that the waste is not prohibited from land disposal and includes: the USEPA hazardous waste and manifest number statement that this waste is not prohibited from land disposal waste analysis data when available date the waste is subject to the prohibition for hazardous debris, when treating with alternative treatment technologies, the contaminants subject to treatment and an indication that these contaminants are being treated to comply with 40 CFR 268.45. HW.90.3.US. Generators that are managing prohibited wastes in tanks, containers, or containment buildings and treating the waste to meet applicable treatment standards, must develop and follow a written waste analysis plan (40 CFR 268.7(a)(5)) [June 1997]. Verify that the plan describes the procedures the generator will carry out to comply with treatment standards. HW.90.4.US. Generators are required to keep specific documents pertaining to restricted wastes onsite (40 CFR 268.7(a)(6) through 268.7(a)(8)) [Revised June 1998]. Verify that, if the generator is using generator knowledge to determine whether a waste or contaminated soil meets land disposal restriction requirements, the supporting data used in making this determination is retained onsite. (NOTE: Generators treating hazardous debris under the alternative treatment standards are not required to conduct waste analysis.) Verify that the plan is kept onsite and: the plan is based on a detailed chemical and physical analysis of a representative sample of the prohibited waste being treated contains all information necessary to treat the wastes in accordance with regulatory requirements, including the selected testing frequency the plan is kept in the onsite files and made available to inspectors. Verify that, if the generator has determined whether a waste or contaminated soil is restricted using appropriate test methods, the waste analysis data is retained onsite. 4 - 93 Hazardous Waste COMPLIANCE CATEGORY HAZARDOUS WASTE MANAGEMENT U.S. TEAM Guide REGULATORY REQUIREMENTS REVIEWER CHECKS March 2001 Verify that, if the generator has determined they are managing a restricted waste excluded from the definition of a hazardous waste or solid waste or exempt from RCRA Subtitle C, a one-time notice is placed in the generator’s files stating that the generated waste is excluded and the disposition of the waste. Verify that a copy of all notices, certifications, demonstrations, waste analysis data, and other documentation is kept for at least 3 yr from the date the waste was last sent to an onsite or offsite TSDF.. HW.90.5.US. Generators who first claim that hazardous debris is excluded from the definition of hazardous waste are required to meet specific notification and certification requirements (40 CFR 268.7(d)) [June 1997]. Verify that a one-time notification is submitted to the director or authorized state including the following: the name and address of the facility receiving the treated waste a description of the hazardous debris as initially generated, including the applicable USEPA hazardous waste codes, treatability groups, and underlying hazardous constituents for excluded debris, the technology used to treat the debris. Verify that the notification is updated if the debris is shipped to a different facility. Verify that, for debris which is excluded, if a different type of debris is treated or if a different technology is used to treat the debris, the notification is updated. HW.90.6.US. The storage of hazardous waste that is restricted from land disposal is not allowed unless specific conditions are met (40 CFR 268.50). Verify that land disposal restricted waste is not stored onsite unless: the generator is storing the wastes in tanks, containers, or containment buildings onsite only for the purpose of accumulating enough quantity of hazardous waste to facilitate proper recovery, treatment, or disposal and all appropriate standards for containers, tanks, and containment buildings are met. (NOTE: If the 90-day storage period is exceeded, the generator is required to be permitted as a TSDF.) Verify that transporters do not store manifested shipments of land disposal restricted wastes for more than 10 days. (NOTE: The prohibition on storage does not apply to hazardous wastes that have met treatment standards.) Verify that liquid hazardous wastes containing PCBs at concentrations greater than 50 ppm are stored at a site which meets the requirements of 40 CFR 761.65(b) (see the section titled Toxic Substances Management) and is removed from storage within 1 yr of the date it was first placed into storage. 4 - 94 Hazardous Waste COMPLIANCE CATEGORY HAZARDOUS WASTE MANAGEMENT U.S. TEAM Guide REGULATORY REQUIREMENTS REVIEWER CHECKS March 2001 4 - 95 Hazardous Waste COMPLIANCE CATEGORY HAZARDOUS WASTE MANAGEMENT U.S. TEAM Guide REGULATORY REQUIREMENTS HW.100 TRANSPORTATION OF HAZARDOUS WASTE HW.100.1.US. Transporters of hazardous waste that is required to be manifested must have an USEPA identification number and must comply with manifest management requirements (40 CFR 263.10(a), 263.10(b), 263.11, 263.20(a) through 263.20(d), 263.21, and 263.22(a)). REVIEWER CHECKS March 2001 (NOTE: These requirements do not apply to the onsite transportation of hazardous waste. Nor do they apply to CESQGs (40 CFR 261.5(b) [Revised December 1997].) Determine who transports hazardous waste offsite. Verify that the transporter has a USEPA identification number. Verify that all waste accepted, transported, or offered for transport is accompanied by a manifest. Verify that, prior to transport, the transporter signs and dates the manifest and returns a copy to the generator prior to leaving.. Verify that, if the facility is transporter, a copy of the manifest is retained after delivery. Verify that manifests are kept on file for 3 yr. (NOTE: Special issues involved in the transportation of hazardous waste by air, rail, or water are not addressed in this guide.) HW.100.2.US. Before transporting hazardous waste or offering hazardous waste for transportation offsite in the United States, the waste must be packaged and labeled in accordance with DOT regulations contained in 49 CFR 172, 173, 178, and 179 (40 CFR 262.30 through 262.33). Determine what pretransport procedures for hazardous waste are used. Verify that containers are properly constructed and contain no leaks, corrosion, or bulges by inspecting a sample of containers awaiting transport. Examine end-seams for minor weeping that indicates drum failure. Verify that labeling and marking on each container is appropriate for the contents. Verify that the following information is displayed on a random sample of containers of 110 gal or less in accordance with 49 CFR 172.304: HAZARDOUS WASTE Federal Law Prohibits Improper Disposal. If found, contact the nearest police or public safety authority or the U.S. Environmental Protection Agency. Generator's name and address Manifest Document Number____ . Verify that proper DOT placarding is available for the transporter. 4 - 96 Hazardous Waste COMPLIANCE CATEGORY HAZARDOUS WASTE MANAGEMENT U.S. TEAM Guide REGULATORY REQUIREMENTS REVIEWER CHECKS March 2001 HW.100.3.US. Transporters of waste offsite must take immediate notification and clean-up action if a discharge occurs during transport (40 CFR 263.30 and 263.31). Verify that transport operators have instructions to notify local authorities and take cleanup action so the discharge does not present a hazard. HW.100.4.US. The onsite transportation of hazardous wastes between buildings should be accomplished in accordance with good management practices to help prevent spills, releases, and accidents (MP). Determine if procedures exist to manage the onsite movement of hazardous wastes. HW.100.5.US. Transporters must not store manifested shipments in containers meeting DOT packaging requirements for more than 10 days at a transfer facility (40 CFR 263.12). Determine if there is a transfer facility. Verify that transporters give notice to the NRC and report in writing as required by 49 CFR 171.15 and 171.16. Determine if drivers are trained in spill control procedures. Determine if provisions have been made for securing wastes in vehicles when transporting. Verify the following: transfer facility storage is for 10 days or less DOT packaging requirements are met shipments are manifested and manifests accompany shipments storage is consistent with good management practices. (NOTE: Storage for more than 10 days will require a TSDF permit.) 4 - 97 Hazardous Waste COMPLIANCE CATEGORY HAZARDOUS WASTE MANAGEMENT U.S. TEAM Guide REGULATORY REQUIREMENTS HW.102 REVIEWER CHECKS March 2001 (NOTE: See the definition of Military Munitions and the definition of Waste Munitions. These regulations are effective 12 August 1997.) MILITARY MUNITIONS HW.102.1.US. Unless specific requirements are met, waste military munitions in storage that exhibit a hazardous waste characteristic, or are listed as hazardous waste, must be managed according to the requirements in 40 CFR 260 through 40 CFR 279 (40 CFR 266.205(a), 266.205(c), and 40 CFR 266.205(d)). [Revised June 1998]. (NOTE: See HW.167, ALL TSDFs - Hazardous Waste Munitions and Explosives Storage for storage requirements when waste munitions and explosives are not exempted.) Verify that, when waste military munitions in storage that exhibit a hazardous waste characteristic, or are listed as hazardous waste, are not managed according to the requirements in 40 CFR 260 through 40 CFR 279, all of the following conditions are met: the waste military munitions are not chemical agents or chemical munitions the waste military munitions are subject to the jurisdiction of the Department of Defense Explosives Safety Board (DDESB) the waste military munitions are stored in accordance with DDESB storage standards applicable to waste military munitions within 90 days of 12 August 1997, or within 90 days of when a storage unit is first used to store waste military munitions, whichever is later, the USEPA Director is notified of the location of any waste storage unit used to store waste military munitions for which the exemption is claimed oral notice is provided to the USEPA Director within 24 h from the time the installation becomes aware of any loss or theft of the waste military munitions or of any failure to meet the conditions of this exemption written submission of the theft circumstances is provided within 5 days from the time of theft awareness or any failure to meet the conditions of the exemption inventory the waste military munitions annually inspect the waste military munitions at least quarterly maintain records of findings of inventories and inspections for at least 3 yr. limit access to the stored waste military munitions to appropriately trained and authorized personnel. (NOTE: This exemption only applies to storage requirements, not transportation, treatment, or disposal.) (NOTE: If a facility loses its conditional exemption, an application may be filed with the USEPA Director of reinstatement.) Verify that, if all of the above requirements are not met for waste military munitions in storage that exhibit a hazardous waste characteristic, or are listed as hazardous waste, the munitions are managed according to the requirements in 40 CFR 260 through 40 CFR 279. (NOTE: Waste military munitions that are chemical agents or chemical munitions and that exhibit a hazardous waste characteristic or are listed as hazardous waste 4 - 98 Hazardous Waste COMPLIANCE CATEGORY HAZARDOUS WASTE MANAGEMENT U.S. TEAM Guide REGULATORY REQUIREMENTS REVIEWER CHECKS March 2001 are required to be managed according to the requirements of RCRA Subtitle C, except that they are not subject to the prohibitions on storage of restricted wastes found in 40 CFR 268.50.) HW.102.2.US. The USEPA Director must be notified when a facility previously identified to the Director will no longer be used to store waste military munitions (40 CFR 266.205(b)) [February 1997]. Verify that the USEPA Director has been notified if a facility previously identified to the Director will no longer be used to store waste military munitions. HW.102.3.US. Checklist item deleted [Deleted June 1998]. Checklist item incorporated into HW.102.1. HW.102.4.US. The treatment and disposal of hazardous waste military ammunition must meet the applicable permitting, procedures, and technical standards in 40 CFR parts 260 through 270 (40 CFR 266.206) [February 1997]. Verify that the treatment and disposal of hazardous waste military munitions meets the applicable permitting, procedures, and technical standards in 40 CFR parts 260 through 270. 4 - 99 Hazardous Waste COMPLIANCE CATEGORY HAZARDOUS WASTE MANAGEMENT U.S. TEAM Guide REGULATORY REQUIREMENTS REVIEWER CHECKS March 2001 ALL TSDFs HW.105 General HW.105.1.US. All permitted TSDFs are required to meet the hazardous waste management requirements outlined in their permit (40 CFR 270.10 and 270.30 through 270.33). Verify that the TSDF is not treating, storing, or disposing of waste other than those listed in their Part A application, Part A permit, or Part B permit. HW.105.2.US. All TSDFs that have interim status are required to meet the hazardous waste management requirements of 40 CFR 265 and apply for a Part B permit (40 CFR 270.71 and 270.73(g)). Determine if the TSDF is an interim status TSDF. Verify that the TSDF is meeting the requirements outlined in the permit for the following: reporting and recordkeeping compliance schedules allowable wastes allowable activities. Verify that the TSDF is only treating, storing, or disposing of wastes listed in their Part A application. Verify that the TSDF is meeting all applicable requirements for interim status TSDFs outlined in 40 CFR 265. Verify that the TSDF has submitted a Part B permit application. HW.105.3.US. All TSDFs that store, treat, transport, or handle hazardous wastes must obtain an USEPA identification number (40 CFR 264.11 and 265.11). Examine documentation from USEPA for the generator, transporter, or TSDF identification number. HW.105.4.US. TSDFs must control entry to the active portion of the TSDF (40 CFR 264.14 and 265.14). Verify that, unless the TSDF can demonstrate physical contact with the waste, structures and equipment within the active portion of the TSDF will not injure unknowing or unauthorized person or livestock, and that the waste would not be disturbed, the following items are in place at the TSDF: Verify that the correct identification number is used on all appropriate documentation (i.e., manifests). a 24-h surveillance system (e.g., television monitors, surveillance by guards) is in place and in operation or the TSDF is surrounded by a fence or natural barrier controlled entry is provided (an attendant, television monitors, locked 4 - 100 Hazardous Waste COMPLIANCE CATEGORY HAZARDOUS WASTE MANAGEMENT U.S. TEAM Guide REGULATORY REQUIREMENTS REVIEWER CHECKS March 2001 entrances, controlled roadway access) signs with the wording DANGER UNAUTHORIZED PERSONNEL KEEP OUT, are posted at each entrance and other locations as appropriate and are legible from 25 ft signs are in English and other predominant languages. (NOTE: The requirement for surveillance systems or a fence and controlled entry are satisfied if the facility or plant within which the active portion is located itself has a surveillance system, or a barrier, and means to control entry.) HW.105.5.US. All TSDFs must be designed, constructed, maintained, and operated to minimize the possibility of a fire, explosion, or any unplanned release of hazardous waste (40 CFR 264.30 through 264.37 and 265.30 through 265.37). Determine if the following required equipment is easily accessible and in working condition by inspecting the TSDF: an internal communications or alarm system capable of providing immediate emergency instruction to TSDF personnel a telephone or hand-held two-way radio portable fire extinguishers and special extinguishing equipment (foam, inert gas, or dry chemicals) spill control equipment decontamination equipment fire hydrants or another source of water (reservoir, storage tank, etc.) with adequate volume and pressure, foam producing equipment, automatic sprinklers, or water spray systems. Determine if equipment is tested and maintained as necessary to ensure proper operation in an emergency. Verify that sufficient aisle space is maintained to allow unobstructed movement of personnel, fire protection equipment, spill control equipment, and decontamination equipment to any area of the operation. Verify that police, fire department, and emergency response teams are familiar with the layout of the TSDF, properties of the waste being handled, and general operations, unless they have declined such an arrangement. Verify that the hospital is familiar with the properties of hazardous waste handled and the types of injuries that could result in an emergency. (NOTE: When state or local police, fire departments, emergency response teams, or hospitals decline to enter into arrangements, than the refusal must be documented.) HW.105.6.US. All TSDFs must take precautions to prevent accidental ignition or Verify from the operating record and/or observation that the following safe management practices are used: 4 - 101 Hazardous Waste COMPLIANCE CATEGORY HAZARDOUS WASTE MANAGEMENT U.S. TEAM Guide REGULATORY REQUIREMENTS REVIEWER CHECKS March 2001 reaction of ignitable or reactive wastes (40 CFR 264.17(a) and 265.17(a)). wastes are separated and protected from sources of ignition or reaction smoking and open flame is confined to specially designated locations when ignitable or reactive wastes is handled NO SMOKING signs are used when necessary. HW.105.7.US. When TSDFs are required by specific treatment, storage, or disposal sections to prevent reactions from ignitable, reactive, or incompatible wastes, specific standards must be met (40 CFR 264.17(b) and 265.17(b)). Verify from the operating record and/or observation that, during treatment, storage, or disposal of ignitable or reactive wastes or during mixing of incompatible wastes and other materials, precautions are taken to prevent the following reactions: HW.105.8.US. A detailed chemical and physical analysis of a representative sample, as specified in the waste analysis plan, of the hazardous waste must be obtained prior to treatment, storage or disposal (40 CFR 264.13(a) and 265.13(a)). Verify that a detailed physical and chemical analysis is done of a representative sample of the wastes prior to treatment, storage, or disposal. HW.105.9.US. Each TSDF must have an emergency coordinator on the TSDF premises or on call at all times (40 CFR 264.55 and 265.55). Verify that, at all times, there is at least one employee at the TSDF or on call with responsibility for coordinating all emergency response measures. HW.105.10.US. TSDF emergency coordinators must follow certain emergency procedures when ever there is an imminent or actual emergency situation (40 CFR Review the contingency plan for the TSDF. generation of extreme heat or pressure, fire or explosions, or violent reactions production of uncontrolled toxic mists, fumes, dusts, or gases sufficient to threaten human health or the environment production of uncontrolled flammable fumes or gases sufficient to pose a risk of fire or explosions damage to the structural integrity of the device or facility threats to human health or the environment through other like means. (NOTE: Prior studies or published information may be included as a part of the analysis.) Verify that the analysis is repeated as necessary to ensure it is accurate and up to date, specifically when the process or operation generating the waste has changed. Verify that the emergency coordinator is thoroughly familiar with the TSDF, the characteristics of the waste handled, and the provisions of the contingency plan. In addition, verify that the emergency coordinator has the authority to commit the resources needed to carry out the contingency plan. Verify that the emergency coordinator is required to follow these emergency procedures: immediately activate TSDF alarms or communication systems and notify 4 - 102 Hazardous Waste COMPLIANCE CATEGORY HAZARDOUS WASTE MANAGEMENT U.S. TEAM Guide REGULATORY REQUIREMENTS 264.56(a) through 264.56(i) and 265.56(a) through 265.56(i)). REVIEWER CHECKS March 2001 appropriate TSDF, state, and local response parties identify the character, exact source, amount, and real extent of any released materials assess possible hazards to human health or the environment, including direct and indirect effects (e.g., release of gases, surface runoff from water or chemicals used to control fire or explosions, etc.) stop processes and operations at the TSDF when necessary to prevent fires, explosions, or further releases collect and contain the released waste remove or isolate containers when necessary monitor for leaks, pressure buildup, gas generation, or ruptures in valves, pipes, or other equipment whenever appropriate provide for treatment, storage, or disposal of recovered waste, contaminated soil or surface water, or other material ensure that no waste which may be incompatible with the released material is treated, stored, or disposed of until cleanup is completed ensure that all emergency equipment is cleaned and fit for its intended use before operations are resumed notify the USEPA and appropriate state and local authorities when cleanup is complete and operation resumes. 4 - 103 Hazardous Waste COMPLIANCE CATEGORY HAZARDOUS WASTE MANAGEMENT U.S. TEAM Guide REGULATORY REQUIREMENTS REVIEWER CHECKS March 2001 ALL TSDFs HW.110 Personnel Training HW.110.1.US. All TSDF personnel who handle hazardous waste must meet certain training requirements (40 CFR 264.16(a) through 264.16(c) and 265.16(a) through 265.16(c)). Verify that the training program is directed by a person trained in hazardous waste management procedures. Verify that the training program includes the following: contingency plan implementation (emergency procedures, equipment, and systems) key parameters for automatic waste feed cut-off system procedures for using, inspecting, and repairing emergency and monitoring equipment operation of communications and alarm systems response to fire or explosion response to leaks or spills. Verify that new employee training is completed within 6 mo of employment. Verify that an annual review of initial training is provided. Verify that employees do not work unsupervised until training is completed. Verify specifically that accumulation point managers and hazardous waste handlers have been trained. HW.110.2.US. Training records must be maintained for all TSDF staff who manage hazardous waste (40 CFR 264.16(d), 264.16(e), 265.16(d), and 265.16(e)). Verify through examination that training records include the following: job title and description for each employee by name written description of how much training each position will obtain documentation of training received by name. Determine if training records are retained for 3 yr after employment at the TSDF terminates or until closure of the facility. 4 - 104 Hazardous Waste 4 - 105 Hazardous Waste COMPLIANCE CATEGORY HAZARDOUS WASTE MANAGEMENT U.S. TEAM Guide REGULATORY REQUIREMENTS ALL TSDFs HW.115 Containers HW.115.1.US. Empty containers at TSDFs previously holding hazardous wastes must meet the regulatory definition of empty before they are exempted from hazardous waste requirements (40 CFR 261.7). REVIEWER CHECKS March 2001 (NOTE: See Appendix 4-8a for guidance on the schedule for implementation of air emissions standards in 40 CFR 265.1080 through 265.1090. Also in relation to the requirements for air emissions standard, see the definition of Exempted Hazardous Waste Containers and Surface Impoundments and Exempted Hazardous Waste Management Unit. There are documentation requirements for exempted containers.) Verify that, for containers or inner liners holding hazardous wastes, the following is done: wastes are removed that can be removed using common practices and no more than 2.5 cm [1 in.] of residue remains if the container is less than or equal to 110 gal, no more than 3 percent by weight of total container capacity remains when the container is greater than 110 gal, no more than 0.3 percent by weight of the total container capacity remains. Verify that, for containers which held a compressed gas, the pressure in the container approaches atmospheric. Verify that, for containers or inner liners which hold an acute hazardous waste listed in Appendix 4-5, one of the following is done: it is triple rinsed it is cleaned by another method identified through the literature or testing as achieving equivalent removal the inner liner is removed. HW.115.2.US. Containers used to store hazardous waste at TSDFs must be in good condition and not leaking (40 CFR 264.171 and 265.171). Verify that containers are not leaking, bulging, rusting, damaged, or dented. HW.115.3.US. Containers used at TSDFs must be made of or lined with materials compatible with the waste stored in them (40 CFR 264.172 and 265.172). Verify that containers are compatible with the waste, in particular, check that strong caustics and acids are not stored in metal drums. HW.115.4.US. Containers at Verify that containers are closed except when it is necessary to add or remove Verify that waste is transferred to a new container or managed in another appropriate manner when necessary. 4 - 106 Hazardous Waste COMPLIANCE CATEGORY HAZARDOUS WASTE MANAGEMENT U.S. TEAM Guide REGULATORY REQUIREMENTS REVIEWER CHECKS March 2001 TSDFs must be closed during storage and handled in a safe manner (40 CFR 264.173 and 265.173). waste (check bungs and look for open funnels). HW.115.5.US. The handling of incompatible wastes, or incompatible wastes and materials in containers at TSDFs must comply with safe management practices (40 CFR 264.17(b), 264.177, 265.17(b), and 265.177). Verify that incompatible wastes or incompatible wastes and materials are not placed in the same containers unless it is done so that it does not: Verify that handling and storage practices do not cause damage to the containers or cause them to leak. generate extreme heat or pressure, fire, explosion, or violent reaction produce uncontrolled toxic mists, fumes, dusts, or gases in sufficient quantities to threaten human health produce uncontrolled flammable fumes or gases in sufficient quantities to pose a risk of fire or explosions damage the structural integrity of the device or TSDF by any other like means threaten human health. (NOTE: Incompatible wastes as listed in Appendix 4-6 should not be placed in the same containers.) Verify that hazardous wastes are not placed in an unwashed container which previously held an incompatible waste or material. Verify that containers holding hazardous wastes incompatible with wastes stored nearby in other containers, open tanks, piles, or surface impoundments are separated or protected from each other by a dike, berm, wall, or other device. HW.115.6.US. Containers of hazardous waste at TSDFs should be managed in accordance with specific management practices (MP). Verify the following by inspecting the container storage areas: HW.115.7.US. Containers with design capacities greater than 0.1 m3 [ 26 gal] and less than or equal to 0.46 m3 [ 122 gal] into which hazardous waste is placed are required to meet specific design and operating standards (40 CFR 264.1086(a) through 264.1086(b)(1)(i), 264.1086(c); 265.1087(a) (NOTE: The requirements of 40 CFR 264.1986 and 265.1087 do not apply to containers in which all the hazardous waste entering the container meets one of the following [see also the definition for exempted hazardous waste containers and surface impoundments] (40 CFR 264.1082(c) and 40 CFR 265.1083(c): the average VO concentration of the hazardous waste at the point of waste origination is less than 500 ppmw the organic content of the hazardous waste has been reduced by an organic destruction or removal process the waste meets the numerical concentration limits for organic hazardous constituents as specified in 40 CFR 268.40 or has been treated by the treatment technology established by the USEPA for the waste in 268.42(a) or containers are not stored more than two high and have pallets between them containers of highly flammable wastes are electrically grounded (check for clips and wires and make sure wires lead to ground rod or system) at least 3 ft of aisle space is provided between rows of containers. 4 - 107 Hazardous Waste COMPLIANCE CATEGORY HAZARDOUS WASTE MANAGEMENT U.S. TEAM Guide REGULATORY REQUIREMENTS through 265.1087(b)(1)(i), and 265.1087(c)) [Revised December 1997]. REVIEWER CHECKS March 2001 an equivalent method.) (NOTE: These requirements do not apply to a container that has a design capacity less than or equal to 0.1 m3 [ 26 gal] (40 CFR 264.1080(b)(2) and 40 CFR 265.1080(b)(2).) (NOTE: Standards for containers used in waste stabilization processes (40 CFR 264.1086(b)(2) and 265.1087(b)(2)) are in checklist item HW.115.9.) Verify that, for containers with a design capacity greater than 0.1 m3 and less than or equal to 0.46 m3 [ 122 gal], air emissions are controlled according to the following Container Level 1 standards: a container is used that meets applicable U.S. DOT regulations on the packaging of hazardous materials for transportation a container is used that is equipped with a cover and closure devices that form a continuous barrier over the container openings so that when the cover and closure devices are secured in the closed position there are not visible holes, gaps, or other open spaces into the interior of the container an open-top container is used in which an organic vapor suppressing barrier is placed on or over the hazardous waste in the container so that no hazardous waste is exposed to the atmosphere. Verify that, when a container using Level 1 standards, other than DOT approved containers, are used, they are equipped with covers and closure devices composed of suitable materials to minimize exposure, to the extent practical, of the hazardous waste to the atmosphere and to maintain the equipment integrity throughout the intended service life. Verify that, whenever waste is in a container using Level 1 controls, covers and closure devices are installed and closure devices are secured and maintained in the closed position except as follows: opening of a closure device or cover is allowed for adding waste or other material to the container as follows: when the container is filled to the intended final level in one continuous operation, the closure devices are secured in the closed position and the covers installed at the conclusion of the filling operation when discrete batches or quantities of material are added intermittently to the container over a period of time, the closure devices are secured in the closed position and covers installed upon either: the container being filled to the intended final level the completion of a batch loading after which no additional material will be added to the container within 15 min the person performing the loading operation leaving the immediate vicinity of the container the shutdown of the process generating the material being added 4 - 108 Hazardous Waste COMPLIANCE CATEGORY HAZARDOUS WASTE MANAGEMENT U.S. TEAM Guide REGULATORY REQUIREMENTS REVIEWER CHECKS March 2001 to the container, whichever condition occurs first opening of a closure device or cover is allowed for removing the hazardous waste as follows: in order to meet the requirements for an empty container when discrete quantities or batches of material are removed from the container but the container is not empty, the closure devices are promptly returned to the closed position and the covers installed upon either: completion of batch removal after which no additional material is removed within 15 min the person performing the unloading leaves the immediate vicinity, whichever condition occurs first opening of a closure device or cover is allowed when access inside the container is needed to perform routine activities other than transfer of hazardous waste opening of a spring loaded, pressure vacuum relief valve, conservation vent, or similar type of pressure relief device which vents to the atmosphere is allowed during normal operations for the purpose of maintaining internal container pressure opening of a safety device to avoid unsafe conditions. HW.115.8.US. Containers with design capacities greater than 0.46 m3 [ 122 gal] into which hazardous waste is placed are required to meet specific design and operating standards (40 CFR 264.1086(a), 264.1087(b)(1)(ii) through 264.1086(b)(1)(iii), 264.1086(c)(1) through 264.1086(c)(3), and 264.1086(d); 265.1087(a), 265.1087(b)(1)(ii) through 265.1087(b)(1)(iii), 265.1087(c)(1) through 265.1087c(3), and 265.1087(d)) [December 1996]. (NOTE: The requirements of 40 CFR 264.1086 and 265.1087 do not apply to containers in which all the hazardous waste entering the container meets one of the following [see also the definition for exempted hazardous waste containers and surface impoundments] (40 CFR 264.1082(c) and 40 CFR 265.1083(c)): the average VO concentration of the hazardous waste at the point of waste origination is less than 500 ppmw the organic content of the hazardous waste has been reduced by an organic destruction or removal process the waste meets the numerical concentration limits for organic hazardous constituents as specified in 40 CFR 268.40 or has been treated by the treatment technology established by the USEPA for the waste in 268.42(a) or an equivalent method.) (NOTE: These requirements do not apply to a container that has a design capacity less than or equal to 0.1 m3 [ 26 gal] (40 CFR 264.1080(b)(2) and 40 CFR 265.1080(b)(2)).) (NOTE: Standards for containers used in waste stabilization processes (40 CFR 265.1087(b)(2)) are in checklist item HW.115.9.) Verify that, for containers with a design capacity greater than 0.46 m3 [ 122 gal] that are not in light material service, air emissions are controlled according to the following Container Level 1 standards: a container is used that meets applicable U.S. DOT regulations on the 4 - 109 Hazardous Waste COMPLIANCE CATEGORY HAZARDOUS WASTE MANAGEMENT U.S. TEAM Guide REGULATORY REQUIREMENTS REVIEWER CHECKS March 2001 packaging of hazardous materials for transportation a container is used that is equipped with a cover and closure devices that form a continuous barrier over the container openings so that when the cover and closure devices are secured in the closed position there are not visible holes, gaps, or other open spaces into the interior of the container an open-top container is used in which an organic vapor suppressing barrier is placed on or over the hazardous waste in the container so that no hazardous waste is exposed to the atmosphere. Verify that, for containers with a design capacity greater than 0.46 m3 [ 122 gal] that are in light material service, air emissions are controlled according to the following Container Level 2 standards: a container is used that meets applicable U.S. DOT regulations on the packaging of hazardous materials for transportation a container is used that operates with no detectable organic emissions a container is used that has been demonstrated within the preceding 12 mo to be vapor tight. Verify that, when a container using Level 1 standards, other than DOT-approved containers, is used, it is equipped with covers and closure devices composed of suitable materials to minimize exposure of the hazardous waste to the atmosphere and to maintain the equipment integrity for as long as it is in service. Verify that, whenever waste is in a container using Level 1 or Level 2 controls, covers and closure devices are installed and closure devices are secured and maintained in the closed position except as follows: opening of a closure device or cover is allowed for adding waste or other material to the container as follows: when the container is filled to the intended final level in one continuous operation, the closure devices shall be secured in the closed position and the covers installed at the conclusion of the filling operation when discrete batches or quantities of material are added intermittently to the container, over a period of time, the closure devices are secured in the closed position and covers installed upon either: the container being filled to the intended final level the completion of a batch loading after which no additional material will be added to the container within 15 min the person performing the loading operation leaving the immediate vicinity of the container the shutdown of the process generating the material being added to the container, whichever condition occurs first opening of a closure device or cover is allowed for removing the hazardous waste as follows: in order to meet the requirements for an empty container when discrete quantities or batches of material are removed from the container, but the container is not empty the closure devices will 4 - 110 Hazardous Waste COMPLIANCE CATEGORY HAZARDOUS WASTE MANAGEMENT U.S. TEAM Guide REGULATORY REQUIREMENTS REVIEWER CHECKS March 2001 promptly be returned to the closed position and the covers installed upon either: completion of batch removal after which no additional material will be removed within 15 min the person performing the unloading leaves the immediate vicinity, whichever condition occurs first opening of a closure device or cover is allowed when access inside the container is needed to perform routine activities other than transfer of hazardous waste opening of a spring loaded, pressure vacuum relief valve, conservation vent, or similar type of pressure relief device which vents to the atmosphere is allowed during normal operations for the purpose of maintaining internal container pressure opening of a safety device to avoid unsafe conditions. Verify that the transfer of hazardous waste in or out of containers meeting Container Level 2 controls is done in a manner to minimize exposure of the hazardous waste to the atmosphere (i.e., a submerged fill pipe, a vapor balancing system, a vapor recovery system, a fitted opening in the top of the container through which the hazardous waste is filled; subsequently purge the transfer line before removing it). HW.115.9.US. Containers with design capacities greater than 0.1 m3 [ 26 gal] used for the treatment of a hazardous waste by a waste stabilization process are required to meet specific design and operating standards (40 CFR 264.1086(a), 264.1086(b)(2), 264.1086(e)(1) through 264.1086(e)(3), 264.1086(e)(6); 265.1087(a), 265.1087(b)(2), 265.1087(e)(1) through 265.1087(e)(3), and 265.1087(e)(6)) [Revised April 1999] (NOTE: The requirements of 40 CFR 264.1086 and 265.1087 do not apply to containers in which all the hazardous waste entering the container meets one of the following [see also the definition for exempted hazardous waste containers and surface impoundments] (40 CFR 264.1082(c) and 40 CFR 265.1083(c): the average VO concentration of the hazardous waste at the point of waste origination is less than 500 ppmw the organic content of the hazardous waste has been reduced by an organic destruction or removal process the waste meets the numerical concentration limits for organic hazardous constituents as specified in 40 CFR 268.40 or has been treated by the treatment technology established by the USEPA for the waste in 268.42(a) or an equivalent method.) (NOTE: These requirements do not apply to a container that has a design capacity less than or equal to 0.1 m3 [ 26 gal] (40 CFR 264.1080(b)(2) and 40 CFR 265.1080(b)(2)).) (NOTE: Safety devices may be installed and operated as necessary.) Verify that containers with design capacities greater than 0.1 m3 [ 26 gal] used for the treatment of a hazardous waste by a waste stabilization process meet the following Container Level 3 standards at those times during the waste stabilization process when the hazardous waste in the container is exposed to the atmosphere: a container is used that is vented directly through a closed vent system to a 4 - 111 Hazardous Waste COMPLIANCE CATEGORY HAZARDOUS WASTE MANAGEMENT U.S. TEAM Guide REGULATORY REQUIREMENTS REVIEWER CHECKS March 2001 control device a container is used that is vented inside an enclosure that is exhausted through a closed vent system to a control device. Verify that, for Level 3 containers, the following requirements are met: the container enclosure is designed and operated in accordance with the criteria for a permanent total enclosure under 40 CFR 52.741 the closed vent system and control device is designed and operated in accordance with 264.1087 and 265.1088 (see checklist item HW.115.12). Verify that the transfer of hazardous waste in or out of a container using Container Level 3 controls is done in such a manner as to minimize exposure of the hazardous waste to the atmosphere, to the extent practical, considering the physical properties of the hazardous waste and good engineering and safety practices for handling flammable, ignitable, explosive, reactive, or other hazardous materials. (NOTE: Examples of container loading procedures that the USEPA considers to meet these requirements include using any one of the following: a submerged-fill pipe or other submerged-fill method to load liquids into the container a vapor-balancing system or a vapor-recovery system to collect and control the vapors displaced from the container during filling operations a fitted opening in the top of a container through which the hazardous waste is filled and subsequently purging the transfer line before removing it from the container opening.) HW.115.10.US. Facilities are required to have a written plan and schedule for inspection and monitoring requirements for containers and meet specific inspection requirements (40 CFR 264.1086(c)(4), 264.1086(d)(4), 264.1088; 265.1087(c)(4), 265.1087(d)(4), and 265.1089) [Revised December 1997]. (NOTE: These requirements do not apply to a container that has a design capacity less than or equal to 0.1 m3 [ 26 gal] (40 CFR 264.1080(b)(2) and 40 CFR 265.1080(b)(2)).) Verify that the facility has a written plan and schedule for performing inspections and monitoring. Verify that the plan and schedule are being met. Verify that inspections of the containers and their covers and closure devices for containers using Container Level 1 or Level 2 controls are done as follows: when a hazardous waste is already in the container at first acceptance and the container is not emptied within 24 h after it is accepted, the container and its cover are visually inspected on the date of acceptance for cracks, holes, gaps, or other open spaces into the interior of the container when the cover and closure devices are secured in the closed position when a container is used for managing hazardous waste for 1 yr or more, it is 4 - 112 Hazardous Waste COMPLIANCE CATEGORY HAZARDOUS WASTE MANAGEMENT U.S. TEAM Guide REGULATORY REQUIREMENTS REVIEWER CHECKS March 2001 visually inspected at least once every 12 mo for visible cracks, holes, gaps, or other open spaces when the cover and closure devices are secured in the closed position. Verify that, when a defect is detected, the first efforts at repairs are within 24 h after detection and repair is completed as soon as possible but no later than 5 calendar days after detection. (NOTE: If repair cannot be completed within 5 calendar days, the hazardous waste must be removed from the container.) HW.115.11.US. Facilities are required to meet documentation requirements for containers (40 CFR 264.1086(c)(5), 264.1089(a), 264.1089(d) through 264.1089(i); 265.1087(c)(5), 265.1090(a), and 265.1090(d) through 265.1090(i)) [December 1996]. (NOTE: These requirements do not apply to a container that has a design capacity less than or equal to 0.1 m3 [ 26 gal] (40 CFR 264.1080(b)(2) and 40 CFR 265.1080(b)(2)).) Verify that a copy of the procedure used to determine that containers with a capacity of 0.46 m3 [ 122 gal] or greater that do not meet DOT standards are not managing hazardous waste in light material service. Verify that, if using Container Level 3 air emissions controls, the facility prepares and maintains records that include: the most recent set of calculations and measurements performed by the owner/operator to verify that the enclosure meets the criteria of a permanent total enclosure as specified in 40 CFR 52.741, Appendix B all the records required for closed vent systems. Verify that, if using a closed-vent system and control device, the following records are maintained: certification that is signed and dated by the owner/operator stating that the control device is designed to operate at the performance level documented by a design analysis or by performance tests when the container is operating at capacity or the highest level reasonably expected to occur design documents if design analysis is used, including information describing the control device design and certification that the equipment meets the applicable specification a performance test plan if performance tests are used, and all test results description and date of each modification, as applicable identification of operating parameters, description of monitoring devices, and diagrams of monitoring sensor locations, as applicable semiannual records of the following for those planned routine maintenance operations that would require the control device to exceed limitations: a description of the planned routine maintenance that is anticipated to be performed for the control device during the next 6-mo period, including the type of maintenance needed, planned frequency, and lengths of 4 - 113 Hazardous Waste COMPLIANCE CATEGORY HAZARDOUS WASTE MANAGEMENT U.S. TEAM Guide REGULATORY REQUIREMENTS REVIEWER CHECKS March 2001 maintenance periods a description of the planned routine maintenance that was performed for the control device during the previous 6-mo period, including the type of maintenance performed and the total number of hours during those 6 mo that the control device did not meet applicable requirements records of the following for those unexpected control device system malfunctions that would cause the control device to not meet specifications: the occurrence and duration of each malfunction of the control device system the duration of each period during a malfunction when gases, vapors, or fumes are vented from the waste management unit through the closed vent system to the control device while the control device is not properly functioning actions taken during periods of malfunction to restore a malfunctioning control device to its normal or usual manner of operation records of the management of the carbon removed from a carbon adsorption system. Verify that, for exempted containers (see the definition of Exempted Hazardous Waste Containers and Surface Impoundments), the following records are prepared and maintained as applicable: if exempted under the hazardous waste concentration conditions, information used for the waste determination in the facility operating log and/or the date, time, and location of each waste sample if analysis results for samples are used if exempted under incineration use or process destruction use, the identification number for the incinerator, boiler, or industrial furnace in which the hazardous waste is treated. Verify that the covers designated as unsafe to monitor are listed in a log kept in the facility operating record with an explanation of why they are unsafe to inspect and monitor and a plan and schedule of inspection and monitoring is recorded. Verify that, for containers not using the air emissions controls specified in 40 CFR 265.1085 through 265.1088 (see checklist items HW.115.7 through HW.115.12), the following information is maintained: a list of the individual organic peroxide compounds manufactured at the facility if it produces more than one functional family of organic peroxides or multiple organic peroxides within one functional family, and one or more of these organic peroxides could potentially undergo self-accelerating thermal decomposition at or below ambient temperatures a description of how the hazardous waste containing the organic peroxide compounds identified in the above list are managed, including: a facility identification number for the container or group of containers the purpose and placement of this container or group of containers in the management train of this hazardous waste 4 - 114 Hazardous Waste COMPLIANCE CATEGORY HAZARDOUS WASTE MANAGEMENT U.S. TEAM Guide REGULATORY REQUIREMENTS REVIEWER CHECKS March 2001 the procedures used to ultimately dispose of the hazardous waste handled in the containers an explanation why managing these containers would be an undue safety hazard. Verify that all records, except design information records, are kept for at least 3 yr. Verify that design information records are maintained in the operating record until the air emissions control equipment is replaced or is otherwise no longer in service. HW.115.12.US. Facilities are required to meet specific requirements for closed vent systems and control devices used to achieve compliance (40 CFR 264.1087, and 265.1088) [Revised December 1997]. (NOTE: The requirements of 40 CFR 264.1087 and 265.1088 do not apply to containers in which all the hazardous waste entering the container meets one of the following (40 CFR 264.1082(c) and 40 CFR 265.1083(c): the average VO concentration of the hazardous waste at the point of waste origination is less than 500 ppmw the organic content of the hazardous waste has been reduced by an organic destruction or removal process the waste meets the numerical concentration limits for organic hazardous constituents as specified in 40 CFR 268.40 or has been treated by the treatment technology established by the USEPA for the waste in 268.42(a) or an equivalent method.) (NOTE: These requirements do not apply to a container that has a design capacity less than or equal to 0.1 m3 [ 26 gal] (40 CFR 264.1080(b)(2) and 40 CFR 265.1080(b)(2)).) Verify that closed vent systems meet the following: it routes the gases, vapors, and fumes emitted from the hazardous waste in the waste management unit to a control device it is designed and operated in accordance with 40 CFR 264.1033(j) or 265.1033(j) (see checklist item HW.135.2) if it includes bypass devices that could be used to divert the gas or vapor stream to the atmosphere before entering the control device, one of the following equipment requirements is met for each type of bypass device (NOTE: Low leg drains, high point bleeds, analyzer vents, open-ended valve or lines, spring loaded pressure relief valves, and other fittings used for safety purposes are not considered bypass devices): a flow indicator is installed, calibrated, maintained, and operated at the inlet to the bypass line used to divert gases and vapors from the closedvent system to the atmosphere at a point upstream of the control device inlet a seal or locking device is placed on the mechanism by which the bypass device position is controlled when the bypass valve is in the closed position so that the bypass device cannot be opened without breaking the seal or removing the lock. 4 - 115 Hazardous Waste COMPLIANCE CATEGORY HAZARDOUS WASTE MANAGEMENT U.S. TEAM Guide REGULATORY REQUIREMENTS REVIEWER CHECKS March 2001 Verify that the seal or closure mechanism is visually inspected at least once every month. Verify that one of the following control devices are used: a device designed and operated to reduce the total organic content of the inlet vapor stream vented to the control device by at least 95 percent by weight an enclosed combustion device designed and operated in accordance with 264.1033(c) and 265.1033(c) (see checklist item HW.135.2) a flare designed and operated in accordance with 40 CFR 264.1033(d) and 265.1033(d) (see checklist item HW.135.2). Verify that, when a closed vent system and control device is used, the following are met: periods of planned routine maintenance of the control device during which the device does not meet specifications do not exceed 240 h/yr control device system malfunctions are corrected as soon as practicable it is operated such that gases, vapors, and/or fumes are not actively vented to the control device during periods of planned maintenance or control device system malfunction, except in cases where it is necessary to do so in order to avoid an unsafe condition or to implement malfunction corrective actions or planned maintenance actions. Verify that, if a carbon adsorption system is used, the following requirements are met: all activated carbon is replaced with fresh carbon on a regular basis as outlined in 40 CFR 264.1033(g), 264.1033(h), 265.1033(g) and 265.1033(h) (see check list item HW.135.2) all carbon that is a hazardous waste and that is removed from the control device is managed according to 264.1033(n) or 265.1033(m) regardless of the average volatile organic concentration. Verify that, if a control device other than thermal vapor incinerators, flare, boiler, process heater, condenser, or carbon adsorption system are used, the requirements in 40 CFR 264.1033(i) and 265.1033(i) are met (see checklist item HW.135.2). Verify that, for control devices, it is demonstrated by either a performance test or a design analysis that the device achieves compliance except for the following: a flare a boiler or process heater with a design heat input capacity of 44 MW or greater a boiler or process heater into which the vent stream is introduced with the primary fuel a boiler or process heater burning hazardous waste for which the owner or 4 - 116 Hazardous Waste COMPLIANCE CATEGORY HAZARDOUS WASTE MANAGEMENT U.S. TEAM Guide REGULATORY REQUIREMENTS REVIEWER CHECKS March 2001 operator has been issued a final permit under 40 CFR 270 and has designed and operates the unit in accordance with the requirements of 40 CFR 266, subpart H a boiler or industrial furnace burning hazardous waste for which the owner or operator has certified compliance with the interim status requirements of 40 CFR 265, subpart H. Verify that the readings from each control device are inspected at least once each operating day to check control device operation. 4 - 117 Hazardous Waste COMPLIANCE CATEGORY HAZARDOUS WASTE MANAGEMENT U.S. TEAM Guide REGULATORY REQUIREMENTS REVIEWER CHECKS March 2001 ALL TSDFs HW.120 Container Storage Areas HW.120.1.US. Containers at TSDFs should be kept in storage areas designated in the management plan and identified by signs (MP). Verify that all containers are identified and stored in appropriate areas. HW.120.2.US. Containers holding ignitable or reactive waste must be located 15 m (50 ft) from the property line of a TSDF (40 CFR 264.176 and 265.176). Determine the distance from any storage containers to the property line. HW.120.3.US. TSDF personnel must conduct weekly inspections of container storage areas (40 CFR 264.174 and 265.174). Verify that inspections are conducted at least weekly to look for leaking containers and signs of deterioration of containers. (NOTE: Any unidentified contents of solid waste containers and/or containers not in designated storage areas must be tested to determine if solid or hazardous waste requirements apply.) 4 - 118 Hazardous Waste 4 - 119 Hazardous Waste COMPLIANCE CATEGORY HAZARDOUS WASTE MANAGEMENT U.S. TEAM Guide REGULATORY REQUIREMENTS ALL TSDFs HW.125 Containment Buildings REVIEWER CHECKS March 2001 (NOTE: According to the Background Information published on page 37211 of the 18 August 1992 edition of the Federal Register, a hazardous waste containment building involves "the management of a hazardous waste inside a unit designed and operated to contain the hazardous waste within the unit.” This is not a building that holds drums or tanks filled with hazardous waste, but a building that holds the hazardous waste itself.) HW.125.1.US. TSDFs with containment buildings that are in compliance are not subject to the definition of land disposal if specific requirements are met (40 CFR 264.1100 and 265.1100). Verify that the containment building meets the following: HW.125.2.US. Containment buildings are required to be designed according to specific standards (40 CFR 264.1101(a)(1) through 264.1101(a)(2), 264.1101(b), 265.1101(a)(1) through 265.1101(a)(2), and 265.1101(b)). Verify that containment buildings meet the following design standards: it is a completely enclosed, self-supporting structure that is designed and constructed of manmade materials of sufficient strength and thickness to support themselves, the waste contents, and any personnel and heavy equipment that operate within the unit it is designed to prevent failure due to pressure gradients, settlement, compression or uplift, physical contact with the hazardous wastes, climatic conditions, and the stress of daily operations it has a primary barrier that is designed to be sufficiently durable to withstand the movement of personnel, wastes, and handling of equipment within the unit if the unit is used to manage liquids: there is a primary barrier designed and constructed of materials to prevent migration of hazardous constituents into the barrier there is a liquid collection system designed and constructed of materials to minimize the accumulation of liquid on the primary barrier there is a secondary containment system designed and constructed of materials to prevent migration of hazardous constituents into the barrier, with a leak detection and liquid collection system capable of detecting, collecting, and removing leaks of hazardous constituents at the earliest practicable time it has controls sufficient to prevent fugitive dust emissions it is designed and operated to ensure containment and prevent the tracking of materials from the unit by personnel and equipment. it is completely enclosed with a floor, walls, and a roof to prevent exposure to the elements and to assure containment of wastes the floor and containment walls, including any required secondary containment system, are designed and constructed of manmade materials of sufficient strength and thickness to support themselves, the waste contents, and any personnel and heavy equipment that operate within the unit it is designed to prevent failure due to pressure gradients, settlement, compression or uplift, physical contact with the hazardous wastes, climatic conditions, and the stress of daily operations 4 - 120 Hazardous Waste COMPLIANCE CATEGORY HAZARDOUS WASTE MANAGEMENT U.S. TEAM Guide REGULATORY REQUIREMENTS REVIEWER CHECKS March 2001 it has sufficient structural strength to prevent collapse or other failure all surfaces in contact with hazardous wastes are compatible with the wastes it has a primary barrier that is designed to be sufficiently durable to withstand the movement of personnel, wastes, and handling of equipment within the unit and is appropriate for the chemical and physical characteristics of the waste. Verify that, if the containment building is going to manage hazardous wastes with free liquids or treated with free liquids, the following design requirements are also met: there is a primary barrier designed and constructed of materials to prevent migration of hazardous constituents into the barrier (e.g., a geomembrane covered by a concrete wear surface) there is a liquid collection and removal system designed and constructed of materials to minimize the accumulation of liquid on the primary barrier: the primary barrier is sloped to drain liquids to the associated collection system liquids and wastes are collected and removed to minimized hydraulic head on the containment system at the earliest practicable time there is a secondary containment system, including a secondary barrier, designed and constructed of materials to prevent migration of hazardous constituents into the barrier with a leak detection and liquid collection system capable of detecting, collecting, and removing leaks of hazardous constituents at the earliest practicable time the leak detection component of the secondary containment system meets the following: it is constructed with a bottom slope of 1 percent or more it is constructed of granular drainage materials with a hydraulic conductivity of 1 x 10-2 cm/s or more and a thickness of 12 in. (30.5 cm) or more, or constructed of synthetic or geonet drainage materials with a transmissivity of 3 x 10-5 m2/s or more if treatment is to be conducted in the building, the treatment area is designed to prevent the release of liquids, wet materials, or liquid aerosols to other portions of the building the secondary containment system is constructed of materials that are chemically resistant to the waste and liquids managed in the building and of sufficient strength and thickness to prevent collapse under pressure exerted by overlaying materials and by any equipment used. (NOTE: An exception to the structural strength requirement may be made for light- weight doors and windows based on the nature of the waste management operations if the following criteria are met: the doors and windows provide an effective barrier against fugitive dust emissions the unit is designed and operated in a manner that ensures the waste will not come in contact with the doors or windows.) 4 - 121 Hazardous Waste COMPLIANCE CATEGORY HAZARDOUS WASTE MANAGEMENT U.S. TEAM Guide REGULATORY REQUIREMENTS REVIEWER CHECKS March 2001 (NOTE: A containment building can serve as an external liner or a secondary containment systems for tanks within the building if: it meets the requirements of 264.193(d) (see Storage Tank Management) it meets the requirements of 264.193(b), 264.193(c)(1), and 264.193(c)(2) (see Storage Tank Management.) HW.125.3.US. Containment buildings are required to be operated according to specific standards (40 CFR 264.1101(a)(3), 264.1101(c)(1), 264.1101(c)(4), 265.1101(a)(3), 265.1101(c)(1), and 265.1101(c)(4)). Verify that incompatible wastes or treatment reagents are not placed in the building or its secondary containment system if they could cause the unit or the secondary containment system to leak, corrode, or otherwise fail. Verify that the following operational procedures are done: controls and practices are used to ensure the containment of the waste within the building the primary barrier is maintained so that it is free of significant cracks, gaps, corrosion, or other deterioration that could cause hazardous waste to be released from the primary barrier the level of the stored/treated hazardous waste is maintained so that the height of any containment wall is not exceeded measures are implemented to prevent the tracking of hazardous waste out of the unit by personnel or equipment used in the handling of the waste there is a designated area for the decontamination of equipment and collection of rinsate any collected rinsate is managed as needed according to its constituents measures are implemented to control fugitive dust emissions so that no openings exhibit visible emissions particulate collection devices are maintained and operated according to sound air pollution control practices. Verify that data is gathered from monitoring equipment and leak detection equipment, the site is inspected at least once every 7 days, and the results are recorded in the operating record. HW.125.4.US. Containment buildings are required to be certified by a registered professional engineer (40 CFR 264.1101(c)(2) and 265.1101(c)(2)). Verify that the building has been certified. HW.125.5.US. Leaks in containment buildings must be repaired and reported (40 Verify that, if a condition is detected which could lead to a leak or has already caused a leak, it is repaired promptly. 4 - 122 Hazardous Waste COMPLIANCE CATEGORY HAZARDOUS WASTE MANAGEMENT U.S. TEAM Guide REGULATORY REQUIREMENTS CFR 264.1101(c)(3) 265.1101(c)(3)). REVIEWER CHECKS March 2001 and Verify that, when a leak is discovered: the discovery is recorded in the TSDF operating record the portion of the containment building that is affected is removed from service a cleanup and repair schedule is established within 7 days the Regional Administrator is notified and within 14 working days written notice is provided to the Regional Administrator the Regional Administrator is notified upon the completion of all repairs, and certification from a registered professional engineer is also submitted. HW.125.6.US. Containment buildings that contain both areas with and without secondary containment must meet specific requirements (40 CFR 264.1101(d) and 265.1101(d)). Verify that each area is designed and operated according to the requirements in 40 CFR 264.1101(a) through 264.1101(c) and 265.1101(a) through 265.1101(c) (see checklist items HW.125.2 through HW.125.5). Verify that measures are taken to prevent the release of liquids or wet materials into areas without secondary containment. Verify that a written description is maintained in the TSDF operating log of operating procedures used to maintain the integrity of areas without secondary containment. HW.125.7.US. When a containment building is closed, specific requirements must be met (40 CFR 264.1102 and 265.1102). Determine if the TSDF has closed a containment building recently. Verify that, at closure, all waste residues, contaminated containment system components, contaminated subsoils, and structures and equipment contaminated with waste and leachate were removed or decontaminated. Verify that the containment building is closed in accordance with closure and postclosure requirements for TSDFs as outlined in the subsections pertaining to all TSDFs titled Documentation Requirements and Closure. Verify that, if it is found that not all contaminated subsoils can be practicably removed or decontaminated, the site is closed and landfill postclosure requirements are implemented. 4 - 123 Hazardous Waste COMPLIANCE CATEGORY HAZARDOUS WASTE MANAGEMENT U.S. TEAM Guide REGULATORY REQUIREMENTS REVIEWER CHECKS March 2001 (NOTE: Appendix 4-7 contains a summary of recordkeeping and notification requirements in relation to restricted wastes.) ALL TSDFs HW.130 Restricted Wastes HW.130.1.US. TSDFs must not dispose of the wastes listed in Appendix 4-8 on land unless specific parameters are met (40 CFR 268.1, 268.4, 268.40 through 268.43, and Appendix VII) [June 1997]. Verify that the wastes listed in Appendix 4-8 are not land disposed after the indicated dates unless: the TSDF was granted an extension the waste is hazardous only because it exhibits a hazardous characteristic, and is otherwise prohibited from land disposal, is not prohibited from land disposal if the waste: is disposed of into a nonhazardous or hazardous injection well does not exhibit any prohibited characteristic of a hazardous waste at the point of injection includes D001 High TOC subcategory wastes or D012-D017 pesticides wastes that are prohibited, but these wastes have been treated to meet applicable standards disposal is done in a surface impoundment and: treatment of the wastes occurs at the impoundment sampling, testing, and removal procedures and design requirements out lined in 40 CFR 268.4 are followed the waste is treated. (NOTE: The following are exempted from all of the requirements concerning restricted wastes found in 40 CFR 268: waste generated by an SQG of less than 100 kg [ 220 lb] of nonacute hazardous waste and less than 1 kg [ 2 lb] of acute hazardous waste per month waste pesticides that a farmer disposes of according to 262.70 wastes identified or listed as hazardous after 8 November 1984 for which USEPA has not promulgated land disposal prohibitions or treatment standards De minimis losses of characteristic wastes to wastewaters.) (NOTE: As of 8 May 1993 debris that is contaminated with the wastes listed in Appendix 4-8 and debris that is contaminated with any characteristic waste for which there are treatment standards is prohibited from land disposal.) HW.130.2.US. are restricted disposal or the the treatment restricted from shall not be Wastes that from land residual from of a waste land disposal diluted as a Verify that restricted wastes or the residual from the treatment of restricted wastes are not diluted. (NOTE: Dilution is permitted if universal treatment standards are met and the wastes or residual are hazardous only because they exhibit a characteristic in a treatment system which treats wastes that are than discharged into a water of the 4 - 124 Hazardous Waste COMPLIANCE CATEGORY HAZARDOUS WASTE MANAGEMENT U.S. TEAM Guide REGULATORY REQUIREMENTS REVIEWER CHECKS March 2001 substitute for adequate treatment (40 CFR 268.3(a) and 268.3(b)) [Citation Revised June 1998]. United States by permit or which treats wastes for the purpose of pretreatment or unless the waste is a D003 reactive cyanide wastewater or nonwastewater.) HW.130.3.US. A restricted waste may be land disposed only if the constituent concentrations in the waste or waste treatment residue meet applicable treatment standards, or if the waste is treated using a specified treatment technology or equivalent treatment method (40 CFR 268.2(f) and 268.40 through 268.43). Verify that wastes identified in Appendix 4-9 are land disposed only if they meet the requirements in Appendix 4-9. (NOTE: Appendix 4-9 identifies one of three following types of treatment standard requirements: all hazardous constituents in the waste or in the treatment residue must be at or below the value s found in the appendix for that waste (total waste standards) the hazardous constituents in the extract of the waste or in the extract of the waste residue must be at or below the values found in the appendix (waste extract standards) the waste must be treated using the technology specified.) (NOTE: An explanation of the treatment codes is found in Appendix 4-10.) HW.130.4.US. Treatment facilities are required to follow specific procedures for restricted wastes (40 CFR 268.7(b)) [Revised June 1998]. Verify that treatment facilities are testing their waste or contaminated soil according to the frequency out lined in their waste analysis plan. Verify that the treatment facility sends a notice with each waste or contaminated soil shipment going to a land disposal facility, except for debris excluded from the definitions of hazardous waste, that includes the following: USEPA hazardous waste and manifest number the waste is subject to LDRs and the constituents of concern for F001 - F005 and F039, and underlying hazardous constituents (for wastes that are not managed in a CWA or CWA-equivalent facility), unless the waste will be treated and monitored for all constituents (NOTE: If all wastes will be treated and monitored, there is no need to put them on the LDR notice.) whether the waste is a nonwastewater or wastewater and subdivision made within a waste code based on waste specific criteria certification statement as outlined in 40 CFR 268.7(b)(4). Verify that a copy of the notice is kept on file. (NOTE: If waste or treatment residues will be further managed at a different treatment or storage facility, the TSDF sending the waste or treatment residue offsite must comply with notice and certification requirements.) (NOTE: When the wastes are recyclable materials used in a manner constituting 4 - 125 Hazardous Waste COMPLIANCE CATEGORY HAZARDOUS WASTE MANAGEMENT U.S. TEAM Guide REGULATORY REQUIREMENTS REVIEWER CHECKS March 2001 disposal, the treatment facility is not required to notify the receiving facility.) HW.130.5.US. Land disposal facilities for restricted wastes are required to maintain copies of notices and certifications and test the waste, except when disposing of waste that is recycled material used in a manner constituting disposal (40 CFR 268.7(c)) [June 1997]. Verify that copies of the certifications and notification are kept on hand. HW.130.6.US. The storage of hazardous waste that is restricted from land disposal is not allowed unless specific conditions are met (40 CFR 268.50). Verify that land-disposal restricted waste is not stored at the TSDF unless the TSDF is storing the wastes in tanks, containers, or containment buildings in order to accumulate the necessary quantities for proper recovery, treatment, or disposal, and: Verify that the facility is testing waste as specified in the facilities waste analysis plan. each container is marked to identify contents and the date accumulation began each tank is clearly marked with a description of the contents, the quantity of each hazardous waste received, and the start date of accumulation or a record of such information is maintained. Verify that transporters do not store manifested shipments of land-disposal restricted wastes for more than 10 days. (NOTE: A TSDF may store the land-disposal restricted wastes for up to 1 yr provided that the reason for storage is to accumulate such quantities of hazardous waste as are necessary to facilitate proper recovery, treatment, or disposal.) (NOTE: The prohibition on storage does not apply to hazardous wastes that have met treatment standards.) Verify that liquid hazardous wastes containing PCBs at concentrations greater than 50 ppm are stored at a site that meets the requirements of 40 CFR 761.65(b) (see Toxic Substances Management) and is removed from storage within 1 yr of the date it was first placed into storage. 4 - 126 Hazardous Waste 4 - 127 Hazardous Waste COMPLIANCE CATEGORY HAZARDOUS WASTE MANAGEMENT U.S. TEAM Guide REGULATORY REQUIREMENTS REVIEWER CHECKS March 2001 ALL TSDFs HW.135 Emissions From Process Vents HW.135.1.US. TSDFs with process vents associated with distillation, fractionation, thinfilm evaporation, solvent extraction, or air or steam stripping operations that manage hazardous wastes with organic concentrations of at least 10 ppmw are required to meet specific standards (40 CFR 264.1030(b), 264.1030(e), 264.1032, 265.1030(b), 265.1030(d), and 265.1032) [Revised December 1997]. (NOTE: This applies only if the operations are conducted in one of the following: a unit that is subject to the permitting requirements of 40 CFR 270 a unit (including a hazardous waste recycling unit) that is not exempt from permitting under the provisions of 40 CFR 262.34(a) (i.e., a hazardous waste recycling unit that is not a 90-day tank or container) and that is located at a hazardous waste management facility that is otherwise subject to the permitting requirements of 40 CFR 270 a unit that is exempt from permitting under the provisions of 40 CFR 262.34(a) (i.e., a 90-day tank or container) and is not a recycling unit under the provisions of 40 CFR 261.6.) Verify that one of the following is met: total organic emissions from the process vents do not exceed 1.4 kg/h (3 lb/h) and 2.8 Mg/yr (3.1 tons/yr) total organic emissions are reduced by use of a control device from all process vents by 95 weight percent. (NOTE: These requirements do not apply to the process vents at a facility where the owner/operator certifies all of the process vents that would otherwise have to meet these requirements are equipped with and operating air emission controls in accordance with the process vent requirements of an applicable regulation under 40 CFR part 60, part 61, or part 63. The documentation of compliance with these other regulations must be kept with, or made readily available with, the facility operating record.) HW.135.2.US. When a TSDF uses a closed-vent system and control device to meet the standards for total organic emissions, the closed-vent system and control device must meet certain minimum requirements (40 CFR 264.1030(b), 264.1030(e), 264.1033(a) through 264.1033(h), 264.1033(j) 264.1033(k); 265.1030(b), (NOTE: This applies to TSDFs with process vents associated with distillation, fractionation, thin-film evaporation, solvent extraction, or air or steam stripping operations that manage hazardous wastes with organic concentrations of at least 10 ppmw, if the operations are conducted in one of the following: a unit that is subject to the permitting requirements of 40 CFR 270 a unit (including a hazardous waste recycling unit) that is not exempt from permitting under the provisions of 40 CFR 262.34(a) (i.e., a hazardous waste recycling unit that is not a 90-day tank or container) and that is located at a hazardous waste management facility that is otherwise subject to the permitting requirements of 40 CFR 270 a unit that is exempt from permitting under the provisions of 40 CFR 262.34(a) (i.e., a 90-day tank or container) and is not a recycling unit under the provisions of 40 CFR 261.6.) 4 - 128 Hazardous Waste COMPLIANCE CATEGORY HAZARDOUS WASTE MANAGEMENT U.S. TEAM Guide REGULATORY REQUIREMENTS 265.1030(d), and 265.1033(a) through 265.1033(j)) [Revised December 1997]. REVIEWER CHECKS March 2001 (NOTE: These requirements do not apply to the process vents at a facility where the owner/operator certifies all of the process vents that would otherwise have to meet these requirements are equipped with and operating air emission controls in accordance with the process vent requirements of an applicable regulation under 40 CFR part 60, part 61, or part 63. The documentation of compliance with these other regulations must be kept with, or made readily available with, the facility operating record.) Verify that control devices involving vapor recovery are designed and operated to recover the organic vapors vented to the air with an efficiency of 95 weight percent or greater unless the total organic emission limit can be attained at an efficiency of less than 95 weight percent. Verify that, if an enclosed combustion device is used (i.e., vapor incinerator, boiler, or process heater), it is designed and operated to reduce the organic emissions vented to it by 95 weight percent or greater, to achieve a total organic compound concentration of 20 ppmv expressed as the sum of the actual compounds, not carbon equivalents, on a dry basis corrected to 3 percent oxygen, or to provide a minimum residence time of 0.50 s at a minimum temperature of 760 °C [1400 °F]. Verify that, if a boiler or process heater is used as the control device, the vent stream is introduced into the flame zone of the boiler or process heater. Verify that, if flares are used: they are designed and operated with no visible emissions except for periods not in excess of 5 min during any 2 consecutive hours they are operated with a flame present at all times they are used only if the net heating value of the gas being combusted is 11.2 MJ/scm (300 Btu/scf) or greater, if the flare is steam assisted or air assisted if nonassisted, the net heating value of the gas being combusted is 7.45 MJ/scm (200 Btu/scf) or greater if nonassisted or steam assisted, they have an exit velocity less than 18.3 m/s (60 ft/s), except when the net heating value of the gas being combusted is greater than 37.3 MJ/scm (1000 Btu/scf) and the exit velocity is equal to or greater than 18.3 m/s (60 ft/s) but less than 122 m/s (400 ft/s). Verify that each monitor and control device is inspected on a routine basis. Verify that each required control device is installed, calibrated, monitored and inspected as follows: a flow indicator is installed in the vent stream at the nearest feasible point to the control device inlet, but before being combined with other streams, and provides a record of vent stream flow from each affected process vent to the control device at least once every hour 4 - 129 Hazardous Waste COMPLIANCE CATEGORY HAZARDOUS WASTE MANAGEMENT U.S. TEAM Guide REGULATORY REQUIREMENTS REVIEWER CHECKS March 2001 a device to continuously monitor control device operations as specified: a temperature monitoring device equipped with a continuous recorder for a thermal vapor incinerator a temperature monitoring device equipped with a continuous recorder for a catalytic vapor incinerator a heat sensing monitor with a continuous recorder for flares a temperature monitoring device equipped with a continuous recorder to measure a parameter that indicates good combustion operating practices are being used for a boiler or process heater having a design heat input capacity less than 44 MW for a condenser, one of the following: a monitoring device with a continuous recorder to measure the concentration level of the organic compound in the exhaust vent stream from the condenser a temperature monitoring device equipped with a continuous recorder capable of monitoring temperature in the exhaust vent stream from the condenser exit with an accuracy of +/- 1 percent of the temperature being monitored in Celsius or in +/- 0.5 Celsius, whichever is greater for a carbon adsorption system such as a fixed bed carbon adsorber that regenerates the carbon bed directly in the control device, one of the following: a monitoring device equipped with a continuous recorder to measure the concentration levels of the organic compounds in the exhaust vent stream from the carbon bed a monitoring device equipped with a continuous recorder to measure a parameter that indicates the carbon bed is regenerated on a regular, predetermined time cycle. Verify that readings from monitoring devices are checked at least once a day. Verify that, if a carbon adsorption system is being used that regenerates the carbon bed directly onsite, the existing carbon in the control device is replaced with fresh carbon at a regular, predetermined time intervals. (NOTE: The predetermined time interval is based on the design analysis required under 40 CFR 265.1035(b)(4)(iii)(F).) Verify that if a carbon adsorption system is being used that does not regenerate the carbon bed directly onsite in the control device, the existing carbon in the control device is replaced on a regular basis. (NOTE: When to replace the carbon is determined by one of the following procedures: monitoring the concentration level of the organic compound in the exhaust vent stream from the carbon adsorption system daily or at an interval no greater than 20 percent of the time required to consume the total carbon working 4 - 130 Hazardous Waste COMPLIANCE CATEGORY HAZARDOUS WASTE MANAGEMENT U.S. TEAM Guide REGULATORY REQUIREMENTS REVIEWER CHECKS March 2001 capacity, whichever is longer replace the carbon at a regular predetermined time interval that is less than the design carbon replacement interval.) Verify that closed vent systems meet one of the following: are designed and operated with no detectable emissions as indicated by an instrument reading of less than 500 ppm above background as determined by the procedures in 40 CFR 264.1035(b) and 265.1034(b) and by visual inspection are designed to operate at a pressure below atmospheric pressure and are equipped with at least one pressure gauge or other pressure measurement device that can be read from a readily accessible location. HW.135.3.US. TSDFs are required to maintain specific records pertaining to process vent emissions (40 CFR 264.1035 and 265.1035). Verify that the following information is kept in the operating record: an implementation schedule up-to-date documentation of compliance the test plan if test data is used to determine the organic removal efficiency or the total organic compound concentration achieved by a control device documentation of compliance with 40 CFR 265.1033, including: a list of all information references and sources used in preparing the documentation records, including the dates of required compliance tests design analysis, specifications, drawing, schematics, and piping and instrumentation diagrams if engineering calculations are used a statement signed and dated by the operator or owner certifying that the operating parameters used in the design analysis reasonably represent the conditions which exist when the hazardous waste management unit is or would be operating at the highest load or capacity level reasonably expected a statement signed and dated by the owner or operator certifying that the control device is designed to operate at an efficiency of 95 percent or greater unless the total organic concentration limit is achieved at an efficiency of less than 95 weight percent or the total organic emissions limits for affected process vents can be attained by a control device involving vapor recovery at an efficiency less than 95 weight percent. all performance test results if used to demonstrate compliance design documentation monitoring and inspection results notations of exceedance explanation for each period of exceedance for carbon adsorption systems: when the carbon is replaced in carbon adsorption systems date and time when a control device is monitored for carbon breakthrough the date of each control device startup and shutdown. 4 - 131 Hazardous Waste COMPLIANCE CATEGORY HAZARDOUS WASTE MANAGEMENT U.S. TEAM Guide REGULATORY REQUIREMENTS REVIEWER CHECKS March 2001 Verify that records of monitoring operations and inspection information are kept for 3 yr. HW.135.4.US. Closed vent systems are required to be monitored, inspected, and leaks repaired (40 CFR 264.1030(b), 264.1030(e), 264.1033(l), 264.1033(o); 265.1030(b), 265.1030(d), 265.1033(k) and 265.1033(n) [Revised December 1997]. (NOTE: This applies to TSDFs with process vents associated with distillation, fractionation, thin-film evaporation, solvent extraction, or air or steam stripping operations, that manage hazardous wastes with organic concentrations of at least 10 ppmw, if the operations are conducted in one of the following: a unit that is subject to the permitting requirements of 40 CFR 270 a unit (including a hazardous waste recycling unit) that is not exempt from permitting under the provisions of 40 CFR 262.34(a) (i.e., a hazardous waste recycling unit that is not a 90-day tank or container) and that is located at a hazardous waste management facility that is otherwise subject to the permitting requirements of 40 CFR 270 a unit that is exempt from permitting under the provisions of 40 CFR 262.34(a) (i.e., a 90-day tank or container) and is not a recycling unit under the provisions of 40 CFR 261.6.) (NOTE: These requirements do not apply to the process vents at a facility where the owner/operator certifies all of the process vents that would otherwise have to meet these requirements are equipped with and operating air emission controls in accordance with the process vent requirements of an applicable regulation under 40 CFR part 60, part 61, or part 63. The documentation of compliance with these other regulations must be kept with, or made readily available with, the facility operating record.) Verify that closed vents systems designed and operated with no detectable emissions (i.e., one at a pressure below atmospheric pressure) as indicated by an instrument reading of less than 500 ppm above background are monitored as follows: an initial leak detection monitoring of the closed vent system using the procedures outlined in 40 CFR 264.1034(b) or 265.1034(b) on or before the date the system become subject to this section of the CFR visual inspection at least once a year for closed vent system joints, seams, or other connections that are permanently or semi-permanently sealed (e.g., a welded joint between two sections of hard piping or a bolted and gasketed ducting flange) annual and at times required by the Regional Administrator for all other parts of the system using the procedures specified in 40 CFR 265.1034(b). Verify that closed vent systems designed to operate at no detectable emissions are monitored as follows: annual visual inspection to check for defects that could result in air pollutant emissions initial inspection on or before the date the system becomes subject to this section of the CFR. 4 - 132 Hazardous Waste COMPLIANCE CATEGORY HAZARDOUS WASTE MANAGEMENT U.S. TEAM Guide REGULATORY REQUIREMENTS REVIEWER CHECKS March 2001 (NOTE: For closed vent systems designed to operate at no detectable emissions, portions of the system designated as unsafe to monitor are exempt from the visual monitoring if: the components are unsafe to monitor because monitoring personnel would be exposed to an immediate danger a written plan that requires monitoring as practicable during safe to monitor periods is in place and followed.) Verify that detectable emissions, as indicated by visual inspection or by an instrument reading of greater than 500 ppmv above background, are controlled as soon as practicable but not later than 15 days after the emissions is detected. Verify that a first attempt at repair is made no later than 5 calendar days after the emission is detected. (NOTE: Delay of repair of a closed vent system for which leaks have been detected is allowed if the repair is technically infeasible without a process unit shutdown, or if it is determined that the emissions resulting from the immediate repair would be greater than the fugitive emissions likely to result from delay of repair.) HW.135.5.US. Closed vent systems and control devices used to comply with the provisions of 40 CFR 264.1030 through 264.1035 and 265.1030 through 265.1035 are required to be operated at all times when emissions may be vented to them (40 CFR 264.1030(b), 264.1030(e), 264.1033(m), 265.1030(b), 265.1030(d), and 265.1033(l)) [Revised December 1997]. (NOTE: This applies to TSDFs with process vents associated with distillation, fractionation, thin-film evaporation, solvent extraction, or air or steam stripping operations, that manage hazardous wastes with organic concentrations of at least 10 ppmw, if the operations are conducted in one of the following: a unit that is subject to the permitting requirements of 40 CFR 270 a unit (including a hazardous waste recycling unit) that is not exempt from permitting under the provisions of 40 CFR 262.34(a) (i.e., a hazardous waste recycling unit that is not a 90-day tank or container) and that is located at a hazardous waste management facility that is otherwise subject to the permitting requirements of 40 CFR 270 a unit that is exempt from permitting under the provisions of 40 CFR 262.34(a) (i.e., a 90-day tank or container) and is not a recycling unit under the provisions of 40 CFR 261.6.) Verify that closed vent systems and control devices are operated at all times when emissions may be vented to them. (NOTE: These requirements do not apply to the process vents at a facility where the owner/operator certifies all of the process vents that would otherwise have to meet these requirements are equipped with and operating air emission controls in accordance with the process vent requirements of an applicable regulation under 40 CFR part 60, part 61, or part 63. The documentation of compliance with these other regulations must be kept with, or made readily available with, the facility operating record.) 4 - 133 Hazardous Waste COMPLIANCE CATEGORY HAZARDOUS WASTE MANAGEMENT U.S. TEAM Guide REGULATORY REQUIREMENTS REVIEWER CHECKS March 2001 HW.135.6.US. When carbon adsorption systems are used, operators are required to manage all carbon that is a hazardous waste according to specific parameters (40 CFR 264.1030(b), 264.1030(e), 264.1033(n), 265.1030(b), 265.1030(d), and 265.1033(m)) [Revised December 1997]. (NOTE: This applies to TSDFs with process vents associated with distillation, fractionation, thin-film evaporation, solvent extraction, or air or steam stripping operations, that manage hazardous wastes with organic concentrations of at least 10 ppmw, if the operations are conducted in one of the following: a unit that is subject to the permitting requirements of 40 CFR 270 a unit (including a hazardous waste recycling unit) that is not exempt from permitting under the provisions of 40 CFR 262.34(a) (i.e., a hazardous waste recycling unit that is not a 90-day tank or container) and that is located at a hazardous waste management facility that is otherwise subject to the permitting requirements of 40 CFR 270 a unit that is exempt from permitting under the provisions of 40 CFR 262.34(a) (i.e., a 90-day tank or container) and is not a recycling unit under the provisions of 40 CFR 261.6.) (NOTE: These requirements do not apply to the process vents at a facility where the owner/operator certifies all of the process vents that would otherwise have to meet these requirements are equipped with and operating air emission controls in accordance with the process vent requirements of an applicable regulation under 40 CFR part 60, part 61, or part 63. The documentation of compliance with these other regulations must be kept with, or made readily available with, the facility operating record.) Verify that carbon removed from control devices that is a hazardous waste is managed in one of the following manners, regardless of the average VOC concentration of the carbon: regenerated or reactivated in a thermal treatment unit that meets one of the following: the unit has a final permit under 40 CFR 270 which implements the requirements of 40 CFR 264, subpart X the unit is equipped with and operating air emission controls in accordance with applicable requirements incinerated in a hazardous waste incinerator for which the operator either: has a final permit under 40 CFR 270 which implement the requirements of 40 CFR 264, subpart O has designed and operates the incinerator in accordance with the interim status required in 40 CFR 265, subpart O burned in a boiler or industrial furnace for which the operator either: has been issued a final permit under 40 CFR part 270 implementing 40 CFR 266 has designed and operates the boiler or industrial furnace in accordance with the interim status requirements of 40 CFR 266, Subpart H. 4 - 134 Hazardous Waste COMPLIANCE CATEGORY HAZARDOUS WASTE MANAGEMENT U.S. TEAM Guide REGULATORY REQUIREMENTS ALL TSDFs HW.140 Air Emission Standards for Equipment Leaks REVIEWER CHECKS March 2001 (NOTE: This section applies to equipment that contains or contacts hazardous waste with organic concentrations of at least 10 percent by weight that are managed in one of the following (40 CFR 264.1050(b) and 265.1050(b)) [Revised December 1997]: a unit that is subject to the permitting requirements of 40 CFR 270 a unit (including a hazardous waste recycling unit) that is not exempt from permitting under the provisions of 40 CFR 262.34(a) (i.e., a hazardous waste recycling unit that is not a 90-day tank or container) and that is located at a hazardous waste management facility that is otherwise subject to the permitting requirements of 40 CFR 270 a unit that is exempt from permitting under the provisions of 40 CFR 262.34(a) (i.e., a 90-day tank or container) and is not a recycling unit under the provisions of 40 CFR 261.6.) (NOTE: This section does not apply to (40 CFR 264.1050(e), 264.1050(f), 265.1050(d), and 265.1050(e)) [Revised December 1997]: equipment that is in vacuum service and is identified as such on the required list equipment that contains or contacts hazardous waste with an organic concentration of at least 10 percent by weight for less than 300 h per calendar year and is identified as such. HW.140.1.US. TSDFs with pumps in light liquid service that contain or contact hazardous wastes with organic concentrations of at least 10% by weight are required to meet specific standards (40 CFR 264.1052 and 265.1052) [December 1996]. Verify that pumps in light liquid service are monitored monthly according to designated reference methods and inspected visually weekly. (NOTE: A leak is detected if there is an instrument reading of 10,000 ppm or greater or if there is an indication of liquid dripping from the pump seal.) Verify that, when a leak is detected, the first attempt at repair is made within 5 calendar days and repair is completed within 15 calendar days. Verify that, if the TSDF has chosen to not monitor monthly or visually check weekly, pumps equipped with a dual mechanical seal system meet the following design and operation requirements: the dual mechanical seal system is operated with barrier fluid at a pressure that is at all times greater than the pump stuffing box, or equipped with a barrier fluid degassing reservoir that is connected by a closed-vent system to a control device or equipped with a system that purges the barrier fluid into a hazardous waste stream with no detectable emission to the atmosphere the barrier fluid system has no hazardous waste with organic concentrations 10 percent or greater by weight the barrier fluid system is equipped with a sensor that will detect failure if the seal is broken. pumps are checked by visual inspection weekly sensors are checked daily or equipped with an audible alarm that is checked 4 - 135 Hazardous Waste COMPLIANCE CATEGORY HAZARDOUS WASTE MANAGEMENT U.S. TEAM Guide REGULATORY REQUIREMENTS REVIEWER CHECKS March 2001 monthly. Verify that, if the TSDF has chosen to not monitor monthly or visually check weekly, pumps designated for no detectable emissions as indicated by an instrument reading of 500 ppm above background or less meet the following: they are operated with no detectable emissions they are tested for compliance initially upon designation, annually, and at other times as requested by the Regional Administrator no externally actuated shaft penetrates the pump housing. (NOTE: Any pump that is equipped with a closed-vent system capable of capturing and transporting any leakage from the seal or seals to a control device is exempt from these requirements.) Verify that the owner/operator has determined, based on design considerations and operating experience, a criterion that indicates failure of the deal system, the barrier fluid system, or both. HW.140.2.US. TSDFs with compressors that contain or contact hazardous wastes with organic concentrations of at least 10% by weight are required to meet specific standards (40 CFR 264.1053 and 265.1053) [December 1996]. Verify that each compressor is equipped with a seal system which includes a barrier fluid system and prevents leakage of total organic emissions to the atmosphere except if: it is equipped with a closed-vent system capable of capturing and transporting any leakage from the seal to a control device it is designated for no detectable emissions, and: it operates at an instrument reading of less than 500 ppm above back ground it is tested for compliance initially upon designation, annually, and at times as requested by the Regional Administrator. Verify that compressor seal systems meet one of the following: it is operated with the barrier fluid at a pressure that is at all times greater than the compressor stuffing box pressure it is equipped with a barrier fluid system that is connected to a closed-vent system to a control device it is equipped with a system that purges the barrier fluid into a hazardous waste stream with no detectable emissions to the atmosphere. Verify that the barrier fluid is not a hazardous waste with organic concentrations 10 percent or greater by weight. Verify that each barrier fluid system is equipped with a sensor which will detect failure of the seal system, barrier fluid system, or both. Verify that each sensor is checked daily or it is equipped with an audible alarm 4 - 136 Hazardous Waste COMPLIANCE CATEGORY HAZARDOUS WASTE MANAGEMENT U.S. TEAM Guide REGULATORY REQUIREMENTS REVIEWER CHECKS March 2001 that is checked monthly. (NOTE: Sensors on compressors located within the boundary of an unmanned site must be checked daily.) Verify that, when a leak is detected, the first attempt at repair is made within 5 calendar days and the repair is made within 15 calendar days. HW.140.3.US. TSDFs with pressure relief devices in gas/vapor service that contain or contact hazardous wastes with organic concentrations of at least 10 percent by weight are required to meet specific standards (40 CFR 264.1054 and 265.1054) [December 1996]. Verify that, except during pressure releases, each pressure relief device in gas/vapor service is operated with no detectable emissions as indicated by an instrument reading of less than 500 ppm above background. HW.140.4.US. TSDFs with sampling connecting systems that contain or contact hazardous wastes with organic concentrations of at least 10 percent by weight are required to meet specific standards (40 CFR 264.1055 and 265.1055) [December 1996]. Verify that each sampling connection system is equipped with a closed-purge, closed loop system or closed-vent system. Verify that, if there is a pressure release, the device is returned to a no detectable emission status within 5 calendar days and the device is monitored to ensure compliance. (NOTE: Any pressure relief device that is equipped with a closed-vent system capable of capturing and transporting leakage from the pressure relief device to a control device is exempt from these requirements.) Verify that each system collects the sample purge for return to the processing or for routing to the appropriate treatment system. (NOTE: Gases displaced through filling of the sample container are not required to be collected or captured.) Verify that each closed-purge, closed-loop system or closed-vent system does one of the following: returns the purged process fluid directly to the process line collects and recycles the purged process fluid is designed and operated to capture and transport all the purged process fluid to a waste management unit that is in compliance or a control device that is in compliance. (NOTE: In-situ sampling systems are exempt from these requirements.) HW.140.5.US. TSDFs with open-ended valves or lines Verify that each open-ended valve or line is equipped with a cap, blind flange, 4 - 137 Hazardous Waste COMPLIANCE CATEGORY HAZARDOUS WASTE MANAGEMENT U.S. TEAM Guide REGULATORY REQUIREMENTS that contain or contact hazardous wastes with organic concentrations of at least 10 percent by weight are required to meet specific operation standards (40 CFR 264.1056 and 265.1056) [December 1996]. REVIEWER CHECKS March 2001 plug, or a second valve. Verify that the cap, blind flange, plug, or second valve seals the open end at all times, except during operations requiring hazardous waste stream flow through the open- ended valve of line. Verify that each open-ended valve or line equipped with a second valve is operated so the valve on the hazardous waste stream end is closed before the second valve is closed. Verify that, when a double block and bleed system is being used, the bleed valve is shut or plugged except during operations which require venting the line between the block valves. HW.140.6.US. TSDFs with valves in gas/vapor service or light liquid service that contain or contact hazardous wastes with organic concentrations of at least 10 percent by weight are required to meet specific monitoring and repair standards (40 CFR 264.1057, 264.1061, 265.1057, and 265.1061) [December 1996]. Verify that valves in gas/vapor service or light liquid service are monitored monthly to detect leaks. (NOTE: A leak is detected if an instrument reading of 10,000 ppm or greater is measured. But, if a leak is not detected for 2 consecutive months, monitoring may be cut back to quarterly until a leak is detected.) (NOTE: Valves that are designated for no detectable emissions, as indicated by an instrument reading of less than 500 ppm above background, do not have to be monitored monthly if: the valve has no external actuating mechanism in contact with the hazardous waste stream the valve is operated with emission less than 500 ppm above background the valve is tested initially upon designation, annually, and at the request of the Regional Administrator.) (NOTE: Valves that are designated as unsafe to monitor are exempt from the requirement for monthly monitoring if: the valve is unsafe to monitor because monitoring personnel would be exposed to an immediate danger a written monitoring plan is followed that requires monitoring as often as is reasonably practicable during safe to monitor times.) (NOTE: Valves that are designated as difficult to monitor are exempt from monthly monitoring requirements if: the valve cannot be monitored without elevating the monitoring personnel more than 2 m above a support surface the hazardous waste management unit within which the valve is located was in operation before 21 June 1990 a written monitoring plan is followed that requires the monitoring of the valve at least once per calendar year.) 4 - 138 Hazardous Waste COMPLIANCE CATEGORY HAZARDOUS WASTE MANAGEMENT U.S. TEAM Guide REGULATORY REQUIREMENTS REVIEWER CHECKS March 2001 (NOTE: The TSDF may elect to have all valves within a hazardous waste management unit comply with an alternative standard of no greater than 2 percent of the valves to leak, see checklist item HW.140.10 for those alternative standards.) (NOTE: Valves that are designated as difficult to monitor are exempt from monthly monitoring requirements if: the valve cannot be monitored without elevating the monitoring personnel more than 2 m above a support surface the hazardous waste management unit within which the valve is located was in operation before 21 June 1990 a written monitoring plan is followed that requires the monitoring of the valve at least once per calendar year.) (NOTE: The following are alternatives to the prescribed monitoring schedule which can be used until the percentage of valves leaking is greater than 2 percent: after 2 consecutive quarterly leak detection period with the percentage of valves leaking equal to or less than 2 percent, an owner or operator may begin to skip one of the quarterly leak detection periods for the valves after 5 consecutive quarterly leak detection periods with the percentage of valves leaking equal to or less than 2 percent, an owner or operator may begin to skip 3 of the quarterly leak detection periods. Verify that the first attempt at repairing a leak is done within 5 calendar days after detection and leak repair is completed within 15 days after detection. (NOTE: First attempts at repair include, but are not limited to: tightening of bonnet bolts replacement of bonnet bolts tightening of packing gland nuts injection of lubricant into lubricated packing.) HW.140.7.US. TSDFs with pumps and valves in heavy liquid service, pressure relief devices in light liquid service or heavy liquid service, and other connectors that contain or contact hazardous wastes with organic concentrations of at least 10% by weight are required to meet specific monitoring and repair standards (40 CFR 264.1058 and 265.1058) [December 1996]. Verify that pumps and valves in heavy liquid service, pressure relief devices in light liquid service or heavy liquid service, and other connectors are required to be monitored within 5 days if evidence of a potential leak is found by visual, olfactory, audible, or other detection method. (NOTE: A leak is detected if an instrument reading of 10,000 ppm or greater is measured.) Verify that, when a leak is detected, the first attempt at repair occurs within 5 days and repair is done within 15 days after discovery. (NOTE: First attempts at repair include, but are not limited to: tightening of bonnet bolts replacement of bonnet bolts tightening of packing gland nuts 4 - 139 Hazardous Waste COMPLIANCE CATEGORY HAZARDOUS WASTE MANAGEMENT U.S. TEAM Guide REGULATORY REQUIREMENTS REVIEWER CHECKS March 2001 injection of lubricant into lubricated packing.) (NOTE: Any connector that is inaccessible or is ceramic or ceramic lined is exempt from the monitoring requirements.) HW.140.8.US. TSDFs are required to keep specific records pertaining to the valves, pumps, pressure relief devices, and connecting systems being monitored for leaks and submit certain reports (40 CFR 264.1058(e), 264.1064, 264.1065, 265.1058(e), and 265.1064) [Revised December 1997]. Verify that the following information is maintained in the TSDF operating record: equipment identification number and hazardous management unit identification approximate locations type of equipment percent-by-weight total organics in the hazardous waste stream at the equipment hazardous waste state at the equipment (gas, liquid, vapor) method of compliance implementation schedule if needed a performance plan for control devices as needed documentation of compliance documentation of repair, including: the instrument and operator identification numbers and the equipment identification number the date evidence of a potential leak was found the date the leak was detected and the date of each attempt to repair the leak repair methods applies in each attempt “Above 10,000” if the maximum instrument reading after each repair attempt is greater then 10,000 ppm “Repair Delayed” and the reason for delay if the leak is not repaired within 15 calendar days after discovery documentation supporting the delay of valve repair signature of the owner or operator whose decision it was that repair could not be made without a hazardous waste management unit shutdown the expected date of successful repair of the leak when it is not repaired within 15 calendar day the date of successful repair of the leak design documentation and monitoring, operating, and inspection information for each closed vent system control device required to comply with the provisions of 40 CFR 265.1060 monitoring and inspection information indicating proper operation and maintenance of the control device for a control device other than a thermal vapor incinerator, catalytic vapor incinerator, flare, boiler, process heater, condenser, or carbon adsorption system the following information for all equipment subject to 40 CFR 265.1052 through 265.1060: a list of identification numbers for equipment (except welded fittings) a list of identification numbers for equipment that the owner or operator elects to designated for no detectable emissions 4 - 140 Hazardous Waste COMPLIANCE CATEGORY HAZARDOUS WASTE MANAGEMENT U.S. TEAM Guide REGULATORY REQUIREMENTS REVIEWER CHECKS March 2001 a list of equipment identification numbers for pressure relief devices the dates of required compliance tests, background levels, maximum instrument reading, measured during the compliance test a list of identification numbers for equipment in vacuum service identification either by list or location (area or group) of equipment that contains or contacts hazardous waste with an organic concentration of at least 10 percent by weight for less than 300 h per calendar year. Verify that the following information is kept for all valves subject to 40 CFR 265.1057(g) and (h): a list of identification numbers for valves listed as unsafe to monitor, an explanation for each valve stating why it is unsafe to monitor, and the plan for monitoring each valve a list of identification numbers for valves that are designated as difficult to monitor, an explanation for each valve stating why it is difficult to monitor, and the plan for monitoring each valve the following for all valves complying with 40 CFR 265.1062: a schedule of monitoring the percent of valves found leaking in each monitoring period. Verify that the following information is kept for use in determining exemptions: an analysis determining the design capacity of the unit a statement listing the hazardous waste influent to and effluent from each unit subject to 40 CFR 265.1052 through 265.1060 and an analysis determining whether these hazardous wastes are heavy liquids an up-to-date analysis and the supporting information and data used to determine if equipment is subject to the requirements. (NOTE: If repairs are made and the control device does not exceed or operate outside of the design specifications for more than 24 h, a report to the Regional Administrator is not required. Verify that permitted TSDFs submit a semiannual report indicating leaks and repairs to the Regional Administrator. (NOTE: Any connector that is inaccessible or is ceramic or ceramic lined is exempt from the recordkeeping requirements.) HW.140.9.US. Each piece of equipment subject to the requirements in 40 CFR 264.1050 through 264.1064 and 265.1050 through Verify that each piece of equipment subject to the requirements in 40 CFR 264.1050 through 264.1064 and 265.1050 through 265.1064 is marked so that it can be distinguished from other equipment. 4 - 141 Hazardous Waste COMPLIANCE CATEGORY HAZARDOUS WASTE MANAGEMENT U.S. TEAM Guide REGULATORY REQUIREMENTS REVIEWER CHECKS March 2001 265.1064 is required to be marked so that it can be distinguished from other equipment (40 CFR 264.1050(d) and 265.1050(c) [December 1996]. HW.140.10.US. When a TSDF owner/operator has elected to comply with alternative standards, specific actions are required (40 CFR 264.1061 and 265.1061) [May 1997]. Determine if the owner/operator subject to 40 CFR 264.1057/265.1057 (see checklist item HW.140.6) has elected to have all valves within a hazardous waste management unit comply with an alternative standard of allowing 2 percent of the valves to leak. Verify that the following actions have been taken if complying with the 2 percent alternative: the Regional Administrator has been notified of the choice to comply with the alternative standards a performance test was conducted initially upon designation, annually, and at other times as required by the Regional Administrator if a valve leak is detected, first attempt at repair is within 5 calendar days and leak repair is completed within 15 days after detection. Verify that, if the owner/operator has decided to no longer comply with the 2 percent rule, they have notified the Regional Administrator. 4 - 142 Hazardous Waste COMPLIANCE CATEGORY HAZARDOUS WASTE MANAGEMENT U.S. TEAM Guide REGULATORY REQUIREMENTS REVIEWER CHECKS March 2001 ALL TSDFs HW.145 Documentation Requirements HW.145.1.US. TSDFs that treat, store, or dispose of hazardous wastes must develop and follow a written waste analysis plan (40 CFR 264.13(b), 264.13(c), 265.13(b), and 265.13(c)). Determine if the TSDF treats, stores, or disposes of hazardous waste. Verify that the TSDF has a waste analysis plan. Verify that the TSDF is following the waste analysis plan by comparing the plan and records of actual procedures. Verify that the waste analysis plan contains the following: testing parameters for which each hazardous waste will be analyzed test methods sampling methods used to obtain a representative sample frequency in which the analysis will be reviewed or repeated to ensure that the analysis is up-to-date and accurate waste analysis supplied by offsite generators methods used to meet the additional analysis requirements for management of ignitable, reactive, or incompatible materials, bulk and containerized liquids, and incineration are stated (if applicable) additional information as follows for offsite facilities: specific procedures to inspect (and analyze if necessary) each movement of hazardous waste received to ensure that it matches the identity of the waste designated in the manifest the method of sampling used to obtain a representative sample (if the identification method includes sampling) the procedures that an offsite landfill receiving containerized hazardous waste will use to determine if a hazardous waste generator or treater has added a biodegradable sorbent to the waste in the container. HW.145.2.US. TSDFs must have a formal written inspection schedule and a log of inspection results (40 CFR 264.15 and 265.15). Verify that the TSDF has a formal written inspection schedule for inspecting monitoring equipment, safety and emergency equipment, security devices, and operating and structural equipment that are important to preventing, detecting, or responding to environmental or human health hazards. Verify that the schedule is kept at the TSDF and lists types of problems to be looked for at the TSDF. Verify that areas subject to spills, such as loading and unloading areas, are inspected daily when in use. 4 - 143 Hazardous Waste COMPLIANCE CATEGORY HAZARDOUS WASTE MANAGEMENT U.S. TEAM Guide REGULATORY REQUIREMENTS REVIEWER CHECKS March 2001 Verify that logs, or records, of the inspections are kept for 3 yr and include the following: the date and time of the inspection the name of the inspector a notation of the observations made the date and nature of any repairs or other remedial actions. HW.145.3.US. TSDFs must have a contingency plan (40 CFR 264.50 through 264.54 and 265.50 through 265.54). (NOTE: TSDFs may be addressed in the SPCC plan or other emergency plan, or, if none exists, in a separate contingency plan.) Verify that the contingency plan is designed to minimize hazards to human health or the environment from fires, explosions, or any unplanned sudden or nonsudden release of hazardous waste or hazardous waste constituents. Verify that the plan includes the following: a description of actions to be taken during an emergency a description of arrangements, as appropriate, agreed to by local police departments, fire departments, hospitals, contractors, and state and local emergency response teams names, addresses, and phone numbers of all persons qualified to act as emergency coordinator a list of all emergency equipment at the TSDF and where this equipment is required, located, and what it looks like in an evacuation plan for TSDF personnel where there is a possibility evacuation would be needed. Verify that copies of the contingency plan are maintained at the TSDF and have been submitted to organizations which may be called upon to provide emergency services. Verify that the contingency plan is routinely reviewed and updated, especially when the TSDF is issued a new permit, the plan fails in an emergency, the emergency coordinators change, the waste being handled changes, and/or the list of emergency equipment changes. HW.145.4.US. TSDF operators must record the time, date, and details of any incident that requires implementing the contingency plan (40 CFR 264.56(j) and 265.56(j)). Determine if incidents have been recorded and corrective actions taken through a review of TSDF operating records. Verify that written reports have been submitted to the USEPA Regional Administrator within 15 days after the incident. 4 - 144 Hazardous Waste COMPLIANCE CATEGORY HAZARDOUS WASTE MANAGEMENT U.S. TEAM Guide REGULATORY REQUIREMENTS HW.145.5.US. operators must keep operating records facility (40 CFR through 264.74 and through 265.74). TSDF written at the 264.73 265.73 REVIEWER CHECKS March 2001 Verify that the TSDF has a written operating record. Determine if the operating record includes: a description and quantity of each hazardous waste received at the TSDF, and the method(s) and date(s) of treatment, storage, or disposal of each waste received at the TSDF the location of each hazardous waste within the TSDF (cross-referenced to specific manifest document numbers and the quantity at each location) for disposal facilities, the location and quantity is recorded on a map or diagram of each cell or disposal area records and results of waste analyses reports of all the incidents that required the implementation of the contingency plan records and results of inspections (only a 3-yr retention period) monitoring, testing, and analytical data (where required) for offsite facilities, notices to the generator annual certification that the TSDF has a program in place to reduce the volume and toxicity of hazardous waste, and that the proposed method of treatment, storage, or disposal minimizes the present and future threat to human health and the environment the record of the quantities and date of placement for each shipment of hazardous waste placed in land disposal units under an extension granted by 40 CFR 268.5, a petition granted under 40 CFR 268.6, or a certification granted under 40 CFR 268.8 a copy of the applicable notice, demonstration, and certification required for any restricted hazardous wastes certifications and demonstrations provided to generators or received from generators. (NOTE: This information must be recorded and maintained in the operating record until closure of the TSDF.) (NOTE: The retention period for all records is extended automatically during the course of any unresolved enforcement action or as required by the USEPA administrator.) HW.145.6.US. TSDFs must prepare and submit a single copy of a biennial report to the USEPA Regional Administrator by March 1 of each even numbered year (40 CFR 264.75 and 265.75). Obtain a copy of the biennial report (USEPA Form 8700-13D or applicable state form). Verify that biennial reports are prepared, submitted, and contain the following information: USEPA identification number TSDF name and address calendar year covered by report description and quantity of each waste received 4 - 145 Hazardous Waste COMPLIANCE CATEGORY HAZARDOUS WASTE MANAGEMENT U.S. TEAM Guide REGULATORY REQUIREMENTS REVIEWER CHECKS March 2001 method of treatment, storage, or disposal for each waste certification signed by owner or operator of the TSDF offsite facilities must also report USEPA identification number for each hazardous waste generator from which waste was received description of efforts undertaken during the year to reduce the volume and toxicity of waste generated description of changes in volume and toxicity of waste actually achieved during the year in comparison to previous years to the extent that information is available for the years prior to 1984. (NOTE: This may not be required if annual or biennial reports are submitted to the state depending on state requirements.) HW.145.7.US. TSDFs must have a written closure plan for each TSDF (40 CFR 264.110(a), 264.110(c), 264.112(a) through 2664.112(c), 265.110(a), 265.110(c), and 265.112(a) through 265.112(c)) [Revised January 1999]. (NOTE: These requirements apply to all hazardous waste management facilities. The Regional Administrator may substitute alternate requirements where it is determined that: the regulated unit is situated among solid waste management units (or areas of concern), a release has occurred, and both the regulated unit and one or more solid waste management units (or areas of concern) are likely to have contributed to the release it is not necessary to apply the closure requirements because alternative requirements will protect human health and the environment.) Verify that the TSDF has a written closure plan that is approved by the Regional Administrator. Verify that the closure plan addresses: how each hazardous waste management unit will be closed how final closure will be conducted estimates of the maximum amount of wastes in storage and in treatment during the life of the TSDF description of decontamination procedures to be used during closure schedule for closure of each unit description of other activities necessary during closure. Verify that a written notification of or request for a permit modification was submitted to authorize a change in the approved closure plan whenever: changes in operating plans or facility design affect the closure plan there is a change in the expected year of closure in conducting partial or final closure activities, unexpected events required a modification of the approved closure plan the owner or operator requests the Regional Administrator to apply alternative requirements to a regulated unit. Verify that the written notification was submitted at least 60 days prior to the 4 - 146 Hazardous Waste COMPLIANCE CATEGORY HAZARDOUS WASTE MANAGEMENT U.S. TEAM Guide REGULATORY REQUIREMENTS REVIEWER CHECKS March 2001 proposed change in facility design or operation or no later than 60 days after an unexpected event has affected the closure plan. (NOTE: If an unexpected event occurs during the partial or final closure period, a permit modification must be requested no later than 30 days after the unexpected event.) HW.145.8.US. TSDFs with hazardous waste disposal units are required to have a written postclosure plan (40 CFR 264.110(b), 264.118, 264.110(b), and 265.118(a) through 265.118(d)) [Revised January 1999]. (NOTE: This requirement applies to the following: all hazardous waste disposal facilities waste piles and surface impoundments from which the owner or operator intends to remove the wastes at closure tank systems that are required to meet the requirements for landfills containment buildings that are required to meet the requirements for landfills.) Verify that the written postclosure plan includes the following information: identifies the activities that will be carried on after closure of each disposal unit and the frequency of these activities such as monitoring and maintenance name, address, and phone number of the person or office to contact during postclosure care alternative requirements that apply to the unit or a reference to the enforceable document containing those requirements when applicable. Verify that the postclosure plan is amended if there is a change in the expected year of final closure, events occur during the life of the TSDF that impact closure care, a change in TSDF design, or a request has been made to the Regional Administrator to apply alternate standards. HW.145.9.US. TSDFs that receive waste from offsite sources must comply with manifest requirements (40 CFR 264.70, 264.71, 265.70, and 265.71) [February 1995]. Determine if the TSDF receives waste from offsite sources and if their permit allows for the receipt of offsite waste. Determine if manifests contain the following by reviewing a random number of manifests: proper signature date of receipt. Verify that a copy was sent to the generator within 30 days of receipt of waste. Verify that copies are retained at the TSDF for 3 yr. Verify that exclusion certification from CESQGs are kept on file. (NOTE: Periods of retention of records are extended automatically during the course of any unresolved enforcement action or as requested by the USEPA 4 - 147 Hazardous Waste COMPLIANCE CATEGORY HAZARDOUS WASTE MANAGEMENT U.S. TEAM Guide REGULATORY REQUIREMENTS REVIEWER CHECKS March 2001 administrator.) HW.145.10.US. TSDFs receiving hazardous waste from a foreign source must notify the Regional Administrator (40 CFR 264.12(a) and 265.12(a)). Verify that notification is sent in writing at least 4 wk before delivery is expected. HW.145.11.US. TSDFs that receive waste from offsite sources are required to attempt to resolve manifest discrepancies when they occur (40 CFR 264.72 and 265.72). Determine if significant discrepancies existed between the quantity or type of waste designated on the manifest or shipping paper and the quantity or type of waste the TSDF received. Verify that, on discovery of a significant discrepancy, an attempt was made to reconcile the discrepancy with the generator and/or the transporter. Verify that, if the discrepancy could not be resolved within 15 days after receipt of the waste, the Regional Administrator was notified by mail and the following was included: a letter describing the discrepancy and the attempts to reconcile it a copy of the manifest or shipping paper at issue. (NOTE: For bulk waste, variations greater than 10 percent in weight, and for batch waste, any variation in piece count is a significant discrepancy. Significant discrepancies in type are obvious differences that can be discovered by inspection or waste analysis, such as waste solvent substituted for waste acid, or toxic constituents not reported on the manifest or shipping paper. These discrepancies may only be discovered after waste analysis.) HW.145.12.US. Reports must be submitted to the USEPA when a TSDF accepts an unmanifested waste shipment (40 CFR 264.76 and 265.76). Determine if unmanifested shipments have been accepted. HW.145.13.US. TSDFs that initiate a shipment of Verify that the TSDF complies with the Generator standards in 40 CFR 262.12(c), and 262.40 through 262.42 (see checklist items HW.55.3,US through Verify that reports (Form 8700-13B) are submitted within 15 days. (NOTE: Small quantities of hazardous waste (i.e., waste from CESQGs) are excluded from the manifest requirements. When a TSDF receives such unmanifested wastes without certification from the generator that the waste qualified for exclusion, the TSDF should file an unmanifested waste report.) 4 - 148 Hazardous Waste COMPLIANCE CATEGORY HAZARDOUS WASTE MANAGEMENT U.S. TEAM Guide REGULATORY REQUIREMENTS REVIEWER CHECKS March 2001 hazardous waste to a different, offsite TSDF must meet certain Generator standards (40 CFR 262.10(f)). HW.55.6.US), if initiating shipments of hazardous waste to a different, offsite TSDF. 4 - 149 Hazardous Waste 4 - 150 Hazardous Waste COMPLIANCE CATEGORY HAZARDOUS WASTE MANAGEMENT U.S. TEAM Guide REGULATORY REQUIREMENTS ALL TSDFs HW.150 Surface Impoundments HW.150.1.US. TSDFs must follow specific restrictions concerning the types of wastes placed in any surface impoundment (40 CFR 264.229, 264.230, 265.229, and 265.230). REVIEWER CHECKS March 2001 (NOTE: See Appendix 4-8a for guidance on the schedule for implementation of air emissions standards in 40 CFR 265.1080 through 265.1091. Also, in relation to the requirements for air emissions standard, see the definition of Exempted Hazardous Waste Management Unit.) Verify that incompatible wastes or incompatible wastes and materials are not placed in the same surface impoundment unless precautions are taken to prevent: generation of extreme heat or pressure, fire or explosions, or violent reactions production of uncontrolled toxic mists, fumes, dusts, or gases in quantities that would threaten human health or the environment production of uncontrolled flammable fumes or gases in quantities that would pose a risk of fire or explosion damage to structural integrity of the device or TSDF threats to human health or the environment through other means. Verify that ignitable or reactive wastes are not placed in surface impoundments unless the wastes and impoundments satisfy the restrictions in 40 CFR 268 (see checklist items HW.130.1 through HW.130.6) and they are treated, rendered, or mixed so that they are no longer ignitable or reactive. Verify that one of the following conditions is also met for the surface impoundment: precautions are taken so that the following are prevented: generation of extreme heat or pressure, fire or explosions, or violent reactions production of uncontrolled toxic mists, fumes, dusts, or gases in quantities that would threaten human health or the environment production of uncontrolled flammable fumes or gases in quantities that would pose a risk of fire or explosion damage to structural integrity of the device or TSDF threats to human health or the environment through other means the waste is managed so that it is protected from any materials or conditions which may cause it to ignite or react the surface impoundment is used only for emergencies. HW.150.2.US. When surface impoundments use floating membrane covers, the covers are required to meet specific design standards (40 CFR 264.1085(a) through 264.1085(c)(2), 265.1086(a) through 265.1086(c)(ii)) (NOTE: These requirements do not apply to a surface impoundment in which an owner or operator has stopped adding hazardous waste (except to implement an approved closure plan) and the owner or operator has begun implementing or completed closure following an approved closure plan (40 CFR 264.1080(b)(4) and 265.1080(b)(4)).) (NOTE: These requirements do not apply to surface impoundments in which all the hazardous waste entering the surface impoundment meets one of the following 4 - 151 Hazardous Waste COMPLIANCE CATEGORY HAZARDOUS WASTE MANAGEMENT U.S. TEAM Guide REGULATORY REQUIREMENTS [Revised December 1997]. REVIEWER CHECKS March 2001 (40 CFR 264.1082(c) and 265.1083(c).): the average VO concentration of the hazardous waste at the point of waste origination is less than 500 ppmw the organic content of the hazardous waste has been reduced by an organic destruction or removal process the waste meets the numerical concentration limits for organic hazardous constituents as specified in 40 CFR 268.40 or has been treated by the treatment technology established by the USEPA for the waste in 268.42(a) or an equivalent method.) Verify that the surface impoundment has installed and operates one of the following: a floating membrane cover a cover that is vented through a closed-vent system to an approved control device. Verify that the floating membrane cover is designed and operated to meet the following: it is designed to float on the liquid surface during normal operations and form a continuous barrier over the entire surface area of the liquid it is fabricated from a synthetic membrane materials that is either high density polyethylene with a thickness no less than 2.5 mm or a material or a composite of different materials determined to have both organic permeability properties that are equivalent to the polyethylene and chemical and physical properties that maintain the material integrity for the intended service life of the material it is installed so that there are no visible cracks, holes, gaps or other open spaces between cover section seams or between the interface of the cover edge and its foundation mountings all openings, except for emergency cover drains, are equipped with a closure device designed to operate so that when the closure device is secured in the closed position there are no visible cracks, holes, gaps, or other open spaces in the closure device or between the perimeter of the cover opening and the closure device the emergency cover drains are equipped with a slotted membrane fabric cover that covers at least 90 percent of the area of the opening or a flexible fabric sleeve seal the closure device is made of suitable materials to minimize the exposure of the hazardous waste to the atmosphere and maintain the integrity of the closure devices through their intended service life. Verify that, whenever hazardous waste is in the surface impoundment, the floating membrane cover floats on the liquid and each closure device is secured in the closed position except for the following: to provide access to the surface impoundment for performing routine 4 - 152 Hazardous Waste COMPLIANCE CATEGORY HAZARDOUS WASTE MANAGEMENT U.S. TEAM Guide REGULATORY REQUIREMENTS REVIEWER CHECKS March 2001 maintenance, inspection, or other activities for normal operations to remove accumulated sludge or other residues from the bottom of the surface impoundments when necessary to avoid an unsafe condition. HW.150.3.US. When surface impoundments use a cover that is vented through a closed-vent system to a control device, the cover is required to meet specific design standards (40 CFR 264.1085(d)(1), 264.1085(d)(2), 265.1086(d)(1), and 265.1086(d)(2)) [December 1996]. (NOTE: These requirements do not apply to a surface impoundment in which an owner or operator has stopped adding hazardous waste (except to implement an approved closure plan) and the owner or operator has begun implementing or completed closure following an approved closure plan (40 CFR 264.1080(b)(4) and 265.1080(b)(4)).) (NOTE: These requirements do not apply to surface impoundments in which all the hazardous waste entering the surface impoundment meets one of the following (40 CFR 264.1082(c) and 265.1083(c): the average VO concentration of the hazardous waste at the point of waste origination is less than 500 ppmw the organic content of the hazardous waste has been reduced by an organic destruction or removal process the waste meets the numerical concentration limits for organic hazardous constituents as specified in 40 CFR 268.40 or has been treated by the treatment technology established by the USEPA for the waste in 268.42(a) or an equivalent method.) Verify that the cover is vented directly through a closed vent system to a control device as follows: the cover and the closure devices form a continuous barrier over the entire surface area of the liquid in the surface impoundment each opening not vented to the control device is equipped with a closure device when the pressure in the vapor headspace underneath the cover is less than atmospheric pressure when the control device is operation, closure devices are designed to operate so that when the closure device is secure in the closed position there are no visible cracks, holes, gaps, or other open spaces in the closure device or between the perimeter of the cover opening and the closure device when the pressure in the vapor headspace is equal to or greater than atmospheric pressure when the control device is operating, the closure device is designed to operate with no detectable organic emissions the cover and its closure devices are made of suitable materials to minimize exposure of the hazardous waste to the atmosphere, to the extent practical, and maintains the integrity of the cover and closure devices throughout their intended life service. Verify that, when a hazardous waste is in the surface impoundment, the cover is installed with each closure device secured in the closed position, and the vapor underneath the cover vented to the control devices except as follows: venting to the control device is not done and opening of the closure devices or 4 - 153 Hazardous Waste COMPLIANCE CATEGORY HAZARDOUS WASTE MANAGEMENT U.S. TEAM Guide REGULATORY REQUIREMENTS REVIEWER CHECKS March 2001 removal is allowed in order to provide access to the surface impoundment for performing routine inspection, maintenance, or other activities needed for normal operations venting to the control device is not done and opening of the closure devices or removal is allowed to remove accumulated sludge or other residues from the bottom of the surface impoundment opening of safety devices to avoid an unsafe condition. HW.150.4.US. Closed vent systems and control devices are required to be designed according to 40 CFR 264.1087 or 265.1088 (40 CFR 264.1085(d)(1)(iv), 264.1087, 265.1086(d)(1)(iv), 265.1088) [December 1996]. (NOTE: These requirements do not apply to a surface impoundment in which an owner or operator has stopped adding hazardous waste (except to implement an approved closure plan) and the owner or operator has begun implementing or completed closure following an approved closure plan (40 CFR 264.1080(b)(4) and 265.1080(b)(4)).) (NOTE: These requirements do not apply to surface impoundments in which all the hazardous waste entering the surface impoundment meets one of the following (40 CFR 264.1082(c) and 265.1083(c)): the average VO concentration of the hazardous waste at the point of waste origination is less than 500 ppmw the organic content of the hazardous waste has been reduced by an organic destruction or removal process the waste meets the numerical concentration limits for organic hazardous constituents as specified in 40 CFR 268.40 or has been treated by the treatment technology established by the USEPA for the waste in 268.42(a) or an equivalent method.) Verify that closed vent systems: route the gases, vapors, and fumes emitted from the hazardous waste to a control device are designed according to 264.1033(k) or 265.1033(j) as appropriate are equipped with one of the following when the system includes bypass devices (except for low leg drains, high point bleeds, analyzer vents, openended valves or lines, spring-loaded pressure relief valves, and other fittings used for safety purposes) that could be used to divert the gas or vapor stream to the atmosphere: a flow indicator at the inlet to the bypass device that indicates whether gas or vapor flow is present in the bypass device a seal or locking device placed on the mechanism by which the bypass device position is controlled when the bypass device is in the closed position so that the bypass device cannot be opened without breaking the seal or removing the lock. Verify that, if a control device is used, it is one of the following: a control device designed and operated to reduce the total organic content of the inlet vapor stream vented to the control device by at lest 95 percent 4 - 154 Hazardous Waste COMPLIANCE CATEGORY HAZARDOUS WASTE MANAGEMENT U.S. TEAM Guide REGULATORY REQUIREMENTS REVIEWER CHECKS March 2001 weight an enclosed combustion device (i.e., vapor incinerator, boiler, or process heater), designed and operated to reduce the organic emissions vented to it by 95 weight percent or greater, to achieve a total organic compound concentration of 20 ppmv, expressed as the sum of the actual compounds, not carbon equivalents, on a dry basis corrected to 3 percent oxygen, or to provide a minimum residence time of 0.50 s at a minimum temperature of 760 °C [1400 °F] a flare that: is designed and operated with no visible emissions except for periods not in excess of 5 min during any 2 consecutive hours is operated with a flame present at all times is used only if the net heating value of the gas being combusted is 11.2 MJ/scm (300 Btu/scf) or greater if the flare is steam assisted or air assisted if nonassisted, the net heating value of the gas being combusted is 7.45 MJ/scm (200 Btu/scf) or greater if nonassisted or steam assisted, have an exit velocity less than 18.3 m/s (60 ft/s) except when the net heating value of the gas being combusted is greater than 37.3 MJ/scm (1000 Btu/scf) and the exit velocity is equal to or greater than 18.3 m/s (60 ft/s) but less than 122 m/s (400 ft/s). (NOTE: These specifications do not apply during periods of planned routine maintenance. Nor do they apply during control device system malfunctions.) (NOTE: The performance of each flare will be demonstrated in accordance with 40 CFR 265.1033(e).) Verify that, when using a closed vent system and control device, periods of planned routine maintenance of the control device during which specifications will be exceeded do not exceed 240 h/yr. Verify that malfunctions are corrected as soon as is practical. Verify that closed vent systems are operated so that gases, vapors, and/or fumes are not actively vented to the control device during periods of planned maintenance or control device system malfunctions. Verify that, when a carbon adsorption system is used, all activated carbon in the control device is replaced on a regular basis after start-up. Verify that carbon removed from control devices that is a hazardous waste is managed in one of the following manners, regardless of the average VOC concentration of the carbon: regenerated or reactivated in a thermal treatment unit that meets one of the following: the unit has a final permit under 40 CFR 270 which implements the 4 - 155 Hazardous Waste COMPLIANCE CATEGORY HAZARDOUS WASTE MANAGEMENT U.S. TEAM Guide REGULATORY REQUIREMENTS REVIEWER CHECKS March 2001 requirements of 40 CFR 264, subpart X the unit is equipped with and operating air emission controls in accordance with applicable requirements incinerated in a hazardous waste incinerator for which the operator either: has a final permit under 40 CFR 270 which implement the requirements of 40 CFR 264, subpart O has designed and operates the incinerator in accordance with the interim status required in 40 CFR 265, subpart O burned in a boiler or industrial furnace for which the operator either: has been issued a final permit under 40 CFR 270 implementing 40 CFR 266 has designed and operates the boiler or industrial furnace in accordance with the interim status requirements of 40 CFR 266, Subpart H. Verify that operation and maintenance is done in accordance with 264.1033(j) or 265.10033 (i) if a control device is used other than a thermal vapor incinerator, flare, boiler, process heater, condenser, or carbon adsorption system. Verify that achievement of control device performance requirements is demonstrated by a performance test or design analysis is used for each control device except for the following: a flare a boiler or process heater with a design heat input capacity of 44 MW or greater a boiler of process heater into which the vent stream is introduced with the primary fuel a boiler or process heater burning hazardous waste for which a final permit has been issued under 40 CFR 270 and is designed and operated in accordance with the requirements of 40 CFR 266, subpart H a boiler or industrial furnace burning hazardous waste which the owner or operator has designed and operates in accordance with the interim status requirements of 40 CFR 266, subpart H. Verify that carbon adsorption systems demonstrate achievement of performance requirements based on the total quantity of organics vented to the atmosphere from all carbon adsorption equipment that is used for organic adsorption, organic desorptions or carbon regeneration, organic recovery, and carbon disposal. HW.150.5.US. Surface impoundments are required to have enclosed pipes or other closed systems for the transfer of hazardous waste in certain circumstances (40 CFR 264.1085(e) and 265.1086(e)) (NOTE: These requirements do not apply to a surface impoundment in which an owner or operator has stopped adding hazardous waste (except to implement an approved closure plan) and the owner or operator has begun implementing or completed closure following an approved closure plan (40 CFR 264.1080(b)(4) and 265.1080(b)(4)).) (NOTE: These requirements do not apply to surface impoundments in which all 4 - 156 Hazardous Waste COMPLIANCE CATEGORY HAZARDOUS WASTE MANAGEMENT U.S. TEAM Guide REGULATORY REQUIREMENTS [December 1996]. REVIEWER CHECKS March 2001 the hazardous waste entering the surface impoundment meets one of the following (40 CFR 264.1082(c) and 265.1083(c): the average VO concentration of the hazardous waste at the point of waste origination is less than 500 ppmw the organic content of the hazardous waste has been reduced by an organic destruction or removal process the waste meets the numerical concentration limits for organic hazardous constituents as specified in 40 CFR 268.40 or has been treated by the treatment technology established by the USEPA for the waste in 268.42(a) or an equivalent method.) Verify that transfer of hazardous waste is done using continuous hard piping or another closed system that does not allow exposure of the waste to the atmosphere. HW.150.6.US. Checklist item deleted. [December 1996]. HW.150.7.US. Facilities are required to meet inspection and monitoring requirements and requirements for the repair of defects identified in the inspection and monitoring process for surface impoundments (40 CFR 264.1085(c)(3), 264.1085(d)(3), 264.1085(f), 264.1085(g), 264.1087(c)(7), 264.1088, 265.1086(c)(3), 265.1086(d)(3), 265.1086(f), 265.1086(g), 265.1088(c)(7), and 265.1089.) [December 1996]. (NOTE: These requirements do not apply to a surface impoundment in which an owner or operator has stopped adding hazardous waste (except to implement an approved closure plan) and the owner or operator has begun implementing or completed closure following an approved closure plan (40 CFR 264.1080(b)(4) and 265.1080(b)(4)).) (NOTE: These requirements do not apply to surface impoundments in which all the hazardous waste entering the surface impoundment meets one of the following (40 CFR 264.1082(c) and 265.1083(c): the average VO concentration of the hazardous waste at the point of waste origination is less than 500 ppmw the organic content of the hazardous waste has been reduced by an organic destruction or removal process the waste meets the numerical concentration limits for organic hazardous constituents as specified in 40 CFR 268.40 or has been treated by the treatment technology established by the USEPA for the waste in 268.42(a) or an equivalent method.) Verify that the facility has a written plan and schedule for performing inspections and monitoring. Verify that, when a floating membrane cover is used, inspection is done as follows: initial visual inspection of the cover and its closure devices to check for defects that could result in air emissions on or before the date that the surface impoundment becomes subject to this section 4 - 157 Hazardous Waste COMPLIANCE CATEGORY HAZARDOUS WASTE MANAGEMENT U.S. TEAM Guide REGULATORY REQUIREMENTS REVIEWER CHECKS March 2001 annual visual inspection of the cover and its closure devices to check for defects that could result in air emissions. Verify that, when a cover vented to a control device is used, inspection is done as follows: initial visual inspection of the cover and its closure devices to check for defects that could result in air emissions on or before the date that the surface impoundment becomes subject to this section annual visual inspection of the cover and its closure devices to check for defects that could result in air emissions. (NOTE: After the initial inspection, subsequent inspection and monitoring may be done at intervals longer than 1 yr when inspecting or monitoring the cover would expose a worker to dangerous, hazardous, or other unsafe conditions as long as there is a written explanation stating the reasons the cover is unsafe to inspect and there is a written plan to inspect the cover.) Verify that, when a defect is identified, the first efforts at repair are made no later than 5 calendar after detection and repair is completed as soon as possible, but no later than 45 calendar days after detection. (NOTE: Repair may be delayed beyond 45 calendar days if the owner or operator determines that repair requires emptying or temporary removal from service of the surface impoundment and no alternative capacity is available at the site to accept the hazardous waste normally managed in the surface impoundment.) Verify that each required control device has a device to continuously monitor it as follows: a temperature monitoring device equipped with a continuous recorder for a thermal vapor incinerator a temperature monitoring device equipped with a continuous recorder for a catalytic vapor incinerator a heat sensing monitor with a continuous recorder for flares a temperature monitoring device equipped with a continuous recorder to measure a parameter that indicate good combustion operating practices are being used for a boiler or process heater having a design heat input capacity less than 44 MW for a condenser, one of the following: a monitoring device with a continuous recorder to measure the concentration level of the organic compound in the exhaust vent stream from the condenser a temperature monitoring device equipped with a continuous recorder capable of monitoring temperature in the exhaust vent stream from the condenser with an accuracy of +/- 1 percent of the temperature being monitored in Celsius or in +/- 0.5 °C, whichever is greater for a carbon adsorption system such as a fixed bed carbon adsorber that 4 - 158 Hazardous Waste COMPLIANCE CATEGORY HAZARDOUS WASTE MANAGEMENT U.S. TEAM Guide REGULATORY REQUIREMENTS REVIEWER CHECKS March 2001 regenerates the carbon bed directly in the control device, one of the following: a monitoring device equipped with a continuous recorder to measure the concentration levels of the organic compounds in the exhaust vent stream from the carbon bed a monitoring device equipped with a continuous recorder to measure a parameter that indicates the carbon bed is regenerated on a regular, predetermined time cycle. Verify that the continuous monitoring devices are inspected at least once each operating day to check control device operation. Verify that closed vents systems designed and operated with no detectable emissions, as indicated by an instrument reading of less than 500 ppm above background, are monitored as follows: an initial leak detection monitoring of the closed vent system on or before the date the system become subject to this section of the CFR visual inspection according to 40 CFR 264.1034(b)/265.1034(b) at least once a year for closed vent system joints, seams, or other connections that are permanently or semi-permanently sealed (e.g., a welded joint between two sections of hard piping or a bolted and gasketed ducting flange) annually and at times required by the Regional Administrator for all other parts of the system using. Verify that closed vent systems designed to operate at no detectable emissions are monitored as follows: annual visual inspection to check for defects that could result in air pollutant emissions initial inspection on or before the date the system becomes subject to this section of the CFR. (NOTE: For closed vent systems designed to operate at no detectable emissions, portions of the system designated as unsafe to monitor are exempt from the visual monitoring if: the components are unsafe to monitor because monitoring personnel would be exposed to an immediate danger a written plan that requires monitoring as practicable during safe to monitor periods is in place and followed.) Verify that detectable emissions, as indicated by visual inspection or by an instrument reading of greater than 500 ppmv above background, are controlled as soon as practicable but not later than 15 days after the emissions is detected. Verify that a first attempt at repair is made no later than 5 calendar days after the emission is detected. 4 - 159 Hazardous Waste COMPLIANCE CATEGORY HAZARDOUS WASTE MANAGEMENT U.S. TEAM Guide REGULATORY REQUIREMENTS REVIEWER CHECKS March 2001 (NOTE: Delay of repair of a closed vent system for which leaks have been detected is allowed if the repair is technically infeasible without a process unit shutdown, or if it is determined that the emissions resulting from the immediate repair would be greater than the fugitive emissions likely to result from delay of repair.) HW.150.8.US. Facilities are required to meet documentation requirements for surface impoundments (40 CFR 264.1089(a), 264.1089(c), 264.1089(e) through 264.1089(h), 265.1090(a), 265.1090(c), 265.1090(e) through 265.1090(h)) [Revised December 1997]. Verify that the facility records and maintains the following: the surface impoundment identification number (or other unique identification description as selected by the owner/operator documentation describing the floating membrane cover or cover design, as applicable, that includes information prepared by the owner/operator or provided by the cover manufacturer or vendor describing the cover design, and certification by the owner/operator that the cover meets specifications a records of each required inspection, including the following information: date inspection was completed for each defect, the location, descriptions the defect, date of detection, and corrective action taken. Verify that the following documentation is kept for closed vent systems and control devices: certification that the control device is designed to operate at the necessary performance level when the surface impoundment is or would be operating at capacity or the highest level reasonably expected to occur design documentation, if design analysis is used a performance test plan if performance tests are used description and date of each modification identification of operating parameters, description of monitoring devices, and diagram of monitoring sensor location or locations for planned routine maintenance operations where the control device would not meet requirements, the following semiannually: a description of the planned routine maintenance that is anticipated for the next 6-mo period a description of the planned routine maintenance that was performed during the pervious 6-mo period. the total number of hours that the control device did not meet the requirements of 40 CFR 264.1089(i)(1)/265.1090(i)(1) for unexpected malfunctions: the duration, and occurrence of each malfunction the duration of each period during a malfunction when gases, vapors, or fumes are vented from the waste management unit through the closedvent system to the control device while the control device is not properly functioning actions taken during periods of malfunction to restore a malfunctioning control device to its normal or usual manner of operation records of the management of carbon removed from a carbon adsorption 4 - 160 Hazardous Waste COMPLIANCE CATEGORY HAZARDOUS WASTE MANAGEMENT U.S. TEAM Guide REGULATORY REQUIREMENTS REVIEWER CHECKS March 2001 system. Verify that all records, except design information records, are kept for a minimum of 3 yr. Verify that design information records are kept in the operating record until the air pollution control equipment is replaced or otherwise no longer in service. Verify that records for exempted facilities are kept as long as the facility is not using air emissions controls. Verify that, for exempted facilities, the following information is kept: the information used for waste determination in the operating log the identification number of the incinerator, boiler, or industrial furnace in which the hazardous waste is treated. Verify that, for unsafe to inspect and monitor covers, a record is kept of the identification numbers of the units and the reasons why the cover is unsafe to monitor and a plan and a schedule for inspecting and monitoring each cover. 4 - 161 Hazardous Waste 4 - 162 Hazardous Waste COMPLIANCE CATEGORY HAZARDOUS WASTE MANAGEMENT U.S. TEAM Guide REGULATORY REQUIREMENTS REVIEWER CHECKS March 2001 ALL TSDFs HW.155 Waste Piles HW.155.1.US. All waste piles containing ignitable or incompatible wastes must follow certain requirements (40 CFR 264.256 and 264.257). Verify that ignitable wastes are not placed into piles unless the following are met: the waste is treated, rendered, or mixed before or immediately after placement in the pile so that: the waste or mixture no longer meets the definition of ignitable or reactive waste there is no generation of extreme heat or pressure, fire or explosions, or violent reactions there is no production of uncontrolled toxic mists, fumes, dusts, or gases in quantities that would threaten human health or the environment there is no production of uncontrolled flammable fumes or gases in quantities that would pose a risk of fire or explosion there is no damage to structural integrity of the device or TSDF there is no threat to human health or the environment through other means the waste is managed in such a way that it is protected from any material or conditions that may cause it to ignite or react. Verify that incompatible wastes are not placed in the same pile and hazardous waste is not piled on the same base where incompatible wastes or materials were previously piled unless the base has been decontaminated and the following are avoided: generation of extreme heat or pressure, fire or explosions, or violent reactions production of uncontrolled toxic mists, fumes, dusts, or gases in quantities that would threaten human health or the environment production of uncontrolled flammable fumes or gases in quantities that would pose a risk of fire or explosion damage to structural integrity of the device or TSDF threats to human health or the environment through other means. Verify that piles of hazardous waste that are incompatible with any waste or other material stored nearby in other containers, piles, open tanks, or surface impoundments are separated from the other materials or protected from them by means of a dike, berm, wall, or other device. 4 - 163 Hazardous Waste 4 - 164 Hazardous Waste COMPLIANCE CATEGORY HAZARDOUS WASTE MANAGEMENT U.S. TEAM Guide REGULATORY REQUIREMENTS REVIEWER CHECKS March 2001 ALL TSDFs HW.160 Land Treatment Units HW.160.1.US. All land treatment facilities must follow specific guidelines for ignitable or reactive wastes and incompatible wastes (40 CFR 264.281, 264.282, 265.281, and 265.282). Determine if the land treatment facility handles any ignitable or incompatible waste. Verify that ignitable or reactive waste are not land treated unless: the waste is immediately incorporated into the soil so that the resulting mixture no longer meets the definition of ignitable or reactive waste either the waste is managed in such a way that it is protected from any materials that may cause it to react or the following are prevented: generation of extreme heat or pressure, fire or explosions, or violent reactions production of uncontrolled toxic mists, fumes, dusts, or gases in quantities that would threaten human health or the environment production of uncontrolled flammable fumes or gases in quantities that would pose a risk of fire or explosion damage to structural integrity of the device or facility threats to human health or the environment through other means. 4 - 165 Hazardous Waste 4 - 166 Hazardous Waste COMPLIANCE CATEGORY HAZARDOUS WASTE MANAGEMENT U.S. TEAM Guide REGULATORY REQUIREMENTS REVIEWER CHECKS March 2001 ALL TSDFs HW.165 Hazardous Waste Landfills HW.165.1.US. All hazardous waste landfills are required to have a run-on control system, a runoff management system, and control the wind dispersal of particulate matter (40 CFR 264.301(g) through 264.301(k) and 265.301(f) through 265.301(i)) [February 1995]. Verify that: the run-on control system has the capacity to prevent flow onto the active portion of the landfill during peak discharge of a 25-yr storm the runoff management system has an adequate capacity to collect and control water from a 24-h, 25-yr storm and the contents tested to determine correct disposal methodology collection and holding tanks or basins for run-on and runoff control systems are emptied expeditiously after storms there is adequate control of wind dispersal, no blowing debris there is adequate cover of waste material. (NOTE: For permitted TSDFs, the permit will specify all design and operating practices necessary to ensure compliance.) HW.165.2.US. All hazardous waste landfills must have specific information in their required operating records (40 CFR 264.309 and 265.309) [Added April 1998]. Verify that there is a map with the exact location and dimensions, including depth of each cell with respect to permanently surveyed benchmarks HW.165.3.US. To place ignitable or reactive materials in a hazardous waste landfill, specific requirements must be met (40 CFR 264.17(b), 264.312, 265.17(b), and 265.31) [Added April 1999]. Verify that: Verify that the contents of each cell and the approximate location of each hazardous waste type within the cell are recorded. both waste and landfill meet all applicable requirements of 40 CFR 268 waste, mixture, or dissolution of materials no longer meets the definition of ignitable or reactive waste precautions are taken to prevent reactions which: generate extreme heat, pressure, fire, explosions, or violent reactions produce uncontrolled toxic mists, fumes, dust, or gases at levels dangerous to human health or to the environment produce uncontrolled flammable fumes or gases at levels high enough to pose a risk of fire or explosion damage the structural integrity of the facility through other like means threaten human health or the environment. (NOTE: Ignitable wastes may be landfilled without meeting these standards if they 4 - 167 Hazardous Waste COMPLIANCE CATEGORY HAZARDOUS WASTE MANAGEMENT U.S. TEAM Guide REGULATORY REQUIREMENTS REVIEWER CHECKS March 2001 are disposed of in such a way that they are protected from any material or conditions which may cause them to ignite. At a minimum, these wastes must be: disposed of in non-leaking containers carefully handled and placed to avoid heat, sparks, rupture, or any other condition that might cause ignition of the wastes covered daily with soil or other non-combustible material NOT disposed of in cells that contain other wastes which may generate heat sufficient to cause ignition of the waste. This exception does not apply to prohibited wastes, which are listed in a table in subpart D of 40 CFR 268.) HW.165.4.US. Incompatible wastes or incompatible wastes and materials must not be placed in the same landfill cell, unless certain precautions are taken (40 CFR 264.17(b), 264.313, 265.17(b), and 265.313) [Added April 1999]. Verify that precautions are taken to prevent reactions which: HW.165.5.US. Bulk or noncontainerized liquid waste or waste containing free liquids cannot be placed in landfills after 8 May 1985 (40 CFR 264.314(a) through 254.314(d), 254.314(f), 265.314(a) through 265.314(e), and 265.314(g)) [Added April 1999]. Verify that, after 8 May 1985, bulk or noncontainerized liquid waste or waste containing free liquids is not placed in the landfill. generate extreme heat, pressure, fire, explosions, or violent reactions produce uncontrolled toxic mists, fumes, dust, or gases at levels dangerous to human health or to the environment produce uncontrolled flammable fumes or gases at levels high enough to pose a risk of fire or explosion damage the structural integrity of the facility through other like means threaten human health or the environment. (NOTE: The presence or absence of free liquids is demonstrated by Method 9095 (Paint Filter Liquids Test) as described in “Test Methods for Evaluating Solid Waste, Physical/Chemical Methods,” in EPA Publication SW-846.) (NOTE: Containers holding free liquids may only be placed in a landfill if they meet one of the following standards: all free-standing liquid has been: removed by decanting, or other methods mixed with sorbent or solidified so that free-standing liquid is no longer observed otherwise eliminated the container is very small, such as an ampule the container is designed to hold free liquids for use other than storage (for ex., a battery or capacitor) the container is a lab pack as defined in 264.316 or 265.316 (see checklist item HW.165.6).) (NOTE: The placement of any nonhazardous liquid in a landfill is prohibited, unless the Regional Administrator has determined that: the only reasonably available alternative would be to place it in a landfill or unlined surface impoundment, which contains or is reasonably believed to contain hazardous waste 4 - 168 Hazardous Waste COMPLIANCE CATEGORY HAZARDOUS WASTE MANAGEMENT U.S. TEAM Guide REGULATORY REQUIREMENTS REVIEWER CHECKS March 2001 placement in the landfill will not present a risk of contamination of any underground source of drinking water, as defined in 40 CFR 144.3.) HW.165.6.US. Sorbents used to treat free liquids to be disposed of in landfills must be nonbiodegradable (40 CFR 264.314(e) and 265.314(f)) [Added April 1999]. Verify that, the sorbent used is either an approved material, or is determined to be nonbiodegradable under one of the following tests: ASTM Method G21-70 (1984a) Standard Practice for Determining Resistance of Synthetic Polymer Materials to Fungi ASTM Method G22-76 (1984b) Standard Practice for Determining Resistance of Plastics to Bacteria OECD Test 301B-CO2 Evolution (Modified Sturm Test). (NOTE: Approved sorbents include: inorganic minerals, other inorganic materials, and elemental carbon high molecular weight synthetic polymers, except for polymers derived from biological material or polymers specifically designed to be degradable mixtures of nonbiodegradable materials.) HW.165.7.US. Containers must meet certain requirements in order to be placed in a hazardous waste landfill (40 CFR 264.315 and 265.315) [Added April 1999]. Verify that, unless they are very small (such as ampules), containers are: HW.165.8.US. Lab packs are required to meet specific parameters if placed in a landfill (40 CFR 264.316 and 265.316) [Added April 1999]. Verify that the following are met for lab packs being placed in a landfill: at least 90 percent full crushed, shredded, or similarly reduced in volume to the maximum practical extent. the hazardous waste is packaged in nonleaking inside containers designed and constructed of material that: will not react dangerously with the waste, be decomposed by the waste, or be ignited by the waste are tightly and securely sealed are of the size and type specified in the DOT hazardous materials regulations, defined by 49 CFR parts 173, 178, and 179, if such specifications exist for the particular waste the outside container used for overpack is: an open head DOT-specification metal shipping container of no more than 416 L (110 gal) capacity packed full with a combination of inside containers and nonbiodegradable sorbent materials not packed with incompatible wastes (i.e., wastes that may cause corrosion or decay of containment materials, and/or wastes that may 4 - 169 Hazardous Waste COMPLIANCE CATEGORY HAZARDOUS WASTE MANAGEMENT U.S. TEAM Guide REGULATORY REQUIREMENTS REVIEWER CHECKS March 2001 produce heat, pressure, fire, explosion, violent reaction, toxic dusts, mists, fumes, or gases, or flammable fumes or gases). Verify that the sorbent material is not capable of reacting dangerously with the waste, being decomposed by the waste, or being ignited by the waste. Verify that reactive wastes are treated or rendered nonreactive prior to packaging. Verify that disposal is in compliance with 40 CFR 268. (NOTE: If lab packs are to be incinerated in accordance with 40 CFR 268.42(c)(1), fiber drums may be used in place of metal drums. Fiber drums must meet the DOT specifications in 49 CFR 173.12. The packing procedures for fiber drums is the same as for metal drums.) HW.165.9.US. When permanently closing any landfill or any cell within a landfill, a final cover must be placed over the landfill or cell (40 CFR 264.310(a) and 265.310(a))[Added April 1999]. Verify that final cover is designed and constructed for the long term to: HW.165.10.US. After final closure of a hazardous waste landfill, certain procedures must be followed (40 CFR 264.310(b) and 265.310(b)) [Added April 1999]. Verify that, for a hazardous waste landfill, the owner/operator: minimize migration of liquids through the closed landfill function with minimum maintenance promote drainage and minimize erosion or abrasion of the cover tolerate settling and subsidence so that the cover’s integrity is maintained have a permeability less than or equal to the permeability of the bottom liner system or natural subsoil present. complies with all post-closure requirements maintains the integrity and effectiveness of the final cover makes repairs to the cap (cover) as necessary to correct the effects of settling, subsidence, erosion, or other disruptive events maintains and monitors the leak detection system maintains and monitors the groundwater monitoring system prevents run-on and runoff from eroding or otherwise damaging the final cover protects and maintains surveyed benchmarks. 4 - 170 Hazardous Waste COMPLIANCE CATEGORY HAZARDOUS WASTE MANAGEMENT U.S. TEAM Guide REGULATORY REQUIREMENTS ALL TSDFs HW.167 Hazardous Waste Munitions and Explosives Storage HW.167.1.US. Hazardous waste munitions and explosives storage units must be designed and operated with containment systems, controls and monitoring (40 CFR 264.1201(a) and 40 CFR 265.1201(a) [February 1997]. REVIEWER CHECKS March 2001 (NOTE: Depending on explosive hazards, hazardous waste munitions and explosives may also be managed in other types of storage units, including containment buildings, tanks, or containers.) Verify that the containment systems, controls, and monitoring minimize the potential for detonation or other means of release of hazardous waste, hazardous constituents, hazardous decomposition products, or contaminated runoff to the soil, groundwater, surface water, and atmosphere. Verify that the storage units provide a primary barrier which may be a container or a tank, designed to contain the hazardous waste. Verify that wastes stored outdoors are not standing in precipitation. Verify that liquid wastes are provided with a secondary containment system that assure that any released liquids are contained and promptly detected and removed from the waste area, or there are vapor detection systems that assure that any released liquids or vapors are promptly detected and an appropriate response is taken. Verify that there are monitoring and inspection procedures to assure the controls and containment systems are working as designed and that releases are not escaping from the unit. HW.167.2.US. Hazardous waste munitions and explosives stored are require to be stored in either earth covered magazines, aboveground magazines, or outdoor/open storage areas meeting specific requirements (40 CFR 264.1201(b) and 265.1201(b) [February 1997]. Verify that, when used, earth covered magazines meet the following requirements: constructed of waterproofed, reinforced concrete or structural steel arches, and steel doors that are kept closed when not being accessed designed and constructed: to be of sufficient strength and thickness to support the weight of any explosives or munitions stored and any equipment used in the unit to provide working space for personnel and equipment in the unit to withstand movement activities that occur in the unit located and designed with walls and earthen covers that direct an explosion in the unit in a safe direction, so as to minimize the propagation of an explosion to adjacent units and to minimize other effects of any explosion. Verify that, when used, aboveground magazines are located and designed to minimize the propagation of an explosion to adjacent units and to minimize other effects of any explosion. Verify that outdoor or open storage areas are located and designed to minimize the propagation of an explosion to adjacent units and to minimize other effects of any 4 - 171 Hazardous Waste COMPLIANCE CATEGORY HAZARDOUS WASTE MANAGEMENT U.S. TEAM Guide REGULATORY REQUIREMENTS REVIEWER CHECKS March 2001 explosion. HW.167.3.US. Hazardous waste munitions and explosive storage areas are required to have an SOP that ensures safety, security, and environmental protection (40 CFR 264.1201(c) and 265.1201(c) [February 1997]. Verify that the storage area has an SOP specifying procedures to ensure safety, security, and environmental protection. HW.167.4.US. Hazardous waste munitions and explosives must be managed according to specific parameters (40 CFR 264.1201(d) through 264.1201(f) and 265.1201(d) through 265.1201(f) [February 1997]. Verify that hazardous waste munitions and explosives are packaged to ensure safety in handling and storage. HW.167.5.US. Hazardous waste munitions and explosive storage areas are required to undergo specific closure procedures (40 CFR 264.1202 and 265.1202 [February 1997]. Verify that, at the closure of a magazine or unit which stored hazardous waste, all waste residues, contaminated containment system components, contaminated sub soils, and structures and equipment contaminated with waste are removed or decontaminated. (NOTE: If these procedures serve the same purpose as the security and inspection requirements of 40 CFR 264.14 and 265.14, the preparedness and prevention procedures of 40 CFR 264. subpart C and 265, subpart C, and the contingency plan and emergency procedure requirements of 40 CFR 264, subpart D and 265, subpart D, then these procedures will be used to fulfill those requirements.) Verify that hazardous waste munitions and explosives are inventoried at least annually. Verify that hazardous waste munitions and explosives and their storage units are inspected and monitored as necessary to ensure explosive safety and to ensure there is no migration of contaminants outside of the unit. (NOTE: Additional requirements for closure and postclosure of nonhazardous waste munitions TSDFs also apply.) Verify that if not all contaminated subsoils can be properly removed or decontaminated, postclosure care is performed. 4 - 172 Hazardous Waste COMPLIANCE CATEGORY HAZARDOUS WASTE MANAGEMENT U.S. TEAM Guide REGULATORY REQUIREMENTS REVIEWER CHECKS March 2001 ALL TSDFs HW.170 Closure HW.170.1.US. TSDFs must comply with certain closure schedules (40 CFR 264.110(a), 264.110(c), 264.113(a) through 264.113(d), 264.114, 265.110(a), 265.110(c), 265.113(a) through 265.113(d), and 265.114) [Revised January 1999]. (NOTE: These requirements apply to all hazardous waste management facilities. The Regional Administrator may substitute alternate requirements where it is determined that: the regulated unit is situated among solid waste management units (or areas of concern), a release has occurred, and both the regulated unit and one or more solid waste management units (or areas of concern) are likely to have contributed to the release it is not necessary to apply the closure requirements because alternative requirements will protect human health and the environment.) Verify that, within 90 days after receiving the final volume of waste, all hazardous waste has been treated and removed or disposed of onsite in accordance with the closure plan. Verify that partial and final closure activities are completed in accordance with the approved closure plan within 180 days after receiving the final volume of waste. (NOTE: The Regional Administrator may grant variances on the time period.) (NOTE: During partial and final closure periods, all contaminated equipment, structures, and soils must be properly disposed of. By removing any hazardous wastes or constituents during closure, the TSDF becomes a hazardous waste generator and is subject to the requirements of 40 CFR 262.) HW.170.2.US. All TSDFs are required to follow certain notification procedures for partial and final closure (40 CFR 264.110(a), 264.110(c), 264.112(d), 265.110(a), 265.110(c) and 265.112(d)) [Revised January 1999]. (NOTE: These requirements apply to all hazardous waste management facilities. The Regional Administrator may substitute alternate requirements where it is determined that: the regulated unit is situated among solid waste management units (or areas of concern), a release has occurred, and both the regulated unit and one or more solid waste management units (or areas of concern) are likely to have contributed to the release it is not necessary to apply the closure requirements because alternative requirements will protect human health and the environment.) Verify that TSDFs with surface impoundments, waste piles, land treatment, or landfill units notify the Regional Administrator: 180 days prior to the expected date of beginning closure of the first unit for interim status TSDFs without an approved closure plan; 60 days with an approved closure plan 4 - 173 Hazardous Waste COMPLIANCE CATEGORY HAZARDOUS WASTE MANAGEMENT U.S. TEAM Guide REGULATORY REQUIREMENTS REVIEWER CHECKS March 2001 45 days prior to the expected date of beginning closure for all permitted TSDFs. Verify that TSDFs with only tanks, containers, or incinerator units notify the Regional Administrator within 45 days prior to the date of beginning final closure. HW.170.3.US. Within 60 days of completion of closure of each hazardous waste surface impoundment, waste pile, land treatment, and landfill unit facilities must submit a certification of closure to the Regional Administrator (40 CFR 264.110(a), 264.110(c), 264.115, 265.110(a), 265.110(c), and 265.115) [Revised January 1999]. Verify that a certification of closure was sent to the Regional Administrator by registered mail within 60 days of closure of each hazardous waste surface impoundment, waste pile, land treatment unit, and landfill unit. HW.170.4.US. By the time that certification of closure has been submitted, TSDFs are required to submit a survey plat indicating the location and dimensions of landfill cells in relationship to permanently surveyed landmarks to specific authorities (40 CFR 264.110(b), 264.116, 265.110(b) and 265.116) [Revised January 1999]. Verify that a survey plat was submitted to the local zoning authorities (or the authority with jurisdiction over local land use) and the Regional Administrator no later than the submission of the certification of closure. HW.170.5.US. Postclosure care of hazardous waste management units must meet specific parameters (40 CFR 264.110(b), 264.117, 264.199,m 264..120, 265.110(b), 265.117, 265.119, 265.120) [Revised (NOTE: This requirement applies to the following: all hazardous waste disposal facilities waste piles and surface impoundments from which the owner or operator intends to remove the wastes at closure tank systems that are required to meet the requirements for landfills containment buildings that are required to meet the requirements for landfills.) (NOTE: These requirements apply to all hazardous waste management facilities. The Regional Administrator may substitute alternate requirements where it is determined that: the regulated unit is situated among solid waste management units (or areas of concern), a release has occurred, and both the regulated unit and one or more solid waste management units (or areas of concern) are likely to have contributed to the release it is not necessary to apply the closure requirements because alternative requirements will protect human health and the environment.) Verify that a professional land surveyor prepared and certified the plat. (NOTE: This requirement applies to the following: all hazardous waste disposal facilities waste piles and surface impoundments from which the owner or operator intends to remove the wastes at closure tank systems that are required to meet the requirements for landfills containment buildings that are required to meet the requirements for landfills.) Verify that postclosure care lasts for 30 yr after closure and consists of the 4 - 174 Hazardous Waste COMPLIANCE CATEGORY HAZARDOUS WASTE MANAGEMENT U.S. TEAM Guide REGULATORY REQUIREMENTS January 1999]. REVIEWER CHECKS March 2001 following: monitoring and reporting as required in other sections in Hazardous Waste Management maintenance of waste containment systems use of the property is not allowed to disturb the integrity of the final cover, liner, or any other components is done in accordance with the postclosure plan. (NOTE: Postclosure care generally must continue for 30 yr after the completion of closure. However, the Regional Administrator may shorten or extend the postclosure period.) Verify that, no later than 60 days after certification or closure of each hazardous waste disposal unit, a record of the type, location, and quantity of hazardous waste disposed of within each cell or other disposal unit is submitted to the local zoning authority, or the authority with jurisdiction over local land use, and to the Regional Administrator. (NOTE: For hazardous waste disposed of before 12 January 1981, the type, location, and quantity of the hazardous wastes are identified to the best of the owner/operators knowledge and in accordance with any records that have been kept.) Verify that, within 60 days of certification of closure of the first hazardous waste disposal unit and within 60 days of certification of closure of the last hazardous waste disposal unit, the following occur: a notation is recorded on the deed to the facility property, or on some other instrument that is normally examined during a title search, that the land has been used to manage hazardous waste and its use is restricted, and the survey plat and record of waste disposal have been filed with appropriate authorities submit a signed certification to the Regional Administrator that the required notation has been recorded. Verify that, if any current or subsequent owner of the property wishes to remove the hazardous waste and hazardous waste residues, the liner, or contaminated soils, a modification to the postclosure permit is requested. Verify that, no later than 60 days after completion of the established postclosure period for each hazardous waste disposal unit, a certification that the postclosure care period was performed in accordance with required specifications is submitted by registered mail to the Regional Administrator. 4 - 175 Hazardous Waste COMPLIANCE CATEGORY HAZARDOUS WASTE MANAGEMENT U.S. TEAM Guide REGULATORY REQUIREMENTS REVIEWER CHECKS March 2001 ADDITIONAL REQUIREMENTS FOR PERMITTED TSDFs HW.180 General HW.180.1.US. Permitted TSDFs that receive hazardous waste from offsite sources must inform the generator in writing that the TSDF has the appropriate permit and will accept the waste (40 CFR 264.12(b)). Verify that notification is sent and a copy is kept in the operating record. HW.180.2.US. Permitted TSDFs are required to institute corrective actions as outlined in the permit to protect human health and the environment for all releases from solid waste management units (40 CFR 264.90(a), 264.90(b), and 264.101) [Revised January 1999]. (NOTE: These requirements apply to all wastes (or constituents thereof) contained in solid waste management units, regardless of when the waste was placed in the solid waste management unit.) Verify that corrective actions required by the permit are being done. Verify that corrective actions are implemented beyond the property boundary where necessary to protect human health and the environment unless permission for such actions is not obtainable. (NOTE: The Regional Administrator may identify the unit as not having to comply with this requirement.) (NOTE: These requirements do not apply to surface impoundments, waste piles, or land treatment units receiving waste after 26 July 1982.) (NOTE: As a part of the corrective action program, the Regional Administrator may designate an area of the TSDF as a corrective action management unit (CAMU) or a temporary unit (TU).) HW.180.3.US. Container storage areas at TSDFs must have a containment system that meets specific standards (40 CFR 264.175(a) and 264.175(b)). Verify that all container storage areas meet the following criteria: containers are stored on a base that is free from cracks or gaps and is impervious so leaks, spills, and precipitation are contained the base is sloped (or otherwise designed) to drain and remove liquids resulting from leaks, spills, or precipitation unless the containers are elevated spilled or leaked waste and accumulated precipitation is removed in a timely 4 - 176 Hazardous Waste COMPLIANCE CATEGORY HAZARDOUS WASTE MANAGEMENT U.S. TEAM Guide REGULATORY REQUIREMENTS REVIEWER CHECKS March 2001 manner the containment system has adequate capacity to contain 10 percent of the volume of the containers or the volume of the largest container, whichever is greater run-on into the containment system is prevented unless the system has sufficient capacity to contain any run-on that might enter the system in addition to the already required capacity. (NOTE: If the collected material is a hazardous waste, it must be handled accordingly. If it is discharged through a point source, it is subject to the Clean Water Act (CWA) requirements.) HW.180.4.US. Containment at permitted TSDFs for containers holding wastes that do not contain free liquids must meet specific criteria, which is less than that for general containment areas (40 CFR 264.175(c)). Verify that one of the following storage area criteria is met: HW.180.5.US. When container storage areas are closed at permitted TSDFs, specific conditions must be met (40 CFR 264.178). Verify that closure criteria was met: HW.180.6.US. TSDFs with permitted surface impoundments, waste piles, and land treatment units or landfills that received hazardous waste after 26 July 1982 (i.e., a regulated unit] are required to conduct monitoring and response programs under specific circumstances (40 CFR 264.90(a)(2), 264.90(b), 264.90(c)(1), 264.90(e), (NOTE: These requirements apply when either a postclosure document or an enforceable document have been issued to the facility. The Regional Administrator may substitute alternate groundwater monitoring and corrective action requirements where it is determined that: the regulated unit is situated among solid waste management units (or areas of concern), a release has occurred, and both the regulated unit and one or more solid waste management units (or areas of concern) are likely to have contributed to the release it is not necessary to apply the regulations because alternative requirements will protect human health and the environment.) the area is sloped or able to drain and remove liquid resulting from precipitation containers are elevated or protected from contact with accumulated liquid. (NOTE: Storage areas must have complete containment systems when the containers holding F020, F021, F022, F023, F026, and F027 do not contain free liquids.) all hazardous waste and residues were removed from the containment system remaining containers, liners, bases, and soils (containing or contaminated with hazardous waste or hazardous waste residues) were decontaminated or removed all hazardous wastes (including materials removed from the containment system) were managed appropriately. Verify that, whenever permit-designated hazardous constituents are detected at permit-designated compliance points, a compliance monitoring program is started 4 - 177 Hazardous Waste COMPLIANCE CATEGORY HAZARDOUS WASTE MANAGEMENT U.S. TEAM Guide REGULATORY REQUIREMENTS 264.90(f) and 264.91 through 264.95) [Revised January 1999]. REVIEWER CHECKS March 2001 as described in 40 CFR 264.99 (See checklist item HW.180.9). Verify that, whenever permit-designated groundwater protection limits are exceeded, a corrective action program is initiated as described in 40 CFR 264.100 (see checklist item HW.180.10). Verify that, whenever permit-designated hazardous constituents exceed concentration limits in Appendix 4-11 or permit-designated concentrations in groundwater between a designated compliance point and the downgradient property boundary, a corrective action program or a detection monitoring program is started at the TSDF. (NOTE: In situations other than those described here, a detection monitoring program as described in 40 CFR 264.98 is required.) (NOTE: A regulated unit is not subject to regulation for releases into the uppermost aquifer if: it is otherwise exempt from Part 264 the Regional Administrator has exempted the regulated unit it is a waste pile operated in compliance with 40 CFR 254.250(c).) (NOTE: These requirements do not apply after closure of the regulated unit if all waste, waste residues, contaminated containment system components, and contaminated subsoils are removed or decontaminated at closure.) Verify that the TSDF is meeting the elements of the monitoring and response program specified by the Regional Administrator in the permit. HW.180.7.US. Checklist item deleted [Deleted January 1999]. (NOTE: This checklist item was deleted because its contents were incorporated in HW.180.6.) HW.180.8.US. TSDFs with permitted surface impoundments, waste piles, and land treatment units or landfills that received hazardous waste after 26 July 1982 that are required to operate detection monitoring programs must meet specific requirements (40 CFR 264.90(a)(2), 264.90(b), 264.90(c)(1), 264.90(e), 264.90(f) and 264.98) (NOTE: See checklist item HW.180.6 for guidance and who must have a detection monitoring program.) (NOTE: These requirements apply when the either a postclosure document or an enforceable document have been issued to the facility. The Regional Administrator may substitute alternate groundwater monitoring and corrective action requirements where it is determined that: the regulated unit is situated among solid waste management units (or areas of concern), a release has occurred, and both the regulated unit and one or more solid waste management units (or areas of concern) are likely to have contributed to the release it is not necessary to apply the regulations because alternative requirements will protect human health and the environment.) 4 - 178 Hazardous Waste COMPLIANCE CATEGORY HAZARDOUS WASTE MANAGEMENT U.S. TEAM Guide REGULATORY REQUIREMENTS REVIEWER CHECKS March 2001 [Revised January 1999]. Verify that indicator parameters (e.g., specific conductance, total organic carbon, or total organic halon), waste constituents, or reaction products that provide a reliable indication of the presence of hazardous constituents in groundwater and meet the parameters specified in the permit issued by the Regional Administrator. Verify that a record is kept of groundwater analytical data as measured and in a form necessary for the determination of statistical significance. Verify that the groundwater flow rate and direction in the uppermost aquifer are determined at least annually. Verify that it is identified whether or not there is statistically significant evidence of contamination for any chemical parameter or permit-designated hazardous constituent. Verify that the following steps are taken if there is significant evidence of contamination: the Regional Administrator is notified in writing within 7 days the groundwater in all monitoring wells is immediately sampled and analyzed for constituents in Appendix IX of 40 CFR 264 (see Appendix 4-12) sampling may be repeated after 1 mo for any compounds detected that are listed in Appendix IX of 40 CFR 264 within 90 days an application for a permit modification is submitted to the Regional Administrator to establish a compliance monitoring program within 180 days all data necessary to justify an alternate concentration limit and the engineering feasibility plan is submitted to the regional administrate unless an exception applies. (NOTE: A regulated unit is not subject to regulation for releases into the uppermost aquifer if: it is otherwise exempt from Part 264 the Regional Administrator has exempted the regulated unit it is a waste pile operated in compliance with 40 CFR 254.250(c).) (NOTE: These requirements do not apply after closure of the regulated unit if all waste, waste residues, contaminated containment system components, and contaminated subsoils are removed or decontaminated at closure.) HW.180.9.US. TSDFs with permitted surface impoundments, waste piles, and land treatment units or landfills that received hazardous waste after 26 July 1982 that are required to (NOTE: These requirements apply when the either a postclosure document or an enforceable document have been issued to the facility. The Regional Administrator may substitute alternate groundwater monitoring and corrective action requirements where it is determined that: the regulated unit is situated among solid waste management units (or areas of concern), a release has occurred, and both the regulated unit and one or more solid waste management units (or areas of concern) are likely to have 4 - 179 Hazardous Waste COMPLIANCE CATEGORY HAZARDOUS WASTE MANAGEMENT U.S. TEAM Guide REGULATORY REQUIREMENTS operate compliance monitoring programs must meet specific requirements (40 CFR 264.90(a)(2), 264.90(b), 264.90(c)(1), 264.90(e), 264.90(f) and 264.99) [Revised January 1999]. REVIEWER CHECKS March 2001 contributed to the release it is not necessary to apply the regulations because alternative requirements will protect human health and the environment.) Verify that a record is kept of groundwater analytical data as measured and in a form necessary for the determination of statistical significance. Verify that the groundwater flow rate and direction in the uppermost aquifer are determined at least annually. Verify that it is identified whether or not there is statistically significant evidence of contamination for any chemical parameter or permit-designated hazardous constituent. Verify that the following actions are taken when concentration are exceeded: the Regional Administrator is notified in writing within 7 days an application for a permit modification to establish a corrective action program is submitted within 180 days. (NOTE: A regulated unit is not subject to regulation for releases into the uppermost aquifer if: it is otherwise exempt from Part 264 the Regional Administrator has exempted the regulated unit it is a waste pile operated in compliance with 40 CFR 254.250(c).) (NOTE: These requirements do not apply after closure of the regulated unit if all waste, waste residues, contaminated containment system components, and contaminated subsoils are removed or decontaminated at closure.) HW.180.10.US. TSDFs with permitted surface impoundments, waste piles, and land treatment units or landfills that received hazardous waste after 26 July 1982 that are required to operate corrective action programs must meet specific requirements (40 CFR 264.90(a)(2), 264.90(b), 264.90(c)(1), 264.90(e), 264.90(f) and 264.100) [Revised January 1999]. (NOTE: These requirements apply when the either a postclosure document or an enforceable document have been issued to the facility. The Regional Administrator may substitute alternate groundwater monitoring and corrective action requirements where it is determined that: the regulated unit is situated among solid waste management units (or areas of concern), a release has occurred, and both the regulated unit and one or more solid waste management units (or areas of concern) are likely to have contributed to the release it is not necessary to apply the regulations because alternative requirements will protect human health and the environment.) Determine if the TSDF operates a corrective action program. Verify that the corrective action program prevents hazardous constituents from exceeding their designated concentration limits at the compliance point by removing the hazardous waste constituents or treating them in place as specified 4 - 180 Hazardous Waste COMPLIANCE CATEGORY HAZARDOUS WASTE MANAGEMENT U.S. TEAM Guide REGULATORY REQUIREMENTS REVIEWER CHECKS March 2001 by permit. Verify that corrective action was begun in a reasonable period of time after the groundwater protection standard is exceeded. Verify that a groundwater monitoring program is in place to demonstrate the effectiveness of the corrective action program. Verify that a semi-annual progress report is sent to the Regional Administrator. (NOTE: A regulated unit is not subject to regulation for releases into the uppermost aquifer if: it is otherwise exempt from Part 264 the Regional Administrator has exempted the regulated unit it is a waste pile operated in compliance with 40 CFR 254.250(c).) (NOTE: These requirements do not apply after closure of the regulated unit if all waste, waste residues, contaminated containment system components, and contaminated subsoils are removed or decontaminated at closure.) HW.180.11.US. item deleted January 1999]. Checklist [Deleted Checklist item deleted because it was a duplicate of HW.180.2. HW.180.12.US. All permitted TSDFs are required to document compliance with ignitable, reactive, or incompatible waste management requirements (40 CFR 264.17(c)). Verify that compliance documentation is maintained at the TSDF, and that it is based on published scientific or engineering literature, data from field tests, or the results of the treatment of similar wastes by similar treatment processes or similar operating conditions. HW.180.13.US. Permitted TSDFs with process vents associated with distillation, fractionation, thin-film evaporation, solvent extraction, or air or steam stripping operations that manage hazardous wastes with organic concentrations of at least 10 ppmw are required to Verify that a semiannual report is submitted to the Regional Administrator and that it includes the following: the USEPA identification number, name, and address of the TSDF dates when the control device exceeded or operated outside of design specification and the exceedances were not corrected within 24 h dates when a flare operated with visible emissions the duration and cause of exceedance and corrective measures taken. 4 - 181 Hazardous Waste COMPLIANCE CATEGORY HAZARDOUS WASTE MANAGEMENT U.S. TEAM Guide REGULATORY REQUIREMENTS REVIEWER CHECKS March 2001 submit a semi-annual report concerning process vent emissions (40 CFR 264.1036). (NOTE: If there are no exceedance a report is not required.) HW.180.14.US. Permitted facilities are required to meet specific reporting requirements as related to air emissions controls (40 CFR 264.1090(a), 264.1090(c), and 264.1090(d)) [Revised December 1997]. Verify that a written report is submitted to the Regional Administrator within 15 days of becoming aware that hazardous waste is being managed in an exempted container in noncompliance with the applicable design and operating requirements. Verify that, in regard to required control devices, a semi-annual written report is submitted to the Regional Administrator describing each occurrence of noncompliance during the previous 6 mo when either of the following occurred: a control device is operated continuously for 24 h or longer in noncompliance with the applicable operating values a flare is operated with visible emissions for 5 min or longer in a 2-h period. Verify that the report contains an explanation of why the control device could not be returned to compliance within 24 h and actions taken to correct noncompliance. (NOTE: The semiannual report is not required for a 6-mo period if all control devices are operated so there is not a period of 24 h or longer in which the control device was in continuous noncompliance and no flare was operated with visible emissions for 5 min or longer in a 2-h period.) (NOTE: If the facility received its permit under RCRA Section 3005 prior to 6 December 1996, these requirements will be incorporated in the permit when it is reviewed. Until that time, the TSDF is required to comply with 40 CFR 265 Subpart CC (40 CFR 264.1080(c) and 265.1080(c)).) 4 - 182 Hazardous Waste 4 - 183 Hazardous Waste COMPLIANCE CATEGORY HAZARDOUS WASTE MANAGEMENT U.S. TEAM Guide REGULATORY REQUIREMENTS REVIEWER CHECKS March 2001 ADDITIONAL REQUIREMENTS FOR PERMITTED TSDFs HW.185 Surface Impoundments HW.185.1.US. Permitted surface impoundments must be designed according to specific parameters (40 CFR 264.221(a) and 264.221(g) through 264.221(i)). Determine if the TSDF has a permitted surface impoundment. Verify that surface impoundments have a liner for all portions of the impoundment. Verify that the impoundment is designed, constructed, maintained, and operated to prevent overtopping as a result of overfilling, wind and wave action, rainfall, runon, malfunctions of level controllers, alarms and other equipment, and human error. Verify that the impoundment has dikes which are designed, constructed, and maintained to prevent massive failure of the dikes. (NOTE: The Regional Administrator will specify in the permit all design and operating practices that are necessary.) HW.185.2.US. New permitted surface impoundments that started construction after 29 January 1992, lateral expansions of permitted surface impoundments which started construction after 29 July 1992, and replacements of existing surface impoundments for which reuse started after 29 July 1992 are required to meet specific design and operating criteria (40 CFR 264.19, 264.221(c) through 264.221(f), 264.222, 264.223, and 264.226(d)). Verify that the impoundment has two or more liners and a leachate collection and removal system between liners, or the double liner requirement has been waived by the USEPA Regional Administrator. Verify that the liner meets the specifications stated in 40 CFR 264.221(c). Verify that the TSDF has a construction quality assurance (CQA) program to ensure that constructed units meet or exceed all design criteria and specifications in the permit. Verify that the designated CQA officer is a registered professional engineer. Verify that the TSDF has a written CQA plan that addresses the following: identification of applicable units and a description of how they will be constructed identification of key personnel a description of sampling and inspection activities. Verify that waste is not received in a unit until an approved CQA plan has been submitted to the Regional Administrator. 4 - 184 Hazardous Waste COMPLIANCE CATEGORY HAZARDOUS WASTE MANAGEMENT U.S. TEAM Guide REGULATORY REQUIREMENTS REVIEWER CHECKS March 2001 Verify that these surface impoundments comply with the action leakage rate assigned by the Regional Administrator. Verify that the surface impoundment facility has an approved response action plan prior to the receipt of waste. Verify that the amount of liquid removed from each leak detection system sump is recorded at least once a week during the active life and closure period. Verify that, after a final cover is installed, the amount of liquids removed from each leak detection system sump is recorded at least monthly or: if the liquid level in the sump stays below the pump operating level for 2 consecutive months, then the liquid amounts may be recorded quarterly if the liquid level in the sump stays below the pump operating level for 2 consecutive quarters, then the liquid amounts may be recorded semiannually. (NOTE: TSDFs with replacement surface impoundments may be exempt from these requirements if the existing unit was constructed in compliance with the design standards of sections 3004(o)(1)(A)(i) and (o)(5) of RCRA and there is no reason to believe the liner is not functioning as designed.) HW.185.3.US. Permitted TSDFs must inspect liners and cover systems during construction and installation of liners (40 CFR 264.226(a)). (NOTE: This excludes existing portions of surface impoundments exempt from 264.221(a).) HW.185.4.US. TSDFs must conduct inspections while surface impoundments are in operation (40 CFR 264.226(b)). Verify that inspections are conducted at least weekly and after storms to detect evidence of the following: HW.185.5.US. Prior to the issuance of a permit and/ or after any period of greater than 6 mo of disuse, the TSDF must obtain certification from a qualified engineer that Determine if the TSDF is permitted or if any impoundment has been out of service for 6 mo or more. Verify that liners and covers are inspected for uniformity, damage, and imperfections. deterioration, malfunctions, or improper operation of overtopping control systems sudden drops in the level of the impoundment contents severe erosion or other signs of deterioration in dikes or other containment devices. Verify that the certification of structural integrity includes: verification that the impoundment can withstand the amounts and types of 4 - 185 Hazardous Waste COMPLIANCE CATEGORY HAZARDOUS WASTE MANAGEMENT U.S. TEAM Guide REGULATORY REQUIREMENTS REVIEWER CHECKS March 2001 surface impoundment dikes have structural integrity (40 CFR 264.226(c)). waste it will contain that the impoundment will not fail due to scouring or piping without dependence on any liner system. HW.185.6.US. TSDFs must follow specific restrictions concerning the types of wastes placed in permitted surface impoundments (40 CFR 264.231). Verify that hazardous waste F020, F021, F022, F023, F026, and F027 are not placed in the impoundment unless it is done according to a management plan approved by the Regional Administrator. HW.185.7.US. Permitted surface impoundments are required to be removed from service under specific circumstances (40 CFR 264.227(a)). Verify that surface impoundments have been removed from service if any of the following circumstances exist: HW.185.8.US. In order to remove a permitted surface impoundment from service, specific parameters have to be met (40 CFR 264.227(b), 264.227(c), and 264.227(e)). Verify that, when a surface impoundment is removed from service, the following requirements are met: the level of liquid suddenly drops and the drop is not known to be caused by changes in flow the dike leaks. the flow or addition of waste is immediately shut off or stopped surface leakage is immediately contained leaks are stopped or empty the impoundment the Regional Administrator is notified in writing within 7 days of problems take any of the necessary steps to stop or prevent catastrophic failure. Verify that the contingency plan specifies a procedure for taking a surface impoundment out of service. Verify that, if a surface impoundment is removed from service and it is not being repaired, it is closed. HW.185.9.US. Surface impoundments may not be restored to service unless specific standards are met (40 CFR 264.227(d)). Verify that prior to being returned to service the following is done: HW.185.10.US. TSDFs that Determine if the TSDF has closed, or plans to close, any surface impoundment the portion of the impoundment that was failing is repaired the dike is recertified if the reason for removal from service was faulty dike integrity liners are correctly installed and operating. 4 - 186 Hazardous Waste COMPLIANCE CATEGORY HAZARDOUS WASTE MANAGEMENT U.S. TEAM Guide REGULATORY REQUIREMENTS have surface impoundments must follow certain closure and postclosure requirements (40 CFR 264.228(a) and 264.228(b)). REVIEWER CHECKS March 2001 activities. Verify that, at closure, the TSDF does one of the following: removes or decontaminates all waste residues, contaminated containment system components, contaminated subsoils, and structures and equipment contaminated with waste and leachate and manages them as hazardous waste eliminates the free liquids by removing liquid wastes or solidifying the remaining wastes and water residue; stabilizes remaining wastes to a bearing capacity sufficient to support final cover and cover the surface impoundment with a final cover designed and constructed to: provide long-term minimization of the migration of liquids function with minimum maintenance promote drainage and minimized erosion or abrasion of the final cover accommodate settling and subsidence so that the cover’s integrity is maintained have a permeability less than or equal to the permeability of any bottom liner system or natural subsoils present. Verify that, if waste residues or contaminated materials are left in place, the TSDF meets postclosure requirements outlined in 40 CFR 264.117 through 264.120 (see checklist items HW.145.8 and HW.170.5) and: maintains the integrity and effectiveness of the final cover maintains and monitors the leak detection system maintains and monitors the groundwater monitoring system prevents run-on and runoff from eroding or otherwise damaging the final cover. HW.185.11.US. Facilities are required to meet specific reporting requirements as related to air emissions (40 CFR 264.1090(a), 264.1090(c), and 264.1090(d)) [Revised December 1997]. Verify that a written report is submitted to the Regional Administrator within 15 days of becoming aware that hazardous waste is being managed in an exempted surface impoundment in noncompliance with the applicable design and operating requirements. Verify that, in regard to required control devices, a semiannual written report is submitted to the Regional Administrator describing each occurrence of noncompliance during the previous 6 mo when either of the following occurred: a control device is operated continuously for 24 h or longer in noncompliance with the applicable operating values a flare is operated with visible emissions for 5 min or longer in a 2-h period. Verify that the report contains an explanation of why the control devices could not be returned to compliance within 24 h and actions taken to correct noncompliance. (NOTE: The semiannual report is not required for a 6-mo period if all control devices are operated so there is not a period of 24 h or longer in which the control 4 - 187 Hazardous Waste COMPLIANCE CATEGORY HAZARDOUS WASTE MANAGEMENT U.S. TEAM Guide REGULATORY REQUIREMENTS REVIEWER CHECKS March 2001 device was in continuous noncompliance and no flare was operated with visible emissions for 54 min or longer in a 2-h period. (NOTE: If the facility received its permit under RCRA Section 3005 prior to 6 December 1996, these requirements will be incorporated in the permit when it is reviewed. Until that time, the TSDF is required to comply with all 40 CFR 265, Subpart CC (40 CFR 165.1080(c).) HW.185.12.US. Surface impoundments not in compliance with the liner and leachate collection system requirements are required to perform specific actions (40 CFR 264.110(a), 264.110(c), and 264.113(e)) [Added January 1999]. (NOTE: These requirements apply to all hazardous waste management facilities. The Regional Administrator may substitute alternate requirements where it is determined that: the regulated unit is situated among solid waste management units (or areas of concern), a release has occurred, and both the regulated unit and one or more solid waste management units (or areas of concern) are likely to have contributed to the release it is not necessary to apply the closure requirements because alternative requirements will protect human health and the environment.) Verify that a request has been submitted to modify the permit. Verify that all hazardous wastes have been removed from the unit by removing all hazardous liquids, and removing all hazardous sludges to the extent practicable without impairing the integrity of the liner, if any. Verify that removal of hazardous waste is done within 90 days after the final receipt of hazardous waste. (NOTE: The Regional Administrator may approve an extension.) Verify that, if a release that is a statistically significant increase (or decrease in the case of pH) over background values for detection monitoring parameters or constituents specified in the permit or that exceeds the impoundment’s groundwater protection standard at the point of compliance is detected, the owner/operator: implements corrective measures in accordance with approved contingent corrective measures plan no later than 1 yr after detection or approval of the plan, whichever is later continues to receive waste only if the approved corrective measures plan includes a demonstration that continued receipt of wastes will not impede corrective action responds to Regional Administrator imposed timelines. Verify that, during the period of corrective action, semi-annual reports are provided to the Regional Administrator describing the progress of the corrective action program, compiles all groundwater monitoring data, and evaluates the effect 4 - 188 Hazardous Waste COMPLIANCE CATEGORY HAZARDOUS WASTE MANAGEMENT U.S. TEAM Guide REGULATORY REQUIREMENTS REVIEWER CHECKS March 2001 of the continued receipt of nonhazardous wastes on the effectiveness of the corrective action. 4 - 189 Hazardous Waste COMPLIANCE CATEGORY HAZARDOUS WASTE MANAGEMENT U.S. TEAM Guide REGULATORY REQUIREMENTS REVIEWER CHECKS March 2001 ADDITIONAL REQUIREMENTS FOR PERMITTED TSDFs HW.190 Waste Piles HW.190.1.US. Permitted TSDFs that store or treat hazardous waste in waste piles must meet specific design and operating standards (40 CFR 264.250, 264.251(a), 264.251(b), and 264.251(g) through 264.251(k)). (NOTE: Waste piles closed with wastes left in place are regulated as landfills. Waste piles inside or under a protective structure are exempt from the standards in 264.250 through 264.259 if they contain no liquids, are protected from run-on, are designed and operated to control dispersal of waste by wind, and do not generate leachate through decomposition or other reactions.) Determine if the TSDF treats or stores hazardous waste in waste piles. Verify that the following standards are met for each waste pile: the pile has a liner and is located on a foundation that provides support the liner is installed to cover all surrounding earth likely to be in contact with the waste or leachate a leachate collection and removal system is located immediately above the liner leachate depth over the liner does not exceed 30 cm (1 ft) protection from wind and run-on is provided a runoff management system is in place and in operating condition tanks and basins associated with the run-on and runoff control systems are emptied. (NOTE: The permit will designate all design and operating practices necessary to ensure that the requirements are satisfied.) HW.190.2.US. Permitted waste piles constructed after 29 January 1992, lateral expansions that started after 29 July 1992, and replacement of existing waste piles where reuse started after 29 July 1992 are required to meet specific design and operating requirements (40 CFR 264.19, 264.251(c) through 264.251(f), 264.252, and 264.253). Verify that the described waste piles have two or more liners and a leachate collection and removal system above and between the liners. Verify that the liners are designed and constructed of materials to prevent the migration of hazardous constituents into the liner during the active life and postclosure care period. (NOTE: See 40 CFR 264.251(c)(1) and 264.251(c)(2) for details on the design of the liners and the leachate collection system.) Verify that the TSDF has a CQA program to ensure that constructed units meet or exceed all design criteria and specifications in the permit. Verify that the designated CQA officer is a registered professional engineer. 4 - 190 Hazardous Waste COMPLIANCE CATEGORY HAZARDOUS WASTE MANAGEMENT U.S. TEAM Guide REGULATORY REQUIREMENTS REVIEWER CHECKS March 2001 Verify that the TSDF has a written CQA plan that addresses the following: identification of applicable units and a description of how they will be constructed identification of key personnel a description of sampling and inspection activities. Verify that waste is not received in a unit until an approved CQA plan has been submitted to the Regional Administrator. Verify that the pumpable liquids in the leak detection sumps are removed to minimize the head on the bottom liner. Verify that the TSDF is complying with the action leakage rate assigned by the Regional Administrator. Verify that the TSDF has an approved response action plan prior to the receipt of waste. (NOTE: The Regional Administrator may approve alternative designs or grant a waiver.) HW.190.3.US. TSDFs must conduct inspections of permitted waste piles during construction and while they are in operation (40 CFR 264.254). Verify that, if construction of a waste pile is occurring at the TSDF, the following inspections are taking place: liners and cover systems are inspected for uniformity, damage, and imperfection synthetic liners and covers are inspected for tight seams and joints immediately after construction soil-based and admixed liners and covers are inspected for imperfections. Verify that the waste pile is inspected at least weekly and after storms to detect evidence of the following: deterioration, malfunctions, or improper operation in run-on and runoff systems proper functioning of wind dispersal control system presence of leachate in, and proper functioning of, leachate control system. Verify that the amount of liquids removed from each leak detection system is recorded at least once a week during the active life and closure period. HW.190.4.US. TSDFs that treat F020, F021, F022, F023, F026, and/or F027 in Determine if the TSDF treats F020-F023, F026, or F027. Verify that these wastes are kept in enclosed piles unless the owner/operator has a 4 - 191 Hazardous Waste COMPLIANCE CATEGORY HAZARDOUS WASTE MANAGEMENT U.S. TEAM Guide REGULATORY REQUIREMENTS REVIEWER CHECKS March 2001 permitted waste piles are required to follow specific operating procedures (40 CFR 264.259). management plan approved by the Regional Administrator. HW.190.5.US. TSDFs that operate permitted waste piles must follow specific requirements for closure and postclosure care (40 CFR 264.258). Verify that, at the time of closure, all waste residues, contaminated containment system components, subsoils, and structures and equipment contaminated with hazardous waste have been removed or decontaminated. Verify that, if all contaminated subsoils cannot be removed or decontaminated practicably, the site is closed and managed according to closure and postclosure care requirements for a landfill. Verify that, if the TSDF has a waste pile that does not comply with the liner requirement, and is not exempted from this requirement, it complies with the following: the written closure plan addresses the removal of all contaminated substances and a contingency plan if all contamination cannot be removed from the pile a contingency postclosure plan is prepared for the waste pile and be submitted to the appropriate agency within 90 days after determining the waste pile must be closed. 4 - 192 Hazardous Waste COMPLIANCE CATEGORY HAZARDOUS WASTE MANAGEMENT U.S. TEAM Guide REGULATORY REQUIREMENTS REVIEWER CHECKS March 2001 ADDITIONAL REQUIREMENTS FOR PERMITTED TSDFs HW.195 Land Treatment Units HW.195.1.US. TSDFs with permitted hazardous waste land treatment units must meet certain standards (40 CFR 264.270 through 264.273(f)). Determine if the TSDF disposes of hazardous waste in an onsite land treatment unit. Verify that the TSDF has a land treatment program that is designed to ensure that hazardous constituents placed in or on the treatment zone are degraded, transformed, or immobilized within the treatment zone. Verify that the unit is operating according to the parameters established by the Regional Administrator in the permit. Verify that prior to the application of a waste, the TSDF has demonstrated that the hazardous constituents in the waste can be completely degraded, transformed, or immobilized in the treatment zone. Verify that if, as a part of the demonstration, the TSDF conducts field tests or laboratory analysis, a treatment of disposal permit was acquired prior to the tests or analyses. Verify that the following standards are met at each permitted hazardous waste land treatment unit: the treatment zone is no more than 1.5 m (5 ft) from the initial soil surface the treatment zone is more than 1 m (3 ft) above the seasonal high water table run-on control systems are operated to prevent flow onto the treatment zone during peak discharge from at least a 25-yr storm runoff management systems are constructed and operated to collect and control at least the water volume resulting from a 24-h, 25 yr storm tanks and basins associated with the run-on and runoff control systems are emptied or otherwise managed after storms wind dispersal is controlled. HW.195.2.US. TSDFs must conduct inspections while land treatment facilities are in operation (40 CFR 264.273(g)). Verify that the land treatment system is inspected weekly and after storms to detect evidence of: deterioration, malfunctions, or improper operation of run-on and runoff control systems improper functioning of wind dispersal control measures. 4 - 193 Hazardous Waste COMPLIANCE CATEGORY HAZARDOUS WASTE MANAGEMENT U.S. TEAM Guide REGULATORY REQUIREMENTS HW.195.3.US. TSDFs with food chain crops grown in or on the treatment zone are required to meet specific operational standards (40 CFR 264.276). REVIEWER CHECKS March 2001 Determine if food chain crops are grown in or on the treatment zone. Verify that prior to the growth of food chain crops in or on the treatment zone, it has been demonstrated that there is no substantial risk to human health caused by the growth of the crops by demonstrating that hazardous constituents other than cadmium meet one of the following: will not be transferred to the food or feed portions of the crop by plant uptake or direct contact, and will not otherwise be ingested by food chain animals will not occur in greater concentrations in or on food or feed portions of the crops grown on the treatment zone than in or on identical portions of the same crops grown on untreated soils under similar conditions in the same region. Verify that, if food chain crops are grown, only those specified in the permit by the Regional Administrator are being grown. Verify that, if cadmium-containing wastes are applied to food chain crops in or on treatment zones, the following are met: the pH of the waste and soil mixture is 6.5 or greater at the time of application, except in cases where the waste contains cadmium at concentrations of 2 mg/kg or less the annual application of cadmium from waste does not exceed 0.5 kg/ha on land used for production of tobacco, leafy vegetables, or root crops grown for human consumption. For other food chain crops the annual cadmium does not exceed 0.5 kg/ha the cumulative application of cadmium from waste does not exceed 5 kg/ha if the waste and soil mixture has a pH less than 6.5 if the waste and soil mixture has a pH of 6.5 or greater or is maintained at a pH of 6.5 or greater during crop growth and one of the following is met: the cumulative application of cadmium from waste does not exceed 5 kg/ ha if soil cation exchange capacity is less than 5 meq/100 g the cumulative application of cadmium from waste does not exceed 10 kg/ ha if soil cation exchange capacity is 5 to 15 meq/100 g the cumulative application of cadmium from waste does not exceed 20 kg/ ha if soil cation exchange capacity is greater than 15 meq/100 g animal feed is the only food chain crop produced. HW.195.4.US. Permitted land treatment units must have an unsaturated zone monitoring program (40 CFR 264.278). Verify that the unsaturated zone monitoring program meets the following: the soil and soil-pore liquid are monitored to determine if hazardous constituents migrate out of the treatment zone a system is installed that includes soil monitoring using soil cores and soil-pore liquid monitoring using devices such as lysimeters a background value has been established for each hazardous constituent to be monitored (see permit) 4 - 194 Hazardous Waste COMPLIANCE CATEGORY HAZARDOUS WASTE MANAGEMENT U.S. TEAM Guide REGULATORY REQUIREMENTS REVIEWER CHECKS March 2001 the soil monitoring and soil-pore liquid monitoring is done immediately below the treatment zone consistent sampling and monitoring procedures are used. Verify that the contaminants listed in the permit are being monitored. Verify that, when it is found that there is a statistically significant increase of hazardous constituents below the treatment zone the following steps are taken: the Regional Administrator is notified within 7 days in writing within 90 days a permit application is submitted to the Regional Administrator for a permit modification to modify the operating practices. HW.195.5.US. Land treatment facilities must keep an operating record that includes dates and rates of application (40 CFR 265.279). Verify that the operating record contains the dates and rates of applications. HW.195.6.US. All land treatment facilities are required to meet specific closure and postclosure plans (40 CFR 264.280). Verify that, during the closure period, the following requirements are met: all operations are continued as necessary to maximize degradation, transformation, or immobilization of hazardous constituents in the treatment zone runoff is minimized run-on and runoff management systems are maintained wind dispersal of hazardous waste is controlled compliance with food chain crop prohibitions is continued unsaturated zone monitoring is continued, except that soil-pore liquid monitoring may be terminated 90 days after the last application of waste to the treatment zone a vegetative cover is established on the portion of the land treatment facility being closed when the cover will not substantially impede degradation, transformation, or immobilization of hazardous constituents. Verify that, when closure is completed, certification by an independent, qualified soil scientist or independent, registered professional engineer was submitted to the Regional Administrator that the facility has been closed according to the specifications of an approved closure plan. Verify that, during the postclosure period: operations are continued to enhance degradation, transformation, and sustain immobilization of hazardous constituents in the treatment zone 4 - 195 Hazardous Waste COMPLIANCE CATEGORY HAZARDOUS WASTE MANAGEMENT U.S. TEAM Guide REGULATORY REQUIREMENTS REVIEWER CHECKS March 2001 a vegetative cover is maintained run-on control systems are maintained runoff management systems are maintained wind dispersal of hazardous waste is controlled food chain crop prohibitions are met unsaturated zone monitoring is continued, except that soil-pore liquid monitoring may be terminated 90 days after the last application of waste to the treatment zone. (NOTE: The TSDF may not be required to establish a vegetative cover or meet post- closure requirements if the Regional Administrator finds that the level of hazardous waste constituents in the treatment soil zone does not exceed the background value of those constituents by an amount that is statistically significant.) HW.195.7.US. Hazardous wastes F020 through F023, F026, and F027 must not be placed in a land treatment facility unless it is done according to an approved management plan for these wastes (40 CFR 264.283). Verify that these wastes are only placed in a land treatment unit according to the requirements of the approved waste management plan. 4 - 196 Hazardous Waste COMPLIANCE CATEGORY HAZARDOUS WASTE MANAGEMENT U.S. TEAM Guide REGULATORY REQUIREMENTS REVIEWER CHECKS March 2001 ADDITIONAL REQUIREMENTS FOR PERMITTED TSDFs HW.200 Hazardous Waste Landfills HW.200.1.US. Permitted hazardous waste landfills are required to have a liner and a leachate collection and removal system (40 CFR 264.301(a) through 264.301(b)) [February 1995]. Determine if the TSDF disposes of hazardous wastes in an onsite landfill. Verify that the landfill liner is: designed, constructed, and installed to prevent any migration of waste out of the landfill placed on a properly supported base or foundation installed to cover all surrounding earth likely to be in contact with the waste. Verify that the leachate collection and removal system is immediately above the liner and will operate to remove leachate from the landfill. (NOTE: The permit will contain specific design and operating conditions.) Verify that collected leachate is tested to determine the correct disposal methodology. HW.200.2.US. New landfills on which construction started after 29 January 1992, lateral expansions that started construction after 29 July 1992, and each replacement of an existing land fill that will start reuse after 29 July 1992 are required to meet specific design and operating standards (40 CFR 264.19, 264.301(c) through 264.301(f), 264.302, and 264.304). Determine if the TSDF has any landfills meeting the stated criteria. Verify that the landfill has two or more liners and a leachate collection and removal system above and between the liners, or a waiver of double liner requirement has been obtained from the USEPA Regional Administrator. Verify that the TSDF has a CQA program to ensure that constructed units meet or exceed all design criteria and specifications in the permit. Verify that the designated CQA officer is a registered professional engineer. Verify that the TSDF has a written CQA plan that addresses the following: identification of applicable units and a description of how they will be constructed identification of key personnel a description of sampling and inspection activities. Verify that waste is not received in a unit until an approved CQA plan has been submitted to the Regional Administrator. Verify that the pumpable liquids in the leak detection system sumps are collected 4 - 197 Hazardous Waste COMPLIANCE CATEGORY HAZARDOUS WASTE MANAGEMENT U.S. TEAM Guide REGULATORY REQUIREMENTS REVIEWER CHECKS March 2001 and removed to minimize the head on the bottom liner. Verify that surface impoundments subject to these requirements meet the action leak age rate set by the Regional Administrator. Verify that the TSDF has an approved response action plan before the receipt of waste. Verify that, if the flow rate into the leak detection system exceeds the action leakage rate for any sump: the Regional Administrator is notified within 7 days a written notification is submitted within 14 days to the extent practicable, the location, size and cause of any leak is determined a determination is made as to whether waste receipt should be stopped or restricted the Regional Administrator is notified of actions taken and actions to be taken within 30 days after discovery a monthly report is submitted to the Regional Administrator as long as the flow rate in the leak detection systems exceeds the action leakage rate. (NOTE: These restrictions do not apply if the existing unit was constructed in accordance with the design standards of section 3004(o)(1)(A)(i) and (o)(5) of RCRA and there is no reason to believe that the liner is not functioning as designed.) HW.200.3.US. Hazardous waste landfills are required to be inspected (40 CFR 264.303). Verify that liners were inspected during construction for overall integrity. Verify that, immediately after construction was completed, the following inspections were performed: synthetic liners and covers to ensure tight seams and joints and absence of tears soil-based and admixed liners for imperfections that may increase impermeability (e.g., cracks and root-holes). Verify that, while a landfill is in operation, it is inspected weekly and after storms to detect evidence of the following: deterioration, malfunctions, or improper operations of run-on and runoff control systems proper functioning of wind dispersal control systems where present the presence of leachate in and proper functioning of the leachate collection system. Verify that the amount of liquid removed from each leak detection sump is recorded at least once a week during the active life of the landfill and closure period. 4 - 198 Hazardous Waste COMPLIANCE CATEGORY HAZARDOUS WASTE MANAGEMENT U.S. TEAM Guide REGULATORY REQUIREMENTS REVIEWER CHECKS March 2001 Verify that after a final cover is installed, the amount of liquids removed from each leak detection system sump is recorded at least monthly or: if the liquid level in the sump stays below the pump operating level for 2 consecutive months, the liquid amounts are recorded quarterly if the liquid level in the sump stays below the pump operating level for 2 consecutive quarters, the liquid amounts are recorded semi-annually. HW.200.4.US. TSDFs with permitted hazardous waste landfills are required to meet specific standards for hazardous wastes F020, F021, F022, F023, F026, and F027 (40 CFR 264.317). Determine whether or not these wastes are landfilled at the TSDF. Verify that, if they are landfilled, the TSDF has a management plan for their disposal that is approved by the Regional Administrator. 4 - 199 Hazardous Waste 4 - 200 Hazardous Waste COMPLIANCE CATEGORY HAZARDOUS WASTE MANAGEMENT U.S. TEAM Guide REGULATORY REQUIREMENTS ADDITIONAL REQUIREMENTS FOR PERMITTED TSDFs HW.205 Incinerators HW.205.1.US. TSDFs with permitted hazardous waste incinerators must comply with certain operating requirements (40 CFR 264.341. 264.342, 264.343(a), 264.344, and 264.345) [Revised April 1999]. REVIEWER CHECKS March 2001 (NOTE: After consideration of the waste analysis included in the part B permit application, the Regional Administrator, when establishing permit conditions, must exempt the applicant from all requirements in Subpart O except for 264.341 and 264.351, if one of the following is true (40 CFR 264.340(b)): the waste to be burned is listed as a hazardous waste solely because it is ignitable, corrosive, or both the waste to be burned is listed as a hazardous waste solely because it is reactive for characteristics other than those listed in 40 CFR 261.23(a)(4) and 261.23(a)(5) and will not be burned when other hazardous wastes are present in the combustion chamber the waste to be burned is a hazardous waste solely because it possesses the characteristics of ignitability, corrosivity, or both, as determined by the test for characteristic hazardous wastes the waste is a hazardous waste solely because it possesses any of the reactive characteristics described by 40 CFR 261.23(a)(1), (2), (3), (6), (7), and (8) and will not be burned when other hazardous wastes are present in the combustion chamber.) [Added April 1999]. Determine if the TSDF incinerates hazardous waste. Determine if specific wastes (principal organic hazardous constituents (POHCs)) are specified in the permit. Verify that only the wastes listed in the permit are burned, and only under the operating conditions set forth in the permit except in approved trial burns or otherwise approved exemptions Verify that sufficient waste analyses are conducted throughout normal operations to ensure that waste feed is within the limits specified in the permit. Verify that, for each waste specified in the permit, the incinerator achieves a destruction and removal efficiency (DRE) of 99.99 percent. Verify that the DRE for all wastes incinerated is determined by the following equation: (Win - Wout) DRE = --------------------- x 100 percent Win Win = mass feed rate of one POHC in the waste stream feeding the incinerator Wout = mass emissions rate of the same POHC present in the exhaust emissions.) Verify that, when USEPA hazardous waste numbers F020 through F023, F026, or 4 - 201 Hazardous Waste COMPLIANCE CATEGORY HAZARDOUS WASTE MANAGEMENT U.S. TEAM Guide REGULATORY REQUIREMENTS REVIEWER CHECKS March 2001 F027 are incinerated, a DRE of 99.9999 percent is achieved and the Regional Administrator is notified of the intent to burn. HW.205.2.US. Permitted hazardous waste incinerators are required to meet specific emission standards (40 CFR 264.343(b) and 264.343(c)). Determine if the incinerator produces stack emissions of hydrogen chloride (HCL). Verify that, if HCL emissions exceed 1.8 kg/h (4 lb/h), the emissions are controlled so the rate of emission is no greater than the larger of either 1.8 kg/h (4 lb/h) or 1 percent HCL in the stack gas prior to entering any pollution control equipment. Verify that particulate matter no greater than 180 mg/dscm is emitted. HW.205.3.US. Operators of incinerators must conduct monitoring while incinerating hazardous waste (40 CFR 264.347). Verify that the operator monitors, at a minimum, the following at the indicated intervals: waste feed rate, combustion temperature, combustion gas velocity, CO (prior to release): continuously the incinerator and associated equipment for leaks, spills, etc.: daily the emergency waste feed cutoff system and associated emergency cutoff alarms: weekly. Verify that monitoring and inspection data is recorded and the records placed in the operating log. HW.205.4.US. When permitted hazardous waste incinerators are closed, all hazardous waste and hazardous waste residues must be removed (40 CFR 264.351). Verify that all hazardous wastes and hazardous waste residues, including ash, scrubber waters, and scrubber sludges, are removed from the incinerator site. 4 - 202 Hazardous Waste COMPLIANCE CATEGORY HAZARDOUS WASTE MANAGEMENT U.S. TEAM Guide REGULATORY REQUIREMENTS ADDITIONAL REQUIREMENTS FOR PERMITTED TSDFs REVIEWER CHECKS March 2001 (NOTE: The open burning/open detonation (OB/OD) of waste explosives at permitted TSDFs is done under the classification of miscellaneous unit. This is also some times referred to as a Subpart X Permit.) HW.210 Miscellaneous Units HW.210.1.US. TSDFs that treat, store, or dispose of hazardous wastes in permitted miscellaneous units must comply with specific environmental performance standard requirements (40 CFR 264.601). Determine whether the TSDF treats, stores, or disposes of any hazardous waste in miscellaneous units. Verify that miscellaneous units are located, designed, constructed, operated, maintained, and closed in a manner that will ensure protection of human health and the environment, including: prevention of any release that may have adverse effects on human health or the environment due to migration in the surface water, wetlands, or the soil surface, taking in to consideration: volume and physical and chemical characteristics of the waste in the unit, including its potential for migration through soil, liners, or other containing structures the hydrologic and geologic characteristics of the unit and surrounding area existing quality of groundwater, including other sources of contamination and their cumulative impact on the groundwater quantity and direction of groundwater flow proximity to and withdrawal rates of current and potential groundwater users regional pattern of land use potential for deposition or migration of waste constituents into subsurface physical structures, and into the root zone of food-chain crops and other vegetation potential health risks caused by human exposure to the waste potential for damage from exposure to domestic animals, wildlife, crops, vegetation, and physical structures. prevention of any release that may have adverse affects on human health or the environment due to migration of waste constituents in the groundwater or sub surface environment, taking into consideration: volume, physical, and chemical characteristics of waste, including its potential for migration through soil, liners, or other containing structures the hydrological and geological characteristics of the unit and surrounding area existing quality of groundwater, including other sources of contamination and their cumulative impact on the groundwater the quantity and direction of groundwater flow proximity to and withdrawal rates of current and potential groundwater users 4 - 203 Hazardous Waste COMPLIANCE CATEGORY HAZARDOUS WASTE MANAGEMENT U.S. TEAM Guide REGULATORY REQUIREMENTS REVIEWER CHECKS March 2001 regional pattern of land use potential for deposition or migration of waste into subsurface physical structures, and the root zone of food-chain crops and other vegetation potential health risks caused by human exposure to the waste potential for damage from exposure to domestic animals, wildlife, crops, vegetation, and physical structures regional pattern of precipitation. Verify that miscellaneous units are designed and operated according to their permit restrictions. HW.210.2.US. TSDFs that treat, store, or dispose of hazardous wastes in permitted miscellaneous units must comply with monitoring, analysis, inspection, responses, reporting, and corrective action regulations (40 CFR 264.602). Determine if the TSDF complies with the following regulations: HW.210.3.US. A permitted miscellaneous unit that is a disposal unit must be maintained according to the permit requirements during the postclosure period (40 CFR 264.603). Determine if the TSDF has a closed miscellaneous unit. follow the general inspection requirements of 40 CFR 264.15 (see checklist item HW.145.2) test and maintain equipment in compliance with 40 CFR 264.33 (see checklist item HW.105.5) prepares a biennial report as specified in 40 CFR 264.75 (see checklist item HW.145.6) prepares unmanifested waste reports and additional reports, if applicable, as required in 40 CFR 264.76 through 264.77 (see checklist item HW.145.12) takes corrective action to prevent releases as defined in 40 CFR 264.101 (see checklist items HW.180.2 and HW.180.11). Verify that the postclosure requirements specified in the permit are being carried out. 4 - 204 Hazardous Waste COMPLIANCE CATEGORY HAZARDOUS WASTE MANAGEMENT U.S. TEAM Guide REGULATORY REQUIREMENTS REVIEWER CHECKS March 2001 ADDITIONAL REQUIREMENTS FOR INTERIM STATUS TSDFs HW.220 General HW.220.1.US. Interim status TSDFs are allowed to conduct OB/OD of waste explosives under specific conditions (40 CFR 265.382). Determine if the TSDF is conducting OB/OD activities. Verify that the OB/OD occurs at the distance from an adjoining property line indicated in the following chart: Pounds of waste explosive or propellants 0 to 100 101 to 1000 1001 to 10,000 10,000 to 30,000 Minimum distance from OB/OD activity to the property of others 204 m (670 ft) 380 m (1250 ft) 530 m (1730 ft) 690 m (2260 ft) HW.220.2.US. Checklist item deleted. [Deleted January 1999.] This checklist item was incorporated into HW.220.3 HW.220.3.US. Interim status TSDFs operating surface impoundments, landfills, or land treatment facilities are required to have a groundwater monitoring program that meets specific standards (40 CFR 265.90, 265.91) [Revised January 1999]. (NOTE: These requirements apply during the active life of the facility, and for disposal facilities, during the postclosure care period as well.) (NOTE: All or part of the groundwater monitoring requirements may be waived: if the owner/operator has demonstrated in writing that there is a low potential for migration of hazardous waste constituents from the facility via the uppermost aquifer to water supply wells or surface water for any surface impoundment that is used to neutralize wastes which are hazardous solely because they exhibit the corrosivity characteristic or are listed as hazardous wastes only for that reason and that contains no other hazardous wastes and it can be demonstrated in writing there is no potential for migration.) (NOTE: All demonstrations in writing must be kept at the facility and be certified by a qualified geologist or geotechnical engineer.) Verify that the groundwater monitoring system is capable of yielding groundwater samples for analysis and consists of: monitoring wells, at least one, installed hydraulically upgradient from the limit of the waste management area at appropriate locations and depth to yield 4 - 205 Hazardous Waste COMPLIANCE CATEGORY HAZARDOUS WASTE MANAGEMENT U.S. TEAM Guide REGULATORY REQUIREMENTS REVIEWER CHECKS March 2001 samples that are representative of background water quality in the uppermost aquifer near the facility and not affected by the facility monitoring wells, at least three, installed hydraulically downgradient at the limit of the waste management area at appropriate locations and depths to immediately detect any statistically significant amounts of hazardous waste or hazardous waste constituents that migrate from the waste management area to the uppermost aquifer an alternate hydraulically downgradient monitoring well location that has been demonstrated in writing to be sufficient. (NOTE: Separate monitoring systems are not required for each component of a facility if the upgradient and downgradient sampling will detect any discharge from the waste management area.) Verify that all monitoring wells are cased in a manner that maintains the integrity of the monitoring well bore hole. Verify that if the owner/operator uses an alternate groundwater monitoring system, the following are met: a plan is submitted to the Regional Administrator that is certified by a qualified geologist or geotechnical engineer and specifies: the number, location, and depth of wells sampling and analytical methods for those hazardous wastes or hazardous waste constituents in the facility evaluation procedures, including any use of previously gathered groundwater quality information a schedule of implementation the rate and extent of migration of the hazardous waste or constituents in the groundwater and their concentration are determined submit a report to the Regional Administrator within 15 days of the determinations containing an assessment of the groundwater quality continue to make necessary determinations quarterly until final closure keep records of analyses and evaluation throughout the active life of the facility, and for disposal facilities, throughout the postclosure period submit an annual report to the Regional Administrator with the results of the groundwater quality assessment program. HW.220.4.US. Interim status TSDFs must gather and analyze samples from the groundwater monitoring system according to specific parameters (40 CFR 265.90(a) through 265.90(c), 265.90(e), 265.92) [Revised January (NOTE: These requirements apply during the active life of the facility, and for disposal facilities, during the postclosure care period as well.) (NOTE: All or part of the groundwater monitoring requirements may be waived: if the owner/operator has demonstrated in writing that there is a low potential for migration of hazardous waste constituents from the facility via the uppermost aquifer to water supply wells or surface water for any surface impoundment that is used to neutralize wastes that are hazardous solely because they exhibit the corrosivity characteristic or are 4 - 206 Hazardous Waste COMPLIANCE CATEGORY HAZARDOUS WASTE MANAGEMENT U.S. TEAM Guide REGULATORY REQUIREMENTS 1999]. REVIEWER CHECKS March 2001 listed as hazardous wastes only for that reason and contain no other hazardous wastes and it can be demonstrated in writing there is no potential for migration.) (NOTE: All demonstrations in writing must be kept at the facility and be certified by a qualified geologist or geotechnical engineer.) Verify that the groundwater sampling and analysis plan includes procedures and techniques for the following: sample collection sample preservation and shipment analytical procedures chain of custody control. Verify that the concentrations and/or values are determined for the following parameters and samples collected as indicated: parameters characterizing the suitability of groundwater as drinking water as found in Appendix III of 40 CFR 265 (see Appendix 4-13) parameters establishing groundwater quality: chloride, iron, manganese, phenols, sodium, sulfate parameters used as indicators of groundwater contamination: pH, specific conductance, total organic carbon, total organic halogen. Verify that the TSDF established initial background concentrations for all parameters quarterly for 1 yr. Verify that parameters used as indicators of groundwater contamination are sampled with at least four replicate measurements obtained for each sample and the initial background arithmetic mean and variance are determined by pooling the replicate measurements for the respective parameter concentration or values in samples obtained from upgradient wells during the first year. Verify that, after the first year, the following frequencies are met: parameters establishing groundwater quality: annually parameters used as indicators of groundwater contamination: semiannually. Verify that the elevation of the groundwater surface at each monitoring well is determined each time a sample is obtained. HW.220.5.US. Interim status TSDFs must have an outline of a more extensive groundwater quality assessment program and implement that program (NOTE: These requirements apply during the active life of the facility, and for disposal facilities, during the postclosure care period as well.) (NOTE: All or part of the groundwater monitoring requirements may be waived: if the owner/operator has demonstrated in writing that there is a low potential for migration of hazardous waste constituents from the facility via the 4 - 207 Hazardous Waste COMPLIANCE CATEGORY HAZARDOUS WASTE MANAGEMENT U.S. TEAM Guide REGULATORY REQUIREMENTS according to specific parameters when contamination is detected (40 CFR 265.90(a) through 265.90(c), 265.90(e), 265.93(a)) [Revised January 1999]. REVIEWER CHECKS March 2001 uppermost aquifer to water supply wells or surface water for any surface impoundment that is used to neutralize wastes that are hazardous solely because they exhibit the corrosivity characteristic or are listed as hazardous wastes only for that reason and contains no other hazardous wastes and it can be demonstrated in writing that there is no potential for migration.) (NOTE: All demonstrations in writing must be kept at the facility and be certified by a qualified geologist or geotechnical engineer.) Determine if a groundwater quality assessment program outline has been developed. Verify that the program outline describes a more comprehensive program capable of determining: whether hazardous waste or hazardous waste constituents have entered the groundwater the rate and extent of migration of hazardous waste or hazardous waste constituents in the groundwater the concentrations of hazardous waste or hazardous waste constituents in the groundwater. Verify that, for indicator parameters (pH, specific conductance, total organic carbon, total organic halogen): the arithmetic mean and variance, based on at least four replicate measurements on each sample, for each well monitored for indicator parameters semiannually results of calculations are compared with the initial background arithmetic mean. Verify that, if the comparisons for the indicator parameters from upgradient wells show a significant increase (or pH decrease), this is included in the annual report to the Regional Administrator. Verify that, if the comparisons for the indicator parameters from downgradient wells show a significant increase (or pH decrease), additional groundwater samples are immediately taken from those downgradient wells where a significant difference was detected, split the samples in two, and determine if there was laboratory error. Verify that, if the cross check confirms a significant increase (or pH decrease) in a downgradient well: a written notice is provided to the Regional Administrator within 7 days of confirmation that the facility may be affecting groundwater quality submit a plan based on the groundwater quality assessment program outline to 4 - 208 Hazardous Waste COMPLIANCE CATEGORY HAZARDOUS WASTE MANAGEMENT U.S. TEAM Guide REGULATORY REQUIREMENTS REVIEWER CHECKS March 2001 the Regional Administrator within 15 days after the notification. Verify that the plan is certified by a qualified geologist or geotechnical engineer and specifies: number, location, and depth of wells sampling and analytical methods for the wastes and constituents in the facility evaluation procedures, including any use of previously gathered groundwater quality data a schedule of implementation. Verify that the plan is implemented with the first determinations being made as soon as technically feasible. Verify that within 15 days after the first determinations, a written report is submitted to the Regional Administrator containing an assessment of the groundwater quality. (NOTE: When it is determined there is no contamination, the original indicator evaluation program may be resumed.) HW.220.6.US. Checklist item deleted. [Deleted January 1999]. This checklist item was incorporated into HW.220.5. HW.220.7.US. Checklist item deleted. [Deleted January 1999]. This checklist item was incorporated into HW.220.5. HW.220.8.US. The interim status TSDF is required to meet specific reporting and recordkeeping requirements except when the groundwater is being monitored to satisfy a groundwater assessment program resulting from downgradient well contamination (40 CFR 265.90(a) through 265.90(c), 265.90(e), and 265.94(a)) [Revised January 1999]. (NOTE: These requirements apply during the active life of the facility, and for disposal facilities, during the postclosure care period as well.) (NOTE: All or part of the groundwater monitoring requirements may be waived: if the owner/operator has demonstrated in writing that there is a low potential for migration of hazardous waste constituents from the facility via the uppermost aquifer to water supply wells or surface water for any surface impoundment that is used to neutralize wastes that are hazardous solely because they exhibit the corrosivity characteristic or are listed as hazardous wastes only for that reason and contain no other hazardous wastes and it can be demonstrated in writing there is no potential for migration.) (NOTE: All demonstrations in writing must be kept at the facility and be certified 4 - 209 Hazardous Waste COMPLIANCE CATEGORY HAZARDOUS WASTE MANAGEMENT U.S. TEAM Guide REGULATORY REQUIREMENTS REVIEWER CHECKS March 2001 by a qualified geologist or geotechnical engineer.) Verify that records of initial background concentrations, ongoing analyses, and groundwater elevations are kept throughout the life of the site, and for disposal facilities through postclosure. Verify that, during the first year of groundwater monitoring, the results of parameter monitoring are submitted to the Regional Administrator within 15 days after completing each quarterly analysis. Verify that, after the first year, concentrations and values for monitored parameters are reported annually to the Regional Administrator by 1 March of each calendar year. HW.220.9.US. When the groundwater is being monitored to satisfy a groundwater assessment program resulting from downgradient well contamination, specific records have to be maintained and reports submitted (40 CFR 265.90(a) through 265.90(c), 265.90(e), and 265.94(b)) [Revised January 1999]. (NOTE: These requirements apply during the active life of the facility, and for disposal facilities, during the postclosure care period as well.) (NOTE: All or part of the groundwater monitoring requirements may be waived: if the owner/operator has demonstrated in writing that there is a low potential for migration of hazardous waste constituents from the facility via the uppermost aquifer to water supply wells or surface water for any surface impoundment that is used to neutralize wastes that are hazardous solely because they exhibit the corrosivity characteristic or are listed as hazardous wastes only for that reason and contain no other hazardous wastes and it can be demonstrated in writing that there is no potential for migration.) (NOTE: All demonstrations in writing must be kept at the facility and be certified by a qualified geologist or geotechnical engineer.) Verify that records of analyses and evaluations specified in the plan are maintained throughout the active life of the site, and for disposal facilities throughout postclosure. Verify that the results of the program are submitted annually to the Regional Administrator by 1 March of each calendar year. 4 - 210 Hazardous Waste COMPLIANCE CATEGORY HAZARDOUS WASTE MANAGEMENT U.S. TEAM Guide REGULATORY REQUIREMENTS REVIEWER CHECKS March 2001 ADDITIONAL REQUIREMENTS FOR INTERIM STATUS TSDFs HW.225 Surface Impoundments HW.225.1.US. New surface impoundments that started construction after 29 January 1992, lateral expansions of surface impoundments that started construction after 29 July 1992, and replacements of existing surface impoundments for which reuse started after 29 July 1992 are required to meet specific design and operating criteria (40 CFR 265.19, 265.221(a) through 265.221(e), 265.221(h), 265.222, and 265.223). Verify that the listed surface impoundments have two liners and a leachate collection and removal system between the liners unless a waiver has been granted by the Regional Administrator. Verify that the TSDF has a CQA program to ensure that constructed units meet or exceed all design criteria and specifications in the permit. Verify that the designated CQA officer is a registered professional engineer. Verify that the TSDF has a written CQA plan that addresses the following: identification of applicable units and a description of how they will be constructed identification of key personnel a description of sampling and inspection activities. Verify that waste is not received in a unit until an approved CQA plan has been submitted to the Regional Administrator. Verify that the Regional Administrator is notified 60 days prior to the receipt of wastes. Verify that a TSDF submitting notice files a Part B application within 6 mo of the receipt of notice. Verify that the TSDF is complying with the action leakage rate established by the Regional Administrator and if the rate is exceeded by flow into any sump: the Regional Administrator is notified within 7 days a written notification is submitted within 14 days the location, size, and cause of any leak is determined to the extent practicable a determination is made as to whether waste receipt should be stopped or restricted the Regional Administrator is notified of actions taken and actions to be taken within 30 days after discovery of a leak a monthly report is submitted to the Regional Administrator as long as the flow rate in the leak detection system exceeds the action leakage rate. Verify that the TSDF has an approved response action plan. 4 - 211 Hazardous Waste COMPLIANCE CATEGORY HAZARDOUS WASTE MANAGEMENT U.S. TEAM Guide REGULATORY REQUIREMENTS REVIEWER CHECKS March 2001 (NOTE: As of 18 February 1993, surface impoundments that are newly subject to hazardous waste requirements because of new additions or characteristics for the identification of hazardous waste are required to meet the standards outlined above concerning having two or more liners and a leachate collection system within 1 mo after promulgation of the additional listing of a characteristic waste.) HW.225.2.US. Interim status surface impoundments are required to meet specific operating and containment standards (40 CFR 265.221(f), 265.221(g), 265.223, and 265.226). Verify that there is enough freeboard to prevent any overtopping of the dike by over filling, wave actions, or a storm. Verify that there is a freeboard of 60 cm (2 ft) unless written certification states that a lesser freeboard is acceptable. Verify that all earthen dikes have a protective cover such as grass, shale, or rock to minimize wind and water erosion and preserve integrity. Verify that the freeboard is inspected at least once each day. Verify that the surface impoundment is inspected at least once a week for signs of deterioration, leaks, or failure. Verify that the amount of liquids removed from each leak detection system sump is recorded at least: once a week during the active life and closure period monthly after the final cover is installed or: if the liquid level in the sump stays below the pump operating level of 2 consecutive months, quarterly if the liquid level in the sump stays below the pump operating level for 2 consecutive quarters, semi-annually. HW.225.3.US. In specific circumstances additional waste analyses must be done (40 CFR 265.225). Verify that additional waste analyses are done whenever one of the following situations exists: HW.225.4.US. Specific procedures must be followed during the closure and postclosure periods for an interim status surface impoundment (40 CFR Verify that at closure all waste residues, contaminated containment system components, contaminated subsoils, and structures and equipment contaminated with waste and leachate are removed or decontaminated. the surface impoundment is used to treat a substantially different hazardous waste from what was previously treated a substantially different process is used to treat the waste. Verify that postclosure care includes care equivalent to that for interim status land fills and 40 CFR 265.310, including: 4 - 212 Hazardous Waste COMPLIANCE CATEGORY HAZARDOUS WASTE MANAGEMENT U.S. TEAM Guide REGULATORY REQUIREMENTS 265.228). REVIEWER CHECKS March 2001 elimination of free liquids stabilization of wastes to a bearing capacity sufficient to support the final cover covering of surface impoundment. Verify that if wastes, waste residues, or contaminated materials remain after closure: the integrity of the final cover is maintained a groundwater monitoring system is maintained that meets the requirements of 40 CFR 265.90 through 265.94 (see checklist item HW.220.2 through HW.220.9) run-on and runoff are prevented from damaging or eroding the final cover maintenance and monitoring of leak detection system. HW.225.5.US. Checklist item deleted [December 1996]. 4 - 213 Hazardous Waste 4 - 214 Hazardous Waste COMPLIANCE CATEGORY HAZARDOUS WASTE MANAGEMENT U.S. TEAM Guide REGULATORY REQUIREMENTS REVIEWER CHECKS March 2001 ADDITIONAL REQUIREMENTS FOR INTERIM STATUS TSDFs HW.230 Waste Piles HW.230.1.US. Interim status waste piles are required to meet specific standards for wind protection, waste analysis, and containment (40 CFR 265.250, 265.251, and 265.253). Determine if the TSDF operates an interim status waste pile. Verify that interim status waste piles are covered or otherwise managed to prevent dispersal of the pile contents by the wind. Verify that, if the leachate or runoff from a pile is a hazardous waste, one of the following is done: Option one: place the pile on an impermeable base that is compatible with the waste design, construct, operate, and maintain a run-on control system capable of preventing flow onto the active portion of the pile during peak discharge from at least a 25-yr storm design, construct, operate, and maintain a runoff management system to collect and control at least the water volume resulting from a 24-h, 25yr storm empty and manage collection and holding facilities for the run-on and runoff systems Option two protect the pile from precipitation and run-on no liquids or wastes containing liquids are placed in the pile. HW.230.2.US. New interim status piles that started construction after 29 January 1992, lateral expansions of a waste pile unit which started after 29 July 1992, and each such replacement of an existing waste pile unit for which reuse started after 29 July 1992 must meet specific design and operating standards (40 CFR 265.19, 265.254, 265.255, 265.259, and 265.260). Determine if the TSDF operates interim status waste piles meeting the listed description. Verify that the waste pile has two or more liners and a leachate collection and removal system. Verify that the TSDF has a CQA program to ensure that constructed units meet or exceed all design criteria and specifications in the permit. Verify that the designated CQA officer is a registered professional engineer. Verify that the TSDF has a written CQA plan that addresses the following: identification of applicable units and a description of how they will be constructed identification of key personnel a description of sampling and inspection activities. 4 - 215 Hazardous Waste COMPLIANCE CATEGORY HAZARDOUS WASTE MANAGEMENT U.S. TEAM Guide REGULATORY REQUIREMENTS REVIEWER CHECKS March 2001 Verify that waste is not received in a unit until an approved CQA plan has been submitted to the Regional Administrator. Verify that waste piles subject to these requirements meet the action leakage rate set by the Regional Administrator. Verify that the TSDF has an approved response action plan before the receipt of waste. Verify that, if the flow rate into the leak detection system exceeds the action leakage rate for any sump: the Regional Administrator is notified within 7 days a written notification is submitted within 14 days the location, size, and cause of any leak is determined to the extent practicable a determination is made as to whether waste receipt should be stopped or restricted the Regional Administrator is notified of actions taken and actions to be taken within 30 days after discovery of a leak a monthly report is submitted to the Regional Administrator as long as the flow rate in the leak detection system exceeds the action leakage rate. Verify that the amount of liquids removed from each leak detection sump is recorded at least once a week during the active life and closure period. HW.230.3.US. Except in specific instances, TSDFs are required to analyze a representative sample from each incoming waste before adding the waste to an existing pile (40 CFR 265.252). Verify that an analysis is performed unless one of the following occurs: HW.230.4.US. Interim status waste piles must meet specific closure and post closure requirements (40 CFR 265.258). Verify that, at closure, all waste residues, contaminated containment system components, contaminated subsoils, and structures and equipment contaminated with waste and leachate are removed or decontaminated. the only wastes that the TSDF receives for piling are compatible the waste received is compatible with the pile in which it is to be placed. Verify that, if all residues cannot be removed, the waste pile is closed and postclosure care is carried out as for a landfill. 4 - 216 Hazardous Waste COMPLIANCE CATEGORY HAZARDOUS WASTE MANAGEMENT U.S. TEAM Guide REGULATORY REQUIREMENTS REVIEWER CHECKS March 2001 ADDITIONAL REQUIREMENTS FOR INTERIM STATUS TSDFs HW.235 Land Treatment Units HW.235.1.US. Interim status land treatment units are required to be operated according to specific standards (40 CFR 265.270, 265.272, 265.273, and 265.279) Determine if the TSDF operates an interim status land treatment unit. Verify that the following standards are met at the land treatment unit: hazardous wastes are not placed in or on a land treatment facility unless it can be made less hazardous or nonhazardous by degradation, transformation, or immobilization processes occurring in or on the soil run-on control systems are operated to prevent flow onto the treatment zone during peak discharge from at least a 25-yr storm runoff management systems are capable of controlling and collecting a water volume at least equivalent to a 24-h, 25-yr storm tanks and basins associated with the run-on and runoff control systems are emptied or otherwise managed after storms wind dispersal is controlled. Verify that, in addition to required waste analysis, prior to placing a hazardous waste in or on a land treatment facility the owner or operator: determines the concentrations in the waste of any substance that equaled or exceeded the maximum concentrations contained in Table 1 of 264.24 determines the concentration of any substance that caused the waste to be listed as hazardous determines the concentrations of arsenic, cadmium, lead, and mercury if food chain crops are grown unless there is documentation present to prove that none of these constituents exist Verify that hazardous waste application dates and rates are included in the operating record. HW.235.2.US. TSDFs are required to operate interim status land treatment facilities where food-chain crops are grown according to specific standards (40 CFR 265.276). Determine if the TSDF grows food-chain crops on their land treatment facilities. Verify that the TSDF notified the Regional Administrator that food-chain crops were being grown. Verify that food-chain crops are not grown on the land treatment facility unless there is proof that the crop will not be contaminated by arsenic, lead, mercury, or other harmful constituents. 4 - 217 Hazardous Waste COMPLIANCE CATEGORY HAZARDOUS WASTE MANAGEMENT U.S. TEAM Guide REGULATORY REQUIREMENTS REVIEWER CHECKS March 2001 Verify that if the TSDF accepts waste is contaminated with cadmium, the handling practices outlined in 40 CFR 265.276(c) are followed. HW.235.3.US. TSDFs with interim status land treatment facilities are required to have an unsaturated zone monitoring plan (40 CFR 265.278). Verify that the TSDF has an unsaturated zone monitoring plan which includes: soil monitoring using soil cores soil-pore water monitoring using devices such as lysimeters depth and number of samples to be taken. Verify that the TSDF is following the plan. HW.235.4.US. TSDFs with interim status land treatment facilities are required to meet specific requirements concerning closure and postclosure (40 CFR 265.280). Verify that, in the closure plan, the TSDF has addressed the following issues for interim status land treatment facilities: control of migration of wastes control of the release of contaminated runoff into surface water control of the release of airborne particulates compliance with food-chain crop restrictions. Verify that during closure: unsaturated zone monitoring is continued the run-on control system is maintained the runoff management system is maintained there is continued control of wind dispersal of particulate matter. Verify that, when closure was completed, the TSDF notified the Regional Administrator. Verify that during postclosure the following is done: soil-core monitoring is continued as specified in the postclosure plan access to the unit is restricted as appropriate growth of food-chain crops complies with restrictions wind dispersal of hazardous wastes is controlled. 4 - 218 Hazardous Waste COMPLIANCE CATEGORY HAZARDOUS WASTE MANAGEMENT U.S. TEAM Guide REGULATORY REQUIREMENTS REVIEWER CHECKS March 2001 ADDITIONAL REQUIREMENTS FOR INTERIM STATUS TSDFs HW.240 Hazardous Waste Landfills HW.240.1.US. New interim status landfill units that started construction after 29 January 1992, each lateral expansion of a land fill unit that started construction after 29 July 1992, and each replacement of an existing land fill that will begin reuse after 29 July 1992 is required to meet specific design and operating standards (40 CFR 265.19, 265.301(a) through 265.301(e) and 265.302 through 265.304). Determine if the TSDF has any interim status landfills meeting the stated criteria. Verify that the landfill has two or more liners and a leachate collection system above and between the liners or a waiver of the double liner requirement has been obtained from the USEPA Regional Administrator. Verify that the TSDF has a CQA program to ensure that constructed units meet or exceed all design criteria and specifications in the permit. Verify that the designated CQA officer is a registered professional engineer. Verify that the TSDF has a written CQA plan that addresses the following: identification of applicable units and a description of how they will be constructed identification of key personnel a description of sampling and inspection activities. Verify that waste is not received in a unit until an approved CQA plan has been submitted to the Regional Administrator. Verify that the TSDF notifies the Regional Administrator at least 60 days prior to receiving waste and files a Part B application within 6 mo of the receipt of notice. Verify that landfills subject to these requirements meet the action leakage rate set by the Regional Administrator. Verify that the TSDF has an approved response action plan before the receipt of waste. Verify that, if the flow rate into the leak detection system exceeds the action leakage rate for any sump: the Regional Administrator is notified within 7 days a written notification is submitted within 14 days to the extent practicable, the location, size and cause of any leak is determined a determination is made as to whether waste receipt should be stopped or restricted the Regional Administrator is notified of actions taken and actions to be taken within 30 days after discovery 4 - 219 Hazardous Waste COMPLIANCE CATEGORY HAZARDOUS WASTE MANAGEMENT U.S. TEAM Guide REGULATORY REQUIREMENTS REVIEWER CHECKS March 2001 a monthly report is submitted to the Regional Administrator as long as the flow rate in the leak detection systems exceeds the action leakage rate. Verify that, after a final cover is installed, the amount of liquids removed from each leak detection system sump is recorded at least monthly or: if the liquid level in the sump stays below the pump operating level for 2 consecutive months, quarterly if the liquid level in the sump stays below the pump operating level for 2 consecutive quarters, semiannually. 4 - 220 Hazardous Waste COMPLIANCE CATEGORY HAZARDOUS WASTE MANAGEMENT U.S. TEAM Guide REGULATORY REQUIREMENTS REVIEWER CHECKS March 2001 ADDITIONAL REQUIREMENTS FOR INTERIM STATUS TSDFs HW.245 Incinerators HW.245.1.US. TSDFs with interim status that use incinerators for hazardous waste must sufficiently analyze all wastes burned (40 CFR 265.340 and 265.341). Determine if the TSDF incinerates hazardous wastes. Determine if the results of each waste analysis are kept on file in the operating record. Verify that, for each waste not previously burned at the site, the results of the waste analysis establish: steady state (normal) operating conditions including: waste fuel feed auxiliary fuel feed air flow type of pollutants that might be emitted heating value halogen content sulfur content lead concentration level mercury concentration level. (NOTE: TSDFs with interim status may be exempt from all the requirements for hazardous waste incinerators (except closure) under certain conditions: the TSDF has written documentation that the wastes they incinerate do not contain any hazardous constituents listed in Appendix 4-4 the documentation is retained at the TSDF the wastes are listed as hazardous solely because of their ignitable (Hazard Code I) or corrosive (Hazard Code C) properties, or both, as listed and deter mined in 40 CFR 261, part C or D the wastes are listed as reactive (Hazard Code R) for characteristics other than those listed in 40 CFR 261.23(a)(1),(2), (3), (6), (7), or (8) and will not be burned when other hazardous wastes are present in the combustion zone the wastes are hazardous wastes solely because they possesses the characteristic of ignitibility, corrosivity or both, as determined by the tests for characteristics of hazardous waste the wastes are hazardous wastes solely because they posses the reactivity characteristics described in 261.23(a)(1), (2), (3), (6), (7), (8) and will not be burned when other hazardous wastes are present in the combustion zone.) 4 - 221 Hazardous Waste COMPLIANCE CATEGORY HAZARDOUS WASTE MANAGEMENT U.S. TEAM Guide REGULATORY REQUIREMENTS REVIEWER CHECKS March 2001 HW.245.2.US. TSDFs with interim status may burn F020 through F023, F026, or F027 if they have proper certification (40 CFR 265.352). Determine if the TSDF burns USEPA hazardous waste numbers F020 through F023, F026, or F027. HW.245.3.US. TSDFs with interim status that incinerate hazardous waste must not feed hazardous waste unless the incinerator is at a steady state (40 CFR 265.345). Verify that the waste is not fed until steady state conditions are reached by observing the incinerator during startup and shutdown. HW.245.4.US. An interim status TSDF that incinerates hazardous waste must conduct monitoring and inspections (40 CFR 265.347). Verify that the following monitoring and inspection procedures are followed: HW.245.5.US. At closure of an interim status incinerator, all hazardous waste and hazardous waste residues must be removed (40 CFR 265.351). Verify that, when an interim status hazardous waste incinerator is closed, the wastes and residues are removed. Verify that the TSDF has received certification from the Assistant Administrator for Solid Waste and Emergency Response if such wastes are burned at the site. existing instruments related to combustion and emission are monitored every 15 min, with appropriate adjustments made to maintain steady state combustion, including the instruments that control: waste feed auxiliary fuel feed air flow incinerator temperature scrubber flow scrubber pH relevant level controls the complete incinerator and associated equipment are monitored at least daily for leaks, spills, and fugitive emissions, including: pumps valves conveyors pipes emergency shutdown controls system alarms. 4 - 222 Hazardous Waste COMPLIANCE CATEGORY HAZARDOUS WASTE MANAGEMENT U.S. TEAM Guide REGULATORY REQUIREMENTS REVIEWER CHECKS March 2001 ADDITIONAL REQUIREMENTS FOR INTERIM STATUS TSDFs HW.250 Thermal Treatment HW.250.1.US. TSDFs with interim status thermal treatment facilities must meet specific requirements (40 CFR 265.370, 265.373, 265.375, 265.381, and 265.382). Determine if the TSDF operates an interim status thermal treatment facility (other than enclosed devices using controlled flame combustion). Verify that the following requirements are met: the thermal treatment process is operating at steady state (normal) conditions, including temperature, before adding hazardous waste (unless the process is a noncontinuous [batch] process that requires a complete thermal cycle to treat the waste) waste analysis is performed on waste not previously treated at the thermal treatment facility that includes: establishing steady state (normal) operating condition type of pollutants that might be emitted heating value halogen and sulfur content concentrations of lead and mercury. (NOTE: The open burning of hazardous waste is prohibited except for the open burning and detonation of waste explosives.) Verify that, if open burning or detonation of waste explosives is conducted, the following standards are met: pounds of waste explosives or propellants determines the minimum distance from open burning or detonation to property of others as shown below: 0-100: 204 m (670 ft) 101-1000: 380 m (1250 ft) 1001-10,000: 530 m (1730 ft) 10,001-30,000: 690 m (2260 ft). Verify that at closure all wastes and residues are removed. HW.250.2.US. Interim status thermal treatment facilities must be certified if they treat certain wastes (40 CFR 265.383). Determine if the TSDF thermally treats USEPA waste numbers F020 through F023, F026, or F027. Verify that the TSDF has received certification from the Assistant Administrator for Solid Waste and Emergency Response to burn such wastes. 4 - 223 Hazardous Waste COMPLIANCE CATEGORY HAZARDOUS WASTE MANAGEMENT U.S. TEAM Guide REGULATORY REQUIREMENTS REVIEWER CHECKS March 2001 HW.250.3.US. Operators of interim status thermal treatment facilities must conduct monitoring and inspections while thermally treating hazardous waste (40 CFR 265.377). Determine if the operator conducts, at a minimum, the following monitoring while thermally treating hazardous wastes: every 15 min, the following instrumentation for temperature and emission controls are monitored and appropriate corrections are made immediately: waste feed rate auxiliary fuel rate treatment process temperature relevant process flow and level controls every hour, stack emissions are visually checked for normal appearance (color and opacity) with immediate correction if needed every day, the complete thermal treatment process and associated equipment are checked including: pumps, valves, conveyors, pipes, etc. inspected for leaks, spills, and fugitive emissions emergency shutdown controls and systems alarms are checked for proper operation. 4 - 224 Hazardous Waste COMPLIANCE CATEGORY HAZARDOUS WASTE MANAGEMENT U.S. TEAM Guide REGULATORY REQUIREMENTS REVIEWER CHECKS March 2001 ADDITIONAL REQUIREMENTS FOR INTERIM STATUS TSDFs HW.255 Chemical/Physical/ Biological Treatment HW.255.1.US. TSDFs with interim status chemical, physical, and biological treatment facilities must meet certain requirements (40 CFR 265.400 through 265.402 and 265.404). Determine if the TSDF operates a chemical, physical, or biological treatment facility to treat hazardous wastes. (NOTE: These requirements apply to TSDFs that treat hazardous wastes by chemical, physical, or biological methods in other than tanks, surface impoundments, and land treatment units.) Verify that the following criteria are met: wastes or treatment reagents are not placed in treatment process or equipment if they could cause ruptures, leaks, corrosion, or other failures continuously fed systems are equipped with waste feed cutoff or bypass system waste analyses and treatment tests (e.g., bench scale or pilot plant tests) are performed, or written, documented information is obtained whenever a substantially different waste is treated or a substantially different treatment process is used. Verify that at closure all wastes and residues are removed. HW.255.2.US. TSDFs with chemical, physical, and biological treatment facilities must conduct regular inspections (40 CFR 265.403). Determine if the chemical, physical, and biological treatment facility is inspected in accordance with the following: HW.255.3.US. TSDFs with interim status may not place ignitable, reactive, or incompatible waste in a Determine whether the TSDF treats any of these wastes. at least daily, discharge control and safety equipment (e.g., waste feed cutoff system, bypass system, drainage systems, and pressure relief systems) to ensure good working order at least daily, data from monitoring equipment is checked to ensure process is operated in accordance with its design at least weekly, construction materials of the treatment process or equipment is inspected to detect corrosion, leaks, etc. at least weekly, construction materials of and the area surrounding dikes or other discharge confinement structures are inspected to detect erosion or signs of leakage (dead vegetation, wet spots, etc.). Verify that any ignitable or reactive waste is treated or mixed in such a way before or immediately after placement in the treatment process so that the resultant 4 - 225 Hazardous Waste COMPLIANCE CATEGORY HAZARDOUS WASTE MANAGEMENT U.S. TEAM Guide REGULATORY REQUIREMENTS REVIEWER CHECKS March 2001 treatment process or equipment unless certain requirements are met (40 CFR 265.405 through 265.406). material no longer meets the definition for ignitable or reactive wastes or is treated in such a way that it is not exposed to conditions that may cause it to react or ignite. Verify that incompatible wastes are not placed in the same treatment process, equipment, or in unwashed equipment that previously held an incompatible waste. 4 - 226 Hazardous Waste COMPLIANCE CATEGORY HAZARDOUS WASTE MANAGEMENT U.S. TEAM Guide REGULATORY REQUIREMENTS REVIEWER CHECKS March 2001 HW.265 EXPORT/IMPORT OF HAZARDOUS WASTE HW.265.1.US. Exporters of hazardous waste outside the United States must comply with specific notification requirements (40 CFR 262.53(a) and 262.53(b)). Verify that 60 days prior to the initial shipment of hazardous waste to each country in each calendar year, the exporter has notified the USEPA (in writing) of the following: HW.265.2.US. When shipping hazardous waste out side the United States, an USEPA acknowledgment of consent is required that confirms the consent of the foreign country to receive the waste (40 CFR 262.52(c) and 262.53(f)). Verify that a copy of the USEPA acknowledgment of consent is on file by checking the records. HW.265.3.US. Primary exporters of hazardous waste must require confirmation of the delivery of the hazardous waste and a description of any significant discrepancies (40 Verify that the facility has been receiving confirmation of delivery by reviewing the manifest files. name, mailing address, telephone number, and USEPA identification number of the primary exporter by consignee, for each hazardous waste type: identification of the hazardous waste shipped by USEPA identification number DOT shipping name, hazard class, and identification number for the waste estimated frequency/rate at which such waste(s) is to be exported estimated total quantity (in units) all points of entry to and departure from each foreign country the waste will pass through a description of the approximate length of time the waste will remain in each country, and how it will be handled there the mode of transportation used to transport the waste type(s) of containers used description of the treatment, storage, or disposal method to be used in the receiving country name and address of the foreign consignee. Determine if there are any notations of discrepancies. 4 - 227 Hazardous Waste COMPLIANCE CATEGORY HAZARDOUS WASTE MANAGEMENT U.S. TEAM Guide REGULATORY REQUIREMENTS REVIEWER CHECKS March 2001 CFR 262.54(f)). HW.265.4.US. Primary exporters of hazardous waste outside the United States are required to use manifests with special additions (40 CFR 262.54(a) through 262.54(e) and 262.54(i)). Verify that the manifest copies comply with the general manifest requirements of 40 CFR 262.20 through 262.23. Determine if the following exceptions and additions are noted by reviewing the manifest copies: the name and address of the foreign consignee is put in the place of the designated facility's name, address, and USEPA number the point of departure through which the waste must travel in the United States before entering the foreign country is indicated this statement "and conform to the terms of the attached USEPA Acknowledgment of Consent" is added to the end of the first sentence of the certification in Item 16. Verify that a copy of the manifest is provided for delivery to the U.S. Customs official at the U.S. point of departure. (NOTE: The primary exporter's state may require the use of its manifest.) HW.265.5.US. Primary exporters of hazardous waste outside the United States are required to file an exception report under certain conditions (40 CFR 262.55). Verify that an exception report was filed if: HW.265.6.US. Primary exporters of hazardous waste are required to follow specific procedures when a shipment cannot be delivered to the designated or alternate consignee (40 CFR 262.54(g)). Verify that, when a shipment cannot be delivered, the exporter does one of the following: a signed copy of the manifest from the transporter containing the following information was not received within 45 days from the day it was accepted by the initial transporter: date of departure of the waste from the United States place of departure of the waste from the United States within 90 days from the date the waste was accepted by the initial transporter, the exporter has not received a written confirmation from the foreign consignee stating that the hazardous waste was received the waste is returned to the United States. renotifies the USEPA of a change in the conditions of the original notification to allow shipment to a new consignee and obtains an USEPA Acknowledgment of Consent prior to delivery instructs the transporter to return the waste to the primary exporter in the United States or designates another facility within the United States. Verify that the exporter instructs the transporter to revise the manifest to reflect 4 - 228 Hazardous Waste COMPLIANCE CATEGORY HAZARDOUS WASTE MANAGEMENT U.S. TEAM Guide REGULATORY REQUIREMENTS REVIEWER CHECKS March 2001 changes made. HW.265.7.US. An annual report must be filed with the Regional Administrator by 1 March of each year by the primary exporter (40 CFR 262.56). Verify that an annual report has been submitted by 1 March of every calendar year by checking the records. Determine if the annual reports contain the following information for all hazardous waste exported during the previous calendar year by checking a random sample: USEPA identification number, name, and mailing and site address for each exporter calendar year covered by the report the name and site address of each consignee by consignee, for each hazardous waste exported: a description of the hazardous waste the USEPA hazardous waste number the DOT hazard class the name and USEPA identification number for each transporter used total amount of waste number of shipment for each notice a certification signed by the primary exporter that states: "I certify under penalty of law that I have personally examined and am familiar with the information submitted in this and all attached documents, and that, based on my inquiry of those individuals immediately responsible for obtaining the information, I believe that the submitted information is true, accurate, and complete. I am aware that there are significant penalties for submitting false information including the possibility of fine and imprisonment." Verify that in even number years the reports, except those for SQGs, contains efforts used to reduce the volume and toxicity of the waste (and the changes achieved during the year in comparison to previous years). HW.265.8.US. Primary exporters of hazardous wastes must maintain additional records that relate to their export activities (40 CFR 262.57). Verify that copies of the following are kept for at least 3 yr: notification of intent to export USEPA Acknowledgment of Consent confirmation of delivery (signed manifests) of the waste annual reports. (NOTE: Periods of retention are automatically extended during the course of any unresolved enforcement action or as requested by the USEPA administrator.) 4 - 229 Hazardous Waste COMPLIANCE CATEGORY HAZARDOUS WASTE MANAGEMENT U.S. TEAM Guide REGULATORY REQUIREMENTS REVIEWER CHECKS March 2001 HW.270 HAZARDOUS WASTE ON PUBLIC VESSELS HW.270.1.US. Public vessels are required to comply with the regulations for the storing, manifesting, inspecting, and recordkeeping of hazardous waste under specific circumstances (FFCA, Section 106). Verify that the standards outlined in checklist items HW.1.1 through HW.265.8 are adhered to if either of the following occurs: the waste is stored on the public vessel for more than 90 days after the public vessel is placed in reserve or is otherwise no longer in service the waste is transferred to another public vessel within the territorial waters of the United States and is stored on the vessel or another public vessel for more than 90 days after the date of transfer. (NOTE: The 90-day period begins the earlier of the following: the date when the public vessel on which the waste was generated was placed in reserve or was otherwise no longer in service the date when the waste was transferred from the public vessel on which the waste was generated, to another public vessel within the territorial waters of the United States.) 4 - 230 Hazardous Waste 4 - 231 Hazardous Waste COMPLIANCE CATEGORY HAZARDOUS WASTE MANAGEMENT U.S. TEAM Guide REGULATORY REQUIREMENTS SMALL QUANTITY UNIVERSAL WASTE HANDLERS HW.280 General REVIEWER CHECKS March 2001 (NOTE: The following waste may, at the option of the generator, be managed under the requirements of 40 CFR 273 (40 CFR 273.5(a)) [Reviewed March 2000]: household wastes that are exempt under 40 CFR 261.4(b)(1) and are also the same type as the universal wastes defined at 273.6 conditionally exempt small quantity generator wastes that are exempt under 40 CFR 261.5 and are also the same types as the universal waste defined in 40 CFR 273.6.) (NOTE: When the following wastes are commingled with universal wastes, the commingled wastes must be managed under 40 CFR 273 as universal waste (40 CFR 273.5(b)) [Reviewed March 2000]: household wastes that are exempt under 40 CFR 261.4(b)(1) and are also the same type as the universal wastes defined at 40 CFR 273.6 conditionally exempt small quantity generator wastes that are exempt under 40 CFR 261.5 and are also the same types as the universal waste defined in 40 CFR 273.6.) HW.280.1.US. Small quantity handlers of universal waste, less than 5000 kg [approx. 11,111 lb] at any time, are generally prohibited from disposing, diluting, or treating universal wastes (40 CFR 273.11) [Revised March 2000]. Determine if the facility is a small quantity handler of universal waste. HW.280.2.US. Small quantity handlers of universal waste are required to meet specific accumulation time limits (40 CFR 273.15) [Reviewed March 2000]. Verify that universal waste is not accumulated for more than 1 yr from the date that the universal waste is generated, or received from another handler. Verify that the facility does not dispose of universal wastes onsite. Verify that, except when responding to a release or performing waste management activities outlined in 40 CFR 273.13 (see checklist item HW.290.1 through HW.290.5), the facility does not dilute or treat universal waste. (NOTE: The 1 yr limit may be exceeded if the sole purpose is to accumulate such quantities as necessary to facilitate proper recovery, treatment, or disposal. However, the handler must be able to prove that this is the case.) Verify that the handler can demonstrate the length of time that the universal waste has been accumulated by one of the following methods: placing the universal waste in a container and marking or labeling the container with the earliest date that any universal waste in the container became a waste or was received marking or labeling each individual item of universal waste with the date it 4 - 232 Hazardous Waste COMPLIANCE CATEGORY HAZARDOUS WASTE MANAGEMENT U.S. TEAM Guide REGULATORY REQUIREMENTS REVIEWER CHECKS March 2001 became waste or was received maintaining an inventory system onsite that identifies the date each universal waste became a waste or was received maintaining an inventory system onsite that identifies the earliest date that any universal waste in a group of universal waste items or a group of containers of universal waste became a waste or was received placing the universal waste in a specific accumulation area and identifying the earliest date that any universal waste in the area became a waste or was received any other method which clearly demonstrates the length of time that the universal waste has been accumulated from the date that it becomes a waste or was received. HW.280.3.US. Small quantity handlers of universal waste are required to handle releases according to specific procedures (40 CFR 273.17) [Reviewed March 2000]. Verify that all releases of universal waste and other universal waste residues are immediately contained. HW.280.4.US. Small quantity handlers of universal waste managing imported universal waste are required to meet specific parameters. (40 CFR 273.70(b) and 273.70(d)) [Added March 2000]. Determine if the small quantity handler of universal waste is receiving universal waste from a foreign country. Verify that the facility determines if the material resulting from the release is a hazardous waste. Verify that the universal waste is handled according to all requirements applicable to small quantity handlers of universal waste (40 CFR 273, Subpart B) immediately after the waste enters the United States. (NOTE: If the universal waste was imported from an Organization for Economic Cooperation and Development (OECD) country as specified in 40 CFR 262.58(a)(1), the requirements of 40 CFR 262, Subpart H apply. The designated OECD countries are: Australia, Austria, Belgium, Denmark, Finland, France, Germany, Greece, Iceland, Ireland, Italy, Japan, Luxembourg, Netherlands, New Zealand, Norway, Portugal, Spain, Sweden, Switzerland, Turkey, United Kingdom, and the United States. Canada and Mexico are considered OECD countries only for the purpose of transit.) 4 - 233 Hazardous Waste COMPLIANCE CATEGORY HAZARDOUS WASTE MANAGEMENT U.S. TEAM Guide REGULATORY REQUIREMENTS SMALL QUANTITY UNIVERSAL WASTE HANDLERS HW.290 Specific Wastes REVIEWER CHECKS March 2001 (NOTE: The following waste may, at the option of the generator, be managed under the requirements of 40 CFR 273 (40 CFR 273.5(a)) [Reviewed March 2000]: household wastes that are exempt under 40 CFR 261.4(b)(1) and are also the same type as the universal wastes defined at 273.6 conditionally exempt small quantity generator wastes that are exempt under 40 CFR 261.5 and are also the same types as the universal waste defined in 40 CFR 273.6.) (NOTE: When the following wastes are commingled with universal wastes, the commingled wastes must be managed under 40 CFR 273 as universal waste (40 CFR 273.5(b)) [Reviewed March 2000]: household wastes that are exempt under 40 CFR 261.4(b)(1) and are also the same type as the universal wastes defined at 40 CFR 273.6 conditionally exempt small quantity generator wastes that are exempt under 40 CFR 261.5 and are also the same types as the universal waste defined in 40 CFR 273.6.) HW.290.1.US. Small quantity handlers of universal waste are required to manage universal waste batteries according to specific parameters (40 CFR 273.12, 273.13(a)(1), and 273.13(a)(2)) [Reviewed March 2000]. (NOTE: A small quantity handler of universal waste is not required to notify the USEPA of universal waste handling activities.) (NOTE: Refer to the definition of Battery and Waste Battery.) Verify that universal waste batteries are managed in a way that prevents releases of any universal waste or component of a universal waste to the environment. Verify that batteries which show evidence of leakage, spillage, or damage that could cause leakage under reasonably foreseeable condition are contained in a container. Verify that containers for batteries with leak potential are closed, structurally sound, compatible with the contents of the battery, and lack evidence of leakage, spillage, or damage that could cause leakage under reasonably foreseeable conditions. Verify that, when conducting any of the following activities, the casing of each individual battery cell is not breached and remains intact and closed: sorting batteries by type mixing battery types in one container discharging batteries so as to remove the electric charge regenerating used batteries disassembling batteries or battery packs into individual batteries or cells removing batteries from consumer products removing electrolyte from batteries. 4 - 234 Hazardous Waste COMPLIANCE CATEGORY HAZARDOUS WASTE MANAGEMENT U.S. TEAM Guide REGULATORY REQUIREMENTS REVIEWER CHECKS March 2001 (NOTE: Cells may be opened to remove electrolyte but must be immediately closed after removal.) HW.290.2.US. Small quantity handlers of universal waste are required to manage the electrolyte from universal waste batteries and other solid wastes generated from battery management activities according to specific parameters (40 CFR 273.13(a)(3)) [Revised March 2000]. Verify that, if the small quantity universal waste handler removes electrolyte from batteries or generates other solid waste (e.g., battery pack materials, discarded consumer products) as a result of battery management activities, the handler determines if any of the wastes exhibit the characteristics of a hazardous waste. HW.290.3.US. Small quantity handlers of universal waste are required to manage universal waste pesticides according to specific parameters (40 CFR 273.12 and 273.13(b)) [Reviewed March 2000]. (NOTE: A small quantity handler of universal waste is not required to notify the USEPA of universal waste handling activities.) Verify that, if it does exhibit the characteristics of a hazardous waste, it is treated and handled as a hazardous waste. Verify that, if the electrolyte or other solid waste is not a hazardous waste, it is managed in accordance with any other applicable state and federal laws and regulations. (NOTE: Refer to the definition of Pesticides and Waste Pesticides.) Verify that universal waste pesticides are managed in a way that prevents releases of any universal waste or component of a universal waste to the environment. Verify that the pesticides are contained in one or more of the following: a container that remains closed, structurally sound, compatible with the pesticide, and that lacks evidence of leakage, spillage, or damage that could cause leakage under reasonably foreseeable conditions (this is considered an appropriate container) an inappropriate container that is overpacked in an appropriate container a tank that meets the requirements of 40 CFR 265, Subpart J, except for 40 CFR 265.197(c) (tank closure plans), 40 CFR 265.200 (waste analysis and trial tests), and 40 CFR 265.201 (requirements for SQGs) a transport vehicle or vessel that is closed, structurally sound, compatible with the pesticide, and that lacks evidence of leakage, spillage, or damage that could cause leakage under reasonably foreseeable conditions. HW.290.4.US. Small quantity handlers of universal waste are required to manage (NOTE: A small quantity handler of universal waste is not required to notify the USEPA of universal waste handling activities.) 4 - 235 Hazardous Waste COMPLIANCE CATEGORY HAZARDOUS WASTE MANAGEMENT U.S. TEAM Guide REGULATORY REQUIREMENTS universal waste thermostats according to specific parameters (40 CFR 273.12, 273.13(c)(1), and 273.13(c)(2)) [Revised March 2000]. REVIEWER CHECKS March 2001 (NOTE: Refer to the definition of Thermostat and Waste Thermostats.) Verify that universal waste thermostats are managed in a way that prevents releases of any universal waste or component of a universal waste to the environment. Verify that the thermostats are contained in a container that remains closed, structurally sound, compatible with the pesticide, and that lacks evidence of leakage, spill age, or damage that could cause leakage under reasonably foreseeable conditions. Verify that, if the handler removes the mercury containing ampules, the following are met: the ampules are removed in a manner designed to prevent breakage of the ampule ampules are removed only over, or in, a containment device a mercury cleanup system is readily available to immediately transfer any mercury spills or leaks from the containment device to an appropriate container per 40 CFR 262.34 there is immediate transfer of any mercury spills or leaks from broken ampules to an appropriate container (40 CFR 262.34) the area in which ampules are removed is well ventilated and monitored to ensure compliance with OSHA exposure levels for mercury employees removing ampules are thoroughly familiar with proper waste mercury handling and emergency procedures, including transfer of mercury from containment devices to appropriate containers removed ampules are stored in closed, nonleaking containers that are in good condition removed ampules are packed in the container with packing materials adequate to prevent breakage during storing, handling, and transportation. HW.290.5.US. Small quantity handlers of universal waste are required to manage the wastes from universal waste thermostats according to specific parameters (40 CFR 273.12 and 273.13(c)(3)) [Reviewed March 2000]. Verify that, if the small quantity universal waste handler removes mercury containing ampules, the handler determines if the mercury or cleanup residues resulting from spills or leaks exhibit the characteristics of a hazardous waste. Verify that, if the small quantity universal waste handler removes mercury containing ampules, the handler determines if the solid waste generated (e.g., remaining thermostat units) exhibit the characteristics of a hazardous waste. Verify that, if it does exhibit the characteristics of a hazardous waste, it is treated and handled as a hazardous waste. Verify that, if the mercury, residues, or other solid waste is not a hazardous waste, it is managed in accordance with any other applicable state and Federal laws and regulations. 4 - 236 Hazardous Waste COMPLIANCE CATEGORY HAZARDOUS WASTE MANAGEMENT U.S. TEAM Guide REGULATORY REQUIREMENTS REVIEWER CHECKS March 2001 HW.290.6.US. Small quantity handlers of universal waste are required to manage universal waste lamps according to specific parameters (40 CFR 273.13(d)) [Added October 1999, Reviewed March 2000]. Verify that a small quantity handler of universal waste contains any lamp in containers or packages that are structurally sound, adequate to prevent breakage, and compatible with the contents of the lamps. Verify that containers and packages remain closed and lack evidence of leakage, spillage or damage that could cause leakage under reasonably foreseeable conditions. Verify that a small quantity handler of universal waste immediately cleans up and places in a container any lamp that is broken and any lamp that shows evidence of breakage, leakage, or damage that could cause the release of mercury or other hazardous constituents to the environment. Verify that containers are closed, structurally sound, compatible with the contents of the lamps and lack evidence of leakage, spillage, or damage that could cause leakage or releases of mercury or other hazardous constituents to the environment under reasonably foreseeable conditions. 4 - 237 Hazardous Waste 4 - 238 Hazardous Waste COMPLIANCE CATEGORY HAZARDOUS WASTE MANAGEMENT U.S. TEAM Guide REGULATORY REQUIREMENTS SMALL QUANTITY UNIVERSAL WASTE HANDLERS HW.300 Personnel Training REVIEWER CHECKS March 2001 (NOTE: The following waste may, at the option of the generator, be managed under the requirements of 40 CFR 273 (40 CFR 273.5(a)) [Reviewed March 2000]: household wastes that are exempt under 40 CFR 261.4(b)(1) and are also the same type as the universal wastes defined at 273.6 conditionally exempt small quantity generator wastes that are exempt under 40 CFR 261.5 and are also the same types as the universal waste defined in 40 CFR 273.6.) (NOTE: When the following wastes are commingled with universal wastes, the commingled wastes must be managed under 40 CFR 273 as universal waste (40 CFR 273.5(b)) [Reviewed March 2000]: household wastes that are exempt under 40 CFR 261.4(b)(1) and are also the same type as the universal wastes defined at 40 CFR 273.6 conditionally exempt small quantity generator wastes that are exempt under 40 CFR 261.5 and are also the same types as the universal waste defined in 40 CFR 273.6.) HW.300.1.US. Employees who handle or have responsibility for managing universal wastes are required to be trained (40 CFR 273.16) [Reviewed March 2000]. Verify that employees have been trained in the proper handling and emergency response procedures appropriate to the types of universal waste handled at the facility. 4 - 239 Hazardous Waste 4 - 240 Hazardous Waste COMPLIANCE CATEGORY HAZARDOUS WASTE MANAGEMENT U.S. TEAM Guide REGULATORY REQUIREMENTS SMALL QUANTITY UNIVERSAL WASTE HANDLERS HW.310 Containers REVIEWER CHECKS March 2001 (NOTE: The following waste may, at the option of the generator, be managed under the requirements of 40 CFR 273 (40 CFR 273.5(a)) [Reviewed March 2000]: household wastes that are exempt under 40 CFR 261.4(b)(1) and are also the same type as the universal wastes defined at 273.6 conditionally exempt small quantity generator wastes that are exempt under 40 CFR 261.5 and are also the same types as the universal waste defined in 40 CFR 273.6.) (NOTE: When the following wastes are commingled with universal wastes, the commingled wastes must be managed under 40 CFR 273 as universal waste (40 CFR 273.5(b)) [Reviewed March 2000]: household wastes that are exempt under 40 CFR 261.4(b)(1) and are also the same type as the universal wastes defined at 40 CFR 273.6 conditionally exempt small quantity generator wastes that are exempt under 40 CFR 261.5 and are also the same types as the universal waste defined in 40 CFR 273.6.) HW.310.1.US. Universal wastes at small quantity universal waste handlers are required to be labeled according to specific parameters (40 CFR 273.14) [Revised October 1999, Reviewed March 2000]. Verify that universal waste batteries (each battery), or a container in which the batteries are contained, are labeled or marked clearly with any one of the following phrases: UNIVERSAL WASTE - BATTERY(IES) WASTE BATTERY(IES) USED BATTERY(IES). Verify that containers or multiple container package units, tanks, transport vehicles, or vessels in which recalled universal waste pesticides are contained are marked clearly with: the label that was on or accompanied the product as sold or distributed the words UNIVERSAL WASTE PESTICIDE(S) or WASTE PESTICIDE(s). Verify that the container, tanks, or transport vehicles or vessels in which unused pesticide products are contained are labeled or marked clearly with: the label that was on the product when purchased, if still legible if this is not feasible, the appropriate DOT label if it is not feasible to use the original or DOT label, an alternate label prescribed or designated by the waste pesticide collection program administered or recognized by a state the words UNIVERSAL WASTE - PESTICIDE(S) or WASTE PESTICIDE(S). Verify that universal waste thermostats or containers in which the thermostats are 4 - 241 Hazardous Waste COMPLIANCE CATEGORY HAZARDOUS WASTE MANAGEMENT U.S. TEAM Guide REGULATORY REQUIREMENTS REVIEWER CHECKS March 2001 contained are labeled or marked clearly with one of the following phrases: UNIVERSAL WASTE - MERCURY THERMOSTAT(S) WASTE MERCURY THERMOSTAT(S) USED MERCURY THERMOSTAT(S). Verify that each lamp or a container or package in which lamps are contained is labeled or marked clearly with one of the following phrases: UNIVERSAL WASTE - LAMP(S) WASTE LAMP(S) USED LAMP(S). 4 - 242 Hazardous Waste COMPLIANCE CATEGORY HAZARDOUS WASTE MANAGEMENT U.S. TEAM Guide REGULATORY REQUIREMENTS SMALL QUANTITY UNIVERSAL WASTE HANDLERS HW.330 Transportation REVIEWER CHECKS March 2001 (NOTE: The following waste may, at the option of the generator, be managed under the requirements of 40 CFR 273 (40 CFR 273.5(a)) [Reviewed March 2000]: household wastes that are exempt under 40 CFR 261.4(b)(1) and are also the same type as the universal wastes defined at 273.6 conditionally exempt small quantity generator wastes that are exempt under 40 CFR 261.5 and are also the same types as the universal waste defined in 40 CFR 273.6.) (NOTE: When the following wastes are commingled with universal wastes, the commingled wastes must be managed under 40 CFR 273 as universal waste (40 CFR 273.5(b)) [Reviewed March 2000]: household wastes that are exempt under 40 CFR 261.4(b)(1) and are also the same type as the universal wastes defined at 40 CFR 273.6 conditionally exempt small quantity generator wastes that are exempt under 40 CFR 261.5 and are also the same types as the universal waste defined in 40 CFR 273.6.) HW.330.1.US. Offsite shipments of universal waste from small quantity handlers is required to be done according to specific parameters (40 CFR 273.18 and 273.19) [Revised March 2000]. Verify that small quantity handlers of universal waste do not send or take universal waste to anyplace other than another universal waste handler, a destination facility, or a foreign destination. (NOTE: If the handler self-transports universal waste, they have to comply with the requirements for transportation in 40 CFR 273.50 through 273.56 (see checklist items HW.450.1 through HW.450.6).) Verify that, if the universal waste being offered for offsite transportation meets the definition of hazardous materials under 49 CFR 171 through 180, the shipment is packaged, labeled, marked, and placarded, and that the proper shipping papers have been prepared under DOT regulations. Verify that, prior to sending the waste to another universal waste handler, the originating handler has ensured that the receiving handler agrees to receive the waste. Verify that, if the receiving handler rejects a waste shipment, the originating handler does one of the following: receives the waste back when notified the shipment was rejected agrees with the receiving handler on a destination facility to which the shipment will be sent. Verify that, if the receiving handler rejects a shipment or a portion of the shipment, the receiving handler notifies the originating handler to discuss reshipment of the load, and either: sends the shipment back to the originating handler 4 - 243 Hazardous Waste COMPLIANCE CATEGORY HAZARDOUS WASTE MANAGEMENT U.S. TEAM Guide REGULATORY REQUIREMENTS REVIEWER CHECKS March 2001 if agreed by both originating and receiving handlers, sends the shipment to a destination facility. Verify that, if a small quantity handler of universal waste receives a shipment containing hazardous waste that is not universal waste, the handler immediately notifies the regional USEPA office of the illegal shipment and provides the name, address, and phone number of the originating shipper. (NOTE: If the handler receives a shipment of nonhazardous nonuniversal waste the handler may manage the waste in any way that is in compliance with federal, state, or local regulations.) (NOTE: A small quantity handler of universal waste is not required to keep records of shipments of universal waste.) HW.330.2.US. Small quantity handlers of universal waste that send universal waste to a foreign destination are required to meet specific requirements (40 CFR 273.20) [Revised March 2000]. Verify that, for universal waste being sent to a foreign destination other than an OECD country, the requirements in 40 CFR 262.53 (notification of intent to export), 40 CFR 262.56(a)(1) through 262.56(a)(4), 262.56(a)(6) and 262.56(b) (annual reports), and 40 CFR 262.57 (recordkeeping) are met. Verify that, for universal waste being sent to an OECD country, the requirements of 40 CFR 262, Subpart H are met. Verify that the receiving country has consented to accept the waste through an Acknowledgment of Consent. Verify that a copy of the USEPA Acknowledgment of Consent for the shipment has been provided to the transporter. 4 - 244 Hazardous Waste COMPLIANCE CATEGORY HAZARDOUS WASTE MANAGEMENT U.S. TEAM Guide REGULATORY REQUIREMENTS LARGE QUANTITY UNIVERSAL WASTE HANDLERS HW.370 General REVIEWER CHECKS March 2001 (NOTE: The following waste may, at the option of the generator, be managed under the requirements of 40 CFR 273 (40 CFR 273.5(a)) [Reviewed March 2000]: household wastes that are exempt under 40 CFR 261.4(b)(1) and are also the same type as the universal wastes defined at 273.6 conditionally exempt small quantity generator wastes that are exempt under 40 CFR 261.5 and are also the same types as the universal waste defined in 40 CFR 273.6.) (NOTE: When the following wastes are commingled with universal wastes, the commingled wastes must be managed under 40 CFR 273 as universal waste (40 CFR 273.5(b)) [Reviewed March 2000]: household wastes that are exempt under 40 CFR 261.4(b)(1) and are also the same type as the universal wastes defined at 40 CFR 273.6 conditionally exempt small quantity generator wastes that are exempt under 40 CFR 261.5 and are also the same types as the universal waste defined in 40 CFR 273.6.) HW.370.1.US. Large quantity handlers of universal waste, more than 5000 kg at any time, are generally prohibited from disposing, diluting, or treating universal wastes (40 CFR 273.31) [Revised March 2000]. Determine if the facility is a large quantity handler of universal waste. HW.370.2.US. Large quantity handlers of universal waste are required to meet specific accumulation time limits (40 CFR 273.35) [Revised March 2000]. Verify that universal waste is not accumulated for more than 1 yr from the date that the universal waste is generated, or received from another handler. Verify that the facility does not dispose of universal wastes onsite. Verify that, except when responding to a release or performing waste management activities outlined in 40 CFR 273.13 (see checklist items HW.290.1 through HW.290.5), the facility does not dilute or treat universal waste. (NOTE: The 1 yr limit may be exceeded if the sole purpose is to accumulate such quantities as are necessary to facilitate proper recovery, treatment, or disposal. However, the handler must be able to prove that this is so.) Verify that the handler can demonstrate the length of time that the universal waste has been accumulated by one of the following methods: placing the universal waste in a container and marking or labeling the container with the earliest date that any universal waste in the container became a waste or was received marking or labeling each individual item of universal waste with the date it became waste or was received maintaining an inventory system onsite that identifies the date each universal waste became a waste or was received maintaining an inventory system onsite that identifies the earliest date that any universal waste in a group of universal waste items or a group of containers 4 - 245 Hazardous Waste COMPLIANCE CATEGORY HAZARDOUS WASTE MANAGEMENT U.S. TEAM Guide REGULATORY REQUIREMENTS REVIEWER CHECKS March 2001 of universal waste became a waste or was received placing the universal waste in a specific accumulation area and identifying the earliest date that any universal waste in the area became a waste or was received any other method which clearly demonstrates the length of time that the universal waste has been accumulated from the date that it becomes a waste or was received. HW.370.3.US. Large quantity handlers of universal waste are required to handle releases according to specific procedures (40 CFR 273.37) [Reviewed March 2000]. Verify that all releases of universal waste and other universal waste residues are immediately contained. HW.370.4.US. Large quantity handlers of universal waste managing imported universal waste are required to meet specific parameters. (40 CFR 273.70(b) and 273.70(d)) [Added March 2000]. Determine if the large quantity handler of universal waste is receiving universal waste from a foreign country. Verify that the facility determines if the material resulting from the release is a hazardous waste and handles it accordingly. Verify that the imported universal waste is handled according all requirements applicable to large quantity handlers of universal waste immediately after the waste enters the United States. (NOTE: If the universal waste was imported from an OECD country as specified in 40 CFR 262.58(a)(1), the requirements of 40 CFR 262, Subpart H apply. The designated OECD countries are: Australia, Austria, Belgium, Denmark, Finland, France, Germany, Greece, Iceland, Ireland, Italy, Japan, Luxembourg, Netherlands, New Zealand, Norway, Portugal, Spain, Sweden, Switzerland, Turkey, United Kingdom, and the United States. Canada and Mexico are considered OECD countries only for the purpose of transit.) 4 - 246 Hazardous Waste COMPLIANCE CATEGORY HAZARDOUS WASTE MANAGEMENT U.S. TEAM Guide REGULATORY REQUIREMENTS LARGE QUANTITY UNIVERSAL WASTE HANDLERS HW.380 Specific Wastes REVIEWER CHECKS March 2001 (NOTE: The following waste may, at the option of the generator, be managed under the requirements of 40 CFR 273 (40 CFR 273.5(a)) [Reviewed March 2000]: household wastes that are exempt under 40 CFR 261.4(b)(1) and are also the same type as the universal wastes defined at 273.6 conditionally exempt small quantity generator wastes that are exempt under 40 CFR 261.5 and are also the same types as the universal waste defined in 40 CFR 273.6.) (NOTE: When the following wastes are commingled with universal wastes, the commingled wastes must be managed under 40 CFR 273 as universal waste (40 CFR 273.5(b)) [Reviewed March 2000]: household wastes that are exempt under 40 CFR 261.4(b)(1) and are also the same type as the universal wastes defined at 40 CFR 273.6 conditionally exempt small quantity generator wastes that are exempt under 40 CFR 261.5 and are also the same types as the universal waste defined in 40 CFR 273.6.) HW.380.1.US. Large quantity handlers of universal waste are required to manage universal waste batteries and other solid waste generated from battery management activities according to specific parameters (40 CFR 273.33(a)(1) and 273.33(a)(2)) [Revised March 2000]. (NOTE: Refer to the definition of Battery and Waste Battery.) Verify that universal waste batteries are managed in a way that prevents releases of any universal waste or component of a universal waste to the environment. Verify that batteries that show evidence of leakage, spillage, or damage that could cause leakage under reasonably foreseeable condition are contained in a container. Verify that containers are closed, structurally sound, compatible with the contents of the battery, and lack evidence of leakage, spillage, or damage that could cause leakage. Verify that, when conducting any of the following activities, the casing of each individual battery cell is not breached and remains intact and closed: sorting batteries by type mixing battery types in one container discharging batteries so as to remove the electric charge regenerating used batteries disassembling batteries or battery packs into individual batteries or cells removing batteries from consumer products removing electrolyte from batteries. (NOTE: Cells may be opened to remove electrolyte but must be immediately closed after removal.) HW.380.2.US. Large quantity handlers of universal waste are required to manage the Verify that, if the large quantity universal waste handler removes electrolyte from batteries or generates other solid waste (e.g., battery pack materials, discarded consumer products) as a result of battery management activities, the handler 4 - 247 Hazardous Waste COMPLIANCE CATEGORY HAZARDOUS WASTE MANAGEMENT U.S. TEAM Guide REGULATORY REQUIREMENTS electrolyte from universal waste batteries according to specific parameters (40 CFR 273.33(a)(3)) [Reviewed March 2000]. REVIEWER CHECKS March 2001 determines if any of the wastes exhibit the characteristics of a hazardous waste. Verify that, if it does exhibit the characteristics of a hazardous waste, it is treated and handled as a hazardous waste. Verify that, if the electrolyte or other solid waste is not a hazardous waste, it is managed in accordance with any other applicable state and federal laws and regulations. HW.380.3.US. Large quantity handlers of universal waste are required to manage universal waste pesticides according to specific parameters (40 CFR 273.33(b)) [Reviewed March 2000]. (NOTE: Refer to the definition of Pesticide and Waste Pesticides.) HW.380.4.US. Large quantity handlers of universal waste are required to manage universal waste thermostats according to specific parameters (40 CFR 273.33(c)(1) and 273.33(c)(2)) [Revised March 2000]. (NOTE: Refer to the definition of Thermostat and Waste Thermostat.) Verify that universal waste pesticides are managed in a way that prevents releases of any universal waste or component of a universal waste to the environment. Verify that the pesticides are contained in one or more of the following: a container that remains closed, structurally sound, compatible with the pesticide, and lacks evidence of leakage, spillage, or damage that could cause leak age under reasonably foreseeable conditions (NOTE: This is considered an appropriate container) an inappropriate container that is overpacked in an appropriate container a tank that meets the requirements of 40 CFR 265, Subpart J except for 40 CFR 265.197(c) (tank closure plans), 40 CFR 265.200 (waste analysis and trial tests), and 40 CFR 265.201 (requirements for SQGs) a transport vehicle or vessel that is closed, structurally sound, compatible with the pesticide, and that lacks evidence of leakage, spillage, or damage that could cause leakage under reasonably foreseeable conditions. Verify that universal waste thermostats are managed in a way that prevents releases of any universal waste or component of a universal waste to the environment. Verify that the thermostats are contained in a container that remains closed, structurally sound, compatible with the pesticide, and that lacks evidence of leakage, spill age, or damage that could cause leakage under reasonably foreseeable conditions. Verify that, if the handler removes the mercury containing ampules, the following are met: the ampules are removed in a manner designed to prevent breakage of the ampule ampules are removed only over, or in, a containment device a mercury cleanup system is readily available to immediately transfer any 4 - 248 Hazardous Waste COMPLIANCE CATEGORY HAZARDOUS WASTE MANAGEMENT U.S. TEAM Guide REGULATORY REQUIREMENTS REVIEWER CHECKS March 2001 mercury spills or leaks from the containment device to an appropriate container (i.e. one that meets the requirements under 40 CFR 262.34) there is immediate transfer of any mercury spills or leaks from broken ampules to an appropriate container the area in which ampules are removed is well ventilated and monitored to ensure compliance with OSHA exposure levels for mercury employees removing ampules are thoroughly familiar with proper waste mercury handling and emergency procedures removed ampules are stored in closed, nonleaking containers that are in good condition removed ampule are packed in the container with packing materials adequate to prevent breakage during storing, handling, and transportation. HW.380.5.US. Large quantity handlers of universal waste are required to manage the wastes from universal waste thermostats according to specific parameters (40 CFR 273.33(c)(3)) [Reviewed March 2000]. Verify that, if the large quantity universal waste handler removes mercury containing ampules, the handler determines if the mercury or cleanup residues resulting from spills or leaks exhibits the characteristics of a hazardous waste. Verify that, if the large quantity universal waste handler removes mercury containing ampules, the handler determines if the solid waste generated (e.g., remaining thermostat units) exhibits the characteristics of a hazardous waste. Verify that, if it does exhibit the characteristics of a hazardous waste is treated and handled as a hazardous waste. Verify that, if the mercury, residues, or other solid waste is not a hazardous waste, it is managed in accordance with any other applicable state and Federal laws and regulations. HW.380.6.US. Large quantity handlers of universal waste are required to manage universal waste lamps according to specific parameters (40 CFR 273.33(d)) [Added October 1999, Reviewed March 2000]. Verify that a large quantity handler of universal waste contains any lamp in containers or packages that are structurally sound, adequate to prevent breakage, and compatible with the contents of the lamps. Verify that containers and packages remain closed and lack evidence of leakage, spillage or damage that could cause leakage under reasonably foreseeable conditions. Verify that a large quantity handler of universal waste immediately cleans up and places in a container any lamp that is broken and places in a container any lamp that shows evidence of breakage, leakage, or damage that could cause the release of mercury or other hazardous constituents to the environment. Verify that containers are closed, structurally sound, compatible with the contents of the lamps and lack evidence of leakage, spillage, or damage that could cause leakage or releases of mercury or other hazardous constituents to the environment under reasonably foreseeable conditions. 4 - 249 Hazardous Waste COMPLIANCE CATEGORY HAZARDOUS WASTE MANAGEMENT U.S. TEAM Guide REGULATORY REQUIREMENTS REVIEWER CHECKS March 2001 4 - 250 Hazardous Waste 4 - 251 Hazardous Waste COMPLIANCE CATEGORY HAZARDOUS WASTE MANAGEMENT U.S. TEAM Guide REGULATORY REQUIREMENTS LARGE QUANTITY UNIVERSAL WASTE HANDLERS HW.390 Personnel Training REVIEWER CHECKS March 2001 (NOTE: The following waste may, at the option of the generator, be managed under the requirements of 40 CFR 273 (40 CFR 273.5(a)) [Reviewed March 2000]: household wastes that are exempt under 40 CFR 261.4(b)(1) and are also the same type as the universal wastes defined at 273.6 conditionally exempt small quantity generator wastes that are exempt under 40 CFR 261.5 and are also the same types as the universal waste defined in 40 CFR 273.6.) (NOTE: When the following wastes are commingled with universal wastes, the commingled wastes must be managed under 40 CFR 273 as universal waste (40 CFR 273.5(b)) [Reviewed March 2000]: household wastes that are exempt under 40 CFR 261.4(b)(1) and are also the same type as the universal wastes defined at 40 CFR 273.6 conditionally exempt small quantity generator wastes that are exempt under 40 CFR 261.5 and are also the same types as the universal waste defined in 40 CFR 273.6.) HW.390.1.US. Employees who handle or have responsibility for managing universal wastes are required to be trained (40 CFR 273.36) [Revised March 2000]. Verify that all employees have been trained in the proper handling and emergency response procedures relative to their responsibilities during normal facility operations and emergencies. 4 - 252 Hazardous Waste 4 - 253 Hazardous Waste COMPLIANCE CATEGORY HAZARDOUS WASTE MANAGEMENT U.S. TEAM Guide REGULATORY REQUIREMENTS LARGE QUANTITY UNIVERSAL WASTE HANDLERS HW.400 Containers REVIEWER CHECKS March 2001 (NOTE: The following waste may, at the option of the generator, be managed under the requirements of 40 CFR 273 (40 CFR 273.5(a)) [Reviewed March 2000]: household wastes that are exempt under 40 CFR 261.4(b)(1) and are also the same type as the universal wastes defined at 273.6 conditionally exempt small quantity generator wastes that are exempt under 40 CFR 261.5 and are also the same types as the universal waste defined in 40 CFR 273.6.) (NOTE: When the following wastes are commingled with universal wastes, the commingled wastes must be managed under 40 CFR 273 as universal waste (40 CFR 273.5(b)) [Reviewed March 2000]: household wastes that are exempt under 40 CFR 261.4(b)(1) and are also the same type as the universal wastes defined at 40 CFR 273.6 conditionally exempt small quantity generator wastes that are exempt under 40 CFR 261.5 and are also the same types as the universal waste defined in 40 CFR 273.6.) HW.400.1.US. Universal wastes at large quantity universal waste handlers are required to be labeled according to specific parameters (40 CFR 273.34) [Revised October 1999, Reviewed March 2000]. Verify that universal waste batteries (each battery), or a container in which the batteries are contained, are labeled or marked clearly with any one of the following phrases: UNIVERSAL WASTE - BATTERY(IES) WASTE BATTERY(IES) USED BATTERY(IES). Verify that containers or multiple container package units, tanks, transport vehicles, or vessels in which recalled universal waste pesticides are contained are marked clearly with: the label that was on or accompanied the product as sold or distributed the words UNIVERSAL WASTE PESTICIDE(S) or WASTE PESTICIDE(s). Verify that the container, tanks, or transport vehicles or vessels in which unused pesticide products are contained are labeled or marked clearly with: the label that was on the product when purchased, if still legible, or, if this is not feasible, the appropriate DOT label an alternate label prescribed or designated by the waste pesticide collection program administered or recognized by a state the words UNIVERSAL WASTE - PESTICIDE(S) or WASTE PESTICIDE(S). Verify that universal waste thermostats or containers in which the thermostats are contained are labeled or marked clearly with one of the following phrases: 4 - 254 Hazardous Waste COMPLIANCE CATEGORY HAZARDOUS WASTE MANAGEMENT U.S. TEAM Guide REGULATORY REQUIREMENTS REVIEWER CHECKS March 2001 UNIVERSAL WASTE - MERCURY THERMOSTAT(S) WASTE MERCURY THERMOSTAT(S) USED MERCURY THERMOSTAT(S). Verify that each lamp or a container or package in which lamps are contained is labeled or marked clearly with one of the following phrases: UNIVERSAL WASTE - LAMP(S) WASTE LAMP(S) USED LAMP(S). 4 - 255 Hazardous Waste COMPLIANCE CATEGORY HAZARDOUS WASTE MANAGEMENT U.S. TEAM Guide REGULATORY REQUIREMENTS LARGE QUANTITY UNIVERSAL WASTE HANDLERS HW.410 Notifications REVIEWER CHECKS March 2001 (NOTE: The following waste may, at the option of the generator, be managed under the requirements of 40 CFR 273 (40 CFR 273.5(a)) [Reviewed March 2000]: household wastes that are exempt under 40 CFR 261.4(b)(1) and are also the same type as the universal wastes defined at 273.6 conditionally exempt small quantity generator wastes that are exempt under 40 CFR 261.5 and are also the same types as the universal waste defined in 40 CFR 273.6.) (NOTE: When the following wastes are commingled with universal wastes, the commingled wastes must be managed under 40 CFR 273 as universal waste (40 CFR 273.5(b)) [Reviewed March 2000]: household wastes that are exempt under 40 CFR 261.4(b)(1) and are also the same type as the universal wastes defined at 40 CFR 273.6 conditionally exempt small quantity generator wastes that are exempt under 40 CFR 261.5 and are also the same types as the universal waste defined in 40 CFR 273.6.) HW.410.1.US. Large quantity handlers of universal waste are required to perform specific notification activities (40 CFR 273.32) [Revised March 2000]. Verify that the handler has sent written notification of universal waste management to the Regional Administrator and received an USEPA identification number before meeting or exceeding the 5000 kg (11,111 lb] storage limit. (NOTE: In the following circumstances, the handler is not required to notify the USEPA: if the handler has already notified the USEPA of hazardous waste management activity and has received a U.S. EPA identification number if recalled pesticides are being managed and notification has already been sent in under 40 CFR 165.) Verify that the notification includes: the universal waste handlers name and mailing address the name and business phone of the POC at the facility the address or physical location of the universal waste management activities a list of all types of universal waste managed by the handler a statement indicating that the handler is accumulating more than 5000 kg [ 11,111 lb] of universal waste at one time and the types of universal waste that are accumulated above this quantity. 4 - 256 Hazardous Waste 4 - 257 Hazardous Waste COMPLIANCE CATEGORY HAZARDOUS WASTE MANAGEMENT U.S. TEAM Guide REGULATORY REQUIREMENTS LARGE QUANTITY UNIVERSAL WASTE HANDLERS HW.420 Transportation REVIEWER CHECKS March 2001 (NOTE: The following waste may, at the option of the generator, be managed under the requirements of 40 CFR 273 (40 CFR 273.5(a)) [Reviewed March 2000]: household wastes that are exempt under 40 CFR 261.4(b)(1) and are also the same type as the universal wastes defined at 273.6 conditionally exempt small quantity generator wastes that are exempt under 40 CFR 261.5 and are also the same types as the universal waste defined in 40 CFR 273.6.) (NOTE: When the following wastes are commingled with universal wastes, the commingled wastes must be managed under 40 CFR 273 as universal waste (40 CFR 273.5(b)) [Reviewed March 2000]: household wastes that are exempt under 40 CFR 261.4(b)(1) and are also the same type as the universal wastes defined at 40 CFR 273.6 conditionally exempt small quantity generator wastes that are exempt under 40 CFR 261.5 and are also the same types as the universal waste defined in 40 CFR 273.6.) HW.420.1.US. Offsite shipment of universal waste from large quantity handlers is required to be done according to specific parameters (40 CFR 273.38) [Revised March 2000]. Verify that large quantity handlers of universal waste do not send or take universal waste to anyplace other than another universal waste handler, a destination facility, or a foreign destination. (NOTE: If the handler self-transports universal waste, they have to comply with the requirements for transportation in 40 CFR 273.50 through 273.56 (see checklist items HW.450.1 through HW.450.6).) Verify that, if the universal waste being offered for off-site transportation, the material meets the definition of hazardous materials under 49 CFR 171 through 180, the shipment is packaged, labeled, marked, and placarded, and the proper shipping papers have been prepared under DOT regulations. Verify that, prior to sending the waste offsite, the originating handler has ensured that the receiving handler agrees to receive the waste. Verify that, if the receiving handler rejects a waste shipment, the originating handler does one of the following: receives the waste back when notified the shipment was rejected agrees with the receiving handler on a destination facility to which the shipment will be sent. Verify that, if the receiving handler rejects a shipment or a portion of a shipment, the receiving handler notifies the originating handler to discuss reshipment of the load, and either: sends the shipment back to the originating handler, or if agreed by both originating and receiving handlers, sends the shipment to a 4 - 258 Hazardous Waste COMPLIANCE CATEGORY HAZARDOUS WASTE MANAGEMENT U.S. TEAM Guide REGULATORY REQUIREMENTS REVIEWER CHECKS March 2001 destination facility. Verify that, if a large quantity handler of universal waste receives a shipment containing hazardous waste that is not universal waste, the handler immediately notifies the regional USEPA office of the illegal shipment and provides the name, phone numbers, and address of the originating shipper. (NOTE: If the handler receives a shipment of nonhazardous, nonuniversal waste, the handler may manage the waste in any way that is in compliance with federal, state, or local regulations.) HW.420.2.US. Large quantity handlers are required to track offsite shipments (40 CFR 273.39) [Revised March 2000]. Verify that a record of each shipment of universal waste received at the facility is kept in one of the following: a log invoices manifests bill of lading other shipping document. Verify that the record for each shipment received includes the following: name and address of the originating handler or foreign shipper from who the waste was sent the quantity of each type of universal waste received the date of receipt of the shipment. Verify that a record of each shipment of universal waste shipped offsite is kept in one of the following: a log invoices manifests bill of lading other shipping document. Verify that the record for each offsite shipment includes the following: name and address of the handler, destination facility, or foreign destination to whom the universal waste was sent the quantity of each type of universal waste shipped the date the shipment left the facility. Verify that records are retained for at least 3 yr: for shipments received at the facility, from the date of receipt of the shipment 4 - 259 Hazardous Waste COMPLIANCE CATEGORY HAZARDOUS WASTE MANAGEMENT U.S. TEAM Guide REGULATORY REQUIREMENTS REVIEWER CHECKS March 2001 for shipments sent off-site by the handler, from the date the shipment left the facility. HW.420.3.US. Large quantity handlers of universal waste that send universal waste to a foreign destination are required to meet specific requirements (40 CFR 273.20) [Revised March 2000]. Verify that, for universal waste being sent to a foreign destination other than an OECD country, the requirements in 40 CFR 262.53 (notification of intent to export), 40 CFR 262.56(a)(1) through 262.56(a)(4), 262.56(a)(6) and 262.56(b) (annual reports), and 40 CFR 262.57 (recordkeeping) are met. Verify that, for universal waste being sent to an OECD country, the requirements of 40 CFR 262, Subpart H are met. Verify that the receiving country has consented to accept the waste through an Acknowledgment of Consent. Verify that a copy of the USEPA Acknowledgment of Consent for the shipment has been provided to the transporter. 4 - 260 Hazardous Waste 4 - 261 Hazardous Waste COMPLIANCE CATEGORY HAZARDOUS WASTE MANAGEMENT U.S. TEAM Guide REGULATORY REQUIREMENTS REVIEWER CHECKS March 2001 HW.450 UNIVERSAL WASTE TRANSPORTERS HW.450.1.US. Universal waste transporters are prohibited from disposing or treating universal wastes (40 CFR 273.51) [Reviewed March 2000]. Determine if the facility is a transporter of universal waste. HW.450.2.US. Universal waste transporters are required to manage the waste they transport according to specific parameters (40 CFR 273.52) [Reviewed March 2000]. Verify that the waste is managed according to applicable DOT regulations depending on whether it meets the criteria for definition as a hazardous material or as a hazardous waste. HW.450.3.US. Universal waste transporters may only store the universal waste at a transfer facility for 10 days (40 CFR 273.53) [Reviewed March 2000]. Verify that universal waste is not stored at a transfer facility for more than 10 days. HW.450.4.US. Universal waste transporters are required to handle releases according to specific procedures (40 CFR 273.54) [Reviewed March 2000]. Verify that all releases of universal waste and other universal waste residues are immediately contained. HW.450.5.US. Offsite shipments of universal waste transporters are required to be done according to specific Verify that transporters of universal waste do not send or take universal waste to any place other than a universal waste handler, a destination facility, or a foreign destination. Verify that the facility does not dispose of universal wastes onsite. Verify that, except when responding to a release or performing waste management activities outlined in 40 CFR 273.13 (see checklist item HW.290.1 through HW.290.5), the facility does not dilute or treat universal waste. (NOTE: If the waste is stored for more than 10 days, the transporter becomes a handler.) Verify that the transporter determines if the material resulting from the release is a hazardous waste. 4 - 262 Hazardous Waste COMPLIANCE CATEGORY HAZARDOUS WASTE MANAGEMENT U.S. TEAM Guide REGULATORY REQUIREMENTS REVIEWER CHECKS March 2001 parameters (40 CFR 273.18 and 273.19) [Reviewed March 2000]. Verify that, if the universal waste being offered for offsite transportation meets the definition of hazardous materials under 49 CFR 171 through 180, it is placarded, packaged and shipped according to DOT requirements. HW.450.6.US. Transporters of universal waste that send universal waste to a foreign destination are required to meet specific requirements (40 CFR 273.56) [Revised March 2000]. (NOTE: These requirements apply when shipping to other than those OECD countries specified in 40 CFR 262.58(a)(1). The designated OECD countries are: Australia, Austria, Belgium, Denmark, Finland, France, Germany, Greece, Iceland, Ireland, Italy, Japan, Luxembourg, Netherlands, New Zealand, Norway, Portugal, Spain, Sweden, Switzerland, Turkey, United Kingdom, and the United States. Canada and Mexico are considered OECD countries only for the purpose of transit.) Verify that the transporter has determined that the shipment conforms to the U.S. EPA Acknowledgment of Consent. Verify that a copy of the USEPA Acknowledgment of Consent accompanies the shipment. Verify that appropriate measures are taken to ensure the universal waste is delivered to the facility designated by the person initiating the shipment. HW.450.7.US. Universal waste transporters managing imported universal waste are required to meet specific parameters. (40 CFR 273.70(a) and 273.70(d)) [Added March 2000]. Determine if the universal waste transporter is managing universal waste from a foreign country. Verify that the universal waste is handled according all requirements applicable to universal waste transporters immediately after the waste enters the United States. (NOTE: If the universal waste was imported from an OECD country as specified in 40 CFR 262.58(a)(1), the requirements of 40 CFR 262, Subpart H apply. The designated OECD countries are: Australia, Austria, Belgium, Denmark, Finland, France, Germany, Greece, Iceland, Ireland, Italy, Japan, Luxembourg, Netherlands, New Zealand, Norway, Portugal, Spain, Sweden, Switzerland, Turkey, United Kingdom, and the United States. Canada and Mexico are considered OECD countries only for the purpose of transit.) 4 - 263 Hazardous Waste COMPLIANCE CATEGORY HAZARDOUS WASTE MANAGEMENT U.S. TEAM Guide REGULATORY REQUIREMENTS REVIEWER CHECKS March 2001 HW.470 UNIVERSAL WASTE DESTINATION FACILITIES HW.470.1.US. Destination facilities are required to meet specific requirements (40 CFR 273.60) [Revised October 1999, Reviewed March 2000]. Verify that the owner or operator of a destination facility meets all applicable requirements of 40 CFR 264, 265, 266, 268, 270, and the notification requirement under section 3010 of RCRA. HW.470.2.US. Destination facilities are required to meet specific standards in relation to offsite shipments of universal waste (40 CFR 273.61) [Revised March 2000]. Verify that the destination facility does not send or take universal waste to a place other than a universal waste handler, another destination facility, or foreign destination. Verify that the owner/operator of a destination facility that recycles a particular universal waste without storing that universal waste before it is recycled complies with 40 CFR 261.6(c)(2). Verify that, if the destination facility reject a shipment or portion of a shipment containing universal waste, they contact the shipper to notify him of the rejection and discuss reshipment of the load. Verify that, if a shipment is rejected, the destination facility does one of the following: sends the shipment back to the original shipper sends the shipment to another destination facility if agreed upon by the shipper and the holding destination facility. Verify that, if a destination facility receives a shipment containing hazardous waste that is not universal waste, the facility immediately notifies the regional USEPA office of the illegal shipment and provides the name, phone numbers, and address of the originating shipper. (NOTE: If the facility receives a shipment of nonhazardous nonuniversal waste, the facility may manage the waste in any way that is in compliance with Federal, state, or local regulations.) 4 - 264 Hazardous Waste COMPLIANCE CATEGORY HAZARDOUS WASTE MANAGEMENT U.S. TEAM Guide REGULATORY REQUIREMENTS REVIEWER CHECKS March 2001 HW.470.3.US. Destination facilities are required to track universal waste shipments (40 CFR 273.62) [Revised March 2000]. Verify that a record of each shipment of universal waste received at the facility is kept in one of the following: a log invoices manifests bill of lading other shipping document. Verify that the record for each shipment received includes the following: name and address of the originating universal waste handler, destination facility or foreign shipper from whom the waste was sent the quantity of each type of universal waste received the date of receipt of the shipment. Verify that records are retained for 3 yr from the date of receipt of a shipment of universal waste. HW.470.4.US. Universal waste destination facility managing imported universal waste are required to meet specific parameters. (40 CFR 273.70(c) and 273.70(d)) [Added March 2000]. Determine if the universal waste destination facility is managing universal waste from a foreign country. Verify that the universal waste is handled according all requirements applicable to universal waste destination facility immediately after the waste enters the United States. (NOTE: If the universal waste was imported from an OECD country as specified in 40 CFR 262.58(a)(1), the requirements of 40 CFR 262, Subpart H apply. The designated OECD countries are: Australia, Austria, Belgium, Denmark, Finland, France, Germany, Greece, Iceland, Ireland, Italy, Japan, Luxembourg, Netherlands, New Zealand, Norway, Portugal, Spain, Sweden, Switzerland, Turkey, United Kingdom, and the United States. Canada and Mexico are considered OECD countries only for the purpose of transit.) 4 - 265 Hazardous Waste Appendix 4-1 Hazardous Waste from Nonspecific Sources and from Specific Sources (40 CFR 261.31 and 261.32) Table I Hazardous Waste from Nonspecific Sources Industry and USEPA Hazardous Waste Number Hazardous Waste Hazard Code* Generic F001 The spent halogenated solvents used in degreasing. Trichloroethylene, methylene chloride, 1,1,1-trichloroethane, carbon tetrachloride, and the chlorinated fluorocarbons; all spent solvent mixtures or blends used in degreasing containing before use, a total of 10 percent or more (by volume) of one or more of the above halogenated solvents listed in F002, F004, F005; and still bottoms from the recovery of these spent solvents and spent solvent mixtures. (t) F002 The following spent halogenated solvents: tetrachloroethylene, methylene chloride, trichloroethylene, 1,1,1-trichloroethane, chlorobenzene, 1,1,2trichloro-1,1,2-trifluoroethane, ortho-dichlorobenzene, trichlorofluoromethane, and 1,1,2-trichloroethane; all spent solvent mixtures or blends containing, before use, a total of 10 percent or more by volume, of one or more of the above halogenated solvents or those listed in F001, F004, or F005; and still bottoms from the recovery of these spent solvents and spent solvent mixtures. (t) F003 The spent nonhalogenated solvents, xylene, acetone, ethyl acetate, ethyl benzene, ethyl ether, methyl isobutyl ketone, n-butyl alcohol, cyclohexanone, and methanol; and the still bottoms from the recovery of these solvents and spent solvent mixtures. (i) F004 The spent nonhalogenated solvents, cresols and cresylic acid, and nitrobenzene; and the still bottoms from the recovery of these solvents. (t) F005 The following spent nonhalogenated solvents: toluene, methyl ethyl ketone, carbons disulfide, isobutanol, pyridine, benzene, 2-ethoxylethanol, and 2nitropropane; all spent solvent mixtures or blends containing, before use, a total of 10 percent or more by volume of one or more of the above nonhalogenated solvents or those solvents listed in F001, F002, or F004; and still bottoms from the recovery of these solvents. (i,t) F006 Wastewater treatment sludges from electroplating operations except from the following processes: (1) sulfuric acid anodizing of aluminum; (2) tin plating on carbon steel; (3) zinc plating (segregated basis) on carbon steel; (4) aluminum or zinc-aluminum plating on carbon steel; (5) cleaning strip ping associated with tin, zinc, and aluminum plating on carbon steel; and (6) chemical etching and milling of aluminum. (t) F007 Spent cyanide plating bath solution from electroplating operations. (r,t) 4 - 266 Hazardous Waste Industry and USEPA Hazardous Waste Number Hazardous Waste Hazard Code* F008 Plating bath residues from the bottom of plating baths from electroplating operations where cyanides are used in the process. (r,t) F009 Spent stripping and cleaning bath solutions from electroplating operations when cyanides are used in the process. (r,t) F010 Quenching bath residues from oil baths from metal heat treating operations when cyanides are used in the process. (r,t) F011 Spent cyanide solutions from salt bath pot cleaning from metal heat treating operations. (r,t) F012 Quenching wastewater treatment sludges from metal heat treating operations where cyanides are used in the process. (t) F019 Wastewater treatment sludges from the chemical conversion coating of aluminum except from zirconium phosphating in aluminum can washing when such phosphating is an exclusive conversion coating process. (t) F020 Wastes from use of tri-, or tetrachlorophenol, or intermediates used to produce its pesticide derivatives. ** (h) F021 Wastes of pentachlorophenol or intermediates used to produce its derivatives. ** (h) F022 Wastes, of tetra-, penta-, or hexachlorobenzenes under alkaline conditions. ** (h) F023 Wastes, of tri and tetrachlorophenols. ** (t) F024 Wastes, including but not limited to distillation residues, heavy ends, tars, and reactor cleanout wastes from the production of chlorinated aliphatic hydrocarbons, utilizing free radical catalyzed processes having carbon chain lengths from one to five (omits light ends, spent filters and filter aids, spent desiccants, wastewater, wastewater treatment sludges, spent catalysts and wastes listed in 40 CFR 261.32). (t) F025 Condensed light ends, spent filters aids, and spent desiccant wastes from the production of certain chlorinated aliphatic hydrocarbons, by free radical catalyzed processes. These chlorinated aliphatic hydrocarbons are those having carbon chain lengths ranging from one to and including five, with varying amounts and positions of chlorine substitution. (t) F026 Wastes of tetra-, penta-, or hexachlorobenzene under alkaline conditions. (h) F027 Discarded, unused formulations containing tri-, tetra-, or pentachlorophenol or discarded, unused formulations containing compounds derived from these chlorophenols (does not include hexachlorophene synthesized from prepurified 2,4,5-trichlorophenol as the sole component. (h) 4 - 267 Hazardous Waste Industry and USEPA Hazardous Waste Number Hazardous Waste Hazard Code* F028 Residues from incineration or thermal treatment of soil contaminated with USEPA hazardous waste Nos. F020, F021, F022, F023, F026, and F027. (t) F032 Wastewaters (except those that have not come into contact with process contaminants), process residue, preservative drippage, and spent formulations from wood preserving processes generated at plants that currently use or have previously used chlorophenolic formulations (except potentially cross-contaminated wastes that have had the F032 waste code deleted in accordance with 261.35 and the generator does not resume or initiate use of chlorophenolic formulations). This listing does not include K001 bottom sediment sludge from the treatment of wastewater from wood preserving processes that use creosote and/or pentachlorophenol. (t) F034 Wastewaters (except those that have come into contact with process contaminants), process residuals, preservative drippage, and spent formulations from wood preserving processes generated at plants that use creosote formulations. This listing does not include K001 bottom sludge from the treatment of wastewater from wood preserving processes that use creosote and or phentachlorophenol. (t) F035 Wastewaters (except those that have come into contact with process contaminants), process residuals, preservative drippage, and spent formulations from wood preserving processes generated at plants that use inorganic preservatives containing arsenic or chromium. This listing does not include K001 bottom sediment sludge from the treatment of wastewater from wood preserving processes that use creosote and/or pentachlorophenol. (t) F037 Petroleum refinery primary oil/water/solids separation sludgeAny sludge generated from the gravitational separation of oil/ water/solids during the storage or treatment of process wastewaters and oily cooling wastewaters from petroleum refineries. Such sludges include, but are not limited to, those generated in oil/water/solids separators; tanks and impoundments; ditches and other conveyances; sumps; and stormwater units receiving dry weather flow, sludge generated in stormwater units that do not receive dry weather flow, sludges generated from non-contact once-through cooling waters segregated for treatment from other process or oily cooling waters, sludges generated in aggressive biological treatment units as defined in Sec. 261.31(b)(2) (including sludges generated in one or more additional units after wastewaters have been treated in aggressive biological treatment units) and K051 wastes are not included in this listing. This listing does include residuals generated from processing or recycling oil-bearing hazardous secondary materials excluded under Sec. 261.4(a)(12)(i), if those residuals are to be disposed of. (t) 4 - 268 Hazardous Waste Industry and USEPA Hazardous Waste Number Hazardous Waste Hazard Code* F038 Petroleum refinery secondary (emulsified) oil/water/solids separation sludge--any sludge and/or float generated from the physical and/or chemical separation of oil/water/solids in process wastewaters and oily cooling wastewaters from petroleum refineries. Such wastes include, but are not limited to, all sludges and floats generated in: induced air flotation (IAF) units, tanks and impoundments, and all sludges generated in DAF units. Sludges generated in stormwater units that do not receive dry weather flow, sludges generated from noncontact once- through cooling waters segregated for treatment from other process or oily cooling waters, sludges, and floats generated in aggressive biological treatment units*** (including sludges and floats generated in one or more additional units after wastewaters have been treated in aggressive biological treatment units) and F037, K048, and K051 wastes are not included in this listing. F039 Leachate resulting from the management of one or more of the following wastes and no other hazardous waste retains its hazardous waste number(s): F020, F021, F022, F023, F026, F027, and/or F028. (t) * HAZARD CODES (Column 3) t = toxic waste i = ignitable waste r = reactive waste h = acute hazardous waste ** (Except wastewater and spent carbon from hydrogen chloride purification); the manufacturing or production use: as a reactant, chemical intermediate, or component in a formulating process. The listing for F020 and F023 does not include wastes from the production of hexachlorophene from highly purified 2,4,5-trichlorophenol. *** Aggressive biological treatment units are defined as units that employ one of the following treatment methods: activated sludge; trickling filter; rotating biological contactor for the continuous accelerated biological oxidation of wastewaters; or high-rate aeration. High-rate aeration is a system of surface impoundments or tanks, in which intense mechanical aeration is used to completely mix the wastes, enhance biological activity, and (A) the units employ a minimum of 6 hp per million gallons of treatment volume; and either (B) the hydraulic retention time of the unit is no longer than 5 days; (C) the hydraulic retention time is no longer than 30 days and the unit does not generate a sludge that is a hazardous waste by the toxicity characteristic. NOTE: The listing of wastewaters that have not come into contact with process contaminants is stayed administratively. The listing for plants that have previously used chlorophenolic formulations is administratively stayed whenever these wastes are covered by the F032, F034 or F035 listings. These stays will remain in effect until further administrative action is taken. 4 - 269 Hazardous Waste Appendix 4-1 Table 2 Hazardous Wastes from Specific Sources (40 CFR 261.32) [Revised October 1998, Revised January 2001] Industry and USEPA Hazardous Waste Number Hazardous Waste Hazard Code* Wood Preservation K001 Bottom sediment sludge from the treatment of wastewaters from wood preserving processes that use creosote and /or pentachlorophenol. (t) Inorganic Pigments K002 Wastewater treatment sludge from the production of chrome yellow and organe pigments. (t) K003 Wastewater treatment sludge from the production of molybdate orange pigments. (t) K004 Wastewater treatment sludge from the production of zinc yellow pigments. (t) K005 Wastewater treatment sludge from the production of chrome green pigments. (t) K006 Wastewater treatment sludge from the production of chrome green pigments (anhydrous and hydrated). (t) K007 Wastewater treatment sludge from the production of iron blue pigments. (t) K008 Oven residue from the production of chrome oxide green pigments. (t) Organic Chemicals K009 Distillation bottoms from the production of acetaldehyde from ethylene. (t) K010 Distillation side cuts from the production of acetaldehyde from ethylene. (t) K011 Bottom stream from the wastewater stripper in the production of acrylonitrile. (r,t) K013 Bottom stream from the acetonitrile column in the production of acrylonitrile. (r,t) K014 Bottoms from the acetonitrile purification column in the production of acrylonitrile. (t) K015 Still bottoms from the distillation of benzyl chloride. (t) 4 - 270 Hazardous Waste Industry and USEPA Hazardous Waste Number Hazardous Waste Hazard Code* K016 Heavy ends or distillation residues from the production of carbon tetrachloride. (t) K017 Heavy ends (still bottoms) from the purification column in the production of epichlorohydrin. (t) K018 Heavy ends from fractionation in ethyl chloride production. (t) K019 Heavy ends from the distillation of ethylene dichloride in ethylene dichloride production. (t) K020 Heavy ends from the distillation of vinyl chloride in vinyl chloride monomer production. (t) K021 Aqueous spent antimony catalyst waste from fluoromethanes production. (t) K022 Distillation bottom tars from the production of phenol/acetone from cumene. (t) K023 Distillation light ends from the production of phthalic anhydride from naphthalene. (t) K024 Distillation bottoms from the production of phthalic anhydride from naphthalene. (t) K025 Distillation bottoms from the production of nitrobenzene by the nitration of benzene. (t) K026 Stripping still tails from the production of methyl ethyl pyridines. (t) K027 Centrifuge residue from toluene diisocyanate production. (r,t) K028 Spent catalyst from the hydrochlorinator reactor in the production of 1,1,1trichloroethane. (t) K029 Waste from the product stream stripper in the production of 1,1,1trichloroethane. (t) K030 Column bottoms or heavy ends from the combined production of trichloroethylene and perchloroethylene. (t) K083 Distillation bottoms from aniline production. (t) K085 Distillation of fractionation column bottoms from the production of chlorobenzene. (t) K093 Distillation light ends from the production of phthalic anhydride from orthoxylene. (t) K094 Distillation bottoms from the production of phthalic anhydride from orthoxylene. (t) 4 - 271 Hazardous Waste Industry and USEPA Hazardous Waste Number Hazardous Waste Hazard Code* K095 Distillation bottoms from the production of 1,1,1-trichloroethane. (t) K096 Heavy ends from the heavy ends column from the production of 1,1,1trichloroethane. (t) K103 Process residues from aniline extraction from the production of aniline. (t) K104 Combined wastewater streams generated from nitrobenzene or aniline production. (t) K105 Separated aqueous stream from the reactor product washing step in the production of chlorobenzenes. (t) K107 Column bottoms from product separation from the production of 1,1dimethylhydrazine (UDMH) from carboxylic acid. (C,T) K108 Condensed column overheads from product separation and condensed reactor vent gases from the production of 1,1-dimethylhydrazine (UDMH) from car boxylic acid hydrazides. (I,T) K109 Spent filter cartridges from product purification from production of 1,1-dime thylhydrazine (UDMH) from carboxylic acid hydrazides. (T) K110 Condensed column overheads from intermediate separation from the production of 1,1-dimethylhydrazine (UDMH) from carboxylic acid hydrazides. (T) K111 Product washwaters from the production of dinitrotoluene via nitration of toluene. (c,t) K112 Reaction byproduct water from the drying column in the production of toluenediamine via hydrogenation of dinitrotoluene. (t) K113 Condensed liquid light ends from the purification of toluenediamine in the production of toluenediamine via hydrogenation of dinitrotoluene. (t) K114 Vicinals from the purification of toluenediamine in the production of toluene diamine. (t) K115 Heavy ends from the purification of toluenediamine in the production of toluenediamine via hydrogenation of dinitrotoluene. (t) K116 Organic condensate from the solvent recovery column in the production of toluene diisocyanate via phosgenation of toluenediamine. (t) K117 Wastewater from the reactor vent gas scrubber in the production of ethylene dibromide via bromination of ethene. (t) K118 Spent adsorbent solids from purification of ethylene dibromide in the production of ethylene dibromide via bromination of ethene. (t) 4 - 272 Hazardous Waste Industry and USEPA Hazardous Waste Number Hazardous Waste Hazard Code* K136 Still bottoms from the purification of ethylene dibromide in the production of ethylene dibromide via bromination of ethene. (t) K140 Floor sweepings, off-specification product and spent filter media from the production of 2,4,6-tribromophenol.. (t) K149 Distillation bottoms from the production of alpha- (or methyl) chlorinated toluenes, ring-chlorinated toluenes, benzoyl chlorides, and compounds with mixtures of these functional groups. (This waste does not include still bottoms for the distillation of benzyl chloride.) (t) K150 Organic residuals, excluding spent carbon adsorbent, from the spent chlorine gas and hydrochloric acid recovery processes associated with the production of alpha- (or methyl) chlorinated toluenes, ring -chlorinated toluenes, benoyl chlorides, and compounds with mixtures of these functional groups. (t) K151 Wastewater treatment sludges, excluding neutralization and biological sludges, generated during the treatment of wastewaters from the production of alpha- (or methyl-) chlorinated toluenes, ring-chlorinated toluenes, benzyo; chlorides, and compounds with mixtures of these functional groups. (t) K174 Wastewater treatment sludges from the production of ethylene dichloride or vinyl chloride monomer (including sludges that result from commingled ethylene dichloride or vinyl chloride monomer wastewater and other wastewater), unless the sludges meet the following conditions: (i) they are disposed of in a subtitle C or non- hazardous landfill licensed or permitted by the state or federal government; (ii) they are not otherwise placed on the land prior to final disposal; and (iii) the generator maintains documentation demonstrating that the waste was either disposed of in an on-site landfill or consigned to a transporter or disposal facility that provided a written commitment to dispose of the waste in an off-site landfill. Respondents in any action brought to enforce the requirements of subtitle C must, upon a showing by the government that the respondent managed wastewater treatment sludges from the production of vinyl chloride monomer or ethylene dichloride, demonstrate that they meet the terms of the exclusion set forth above. In doing so, they must provide appropriate documentation (e.g., contracts between the generator and the landfill owner/operator, invoices documenting delivery of waste to landfill, etc.) that the terms of the exclusion were met. (t) K175 Wastewater treatment sludges from the production of vinyl chloride monomer using mercuric chloride catalyst in an acetylene-based process. (t) Inorganic Chemicals K071 Brine purification muds from the mercury cell process in chlorine production, where separately prepurified brine is not used. (t) K073 Chlorinated hydrocarbon waste from the purification step of the diaphragm cell process using graphite anodes in chlorine production. (t) 4 - 273 Hazardous Waste Industry and USEPA Hazardous Waste Number K106 Hazardous Waste Hazard Code* Wastewater treatment sludge from the mercury cell process in chlorine production. (t) Hazardous Waste from Explosives Manufacturing K044 Wastewater treatment sludge from the manufacturing and processing of explosives. (r) K045 Spent carbon from the treatment of wastewater containing explosives. (r) K046 Wastewater treatment sludges from the manufacturing, formulation, and loading of lead-based initiating compounds. (t) K047 Pink/red water from TNT operations. (t) NOTE: Hazardous waste created from the production of pesticides, petroleum refining, coking, ink formulation, the production of: iron and steel, primary copper, primary lead, primary zinc, primary aluminum, ferroalloys, veterinary pharmaceuticals, and secondary lead are not included in this table due to their nonapplicability at Federal facilities. Petroleum Refining K169 Crude oil operations. storage tank sediment from petroleum refining (t) K170 Clarified slurry oil tank sediment and/or in-line filter/separation solids from petroleum refining operations. (t) K171 Spent Hydrotreating catalyst from petroleum refining operations, including guard beds used to desulfurize feeds to other catalytic reactors (this listing does not include inert support media). (i,t) K172 Spent Hydrorefining catalyst from petroleum refining operations, including guard beds used to desulfurize feeds to other catalytic reactors (this listing does not include inert support media). (i,t) * HAZARD CODES (Column 3) t = toxic waste i = ignitable waste r = reactive waste h = acute hazardous waste 4 - 274 Hazardous Waste 4 - 275 Hazardous Waste 4 - 276 Hazardous Waste Appendix 4-2 Commercial Chemical Products or Manufacturing Chemical Intermediates Identified as Toxic Wastes (40 CFR 261.33(f)) [Revised June 1998] (COMMENT: primary hazardous properties of these materials have been indicated by the letter (t) (toxicity), (r) (reactivity), (i) (ignitibility), and (c) (corrosivity); absence of a letter indicates that the compound is only listed for acute toxicity.) USEPA Hazardous Substance Waste Number U394 A2213 U001 acetaldehyde (i) U034 acetaldehyde, trichloro- U187 acetamide, N-(4-ethoxyphenyl)- U005 acetamide, N-9H-fluoren-2-y1- U240 acetic acid, (2,4-dichloropheoxy)-, salts, and esters U112 acetic acid, ethyl ester (i) U144 acetic acid, lead(2+) salt U214 acetic acid, thallium(1+) salt see F027 acetic acid, (2,4,5-trichlorophenoxy)- U002 acetone (i) U003 acetonitrile (i, t) U004 acetophenone U005 2-acetylaminoflourene U006 acetyl chloride (c, r, t) U007 acrylamide U008 acrylic acid (i) U009 acrylonitrile U011 amitrole U012 aniline (i, t) 4 - 277 Hazardous Waste USEPA Hazardous Waste Number Substance U136 arsenic acid, dimethyl- U014 auramine U015 azaserine U010 azirino(2,3,3,4(pyrrolo(1,2-a)indole -4,7-dione, 6-amino8-[((aminocarbonyl)oxy)methyl]-1,1a,2,8,8a,8bhexahydro-8a-methoxy-5-methyl-, U280 barban U278 bendiocarb U364 bendiocarb phenol U271 benomyl U157 benz[j]aceanthrylene, 1,2-dihydro-3- methyl- U016 benza[c]ridine U017 benzal chloride U192 benzamide, 3,5-dichloro-n- (1,1-diethyl-2-propynyl- U018 benz[a]anthracene U094 1,2-benzanthracene, 7,12-dimethyl- U012 benzenamine (i,t) U014 benzenamine, 4,4-carbonimidoylbis(N,N-dimethyl- U049 benzenamine, 4-chloro-2-methyl-,hydrochloride U093 benzenamine, N,N-dimethyl-4-(phenylazo)- U328 benzenamine, 2-methyl- U353 benzenamine, 4-methyl- U158 benzenamine, 4,4-methylenebis(2-chloro- U222 benzenamine, 2-methyl-, hydrochloride U181 benzenamine, 2,-methyl-5-nitro U019 benzene (i, t) U038 benzeneacetic acid, 4-chloro-alpha-(4-chlorophenyl)alpha-hydroxy, ethyl ester 4 - 278 Hazardous Waste USEPA Hazardous Waste Number Substance U030 benzene, 1-bromo-4-phenoxy- U035 benzenebutanoic acid, 4-[bis(2-chloroethyl)amino]- U037 benzene, chloro- U221 benzenediamine, ar-methyl- U028 1,2-benzendicarboxylic acid, [bis(2-ethyl-hexyl)]ester U069 1,2-benzenedicarboxylic acid, dibutyl ester U088 1,2-benzenedicarboxylic acid, diethyl ester U102 1,2-benzendicarboxylic acid, dimethyl ester U107 1,2-benzenedicarboxylic acid, dioctyl ester U070 benzene, 1,2-dichloro- U071 benzene, 1,3-dichloro- U072 benzene, 1,4-dichloro- U060 benzene, 1,1’- (2,2-dichloroethylidene) bis[4-chloro- U017 benzene, (dichloromethyl)- U223 benzene, 1,3-diisocyanatomethyl- (r,t) U239 benzene, dimethyl-(i,t) U201 1,3-benzenediol U127 benzene, hexachloro- U056 benzene, hexahydro- (i) U220 benzene, methyl- U105 benzene, 1-methyl-2,4-dinitro- U106 benzene, 2-methyl-1,3-dinitro- U055 benzene, (1-methylethyl)-(i) U169 benzene, nitro- (i,t) U183 Benzene, pentachloro- U185 benzene, pentachloronitro- 4 - 279 Hazardous Waste USEPA Hazardous Waste Number Substance U020 benzenesulfonic acid chloride (c,r) U020 benzenesulfonyl chloride (c,r) U207 benzene, 1,2,4,5-tetrachloro- U061 benzene, 1,1’-(2,2,2- trichloroethylidene) bis[4-chloro U247 benzene, 1,1’(2,2,2- trichloroethylidene)[4-methoxy- U023 benzene, (trichloromethyl)- U234 benzene, 1,3,5-trinitro- U021 benzidine U202 1,2-benzisothiazolin-3-one, 1,1-dioxide, and salts U278 1,3-benzodioxol-4-ol, 2,2-dimethyl-, methyl carbamate U364 1,3-benzodioxol-4-ol, 2,2-dimethyl-, U203 1,3-benzodioxole, 5-(2-propenyl)- U141 1,3-benzodioxole, 5-(1-propenyl)- U090 1,3-benzodioxole, 5-propyl- U367 benzofuranol, 2,3-dihydro-2,2-dimethyl- U064 benzo[rst]pentaphene U248 2-H-1-benzopyran-2-on2, 4-hydroxy-3-(3-oxo-1phenylbutyl)-, and salts, when present at concentrations of 0.3% or less U022 benzo[a]pyrene U197 p-benzoquinone U023 benzotrichloride (c,r,t) U085 2,2-bioxirane U021 (1,1-biphenyl)-4,4-diamine U073 (1,1-biphenyl)-4,4-diamine, 3,3-dichloro U091 (1,1-biphenyl)-4,4-diamine, 3,3- dimethoxy- U095 (1,1-biphenyl)4,4-diamine, 3,3- dimethyl- 4 - 280 Hazardous Waste USEPA Hazardous Waste Number Substance U225 bromoform U030 4-bromophenyl phenyl ether U128 1,3-butadiene, 1,1,2,3,4,4- hexachloro U172 1-butanamine, N-butyl-N-nitroso- U031 1-butanol (i) U159 2-butanone (i,t) U160 2-butanone peroxide (r,t) U053 2-butenal U074 2-butene, 1,4-dichloro- (i,t) U143 2-butenoic acid, 2-methyl-, 7- [(2,3-dihydroxy-2-(1methoxyethyl) -3-methyl-1-oxobutoxy)methyl] -2,3,5,7syrytshyfto-1- pyrrolizin-1-yl ester, [1S-[alpha(Z),7(2S,3R), 7aalpha]]- U031 n-Butyl alcohol (i) U136 cacodylic acid U032 calcium chromate U372 carbamic acid, 1H0benzimidazol-2-yl, methyl ester U271 carbamic acid, [1-[(butylamino)carbonyl)-1Hbenzimidazol-2-yl]-, methyl ester U280 carbamic acid, (3-chlorophenyl)-, 4-chloro-2-butynyl ester U238 carbamic acid, ethyl ester U178 carbamic acid, methylnitroso- ethyl ester U373 carbamic acid, phenyl-, 1-methylethyl ester U409 carbamic acid, [1,2-phenylenebis (iminocarbonothioyl)]bis-, dimethyl ester U097 carbamic chloride, dimethyl- U114 carbamodithioic acid, 1,2- ethanediylbis-, salts and esters U062 carbamothioic acid, bis(1-methylethyl)-S- (2,3-dichloro-2propenyl) ester 4 - 281 Hazardous Waste USEPA Hazardous Waste Number Substance U389 carbamothioic acid, bis(1-methylethyl)-S-(2,3,3-trichloro2-propenyl) ester U387 carbamothioic acid, dipropyl-, S-(phenylmethyl) ester U279 carbaryl U372 carbendazim U367 carbofuran phenol U215 carbonic acid, dithallium(1+)salt U033 carbonic difluoride U156 carbonochlorodic acid, methyl ester (i,t) U033 carbon oxyfluoride (r,t) U211 carbon tetrachloride U034 chloral U035 chlorambucil U036 chlordane, alpha and gamma isomers U026 chlomaphazine U037 chlorobenzene U039 p-chloro-m-cresol U042 2-chloroethyl vinyl ether U044 chloroform U046 chloromethyl methyl ether U047 beta-chloronaphthalene U048 o-chlorophenol U049 4-chloro-o-toluidine, hydrochloride U032 chromic acid H2CrO4, calcium salt U050 chrysene U051 creosote U052 cresols (cresylic acid) 4 - 282 Hazardous Waste USEPA Hazardous Waste Number Substance U053 crotonaldehyde U055 cumene (i) U246 cyanogen bromide U197 2,5-cyclohexadiene-1, 4-dione U056 cyclohexane (i) U129 cyclohexane 1,2,3,4,5,6- hexachloro-, (1alpha, 2alpha, 3beta, 4alpha, 6beta)- U057 cyclohexanone (i) U130 1,3-cyclopentadiene, 1,2,3,4,5,5- hexachloro- U058 cyclophosphamide U240 2,4-d, salts, and esters U059 daunomycin U060 DDD U061 DDT U062 diallate U063 dibenz[a,h]anthracene U064 dibenzo[a,i]pyrene U066 1,2-dibromo-3-chloropropane U069 dibutyl phthalate U070 o-Dichlorobenzene U071 m-Dichlorobenzene U072 p-Dichlorobenzene U073 3,3’-dichlorobenzidine U074 1,4-dichloro-2-butene (i,t) U075 dichlorodifluoromethane U078 1,1-dichloroethylene U079 1,2-dichloroethylene 4 - 283 Hazardous Waste USEPA Hazardous Waste Number Substance U025 dichloroethyl ether U027 dichloroisopropyl ether U024 dichloromethoxy ethane U081 2,4-dichlorophenol U082 2,6-dichlorophenol U084 1,3-dichlorpropene U085 1,2:3,4-diepoxybutane (i,t) U395 diethylene glycol, dicarbamate U108 1,4-diethyleneoxide U028 diethylhexyl phthalate U086 N,N-diethylhydrazine U087 O,O-diethyl-s-methyl dithiophosphate U088 diethyl phthalate U089 diethylstilbestrol U090 dihydrosafrole U091 3,3’-dimethoxybenzidine U092 dimethylamine (i) U093 dimethylaminoazobenzene U094 7,12-dimethylbenz[a]anthracene U095 3,3-dimethylbenzidine U096 alpha,alpha-dimethylbenzylhydroperoxide (r) U097 dimethylcarbamoyl chloride U098 1,1-dimethylhydrazine U099 1,2-dimethylhydrazine U101 2,4-dimethylphenol U102 dimethyl phthalate 4 - 284 Hazardous Waste USEPA Hazardous Waste Number Substance U103 dimethyl sulfate U105 2,4-dinitrotoluene U106 2,6-dinitrotoluene U107 di-n-octyl phthalate U108 1,4-dioxane U109 1,2-diphenylhydrazine U110 dipropylamine (i) U111 di-n-propylnitrosamine U041 epichlorhydrin U001 ethanal (i) U404 ethanamine, N,N-diethyl- U174 ethanamine, N-ethyl-N-nitroso- U155 1,2-ethanediamine, n,n- dimethyl-n’-2-pyridinyl- n’-(2thienylmethyl)- U067 ethane, 1,2-dibromo- U076 ethane, 1,1-dichloro- U077 ethane, 1,2-dichloro- U131 ethane, hexachloro- U024 ethane, 1,1-[methylenebis(oxy)] bis[2-chloro- U117 ethane, 1,1-oxybis- (i) U025 ethane 1,1-oxybis[2-chloro- U184 ethane, pentachloro- U208 ethane, 1,1,1,2-tetrachloro- U209 ethane, 1,1,2,2-tetrachloro- U218 ethanethioamide U226 ethane, 1,1,1-trichloro U359 ethane, 1,1,2-trichloro- 4 - 285 Hazardous Waste USEPA Hazardous Waste Number Substance U227 ethane, trichloro U410 ethanimidothioic acid, N,N’[thiobis[(methylimino)carbonyloxy]]bis-, dimethyl ester U394 ethanimidothioic acid, 2-(dimethylamino)-N-hydroxy-2oxo-, methyl ester U359 ethanol, 2-ethoxy- U173 ethanol, 2,2’-(nitrosoimino)bis- U395 Ethanol, 2,2’poxybis-, dicarbamate U004 ethanone, 1-phenyl- U043 ethene, chloro- U042 ethene, (2-chloroethoxy-) U078 ethene, 1,1-dichloro- U079 ethene, 1,2-dichloro- (e) U210 ethene, tetrachloro- U228 ethene, trichloro U112 ethyl acetate (i) U113 ethyl acrylate (i) U238 ethyl carbamate (urethane) U117 ethyl ether (i) U114 ethylenebisdithiocarbamic acid, salts, and esters U067 ethylene dibromide U077 ethylene dichloride U359 ethylene glycol monoethyl ether U115 ethylene oxide (i,t) U116 ethylenethiourea U076 ethylidene dichloride U118 ethyl methacrylate 4 - 286 Hazardous Waste USEPA Hazardous Waste Number Substance U119 ethyl methanesulfonate U120 fluoranthene U122 formaldehyde U123 formic acid (c,t) U124 furan (i) U125 2-furancarboxaldehyde (i) U147 2,5-furandione U213 furan, tetrahydro- (i) U125 furfural (i) U124 furfuran (i) U206 glucopyranose, 2-deoxy-2 (3-methyl-3-nitrosoureido)- U126 glycidylaldehyde U163 guanidine, N-methyl-N’-nitro- N-nitroso- U127 hexachlorobenzene U128 hexachlorobutadiene U130 hexachlorocyclopentadiene U131 hexachloroethane U132 hexachlorophene U243 hexachloropropene U133 hydrazine (r,t) U086 hydrazine, 1,2-diethyl- U098 hydrazine, 1,1-dimethyl- U099 hydrazine, 1,2-dimethyl- U109 hydrazine, 1,2-diphenyl- U134 hydrofluoric acid (c,t) U134 hydrogen fluoride (c,t) 4 - 287 Hazardous Waste USEPA Hazardous Waste Number Substance U135 hydrogen sulfide U135 hydrogen sulfide U096 hydroperoxide, 1-methyl-1-phenylethyl- (r) U116 2-imidazolidinethione U137 indeno(1,2,3-cd)pyrene U190 1,3-isobenzofurandione U140 isobutyl alcohol (i,t) U141 isosafrole U142 kepone U143 lasiocarpine U144 lead acetate U146 lead, bis(acetato-O) tetrahydroxytri- U145 lead phosphate U146 lead subacetate U129 lindane U163 mnng U147 maleic anhydride U148 maleic hydrazide U149 malononitrile U150 melphalan U151 mercury U152 methacrylonitrile (i,t) U092 methanamine (N-methyl- (i) U029 methane, bromo- U045 methane, chloro- (i,t) U046 methane, chloromethoxy- 4 - 288 Hazardous Waste USEPA Hazardous Waste Number Substance U068 methane, dibromo- U080 methane, dichloro- U075 methane, dichlorodifluoro- U138 methane, iodo- U119 methanesulfonic acid, ethyl ester U211 methane, tetrachloro- U153 methanethiol (i,t) U225 methane, tribromo- U044 methane, trichloro- U121 methane, trichlorofluoro- U036 4-7-Methano-1Hindene, 2,3,3a,4,7,7a-hexahydro U154 methanol (i) U155 methapyrilene U142 1,3,4-metheno-2Hcyclobuta[cd]pentalen-2-one1,1a,3,3a,4,5,5,5a,5b,6- decachlorooctahydro- U247 methoxychlor U154 methyl alcohol (i) U029 methyl bromide U186 1-methylbutadiene (i) U045 methyl chloride (i,t) U156 methyl chlorocarbonate (i,t) U226 methyl chloroform U157 3-methylcholanthrene U158 4,4-methylenebis-(2-chloroaniline) U068 methylene bromide U080 methylene chloride 1,2,4,5,6,7,8,8-ocachloro- 4 - 289 Hazardous Waste USEPA Hazardous Waste Number Substance U159 methyl ethyl ketone (mek) (i,t) U160 methyl ethyl ketone peroxide (r,t) U138 methyl iodide U161 methyl isobutyl ketone (i) U162 methyl methacrylate (i,t) U161 4-methyl-2-pentanone (i) U164 methylthiouracil U010 mitomycin C U059 5,12-Naphthacenedione, (Bs(cis)8- acetyl-10-[(3-amino2,3,6-trideoxy- alpha-L-lyxo-hexopyranosyl)oxyl]- 78,9,10-tetrahydro-6,8,11- trihydroxy-1-methoxy- U167 1-naphthalenamine U168 2-naphthalenamine U026 naphthalenamine, N,N’-bis (2-chloroethyl)- U165 naphthalene U047 naphthalene, 2-chloro- U166 1,4-naphthalenedione U236 2,7-naphthalenedisulfonic acid, 3,3’-[(3,3’-dimethyl-(1,1’biphenyl)-bis(azo)bis(5-amino-4-hydroxy)-, tetrasodium salt U279 1-Naphthalenol, methylcarbamate U166 1,4-Naphthoquinone U167 alpha-naphthylamine U168 beta-naphthylamine U217 nitric acid, thallium(1+) salt (2-chloromethyl)- U169 nitrobenzene (i,t) U170 p-nitrophenol U171 2-nitropropane (i,t) 4 - 290 Hazardous Waste USEPA Hazardous Waste Number Substance U172 n-nitrosodi-n-butylamine U173 n-nitrosodiethanolamine U174 n-nitrosodiethylamine U176 n-nitroso-n-ethylurea U177 n-nitroso-n-methylurea U178 n-nitroso-n-methylurethane U179 n-nitrosopiperidine U180 n-nitrosopyrrolidine U181 5-nitro-o-toluidine U193 1,2-oxathiolane, 2,2-dioxide U058 2H-1,3,2-Oxazaphosphorine,2[bis(2chloroethyl)amino]tetrahydro-, 2-oxide. U115 oxirane (i,t) U126 oxiranecarboxyaldehyde U041 oxirane, 2-(chloromethyl)- U182 paraldehyde U183 pentachlorobenzene U184 pentachloroethane U185 pentachloronitrobenzene see F027 pentachlorophenol U161 pentanol, 4-methyl- U186 1,3-pentadiene (i) U187 phenacetin U188 phenol U048 phenol, 2-chloro- U039 phenol, 4-chloro-3-methyl- U081 phenol, 2,4-dichloro- 4 - 291 Hazardous Waste USEPA Hazardous Waste Number Substance U082 phenol, 2,6-dichloro- U089 phenol, 4,4’-(1,2-diethyl- 1,2-ethenediyl)bis-, U101 phenol, 2,4-dimethyl- U052 phenol, methyl U132 phenol, 2,2’-methylenebis [3,4,6-trichloro- U411 phenol, 2-(1-methylethoxy)-, methylcarbamate U170 phenol, 4-nitro- see F027 phenol, pentachloro- see F027 phenol, 2,3,4,6-tetrachloro- see F027 phenol, 2,4,5-trichloro- see F027 phenol, 2,4,6-trichloro- U150 l-phenylalanine, 4- [bis(2-chloroethyl)amino]- U145 phosphoric acid, lead salt U087 phosphorodithioic acid, 0,0-diethyl S-methyl ester U189 phosphorus sulfide (r) U190 phthalic anhydride U191 2-picoline U179 piperidine, 1-nitroso- U192 pronamide U194 1-propanamine (i,t) U111 1-propanamine, n-nitroso-n-propyl- U110 1-propanamine, n-propyl- (i) U066 propane, 1,2-dibromo-3-chloro- U083 propane, 1,2-dichloro- U149 propanedinitrile U171 propane, 2-nitro- (i,t) 4 - 292 Hazardous Waste USEPA Hazardous Waste Number Substance U027 propane, 2,2-oxybis[2-chloro- U193 1,3-propane sultone see F027 propanoic acid, 2-(2,4,5- trichlorophenoxy)- U235 1-propanol, 2,3-dibromo-, phosphate (3:1) U140 1-propanol, 2-methyl- (i,t) U002 2-propanone (i) U007 2-propenamide U084 1-propene, 1,3-dichloro- U243 1-propene, 1,1,2,3,3,3-hexachloro- U009 2-propenenitrile U152 2-propanenitrile, 2-methyl- (i,t) U008 2-propenoic acid (i) U113 2-propenic acid, ethyl ester (i) U118 2-propenoic acid, 2-methyl-, ethyl ester U162 2-propenoic acid, 2-methyl-, methyl ester (i,t) U373 Propham U411 Propoxur U194 n-propylamine (i,t) U083 propylene dichloride U387 Prosulfocarb U148 3,6-pyridazinedione, 1,2-dihydro- U196 pyridine U191 pyridine, 2-methyl- U237 2,4(1H,3H)-pyrimidinedione, 5-[bis(2-chloroethyl)amino]- U164 4(1H)-pyrimidinone, 2,3-dihydro-6-methyl 2-thioxo- U180 pyrrolidine, 1-nitroso- 4 - 293 Hazardous Waste USEPA Hazardous Waste Number Substance U200 reserpine U201 resorcinol U202 saccharin and salts U203 safrole U204 selenious acid U204 selenium dioxide U205 selenium sulfide U205 selenium sulfide SeS2 (r,t) U015 l-serine, diazoacetate (ester) see F027 silvex (2,4,5-tp) U206 streptozotocin U103 sulfuric acid, dimethyl ester U189 sulfur phosphide (r) see FO27 2,4,5-T U207 1,2,4,5-tetrachlorobenzene U208 1,1,1,2-tetrachloroethane U209 1,1,2,2-tetrachloroethane U210 tetrachloroethylene see F027 2,3,4,6-tetrachlorophenol U213 tetrahydrofuran (i) U214 thallium (i) acetate U215 thallium (i) carbonate U216 thallium chloride U216 thallium chloride Tlcl U217 thallium (i) nitrate U218 thioacetamide 4 - 294 Hazardous Waste USEPA Hazardous Waste Number Substance U410 thiodicarb U153 thiomethanol (i,t) U244 thioperoxydicarbonic diamide, tetramethyl- U409 thiophanate-methyl U219 thiourea U244 thiuram U220 toluene U221 toluenediamine U223 toluene diisocyanate (r,t) U328 o-toluidine U353 p-toluidine U222 o-toluidine hydrochloride U389 triallate U011 1H-1,2,4-triazol-3-amine U408 2.4.6. tribromophenol U227 1,1,2-trichloroethane U228 trichloroethylene U121 trichloromonofluoromethane See F023 2,4,5-trichlorophenol See F023 2,4,6-trichlorophenol U404 triethylamine U234 1,3,5-trinitrobenzene (r,t) U182 1,3,5-trioxane, 2,4,6-trimethyl- U235 tris(2,3-dibromopropyl)phosphate U236 trypan blue U237 uracil mustard 4 - 295 Hazardous Waste USEPA Hazardous Waste Number Substance U176 urea, n-ethyl-n-nitroso- U177 urea, n-methyl-n-nitroso- U043 vinyl chloride U248 Warfarin, when present at concentrations of .3% or less U239 xylene (i) U200 yohimban-16-carboxylic acid, 11,17-dimethoxy-18-[(3,4, 5-trimethoxy-benzoyl)oxy], methyl ester U249 Zinc phosphide, when present at concentrations of 10% or less 4 - 296 Hazardous Waste Appendix 4-3 Toxicity Characteristics Constituents and Regulatory Levels (40 CFR 261.24) USEPA HW No. Constituent CAS No Regulatory level (mg/L) D004 D005 D018 D006 D019 D020 D021 D022 D007 D023 D024 D025 D026 D016 D027 D028 D029 D030 D012 D031 D032 D033 D034 D008 D013 D009 D014 D035 D036 D037 D038 D010 D011 D039 D015 D040 D041 D042 D017 D043 Arsenic Barium Benzene Cadmium Carbon tetrachloride Chlordane Chlorobenzene Chloroform Chromium o-Cresol m-Cresol p-Cresol Cresol 2,4-D 1,4-Dichlorobenzene 1,2-Dichloroethane 1,1-Dichloroethylene 2,4-Dinitrotoluene Endrin Heptachlor (and its hydroxide) Hexachlorobenzene Hexachloro-1,3-butadiene Hexachloroethane Lead Lindane Mercury Methoxychlor Methyl ethyl ketone Nitrobenzene Pentachlorophenol Pyridine Selenium Silver Tetrachloroethylene Toxaphene Trichloroethylene 2,4,5-Trichlorophenol 2,4,6-Trichlorophenol 2,4,5-TP (Silvex) Vinyl chloride 7440-38-2 7440-39-3 71-43-2 7440-43-9 56-23-5 57-74-9 108-90-7 67-66-3 7440-47-3 95-48-7 108-39-4 106-44-5 5.0 100.0 0.5 1.0 0.5 0.03 100.0 6.0 5.0 200.0 1 200.0 1 200.0 1 200.0 1 10.0 7.5 0.5 0.7 0.13 2 0.02 0.008 0.13 2 0.50 3.0 5.0 0.4 0.2 10.0 200.0 2.0 100.0 5.0 2 1.0 5.0 0.7 0.5 0.5 400.0 2.0 1.0 0.2 94-75-7 106-46-7 107-06-2 75-35-4 121-14-2 72-20-8 76-44-8 118-74-1 87-68 67-72-1 7439-92-1 58-89-9 7439-97-6 72-43-5 78-93-3 98-95-3 87-86-5 110-86-1 7782-49-2 7440-22-4 127-18-4 8001-35-2 79-01-6 95-95-4 88-06-2 93-72-1 75-01-4 1 If o-, m-, and p-cresol concentrations cannot be differentiated, the total cresol (D026) concentration is used. Quantitation limit is greater than the calculated regulatory level. Therefore, the quantitation limit becomes the regulatory level. 2 4 - 297 Hazardous Waste 4 - 298 Hazardous Waste Appendix 4-4 This Appendix has been deleted. 4 - 299 Hazardous Waste 4 - 300 Hazardous Waste Appendix 4-5 Commercial Chemical Products or Manufacturing Chemical Intermediates Identified as Acute Hazardous Waste (40 CFR 261.33(a) through 261.33(e)) (COMMENT: Primary hazardous properties of these materials have been indicated by the letters (t) (toxicity), and (r) (reactivity); absence of a letter indicates that the compound only is listed for acute toxicity.) Hazardous Waste Number P023 P002 P057 P058 P002 P003 P070 P203 P004 P005 P006 P007 P008 P009 P119 P099 P010 P012 P011 P011 P012 P038 P036 P054 P067 P013 P024 P077 P028 P042 P046 P014 P127 P188 P001 P028 P015 P016 P017 Substance Acetaldehyde, chloroAcetamide, N-(aminothioxomethyl)Acetamide, 2-fluoroAcetic acid, fluoro-, sodium salt 1-Acetyl-2-thiourea Acrolein Aldicarb Aldicarb sulfone Aldrin Allyl alcohol Aluminum phosphide 5-(Aminomethyl)-3-isoxazolol 4-Aminopyridine Ammonium picrate Ammonium vanadate Argebtate(1), bis(cyano-C)-, potassium Arsenic acid H3AsO4 Arsenic oxide As2O3 Arsenic oxide As2O5 Arsenic pentoxide Arsenic trioxide Arsine, diethyl Arsonous dichloride, phenyl Aziridine Aziridine, 2-methyl Barium cyanide Benzenamine, 4-chloroBenzenamine, 4-nitroBenzene, (chloromethyl)1,2-Benzenediol, 4-[1-hydroxy2(methylamino)ethyl]Benzeneethanamine, alpha,alpha- dimethylBenzenethiol 7-Benzofuranol, 2,3-dihydro-2,2-dimethyl)-, methylcarbamate Benzoic Acid 2H-1-Benzopyran-2-one,4-hydroxy-3- (3-oxo1-phenylbutyl)-, and salts when present at concentrations greater than 0.3% Benzyl chloride Beryllium powder Bis(chloromethyl)ether Bromoacetone (r,t) (r) (r) (r) 4 - 301 Hazardous Waste Hazardous Waste Number P018 P045 P021 P021 P189 P191 P192 P193 P127 P022 P095 P189 P023 P024 P026 P027 P029 P029 P202 P030 P031 P033 P033 P034 P016 P036 P037 P038 P041 P040 P043 P004 P060 P037 P051 P044 P045 P046 P191 P047 P048 Substance Brucine 2-Butanone, 3,3-dimethyl-1-(methylthio)-, O-(methylamino)carbonyl) oxime Calcium cyanide Calcium cyanide Ca(CN)2 Carbamic acid Carbamic acid, dimethyl, Carbamic Acid, dimethyl, 3-methyl-1-(1methylethyl)-1H-pyrazol-5y) ester Carbamic Acid, methyl, 3-methylphenyl ester Carbofuran Carbon disulfide Carbonic dichloride Carbosulfan Chloroacetaldehyde p-Chloroaniline 1-(o-Chlorophenyl)thiourea 3-Chloropropionitrile Copper cyanide Copper cyanide Cu(CN) m-Cumenyl methylcarbamate Cyanides (soluble cyanide salts), n.o.s. Cyanogen Cyanogen chloride Cyanogen chloride (CN)Cl 2-Cyclohexyl-4,6-dinitrophenol Dichloromethyl ether Dichlorophenylarsine Dieldrin Diethylarsine Diethyl-p-nitrophenyl phosphate O,O-Diethyl O-pyrazinyl phosphorothioate Diisopropyl fluorophosphate (DEP) 1,4:5,8-Dimethanonapthalene, 1,2,3,4,10,10hexachloro-1,4,4a,5,8,8a- hexahydro-,(1alpha, 4alpha,4abeta,5alpha, 8alpha,8abeta)1,4:5,8-Dimethanonapthalene, 1,2,3,4,10,10hexachloro-1,4,4a,5,8,8a- hexahydro-, (1alpha, 4alpha,4abeta,5beta, 8beta,8abeta)2,7:3,6-Dimethanonapth[2,3b]oxirane, 3,4,5,6,9,9-hexachloro-1a,2,2a,3, 6,6a,7,7aoctahydro-,(1-aalpha,2beta,2aalpha,3beta, 6beta,6aalpha, 7beta,7aalpha)2,7:3,6-Dimethanonapth[2,3b]oxirane, octahydro-,(1aalpha,2beta,2abeta,3alpha, 6alpha, 6abeta,7beta,7aalpha)Dimethoate 3,3-Dimethyl-1-(methylthio)-2-butanone, O[(methylamino)carbonyl]oxime alpha,alpha-Dimethylphenethylamine Dimetilan 4,6-Dinitro-o-cresol and salts 2,4-Dinitrophenol 4 - 302 Hazardous Waste Hazardous Waste Number P020 P085 P111 P039 P049 P185 P050 P088 P051 P051 P042 P031 P066 P194 P101 P054 P097 P056 P057 P058 P198 P197 P065 P059 P062 P116 P068 P063 P063 P096 P064 P060 P192 P202 P007 P196 P196 P092 P065 P082 P197 P064 P016 P112 P118 P050 Substance Dinoseb Diphosphoramide, octamethylDiphosphoric acid, tetraethyl ester Disulfoton Dithiobiuret 1,3-Dithiolane-2-carboxaldehyde, 2,4-dimethyl, O-[(methylamino)-carbonyl]oxime Endosulfan Endothall Endrin Endrin and metabolites Epinephrine Ethanedinitrile Ethanimidothioic acid, N[[(methylamino)carbony] oxy]-, methyl ester Ethanimidothioic acid, 2-(dimethylamino)-N[[(methylamino) carbonyl]oxy]-2-oxo-, methyl ester Ethyl cyanide Ethyleneimine Famphur Fluorine Fluoroacetamide Fluoroacetic acid, sodium salt Formetanate hydrochloride Formparanate Fulminic acid, mercury(2+)salt Heptachlor Hexaethyl tetraphosphate Hydrazinecarbothioamide Hydrazine, methylHydrocyanic acid Hydrogen cyanide Hydrogen phosphide Isocyanic acid, methyl ester Isodrin Isolan 3-Isopropylphenyl N-methylcarbamate 3(2H)-Isoxazolone, 5-(aminomethyl)Manganese, bis(dimethylcarbam Manganese dimethyldithiocarbamate Mercury (acetato-O)phenylMercury fulminate Methanamine, N-methyl-N-nitroso Methanimidamide, N,N-dimethyl-N’-[2methyl-4-[[(methylamino)carbonyl]oxy]phenyl) Methane, isocyanatoMethane, oxybis[chloroMethane, tetranitroMethanethiol, trichloro6,9-Methano-2,4,3-benzodioxathlepen, 6,7,8,9,10,10-hexachloro-1,5,5a,6,9,9ahexahydro-,3-oxide (r,t) (r,t) (r) 4 - 303 Hazardous Waste Hazardous Waste Number P059 P199 P066 P068 P064 P069 P071 P190 P199 P072 P073 P073 P074 P074 P075 P076 P077 P078 P076 P078 P081 P082 P084 P074 P085 P087 P087 P088 P194 P089 P034 P128 P199 P048 P047 P202 P201 P020 P009 P092 P093 P094 P095 P096 P041 P039 Substance 4,7-Methano-1H-indene, 1,4,5,6,7,8,8heptachloro-3a,4,7,7a-tetrahydroMethiocarb Methomyl Methyl hydrazine Methyl isocyanate 2-Methyllactonitrile Methyl parathion Metolcarb Mexacarbate alpha-Naphthylthiourea Nickel carbonyl Nickel carbonyl, (T-4)Nickel cyanide Nickel cyanide Ni (CN)2 Nicotine and salts Nitric oxide p-Nitroaniline Nitrogen dioxide Nitrogen oxide NO Nitrogen oxide Nitroglycerine N-Nitrosodimethylamine N-Nitrosomethylvinylamine Nickel cyanide Octamethylpyrophosphoramide Osmium oxide Osmium tetroxide 7-Oxabicyclo[2.2.1]heptane-2,3- dicarboxylic acid Oxamyl Parathion Phenol, 2-cyclohexyl-4,6-dinitro Phenol, 4-(dimethylamino)-3,5-dimethyl-, methylcarbamate (ester) Phenol, (3,5-dimethyl-4-methylthio)-=, methylcarbamate Phenol, 2,4-dinitro Phenol, 2-methyl-4,6-dinitro- and salts Phenol, 3-(1-methylethyl)-, methyl carbamate Phenol, 3-methyl-5-(1-methylethyl)-, methyl carbamate Phenol, 2-(1-methylpropyl)-4,6-dinitro Phenol, 2,4,6-trinitro-, ammonium salt Phenylmercury acetate Phenylthiourea Phorate Phosgene Phosphine Phosphoric acid, diethyl 4- nitrophenyl ester Phosphorodithioic acid, O,O-diethyl S-[2(ethylthio)ethyl] ester (r) (r) 4 - 304 Hazardous Waste Hazardous Waste Number P094 P044 P043 P089 P040 P097 P071 P204 P188 P110 P098 P098 P099 P201 P203 P070 P101 P027 P069 P081 P017 P102 P003 P005 P067 P102 P008 P075 P204 P114 P103 P104 P104 P105 P106 P106 P108 P018 P108 P115 P109 P110 Substance Phosphorodithioic acid, O,O-diethyl S[(ethylthio)methyl] ester Phosphorodithioic acid, O,O-dimethyl S[2(methylamino)-2-oxoethyl] ester Phosphorofluoric acid, bis(1-methylethyl) -ester Phosphorothioic acid, O,O-diethyl O- (4nitrophenyl) ester Phosphorothioic acid, O,O-diethyl O- pyrazinyl ester Phosphorothioic acid, O-[4-[(dimethylamino) sulfonyl]phenyl] O,O-dimethyl ester Phosphorothioic acid, O,O-dimethyl O- (4nitrophenyl) ester Physostigmine Phosostigmine salicylate Plumbane, tetraethylPotassium cyanide Potassium cyanide K(CN) Potassium silver cyanide Promecarb Propanol, 2-methyl-2-(methyl-sulfonyl)-, O[(methylamino)carbonyl) oxime Propanal, 2-methyl-2-(methylthio)-, O[(methylamino)carbonyl]oxime Propanenitrile Propanenitrile, 3-chloroPropanenitrile, 2-hydroxy-2-methyl 1,2,3-Propanetriol, trinitrate 2-Propanone, 1-bromoPropargyl alcohol 2-Propenal 2-Propen- 1 -ol 1,2-Propylenimine 2-Propyn-1 -ol 4-Pyridinamine Pyridine, (S)-3-(1-methyl-2-pyrrolidinyl)-,(S)-, and salts Pyrrolo(2,3-b)indol-5-ol, 1,2,3a,8,8ahexahydro-1,3a,8-trimethyl-,methylcarbamate (ester), (3aS-cis) Selenious acid, dithallium(1+) salt Selenourea Silver cyanide Silver cyanide Ag(CN) Sodium azide Sodium cyanide Sodium cyanide Na(CN) Strychnidin-10-one, and salts Strychnidin 10-one, 2,3-dimethoxyStrychnine and salts Sulfuric acid, dithallium(l) salt Tetraethyldithiopyrophosphate Tetraethyl lead (r) 4 - 305 Hazardous Waste Hazardous Waste Number P111 P112 P062 P113 P113 P114 P115 P109 P045 P049 P014 P116 P026 P072 P093 P185 P123 P118 P119 P120 P120 P084 P001 P205 P121 P121 P122 P205 Substance Tetraethylpyrophosphate Tetranitromethane (r) Tetraphosphoric acid, hexaethyl ester Thallic oxide Thallium(lll) oxide Thallium(l) selenite Thallium(l) sulfate Thiodiphosphoric acid, tetraethyl ester Thiofanox Thiomidodicarbonic diamide Thiophenol Thiosemicarbazide Thiourea, (2-chlorophenyl)Thiourea, 1-naphthalenylThiourea, phenylTirpate Toxaphene Trichloromethanethiol Vanadic acid, ammonium salt Vanadium oxide V2O3 Vanadium pentoxide Vinylamine, N-methyl-N-nitroso Warfarin, and salts, when present at concentrations greater than 0.3% Zinc, bis(dimethylcarbamodithioato-S,S’)Zinc cyanide Zinc cyanide Zn(CN)2 Zinc phosphide Zn3P2, when present at concentrations greater than 0.10% Ziram 4 - 306 Hazardous Waste Appendix 4-6 Hazardous Waste Storage Incompatibility Chart If the material contains: Substances in bold have detailed example lists on the next page. It may not be stored with any of the following: Acid (pH below 2.0) Caustic (pH above 12.5) Reactive Metals Reactive Organic Compounds and Solvents Spent Cyanide and Sulfide Solutions Oxidizers Caustics (pH above 12.5) Reactive Metals Alcohol Water Aldehydes Halogenated, Nitrated, or Unsaturated Hydrocarbons Reactive Organic Compounds and Solvents Spent Cyanide and Sulfide Solutions Oxidizers Acid (pH below 2.0) Reactive Metals Alcohol Water Aldehydes Halogenated, Nitrated, or Unsaturated Hydrocarbons Reactive Organic Compounds and Solvents Caustics Acids Alcohol Aldehydes Halogenated, Nitrated, or Unsaturated Hydrocarbons Reactive Organic Compounds and Solvents Oxidizers Caustics Acids Reactive Metals Acids Acetic or Other Organic Acids Concentrated Mineral Acids Reactive Metals Reactive Organic Compounds and Solvents Ignitable [Flammable/Combustible] Wastes* * “Ignitable” in this context refers to substances with a flashpoint below 140× oF, and includes: Combustible substances, with a flashpoint below 140× oF Flammable substances, with a flashpoint below 100× oF. Some Deadly Combinations Acids + Oil or Grease = Fire Flammable Liquids + Hydrogen Peroxide = Fire/Explosion Acids + Caustics = Heat/Spattering Aluminum Powder + Ammonium Nitrate = Explosion Caustics + Epoxies = Extreme Heats Sodium Cyanide + Sulfuric Acid = Lethal Hydrogen Cyanide Chlorine Gas + Acetylene = Explosion Ammonia + Bleach = Noxious Fumes In general: Reactives must be segregated from Ignitables Acids must be segregated from Caustics Corrosives should be segregated from Flammables Oxidizers should be segregated from EVERYTHING Many Corrosives are “Water Reactive” 4 - 307 Hazardous Waste Most Organic Reactives must be segregated from Inorganic Reactives (metals) Ignitables (Flammables/Combustibles) Corrosives Acids Carburetor Cleaners Engine Cleaners Epoxy, Resins, Adhesives, and Rubber Cements Finishes Fuels Lacquers Paints Paint Thinners Paint Wastes Pesticides that contain Solvents (such as Methyl Alcohol, Ethyl Alcohol, Isopropyl Alcohol, Toluene, Xylene). Petroleum Solvents (Drycleaning Fluid) Solvents: Acetone Benzene Carbon Tetrachloride (Carbon Tet) Ethanol (Ethyl Alcohol) Ethyl Benzene Isopropanol (Isopropyl Alcohol) Kerosene (Fuel Oil #1) Methanol (Wood Alcohol) Methyl Ethyl Ketone (MEK) Petroleum Distillates Tetrahydrofuran (THF) Toluene (Methacide, Methylbenzene, Methylbenzol, Phenylmethane, Toluol, Antisal 1A) White Spirits (White Spirits, Mineral Spirits, Naptha) Xylene (Xylol) Stains Stripping Agents Varsol Waste Fuels Waste Ink Wax Removers Wood Cleaners Caustics Battery Acids Degreasers and Engine Cleaners Etching Fluids Hydrobromic Acid Hydrochloric Acid (Muriatic Acid) Nitric Acid (<40%) (Aquafortis) Phosphoric Acid Rust Removers Sulfuric Acid (Oil of Vitriol) Acetylene Sludge Alkaline Battery Acids Alkaline Cleaners Alkaline Degreasers Alkaline Etching Fluids Lime and Water Lime Wastewater Potassium Hydroxide (Caustic Potash) Rust Removers Sodium Hydroxide (Caustic Soda, Soda Lye) ___________________________ Reactive Metals __________________________ ___________________________ Reactive Organic Compounds and Solutions ___________________________ Lithium (Batteries) Aluminum Beryllium Calcium Magnesium Sodium Zinc Powder Alcohols Aldehydes Chromic Acids (from chrome plating, copper stripping and aluminum anodizing) Cyanides (from electroplating operations) Hypochlorides (from water treatment plants, swimming pools, sanitizing operations) Organic Peroxides (including Hydrogen Peroxide) Perchlorates Permanganates Sulfides Oxidizers Chlorine Gas Nitric Acid (>40%), aka Red Fuming Nitric Nitrates (Sodium Nitrate, Ammonium Nitrate) Perchlorates Perchloric Acid Perioxides Calcium Hypochlorite (>60%) 4 - 308 Hazardous Waste Appendix 4-7 Recordkeeping, Notification, and/or Certification Requirements for 40 CFR 268 (40 CFR 268, Appendix X) Entity Generator Scenario Frequency Each shipment Recipient of notification Treatment or storage facility Recordkeeping, notification, and/ or certification requirements Notice must include: - USEPA hazardous waste number - constituents of concern - treatability group - manifest number\ - waste analysis data (where avail.) A. Waste does not meet applicable treatment standards, or exceeds applicable prohibition levels (see 268.7(a)(1) B. Waste can be disposed of without further treatment (meets applicable treatment standards or does not exceed prohibition levels upon generation (see 268.7(a)(2)). Each shipment Land disposal facility Notice and certification statement that wastes meets applicable treatment standards or applicable prohibited levels. Notice must include: USEPA hazardous waste number constituents of concern treatability group manifest number\ waste analysis data (where avail.) Certification statement required under 268.7(a)(2)(ii) that waste complies with treatment standards and prohibitions. C. Waste is subject to exemption from a prohibition on the type of land disposal utilized for the waste, such as a caseby- case extension under 268.5, an exemption under 268.6, or a nation-wide capacity variance (see 268.7(a)(3). Each shipment Receiving facility Notice must include: statement that the waste is not prohibited from land disposal USEPA hazardous waste number constituents of concern treatability group manifest number waste analysis data (where avail.) date the waste is subject ton prohibitions. 4 - 309 Hazardous Waste Entity Generator (continued) Scenario Frequency D. Waste is being accumulated in tanks or containers regulated under 40 CFR 262.34 and is being treated in such tanks or containers to meet applicable treatment standards (see 268.7(a)(4)). Minimum of 30 days prior to treatment activity E. Generator is managing a lab pack containing certain wastes and wishes to use an alternative treatment standard (see 268.7(a)(8)). Each shipment F. SQGs with tolling agreements Initial shipment Recipient of notification USEPA Regional Administrator (or designated representative, or authorized State. Delivery must be verified Treatment facility Recordkeeping, notification, and/ or certification requirements Generator must develop, keep onsite, and follow a written waste analysis plan describing procedures used to comply with the treatment standards. If waste is shipped offsite, generator must also comply with notification requirement in 268.7(a)(2). Notice in accordance with 268.7(a)(1), (a)(5),and (a)(6), where applicable. Certification in accordance with 268.7(a)(8). Treatment facility Must comply with applicable notification and certification requirements in 268.7(a) Generator must also retain copy of the notification and certification together with tolling agreement onsite for at least 3 yr after termination or expiration of the agreement. G. Generator has determined waste is a restricted waste based solely on his knowledge of the waste (see 268.7(a) (5)). NA Generator’s file All supporting data must be retained onsite in generator’s files. H. Generator has determine waste is restricted based on testing waste or an extract (see 268.7(a) 5)). NA Generator’s file All waste analysis data must be retained onsite in generators files. I. Generator has determined that waste is excluded from the definition of hazardous or solid waste or exempt from Subtitle C regulation (see 268.7(a)(6)). One time Generator’s file Notice of generation and subsequent exclusion from the definition of hazardous or solid waste, or exemption from Subtitle C regulation, and information regarding the disposition of the waste. 4 - 310 Hazardous Waste Entity Scenario Frequency J. Generator (or treater) claims that hazardous debris is excluded from the definition of hazardous waste under 40 CFR 261.3(f)(1) (see 268.7(d)). One time Recipient of notification USEPA Regional Administrator or authorized State. notification must be updated as necessary under 268.7(d)(2). Recordkeeping, notification, and/ or certification requirements Notice must include: - name and address of Subtitle D facility receiving treated debris USEPA hazardous waste number and description of debris as initially generated technology used to treat the debris. Certification and recordkeeping is in accordance with 268.7(d)(3). Generator (continued) K. Generator (or treater) claims that characteristic wastes are no longer hazardous (see 268.9(d)). One time Generator’s (or treater’s) files and USEPA Regional, Administrator or authorized State. Notifications must be updated as necessary under 268.9(d). Notice must include: name and address of Subtitle D facility receiving treated debris USEPA hazardous waste number and description of debris as initially generated treatability group underlying hazardous constituents. Certification in accordance with 268.9(d)(2). L. Other recordkeeping requirements (see 268.7(a)(7)). Generator’s files NA Generator must retain a copy of all notices, certifications, demonstrations, waste analysis data, and other documentation produced pursuant to 268.7 onsite for at least 5 yr from the date that the waste was last sent to onsite or offsite treatment, storage, or disposal. This period is automatically extended during enforcement actions or as requested by the Administrator. 4 - 311 Hazardous Waste Entity Treatment Facility Scenario Frequency A. Waste shipped from treatment facility to land disposal facility (see 268.7(b)(4) and (b)(5)). Each shipment Recipient of notification Land disposal facility Recordkeeping, notification, and/ or certification requirements Notice must include: USEPA hazardous waste number constituents of concern treatability group manifest number waste analysis data (where avail.) Applicable certification in accordance with 268.7(b)(5)(i), (ii), or (iii), stating that the waste or treatment residue has been treated in compliance with applicable treatment standards and prohibitions. Treatment Facility (continued) B. Waste treatment residue from a treatment or storage facility will be further managed at a different treatment or storage facility (see 268.7(b)(6)). Each shipment Receiving facility Treatment, storage, or disposal facility must comply with all notices and certification requirements applicable to generators. C. Where wastes are recyclable materials used in a manner consisting disposal subject to 266.20(b) (see 268.7(b)(7)). Each shipment Regional Administrator (or delegated representative) No notification to receiving facility required pursuant to 269.7(b)(4). Certification as described in 268.7(b)(5) and notice with information listed in 268.7(b)(4), except manifest number. Recycling facility must keep records of the name and location of each entity receiving hazardous waste-derived products. Land Disposal Facility A. Wastes accepted by land disposal facility (see 268.7(c)). NA NA Maintain copies of notice and certification specified in 268.7(a) and (b). 4 - 312 Hazardous Waste 4 - 313 Hazardous Waste Appendix 4-8 Land Disposal Restricted Wastes and Their Effective Dates (40 CFR 268, Appendix VII) Part 1--Land Disposal Restricted Wastes and Their Effective Dates Waste Code California list California list California list California list California list D001c D001 D002c D003c D004 D004 D005 D006 D007 D008 D008 D009 D009 D010 D011 D012 (that exhibit the toxicity characteristic based on the TCLP)d D013(that exhibit the toxicity characteristic based on the TCLP)d D014(that exhibit the toxicity characteristic based on the TCLP)d D015 (that exhibit the toxicity characteristic based on the TCLP)d D016 (that exhibit the toxicity characteristic based on the TCLP)d Waste Category Effective Date Liquid hazardous wastes, including free liquids associated with solid or sludge, containing free cyanides at concentrations greater than or equal to 1000 mg/L or certain metals or compounds of these metals greater than or equal to the prohibition levels. Liquid (aqueous) hazardous wastes having a pH less than or equal to 2. Dilute HOC wastewaters, defined as HOC-waste mixtures that are primarily water and that contain greater than or equal to 1000 mg/L but less than 10,000 mg/L. Liquid hazardous waste containing PCBs greater than or equal to 50 ppm. Other liquid and nonliquid hazardous wastes containing HOCs in total concentration greater than or equal to 1000 mg. All (except High TOC Ignitable Liquids) High TOC Ignitable Liquids All All Wastewater Nonwastewaters All All All Lead materials before secondary smelting All others Nonwastewater All others All All All 8 July 1987 All 14 Dec 1994 All 14 Dec 1994 All 14 Dec 1994 All 14 Dec 1994 8 July 1987 8 July 1987 8 July 1987 8 Nov 1988 9 Aug 1993 8 Aug 1990 9 Aug 1993 8 July 1996 8 Aug 1992 8 May 1992 8 Aug 1990 8 Aug 1990 8 Aug 1990 8 May 1992 8 Aug 1990 8 May 1992 8 Aug 1990 8 Aug 1990 8 Aug 1990 14 Dec 1994 4 - 314 Hazardous Waste Waste Code D017 (that exhibit the toxicity characteristic based on the TCLP)d D018 D018 D019 D019 D020 D020 D021 D021 D022 D022 D023 D023 D024 D024 D025 D025 D026 D026 D027 D027 D028 D028 D029 D029 D030 D030 D031 D031 D032 D032 D033 D033 D034 D034 D035 D035 D036 D036 D037 D037 D038 D038 D039 D039 D040 D040 D041 D041 D042 Waste Category Effective Date All 14 Dec 1994 Mixed with radioactive wastes All others Mixed with radioactive wastes All others Mixed with radioactive wastes All others Mixed with radioactive wastes All others Mixed with radioactive wastes All others Mixed with radioactive wastes All others Mixed with radioactive wastes All others Mixed with radioactive wastes All others Mixed with radioactive wastes All others Mixed with radioactive wastes All others Mixed with radioactive wastes All others Mixed with radioactive wastes All others Mixed with radioactive wastes All others Mixed with radioactive wastes All others Mixed with radioactive wastes All others Mixed with radioactive wastes All others Mixed with radioactive wastes All others Mixed with radioactive wastes All others Mixed with radioactive wastes All others Mixed with radioactive wastes All others Mixed with radioactive wastes All others Mixed with radioactive wastes All others Mixed with radioactive wastes All others Mixed with radioactive wastes All others Mixed with radioactive wastes 19 Sept 1996 19 Dec 1994 19 Sept 1996 19 Dec 1994 19 Sept 1996 19 Dec 1994 19 Sept 1996 19 Dec 1994 19 Sept 1996 19 Dec 1994 19 Sept 1996 19 Dec 1994 19 Sept 1996 19 Dec 1994 19 Sept 1996 19 Dec 1994 19 Sept 1996 19 Dec 1994 19 Sept 1996 19 Dec 1994 19 Sept 1996 19 Dec 1994 19 Sept 1996 19 Dec 1994 19 Sept 1996 19 Dec 1994 19 Sept 1996 19 Dec 1994 19 Sept 1996 19 Dec 1994 19 Sept 1996 19 Dec 1994 19 Sept 1996 19 Dec 1994 19 Sept 1996 19 Dec 1994 19 Sept 1996 19 Dec 1994 19 Sept 1996 19 Dec 1994 19 Sept 1996 19 Dec 1994 19 Sept 1996 19 Dec 1994 19 Sept 1996 19 Dec 1994 19 Sept 1996 19 Dec 1994 19 Sept 1996 4 - 315 Hazardous Waste Waste Code D042 D043 D043 F001 F001 F002 (1,1,2 -trichloroethane) F002 F002 F003 F003 F004 F004 F005 (benzene, 2-ethoxy ethanol, 2-nitropropane) F005 F005 F006 F006 F006 (cyanides) F007 F008 F009 F010 F011 (cyanides) F011 F012 (cyanides) F012 F019 F020 F021 F025 F026 F027 F028 F032 F032 F033 F033 F034 F034 F037 Waste Category Effective Date All others Mixed with radioactive wastes All others Small quantity generators, CERCLA response/RCRA corrective action, initial generator’s solvent-water mixtures, solvent- containing sludges and solids. All others Wastewater and nonwastewater Small quantity generators, CERCLA response/RCRA corrective action, initial generator’s solvent-water mixtures, solvent- containing sludges and solids. All others Small quantity generators, CERCLA response/RCRA corrective action, initial generator’s solvent-water mixtures, solvent- containing sludges and solids. All others Small quantity generators, CERCLA response/RCRA corrective action, initial generator’s solvent-water mixtures, solvent- containing sludges and solids. All others Wastewater and nonwastewater 19 Dec 1994 19 Sept 1996 19 Dec 1994 8 Nov 1988. Small quantity generators, CERCLA response/RCRA corrective action, initial generator’s solvent-water mixtures, solvent- containing sludges and soils. All others Wastewater Nonwastewater Nonwastewater All All All All Nonwastewater All others Nonwastewater All others All All All All All All All Mixed with radioactive wastes All others Mixed with radioactive wastes All others Mixed with radioactive wastes All others Not generated from surface impoundment cleanouts or closures 8 Nov 1988 8 Nov 1986. 8 Aug 1990 8 Nov 1988 8 Nov 1986 8 Nov 1988 8 Nov 1986 8 Nov 1988 8 Nov 1986 8 Aug 1990 8 Nov 1986 8 Aug 1990 8 Aug 1988 8 July 1989 8 July 1989 8 July 1989 8 July 1989 8 June 1989 8 Dec 1989 8 July 1989 8 Dec 1989 8 July 1989 8 Aug 1990 8 Nov 1988 8 Nov 1988 8 Aug 1990 8 Nov 1988 8 Nov 1988 8 Nov 1988 12 May 1999 12 May 1997 12 May 1999 12 May 1997 12 May 1999 12 May 1997 30 June 1993 4 - 316 Hazardous Waste Waste Code Waste Category Effective Date F037 Generated from surface impoundment cleanouts or closures 30 June 1994 F037 F038 30 June 1994 30 June 1993 F038 Mixed with radioactive wastes Not generated from surface impoundment cleanouts or closures Generated from surface impoundment cleanouts or closures F038 F039 F039 K001 (organics)b K001 K002 K003 K004 K004 K005 K005 K006 K007 K007 K008 K008 K009 K010 K011 K011 K013 K013 K014 K014 K015 K015 K016 K017 K018 K019 K020 K021 K021 K022 K022 K023 K024 K025 K025 K026 K027 K028 (metals) K028 K029 K029 Mixed with radioactive wastes Wastewater Nonwastewater All All others All All Wastewater Nonwastewater Wastewater Nonwastewater All Wastewater Nonwastewater Wastewater Nonwastewater All All Wastewater Nonwastewater Wastewater Nonwastewater Wastewater Nonwastewater Wastewater Nonwastewater All All All All All Wastewater Nonwastewater Wastewater Nonwastewater All All Wastewater Nonwastewater All All Nonwastewater All others Wastewater Nonwastewater 30 June 1994 8 Aug 1990 8 May 1992 8 Aug 1988 8 Aug 1988 8 Aug 1990 8 Aug 1990 8 Aug 1990 8 Aug 1988 8 Aug 1990 8 June 1989 8 Aug 1990 8 Aug 1990 8 June 1989 8 Aug 1990 8 Aug 1988 8 June 1989 8 June 1989 8 Aug 1990 8 June 1989 8 Aug 1990 8 June 1989 8 Aug 1990 8 June 1989 8 Aug 1988 8 Aug 1990 8 Aug 1988 8 Aug 1990 8 Aug 1988 8 Aug 1988 8 Aug 1988 8 Aug 1990 8 Aug 1988 8 Aug 1990 8 Aug 1988 8 June 1989 8 Aug 1988 8 Aug 1990 8 Aug 1988 8 Aug 1990 8 June 1989 8 Aug 1990 8 June 1989 8 Aug 1990 8 June 1989 30 June 1994 4 - 317 Hazardous Waste Waste Code K030 K031 K031 K032 K033 K034 K035 K036 K036 K037b K037 K038 K039 K040 K041 K042 K043 K044 K045 K046 (nonreactive) K046 K047 K048 K048 K049 K049 K050 K050 K051 K051 K052 K052 K060 K060 K061 K061 K062 K069 (noncalcium sulfate) K069 K071 K073 K083 K084 K084 K085 K086 (organics)b K086 K087 K088 K093 K094 K095 Waste Category All Wastewater Nonwastewater All All All All Wastewater Nonwastewater Wastewater Nonwastewater All All All All All All All All Nonwastewater All others All Wastewater Nonwastewater Wastewater Nonwastewater Wastewater Nonwastewater Wastewater Nonwastewater Wastewater Nonwastewater Wastewater Nonwastewater Wastewater Nonwastewater All Nonwastewater All others All All All Wastewater Nonwastewater All All All others All All others All All Wastewater Effective Date 8 Aug 1988 8 Aug 1990 8 May 1992 8 Aug 1990 8 Aug 1990 8 Aug 1990 8 Aug 1990 8 June 1989 8 Aug 1988 8 Aug 1988 8 Aug 1988 8 June 1989 8 June 1989 8 June 1989 8 Aug 1990 8 Aug 1990 8 June 1989 8 Aug 1988 8 Aug 1988 8 Aug 1988 8 Aug 1990 8 Aug 1988 8 Aug 1990 8 Nov 1990 8 Aug 1990 8 Nov 1990 8 Aug 1990 8 Nov 1990 8 Aug 1990 8 Nov 1990 8 Aug 1990 8 Nov 1990 8 Aug 1990 8 Aug 1988 8 Aug 1990 30 Jun 1992 8 Aug 1988 8 Aug 1988 8 Aug 1990 8 Aug 1990 8 Aug 1990 8 Aug 1990 8 Aug 1990 8 May 1992 8 Aug 1990 8 Aug 1988 8 Aug 1988 8 Aug 1988 8 Jan 1997 8 June 1989 8 June 1989 8 Aug 1990 4 - 318 Hazardous Waste Waste Code K095 K096 K096 K097 K098 K099 K100 K100 K101 (organics) K101 (metals) K101 (organics) K101 (metals) K102 (organics) K102 (metals) K102 (organics) K102 (metals) K103 K104 K105 K106 K106 K107 K107 K108 K108 K109 K109 K110 K110 K111 K111 K112 K112 K113 K114 K115 K116 K117 K117 K118 K118 K123 K123 K124 K124 K125 K125 K126 K126 K131 K131 K132 K132 Waste Category Nonwastewater Wastewater Nonwastewater All All All Wastewater Nonwastewater Wastewater Wastewater Nonwastewater Nonwastewater Wastewater Wastewater Nonwastewater Nonwastewater All All All Wastewater Nonwastewater Mixed with radioactive wastes All others Mixed with radioactive wastes All others Mixed with radioactive wastes All others Mixed with radioactive wastes All others Mixed with radioactive wastes All others Mixed with radioactive wastes All others All All All All Mixed with radioactive wastes All others Mixed with radioactive wastes All others Mixed with radioactive wastes All others Mixed with radioactive wastes All others Mixed with radioactive wastes All others Mixed with radioactive wastes All others Mixed with radioactive wastes All others Mixed with radioactive wastes All others Effective Date 8 June 1989 8 Aug 1990 8 June 1989 8 Aug 1990 8 Aug 1990 8 Aug 1988 8 Aug 1990 8 Aug 1988 8 Aug 1988 8 Aug 1990 8 Aug 1988 8 May 1992 8 Aug 1988 8 Aug 1990 8 Aug 1988 8 May 1992 8 Aug 1988 8 Aug 1988 8 Aug 1990 8 Aug 1990 8 May 1992 30 June 1994 9 Nov 1992 30 June 1994 9 Nov 1992 30 June 1994 9 Nov 1992 30 June 1994 9 Nov 1992 30 June 1994 9 Nov 1992 30 June 1994 9 Nov 1992 8 June 1989 8 June 1989 8 June 1989 8 June 1989 30 June 1994 9 Nov 1992 30 June 1994 9 Nov 1992 30 June 1994 9 Nov 1992 30 June 1994 9 Nov 1992 30 June 1994 9 Nov 1992 30 June 1994 9 Nov 1992 30 June 1994 9 Nov 1992 30 June 1994 9 Nov 1992 4 - 319 Hazardous Waste Waste Code K136 K136 K141 K141 K142 K142 K143 K143 K144 K144 K145 K145 K147 K147 K148 K148 K149 K149 K150 K150 K151 K151 K156 K156 K157 K157 K158 K158 K159 K159 K160 K160 K161 K161 P001 P002 P003 P004 P005 P006 P007 P008 P009 P010 P010 P011 P011 P012 P012 P013 (barium) P013 P014 P015 Waste Category Mixed with radioactive wastes All others Mixed with radioactive wastes All others Mixed with radioactive wastes All others Mixed with radioactive wastes All others Mixed with radioactive wastes All others Mixed with radioactive wastes All others Mixed with radioactive wastes All others Mixed with radioactive wastes All others Mixed with radioactive wastes All others Mixed with radioactive wastes All others Mixed with radioactive wastes All others Mixed with radioactive wastes All others Mixed with radioactive wastes All others Mixed with radioactive wastes All others Mixed with radioactive wastes All others Mixed with radioactive wastes All others Mixed with radioactive wastes All others All All All All All All All All All Wastewater Nonwastewater Wastewater Nonwastewater Wastewater Nonwastewater Nonwastewater All others All All Effective Date 30 June 1994 9 Nov 1992 19 Sep 1996 19 Dec 1994 19 Sep 1996 19 Dec 1994 19 Sep 1996 19 Dec 1994 19 Sep 1996 19 Dec 1994 19 Sep 1996 19 Dec 1994 19 Sep 1996 19 Dec 1994 19 Sep 1996 19 Dec 1994 19 Sep 1996 19 Dec 1994 19 Sep 1996 19 Dec 1994 19 Sep 1996 19 Dec 1994 8 Apr 1998 8 Jul 1996 8 Apr 1998 8 Jul 1996 8 Apr 1998 8 Jul 1996 8 Apr 1998 8 Jul 1996 8 Apr 1998 8 Jul 1996 8 Apr 1998 8 Jul 1996 8 Aug 1990 8 Aug 1990 8 Aug 1990 8 Aug 1990 8 Aug 1990 8 Aug 1990 8 Aug 1990 8 Aug 1990 8 Aug 1990 8 Aug 1990 8 May 1992 8 Aug 1990 8 May 1992 8 Aug 1990 8 May 1992 8 Aug 1990 8 June 1989 8 Aug 1990 8 Aug 1990 4 - 320 Hazardous Waste Waste Code P016 P017 P018 P020 P021 P022 P023 P024 P026 P027 P028 P029 P030 P031 P033 P034 P036 P036 P037 P038 P038 P039 P040 P041 P042 P043 P044 P045 P046 P047 P048 P049 P050 P051 P054 P056 P057 P058 P059 P060 P062 P063 P064 P065 P065 P066 P067 P068 P069 P070 P071 P072 P073 Waste Category All All All All All All All All All All All All All All All All Wastewater Nonwastewater All Wastewater Nonwastewater All All All All All All All All All All All All All All All All All All All All All All Wastewater Nonwastewater All All All All All All All All Effective Date 8 Aug 1990 8 Aug 1990 8 Aug 1990 8 Aug 1990 8 June 1989 8 Aug 1990 8 Aug 1990 8 Aug 1990 8 Aug 1990 8 Aug 1990 8 Aug 1990 8 June 1989 8 June 1989 8 Aug 1990 8 Aug 1990 8 Aug 1990 8 Aug 1990 8 May 1992 8 Aug 1990 8 Aug 1990 8 May 1992 8 June 1989 8 June 1989 8 June 1989 8 Aug 1990 8 June 1989 8 June 1989 8 Aug 1990 8 Aug 1990 8 Aug 1990 8 Aug 1990 8 Aug 1990 8 Aug 1990 8 Aug 1990 8 Aug 1990 8 Aug 1990 8 Aug 1990 8 Aug 1990 8 Aug 1990 8 Aug 1990 8 June 1989 8 June 1989 8 Aug 1990 8 Aug 1990 8 May 1992 8 Aug 1990 8 Aug 1990 8 Aug 1990 8 Aug 1990 8 Aug 1990 8 June 1989 8 Aug 1990 8 Aug 1990 4 - 321 Hazardous Waste Waste Code P074 P075 P076 P077 P078 P081 P082 P084 P085 P087 P088 P089 P092 P092 P093 P094 P095 P096 P097 P098 P099 (silver) P099 P101 P102 P103 P104 (silver) P104 P105 P106 P108 P109 P110 P111 P112 P113 P114 P115 P116 P118 P119 P120 P121 P122 P123 P127 P127 P128 P128 P185 P185 P188 P188 P189 Waste Category All All All All All All All All All All All All Wastewater Nonwastewater All All All All All All Wastewater All others All All All Wastewater All others All All All All All All All All All All All All All All All All All Mixed with radioactive wastes All others Mixed with radioactive wastes All others Mixed with radioactive wastes All others Mixed with radioactive wastes All others Mixed with radioactive wastes Effective Date 8 June 1989 8 Aug 1990 8 Aug 1990 8 Aug 1990 8 Aug 1990 8 Aug 1990 8 Aug 1990 8 Aug 1990 8 June 1989 8 May 1992 8 Aug 1990 8 June 1989 8 Aug 1990 8 May 1992 8 Aug 1990 8 June 1989 8 Aug 1990 8 Aug 1990 8 June 1989 8 June 1989 8 Aug 1990 8 June 1989 8 Aug 1990 8 Aug 1990 8 Aug 1990 8 Aug 1990 8 June 1989 8 Aug 1990 8 June 1989 8 Aug 1990 8 June 1989 8 Aug 1990 8 June 1989 8 Aug 1990 8 Aug 1990 8 Aug 1990 8 Aug 1990 8 Aug 1990 8 Aug 1990 8 Aug 1990 8 Aug 1990 8 June 1989 8 Aug 1990 8 Aug 1990 8 Apr 1998 8 Jul 1996 8 Apr 1998 8 Jul 1996 8 Apr 1998 8 Jul 1996 8 Apr 1998 8 Jul 1996 8 Apr 1998 4 - 322 Hazardous Waste Waste Code P189 P190 P190 P191 P191 P192 P192 P194 P194 P196 P196 P197 P197 P198 P198 P199 P201 P201 P202 P202 P203 P203 P204 P204 P205 P205 U001 U002 U003 U004 U005 U006 U007 U008 U009 U010 U011 U012 U014 U015 U016 U017 U018 U019 U020 U021 U022 U023 U024 U025 U026 U027 U028 Waste Category All others Mixed with radioactive wastes All others Mixed with radioactive wastes All others Mixed with radioactive wastes All others Mixed with radioactive wastes All others Mixed with radioactive wastes All others Mixed with radioactive wastes All others Mixed with radioactive wastes All others Mixed with radioactive wastes All others Mixed with radioactive wastes Mixed with radioactive wastes All others Mixed with radioactive wastes All others Mixed with radioactive wastes All others Mixed with radioactive wastes All others All All All All All All All All All All All All All All All All All All All All All All All All All All All Effective Date 8 Jul 1996 8 Apr 1998 8 Jul 1996 8 Apr 1998 8 Jul 1996 8 Apr 1998 8 Jul 1996 8 Apr 1998 8 Jul 1996 8 Apr 1998 8 Jul 1996 8 Apr 1998 8 Jul 1996 8 Apr 1998 8 Jul 1996 8 Apr 1998 8 Jul 1996 8 Apr 1998 8 Apr 1998 8 Jul 1996 8 Apr 1998 8 Jul 1996 8 Apr 1998 8 Jul 1996 8 Apr 1998 8 Jul 1996 8 Aug 1990 8 Aug 1990 8 Aug 1990 8 Aug 1990 8 Aug 1990 8 Aug 1990 8 Aug 1990 8 Aug 1990 8 Aug 1990 8 Aug 1990 8 Aug 1990 8 Aug 1990 8 Aug 1990 8 Aug 1990 8 Aug 1990 8 Aug 1990 8 Aug 1990 8 Aug 1990 8 Aug 1990 8 Aug 1990 8 Aug 1990 8 Aug 1990 8 Aug 1990 8 Aug 1990 8 Aug 1990 8 Aug 1990 8 June 1989 4 - 323 Hazardous Waste Waste Code U029 U030 U031 U032 U033 U034 U035 U036 U037 U038 U039 U041 U042 U043 U044 U045 U046 U047 U048 U049 U050 U051 U052 U053 U055 U056 U057 U058 U059 U060 U061 U062 U063 U064 U066 U067 U068 U069 U070 U071 U072 U073 U074 U075 U076 U077 U078 U079 U080 U081 U082 U083 U084 Waste Category All All All All All All All All All All All All All All All All All All All All All All All All All All All All All All All All All All All All All All All All All All All All All All All All All All All All All Effective Date 8 Aug 1990 8 Aug 1990 8 Aug 1990 8 Aug 1990 8 Aug 1990 8 Aug 1990 8 Aug 1990 8 Aug 1990 8 Aug 1990 8 Aug 1990 8 Aug 1990 8 Aug 1990 8 Aug 1990 8 Aug 1990 8 Aug 1990 8 Aug 1990 8 Aug 1990 8 Aug 1990 8 Aug 1990 8 Aug 1990 8 Aug 1990 8 Aug 1990 8 Aug 1990 8 Aug 1990 8 Aug 1990 8 Aug 1990 8 Aug 1990 8 June 1989 8 Aug 1990 8 Aug 1990 8 Aug 1990 8 Aug 1990 8 Aug 1990 8 Aug 1990 8 Aug 1990 8 Aug 1990 8 Aug 1990 30 June 1992 8 Aug 1990 8 Aug 1990 8 Aug 1990 8 Aug 1990 8 Aug 1990 8 Aug 1990 8 Aug 1990 8 Aug 1990 8 Aug 1990 8 Aug 1990 8 Aug 1990 8 Aug 1990 8 Aug 1990 8 Aug 1990 8 Aug 1990 4 - 324 Hazardous Waste Waste Code U085 U086 U087 U088 U089 U090 U091 U092 U093 U094 U095 U096 U097 U098 U099 U101 U102 U103 U105 U106 U107 U108 U109 U110 U111 U112 U113 U114 U115 U116 U117 U118 U119 U120 U121 U122 U123 U124 U125 U126 U127 U128 U129 U130 U131 U132 U133 U134 U135 U136 U136 U137 U138 Waste Category All All All All All All All All All All All All All All All All All All All All All All All All All All All All All All All All All All All All All All All All All All All All All All All All All Wastewater Nonwastewater All All Effective Date 8 Aug 1990 8 Aug 1990 8 June 1989 8 June 1989 8 Aug 1990 8 Aug 1990 8 Aug 1990 8 Aug 1990 8 Aug 1990 8 Aug 1990 8 Aug 1990 8 Aug 1990 8 Aug 1990 8 Aug 1990 8 Aug 1990 8 Aug 1990 8 June 1989 8 Aug 1990 8 Aug 1990 8 Aug 1990 8 June 1989 8 Aug 1990 8 Aug 1990 8 Aug 1990 8 Aug 1990 8 Aug 1990 8 Aug 1990 8 Aug 1990 8 Aug 1990 8 Aug 1990 8 Aug 1990 8 Aug 1990 8 Aug 1990 8 Aug 1990 8 Aug 1990 8 Aug 1990 8 Aug 1990 8 Aug 1990 8 Aug 1990 8 Aug 1990 8 Aug 1990 8 Aug 1990 8 Aug 1990 8 Aug 1990 8 Aug 1990 8 Aug 1990 8 Aug 1990 8 Aug 1990 8 Aug 1990 8 Aug 1990 8 May 1992 8 Aug 1990 8 Aug 1990 4 - 325 Hazardous Waste Waste Code U140 U141 U142 U143 U144 U145 U146 U147 U148 U149 U150 U151 U151 U152 U153 U154 U155 U156 U157 U158 U159 U160 U161 U162 U163 U164 U165 U166 U167 U168 U169 U170 U171 U172 U173 U174 U176 U177 U178 U179 U180 U181 U182 U183 U184 U185 U186 U187 U188 U189 U190 U191 U192 Waste Category All All All All All All All All All All All Wastewater Nonwastewater All All All All All All All All All All All All All All All All All All All All All All All All All All All All All All All All All All All All All All All All Effective Date 8 Aug 1990 8 Aug 1990 8 Aug 1990 8 Aug 1990 8 Aug 1990 8 Aug 1990 8 Aug 1990 8 Aug 1990 8 Aug 1990 8 Aug 1990 8 Aug 1990 8 Aug 1990 8 May 1992 8 Aug 1990 8 Aug 1990 8 Aug 1990 8 Aug 1990 8 Aug 1990 8 Aug 1990 8 Aug 1990 8 Aug 1990 8 Aug 1990 8 Aug 1990 8 Aug 1990 8 Aug 1990 8 Aug 1990 8 Aug 1990 8 Aug 1990 8 Aug 1990 8 Aug 1990 8 Aug 1990 8 Aug 1990 8 Aug 1990 8 Aug 1990 8 Aug 1990 8 Aug 1990 8 Aug 1990 8 Aug 1990 8 Aug 1990 8 Aug 1990 8 Aug 1990 8 Aug 1990 8 Aug 1990 8 Aug 1990 8 Aug 1990 8 Aug 1990 8 Aug 1990 8 Aug 1990 8 Aug 1990 8 Aug 1990 8 June 1989 8 Aug 1990 8 Aug 1990 4 - 326 Hazardous Waste Waste Code U193 U194 U196 U197 U200 U201 U202 U203 U204 U205 U206 U207 U208 U209 U210 U211 U213 U214 U215 U216 U217 U218 U219 U220 U221 U222 U223 U225 U226 U227 U228 U234 U235 U236 U237 U238 U239 U240 U243 U244 U246 U247 U248 U249 U271 U271 U277 U277 U278 U278 U279 U279 U280 Waste Category All All All All All All All All All All All All All All All All All All All All All All All All All All All All All All All All All All All All All All All All All All All All Mixed with radioactive wastes All others Mixed with radioactive wastes All others Mixed with radioactive wastes All others Mixed with radioactive wastes All others Mixed with radioactive wastes Effective Date 8 Aug 1990 8 Aug 1990 8 Aug 1990 8 Aug 1990 8 Aug 1990 8 Aug 1990 8 Aug 1990 8 Aug 1990 8 Aug 1990 8 Aug 1990 8 Aug 1990 8 Aug 1990 8 Aug 1990 8 Aug 1990 8 Aug 1990 8 Aug 1990 8 Aug 1990 8 Aug 1990 8 Aug 1990 8 Aug 1990 8 Aug 1990 8 Aug 1990 8 Aug 1990 8 Aug 1990 8 June 1989 8 Aug 1990 8 June 1989 8 Aug 1990 8 Aug 1990 8 Aug 1990 8 Aug 1990 8 Aug 1990 8 June 1989 8 Aug 1990 8 Aug 1990 8 Aug 1990 8 Aug 1990 8 Aug 1990 8 Aug 1990 8 Aug 1990 8 Aug 1990 8 Aug 1990 8 Aug 1990 8 Aug 1990 8 Apr 1998 8 July 1996 8 Apr 1998 8 July 1996 8 Apr 1998 8 July 1996 8 Apr 1998 8 July 1996 8 Apr 1998 4 - 327 Hazardous Waste Waste Code U280 U328 U328 U353 U353 U359 U359 U364 U364 U365 U365 U366 U366 U367 U367 U372 U372 U373 U373 U375 U375 U376 U376 U377 U377 U378 U378 U379 U379 U381 U381 U382 U382 U383 U383 U384 U384 U385 U385 U386 U386 U387 U387 U389 U389 U390 U390 U391 U391 U392 U392 U393 U393 Waste Category All others Mixed with radioactive wastes All others Mixed with radioactive wastes All others Mixed with radioactive wastes All others Mixed with radioactive wastes All others Mixed with radioactive wastes All others Mixed with radioactive wastes All others Mixed with radioactive wastes All others Mixed with radioactive wastes All others Mixed with radioactive wastes All others Mixed with radioactive wastes All others Mixed with radioactive wastes All others Mixed with radioactive wastes All others Mixed with radioactive wastes All others Mixed with radioactive wastes All others Mixed with radioactive wastes All others Mixed with radioactive wastes All others Mixed with radioactive wastes All others Mixed with radioactive wastes All others Mixed with radioactive wastes All others Mixed with radioactive wastes All others Mixed with radioactive wastes All others Mixed with radioactive wastes All others Mixed with radioactive wastes All others Mixed with radioactive wastes All others Mixed with radioactive wastes All others Mixed with radioactive wastes All others Effective Date 8 July 1996 30 June 1994 9 Nov 1992 30 June 1994 9 Nov 1992 30 June 1994 9 Nov 1992 8 Apr 1998 8 July 1996 8 Apr 1998 8 July 1996 8 Apr 1998 8 July 1996 8 Apr 1998 8 July 1996 8 Apr 1998 8 July 1996 8 Apr 1998 8 July 1996 8 Apr 1998 8 July 1996 8 Apr 1998 8 July 1996 8 Apr 1998 8 July 1996 8 Apr 1998 8 July 1996 8 Apr 1998 8 July 1996 8 Apr 1998 8 July 1996 8 Apr 1998 8 July 1996 8 Apr 1998 8 July 1996 8 Apr 1998 8 July 1996 8 Apr 1998 8 July 1996 8 Apr 1998 8 July 1996 8 Apr 1998 8 July 1996 8 Apr 1998 8 July 1996 8 Apr 1998 8 July 1996 8 Apr 1998 8 July 1996 8 Apr 1998 8 July 1996 8 Apr 1998 8 July 1996 4 - 328 Hazardous Waste Waste Code U394 U394 U395 U395 U396 U396 U400 U400 U401 U401 U402 U402 U403 U403 U404 U404 U407 U407 U409 U409 U410 U410 U411 U411 Waste Category Mixed with radioactive wastes All others Mixed with radioactive wastes All others Mixed with radioactive wastes All others Mixed with radioactive wastes All others Mixed with radioactive wastes All others Mixed with radioactive wastes All others Mixed with radioactive wastes All others Mixed with radioactive wastes All others Mixed with radioactive wastes All others Mixed with radioactive wastes All others Mixed with radioactive wastes All others Mixed with radioactive wastes All others Effective Date 8 Apr 1998 8 July 1996 8 Apr 1998 8 July 1996 8 Apr 1998 8 July 1996 8 Apr 1998 8 July 1996 8 Apr 1998 8 July 1996 8 Apr 1998 8 July 1996 8 Apr 1998 8 July 1996 8 Apr 1998 8 July 1996 8 Apr 1998 8 July 1996 8 Apr 1998 8 July 1996 8 Apr 1998 8 July 1996 8 Apr 1998 8 July 1996 a This table does not include mixed radioactive wastes (from the First, Second, and Third Third rules) which received national capacity variance until May 8, 1992. This table also does not include contaminated soil and debris wastes. b The standard has been revised in the Third Third Final Rule, 1 June 1990. c This standard was revised in the Third Third Emergency Rule, 24 May 1993. d This standard was revised in the Phase II Final Rule, 19 September 1994. e The standards for selected reactive wastes was revised in the Phase III Final Rule, 6 April 1996. 4 - 329 Hazardous Waste Part 2--Summary of Effective Dates of Land Disposal Restrictions for Contaminated Soil and Debris (CSD) Restricted hazardous waste in CSD Effective date 1. Solvent-(F001-F005) and dioxin-(F020-F023 and F026-F028) containing soil and debris from CERCLA response of RCRA corrective actions. 8 Nov 1990 2. Soil and debris not from CERCLA response or RCRA corrective actions contaminated with less than 1% total solvents (F001-F005) or dioxins (F020- F023 and F026-F028). 8 Nov 1988 3. All soil and debris contaminated with First Third wastes for which treatment standards are based on incineration. 8 Aug 1990 4. All soil and debris contaminated with Second Third wastes for which treatment standards are based on incineration. 8 June 1991 5. All soil and debris contaminated with Third Third wastes or, First or Second Third “soft hammer” wastes which had treatment standards promulgated in the Third Third rule, for which treatment standards are based on incineration, vitrification, or mercury retorting, acid leaching followed by chemical precipitation, or thermal recovery of metals; as well as all inorganic solids debris contaminated with D004-D011 wastes, and all soil and debris contaminated with mixed RCRA/radioactive wastes. 8 May 1992 6. Soil and debris contaminated with D012-D043, K141-K145ms K147-151 wastes. 19 Dec 1994 7. Debris (only) contaminated with F037, F038, K107-K112, K117, K118, K123-126, K131, K132, K136, U326, U353, U359. 19 Dec 1994 8. Soil and debris contaminated with K156-K161, P127, P128, P188-P192, P194, P196-P199, P201, P205, U271, U277-U280, U364-U367, U372, U373, U375-U379, U381, U387, U389-U396, U400-U404, U407, and U409-U411 wastes. 8 July 1996 9. Soil and debris contaminated with K088 wastes 8 Jan 1997 10. Soil and debris contaminated with radioactive wastes mixed with K088, K156-K161, P127, P128, P188-P182, P184, P196-P199, P201-P206, U271, U277-U280, U362-U367, U372, U373, U375-U379, U381-U387, U389U396, U400-U404, U407, and U409-U411 wastes. 8 Apr 1998 11. Soil and debris contaminated with F032, F034, and F035 12 May 1997 NOTE: 1. Appendix VII is provided for the convenience of the reader. 2. Contaminated Soil and Debris Rule will be promulgated in the future. 4 - 330 Hazardous Waste 4 - 331 Hazardous Waste Appendix 4-8a Schedule for Implementation of Air Emissions Standards (40 CFR 265.1082) Facilities existing on 6 October 1996, which are required to comply with 40 CFR 265, Subparts I, J, and K, shall: install and begin operation of all required control equipment by 6 October 1996. If it cannot be installed and operating by 6 October 1996 the owner and operator shall: install and being operation as soon as possible but not later then 8 December 1997 prepare an implementation schedule which is placed in the operating record by 6 October 1996. Facilities which are required to comply with 40 CFR 265, Subparts I, J, and K due to a statutory or regulatory amendment shall:. install and begin operation of all required control equipment by the date of the amendment. If it cannot be installed and operating by the date of the amendment the owner and operator shall: install and being operation as soon as possible but not later than 30 mo after the amendment date prepare an implementation schedule which is placed in the operating record no later than the date of the amendment. (NOTE: The Regional Administrator may elect to extend the implementation date at a facility on a case-by-case basis.) 4 - 332 Hazardous Waste 4 - 333 Hazardous Waste Appendix 4-9 Treatment Standards for Hazardous Wastes (40 CFR 268.40) [Revised January 2000, Revised January 2001] Waste Code; Waste Description and Treatment/Regulatory Subcategory 1 D0019 Ignitable Characteristic Wastes, except for 261.21(a)(1) High TOC Subcategory. High TOC Ignitable Characteristic Liquids Subcategory based on 40 CFR 261.21(a)(1) - Greater than or equal to 10 percent total organic carbon. (NOTE: This subcategory consists of nonwastewaters only.) D0029 Corrosive Characteristic Wastes. D002, D004, D005, D006, D007, D008, D009, D010, D011 Radioactive high level wastes generated during the reprocessing of fuel rods. (NOTE: This subcategory consists of nonwastewaters only.) Regulated Hazardous Constituent: Common Name; CAS2 Number NA NA NA Wastewaters (Concentration in mg/L3; or Technology Code4) Nonwastewaters (Concentration in mg/kg5 unless noted as “mg/L TCLP”; or Technology Code) DEACT and meet 268.48 standards8; or RORGS, or CMBST NA DEACT and meet 268.48 standards8, or RORGS; or CMBST. RORGS; CMBST; or POLYM DEACT and meet 268.48 standards8 DEACT and meet 268.48 standards8 Corrosivity (pH) NA HLVIT Arsenic (7440-38-2) NA HLVIT Barium (7440-39-3) NA HLVIT Cadmium (7440-43-9) NA HLVIT Chromium (total) (7440-47-3) NA HLVIT Lead (7439-92-1) NA HLVIT 4 - 334 Hazardous Waste Waste Code; Waste Description and Treatment/Regulatory Subcategory 1 Regulated Hazardous Constituent: Common Name; CAS2 Number Mercury (7439-97-6) Wastewaters (Concentration in mg/L3; or Technology Code4) NA Nonwastewaters (Concentration in mg/kg5 unless noted as “mg/L TCLP”; or Technology Code) HLVIT Selenium (7782-49-2) NA HLVIT Silver (7440-22-4) NA HLVIT D0039 Reactive Sulfides Subcategory based on 261.23(a)(5). NA DEACT DEACT Explosives Subcategory based on 261.23(a)(6), (7), and (8). NA Unexploded ordnance and other explosive devices which have been the subject of an emergency response. NA DEACT and meet 268.48 standards8 DEACT DEACT and meet 268.48 standards8 DEACT Other Reactives Subcategory based on 261.23(a)(1). NA Water Reactive Subcategory based on 261.23(a)(2), (3), and (4). (NOTE: This subcategory consists of nonwastewaters only.) NA DEACT and meet 268.48 standards8 NA Reactive Cyanides Subcategory based on 261.23(a)(5) Cyanides (Total)7 (57-12-5) Reserved DEACT and meet 268.48 standards8 DEACT and meet 268.48 standards8 590 0.86 30 Cyanides (Amenable)7 (57-12-5) D0049 Wastes that exhibit, or are expected to exhibit, the characteristic of toxicity for arsenic based on the toxicity characteristic leaching procedure (TCLP) in SW846. Arsenic (7440-38-2) 1.4 and meet 268.48 standards8 5.0 11 and meet 268.48 standards8 D0059 Wastes that exhibit, or are expected to exhibit, the characteristic of toxicity for barium based on the toxicity characteristic leaching Barium (7440-39-3) 1.2 and meet 268.48 21 11 and meet 268.48 4 - 335 Hazardous Waste Waste Code; Waste Description and Treatment/Regulatory Subcategory 1 Regulated Hazardous Constituent: Common Name; CAS2 Number Wastewaters (Concentration in mg/L3; or Technology Code4) standards8 Nonwastewaters (Concentration in mg/kg5 unless noted as “mg/L TCLP”; or Technology Code) standards8 Cadmium (7440-43-9) 0.69 and meet 268.48 standards8 0.11 11 and meet 268.48 standards8 Cadmium (7440-43-9) NA RTHRM procedure (TCLP) in SW846. D0069 Wastes that exhibit, or are expected to exhibit, the characteristic of toxicity for cadmium based on the toxicity characteristic leaching procedure (TCLP) in SW846. Cadmium Containing Batteries Subcategory. subcategory consists of nonwastewaters only.) (NOTE: This D0079 Wastes that exhibit, or are expected to exhibit, the characteristic of toxicity for chromium based on the toxicity characteristic leaching procedure (TCLP) in SW846. Chromium (Total) (7440-47-3) 2.77 and meet 268.48 standards8 0.60 11 and meet 268.48 standards8 D0089 Wastes that exhibit, or are expected to exhibit, the characteristic of toxicity for lead based on the toxicity characteristic leaching procedure (TCLP) in SW846. Lead (7439-92-1) 0.69 and meet 268.48 standards8 0.75 11 and meet 268.48 standards8 Lead Acid Batteries Subcategory. (NOTE: This standard only applies to lead acid batteries that are identified as RCRA hazardous wastes and that are not excluded elsewhere from regulation under the land disposal restrictions of 40 CFR 268 or exempted under other EPA regulations (see 40 CFR 266.80). This subcategory consists of nonwastewaters only.) Lead (7439-92-1) NA RLEAD Radioactive Lead Solids Subcategory. (NOTE: These lead solids include, but are not limited to, all forms of lead shielding and other elemental forms of lead. These lead solids do not include treatment residuals such as hydroxide sludges, other wastewater treatment residuals, or incinerator ashes that can undergo conventional pozzolanic stabilization, nor do they include organo-lead materials that can be incinerated and stabilized as ash. This subcategory consists of Lead (7439-92-1) NA MACRO 4 - 336 Hazardous Waste Waste Code; Waste Description and Treatment/Regulatory Subcategory 1 Regulated Hazardous Constituent: Common Name; CAS2 Number Wastewaters (Concentration in mg/L3; or Technology Code4) Nonwastewaters (Concentration in mg/kg5 unless noted as “mg/L TCLP”; or Technology Code) Mercury (7439-97-6) NA IMERC or RMERC Nonwastewaters that exhibit, or are expected to exhibit, the characteristic of toxicity for mercury based on the toxicity characteristic leaching procedure (TCLP) in SW846; and contain greater than or equal to 260 mg/kg total mercury that are inorganic, including incinerator residues and residues from RMERC (High Mercury-Inorganic Subcategory) Mercury (7439-97-6) NA RMERC Nonwastewaters that exhibit, or are expected to exhibit, the characteristic of toxicity for mercury based on the toxicity characteristic leaching procedure (TCLP) in SW846; and contain less than 260 mg/kg total mercury and that are residues from RMERC only. (Low Mercury Subcategory) Mercury (7439-97-6) NA 0.20 11 and meet 268.48 standards8 All other nonwastewaters that exhibit, or are expected to exhibit, the characteristic of toxicity for mercury based on the toxicity characteristic leaching procedure (TCLP) in SW846; and contain less than 260 mg/kg total mercury and that are not residues from RMERC. (Low Mercury Subcategory) Mercury (7439-97-6) NA 0.25 11 and meet 268.48 standards8 All D009 wastewaters Mercury (7439-97-6) NA Elemental mercury contaminated with radioactive materials. (NOTE: This subcategory consists of nonwastewaters only.) Mercury (7439-97-6) 0.15 and meet 268.48 standards8 NA nonwastewaters only.) D0099 Nonwastewaters that exhibit, or are expected to exhibit, the characteristic of toxicity for mercury based toxicity characteristic leaching procedure (TCLP) in SW846; and contain greater than or equal to 260 mg/kg total mercury that also contain organics and are not incinerator residues. (High Mercury-Organic Subcategory) AMLGM 4 - 337 Hazardous Waste Waste Code; Waste Description and Treatment/Regulatory Subcategory 1 Wastewaters (Concentration in mg/L3; or Technology Code4) Nonwastewaters (Concentration in mg/kg5 unless noted as “mg/L TCLP”; or Technology Code) Mercury (7439-97-6) NA IMERC D0109 Wastes that exhibit, or are expected to exhibit, the characteristic of toxicity for selenium based on the toxicity characteristic leaching procedure (TCLP) in SW846. Selenium (7782-49-2). 0.82 and meet 268.48 standards8 5.7 11 and meet 268.48 standards8 D0119 Wastes that exhibit, or are expected to exhibit, the characteristic of toxicity for silver based on the toxicity characteristic leaching procedure (TCLP) in SW846. Silver (7440-22-4) 0.43 and meet 268.48 standards8 0.14 11 and meet 268.48 standards8 Endrin (720-20-8) BIODG; or CMBST Endrin aldehyde (7421-93-4) BIODG; or CMBST 0.13 and meet 268.48 standards8 0.13 and meet 268.48 standards8 alpha-BHC (319-84-6) CARBN; or CMBST beta-BHC (319-85-7) CARBN; or CMBST delta-BHC (319-86-8) CARBN; or CMBST gamma-BHC (lindane) (58-89-9) CARBN; or Hydraulic oil contaminated with Mercury Radioactive Materials Subcategory. (NOTE: This subcategory consists of nonwastewaters only.) Regulated Hazardous Constituent: Common Name; CAS2 Number D0129 Wastes that are TC for Endrin based on the TCLP in SW846 Method 1311. D0139 Wastes that are TC for Lindane based on the TCLP in SW846 Method 1311. 0.066 and meet 268.48 standards8 0.066 and meet 268.48 standards8 0.066 and meet 268.48 standards8 0.066 4 - 338 Hazardous Waste Waste Code; Waste Description and Treatment/Regulatory Subcategory 1 Regulated Hazardous Constituent: Common Name; CAS2 Number Wastewaters (Concentration in mg/L3; or Technology Code4) CMBST Nonwastewaters (Concentration in mg/kg5 unless noted as “mg/L TCLP”; or Technology Code) and meet 268.48 standards8 D0149 Wastes that are TC for Methoxychlor based on the TCLP in SW846 Method 1311. Methoxychlor (72-43-5) WETOX or CMBST 0.18 and meet 268.48 standards8 D0159 Wastes that are TC for Toxaphene based on the TCLP in SW846 Method 1311. Toxaphene (8001-35-2) BIODG or CMBST 2.6 and meet 268.48 standards8 CHOXD, BIODG, or CMBST 10 and meet 268.48 standards8 CHOXD or CMBST 7.9 and meet 268.48 standards8 D0169 Wastes that are TC for 2,4-D (2,4-Dichlorophenoxyacetic acid) based on the TCLP in SW846 Method 1311. 2,4-D (2,4-Dichlorophenoxyacetic acid) (94-75-7) D0179 Wastes that are TC for 2,4,5-TP (Silvex) based on the TCLP in SW846 Method 1311. 2,4,5-TP (Silvex) (93-72-1) D0189 Wastes that are TC for Benzene based on the TCLP in SW846 Method 1311. Benzene (71-43-2) 0.14 and meet 268.48 standards8 10 and meet 268.48 standards8 D0199 Wastes that are TC for Carbon tetrachloride based on the TCLP in SW846 Method 1311. Carbon tetrachloride (56-23-9) 0.057 and meet 268.48 standards8 6.0 and meet 268.48 standards8 D0209 Wastes that are TC for Chlordane based on the TCLP in SW846 Method 1311. Chlordane (alpha and gamma isomers) (57-74-9) 0.0033 and meet 268.48 standards8 0.26 and meet 268.48 standards8 D0219 Wastes that are TC for Chlorobenzene based on the TCLP in SW846 Chlorobenzene (108-90-7) 0.057 6.0 4 - 339 Hazardous Waste Waste Code; Waste Description and Treatment/Regulatory Subcategory 1 Regulated Hazardous Constituent: Common Name; CAS2 Number Method 1311. Wastewaters (Concentration in mg/L3; or Technology Code4) and meet 268.48 standards8 Nonwastewaters (Concentration in mg/kg5 unless noted as “mg/L TCLP”; or Technology Code) and meet 268.48 standards8 D0229 Wastes that are TC for Chloroform based on the TCLP in SW846 Method 1311. Chloroform (67-66-3) 0.046 and meet 268.48 standards8 6.0 and meet 268.48 standards8 D0239 Wastes that are TC for o-Cresol based on the TCLP in SW846 Method 1311. o-Cresol (95-48-7) 0.11 and meet 268.48 standards8 5.6 and meet 268.48 standards8 m-Cresol (108-39-4) (difficult to distinguish from p-Cresol) 0.77 and meet 268.48 standards8 5.6 and meet 268.48 standards8 p-Cresol (106-44-5) (difficult to distinguish from m-Cresol) 0.77 and meet 268.48 standards8 5.6 and meet 268.48 standards8 Cresol-mixed isomers (Cresylic acid) (sum of o-, m-, and p-cresol concentrations) (1319-77-3) 0.88 and meet 268.48 standards8 11.2 and meet 268.48 standards8 p-Dichlorobenzene Dichlorobenzene] (106-46-7) 0.090 and meet 268.48 standards8 6.0 and meet 268.48 standards8 1,2-Dichloroethane (107-06-2) 0.21 and meet 268.48 standards8 6.0 and meet 268.48 standards8 1,1-Dichloroethylene (75-35-4) 0.025 6.0 D0249 Wastes that are TC for m-Cresol based on the TCLP in SW846 Method 1311. D0259 Wastes that are TC for p-Cresol based on the TCLP in SW846 Method 1311. D0269 Wastes that are TC for Cresols (Total) based on the TCLP in SW846 Method 1311. D0279 Wastes that are TC for p-Dichlorobenzene based on the TCLP in SW846 Method 1311. D0289 Wastes that are TC for 1,2-Dichloroethane based on the TCLP in SW846 Method 1311. D0299 Wastes that are TC for 1,1-Dichloroethylene based on the TCLP in [1,4- 4 - 340 Hazardous Waste Waste Code; Waste Description and Treatment/Regulatory Subcategory 1 Regulated Hazardous Constituent: Common Name; CAS2 Number SW846 Method 1311. Wastewaters (Concentration in mg/L3; or Technology Code4) and meet 268.48 standards8 Nonwastewaters (Concentration in mg/kg5 unless noted as “mg/L TCLP”; or Technology Code) and meet 268.48 standards8 D0309 Wastes that are TC for 2,4-Dinitrotoluene based on the TCLP in SW846 Method 1311. 2,4-Dinitrotoluene (121-14-2) 0.32 and meet 268.48 standards8 140 and meet 268.48 standards8 D0319 Wastes that are TC for Heptachlor based on the TCLP in SW846 Method 1311. Heptachlor (76-44-8) 0.0012 and meet 268.48 standards8 0.016 and meet 268.48 standards8 0.066 and meet 268.48 standards8 0.066 and meet 268.48 standards8 Heptachlor epoxide (1024-57-3) D0329 Wastes that are TC for Hexachlorobenzene based on the TCLP in SW846 Method 1311. Hexachlorobenzene (118-74-1) 0.055 and meet 268.48 standards8 10 and meet 268.48 standards8 D0339 Wastes that are TC for Hexachlorobutadiene based on the TCLP in SW846 Method 1311. Hexachlorobutadiene (87-68-3) 0.055 and meet 268.48 standards8 5.6 and meet 268.48 standards8 D0349 Wastes that are TC for Hexachloroethane based on the TCLP in SW846 Method 1311. Hexachloroethane (67-72-1) 0.055 and meet 268.48 standards8 30 and meet 268.48 standards8 D0359 Wastes that are TC for Methyl ethyl ketone based on the TCLP in SW846 Method 1311. Methyl ethyl ketone (78-93-3) 0.28 and meet 268.48 standards8 36 and meet 268.48 standards8 D0369 4 - 341 Hazardous Waste Waste Code; Waste Description and Treatment/Regulatory Subcategory 1 Wastes that are TC for Nitrobenzene based on the TCLP in SW846 Method 1311. Regulated Hazardous Constituent: Common Name; CAS2 Number Nitrobenzene (98-95-3) Wastewaters (Concentration in mg/L3; or Technology Code4) 0.068 and meet 268.48 standards8 Nonwastewaters (Concentration in mg/kg5 unless noted as “mg/L TCLP”; or Technology Code) 14 and meet 268.48 standards8 D0379 Wastes that are TC for Pentachlorophenol based on the TCLP in SW846 Method 1311. Pentachlorophenol (87-86-5) 0.089 and meet 268.48 standards8 7.4 and meet 268.48 standards8 D0389 Wastes that are TC for Pyridine based on the TCLP in SW846 Method 1311. Pyridine (110-86-1) 0.014 and meet 268.48 standards8 16 and meet 268.48 standards8 D0399 Wastes that are TC for Tetrachloroethylene based on the TCLP in SW846 Method 1311. Tetrachloroethylene (127-18-4) 0.056 and meet 268.48 standards8 6.0 and meet 268.48 standards8 D0409 Wastes that are TC for Trichloroethylene based on the TCLP in SW846 Method 1311. Trichloroethylene (79-01-6) 0.054 and meet 268.48 standards8 6.0 and meet 268.48 standards8 D0419 Wastes that are TC for 2,4,5-Trichlorophenol based on the TCLP in SW846 Method 1311. 2,4,5-Trichlorophenol (95-95-4) 0.18 and meet 268.48 standards8 7.4 and meet 268.48 standards8 D0429 Wastes that are TC for 2,4,6-Trichlorophenol based on the TCLP in SW846 Method 1311. 2,4,6-Trichlorophenol (88-06-2) 0.035 and meet 268.48 standards8 7.4 and meet 268.48 standards8 D0439 Wastes that are TC for Vinyl chloride based on the TCLP in SW846 Method 1311. Vinyl chloride (75-01-4) 0.27 and meet 268.48 standards8 6.0 and meet 268.48 standards8 F001, F002, F003, F004, F005 4 - 342 Hazardous Waste Waste Code; Waste Description and Treatment/Regulatory Subcategory 1 F001, F002, F003, F004 and/or F005 solvent wastes that contain any combination of one or more of the following spent solvents: acetone, benzene, n-butyl alcohol, carbon disulfide, carbon tetrachloride, chlorinated fluorocarbons, chlorobenzene, o-cresol, m-cresol, p-cresol, cyclohexanone, o-dichlorobenzene, 2-ethoxyethanol, ethyl acetate, ethyl benzene, ethyl ether, isobutyl alcohol, methanol, methylene chloride, methyl ethyl ketone, methyl isobutyl ketone, nitrobenzene, 2nitropropane, pyridine, tetrachloroethylene, toluene, 1,1,1trichloroethane, 1,1,2-tricholoroethane, 1,1,2-trichloro-1,2,2trifluoroethane, trichloroethylene, trichloromonofluoromethane, and/or xylenes (except as specifically noted in other subcategories). See further details of these listings in 261.31. Regulated Hazardous Constituent: Common Name; CAS2 Number Acetone (67-64-1) Benzene (71-43-2) n-Butyl alcohol (71-36-3) Carbon disulfide (75-15-0) Carbon tetrachloride (56-23-5) Chlorobenzene (108-90-7) o-Cresol (95-48-7) m-Cresol (difficult to distinguish from pcresol) (108-39-4) p-Cresol (difficult to distinguish from mcresol) (106-44-5) Cresol mixed isomers (cresylic acid) (sum of o-, m-, p-cresol concentrations) (1319-77-3) Cyclohexanone (108-94-1) o-Dichlorobenzene (95-50-1) Ethyl acetate (141-78-6) Ethyl benzene (100-41-4) Ethyl ether (60-29-7) Isobutyl alcohol (78-83-1) Methanol (67-56-1) Methylene chloride (75-9-2) Wastewaters (Concentration in mg/L3; or Technology Code4) 0.28 Nonwastewaters (Concentration in mg/kg5 unless noted as “mg/L TCLP”; or Technology Code) 160 0.14 5.6 3.8 0.057 0.057 0.11 0.77 10 2.6 NA 6.0 6.0 5.6 5.6 0.77 5.6 0.88 11.2 0.36 0.088 0.34 0.057 0.12 5.6 5.6 0.089 NA 6.0 33 10 160 170 NA 30 4 - 343 Hazardous Waste Waste Code; Waste Description and Treatment/Regulatory Subcategory 1 Regulated Hazardous Constituent: Common Name; CAS2 Number Methyl ethyl ketone (78-93-3) Methyl isobutyl ketone (108-10-1) Nitrobenzene (98-95-3) Pyridine (110-86-1) Tetrachloroethylene (127-18-4) Toluene (108-88-3) 1,1,1-Trichloroethane (71-55-6) 1,1,2-Trichloroethane (79-00-5) 1,1,2-Trichloro-1,2,2-trifluoromethane (76-13-1) Trichloroethylene (79-01-6) F003 and/or F005 solvent wastes that contain any combination of one or more of the following three solvents as the only listed F001-5 solvents: carbon disulfide, cyclohexanone, and/or methanol. (formerly 268.41(c)) F005 solvent waste containing 2-Nitropropane as the only listed F0015 solvent. F005 solvent waste containing 2-Ethoxyethanol as the only listed F001-5 solvent. F006 Wastewater treatment sludges from electroplating operations except from the following processes: (1) Sulfuric acid anodizing of aluminum; (2) tin plating on carbon steel; (3) zinc plating (segregated Trichloromonofluoromethane (75-69-4) Xylenes-mixed isomers (sum of o-, m-, p-xylene concentrations) (1330-20-7) Carbon disulfide (75-15-0) Cyclohexanone (108-94-1) Methanol (67-56-1) 2-Nitropropane (79-46-9) 2-Ethoxyethanol (110-80-5) Cyanides (Total)7(57-12-5) Wastewaters (Concentration in mg/L3; or Technology Code4) 0.28 0.14 0.068 0.014 0.056 0.080 0.054 0.054 0.057 Nonwastewaters (Concentration in mg/kg5 unless noted as “mg/L TCLP”; or Technology Code) 36 33 14 16 6.0 10 6.0 6.0 30 0.054 6.0 0.020 0.32 30 30 3.8 4.8 11 0.36 5.6 (WETOX, or CHOXD) fb CARBN; or CMBST BIODG; or CMBST 0.75 11 0.75 11 CMBST 1.2 590 CMBST 4 - 344 Hazardous Waste Waste Code; Waste Description and Treatment/Regulatory Subcategory 1 Regulated Hazardous Constituent: Common Name; CAS2 Number Wastewaters (Concentration in mg/L3; or Technology Code4) Nonwastewaters (Concentration in mg/kg5 unless noted as “mg/L TCLP”; or Technology Code) Cyanides (Amenable)7(57-12-5) Cadmium (7440-43-9) Chromium (Total) (7440-47-3) Lead (7439-92-1) Nickel (7440-02-0) Silver (7440-22-4) 0.86 0.69 2.77 0.69 3.98 NA 30 0.11 11 0.60 11 0.75 11 11 11 0.14 11 Cadmium (7440-43-9) Cyanides (Total)7(57-12-5) Cyanides (Amenable)7(57-12-5) Chromium (Total) (7440-47-3) Lead (7439-92-1) Nickel (7440-02-0) Silver (7440-22-4) NA 1.2 0.86 2.77 0.69 3.98 NA 0.11 11 590 30 0.60 11 0.75 11 11 11 0.14 11 Cadmium (7440-43-9) NA 0.11 11 Cyanides (Total)7(57-12-5) Cyanides (Amenable)7(57-12-5) Chromium (Total) (7440-47-3) Lead (7439-92-1) Nickel (7440-02-0) Silver (7440-22-4) 1.2 0.86 2.77 0.69 3.98 NA 590 30 0.60 11 0.75 11 11 11 0.14 11 Cadmium (7440-43-9) NA 0.11 11 Cyanides (Total)7(57-12-5) Cyanides (Amenable)7(57-12-5) 1.2 0.86 590 30 basis) on carbon steel; (4) aluminum or zinc-aluminum plating on carbon steel; (5) cleaning/stripping associated with tin, zinc, and aluminum plating on carbon steel; and (6) chemical etching and milling of aluminum. F007 Spent cyanide plating bath solutions from electroplating operations. F008 Plating bath residues from the bottom of plating baths from electroplating operations where cyanides are used in the process. F009 Spent stripping and cleaning bath solutions from electroplating operations where cyanides are used in the process. 4 - 345 Hazardous Waste Waste Code; Waste Description and Treatment/Regulatory Subcategory 1 Regulated Hazardous Constituent: Common Name; CAS2 Number Wastewaters (Concentration in mg/L3; or Technology Code4) 2.77 0.69 3.98 NA Nonwastewaters (Concentration in mg/kg5 unless noted as “mg/L TCLP”; or Technology Code) 0.60 11 0.75 11 11 11 0.14 11 Cyanides (Total)7(57-12-5) 1.2 590 Cyanides (Amenable)7(57-12-5) 0.86 NA Cadmium (7440-43-9) NA 0.11 11 Cyanides (Total) (57-12-5) Cyanides (Amenable)7 (57-12-5) Chromium (Total)7 (7440-47-3) Lead (7439-92-1) Nickel (7440-02-0) Silver (7440-22-4) 1.2 0.86 2.77 0.69 3.98 NA 590 30 0.60 11 0.75 11 11 11 0.14 11 Cadmium (7440-43-9) NA 0.11 11 Cyanides (Total)7 (57-12-5) Cyanides (Amenable)7 (57-12-5) Chromium (Total) (7440-47-3) Lead (7439-92-1) Nickel (7440-02-0) Silver (7440-22-4) 1.2 0.86 2.77 0.69 3.98 NA 590 30 0.60 11 0.75 11 11 11 0.14 11 Cyanides (Total)7 (57-12-5) 1.2 590 Cyanides (Amenable)7(57-12-5) 0.86 30 Chromium (Total) (7440-47-3) Lead (7439-92-1) Nickel (7440-02-0) Silver (7440-22-4) F010 Quenching bath residues from oil baths from metal heat treating operations where cyanides are used in the process. F011 Spent cyanide solutions from salt bath pot cleaning from metal heat treating operations. F012 Quenching wastewater treatment sludges from metal heat treating operations where cyanides are used in the process. F019 Wastewater treatment sludges from the chemical conversion coating of aluminum except from zirconium phosphating in aluminum can washing when such phosphating is an exclusive conversion coating process. 4 - 346 Hazardous Waste Waste Code; Waste Description and Treatment/Regulatory Subcategory 1 Regulated Hazardous Constituent: Common Name; CAS2 Number Wastewaters (Concentration in mg/L3; or Technology Code4) 2.77 Nonwastewaters (Concentration in mg/kg5 unless noted as “mg/L TCLP”; or Technology Code) 0.60 11 Hexachlorodibenzo-p- 0.000063 0.001 HxCDFs (All Hexachlorodibenzofurans) PeCDDs (All Pentachlorodibenzo-pdioxins) PeCDFs (All Pentachlorodibenzofurans) TCDDs (All Tetrachlorodibenzo-pdioxins) TCDFs (All Tetrachlorodibenzofurans ) 2,4,5-Trichorophenol (95-95-4) 2,4,6-Trichorophenol (88-06-2) 2,3,4,6-Tetrachlorophenol (58-90-2) Pentachlorophenol (87-86-5) 0.000063 0.000063 0.001 0.001 0.000035 0.000063 0.001 0.001 0.000063 0.18 0.035 0.030 0.089 0.001 7.4 7.4 7.4 7.4 All F024 wastes CMBST11 CMBST11 Chromium (Total) (7440-47-3) F020, F021, F022, F023, F026 Wastes (except wastewater and spent carbon from hydrogen chloride purification) from the production or manufacturing use, (as a reactant, chemical intermediate, or component in a formulating process) of: (1) tri- or tetrachlorophenol, or of intermediates used to produce their pesticide derivatives, excluding wastes from the production of Hexachlorophene from highly purified 2,4,5-trichlorophenol (F020); (2) pentachlorophenol, or of intermediates used to produce its derivatives (i.e. F021); (3) tetra-, penta-, or hexachlorobenzenes under alkaline conditions (i.e. F022); and from the production of materials on equipment previously used for the production or manufacturing use (as a reactant, chemical intermediate, or component in a formulating process) of: (1) tri- or tetrachlorophenols, excluding wastes from equipment used only for the production of Hexachlorophene from highly purified 2,4,5-trichlorophenol (F023); (2) tetra-, penta-, or hexachlorobenzenes under alkaline conditions (i.e., F026). F024 Process wastes, including but no limited to, distillation residues, heavy ends, tars, and reactor clean-out wastes, from the production of certain chlorinated aliphatic hydrocarbons by free radical catalyzed processes. These chlorinated aliphatic hydrocarbons are those having carbon HxCDDs dioxins) (All 4 - 347 Hazardous Waste Waste Code; Waste Description and Treatment/Regulatory Subcategory 1 Regulated Hazardous Constituent: Common Name; CAS2 Number Wastewaters (Concentration in mg/L3; or Technology Code4) Nonwastewaters (Concentration in mg/kg5 unless noted as “mg/L TCLP”; or Technology Code) 2-Chloro-1,3-butadiene (126-99-8) 3-Chloropropylene (107-05-1) 1,1-Dichloroethane (75-34-3) 1,2-Dichloroethane (107-06-2) 1,2-Dichloropropane (78-87-5) cis-1,3-Dichloropropylene (10061-01-5) trans-1,3-Dichloropropylene (10061-026) bis(2-Ethylhexyl)phthalate (117-81-7) Hexachloroethane (67-72-1) Chromium (Total) (7440-47-3) Nickel (7440-02-0) 0.057 0.036 0.059 0.21 0.85 0.036 0.036 0.28 30 6.0 6.0 18 18 18 0.28 0.055 2.77 3.98 28 30 0.60 11 11 11 Carbon tetrachloride (56-23-5) 0.057 6.0 Chloroform (67-66-3) 1,2-Dichloroethane (107-06-2) 1,1-Dichloroethylene (75-35-4) Methylene chloride (75-9-2) 1,1,2-Trichloroethane (79-00-5) Trichloroethylene (79-01-6) Vinyl chloride (75-01-4) Carbon tetrachloride (56-23-5) 0.046 0.21 0.025 0.089 0.054 0.054 0.27 0.057 6.0 6.0 6.0 30 6.0 6.0 6.0 6.0 chain lengths ranging from one to and including five, with varying amounts and positions of chlorine substitution. (This listing does not include wastewaters, wastewater treatment sludges, spent catalysts, and wastes listed in 261.31 or 261.32.). F025 Condensed light ends from the production of certain chlorinated aliphatic hydrocarbons, by free radical catalyzed processes. These chlorinated aliphatic hydrocarbons are those having carbon chain lengths ranging from one to and including five, with varying amounts and positions of chlorine substitution. F025-Light Ends Subcategory. Spent filters and filter aids, and spent desiccant wastes from the production of certain chlorinated aliphatic hydrocarbons, by freed radical catalyzed processes. These chlorinated aliphatic hydrocarbons 4 - 348 Hazardous Waste Waste Code; Waste Description and Treatment/Regulatory Subcategory 1 Regulated Hazardous Constituent: Common Name; CAS2 Number Wastewaters (Concentration in mg/L3; or Technology Code4) Nonwastewaters (Concentration in mg/kg5 unless noted as “mg/L TCLP”; or Technology Code) 0.046 0.055 0.055 0.055 0.089 0.054 0.054 0.27 6.0 10 5.6 30 30 6.0 6.0 6.0 Hexachlorodibenzo-p- 0.000063 0.001 HxCDFs (All Hexachlorodibenzofurans) PeCDDs (All Pentachlorodibenzo-pdioxins) PeCDFs (All Pentachlorodibenzofurans) TCDDs (All Tetrachlorodibenzo-pdioxins) TCDFs (All Tetrachlorodibenzofurans) 2,4,5-Trichorophenol (95-95-4) 2,4,6-Trichorophenol (88-06-2) 2,3,4,6-Tetrachlorophenol (58-90-2) Pentachlorophenol (87-86-5) 0.000063 0.000063 0.001 0.001 0.000035 0.000063 0.001 0.001 0.000063 0.18 0.035 0.030 0.089 0.001 7.4 7.4 7.4 7.4 HxCDDs dioxins) 0.000063 0.001 are those having carbon chain lengths ranging from one to and including five, with varying amounts and positions of chlorine substitution. F025-Spent Filters/Aids and Desiccants Subcategory Chloroform (67-66-3) Hexachlorobenzene (118-74-1) Hexachlorobutadiene (87-68-3) Hexachloroethane (67-72-1) Methylene chloride (75-9-2) 1,1,2-Trichloroethane (79-00-5) Trichloroethylene (79-01-6) Vinyl chloride (75-01-4) F027 Discarded unused formulations containing tri-, tetra-, or pentachlorophenol or discarded unused formulations containing compounds derived from these chlorophenols. (This listing does not include formulations containing hexachlorophene synthesized from prepurified 2,4,5-trichlorophenol as the sole component.) F028 Residues resulting from the incinerations or thermal treatment of soil contaminated with EPA Hazardous waste Nos. F020, F021, F023, F026, and F027. HxCDDs dioxins) (All (All Hexachlorodibenzo-p- 4 - 349 Hazardous Waste Waste Code; Waste Description and Treatment/Regulatory Subcategory 1 Regulated Hazardous Constituent: Common Name; CAS2 Number Wastewaters (Concentration in mg/L3; or Technology Code4) 0.000063 0.000063 Nonwastewaters (Concentration in mg/kg5 unless noted as “mg/L TCLP”; or Technology Code) 0.001 0.001 0.000035 0.000063 0.001 0.001 0.000063 0.18 0.035 0.030 0.089 0.001 7.4 7.4 7.4 7.4 Acenaphthene (83-32-9) 0.059 3.4 Anthracene (120-12-7) Benz(a)anthracene (56-55-3) Benzo(b)fluoranthene (difficult to distinguish from benzo(k)fluoranthene) (205-99-2) Benzo(k)fluoranthene (difficult to distinguish from benzo(b)fluoranthene) (207-08-9) Benzo(a)pyrene (50-32-8) 0.059 0.059 0.11 3.4 3.4 6.8 0.11 6.8 0.061 3.4 HxCDFs (All Hexachlorodibenzofurans) PeCDDs (All Pentachlorodibenzo-pdioxins) PeCDFs (All Pentachlorodibenzofurans) TCDDs (All Tetrachlorodibenzo-pdioxins) TCDFs (All Tetrachlorodibenzofurans) 2,4,5-Trichorophenol (95-95-4) 2,4,6-Trichorophenol (88-06-2) 2,3,4,6-Tetrachlorophenol (58-90-2) Pentachlorophenol (87-86-5) F032 Wastewaters (except those that have not come into contact with process contaminants), process residuals, preservative drippage, and spent formulations from wood preserving processes generated at plants that currently use or have previously used chlorophenolic formulations (except potentially cross-contaminated wastes that have had the F032 waste code deleted in accordance with 261.35 or potentially crosscontaminated wastes that are otherwise currently regulated as hazardous wastes (i.e., F034 or F035), and where the generator does not resume or initiate use of cholorphenolic formulations). This listing does not include K001 bottom sediment sludge from the treatment of wastewater from wood preserving processes that use creosote and/or pentachlophenol. 4 - 350 Hazardous Waste Waste Code; Waste Description and Treatment/Regulatory Subcategory 1 Regulated Hazardous Constituent: Common Name; CAS2 Number Chrysene (218-01-9) Debenz(a,h)anthracene (53-70-3) 2,4,-Dimethyl phenol (105-67-9) Fluorene (86-73-1) Hexachlorodibenzo-p-dioxins Hexachlorodibenzofurans Ideno (1,2,3-c,d) pyrene (193-39-5) Naphthalene (91-20-3) Pentachlorodibenzo-p-dioxins Pentachlorodibenzofurans Pentachlorophenol (87-86-5) Phenanthrene (85-01-8) Phenol (108-95-2) Pyrene (129-00-0) Tetrachlorodibenzo-p-dioxins Tetrachlorodibenzofurans 2,3,4,6-Tetrachlorophenol (58-90-2) 2,4,6,-Trichlorophenol (88-06-2) Arsenic (7440-38-2) Chromium (Total) (7440-47-3) F034 Wastewaters (except those that have not come into contact with process contaminants), process residuals, preservative drippage, and spent formulations from wood preserving processes generated at plants that use creosote formulations. This listing does not include K001 bottom sediment sludge from the treatment of wastewater from wood preserving processes that use creosote and/or pentachlorophenol. Acenaphthene (83-32-9) Wastewaters (Concentration in mg/L3; or Technology Code4) 0.059 0.055 0.036 0.059 0.000063, or CMBST11 0.000063, or CMBST11 0.0055 0.059 0.000063, or CMBST11 0.000035, or CMBST11 0.089 0.059 0.039 0.067 0.000063, or CMBST11 0.000063, or CMBST11 0.030 0.035 1.4 2.77 Nonwastewaters (Concentration in mg/kg5 unless noted as “mg/L TCLP”; or Technology Code) 3.4 8.2 14 3.4 0.001, or CMBST11 0.001, or CMBST11 3.4 5.6 0.001, or CMBST11 0.001, or CMBST11 7.4 5.6 6.2 8.2 0.001, or CMBST11 0.001, or CMBST11 7.4 7.4 5.0 11 0.60 11 0.059 3.4 4 - 351 Hazardous Waste Waste Code; Waste Description and Treatment/Regulatory Subcategory 1 Regulated Hazardous Constituent: Common Name; CAS2 Number Wastewaters (Concentration in mg/L3; or Technology Code4) 0.059 0.059 0.11 Nonwastewaters (Concentration in mg/kg5 unless noted as “mg/L TCLP”; or Technology Code) 3.4 3.4 6.8 0.11 6.8 0.061 0.059 0.055 0.059 0.0055 0.059 0.059 0.067 1.4 2.77 3.4 3.4 8.2 3.4 3.4 5.6 5.6 8.2 5.0 11 0.60 11 Arsenic (7440-38-2) 1.4 5.0 11 Chromium (Total) (7440-47-3) 2.77 0.60 11 Acenaphthene (83-32-9) 0.059 NA Anthracene (120-12-7) Benz(a)anthracene (56-55-3) Benzo(b)fluoranthene (difficult to distinguish from benzo(k)fluoroanthene) (205-99-2) Benxo(k)fluoranthene (difficult to distinguish from benzo(b)fluoroanthene) (207-08-9) Benzo(a)pyrene (50-32-8) Chrysene (218-01-9) Dibenz(a,h)anthracene (53-70-3) Fluorene (86-73-7) Ideno (1,2,3-c,d) pyrene (193-39-5) Naphthalene (91-20-3) Phenanthrene (85-01-8) Pyrene (129-00-0) Arsenic (7440-38-2) Chromium (Total) (7440-47-3) F035 Wastewaters (except those that have not come into contact with process contaminants), process residuals, preservative drippage, and spent formulations from wood preserving processes generated at plants that inorganic preservatives containing arsenic or chromium. This listing does not include K001 bottom sediment sludge from the treatment of wastewater from wood preserving processes that use creosote and/or pentachlorophenol. F037 Petroleum refinery primary oil/water/solids separation sludge-Any sludge generated from the gravitational separation of oil/water/solids during the storage or treatment of process wastewaters and oily cooling wastewaters from petroleum refineries. Such sludges include, but are 4 - 352 Hazardous Waste Waste Code; Waste Description and Treatment/Regulatory Subcategory 1 Regulated Hazardous Constituent: Common Name; CAS2 Number Wastewaters (Concentration in mg/L3; or Technology Code4) Nonwastewaters (Concentration in mg/kg5 unless noted as “mg/L TCLP”; or Technology Code) Anthracene (120-12-7) Benzene (71-43-2) Benz(a)anthracene (56-55-3) Benzo(a)pyrene (50-32-8) bis(2-Ethylhexyl) phthalate (117-81-7) Chrysene (218-01-9) Di-n-butyl phthalate (84-74-2) Ethylbenzene (100-41-4) Fluorene (86-73-7) Naphthalene (91-20-3) Phenanthrene (85-01-8) Phenol (108-95-2) Pyrene (129-00-0) Toluene (108-88-3) Xylenes-mixed isomers (sum of o-, m-, and p-xylene concentrations) (1330-207) Cyanides (Total)7(57-12-5) Chromium (Total) (7440-47-3) Lead (7439-92-1) Nickel (7440-02-0) 0.059 0.14 0.059 0.061 0.28 0.059 0.057 0.057 0.059 0.059 0.059 0.039 0.067 0.080 0.32 3.4 10 3.4 3.4 28 3.4 28 10 NA 5.6 5.6 6.2 8.2 10 30 1.2 2.77 0.69 NA 590 0.60 11 NA 11 11 Benzene (71-43-2) 0.14 10 not limited to, those generated in: oil/water/solids separators; tanks and impoundments; ditches and other conveyances; sumps; and stormwater units receiving dry weather flow. Sludge generated in stormwater units that do not receive dry weather flow, sludges generated from noncontact once-through cooling waters segregated for treatment from other process or oily cooling waters, sludges generated in aggressive biological treatment units as defined in 261.31(b)(2) (including sludges generated in one or more additional units after wastewaters have been treated in aggressive biological treatment units) and K051 wastes are not included in this listing. F038 Petroleum refinery secondary (emulsified) oil/water/solids separation 4 - 353 Hazardous Waste Waste Code; Waste Description and Treatment/Regulatory Subcategory 1 Regulated Hazardous Constituent: Common Name; CAS2 Number Wastewaters (Concentration in mg/L3; or Technology Code4) Nonwastewaters (Concentration in mg/kg5 unless noted as “mg/L TCLP”; or Technology Code) Benzo(a)pyrene (50-32-8) bis(2-Ethylhexyl) phthalate (117-81-7) Chrysene (218-01-9) Di-n-butyl phthalate (84-74-2) Ethylbenzene (100-41-4) Fluorene (86-73-7) Naphthalene (91-20-3) Phenanthrene (85-01-8) Phenol (108-95-2) Pyrene (129-00-0) Toluene (108-88-3) Xylenes-mixed isomers (sum of o-,m-, and p-xylene concentrations) (1330-207) Cyanides (Total)7(57-12-5) Chromium (Total) (7440-47-3) Lead (7439-92-1) Nickel (7440-02-0) 0.061 0.28 0.059 0.057 0.057 0.059 0.059 0.059 0.039 0.067 0.080 0.32 3.4 28 3.4 28 10 NA 5.6 5.6 6.2 8.2 10 30 1.2 2.77 0.69 NA 590 0.60 11 NA 11 11 sludge and/or float generated from the physical and/or chemical separation of oil/water/solids in process wastewaters and oily cooling wastewaters from petroleum refineries. Such wastes include, but are not limited to, all sludges and floats generated in: induced air floatation (IAF) units, tanks and impoundments, and all sludges generated in DAF units. Sludges generated in stormwater units that do not receive dry weather flow, sludges generated from non-contact, once-through cooling waters segregated for treatment from other process or oily cooling waters, sludges and floats generated in aggressive biological treatment units as defined in 261.31(b)(2)(including sludges and floats generated in one or more additional units after wastewaters have been treated in aggressive biological units) and F037, K048, and K051 are not included in this listing. F039 4 - 354 Hazardous Waste Waste Code; Waste Description and Treatment/Regulatory Subcategory 1 Leachate (liquids that have percolated through land disposal wastes) resulting from the disposal of more than one restricted waste classified as hazardous under subpart D of this part. (Leachate resulting from the disposal of one or more of the following USEPA Hazardous Wastes and no other Hazardous Wastes retains its USEPA Hazardous Waste Number(s): F020, F021, F022, F026, F027, and/or F028.). Regulated Hazardous Constituent: Common Name; CAS2 Number Acenaphthylene (208-96-8) Acenaphthene (83-32-9) Acetone (67-64-1) Acetonitrile (75-05-8) Acetophenone (96-86-2) 2-Acetylaminofluorene (53-96-3) Acrolein (107-02-8) Acrylonitrile (107-13-1) Aldrin (309-00-2) 4-Aminobiphenyl (92-67-1) Aniline (62-53-3) Anthracene (120-12-7) Aramite (140-57-8) alpha-BHC (319-84-6) beta-BHC (319-85-7) delta-BHC (319-86-8) gamma-BHC (58-89-9) Benzene (71-43-2) Benz(a)anthracene (56-55-3) Benzo(b)fluoranthene (difficult to distinguish from benzo(k)fluoranthene) (205-99-2) Benzo(k)fluoranthene (difficult to distinguish from benzo(b)fluoranthene) (207-08-9) Benzo(g,h,i)perylene (191-24-2) Benzo(a)pyrene (50-32-8) Bromodichloromethane (75-27-4) Wastewaters (Concentration in mg/L3; or Technology Code4) 0.059 Nonwastewaters (Concentration in mg/kg5 unless noted as “mg/L TCLP”; or Technology Code) 3.4 0.059 0.28 5.6 0.010 0.059 0.29 0.24 0.021 0.13 0.81 0.059 0.36 0.00014 0.00014 0.023 0.0017 0.14 0.059 0.11 3.4 160 NA 9.7 140 NA 84 0.066 NA 14 3.4 NA 0.066 0.066 0.066 0.066 10 3.4 6.8 0.11 6.8 0.0055 0.061 0.35 1.8 3.4 15 4 - 355 Hazardous Waste Waste Code; Waste Description and Treatment/Regulatory Subcategory 1 Regulated Hazardous Constituent: Common Name; CAS2 Number Methyl bromide (Bromomethane) (7483-9) 4-Bromophenyl phenyl ether (101-55-3) n-Butyl alcohol (71-36-3) Butyl benzyl phthalate (85-68-7) 2-sec-Butyl-4,6-dinitrophenol (Dinoseb) (88-85-7) Carbon tetrachloride (56-23-5) Carbon disulfide (75-15-0) Chlordane (alpha and gamma isomers) (57-74-9) p-Chloroaniline (106-47-8) Chlorobenzene (108-90-7) Chlorobenzilate (510-15-6) 2-Chloro-1,3-butadiene (126-99-8) Chlorodibromomethane (124-48-1) Chloroethane (75-00-3) bis(2-Chloroethoxy) methane (111-91-1) bis(2-Chloroethyl) ether (111-44-4) Chloroform (67-66-3) bis(2-Chloroisopropyl) ether (39638-329) p-Chloro-m-cresol (59-50-7) Chloromethane (Methyl chloride) (7487-3) 2-Chloronaphthalene (91-58-7) 2-Chlorophenol (95-57-8) 3-Chloropropylene (107-05-1) Chrysene (218-01-9) o-Cresol (95-48-7) m-Cresol (difficult to distinguish from pCresol) Wastewaters (Concentration in mg/L3; or Technology Code4) 0.11 Nonwastewaters (Concentration in mg/kg5 unless noted as “mg/L TCLP”; or Technology Code) 15 0.055 5.6 0.017 0.066 15 2.6 28 2.5 0.057 3.8 0.0033 6.0 NA 0.26 0.46 0.057 0.10 0.057 0.057 0.27 0.036 0.033 0.046 0.055 16 6.0 NA NA 15 6.0 7.2 6.0 6.0 7.2 0.018 0.19 14 30 0.055 0.044 0.036 0.059 0.11 0.77 5.6 5.7 30 3.4 5.6 5.6 4 - 356 Hazardous Waste Waste Code; Waste Description and Treatment/Regulatory Subcategory 1 Regulated Hazardous Constituent: Common Name; CAS2 Number (108-39-4) p-Cresol (difficult to distinguish from mCresol) (106-44-5) Cyclohexanone (108-94-1) 1,2-Dibromo-3-chloropropane (96-12-8) Ethylene dibromide (1,2-Dibromoethane) (106-93-4) Dibromomethane (74-95-3) 2,4-D (2,4-Dichlorophenoxyacetic acid) (94-75-7) o,p’-DDD (53-19-0) p,p’-DDD (72-54-8) o,p’-DDE (3424-82-6) p,p’-DDE (72-55-9) o,p’-DDT (780-02-6) p,p’-DDT (50-29-3) Dibenz(a,h)anthracene (53-70-3) Dibenzo(a,e)pyrene (192-65-4) m-Dichlorobenzene (541-73-1) o-Dichlorobenzene (95-50-1) p-Dichlorobenzene (106-46-7) Dichlorodifluoromethane (75-71-8) 1,1-Dichloroethane (75-34-3) 1,2-Dichloroethane (107-06-2) 1,1-Dichloroethylene (75-35-4) trans-1,2-Dichloroethylene (156-60-5) 2,4-Dichlorophenol (120-83-2) 2,6-Dichlorophenol (87-65-0) 1,2-Dichloropropane (78-87-5) cis-1,3-Dichloropropylene (10061-01-5) trans-1,3-Dichloropropylene (10061-02- Wastewaters (Concentration in mg/L3; or Technology Code4) Nonwastewaters (Concentration in mg/kg5 unless noted as “mg/L TCLP”; or Technology Code) 0.77 5.6 0.36 0.11 0.028 NA 15 15 0.11 0.72 15 10 0.023 0.023 0.031 0.031 0.0039 0.0039 0.055 0.061 0.036 0.088 0.090 0.23 0.059 0.21 0.025 0.054 0.044 0.044 0.85 0.036 0.036 0.087 0.087 0.087 0.087 0.087 0.087 8.2 NA 6.0 6.0 6.0 7.2 6.0 6.0 6.0 30 14 14 18 18 18 4 - 357 Hazardous Waste Waste Code; Waste Description and Treatment/Regulatory Subcategory 1 Regulated Hazardous Constituent: Common Name; CAS2 Number 6) Dieldrin (60-57-1) Diethyl phthalate (84-66-2) 2,4-Dimethyl phenol (105-67-9) Dimethyl phthalate (131-11-3) Di-n-butyl phthalate (84-74-2) 1,4-Dinitrobenzene (100-25-4) 4,6-Dinitro-o-cresol (534-52-1) 2,4-Dinitrophenol (51-28-5) 2,4-Dinitrotoluene (121-14-2) 2,6-Dinitrotoluene (606-20-2) Di-n-octyl phthalate (117-84-0) Di-n-propylnitrosamine (621-64-7) 1,4-Dioxane (123-91-1) Diphenylamine (difficult to distinguish from diphenylnitrosamine) (122-39-4) Diphenylnitrosamine (difficult to distinguish from diphenylamine) (86-306) 1,2 Diphenylhydrazine (122-66-7) Disulfoton (298-04-4) Endosulfan I (939-98-8) Endosulfan II (33213-6-5) Endosulfan sulfate (1031-07-8) Endrin (72-20-8) Endrin aldehyde (7421-93-4) Ethyl acetate (141-78-6) Ethyl cyanide (Propanenitrile) (107-120) Ethyl benzene (100-41-4) Ethyl ether (60-29-7) bis(2-Ethylhexyl) phthalate (117-81-7) Wastewaters (Concentration in mg/L3; or Technology Code4) Nonwastewaters (Concentration in mg/kg5 unless noted as “mg/L TCLP”; or Technology Code) 0.017 0.20 0.036 0.047 0.057 0.32 0.28 0.12 0.32 0.55 0.017 0.40 12.0 0.92 0.13 28 14 28 28 2.3 160 160 140 28 28 14 170 NA 0.92 NA 0.087 0.017 0.023 0.029 0.029 0.0028 0.025 0.34 0.24 NA 6.2 0.066 0.13 0.13 0.13 0.13 33 360 0.057 0.12 0.28 10 160 28 4 - 358 Hazardous Waste Waste Code; Waste Description and Treatment/Regulatory Subcategory 1 Regulated Hazardous Constituent: Common Name; CAS2 Number Ethyl methacrylate (97-63-2) Ethylene oxide (75-21-8) Famphur (52-85-7) Fluoranthene (206-44-0) Fluorene (86-73-7) Heptachlor (76-44-8) Heptachlor epoxide (1024-57-3) 1,2,3,4,6,7,8-Heptachlorodibenzo-pdioxin (1,2,3,4,6,7,8-HpCDD) (3582246-9) 1,2,3,4,6,7,8-Heptachlorodibenzofuran (1,2,3,4,6,7,8-HpCDF) (67562-39-4) 1,2,3,4,7,8,9-Heptachlorodibenzofuran (1,2,3,4,7,8,9-HpCDF) (55673-89-7) Hexachlorobenzene (118-74-1) Hexachlorobutadiene (87-68-3) Hexachlorocyclopentadiene (77-47-4) HxCDFs (All Hexachlorodibenzofurans) (NA) HxCDDs (All Hexchlorodibenzo-pdioxins) (NA) Hexchloroethane (67-72-1) Hexachloropropylene (1888-71-7) Indeno(1,2,3,-c,d)pyrene (193-39-5) Iodomethane (74-88-4) Isobutyl alcohol (78-83-1) Isodrin (465-73-6) Isosafrole (120-58-1) Kepone (143-50-8) Methacrylonitrile (126-98-7) Methanol (67-56-1) Methapyrilene (91-80-5) Wastewaters (Concentration in mg/L3; or Technology Code4) 0.14 0.12 0.017 0.068 0.059 0.0012 0.016 0.000035 Nonwastewaters (Concentration in mg/kg5 unless noted as “mg/L TCLP”; or Technology Code) 160 NA 15 3.4 3.4 0.066 0.066 0.0025 0.000035 0.0025 0.000035 0.0025 0.055 0.055 0.057 0.000063 10 5.6 2.4 0.001 0.000063 0.001 0.055 0.035 0.0055 0.19 5.6 0.021 0.081 0.0011 0.24 5.6 0.081 30 30 3.4 65 170 0.066 2.6 0.13 84 NA 1.5 4 - 359 Hazardous Waste Waste Code; Waste Description and Treatment/Regulatory Subcategory 1 Regulated Hazardous Constituent: Common Name; CAS2 Number Methoxychlor (72-43-5) 3-Methylcholanthrene (56-49-5) 4,4-Methylene-bis-(2-chloroaniline) (101-14-4) Methylene chloride (75-09-2) Methyl ethyl ketone (78-93-3) Methyl isobutyl ketone (108-10-1) Methyl methacrylate (80-62-6) Methyl methansulfonate (66-27-3) Methyl parathion (298-00-0) Naphthalene (91-20-3) 2-Naphthylamine (91-59-8) p-Nitroaniline (100-01-6) Nitrobenzene (98-95-3) 5-Nitro-o-toluidine (99-55-8) p-Nitrophenol (100-02-7) N-Nitrosodiethylamine (55-18-5) N-Nitrosodimethylamine (62-75-9) N-Nitroso-di-n-butylamine (924-16-3) N-Nitrosomethylethylamine (10595-956) N-Nitrosomorpholine (59-89-2) N-Nitrosopiperidine (100-75-4) N-Nitrosopyrrolidine (930-55-2) 1,2,3,4,6,7,8,9-Octachlorodibenzo-pdioxin (OCDD) (3268-87-9) Parathion (56-38-2) Total PCBs (sum of all PCB isomers, or all Aroclors) (1336-36-3) Pentachlorobenzene (608-93-5) PeCDFs (All Pentachlorodibenzofurans) Wastewaters (Concentration in mg/L3; or Technology Code4) 0.25 0.0055 0.50 Nonwastewaters (Concentration in mg/kg5 unless noted as “mg/L TCLP”; or Technology Code) 0.18 15 30 0.089 0.28 0.14 0.14 0.018 0.014 0.059 0.52 0.028 0.068 0.32 0.12 0.40 0.40 0.40 0.40 30 36 33 160 NA 4.6 5.6 NA 28 14 28 29 28 NA 17 2.3 0.40 0.013 0.013 0.000063 2.3 35 35 0.0025 0.014 0.10 4.6 10 0.055 0.000035 10 0.001 4 - 360 Hazardous Waste Waste Code; Waste Description and Treatment/Regulatory Subcategory 1 Regulated Hazardous Constituent: Common Name; CAS2 Number (NA) PeCDDs (All Pentachlorodibenzo-pdioxins) (NA) Pentachloronitrobenzene (82-68-8) Pentachlorophenol (87-86-5) Phenacetin (62-44-2) Phenanthrene (85-01-8) Phenol (108-95-2) Phorate (298-02-2) Phthalic anhydride (85-44-9) Pronamide (23950-58-5) Pyrene (129-00-0) Pyridine (110-86-1) Safrole (94-59-7) Silvex (2,4,5-TP) (93-72-1) 2,4,5-T (93-76-5) 1,2,4,5,-Tetrachlorobenzene (95-94-3) TCDDs (All Tetrachlorodibenzo-pdioxins) (NA) TCDFs (All Tetrachlorodibenzofurans) (NA) 1,1,1,2-Tetrachloroethane (630-20-6) 1,1,2,2-Tetrachloroethane (79-34-6) Tetrachloroethylene (127-18-4) 2,3,4,6-Tetrachlorophenol (58-90-2) Toluene (108-88-3) Toxaphene (8001-35-2) Bromoform (Tribromomethane) (75-252) 1,2,4-Trichlorobenzene (120-82-1) 1,1,1-Trichloroethane (71-55-6) 1,1,2-Trichloroethane (79-00-5) Wastewaters (Concentration in mg/L3; or Technology Code4) Nonwastewaters (Concentration in mg/kg5 unless noted as “mg/L TCLP”; or Technology Code) 0.000063 0.001 0.055 0.089 0.081 0.059 0.039 0.021 0.055 0.093 0.067 0.014 0.081 0.72 0.72 0.055 0.000063 4.8 7.4 16 5.6 6.2 4.6 NA 1.5 8.2 16 22 7.9 7.9 14 0.001 0.000063 0.001 0.057 0.057 0.056 0.030 0.080 0.0095 0.63 6.0 6.0 6.0 7.4 10 2.6 15 0.055 0.054 0.054 19 6.0 6.0 4 - 361 Hazardous Waste Waste Code; Waste Description and Treatment/Regulatory Subcategory 1 Leachate (liquyids that have percolatedthrough land disposal wastes) resuting from the disposal of omopre than one restricted waste Regulated Hazardous Constituent: Common Name; CAS2 Number Trichloroethylene (79-01-6) Trichloromonofluoromethane (75-69-4) 2,4,5-Trichlorophenol (95-95-4) 2,4,6-Trichlorophenol (88-06-2) 1,2,3-Trichloropropane (96-18-4) 1,1,2-Trichloro-1,2,2-trifluoroethane (76-13-1) Tris(2,3-Dibromopropyl)phosphate (126-72-7) Vinyl chloride (75-01-4) Xylenes-mixed isomers (sum of o-, m-, and p-xylene concentrations) (1330-207) Antimony (7440-36-0) Arsenic (7440-38-2) Barium (7440-39-3) Beryllium (7440-41-7) Cadmium (7440-43-9) Chromium (Total) (7440-47-3) Cyanides (Amenable)7 (57-12-5) Cyanides (Total)7 (57-12-5) Fluoride (16964-48-8) Lead (7439-92-1) Mercury (7439-97-6) Nickel (7440-02-0) Selenium (7782-49-2) Silver (7440-22-4) Sulfide (8496-25-8) Thallium (7440-28-0) Vanadium (7440-62-2) ************** Wastewaters (Concentration in mg/L3; or Technology Code4) 0.054 0.020 0.18 0.035 0.85 0.057 Nonwastewaters (Concentration in mg/kg5 unless noted as “mg/L TCLP”; or Technology Code) 6.0 30 7.4 7.4 30 30 0.11 NA 0.27 0.32 6.0 30 1.9 1.4 1.2 0.82 0.69 2.77 0.86 1.2 35 0.69 0.15 3.98 0.82 0.43 14 1.4 4.3 1.15 11 5.0 11 21 11 NA 0.11 11 0.60 11 NA 590 NA 0.75 11 0.025 11 11 11 5.7 11 0.14 11 NA NA NA 4 - 362 Hazardous Waste Waste Code; Waste Description and Treatment/Regulatory Subcategory 1 Regulated Hazardous Constituent: Common Name; CAS2 Number Wastewaters (Concentration in mg/L3; or Technology Code4) Nonwastewaters (Concentration in mg/kg5 unless noted as “mg/L TCLP”; or Technology Code) 0.000035 0.0025 0.000035 0.0025 0.000035 0.0025 0.000063 0.0025 Naphthalene (91-20-3) 0.059 5.6 Pentachlorophenol (87-86-5) Phenanthrene (85-01-8) Pyrene (129-00-0) Toluene (108-88-3) Xylenes-mixed isomers (sum of o-, m-, and p-xylene concentrations) (1330-207) Lead (7439-92-1) 0.089 0.059 0.067 0.080 0.32 7.4 5.6 8.2 10 30 0.69 0.75 11 Chromium (Total) (7440-47-3) 2.77 0.60 11 Lead (7439-92-1) 0.69 0.75 11 calssified as hazardous under Subpart D of this part. (Leachate resulting from disposal of one or more of the following EPA Hazardous Wastes and no other Hazardous Waste retains its EPA Hazardous Waste Number(s): F020, F021, F022, F026, F027, and/or F028) 1, 2, 3, 4, 6, 7, 8Heptachlorodibenzo-p-dioxin (1,2,3,4,6,7,8-HpCDD) (35822-46-9) 1,2,3,4,6,7,8Heptachlorodibenzofuran (1,2,3,4,6,7,8-HpCDF) (67562-39-4) 1,2,3,4,7,8,9Heptachlorodibenzofuran (1,2,3,4,7,8,9-HpCDF) (55673-89-7)) 1,2,3,4,6,7,8,9Octachlorodibenzo-p-dioxin (OCDD) K001 Bottom sediment sludge from the treatment of wastewaters from wood preserving processes that use creosote and/or pentachlorophenol. K002 Wastewater treatment sludge from the production of chrome yellow and orange pigments. K003 4 - 363 Hazardous Waste Waste Code; Waste Description and Treatment/Regulatory Subcategory 1 Wastewater treatment sludge from the production of molybdate orange pigments. K004 Wastewater treatment sludge from the production of zinc yellow pigments. K005 Wastewater treatment sludge from the production of chrome green pigments. K006 Wastewater treatment sludge from the production of chrome oxide green pigments (anhydrous). Wastewater treatment sludge from the production of chrome oxide green pigments (hydrated). K007 Wastewater treatment sludge from the production of iron blue pigments. K008 Oven residue from the production of chrome oxide green pigments. K009 Distillation bottoms from the production of acetaldehyde from ethylene. Regulated Hazardous Constituent: Common Name; CAS2 Number Wastewaters (Concentration in mg/L3; or Technology Code4) 2.77 Nonwastewaters (Concentration in mg/kg5 unless noted as “mg/L TCLP”; or Technology Code) 0.60 11 Lead (7439-92-1) 0.69 0.75 11 Chromium (Total) (7440-47-3) 2.77 0.60 11 Lead (7439-92-1) 0.69 0.75 11 Chromium (Total) (7440-47-3) 2.77 0.60 11 Lead (7439-92-1) Cyanides(Total)7 (57-12-5) 0.69 1.2 0.75 11 590 Chromium (Total) (7440-47-3) 2.77 0.60 11 Lead (7439-92-1) Chromium (Total) (7440-47-3) 0.69 2.77 0.75 11 0.60 11 Lead (7439-92-1) 0.69 NA Chromium (Total) (7440-47-3) 2.77 0.60 11 Lead (7439-92-1) Cyanides(Total)7 (57-12-5) 0.69 1.2 0.75 11 590 Chromium (Total) (7440-47-3) Lead (7439-92-1) 2.77 0.69 0.60 11 0.75 11 Chloroform (67-66-3) 0.046 6.0 Chromium (Total) (7440-47-3) K010 4 - 364 Hazardous Waste Waste Code; Waste Description and Treatment/Regulatory Subcategory 1 Distillation side cuts from the production of acetaldehyde from ethylene. K011 Bottom stream from the wastewater stripper in the production of acrylonitrile K013 Bottom stream from the acrylonitrile column in the production of acrylonitrile K014 Bottoms from the acetonitrile purification column in the production of acrylonitrile. K015 Still bottoms from the distillation of benzyl chloride. Regulated Hazardous Constituent: Common Name; CAS2 Number Chloroform (67-66-3) Wastewaters (Concentration in mg/L3; or Technology Code4) 0.046 Nonwastewaters (Concentration in mg/kg5 unless noted as “mg/L TCLP”; or Technology Code) 6.0 Acetonitrile (75-05-8) 5.6 38 Acrylonitrile (107-13-1) Acrylamide (79-06-1) Benzene (71-43-2) Cyanide (Total) (57-12-5) 0.24 19 0.14 1.2 84 23 10 590 Acetonitrile (75-05-8) 5.6 38 Acrylonitrile (107-13-1) Acrylamide (79-06-1) Benzene (71-43-2) Cyanide(total) (57-12-5) 0.24 19 0.14 1.2 84 23 10 590 Acetonitrile (75-05-8) 5.6 38 Acrylonitrile (107-13-1) Acrylamide (79-06-1) Benzene (71-43-2) Cyanide (Total) (57-12-5) 0.24 19 0.14 1.2 84 23 10 590 Anthracene (120-12-7) Benzal chloride (98-87-3) Benzo(b)fluoranthene (difficult to distinguish from benzo(k)fluoranthene) (205-99-2) Benzo(k)fluoranthene (difficult to distinguish from benzo(b)fluoranthene)(207-08-9) 0.059 0.055 0.11 3.4 6.0 6.8 0.11 6.8 4 - 365 Hazardous Waste Waste Code; Waste Description and Treatment/Regulatory Subcategory 1 K016 Heavy ends or distillation residues from the production of carbon tetrachloride. K017 Heavy ends (still bottoms) from the purification column in the production of epichlorohydrin. K018 Heavy ends from the fractionation column in ethyl chloride production. K019 Heavy ends from the distillation of ethylene dichloride in ethylene dichloride production. Regulated Hazardous Constituent: Common Name; CAS2 Number Phenanthrene (85-01-8) Toluene (108-88-3) Chromium (Total) (7440-47-3) Nickel (7440-02-0) Wastewaters (Concentration in mg/L3; or Technology Code4) 0.059 0.080 2.77 3.98 Nonwastewaters (Concentration in mg/kg5 unless noted as “mg/L TCLP”; or Technology Code) 5.6 10 0.60 11 11 11 Hexachlorobenzene (118-74-1) 0.055 10 Hexachlorobutadiene (87-68-3) Hexachlorocyclopentadiene (77-47-4) Hexachloroethane (67-72-1) Tetrachloroethylene (127-18-4) 0.055 0.057 0.055 0.056 5.6 2.4 30 6.0 1,2-Dichloropropane (78-87-5) 0.85 18 1,2,3-Trichloropropane (96-18-4) bis(2-Chloroethyl)ether (111-44-4) 0.85 0.033 30 6.0 Chloroethane (75-00-3) 0.27 6.0 Chloromethane (74-87-3) 1,1-Dichloroethane (75-34-3) 1,2-Dichloroethane (107-06-2) Hexachlorobenzene (118-74-1) Hexachlorobutadiene (87-68-3) Hexachloroethane (67-72-1) Pentachloroethane (76-01-7) 1,1,1-Trichloroethane (71-55-6) 0.19 0.059 0.21 0.055 0.055 0.055 NA 0.054 NA 6.0 6.0 10 5.6 30 6.0 6.0 Bis(2-chloroethyl)ether (111-44-4) 0.033 6.0 Chlorobenzene (108-90-7) 0.057 6.0 4 - 366 Hazardous Waste Waste Code; Waste Description and Treatment/Regulatory Subcategory 1 Regulated Hazardous Constituent: Common Name; CAS2 Number Wastewaters (Concentration in mg/L3; or Technology Code4) 0.046 0.09 0.21 0.059 0.055 0.059 0.059 0.055 0.056 0.055 0.054 Nonwastewaters (Concentration in mg/kg5 unless noted as “mg/L TCLP”; or Technology Code) 6.0 NA 6.0 NA 30 5.6 5.6 NA 6.0 19 6.0 1,2-Dichloroethane (107-06-2) 0.21 6.0 1,1,2,2-Tetrachloroethane (79-34-6) Tetrachloroethylene (127-18-4) 0.057 0.056 6.0 6.0 Carbon tetrachloride (56-23-5) 0.057 6.0 Chloroform (67-66-3) Antimony (7440-36-0) 0.046 1.9 6.0 1.15 11 Toluene (108-88-3) 0.080 10 Acetophenone (96-86-2) Diphenylamine (difficult to distinguish from Diphenylnitrosamine) (122-39-4) Diphenylnitrosamine (difficult to distinguish from Diphenylamine)(86-3060) Phenol (108-95-2) Chromium (Total) (7440-47-3) 0.010 0.92 9.7 13 0.92 13 0.039 2.77 6.2 0.60 11 Chloroform (67-66-3) p-Dichlorobenzene (106-46-7) 1,2-Dichloroethane (107-06-2) Fluorene (86-73-7) Hexachloroethane (67-72-1) Naphthalene (91-20-3) Phenanthrene (85-01-8) 1,2,4,5-Tetrachlorobenzene (95-94-3) Tetrachloroethylene (127-18-4) 1,2,4-Trichlorobenzene (120-82-1) 1,1,1-Trichloroethane (71-55-6) K020 Heavy ends from the distillation of vinyl chloride in vinyl chloride monomer production. K021 Aqueous spent antimony catalyst waste from fluoromethanes production. K022 Distillation bottom tars from the production of phenol/acetone from cumene. 4 - 367 Hazardous Waste Waste Code; Waste Description and Treatment/Regulatory Subcategory 1 Regulated Hazardous Constituent: Common Name; CAS2 Number Wastewaters (Concentration in mg/L3; or Technology Code4) 3.98 Nonwastewaters (Concentration in mg/kg5 unless noted as “mg/L TCLP”; or Technology Code) 11 11 Phthalic anhydride (measured as Phthalic acid or Terephthalic acid) (100-21-0) Phthalic anhydride (measured as Phthalic acid or Terephthalic acid) (85-44-9) 0.055 28 0.055 28 Phthalic anhydride (measured as Phthalic acid or Terephthalic acid) (100-21-0) Phthalic anhydride (measured as Phthalic acid or Terephthalic acid) (85-44-9) 0.055 28 0.055 28 NA LLEXT fb SSTRP fb CARBN; or CMBST CMBST NA CMBST CMBST K027 Centrifuge and distillation residues from toluene diisocyanate production. NA CARBN; or CMBST CMBST K028 Spent catalyst from the hydrochlorinator reactor in the production of 1,1,1-trichloroethane. 1,1-Dichloroethane (75-34-3) 0.059 6.0 trans-1,2-Dichloroethylene (156-60-5) Hexachlorobutadiene (87-68-3) Hexachloroethane (67-72-1) Pentachloroethane (76-01-7) 1,1,1,2-Tetrachloroethane (630-20-6) 1,1,2,2-Tetrachloroethane (79-34-6) Tetrachloroethylene (127-18-4) 1,1,1-Trichlorethane (71-55-6) 0.054 0.055 0.055 NA 0.057 0.057 0.056 0.054 30 5.6 30 6.0 6.0 6.0 6.0 6.0 Nickel (7440-02-0) K023 Distillation light ends from the production of phthalic anhydride from naphthalene. K024 Distillation bottoms from the production of phthalic anhydride from naphthalene. K025 Distillation bottoms from the production of nitrobenzene by the nitration of benzene. K026 Stripping still tails from the production of methyl ethyl pyridines. 4 - 368 Hazardous Waste Waste Code; Waste Description and Treatment/Regulatory Subcategory 1 Regulated Hazardous Constituent: Common Name; CAS2 Number Wastewaters (Concentration in mg/L3; or Technology Code4) 0.054 0.69 2.77 0.69 3.98 Nonwastewaters (Concentration in mg/kg5 unless noted as “mg/L TCLP”; or Technology Code) 6.0 NA 0.60 11 0.75 11 11 11 Chloroform (67-66-3) 0.046 6.0 1,2-Dichloroethane (107-06-2) 1,1-Dichloroethylene (75-35-4) 1,1,1-Trichloroethane (71-55-6) Vinyl chloride (75-01-4) 0.21 0.025 0.054 0.27 6.0 6.0 6.0 6.0 o-Dichlorobenzene (95-50-1) 0.088 NA p-Dichlorobenzene (106-46-7) Hexachlorobutadiene (87-68-3) Hexachloroethane (67-72-1) Hexachloroproplylene (1888-71-7) Pentachlorobenzene (608-93-5) Pentachloroethane (76-01-7) 1,2,4,5-Tetrachlorobenzene (95-94-3) Tetrachloroethylene (127-18-4) 1,2,4-Trichlorobenzene (120-82-1) 0.090 0.055 0.055 NA NA NA 0.055 0.056 0.055 NA 5.6 30 30 10 6.0 14 6.0 19 1.4 5.0 11 0.057 0.0033 2.4 0.26 1,1,2-Trichlorethane (79-00-5) Cadmium (7440-43-9) Chromium (Total) (7440-47-3) Lead (7439-92-1) Nickel (7440-02-0) K029 Waste from the product steam stripper in the production of 1,1,1trichloroethane. K030 Column bodies or heavy ends from the combined production of trichloroethylene and perchloroethylene. K031 By-product salts generated in the production of MSMA and cacodylic acid K032 Wastewater treatment sludge from the production of chlordane. Arsenic (7440-38-2) Hexachlorocyclopentadiene (77-47-4) Chlordane (alpha and gamma isomers) (57-74-9) 4 - 369 Hazardous Waste Waste Code; Waste Description and Treatment/Regulatory Subcategory 1 Regulated Hazardous Constituent: Common Name; CAS2 Number Heptachlor (76-44-8) Heptachlor epoxide (1024-57-3) Wastewaters (Concentration in mg/L3; or Technology Code4) 0.0012 0.016 Nonwastewaters (Concentration in mg/kg5 unless noted as “mg/L TCLP”; or Technology Code) 0.066 0.066 K033 Wastewater and scrub water from the chlorination of cyclopentadiene in the production of chlordane. Hexachlorocyclopentadiene (77-47-4). 0.057 2.4 K034 Filter solids from the filtration of hexachlorocyclopentadiene in the production of chlordane. Hexachlorocyclopentadiene (77-47-4). 0.057 2.4 Acenaphthene (83-32-9) Anthracene (120-12-7) Benz(a)anthracene (56-55-3) Benzo(a)pyrene (50-32-8) Chrysene (218-01-9) o-cresol (95-48-7) m-cresol (difficult to distinguish from pcresol) (108-39-4) p-cresol (difficult to distinguish from mcresol) (106-44-5) Dibenz(a,h)anthracene (53-70-3) Fluoranthene (206-44-0) Fluorene (86-73-7) Indeno(1,2,3-cd)pyrene (193-39-5). Naphthalene (91-20-3) Phenanthrene (85-01-8) Phenol (108-95-2) Pyrene (129-00-0) NA NA 0.059 0.061 0.059 0.11 0.77 3.4 3.4 3.4 3.4 3.4 5.6 5.6 0.77 5.6 NA 0.068 NA NA 0.059 0.059 0.039 0.067 8.2 3.4 3.4 3.4 5.6 5.6 6.2 8.2 Disulfoton (298-04-4) 0.017 6.2 K035 Wastewater treatment sludges generated in the production of creosote. K036 Still bottoms from toluene reclamation distillation in the production of disulfoton. 4 - 370 Hazardous Waste Waste Code; Waste Description and Treatment/Regulatory Subcategory 1 K037 Wastewater treatment sludges from the production of disulfonton. K038 Wastewater from the washing and stripping of phorate production. K039 Filter cake from the filtration of diethylphosphorodithioc acid in the production of phorate. Regulated Hazardous Constituent: Common Name; CAS2 Number Wastewaters (Concentration in mg/L3; or Technology Code4) Nonwastewaters (Concentration in mg/kg5 unless noted as “mg/L TCLP”; or Technology Code) Disulfoton (298-04-4) Toluene (108-88-3) 0.017 0.080 6.2 10 Phorate (298-02-2) 0.021 4.6 CARBN; or CMBST CMBST NA K040 Wastewater treatment sludge from the production of phorate. Phorate (298-02-2) 0.021 4.6 K041 Wastewater treatment sludge from the production of toxaphene. Toxaphene (8001-35-2) 0.0095 2.6 o-Dichlorobenzene (95-50-1) 0.088 6.0 p-Dichlorobenzene (106-46-7) Pentachlorobenzene (608-93-5) 1,2,4,5-Tetrachlorobenzene (95-94-3) 1,2,4-Trichlorobenzene (120-82-1). 0.090 0.055 0.055 0.055 6.0 10 14 19 0.044 0.044 0.18 0.035 0.030 0.089 0.056 0.000063 14 14 7.4 7.4 7.4 7.4 6.0 0.001 K042 Heavy ends or distillation residues from the distillation of tetrachlorobenzene in the production of 2,4,5-T. K043 2,6-Dichlorophenol waste from the production of 2,4-D. 2,4-Dichlorophenol (120-83-2) 2,6-Dichlorophenol (187-65-0) 2,4,5-Trichlorophenol (95-95-4) 2,4,6-Trichlorophenol (88-06-2) 2,3,4,6-Tetrachlorophenol (58-90-2) Pentachlorophenol (87-86-5) Tetrachloroethylene (127-18-4) HxCDDs (All Hexachlorodibenzo-p- 4 - 371 Hazardous Waste Waste Code; Waste Description and Treatment/Regulatory Subcategory 1 Regulated Hazardous Constituent: Common Name; CAS2 Number Wastewaters (Concentration in mg/L3; or Technology Code4) Nonwastewaters (Concentration in mg/kg5 unless noted as “mg/L TCLP”; or Technology Code) 0.000063 0.001 0.000063 0.001 0.000035 0.001 0.000063 0.001 0.000063 0.001 NA DEACT DEACT NA DEACT DEACT 0.69 0.75 11 DEACT DEACT Benzene (71-43-2) 0.14 10 Benzo(a)pyrene (50-32-8) Bis(2-ethylhexyl)phthalate (117-81-7) Chrysene (218-01-9) Di-n-butyl phthalate (84-74-2) Ethylbenzene (100-41-4) 0.061 0.28 0.059 0.057 0.057 3.4 28 3.4 28 10 dioxins) (NA) HxCDFs (All Hexachlorodibenzofurans) (NA) PeCDDs (All Pentachlorodibenzo-pdioxins) (NA) PeCDFs (All Pentachlorodibenzofurans) (NA) TCDDs (All Tetrachlorodibenzo-pdioxins) (NA) TCDFs (All Tetrachlorodibenzofurans) (NA) K044 Wastewater treatment sludges from the manufacturing and processing of explosives. K045 Spent carbon from the treatment of wastewaters containing explosives. K046 Wastewater treatment sludges from the manufacturing, formulation, and loading of lead-based initiating compounds. K047 Pink/red water from TNT operations. K048 Dissolved air floatation (DAF) float from the petroleum refining industry. Lead (7439-92-1) NA 4 - 372 Hazardous Waste Waste Code; Waste Description and Treatment/Regulatory Subcategory 1 Regulated Hazardous Constituent: Common Name; CAS2 Number Fluorene (86-73-7) Naphthalene (91-20-3) Phenanthrene (85-01-8) Phenol (108-95-2) Pyrene (129-00-0) Toluene (108-88-33) Xylenes-mixed isomers (sum of o-, m-, and p-xylene concentrations) (1330-207) Chromium (Total) (7440-47-3) Cyanides (Total)7 (57-12-5) Lead (7439-92-1) Nickel (7440-02-0) K049 Slop oil emulsion solids from the petroleum refining industry. Anthracene (120-12-7) Benzene (71-43-2) Benzo(a)pyrene (50-32-8) Bis(2-ethylhexyl)phthalate (117-81-7) Carbon disulfide (75-15-0) Chrysene (2218-01-9) 2,4-Dimethylphenol(105-67-9) Ethylbenzene (100-41-4) Naphthalene (91-20-3) Phenanthrene (85-01-8) Phenol (108-95-2) Pyrene (129-00-0) Toluene (108-88-3) Xylenes-mixed isomers (sum of o-,m,and p-xylene concentrations) (1330-207) Cyanides (Total)7 (57-12-5) Chromium (Total) (7440-47-3) Wastewaters (Concentration in mg/L3; or Technology Code4) 0.059 0.059 0.059 0.039 0.067 0.080 0.32 Nonwastewaters (Concentration in mg/kg5 unless noted as “mg/L TCLP”; or Technology Code) NA 5.6 5.6 6.2 8.2 10 30 2.77 1.2 0.69 NA 0.60 11 590 NA 11 11 0.059 0.14 0.061 0.28 3.8 0.059 0.036 0.057 0.059 0.059 0.039 0.067 0.080 0.32 3.4 10 3.4 28 NA 3.4 NA 10 5.6 5.6 6.2 8.2 10 30 1.2 2.77 590 0.60 11 4 - 373 Hazardous Waste Waste Code; Waste Description and Treatment/Regulatory Subcategory 1 Regulated Hazardous Constituent: Common Name; CAS2 Number Wastewaters (Concentration in mg/L3; or Technology Code4) 0.69 NA Nonwastewaters (Concentration in mg/kg5 unless noted as “mg/L TCLP”; or Technology Code) NA 11 11 Benzo(a)pyrene (50-32-8) 0.061 3.4 Phenol (108-95-2) Cyanides (Total)7 (57-12-5) Chromium (Total) (7440-47-3) Lead (7439-92-1) Nickel (7440-02-0) 0.039 1.2 2.77 0.69 NA 6.2 590 0.60 11 NA 11 11 Acenaphthene (83-32-9) Anthracene (120-12-7) Benz(a)anthracene (56-55-3) Benzene (71-43-2) Benzo(a)pyrene (50-32-8) bis(2-Ethylhexyl)phthalate (117-81-7) Chrysene (2218-01-9) Di-n-butyl phthalate (105-67-9) Ethylbenzene (100-41-4) Fluorene (86-73-7) Naphthalene (91-20-3) Phenanthrene (85-01-8) Phenol (108-95-2) Pyrene (129-00-0) Toluene (108-88-3) Xylenes-mixed isomers (sum of o-,m,and p-xylene concentrations) (1330-207) Cyanides (Total)7 (57-12-5) Chromium (Total) (7440-47-3) Lead (7439-92-1) 0.059 0.059 0.059 0.14 0.061 0.28 0.059 0.057 0.057 0.059 0.059 0.059 0.039 0.067 0.08 0.32 NA 3.4 3.4 10 3.4 28 3.4 28 10 NA 5.6 5.6 6.2 8.2 10 30 1.2 2.77 0.69 590 0.60 11 NA Lead (7439-92-1) Nickel (7440-02-0) K050 Heat exchange bundle cleaning sludge from the petroleum refining industry. K051 API separator sludge from the petroleum refining industry. 4 - 374 Hazardous Waste Waste Code; Waste Description and Treatment/Regulatory Subcategory 1 Regulated Hazardous Constituent: Common Name; CAS2 Number Wastewaters (Concentration in mg/L3; or Technology Code4) NA Nonwastewaters (Concentration in mg/kg5 unless noted as “mg/L TCLP”; or Technology Code) 11 11 Benzene (71-43-2) Benzo(a)pyrene (50-32-8) o-Cresol (95-48-7) m-Cresol (difficult to distinguish from pcresol) (108-39-4) p-Cresol (difficult to distinguish from mcresol) (106-44-5) 2,4-Dimethylphenol (105-67-9) Ethylbenzene (100-41-4) Naphthalene (91-20-3) Phenanthrene (85-01-8) Phenol (108-95-2) Toluene (108-88-3) Xylenes-mixed isomers (sum of o-,m,and p-xylene concentrations) (1330-207) Cyanides (Total)7 (57-12-5) Chromium (Total) (7440-47-3) Lead (7439-92-1) Nickel (7440-02-0) 0.14 0.061 0.11 0.77 10 3.4 5.6 5.6 0.77 5.6 0.036 0.057 0.059 0.059 0.039 0.08 0.32 NA 10 5.6 5.6 6.2 10 30 1.2 2.77 0.69 NA 590 0.60 11 NA 11 11 Benzene (71-43-2) Benzo(a)pyrene (50-32-8) Naphthalene (91-20-3) Phenol (108-95-2) Cyanides(total)7 (57-12-5) 0.14 0.061 0.059 0.039 1.2 10 3.4 5.6 6.2 590 Antimony (7440-36-0) NA 1.15 11 Arsenic (7440-38-2) NA 5.0 11 Nickel (7440-02-0) K052 Tank bottoms(leaded) from the petroleum refining industry. K060 Ammonia still lime sludge from coking operations. K061 Emission control dust/sludge from the primary production of steel in electric furnaces. 4 - 375 Hazardous Waste Waste Code; Waste Description and Treatment/Regulatory Subcategory 1 Barium (7440-39-3) Beryllium (7440-41-7) Cadmium (7440-43-9) Chromium(total) (7440-47-3) Lead (7439-92-1) Mercury (7439-97-6) Nickel (7440-02-0) Selenium (7782-49-2) Silver (7440-22-4) Thallium (7440-28-0)) Zinc (7440-66-6) Wastewaters (Concentration in mg/L3; or Technology Code4) NA NA 0.69 2.77 0.69 NA 3.98 NA NA NA NA Nonwastewaters (Concentration in mg/kg5 unless noted as “mg/L TCLP”; or Technology Code) 21 11 1.22 11 0.11 11 0.60 11 0.75 11 0.025 11 11 11 5.7 11 0.14 11 0.20 11 4.3 11 Chromium(total) (7440-47-3) 2.77 0.60 11 Lead (7439-92-1) Nickel (7440-02-0) 0.69 3.98 0.75 11 NA Cadmium (7440-43-9) 0.69 0.11 11 Lead (7439-92-1) NA 0.69 NA 0.75 11 RLEAD Mercury (7439-97-6) NA 0.20 11 K071 (Brine purification muds from the mercury cell process in chlorine production, where separately prepurified brine is not used) nonwastewaters that are not residues from RMERC. Mercury (7439-97-6) NA 0.025 11 All K071 wastewaters Mercury (7439-97-6) 0.15 NA K062 Spent pickle liquor generated by steel finishing operations of facilities within the iron and steel industry (SIC Codes 331 and 332). K069 Emission control dust/sludge from secondary lead smelting. - Calcium Sulfate (Low Lead) Subcategory. Emission control dust/sludge from secondary lead smelting. - Noncalcium sulfate (High Lead) Subcategory. K071 K071 (Brine purification muds from the mercury cell process in chlorine production, where separately prepurified brine is not used) nonwastewaters that are residues from RMERC. Regulated Hazardous Constituent: Common Name; CAS2 Number 4 - 376 Hazardous Waste Waste Code; Waste Description and Treatment/Regulatory Subcategory 1 K073 Chlorinated hydrocarbon waste from the purification step of the diaphragm cell process using graphite anodes in chlorine production. K083 Distillation bottoms from aniline production. Regulated Hazardous Constituent: Common Name; CAS2 Number Wastewaters (Concentration in mg/L3; or Technology Code4) Nonwastewaters (Concentration in mg/kg5 unless noted as “mg/L TCLP”; or Technology Code) Carbon tetrachloride (56-23-5) 0.057 6.0 Chloroform (67-66-3) Hexachloroethane (67-72-1) Tetrachloroethylene (127-18-4) 1,1,1-Trichloroethane (71-55-6) 0.046 0.055 0.056 0.054 6.0 30 6.0 6.0 Aniline (62-53-3) Benzene (71-43-2) Cyclohexanone (108-94-1) Diphenylamine (difficult to distinguish from Diphenylnitrosamine) (122-39-4) Diphenylnitrosamine (difficult to distinguish from Diphenylamine) (86-306) Nitrobenzene (98-95-3) Phenol (108-95-2) Nickel (7440-02-0) 0.81 0.14 0.36 0.92 14 10 NA 13 0.92 13 0.068 0.039 3.98 14 6.2 11 11 K084 Wastewater treatment sludges generated during the production of veterinary pharmaceuticals from arsenic or organo-arsenic compounds. Arsenic (7440-38-2) 1.4 5.0 11 K085 Distillation or fractionation column bottoms from the production of chlorobenzenes. Benzene (71-43-2) 0.14 10 Chlorobenzene (108-90-7) m-Dichlorobenzene (541-73-1) o-Dichlorobenzene (95-50-1) p-Dichlorobenzene (106-46-7) Hexachlorobenzene (118-74-1) 0.057 0.036 0.088 0.090 0.055 6.0 6.0 6.0 6.0 10 4 - 377 Hazardous Waste Waste Code; Waste Description and Treatment/Regulatory Subcategory 1 Regulated Hazardous Constituent: Common Name; CAS2 Number Wastewaters (Concentration in mg/L3; or Technology Code4) 0.10 Nonwastewaters (Concentration in mg/kg5 unless noted as “mg/L TCLP”; or Technology Code) 10 0.055 0.055 0.055 10 14 19 Acetone (67-64-1) 0.28 160 Acetophenone (96-86-2) bis(2-Ethylhexyl)phthalate (117-81-7) n-Butyl alcohol (71-36-3) Butylbenzyl phthalate (85-68-7) Cyclohexanone (108-94-1) o-Dichlorobenzene (95-50-1) Diethyl phthalate (84-66-2) Dimethyl phthalate (131-11-3) Di-n-butylphthalate (84-74-2) Di-n-octylphthalate (117-84-0) Ethyl acetate (144-78-6) Ethylbenzene (100-41-4) Methanol (67-56-1) Methyl ethyl ketone (78-93-3) Methyl isobutyl ketone (108-10-1) Methylene chloride (75-09-2) Naphthalene (91-20-3) Nitrobenzene (98-95-3) Toluene (108-88-3) 1,1,1-Trichloroethane (71-55-6) Trichloroethylene (79-01-6) Xylenes-mixed isomers (sum of o-,m- 0.010 0.28 5.6 0.017 0.36 0.088 0.20 0.047 0.057 0.017 0.34 0.057 5.6 0.28 0.14 0.089 0.059 0.068 0.080 0.054 0.054 0.32 9.7 28 2.6 28 NA 6.0 28 28 28 28 33 10 NA 36 33 30 5.6 14 10 6.0 6.0 30 Total PCBs (sum of all PCB isomers, or all Aroclors) (1336-36-3) Pentachlorobenzene (608-93-5) 1,2,4,5-Tetrachlorobenzene (95-94-3) 1,2,4-Trichlorobenzene (120-82-1) K086 Solvent wastes and sludges, caustic washes and sludges, or water washes and sludges from cleaning tubs and equipment used in the formulation of ink from pigments, driers, soaps, and stabilizers containing chromium and lead. 4 - 378 Hazardous Waste Waste Code; Waste Description and Treatment/Regulatory Subcategory 1 Regulated Hazardous Constituent: Common Name; CAS2 Number Wastewaters (Concentration in mg/L3; or Technology Code4) Nonwastewaters (Concentration in mg/kg5 unless noted as “mg/L TCLP”; or Technology Code) 2.77 1.2 0.69 0.60 11 590 0.75 11 Acenaphthylene (208-96-8) Benzene (71-43-2) Chrysene (218-01-9) Fluoranthene (206-44-0) Indeno(1,2,3-cd)pyrene (193-39-5) Naphthalene (91-20-3) Phenanthrene (85-01-8) Toluene (108-88-3) Xylenes-mixed isomers (sum of o-,m,and p-xylene concentrations) (1330-207) Lead (7439-92-1) 0.059 0.14 0.059 0.068 0.0055 0.059 0.059 0.080 0.32 3.4 10 3.4 3.4 3.4 5.6 5.6 10 30 0.69 0.75 11 Acenaphthene (83-32-9) Anthracene (120-12-7) Benz(a)anthracene (56-55-3) Benzo(a)pyrene (50-32-8) Benzo(b)fluoranthene (205-99-2) Benzo(k)fluoranthene (207-08-9) Benzo(g,h,i)perylene (191-24-2) Chrysene (218-01-9) Dibenz(a,h)anthracene (53-70-3) Fluoranthene (206-44-0) Indeno(1,2,3-cd)pyrene (193-39-5) Penanthrene (85-01-8) Pyrene (129-00-0) 0.059 0.059 0.059 0.061 0.11 0.11 0.0055 0.059 0.055 0.068 0.0055 0.059 0.067 3.4 3.4 3.4 3.4 6.8 6.8 1.8 3.4 8.2 3.4 3.4 5.6 8.2 ,and p-xylene concentrations) (1330-207) Chromium (Total) (7440-47-3) Cyanides (Total)7 (57-12-5) Lead (7439-92-1) K087 Decanter tank tar sludge from coking operations. K088 Spent potliners from primary aluminum reduction. 4 - 379 Hazardous Waste Waste Code; Waste Description and Treatment/Regulatory Subcategory 1 Regulated Hazardous Constituent: Common Name; CAS2 Number Wastewaters (Concentration in mg/L3; or Technology Code4) 1.9 1.4 1.2 0.82 0.69 2.77 0.69 0.15 3.98 0.82 0.43 1.2 0.86 35 Nonwastewaters (Concentration in mg/kg5 unless noted as “mg/L TCLP”; or Technology Code) 1.15 mg/L TCLP 26.1 21 mg/L TCLP 1.22 mg/L TCLP 0.11 mg/L TCLP 0.60 mg/L TCLP 0.75 mg/L TCLP 0.025 mg/L TCLP 11 mg/L TCLP 5.7 mg/L TCLP 0.14 mg/L TCLP 590 30 NA Phthalic anhydride (measured as Phthalic acid or Terephthalic acid) (100-21-0) Phthalic anhydride (measured as Phthalic acid or Terephthalic acid) (85-44-9) 0.055 28 0.055 28 Phthalic anhydride (measured as Phthalic acid or Terephthalic acid) (100-21-0) Phthalic anhydride (measured as Phthalic acid or Terephthalic acid) (85-44-9) 0.055 28 0.055 28 Hexachloroethane (67-72-1) Pentachloroethane (76-01-7) 1,1,1,2-Tetrachloroethane (630-20-6) 1,1,2,2-Tetrachloroethane (79-34-6) Tetrachloroethylene (127-18-4) 1,1,2-Trichloroethane (79-00-5) Trichloroethylene (79-01-6) 0.055 0.055 0.057 0.057 0.056 0.054 0.054 30 6.0 6.0 6.0 6.0 6.0 6.0 Antimony (7440-36-0) Arsenic (7440-38-2) Barium (7440-39-3) Beryllium (7440-41-7) Cadmium (7440-43-9) Chromium (Total) (7440-47-3) Lead (7439-92-1) Mercury (7439-97-6) Nickel (7440-02-0) Selenium (7782-49-2) Silver (7440-22-4) Cyanide (Total)7 (57-12-5) Cyanide (Amenable)7 (57-12-5) Fluoride (16984-48-8) K093 Distillation light ends from the production of phthalic anhydride from ortho-xylene. K094 Distillation bottoms from the production of phthalic anhydride from ortho-xylene. K095 Distillation bottoms from the production of 1,1,1-trichloroethane. 4 - 380 Hazardous Waste Waste Code; Waste Description and Treatment/Regulatory Subcategory 1 K096 Heavy ends from the heavy ends column from the production of 1,1,1trichloroethane. K097 Vacuum stripper discharge from the chlordane chlorinator in the production of chlordane. K098 Untreated process wastewater from the production of toxaphene. K099 Untreated wastewater from the production of 2,4-D. Regulated Hazardous Constituent: Common Name; CAS2 Number Wastewaters (Concentration in mg/L3; or Technology Code4) Nonwastewaters (Concentration in mg/kg5 unless noted as “mg/L TCLP”; or Technology Code) m-Dichlorobenzene (541-73-1) 0.036 6.0 Pentachloroethane (76-01-7) 1,1,1,2-Tetrachloroethane (630-20-6) 1,1,2,2-Tetrachloroethane (79-34-6) Tetrachloroethylene (127-18-4) 1,2,4-Trichlorobenzene (120-82-1) 1,1,2-Trichloroethane (79-00-5) Trichloroethylene (79-01-6) 0.055 0.057 0.057 0.056 0.055 0.054 0.054 6.0 6.0 6.0 6.0 19 6.0 6.0 Chlordane (alpha and gamma isomers) (57-74-9) Heptachlor (76-44-8) Heptachlor epoxide (1024-57-3) Hexachlorocyclopentadiene (77-47-4) 0.0033 0.26 0.0012 0.016 0.057 0.066 0.066 2.4 Toxaphene (8001-35-2) 0.0095 2.6 0.72 10 0.000063 0.001 0.000063 0.001 0.000063 0.001 0.000035 0.001 0.000063 0.001 0.000063 0.001 2,4-Dichlorophenoxyacetic acid (94-757) HxCDDs (All Hexachlorodibenzo-pdioxins) (NA) HxCDFs (All Hexachlorodibenzofurans) (NA) PeCDDs (All Pentachlorodibenzo-pdioxins) (NA) PeCDFs (All Pentachlorodibenzofurans) (NA) TCDDs (All Tetrachlorodibenzo-pdioxins) (NA) TCDFs (All Tetrachlorodibenzofurans) 4 - 381 Hazardous Waste Waste Code; Waste Description and Treatment/Regulatory Subcategory 1 Regulated Hazardous Constituent: Common Name; CAS2 Number Wastewaters (Concentration in mg/L3; or Technology Code4) Nonwastewaters (Concentration in mg/kg5 unless noted as “mg/L TCLP”; or Technology Code) Cadmium (7440-43-9) 0.69 0.11 11 Chromium (Total) (7440-47-3) Lead (7439-92-1) 2.77 0.69 0.60 11 0.75 11 o-Nitroaniline (88-74-4) 0.27 14 Arsenic (7440-38-2) Cadmium (7440-43-9) Lead (7439-92-1) Mercury (7439-97-6) 1.4 0.69 0.69 0.15 5.0 11 NA NA NA o-Nitrophenol (88-75-5) 0.028 13 Arsenic (7440-38-2) Cadmium (7440-43-9) Lead (7439-92-1) Mercury (7439-97-6) 1.4 0.69 0.69 0.15 5.0 11 NA NA NA Aniline (62-53-3) 0.81 14 Benzene (71-43-2) 2,4-Dinitrophenol (51-28-5) Nitrobenzene (98-95-3) Phenol (108-95-2) 0.14 0.12 0.068 0.039 10 160 14 6.2 Aniline (62-53-3) 0.81 14 (NA) K100 Waste leaching solution from acid leaching of emission control dust/sludge from secondary lead smelting. K101 Distillation tar residues from the distillation of aniline-based compounds in the production of veterinary pharmaceuticals from arsenic or organo-arsenic compounds. K102 Residue from the use of activated carbon for decolorization in the production of veterinary pharmaceuticals from arsenic or organoarsenic compounds. K103 Process residues from aniline extraction from the production of aniline. K104 Combined wastewater streams generated from nitrobenzene/aniline production. 4 - 382 Hazardous Waste Waste Code; Waste Description and Treatment/Regulatory Subcategory 1 Regulated Hazardous Constituent: Common Name; CAS2 Number Wastewaters (Concentration in mg/L3; or Technology Code4) 0.14 0.12 0.068 0.039 1.2 Nonwastewaters (Concentration in mg/kg5 unless noted as “mg/L TCLP”; or Technology Code) 10 160 14 6.2 590 Benzene (71-43-2) 0.14 10 Chlorobenzene (108-90-7) 2-Chlorophenol (95-57-8) o-Dichlorobenzene (95-50-1) p-Dichlorobenzene (106-46-7) Phenol (108-95-2) 2,4,5-Trichlorophenol (95-95-4) 2,4,6-Trichlorophenol (88-06-2) 0.057 0.044 0.088 0.090 0.039 0.18 0.035 6.0 5.7 6.0 6.0 6.2 7.4 7.4 Mercury (7439-97-6) NA RMERC K106 (wastewater treatment sludge from the mercury cell process in chlorine production) nonwastewaters that contain less than 260 mg/kg total mercury that are residues from RMERC. Mercury (7439-97-6) NA 0.20 11 Other K106 nonwastewaters that contain less than 260 mg/kg total mercury and are not residues from RMERC. Mercury (7439-97-6) NA 0.025 11 All K106 wastewaters. Mercury (7439-97-6) 0.15 NA K107 Column bottoms from product separation from the production of 1,1dimethylhydrazine (UDMH) from carboxylic acid hydrazides. NA CMBST; or CHOXD fb CARBN; or CMBST Benzene (71-43-2) 2,4-Dinitrophenol (51-28-5) Nitrobenzene (98-95-3) Phenol (108-95-2) Cyanides (Total)7 (57-12-5) K105 Separated aqueous stream from the reactor product washing step in the production of chlorobenzene. K106 K106 (wastewater treatment sludge from the mercury cell process in chlorine production) nonwastewaters that contain greater than or equal to 260 mg/kg total mercury. 4 - 383 Hazardous Waste Waste Code; Waste Description and Treatment/Regulatory Subcategory 1 K108 Condensed column overheads from product separation and condensed reactor vent gases from the production of 1,1-dimethylhydrazine (UDMH) from carboxylic acid hydrazides. K109 Spent filter cartridges from product purification from the production of 1,1-dimethylhydrazine (UDMH) from carboxylic acid hydrazides. K110 Condensed column overheads from intermediate separation from the production of 1,1-dimethylhydrazine (UDMH) from carboxylic acid hydrazides. K111 Product washwaters from the production of dinitrotoluene via nitration of toluene. Regulated Hazardous Constituent: Common Name; CAS2 Number Wastewaters (Concentration in mg/L3; or Technology Code4) BIODG fb CARBN Nonwastewaters (Concentration in mg/kg5 unless noted as “mg/L TCLP”; or Technology Code) NA CMBST; or CHOXD fb CARBN; or BIODG fb CARBN CMBST NA CMBST; or CHOXD fb CARBN; or BIODG fb CARBN CMBST NA CMBST; or CHOXD fb CARBN; or BIODG fb CARBN CMBST 2,4-Dinitrotoluene (121-1-2) 0.32 140 2,6-Dinitrotoluene (606-20-2) 0.55 28 K112 Reaction by-product water from the drying column in the production of toluenediamine via hydrogenation of dinitrotoluene. NA CMBST; or CHOXD fb CARBN; or BIODG fb CARBN CMBST K113 Condensed liquid light ends from the purification of toluenediamine in the production of tolu enediamine via hydrogenation of dinitrotoluene. NA CARBN; or CMBST CMBST 4 - 384 Hazardous Waste Waste Code; Waste Description and Treatment/Regulatory Subcategory 1 Regulated Hazardous Constituent: Common Name; CAS2 Number Wastewaters (Concentration in mg/L3; or Technology Code4) Nonwastewaters (Concentration in mg/kg5 unless noted as “mg/L TCLP”; or Technology Code) CARBN; or CMBST CMBST 3.98 11 11 NA CARBN; or CMBST CMBST NA CARBN; or CMBST CMBST 0.11 15 0.046 0.028 6.0 15 0.11 15 0.046 0.028 6.0 15 CMBST; or CHOXD fb (BIODG or CARBN) CMBST K114 Vicinals from the purification of toluenediamine in the production of toluenediamine via hydrogenation of dinitrotoluene. NA K115 Heavy ends from the purification of toluenediamine in the production of toluenediamine via hydrogenation of dinitrotoluene. Nickel (7440-02-0) K116 Organic condensate from the solvent recovery column in the production of toluene diisocyanate via phosgenation of toluenediamine. K117 Wastewater from the reactor vent gas scrubber in the production of ethylene dibromide via bromination of ethene. K118 Spent absorbent solids from the purification of ethylene dibromide in the production of ethylene dibromide via bromination of ethene. K123 Process wastewater (including supernates, filtrates, and washwaters) from the production of ethylenebisdithiocarbamic acid and its salts. Methyl bromide (Bromomethane) (7483-9) Chloroform (67-66-3) Ethylene dibromide (1,2-Dibromoethane) (106-93-4) Methyl bromide (Bromomethane) (7483-9) Chloroform (67-66-3) Ethylene dibromide (1,2-Dibromoethane) (106-93-4) NA K124 4 - 385 Hazardous Waste Waste Code; Waste Description and Treatment/Regulatory Subcategory 1 Reactor vent scrubber water from ethylenebisdithiocarbamic acid and its salts. the production Regulated Hazardous Constituent: Common Name; CAS2 Number Wastewaters (Concentration in mg/L3; or Technology Code4) CMBST; or CHOXD fb (BIODG or CARBN) Nonwastewaters (Concentration in mg/kg5 unless noted as “mg/L TCLP”; or Technology Code) CMBST of NA K125 Filtration, evaporation, and centrifugation solids from the production of ethylenebisdithiocarbamic acid and its salts. NA CMBST; or CHOXD fb (BIODG or CARBN) CMBST NA CMBST; or CHOXD fb (BIODG or CARBN) CMBST K126 Baghouse dust and floor sweepings in milling and packaging operations from the production or formulation of ethylenebisdithiocarbamic acid and its salts. K131 Wastewater from the reactor and spent sulfuric acid from the acid dryer from the production of methyl bromide. Methyl bromide (Bromoethane) (74-839) 0.11 15 K132 Spent absorbent and wastewater separator solids from the production of methyl bromide. Methyl bromide (Bromomethane) (7483-9) 0.11 15 Methyl bromide (Bromomethane) (7483-9) Chloroform (67-66-3) Ethylene dibromide (1,2-Dibromoethane) (106-93-4) 0.11 15 0.046 0.028 6.0 15 0.35 7.4 K136 Still bottoms from the purification of ethylene dibromide in the production of ethylene dibromide via bromination of ethene. K140 Floor sweepiongs, off-specification product and spent filter media from the production of 2,4,6-tribromophenol. 2,4,6-Tribromophenol (118-79-6) K141 4 - 386 Hazardous Waste Waste Code; Waste Description and Treatment/Regulatory Subcategory 1 Process residues from the recovery of coal tar, including, but not limited to, collecting sump residues from the production of coke or the recovery of coke by-products produced from coal. This listing does not include K087 (decanter tank tar sludge from coking operations). Regulated Hazardous Constituent: Common Name; CAS2 Number Wastewaters (Concentration in mg/L3; or Technology Code4) 0.14 Nonwastewaters (Concentration in mg/kg5 unless noted as “mg/L TCLP”; or Technology Code) 10 0.059 0.061 0.11 3.4 3.4 6.8 0.11 6.8 0.059 0.055 0.0055 3.4 8.2 3.4 Benzene (71-43-2) 0.14 10 Benz(a)anthracene (56-55-3) Benzo(a)pyrene (50-32-8) Benzo(b)fluoranthene (difficult to distinguish from benzo(k)fluoranthene) (205-99-2) Benzo(k)fluoranthene (difficult to distinguish from benzo(b)fluoranthene) (207-08-9) Chrysene (218-0-9) Dibenz(a,h)anthracene (53-70-3) Indeno(1,2,3-cd)pyrene (193-39-5) 0.059 0.061 0.11 3.4 3.4 6.8 0.11 6.8 0.059 0.055 0.0055 3.4 8.2 3.4 0.14 10 Benzene (71-43-2) Benz(a)anthracene (56-55-3) Benzo(a)pyrene (50-2-8) Benzo(b)fluoranthene (difficult to distinguish from benzo(k)fluoranthene) (205-99-2) Benzo(k)fluoranthene (difficult to distinguish from benzo(b)fluoranthene) (207-08-9) Chrysene (218-01-9) Dibenz(a,h)anthracene (53-70-3) Indeno(1,2,3-cd)pyrene (193-39-5) K142 Tar storage tank residues from the production of coke from coal or from the recovery of coke by-products produced from coal. K143 Process residues from the recovery of light oil, including, but not limited to, those generated in stills, decanters, and wash oil recovery units from the recovery of coke by-products produced from coal. Benzene (71-43-2) 4 - 387 Hazardous Waste Waste Code; Waste Description and Treatment/Regulatory Subcategory 1 Regulated Hazardous Constituent: Common Name; CAS2 Number Wastewaters (Concentration in mg/L3; or Technology Code4) 0.059 0.061 0.11 Nonwastewaters (Concentration in mg/kg5 unless noted as “mg/L TCLP”; or Technology Code) 3.4 3.4 6.8 0.11 6.8 0.059 3.4 Benzene (71-43-2) 0.14 10 Benz(a)anthracene (56-55-3) Benzo(a)pyrene (50-32-8) Benzo(b)fluoranthene (difficult to distinguish from benzo(k)fluoranthene) (205-99-2) Benzo(k)fluoranthene (difficult to distinguish from benzo(b)fluoranthene) (207-08-9) Chrysene (218-01-9) Dibenz(a,h)anthracene (53-70-3) 0.059 0.061 0.11 3.4 3.4 6.8 0.11 6.8 0.059 0.055 3.4 8.2 Benzene (71-43-2) 0.14 10 0.059 0.061 0.059 0.055 0.0059 3.4 3.4 3.4 8.2 5.6 0.14 10 Benz(a)anthracene (56-55-3) Benzo(a)pyrene (50-32-8) Benzo(b)fluoranthene (difficult to distinguish from benzo(k)fluoranthene) (205-99-2) Benzo(k)fluoranthene (difficult to distinguish from benzo(b)fluoranthene) (207-08-9) Chrysene (218-01-9) K144 Wastewater sump residues from light oil refining, including, but not limited to, intercepting or contamination sump sludges from the recovery of coke by-products produced from coal. K145 Residues from naphthalene collection and recovery operations from the recovery of coke by-products produced from coal. Benz(a)anthracene (56-55-3) Benzo(a)pyrene (50-32-8) Chrysene (218-0-9) Dibenz(a,h)anthracene (53-70-3) Naphthalene (91-20-3) K147 Tar storage tank residues from coal tar refining. Benzene (71-43-2) 4 - 388 Hazardous Waste Waste Code; Waste Description and Treatment/Regulatory Subcategory 1 Regulated Hazardous Constituent: Common Name; CAS2 Number Wastewaters (Concentration in mg/L3; or Technology Code4) 0.059 0.061 0.11 Nonwastewaters (Concentration in mg/kg5 unless noted as “mg/L TCLP”; or Technology Code) 3.4 3.4 6.8 0.11 6.8 0.059 0.055 0.0055 3.4 8.2 3.4 Benz(a)anthracene (56-55-3) 0.059 3.4 Benzo(a)pyrene (50-32-8) Benzo(b)fluoranthene (difficult to distinguish from benzo(k)fluoranthene) (205-99-2) Benzo(k)fluoranthene (difficult to distinguish from benzo(b)fluoranthene) (207-08-9) Chrysene (218-01-9) Dibenz(a,h)anthracene (53-70-3) Indeno(1,2,3-cd)pyrene (193-39-5) 0.061 0.11 3.4 6.8 0.11 6.8 0.059 0.055 0.0055 3.4 8.2 3.4 Chlorobenzene (108-90-7) 0.057 6.0 Chloroform (67-66-3) Chloromethane (74-87-3) p-Dichlorobenzene (106-46-7) Hexachlorobenzene (118-74-1) 0.046 0.19 0.090 0.055 6.0 30 6.0 10 Benz(a)anthracene (56-55-3) Benzo(a)pyrene (50-32-8) Benzo(b)fluoranthene (difficult to distinguish from benzo(k)fluoranthene) (205-99-2) Benzo(k)fluoranthene (difficult to distinguish from benzo(b)fluoranthene) (207-08-9) Chrysene (218-01-9) Dibenz(a,h)anthracene (53-70-3) Indeno(1,2,3-od)pyrene (193-39-5) K148 Residues from coal tar distillation, including, but not limited to, still bottoms. K149 Distillation bottoms from the production of alpha- (or methyl-) chlorinated toluenes, ring-chlorinated toluenes, benzoyl chlorides, and compounds with mixtures of these functional groups. (This waste does not include still bottoms from the distillations of benzyl chloride.) 4 - 389 Hazardous Waste Waste Code; Waste Description and Treatment/Regulatory Subcategory 1 Regulated Hazardous Constituent: Common Name; CAS2 Number Wastewaters (Concentration in mg/L3; or Technology Code4) 0.055 0.055 0.080 Nonwastewaters (Concentration in mg/kg5 unless noted as “mg/L TCLP”; or Technology Code) 10 14 10 Carbon tetrachloride (56-23-5) 0.057 6.0 Chloroform (67-66-3) Chloromethane (74-87-3) p-Dichlorobenzene (106-46-7) Hexachlorobenzene (118-74-1) Pentachlorobenzene (608-93-5) 1,2,4,5-Tetrachlorobenzene (95-94-3) 1,1,2,2-Tetrachloroethane (79-34-5) Tetrachloroethylene (127-18-4) 1,2,4-Trichlorobenzene (120-82-1) 0.046 0.19 0.090 0.055 0.055 0.055 0.057 0.056 0.055 6.0 30 6.0 10 10 14 6.0 6.0 19 Benzene (71-43-2) 0.14 10 Carbon tetrachloride (56-23-5) Chloroform (67-66-3) Hexachlorobenzene (118-74-1) Pentachlorobenzene (608-93-5) 1,2,4,5-Tetrachlorobenzene (95-94-3) Tetrachloroethylene (127-18-4) Toluene (108-88-3) 0.057 0.046 0.055 0.055 0.055 0.056 0.080 6.0 6.0 10 10 14 6.0 10 5.6 1.8 Pentachlorobenzene (608-93-5) 1,2,4,5-Tetrachlorobenzene (95-94-3) Toluene (108-88-3) K150 Organic residuals, excluding spent carbon adsorbent, from the spent chlorine gas and hydrochloric acid recovery processes associated with the production of alpha- (or methyl-) chlorinated toluenes, ringchlorinated toluenes, benzoyl chlorides, and compounds with mixtures of these functional groups. K151 Wastewater treatment sludges, excluding neutralization and biological sludges, generated during the treatment of wastewaters from the production of alpha- (or methyl-) chlorinate toluenes, ring-chlorinated toluenes, benzoyl chlorides, and compounds with mixtures of these functional groups. K156 Organic waste (including heavy ends, still bottoms, light ends, spent Acetonitrile (75-05-8) 4 - 390 Hazardous Waste Waste Code; Waste Description and Treatment/Regulatory Subcategory 1 Regulated Hazardous Constituent: Common Name; CAS2 Number Wastewaters (Concentration in mg/L3; or Technology Code4) Nonwastewaters (Concentration in mg/kg5 unless noted as “mg/L TCLP”; or Technology Code) Acetophenone (96-86-2) Aniline (62-53-3) Benomyl (17804-35-2) Benzene (71-43-2) Carbaryl (63-25-2) Carbenzadim (10605-21-7) Carbofuran (1563-66-2) Carbosulfan (55285-14-8) Chlorobenzene (108-90-7) Chloroform (67-66-3) o-Dichlorobenzene (95-50-1) Methomyl (16752-77-5) Methylene chloride (75-09-2) Methyl ethyl ketone (78-93-3) Naphthalene (91-20-3) Phenol (108-95-2) Pyridine (110-86-1) Toluene (108-88-3) Triethylamine (121-44-8) 0.010 0.81 0.056 0.14 0.006 0.056 0.006 0.028 0.057 0.046 0.088 0.028 0.089 0.28 0.059 0.039 0.014 0.080 0.081 9.7 14 1.4 10 0.14 1.4 0.14 1.4 6.0 6.0 6.0 0.14 30 36 5.6 6.2 16 10 1.5 Carbon tetrachloride (56-23-5) 0.057 6.0 Chloroform (67-66-3) Chloromethane (74-87-3) Methomyl (16752-77-5) Methylene chloride (75-09-2) Methyl ethyl ketone (78-93-3) Pyridine (110-86-1) Triethylamine (121-44-8) 0.046 0.19 0.028 0.089 0.28 0.014 0.081 6.0 30 0.14 30 36 16 1.5 solvents, filtrates, and decantates) from the production of carbamates and carbamoyl oximes. 10 K157 Wastewater (including scrubber waters, condenser waters, washwaters, and separation waters) from the production of carbamates and carbamoly oximes. 4 - 391 Hazardous Waste Waste Code; Waste Description and Treatment/Regulatory Subcategory 1 K158 Bag house dusts and filter/separation solids from the production of carbamates and carbamoly oximes. K159 Organics from the treatment of thiocarbamate wastes.10 K161 Purification solids (including filtration, evaporation, and centrifugation solids), baghouse dust and floor sweepings from the production of dithiocarbamate acids and their salts. Regulated Hazardous Constituent: Common Name; CAS2 Number Wastewaters (Concentration in mg/L3; or Technology Code4) Nonwastewaters (Concentration in mg/kg5 unless noted as “mg/L TCLP”; or Technology Code) Benomyl (17804-35-2) 0.056 1.4 Benzene (71-43-2) Carbenzadim (10605-21-7) Carbofuran (1563-66-2) Carbosulfan (55285-14-8) Chloroform (67-66-3) Methylene chloride (75-09-2) Phenol (108-95-2) 0.14 0.056 0.006 0.028 0.046 0.089 0.039 10 1.4 0.14 1.4 6.0 30 6.2 Benzene (71-43-2) Butylate (2008-41-5) EPTC (Eptam) (759-94-4) Molinate (2212-67-1) Pebulate (1114-71-2) Vernolate (1929-77-7) 0.14 0.042 0.042 0.042 0.042 0.042 10 1.4 1.4 1.4 1.4 1.4 1.9 1.1511 1.4 3.8 0.028 0.69 3.98 0.82 5.011 4.811 2811 0.7511 1111 5.711 Antimony (7440-36-0) Arsenic (7440-38-2) Carbon disulfide (75-15-0) Dithiocarbamates (total) (137-30-4) Lead (7439-92-1) Nickel (7440-02-0) Selenium (7782-49-2) K169 Crude oil tank sediment petroleum refining operations. from Benz(a)anthracene (56-55-3) 0.059 3.4 Benzene (71-43-2) Benzo(g,h,i)perylene (191-24-2) 0.14 0.0055 10 1.8 4 - 392 Hazardous Waste Waste Code; Waste Description and Treatment/Regulatory Subcategory 1 K170 Clarified slurry oil sediment from petroleum refining operations. K171 Spent hydrotreating catalyst from petroleum refining operations, including guard beds used to desulfurize feeds to other catalytic reactors (this listing does not include inert support media.). Regulated Hazardous Constituent: Common Name; CAS2 Number Wastewaters (Concentration in mg/L3; or Technology Code4) Nonwastewaters (Concentration in mg/kg5 unless noted as “mg/L TCLP”; or Technology Code) 3.4 10 3.4 5.6 5.6 8.2 10 30 Chrysene (218-01-9) Ethyl benzene (100-41-4) Fluorene(86-73-7) Naphthalene (91-20-3) Phenanthrene (81-05-8) Pyrene (129-00-0) Toluene (Methyl Benzene) (108-88-3) Xylene(s) (Total) (1330-20-7) 0.059 0.057 0.059 0.059 0.059 0.067 0.080 0.32 Benz(a)anthracene (56-55-3) 0.059 3.4 Benzene (71-43-2) Benzo(g,h,i)perylene (191-24-2) Chrysene (218-01-9) Dibenz(a,h)anthracene(53-70-3) Ethyl benzene (100-41-4) Fluorene(86-73-7) Indeno(1,2,3,-cd)pyrene(193-39-5) Naphthalene (91-20-3) Phenanthrene (81-05-8) Pyrene (129-00-0) Toluene (Methyl Benzene) (108-88-3) Xylene(s) (Total) (1330-20-7) 0.14 0.0055 0.059 0.055 0.057 0.059 0.0055 0.059 0.059 0.067 0.080 0.32 10 1.8 3.4 8.2 10 3.4 3.4 5.6 5.6 8.2 10 30 Benz(a)anthracene (56-55-3) 0.059 3.4 Benzene (71-43-2) Chrysene (218-01-9) 0.14 0.059 10 3.4 4 - 393 Hazardous Waste Waste Code; Waste Description and Treatment/Regulatory Subcategory 1 Regulated Hazardous Constituent: Common Name; CAS2 Number Ethyl benzene (100-41-4) Naphthalene (91-20-3) Phenanthrene (81-05-8) Pyrene (129-00-0) Toluene (Methyl Benzene) (108-88-3) Xylene(s) (Total) (1330-20-7) Arsenic(7740-38-2) K174 Wastewater treatment sludges from the production of ethylene dichloride or vinyl chloride monomer. Nonwastewaters (Concentration in mg/kg5 unless noted as “mg/L TCLP”; or Technology Code) 10 5.6 5.6 8.2 10 30 5 11 3.98 4.3 DEACT 11.0 11 1.6 11 DEACT 0.14 10 Ethyl benzene (100-41-4) Toluene (Methyl Benzene) (108-88-3) Xylene(s) (Total) (1330-20-7) Antimony(7740-36-0) Arsenic(7740-38-2) Nickel(7440-02-0) Vanadium(7440-62-2) Reactive sulfides (NA) 0.057 0.080 0.32 1.9 1.4 3.98 4.3 DEACT 10 10 30 1.15 11 5 11 11.0 11 1.6 11 DEACT 1,2,3,4,6,7,8-Heptachlorodibenzo-pdioxin (1,2,3,4,6,7,8-HpCDD (3582246-9) 1,2,3,4,6,7,8-Heptachlorodfuran (1,2,3,4,6,7,8-HpCDF (67562-39-4) 1,2,3,4,7,8,9-Heptachlorodfuran 0.000035 or CMBST11 0.0025 or CMBST11 0.000035 or CMBST11 0.0025 or CMBST11 0.000035 or CMBST11 0.0025 or CMBST11 Nickel(7440-02-0) Vanadium(7440-62-2) Reactive sulfides (NA) K172 Spent hydrorefining catalyst from petroleum refining operations, including guard beds used to desulfurize feeds to other catalytic reactors (this listing does not include inert support media.). 0.057 0.059 0.059 0.067 0.080 0.32 1.4 Wastewaters (Concentration in mg/L3; or Technology Code4) Benzene (71-43-2) 4 - 394 Hazardous Waste Waste Code; Waste Description and Treatment/Regulatory Subcategory 1 Regulated Hazardous Constituent: Common Name; CAS2 Number (1,2,3,4,7,8,9-HpCDF (55673-89-7) HxCDDs (All Hexachlorodibenzofurans) (34465-468) HxCDFs (All Hexachlorodibenzofurans) (55684-941) 1,2,3,4,6,7,8,9-Octachlorodibenzo-pdioxin (OCDD) (3268-87-9) 1,2,3,4,6,7,8,9Octachlorodibenzofuran (OCDF) (39001-02-0) PeCDDS (All Pentachlorodibenzo-pduioxins) (36088-22-9) PeCDFs (All Pentachlorodibenzofurans) (30402-154) TCDDs (All Tetrachlorodibenzo-pdioxins) (41903-57-5) TCDFs (All tetrachlorodibenzofurans) (55722-27-5) Arsenic (7440-36-0 K175 Wastewater treatment sludge from the production of vinyl chloride monomer using mercuric chloride catalyst in an acetylene-based process. Wastewaters (Concentration in mg/L3; or Technology Code4) Nonwastewaters (Concentration in mg/kg5 unless noted as “mg/L TCLP”; or Technology Code) 0.000063 or CMBST11 0.0001 or CMBST11 0.000063 or CMBST11 0.0001 or CMBST11 0.000063 or CMBST11 0.0001 or CMBST11 0.000063 or CMBST11 0.0001 or CMBST11 0.000063 or CMBST11 0.0001 or CMBST11 0.000063 or CMBST11 0.0001 or CMBST11 0.000063 or CMBST11 0.0001 or CMBST11 0.000063 or CMBST11 0.0001 or CMBST11 1.4 5.0 mg/l TCLP Mercury 12 (7438-97-6) NA 0.024 mg/l TCLP PH 12 Mecury (7438-97-6) NA 0.15 PH </= 6.0 NA All K175 wastewaters P001 Warfarin and salts when present at concentrations greater than 0.3 percent. Warfarin (81-81-2) (WETOX or CHOXD) fb CARBN; or CMBST 4 - 395 Hazardous Waste Waste Code; Waste Description and Treatment/Regulatory Subcategory 1 Regulated Hazardous Constituent: Common Name; CAS2 Number Wastewaters (Concentration in mg/L3; or Technology Code4) CMBST Nonwastewaters (Concentration in mg/kg5 unless noted as “mg/L TCLP”; or Technology Code) (WETOX or CHOXD) fb CARBN; or CMBST CMBST P002 1-Acetyl-2-thiourea 1-Acetyl-2-thiourea (591-08-2) P003 Acrolein Acrolein (107-02-8) 0.29 CMBST P004 Aldrin Aldrin (309-00-2) 0.021 0.066 P005 Allyl alcohol Allyl alcohol (107-18-6) (WETOX or CHOXD) fb CARBN; or CMBST CMBST P006 Aluminum phosphide Aluminum phosphide (20859-73-8) CHOXD; CHRED; or CMBST CHOXD; CHRED; or CMBST P007 5-Aminomethyl 3-isoxazolol 5-Aminomethyl 3-isoxazolol (2763-96-4) (WETOX or CHOXD) fb CARBN; or CMBST CMBST P008 4-Aminopyridine 4-Aminopyridine (504-24-5) (WETOX or CHOXD) fb CARBN; or CMBST CMBST P009 Ammonia picrate Ammonia picrate (131-74-8) CHOXD; CHRED; CARBN; BIODG; CHOXD; CHRED; or CMBST 4 - 396 Hazardous Waste Waste Code; Waste Description and Treatment/Regulatory Subcategory 1 Regulated Hazardous Constituent: Common Name; CAS2 Number Wastewaters (Concentration in mg/L3; or Technology Code4) or CMBST Nonwastewaters (Concentration in mg/kg5 unless noted as “mg/L TCLP”; or Technology Code) P010 Arsenic acid Arsenic (7440-38-2) 1.4 5.0 11 P011 Arsenic pentoxide Arsenic (7440-38-2) 1.4 5.0 11 P012 Arsenic trioxide Arsenic (7440-38-2) 1.4 5.0 11 Cyanides (Total)7 (57-12-5) Cyanides (Amenable)7 (57-12-5) Barium (7440-39-3) 1.2 0.86 NA 590 30 21 11 P013 Barium cyanide P014 Thiophenol (Benzenethiol) Thiophenol (Benzenethiol) (108-98-5) (WETOX or CHOXD) fb CARBN; or CMBST CMBST P015 Beryllium dust Beryllium (7440-41-7) RMETL; or RTHRM RMETL; or RTHRM P016 Dichloromethyl ether (Bis(chloromethyl)ether) Dichloromethyl ether (542-88-1) (WETOX or CHOXD) fb CARBN; or CMBST CMBST P017 Bromoacetone Bromoacetone (598-31-2) (WETOX or CHOXD) fb CARBN; or CMBST CMBST P018 4 - 397 Hazardous Waste Waste Code; Waste Description and Treatment/Regulatory Subcategory 1 Brucine P020 2-sec-Butyl-4,6-dinitrophenol (Dinoseb) P021 Calcium cyanide P022 Carbon disulfide Regulated Hazardous Constituent: Common Name; CAS2 Number Wastewaters (Concentration in mg/L3; or Technology Code4) (WETOX or CHOXD) fb CARBN; or CMBST Nonwastewaters (Concentration in mg/kg5 unless noted as “mg/L TCLP”; or Technology Code) CMBST 2-sec-Butyl-4,6-dinitrophenol (Dinoseb) (88-85-7) 0.066 2.5 Cyanides (Total)7 (57-12-5) Cyanides (Amenable)7 (57-12-5) 1.2 0.86 590 30 Carbon disulfide (75-15-0) Carbon disulfide; alternate6 standard for nonwastewaters only (75-15-0) 3.8 NA CMBST 4.8 11 (WETOX or CHOXD) fb CARBN; or CMBST CMBST 0.46 16 Brucine (357-57-3) P023 Chloroacetaldehyde Chloroacetaldehyde (107-20-0) P024 p-Chloroaniline p-Chloroaniline (106-47-8) P026 1-(o-Chlorophenyl)thiourea 1-(o-Chlorophenyl)thiourea (5344-82-1) (WETOX or CHOXD) fb CARBN; or CMBST CMBST P027 3-Chloropropionitrile 3-Chloropropionitrile (542-76-7) (WETOX or CHOXD) fb CARBN; or CMBST CMBST P028 4 - 398 Hazardous Waste Waste Code; Waste Description and Treatment/Regulatory Subcategory 1 Benzyl chloride P029 Copper cyanide P030 Cyanides (soluble salts and complexes) Regulated Hazardous Constituent: Common Name; CAS2 Number Wastewaters (Concentration in mg/L3; or Technology Code4) (WETOX or CHOXD) fb CARBN; or CMBST Nonwastewaters (Concentration in mg/kg5 unless noted as “mg/L TCLP”; or Technology Code) CMBST Cyanides (Total)7 (57-12-5) Cyanides (Amenable)7 (57-12-5) 1.2 0.86 590 30 Cyanides (Total)7 (57-12-5) Cyanides (Amendable)7 (57-12-5) 1.2 0.86 590 30 Benzyl chloride (100-44-7) P031 Cyanogen Cyanogen (460-19-5) CHOXD; WETOX; or CMBST CHOXD; WETOX; or CMBST P033 Cyanogen chloride Cyanogen chloride (506-77-4) CHOXD; WETOX; or CMBST CHOXD; WETOX; or CMBST 2-Cyclohexyl-4,6-dinitrophenol (131-895) (WETOX or CHOXD) fb CARBN; or CMBST CMBST 1.4 5.0 11 0.017 0.13 1.4 5.0 11 P034 2-Cyclohexyl-4,6-dinitrophenol P036 Dichlorophenylarsine Arsenic (7440-38-2) P037 Dieldrin Dieldrin (60-57-1) P038 Diethylarsine Arsenic (7440-38-2) P039 4 - 399 Hazardous Waste Waste Code; Waste Description and Treatment/Regulatory Subcategory 1 Wastewaters (Concentration in mg/L3; or Technology Code4) 0.017 Nonwastewaters (Concentration in mg/kg5 unless noted as “mg/L TCLP”; or Technology Code) 6.2 O,O-Diethyl-O-pyrazinyl phosphorothioate (297-97-2) CARBN; or CMBST CMBST Diethyl-p-nitrophenyl phosphate (31145-5) CARBN; or CMBST CMBST Epinephrine (51-43-4) (WETOX or CHOXD) fb CARBN; or CMBST CMBST Diisopropylfluorophosphate (DFP) (5591-4) CARBN or CMBST CMBST P044 Dimethoate Dimethoate (60-51-5) CARBN; or CMBST CMBST P045 Thiofanox Thiofanox (39196-18-4) (WETOX or CHOXD) fb CARBN; or CMBST CMBST alpha, alpha-Dimethylphenethylamine (122-09-8) (WETOX or CHOXD) fb CARBN; or CMBST CMBST 0.28 160 (WETOX or CMBST Disulfoton P040 O,O-Diethyl-O-pyrazinyl phosphorothioate P041 Diethyl-p-nitrophenyl phosphate P042 Epinephrine P043 Diisopropylfluorophosphate (DFP) P046 alpha, alpha-Dimethylphenethylamine Regulated Hazardous Constituent: Common Name; CAS2 Number Disulfoton (298-04-4) P047 4,6-Dinitro-o-cresol 4,6-Dinitro-o-cresol (543-52-1) 4,6-Dinitro-o-cresol salts NA 4 - 400 Hazardous Waste Waste Code; Waste Description and Treatment/Regulatory Subcategory 1 Regulated Hazardous Constituent: Common Name; CAS2 Number Wastewaters (Concentration in mg/L3; or Technology Code4) CHOXD) fb CARBN; or CMBST Nonwastewaters (Concentration in mg/kg5 unless noted as “mg/L TCLP”; or Technology Code) 0.12 160 (WETOX or CHOXD) fb CARBN; or CMBST CMBST Endosulfan I (939-98-8) Endosulfan II (33213-6-5) Endosulfan sulfate (1031-07-8) 0.023 0.029 0.029 0.066 0.13 0.13 Endrin (72-20-8) Endrin aldehyde (7421-93-4) 0.0028 0.025 0.13 0.13 (WETOX or CHOXD) fb CARBN; or CMBST CMBST 35 ADGAS fb NEUTR P048 2,4-Dinitrophenol 2,4-Dinitrophenol (51-28-5) P049 Dithiobiuret Dithiobiuret (541-53-7) P050 Endosulfan P051 Endrin P054 Aziridine P056 Fluorine Aziridine (151-56-4) Fluoride (measured in wastewaters only) (16964-48-8) P057 Fluoroacetamide Fluoroacetamide (640-19-7) (WETOX or CHOXD) fb CARBN; or CMBST CMBST P058 Fluoroacetic acid, sodium salt Fluoroacetic acid, sodium salt (62-74-8) (WETOX or CMBST 4 - 401 Hazardous Waste Waste Code; Waste Description and Treatment/Regulatory Subcategory 1 Wastewaters (Concentration in mg/L3; or Technology Code4) CHOXD) fb CARBN; or CMBST Nonwastewaters (Concentration in mg/kg5 unless noted as “mg/L TCLP”; or Technology Code) Heptachlor (76-44-8) Heptachlor epoxide (1024-57-3) 0.0012 0.016 0.066 0.066 P060 Isodrin Isodrin (465-73-6) 0.021 0.066 P062 Hexaethyl tetraphosphate Hexaethyl tetraphosphate (757-58-4) CARBN; or CMBST CMBST 1.2 0.86 590 30 (WETOX or CHOXD) fb CARBN; or CMBST CMBST Mercury (7439-97-6) NA IMERC Mercury fulminate nonwastewaters that are either incinerator residues or are residues from RMERC, and contain greater than or equal to 260 mg/kg total mercury. Mercury (7439-97-6) NA RMERC Mercury fulminate nonwastewaters that are residues from RMERC and contain less than 260 mg/kg total mercury. Mercury (7439-97-6) NA 0.20 11 Mercury fulminate nonwastewaters that are incinerator residues and Mercury (7439-97-6) NA 0.025 11 P059 Heptachlor P063 Hydrogen cyanide P064 Isocyanic acid, ethyl ester P065 Mercury fulminate nonwastewaters, regardless of their total mercury content, that are not incinerator residues or are not residues from RMERC. Regulated Hazardous Constituent: Common Name; CAS2 Number Cyanides (Total)7 (57-12-5) Cyanides (Amenable)7 (57-12-5) Isocyanic acid, ethyl ester (624-83-9) 4 - 402 Hazardous Waste Waste Code; Waste Description and Treatment/Regulatory Subcategory 1 Regulated Hazardous Constituent: Common Name; CAS2 Number Wastewaters (Concentration in mg/L3; or Technology Code4) Nonwastewaters (Concentration in mg/kg5 unless noted as “mg/L TCLP”; or Technology Code) 0.15 NA contain less than 260 mg/ kg total mercury. All mercury fulminate wastewaters. Mercury (7439-97-6) P066 Methomyl Methomyl (16752-77-5) (WETOX or CHOXD) fb CARBN; or CMBST CMBST P067 2-Methyl-aziridine 2-Methyl-aziridine (75-55-8) (WETOX or CHOXD) fb CARBN; or CMBST CMBST P068 Methyl hydrazine Methyl hydrazine (60-34-4) CHOXD; CHRED; CARBN; BIODG; or CMBST CHOXD; CHRED; or CMBST P069 2-Methyllactonitrile 2-Methyllactonitrile (75-86-5) (WETOX or CHOXD) fb CARBN; or CMBST CMBST P070 Aldicarb Aldicarb (116-06-3) (WETOX or CHOXD) fb CARBN; or CMBST CMBST P071 Methyl parathion Methyl parathion (298-00-0) 0.014 4.6 P072 1-Naphthyl-2-thiourea 1-Naphthyl-2-thiourea (86-88-4) (WETOX or CMBST 4 - 403 Hazardous Waste Waste Code; Waste Description and Treatment/Regulatory Subcategory 1 P073 Nickel carbonyl P074 Nickel cyanide Regulated Hazardous Constituent: Common Name; CAS2 Number Wastewaters (Concentration in mg/L3; or Technology Code4) CHOXD) fb CARBN; or CMBST Nonwastewaters (Concentration in mg/kg5 unless noted as “mg/L TCLP”; or Technology Code) Nickel (7440-02-0) 3.98 11 11 Cyanides (Total)7 (57-12-5) Cyanides (Amenable)7 (57-12-5) Nickel (7440-02-0) 1.2 0.85 3.98 590 30 11 11 (WETOX or CHOXD) fb CARBN; or CMBST CMBST P075 Nicotine and salts Nicotine and salts (54-11-5) P076 Nitric oxide Nitric oxide (10102-43-9) ADGAS ADGAS P077 p-Nitroaniline p-Nitroaniline (100-01-6) 0.028 28 P078 Nitrogen dioxide Nitrogen dioxide (10102-44-0) ADGAS ADGAS P081 Nitroglycerin Nitroglycerin (55-63-0) CHOXD; CHRED; CARBN; BIODG; or CMBST CHOXD; CHRED; or CMBST P082 N-Nitrosodimethylamine N-Nitrosodimethylamine (62-75-9) 0.40 2.3 P084 N-Nitrosomethylvinylamine N-Nitrosomethylvinylamine (4549-40-0) (WETOX or CMBST 4 - 404 Hazardous Waste Waste Code; Waste Description and Treatment/Regulatory Subcategory 1 Regulated Hazardous Constituent: Common Name; CAS2 Number Wastewaters (Concentration in mg/L3; or Technology Code4) CHOXD) fb CARBN; or CMBST Nonwastewaters (Concentration in mg/kg5 unless noted as “mg/L TCLP”; or Technology Code) Octamethylpyrophosphoramide (152-169) CARBN; or CMBST CMBST P087 Osmium tetroxide Osmium tetroxide (20816-12-0) RMETL; or RTHRM RMETL; or RTHRM P088 Endothall Endothall (145-73-3) (WETOX or CHOXD) fb CARBN; or CMBST CMBST P089 Parathion Parathion (56-38-2) 0.014 4.6 Mercury (7439-97-6) NA IMERC; or RMERC Phenyl mercuric acetate nonwastewaters that are either incinerator residues or are residues from RMERC, and still contain greater than or equal to 260 mg/kg total mercury. Mercury (7439-97-6) NA RMERC Phenyl mercuric acetate nonwastewaters that are residues from RMERC and contain less than 260 mg/kg total mercury. Mercury (7439-97-6) NA 0.20 11 Phenyl mercuric acetate nonwastewaters that are incinerator residues and contain less than 260 mg/kg total mercury. Mercury (7439-97-6) NA 0.025 11 All phenyl mercuric acetate wastewaters. Mercury (7439-97-6) 0.15 NA P085 Octamethylpyrophosphoramide P092 Phenyl mercuric acetate nonwastewaters, regardless of their mercury content, that are not incinerator residues or are not residues from RMERC. 4 - 405 Hazardous Waste Waste Code; Waste Description and Treatment/Regulatory Subcategory 1 Regulated Hazardous Constituent: Common Name; CAS2 Number Wastewaters (Concentration in mg/L3; or Technology Code4) Nonwastewaters (Concentration in mg/kg5 unless noted as “mg/L TCLP”; or Technology Code) (WETOX or CHOXD) fb CARBN; or CMBST CMBST P093 Phenylthiouea Phenylthiouea (103-85-5) P094 Phorate Phorate (298-02-2) 0.021 4.6 P095 Phosgene Phosgene (75-44-5) (WETOX or CHOXD) fb CARBN; or CMBST CMBST P096 Phosphine Phosphine (7803-51-2) CHOXD; CHRED; or CMBST CHOXD; CHRED; or CMBST P097 Famphur Famphur (52-85-7) 0.017 15 Cyanides (Total)7 (57-12-5) Cyanides (Amenable)7 (57-12-5) 1.2 0.86 590 30 Cyanides (Total)7 (57-12-5) Cyanides (amenable)7 (57-12-5) Silver (7440-22-4) 1.2 0.86 0.43 590 30 0.14 11 Ethyl cyanide (Propanenitrile) (107-120) 0.24 360 (WETOX or CHOXD) fb CMBST P098 Potassium cyanide P099 Potassium silver cyanide P101 Ethyl cyanide (Propanenitrile) P102 Propargyl alcohol Propargyl alcohol (107-19-7) 4 - 406 Hazardous Waste Waste Code; Waste Description and Treatment/Regulatory Subcategory 1 P103 Selenourea P104 Silver cyanide P105 Sodium azide P106 Sodium cyanide P108 Strychnine and salts P109 Tetraethyldithiopyrophosphate Regulated Hazardous Constituent: Common Name; CAS2 Number Wastewaters (Concentration in mg/L3; or Technology Code4) CARBN; or CMBST Nonwastewaters (Concentration in mg/kg5 unless noted as “mg/L TCLP”; or Technology Code) Selenium (7782-49-2) 0.82 5.7 11 Cyanides (Total)7 (57-12-5) Cyanides (Amendable)7 (57-12-5) Silver (7440-22-4) 1.2 0.86 0.43 590 30 0.14 11 CHOXD; CARBN; CHRED; BIODG; or CMBST CHOXD; CHRED; or CMBST 1.2 0.86 590 30 Strychnine and salts (57-24-9) (WETOX or CHOXD) fb CARBN; or CMBST CMBST Tetraethyldithiopyrophosphate (3689-245) CARBN; or CMBST CMBST 0.69 0.75 11 CARBN; or CMBST CMBST CHOXD; CARBN; CHRED; BIODG; CHOXD; CHRED; or CMBST Sodium azide (26628-22-8) Cyanides (Total)7 (57-12-5) Cyanides (Amenable)7 (57-12-5) P110 Tetraethyl lead Lead (7439-92-1) P111 Tetraethylpyrophosphate Tetraethylpyrophosphate (107-49-3) P112 Tetranitromethane Tetranitromethane (509-14-8) 4 - 407 Hazardous Waste Waste Code; Waste Description and Treatment/Regulatory Subcategory 1 P113 Thallic oxide P114 Thallium selenite P115 Thallium(1)sulfate Regulated Hazardous Constituent: Common Name; CAS2 Number Wastewaters (Concentration in mg/L3; or Technology Code4) or CMBST Nonwastewaters (Concentration in mg/kg5 unless noted as “mg/L TCLP”; or Technology Code) Thallium (measured in wastewaters only) (7440-28-0) 1.4 RTHRM; or STABL Selenium (7782-49-2) 0.82 5.7 11 Thallium (measured in wastewaters only) (7440-28-0) 1.4 RTHRM; or STABL P116 Thiosemicarbazide Thiosemicarbazide (79-19-6) (WETOX or CHOXD) fb CARBN; or CMBST CMBST P118 Trichloromethanethiol Trichloromethanethiol (75-70-7) (WETOX or CHOXD) fb CARBN; or CMBST CMBST Vanadium (measured in wastewaters only)(7440-62-2) 4.3 STABL Vanadium (measured in wastewaters only)(7440-62-2) 4.3 STABL Cyanides (Total)7 (57-12-5) Cyanides (Amenable)7 (57-12-5) 1.2 0.86 590 30 CHOXD; CHRED; or CMBST CHOXD; CHRED; or CMBST P119 Ammonia vanadate P120 Vanadium pentoxide P121 Zinc cyanide P122 Zinc phosphide, Zn3P2, when present at concentrations greater than 10%. P123 Zinc Phosphide (1314-84-7) 4 - 408 Hazardous Waste Waste Code; Waste Description and Treatment/Regulatory Subcategory 1 Regulated Hazardous Constituent: Common Name; CAS2 Number Toxaphene Toxaphene (8001-35-2) Wastewaters (Concentration in mg/L3; or Technology Code4) 0.0095 Nonwastewaters (Concentration in mg/kg5 unless noted as “mg/L TCLP”; or Technology Code) 2.6 P127 Carbofuran Carbofuran (1563-66-2) 0.006 0.14 P128 Mexacarbate Mexacarbate (315-18-4) 0.056 1.4 P185 Tirpate10 Tirpate (26419-73-8) 0.056 0.28 P188 Physostigmine salicylate Physostigmine salicylate (57-64-7) 0.056 1.4 P189 Carbosulfan Carbosulfan (55285-14-8) 0.028 1.4 P190 Metolcarb Metolcarb (1129-41-5) 0.056 1.4 P191 Dimetilan10 Dimetilan (644-64-4) 0.056 1.4 P192 Isolan10 Isolan (119-38-0) 0.056 1.4 P194 Oxamyl Oxamyl (23135-22-0) 0.056 0.028 P196 Manganese dimethyldithiocarbamate Dithiocarbamates (Total) NA 0.028 28 P197 4 - 409 Hazardous Waste Waste Code; Waste Description and Treatment/Regulatory Subcategory 1 Regulated Hazardous Constituent: Common Name; CAS2 Number Wastewaters (Concentration in mg/L3; or Technology Code4) 0.056 Nonwastewaters (Concentration in mg/kg5 unless noted as “mg/L TCLP”; or Technology Code) 1.4 Formparanate10 Formparanate (17702-57-7) P198 Formetanate hydrochloride Formetanate hydrochloride (23422-53-9) 0.056 1.4 P199 Methiocarb Methiocarb (2032-65-7) 0.056 1.4 P201 Promecarb Promecarb (2631-37-0) 0.056 1.4 P202 m-Cumenyl methylcarbamate m-Cumenyl methylcarbamate (64-00-6) 0.056 1.4 P203 Aldicarb sulfone Aldicarb sulfone (1646-88-4) 0.056 0.28 P204 Physostigmine Physostigmine(57-47-6) 0.056 1.4 P205 Ziram Dithiocarbamates (Total) NA 0.028 28 U001 Acetaldehyde Acetaldehyde (75-07-0) (WETOX or CHOXD) fb CARBN; or CMBST CMBST U002 Acetone Acetone (67-64-1) 0.28 160 U003 Acetonitrile Acetonitrile (75-05-8) 5.6 CMBST 4 - 410 Hazardous Waste Waste Code; Waste Description and Treatment/Regulatory Subcategory 1 Regulated Hazardous Constituent: Common Name; CAS2 Number Acetonitrile; alternate6 standard nonwastewaters only (75-05-8) for Wastewaters (Concentration in mg/L3; or Technology Code4) NA Nonwastewaters (Concentration in mg/kg5 unless noted as “mg/L TCLP”; or Technology Code) 38 U004 Acetophenone Acetophenone (98-86-2) 0.010 9.7 U005 2-Acetylaminofluorene 2-Acetylaminofluorene(53-96-3) 0.059 140 U006 Acetyl chloride Acetyl chloride (75-36-5) (WETOX or CHOXD) fb CARBN; or CMBST CMBST U007 Acrylamide Acrylamide (79-06-1) (WETOX or CHOXD) fb CARBN; or CMBST CMBST U008 Acrylic acid Acrylic acid (79-10-7) (WETOX or CHOXD) fb CARBN; or CMBST CMBST U009 Acrylonitrile Acrylonitrile (107-13-1) 0.24 84 U010 Mitomycin C Mitomycin C (50-07-7) (WETOX or CHOXD) fb CARBN; or CMBST CMBST U011 Amitrole Amitrole (61-82-5) (WETOX or CMBST 4 - 411 Hazardous Waste Waste Code; Waste Description and Treatment/Regulatory Subcategory 1 Regulated Hazardous Constituent: Common Name; CAS2 Number Wastewaters (Concentration in mg/L3; or Technology Code4) CHOXD) fb CARBN; or CMBST Nonwastewaters (Concentration in mg/kg5 unless noted as “mg/L TCLP”; or Technology Code) 0.81 14 U012 Aniline Aniline (62-53-3) U014 Auramine Auramine (492-80-8) (WETOX or CHOXD) fb CARBN; or CMBST CMBST U015 Azaserine Azaserine (115-02-6) (WETOX or CHOXD) fb CARBN; or CMBST CMBST U016 Benz(c)acridine Benz(c)acridine (225-51-4) (WETOX or CHOXD) fb CARBN; or CMBST CMBST U017 Benzal chloride Benzal chloride (98-87-3) (WETOX or CHOXD) fb CARBN; or CMBST CMBST U018 Benz(a)anthracene Benz(a)anthracene (56-55-3) 0.059 3.4 U019 Benzene Benzene (71-43-2) 0.14 10 U020 4 - 412 Hazardous Waste Waste Code; Waste Description and Treatment/Regulatory Subcategory 1 Regulated Hazardous Constituent: Common Name; CAS2 Number Wastewaters (Concentration in mg/L3; or Technology Code4) (WETOX or CHOXD) fb CARBN; or CMBST Nonwastewaters (Concentration in mg/kg5 unless noted as “mg/L TCLP”; or Technology Code) CMBST (WETOX or CHOXD) fb CARBN; or CMBST CMBST Benzenesulfonyl chloride Benzenesulfonyl chloride(98-09-9) U021 Benzidine Benzidine (92-87-5) U022 Benzo(a)pyrene Benzo(a)pyrene (50-32-8) 0.061 3.4 U023 Benzotrichloride Benzotrichloride (98-07-7) CHOXD; CHRED; CARBN; BIODG; or CMBST CHOXD; CHRED; or CMBST U024 bis(2-Chloroethoxy)methane bis(2-Chloroethoxy)methane (111-91-1) 0.036 7.2 U025 bis(2-Chloroethyl)ether bis(2-Chloroethyl)ether (111-44-4) 0.033 6.0 U026 Chlornaphazine Chlornaphazine (494-03-1) (WETOX or CHOXD) fb CARBN; or CMBST CMBST bis(2-Chloroisopropyl)ether (39638-329) 0.055 7.2 bis(2-Ethylhexyl)phthalate (117-81-7) 0.28 28 U027 bis(2-Chloroisopropyl)ether U028 bis(2-Ethylhexyl)phthalate 4 - 413 Hazardous Waste Waste Code; Waste Description and Treatment/Regulatory Subcategory 1 Regulated Hazardous Constituent: Common Name; CAS2 Number Wastewaters (Concentration in mg/L3; or Technology Code4) Nonwastewaters (Concentration in mg/kg5 unless noted as “mg/L TCLP”; or Technology Code) Methyl bromide (Bromomethane) (7483-9) 0.11 15 U030 4-Bromophenyl phenyl ether 4-Bromophenyl phenyl ether (101-55-3) 0.055 15 U031 n-Butyl alcohol n-Butyl alcohol (71-36-3) 5.6 2.6 U032 Calcium chromate Chromium (Total) (7440-47-3) 2.77 0.60 11 U033 Carbon oxyfluoride Carbon oxyfluoride (353-50-4) (WETOX or CHOXD) fb CARBN; or CMBST CMBST Trichloroacetaldehyde (Chloral)(75-876) (WETOX or CHOXD) fb CARBN; or CMBST CMBST Chlorambucil (305-03-3) (WETOX or CHOXD) fb CARBN; or CMBST CMBST Chlordane (alpha and gamma isomers) (57-74-9) 0.0033 0.26 Chlorobenzene (108-90-7) 0.057 6.0 U029 Methyl bromide (Bromomethane) U034 Trichloroacetaldehyde (Chloral) U035 Chlorambucil U036 Chlordane U037 Chlorobenzene 4 - 414 Hazardous Waste Waste Code; Waste Description and Treatment/Regulatory Subcategory 1 Regulated Hazardous Constituent: Common Name; CAS2 Number Wastewaters (Concentration in mg/L3; or Technology Code4) Nonwastewaters (Concentration in mg/kg5 unless noted as “mg/L TCLP”; or Technology Code) U038 Chlorobenzilate Chlorobenzilate (510-15-6) 0.10 CMBST U039 p-Chloro-m-cresol p-Chloro-m-cresol (59-50-7) 0.018 14 (WETOX or CHOXD) fb CARBN; or CMBST CMBST U041 Epichlorohydrin (1-Chloro-2,3-epoxypropane) Epichlorohydrin (1-Chloro-2,3epoxypropane) (106-89-8) U042 2-Chloroethyl vinyl ether 2-Chloroethyl vinyl ether(110-75-8) 0.062 CMBST U043 Vinyl chloride Vinyl chloride (75-01-4) 0.27 6.0 U044 Chloroform Chloroform (67-66-3) 0.046 6.0 Chloromethane (Methyl chloride) (7487-3) 0.19 30 (WETOX or CHOXD) fb CARBN; or CMBST CMBST U045 Chloromethane (Methyl chloride) U046 Chloromethyl methyl ether Chloromethyl methyl ether(107-30-2) U047 2-Chloronaphthalene 2-Chloronaphthalene (91-58-7) 0.055 5.6 U048 2-Chlorophenol 2-Chlorophenol (95-57-8) 0.044 5.7 4 - 415 Hazardous Waste Waste Code; Waste Description and Treatment/Regulatory Subcategory 1 U049 4-Chloro-o-toluidine hydrochloride U050 Chrysene U051 Creosote U052 Cresols (Cresylic acid) U053 Crotonaldehyde Regulated Hazardous Constituent: Common Name; CAS2 Number Wastewaters (Concentration in mg/L3; or Technology Code4) Nonwastewaters (Concentration in mg/kg5 unless noted as “mg/L TCLP”; or Technology Code) (WETOX or CHOXD) fb CARBN; or CMBST CMBST Chrysene (218-01-9) 0.059 3.4 Naphthalene (91-20-3) Pentachlorophenol (87-86-5) Phenanthrene (85-01-8) Pyrene (129-00-0) Toluene (108-88-3) Xylenes-mixed isomers (sum of o-, m-, and p-xylene concentrations) (1330-207) Lead (7439-92-1) 0.059 0.089 0.059 0.067 0.080 0.32 5.6 7.4 5.6 8.2 10 30 0.69 0.75 11 o-Cresol (95-48-7) m-Cresol (difficult to distinguish from pcresol) (108-39-4) p-Cresol (difficult to distinguish from mcresol) (106-44-5) Cresol-mixed isomers (Cresylic acid) (sum of o-, m-, p- cresol concentrations) (1319-77-3) 0.11 0.77 5.6 5.6 0.77 5.6 0.88 11.2 (WETOX or CHOXD) fb CARBN; or CMBST CMBST 4-Chloro-o-toluidine (3165-93-3) hydrochloride Crotonaldehyde (4170-30-3) 4 - 416 Hazardous Waste Waste Code; Waste Description and Treatment/Regulatory Subcategory 1 Regulated Hazardous Constituent: Common Name; CAS2 Number Wastewaters (Concentration in mg/L3; or Technology Code4) Nonwastewaters (Concentration in mg/kg5 unless noted as “mg/L TCLP”; or Technology Code) U055 Cumene Cumene (98-82-8) (WETOX or CHOXD) fb CARBN; or CMBST CMBST U056 Cyclohexane Cyclohexane (110-82-7) (WETOX or CHOXD) fb CARBN; or CMBST CMBST 0.36 NA CMBST 0.75 11 U057 Cyclohexanone Cyclohexanone (108-94-1) Cyclohexanone; alternate6 standard for nonwastewaters only (108-94-1) U058 Cyclophosphamide Cyclophosphamide (50-18-0) CARBN; or CMBST CMBST U059 Daunomycin Daunomycin (20830-81-3) (WETOX or CHOXD) fb CARBN; or CMBST CMBST o,p’-DDD (53-19-0) p,p’-DDD (72-54-8) 0.023 0.023 0.087 0.087 o,p’-DDT (789-02-6) p,p’-DDT (50-29-3) o,p’-DDD (53-19-0) p,p’-DDD (72-54-8) o,p’-DDE (3424-82-6) p,p’-DDE (72-55-9) 0.0039 0.0039 0.023 0.023 0.031 0.031 0.087 0.087 0.087 0.087 0.087 0.087 U060 DDD U061 DDT U062 4 - 417 Hazardous Waste Waste Code; Waste Description and Treatment/Regulatory Subcategory 1 Regulated Hazardous Constituent: Common Name; CAS2 Number Wastewaters (Concentration in mg/L3; or Technology Code4) (WETOX or CHOXD) fb CARBN; or CMBST Nonwastewaters (Concentration in mg/kg5 unless noted as “mg/L TCLP”; or Technology Code) CMBST 0.055 8.2 (WETOX or CHOXD) fb CARBN; or CMBST CMBST Diallate Diallate (2303-16-4) U063 Dibenz(a,h)anthracene Dibenz(a,h)anthracene (53-70-3) U064 Dibenz(a,i)pyrene Dibenz(a,i)pyrene (189-55-9) U066 1,2-Dibromo-3-chloropropane 1,2-Dibromo-3-chloropropane (96-12-8) 0.11 15 Ethylene dibromide (1,2-Dibromoethane) (106-93-4) 0.028 15 U068 Dibromomethane Dibromomethane (74-95-3) 0.11 15 U069 Di-n-butyl phthalate Di-n-butyl phthalate (84-74-2) 0.057 28 U070 o-Dichlorobenzene o-Dichlorobenzene (95-50-1) 0.088 6.0 U071 m-Dichlorobenzene m-Dichlorobenzene (541-73-1) 0.036 6.0 U072 p-Dichlorobenzene p-Dichlorobenzene (106-46-7) 0.090 6.0 U067 Ethylene dibromide (1,2-Dibromoethane) 4 - 418 Hazardous Waste Waste Code; Waste Description and Treatment/Regulatory Subcategory 1 Regulated Hazardous Constituent: Common Name; CAS2 Number Wastewaters (Concentration in mg/L3; or Technology Code4) Nonwastewaters (Concentration in mg/kg5 unless noted as “mg/L TCLP”; or Technology Code) U073 3,3’-Dichlorobenzidine 3,3’-Dichlorobenzidine (91-94-1) (WETOX or CHOXD) fb CARBN; or CMBST CMBST U074 1,4-Dichloro-2-butene cis-1,4-Dichloro-2-butene (1476-11-5) (WETOX or CHOXD) fb CARBN; or CMBST (WETOX or CHOXD) fb CARBN; or CMBST CMBST trans-1,4-Dichloro-2-butene (764-41-0) CMBST U075 Dichlorodifluoromethane Dichlorodifluoromethane (75-71-8) 0.23 7.2 U076 1,1-Dichloroethane 1,1-Dichloroethane (75-34-3) 0.059 6.0 U077 1,2-Dichloroethane 1,2-Dichloroethane (107-06-2) 0.21 6.0 U078 1,1-Dichloroethylene 1,1-Dichloroethylene (75-35-4) 0.025 6.0 U079 1,2-Dichloroethylene trans-1,2-Dichloroethylene (156-60-5) 0.054 30 U080 Methylene chloride Methylene chloride (75-09-2) 0.089 30 U081 4 - 419 Hazardous Waste Waste Code; Waste Description and Treatment/Regulatory Subcategory 1 2,4-Dichlorophenol 2,4-Dichlorophenol (120-83-2) Wastewaters (Concentration in mg/L3; or Technology Code4) 0.044 U082 2,6-Dichlorophenol 2,6-Dichlorophenol (87-65-0) 0.044 14 U083 1,2-Dichloropropane 1,2-Dichloropropane (78-87-5) 0.85 18 cis-1,3-Dichloropropylene (10061-01-5) trans-1,3-Dichloropropylene(10061-026) 0.036 0.036 18 18 U084 1,3-Dichloropropylene Regulated Hazardous Constituent: Common Name; CAS2 Number Nonwastewaters (Concentration in mg/kg5 unless noted as “mg/L TCLP”; or Technology Code) 14 U085 1,2:3,4-Diepoxybutane 1,2:3,4-Diepoxybutane (1464-53-5) (WETOX or CHOXD) fb CARBN; or CMBST CMBST U086 N,N’-Diethylhydrazine N,N’-Diethylhydrazine (1615-80-1) CHOXD; CHRED; CARBN; BIODG; or CMBST CHOXD; CHRED; or CMBST CARBN; or CMBST CMBST U087 O,O-Diethyl S-methyldithiophosphate O,O-Diethyl (3288-58-2) S-methyldithiophosphate U088 Diethyl phthalate Diethyl phthalate (84-66-2) 0.20 28 U089 Diethyl stilbestrol Diethyl stilbestrol (56-53-1) (WETOX or CHOXD) fb CARBN; or CMBST CMBST U090 4 - 420 Hazardous Waste Waste Code; Waste Description and Treatment/Regulatory Subcategory 1 Regulated Hazardous Constituent: Common Name; CAS2 Number Wastewaters (Concentration in mg/L3; or Technology Code4) (WETOX or CHOXD) fb CARBN; or CMBST Nonwastewaters (Concentration in mg/kg5 unless noted as “mg/L TCLP”; or Technology Code) CMBST Dihydrosafrole Dihydrosafrole (94-58-6) U091 3,3’-Dimethoxybenzidine 3,3’-Dimethoxybenzidine(119-90-4) (WETOX or CHOXD) fb CARBN; or CMBST CMBST U092 Dimethylamine Dimethylamine (124-40-3) (WETOX or CHOXD) fb CARBN; or CMBST CMBST U093 p-Dimethylaminoazobenzene p-Dimethylaminoazobenzene (60-11-7) 0.13 CMBST 7,12-Dimethylbenz(a)anthracene(57-976) (WETOX or CHOXD) fb CARBN; or CMBST CMBST 3,3’-Dimethylbenzidine(119-93-7) (WETOX or CHOXD) fb CARBN; or CMBST CMBST CHOXD; CHRED; CARBN; BIODG; or CMBST CHOXD; CHRED; or CMBST (WETOX or CMBST U094 7,12-Dimethylbenz(a)anthracene U095 3,3’-Dimethylbenzidine U096 alpha, alpha-Dimethyl benzyl hydroperoxide U097 Dimethylcarbamoyl chloride alpha, alpha-Dimethyl hydroperoxide (80-15-9) benzyl Dimethylcarbamoyl chloride (79-44-7) 4 - 421 Hazardous Waste Waste Code; Waste Description and Treatment/Regulatory Subcategory 1 Regulated Hazardous Constituent: Common Name; CAS2 Number Wastewaters (Concentration in mg/L3; or Technology Code4) CHOXD) fb CARBN; or CMBST Nonwastewaters (Concentration in mg/kg5 unless noted as “mg/L TCLP”; or Technology Code) U098 1,1-Dimethylhydrazine 1,1-Dimethylhydrazine (57-14-7) CHOXD; CHRED; CARBN; BIODG; or CMBST CHOXD; CHRED; or CMBST U099 1,2-Dimethylhydrazine 1,2-Dimethylhydrazine (540-73-8) CHOXD; CHRED; CARBN; BIODG; or CMBST CHOXD; CHRED; or CMBST U101 2,4-Dimethylphenol 2,4-Dimethylphenol (105-67-9) 0.036 14 U102 Dimethyl phthalate Dimethyl phthalate (131-11-3) 0.047 28 U103 Dimethyl sulfate Dimethyl sulfate (77-78-1) CHOXD; CHRED; CARBN; BIODG; or CMBST CHOXD; CHRED; or CMBST U105 2,4-Dinitrotoluene 2,4-Dinitrotoluene (121-14-2) 0.32 140 U106 2,6-Dinitrotoluene 2,6-Dinitrotoluene (606-20-2) 0.55 28 U107 Di-n-octyl phthalate Di-n-octyl phthalate (117-84-0) 0.017 28 U108 1,4-Dioxane 1,4-Dioxane (123-91-1) (WETOX or CHOXD) fb CMBST 4 - 422 Hazardous Waste Waste Code; Waste Description and Treatment/Regulatory Subcategory 1 Regulated Hazardous Constituent: Common Name; CAS2 Number 1,4-Dioxane; alternate6 (123-91-1) U109 1,2-Diphenylhydrazine 1,2-Diphenylhydrazine(122-66-7) 1,2-Diphenylhydrazine; alternate6 standard for wastewaters only (122-66-7) Wastewaters (Concentration in mg/L3; or Technology Code4) CARBN; or CMBST 12.0 Nonwastewaters (Concentration in mg/kg5 unless noted as “mg/L TCLP”; or Technology Code) CHOXD; CHRED; CARBN; BIODG; or CMBST 0.087 CHOXD; CHRED; or CMBST (WETOX or CHOXD) fb CARBN; or CMBST CMBST 170 NA U110 Dipropylamine Dipropylamine (142-84-7) U111 Di-n-propylnitrosamine Di-n-propylnitrosamine (621-64-7) 0.40 14 U112 Ethyl acetate Ethyl acetate (141-78-6) 0.34 33 U113 Ethyl acrylate Ethyl acrylate (140-88-5) (WETOX or CHOXD) fb CARBN; or CMBST CMBST Ethylenebisdithiocarbamic acid (111-546) (WETOX or CHOXD) fb CARBN; or CMBST CMBST Ethylene oxide (75-21-8) (WETOX or CHOXD) fb CHOXD; or CMBST U114 Ethylenebisdithiocarbamic acid salts and esters U115 Ethylene oxide 4 - 423 Hazardous Waste Waste Code; Waste Description and Treatment/Regulatory Subcategory 1 Regulated Hazardous Constituent: Common Name; CAS2 Number Ethylene oxide; alternate6 standard for wastewaters only (75-21-8) Wastewaters (Concentration in mg/L3; or Technology Code4) CARBN; or CMBST 0.12 Nonwastewaters (Concentration in mg/kg5 unless noted as “mg/L TCLP”; or Technology Code) (WETOX or CHOXD) fb CARBN; or CMBST CMBST NA U116 Ethylene thiourea Ethylene thiourea (96-45-7) U117 Ethyl ether Ethyl ether (60-29-7) 0.12 160 U118 Ethyl methacrylate Ethyl methacrylate (97-63-2) 0.14 160 U119 Ethyl methane sulfonate Ethyl methane sulfonate (62-50-0) (WETOX or CHOXD) fb CARBN; or CMBST CMBST U120 Fluoranthene Fluoranthene (206-44-0) 0.068 3.4 U121 Trichloromonofluoromethane Trichloromonofluoromethane (75-69-4) 0.020 30 U122 Formaldehyde Formaldehyde (50-00-0) (WETOX or CHOXD) fb CARBN; or CMBST CMBST U123 Formic acid Formic acid (64-18-6) (WETOX or CMBST 4 - 424 Hazardous Waste Waste Code; Waste Description and Treatment/Regulatory Subcategory 1 Regulated Hazardous Constituent: Common Name; CAS2 Number Wastewaters (Concentration in mg/L3; or Technology Code4) CHOXD) fb CARBN; or CMBST Nonwastewaters (Concentration in mg/kg5 unless noted as “mg/L TCLP”; or Technology Code) U124 Furan Furan (110-00-9) (WETOX or CHOXD) fb CARBN; or CMBST CMBST U125 Furfural Furfural (98-01-1) (WETOX or CHOXD) fb CARBN; or CMBST CMBST U126 Glycidylaldehyde Glycidylaldehyde (765-34-4) (WETOX or CHOXD) fb CARBN; or CMBST CMBST U127 Hexachlorobenzene Hexachlorobenzene (118-74-1) 0.055 10 U128 Hexachlorobutadiene Hexachlorobutadiene (87-68-3) 0.055 5.6 0.00014 0.00014 0.023 0.0017 0.066 0.066 0.066 0.066 0.057 2.4 U129 Lindane U130 Hexachlorocyclopentadiene alpha-BHC (319-84-6) beta-BHC (319-85-7) delta-BHC (319-86-8) gamma-BHC (Lindane) (58-89-9) Hexachlorocyclopentadiene (77-47-4) U131 4 - 425 Hazardous Waste Waste Code; Waste Description and Treatment/Regulatory Subcategory 1 Regulated Hazardous Constituent: Common Name; CAS2 Number Hexachloroethane Hexachloroethane (67-72-1) U132 Hexachlorophene Hexachlorophene (70-30-4) U133 Hydrazine Hydrazine (302-01-2) U134 Hydrogen fluoride Floride (measured in wastewaters only) (16964-48-8) Wastewaters (Concentration in mg/L3; or Technology Code4) 0.055 Nonwastewaters (Concentration in mg/kg5 unless noted as “mg/L TCLP”; or Technology Code) 30 (WETOX or CHOXD) fb CARBN; or CMBST CMBST CHOXD; CHRED; CARBN; BIODG; or CMBST CHOXD; CHRED; or CMBST 35 ADGAS fb NEUTR; or NEUTR CHOXD; CHRED; or CMBST CHOXD; CHRED; or CMBST 1.4 5.0 11 0.0055 3.4 U135 Hydrogen Sulfide Hydrogen Sulfide (7783-06-4) U136 Cacodylic acid Arsenic (7440-38-2) U137 Indeno(1,2,3-c,d)pyrene Indeno(1,2,3-c,d)pyrene (193-39-5) U138 Iodomethane Iodomethane (74-88-4) 0.19 65 U140 Isobutyl alcohol Isobutyl alcohol (78-83-1) 5.6 170 U141 Isosafrole Isosafrole (120-58-1) 0.081 2.6 U142 4 - 426 Hazardous Waste Waste Code; Waste Description and Treatment/Regulatory Subcategory 1 Regulated Hazardous Constituent: Common Name; CAS2 Number Wastewaters (Concentration in mg/L3; or Technology Code4) 0.0011 Nonwastewaters (Concentration in mg/kg5 unless noted as “mg/L TCLP”; or Technology Code) 0.13 (WETOX or CHOXD) fb CARBN; or CMBST CMBST Kepone Kepone (143-50-8) U143 Lasiocarpine Lasiocarpine (303-34-4) U144 Lead acetate Lead (7439-92-1) 0.69 0.75 11 U145 Lead phosphate Lead (7439-92-1) 0.69 0.75 11 U146 Lead subacetate Lead (7439-92-1) 0.69 0.75 11 U147 Maleic anhydride Maleic anhydride (108-31-6) (WETOX or CHOXD) fb CARBN; or CMBST CMBST U148 Maleic hydrazide Maleic hydrazide (123-33-1) (WETOX or CHOXD) fb CARBN; or CMBST CMBST U149 Malononitrile Malononitrile (109-77-3) (WETOX or CHOXD) fb CARBN; or CMBST CMBST U150 Melphalan Melphalan (148-82-3) (WETOX or CMBST 4 - 427 Hazardous Waste Waste Code; Waste Description and Treatment/Regulatory Subcategory 1 Wastewaters (Concentration in mg/L3; or Technology Code4) CHOXD) fb CARBN; or CMBST Nonwastewaters (Concentration in mg/kg5 unless noted as “mg/L TCLP”; or Technology Code) Mercury (7439-97-6) NA RMERC U151 (mercury) nonwastewaters that contain less than 260 mg/kg total mercury and that are residues from RMERC only. Mercury (7439-97-6) NA 0.20 11 U151 (mercury) nonwastewaters that contain less than 260 mg/kg total mercury and that are not residues from RMERC only. Mercury (7439-97-6) NA 0.025 11 All U151 (mercury) wastewaters. Mercury (7439-97-6) 0.15 NA Elemental Mercury Contaminated with Radioactive Materials. Mercury (7439-97-6) NA AMLGM U152 Methacrylonitrile Methacrylonitrile (126-98-7) 0.24 84 U153 Methanethiol Methanethiol (74-93-1) (WETOX or CHOXD) fb CARBN; or CMBST CMBST U154 Methanol Methanol (67-56-1) (WETOX or CHOXD) fb CARBN; or CMBST 5.6 CMBST U151 U151 (mercury) nonwastewaters that contain greater than or equal to 260 mg/kg total mercury. Regulated Hazardous Constituent: Common Name; CAS2 Number Methanol; alternate6 set of standards for both wastewaters and nonwastewaters (67-56-1) 0.75 11 4 - 428 Hazardous Waste Waste Code; Waste Description and Treatment/Regulatory Subcategory 1 Regulated Hazardous Constituent: Common Name; CAS2 Number Wastewaters (Concentration in mg/L3; or Technology Code4) Nonwastewaters (Concentration in mg/kg5 unless noted as “mg/L TCLP”; or Technology Code) 0.081 1.5 (WETOX or CHOXD) fb CARBN; or CMBST CMBST 0.0055 15 4,4’-Methylenebis(2-chloroaniline) (101-14-4) 0.50 30 U159 Methyl ethyl ketone Methyl ethyl ketone (78-93-3) 0.28 36 U160 Methyl ethyl ketone peroxide Methyl ethyl ketone peroxide(1338-23-4) CHOXD; CHRED; CARBN; BIODG; or CMBST CHOXD; CHRED; or CMBST U161 Methyl isobutyl ketone Methyl isobutyl ketone (108-10-1) 0.14 33 U162 Methyl methacrylate Methyl methacrylate (80-62-6) 0.14 160 (WETOX or CHOXD) fb CARBN; or CMBST CMBST U155 Methapyrilene Methapyrilene (91-80-5) U156 Methyl chlorocarbonate Methyl chlorocarbonate (79-22-1) U157 3-Methylcholanthrene 3-Methylcholanthrene (56-49-5) U158 4,4’-Methylene bis(2-chloroaniline) U163 N-Methyl N’-nitro N-nitrosoguanidine N-Methyl N’-nitro N-nitrosoguanidine (70-25-7) U164 4 - 429 Hazardous Waste Waste Code; Waste Description and Treatment/Regulatory Subcategory 1 Regulated Hazardous Constituent: Common Name; CAS2 Number Wastewaters (Concentration in mg/L3; or Technology Code4) (WETOX or CHOXD) fb CARBN; or CMBST Nonwastewaters (Concentration in mg/kg5 unless noted as “mg/L TCLP”; or Technology Code) CMBST 0.059 5.6 Methylthiouracil Methylthiouracil (56-04-2) U165 Naphthalene Naphthalene (91-20-3) U166 1,4-Naphthoquinone 1,4-Naphthoquinone (130-15-4) (WETOX or CHOXD) fb CARBN; or CMBST CMBST U167 1-Naphthylamine 1-Naphthylamine (134-32-7) (WETOX or CHOXD) fb CARBN; or CMBST CMBST U168 2-Naphthylamine 2-Naphthylamine (91-59-8) 0.52 CMBST U169 Nitrobenzene Nitrobenzene (98-95-3) 0.068 14 U170 p-Nitrophenol p-Nitrophenol (100-02-7) 0.12 29 U171 2-Nitropropane 2-Nitropropane (79-46-9) (WETOX or CHOXD) fb CARBN; or CMBST CMBST U172 N-Nitrosodi-n-butylamine N-Nitrosodi-n-butylamine (924-16-3) 0.040 17 4 - 430 Hazardous Waste Waste Code; Waste Description and Treatment/Regulatory Subcategory 1 Regulated Hazardous Constituent: Common Name; CAS2 Number Wastewaters (Concentration in mg/L3; or Technology Code4) Nonwastewaters (Concentration in mg/kg5 unless noted as “mg/L TCLP”; or Technology Code) (WETOX or CHOXD) fb CARBN; or CMBST CMBST U173 N-Nitrosodiethanolamine N-Nitrosodiethanolamine (1116-54-7) U174 N-Nitrosodiethylamine N-Nitrosodiethylamine (55-18-5) 0.40 28 U176 N-Nitroso-N-ethylurea N-Nitroso-N-ethylurea (759-73-9) (WETOX or CHOXD) fb CARBN; or CMBST CMBST U177 N-Nitroso-N-methylurea N-Nitroso-N-methylurea (684-93-5) (WETOX or CHOXD) fb CARBN; or CMBST CMBST U178 N-Nitroso-N-methylurethane N-Nitroso-N-methylurethane (615-53-2) (WETOX or CHOXD) fb CARBN; or CMBST CMBST U179 N-Nitrosopiperidine N-Nitrosopiperidine (100-75-4) 0.013 35 U180 N-Nitropyrrolidine N-Nitropyrrolidine (930-55-2) 0.013 35 U181 5-Nitro-o-toluidine 5-Nitro-o-toluidine (99-55-8) 0.32 28 4 - 431 Hazardous Waste Waste Code; Waste Description and Treatment/Regulatory Subcategory 1 Regulated Hazardous Constituent: Common Name; CAS2 Number U182 Paraldehyde Paraldehyde (123-63-7) U183 Pentachlorobenzene Pentachlorobenzene (608-93-5) U184 Pentachloroethane Pentachloroethane (76-01-7) Pentachloroethane; alternate6 standards for both wastewa ters and nonwastewaters (76-01-7) Wastewaters (Concentration in mg/L3; or Technology Code4) Nonwastewaters (Concentration in mg/kg5 unless noted as “mg/L TCLP”; or Technology Code) (WETOX or CHOXD) fb CARBN; or CMBST CMBST 0.055 10 (WETOX or CHOXD) fb CARBN; or CMBST 0.055 CMBST 0.055 4.8 (WETOX or CHOXD) fb CARBN; or CMBST CMBST 6.0 U185 Pentachloronitrobenzene Pentachloronitrobenzene (82-68-8) U186 1,3-Pentadiene 1,3-Pentadiene (504-60-9) U187 Phenacetin Phenacetin (62-44-2) 0.081 16 U188 Phenol Phenol (108-95-2) 0.039 6.2 U189 Phosphorus sulfide Phosphorus sulfide (1314-80-3) CHOXD; CHRED; or CMBST CHOXD; CHRED; or CMBST 4 - 432 Hazardous Waste Waste Code; Waste Description and Treatment/Regulatory Subcategory 1 U190 Phthalic anhydride (measured as Phthalic acid or Terephthalic acid) Regulated Hazardous Constituent: Common Name; CAS2 Number Wastewaters (Concentration in mg/L3; or Technology Code4) Nonwastewaters (Concentration in mg/kg5 unless noted as “mg/L TCLP”; or Technology Code) Phthalic anhydride (measured as Phthalic acid or Tereph thalic acid) (100-21-0) Phthalic anhydride (measured as Phthalic acid or Tereph thalic acid) (85-44-9) 0.055 28 0.055 28 (WETOX or CHOXD) fb CARBN; or CMBST CMBST 0.093 1.5 U191 2-Picoline 2-Picoline (109-06-8) U192 Pronamide Pronamide (23950-58-5) U193 1,3-Propane sultone 1,3-Propane sultone (1120-71-4) (WETOX or CHOXD) fb CARBN; or CMBST CMBST U194 n-Propylamine n-Propylamine (107-10-8) (WETOX or CHOXD) fb CARBN; or CMBST CMBST U196 Pyridine Pyridine (110-86-1) 0.014 16 U197 p-Benzoquinone p-Benzoquinone (106-51-4) (WETOX or CHOXD) fb CARBN; or CMBST CMBST U200 Reserpine Reserpine (50-55-5) (WETOX or CMBST 4 - 433 Hazardous Waste Waste Code; Waste Description and Treatment/Regulatory Subcategory 1 Regulated Hazardous Constituent: Common Name; CAS2 Number Wastewaters (Concentration in mg/L3; or Technology Code4) CHOXD) fb CARBN; or CMBST Nonwastewaters (Concentration in mg/kg5 unless noted as “mg/L TCLP”; or Technology Code) U201 Resorcinol Resorcinol (108-46-3) (WETOX or CHOXD) fb CARBN; or CMBST CMBST U202 Saccharin and salts Saccharin (81-07-2) (WETOX or CHOXD) fb CARBN; or CMBST CMBST U203 Safrole Safrole (94-59-7) 0.081 22 U204 Selenium dioxide Selenium (7782-49-2) 0.82 5.7 11 U205 Selenium sulfide Selenium (7782-49-2) 0.82 5.7 11 U206 Streptozotocin Streptozotocin (18883-66-4) (WETOX or CHOXD) fb CARBN; or CMBST CMBST U207 1,2,4,5-Tetrachlorobenzene 1,2,4,5-Tetrachlorobenzene (95-94-3) 0.055 14 U208 1,1,1,2-Tetrachloroethane 1,1,1,2-Tetrachloroethane (630-20-6) 0.057 6.0 4 - 434 Hazardous Waste Waste Code; Waste Description and Treatment/Regulatory Subcategory 1 Regulated Hazardous Constituent: Common Name; CAS2 Number Wastewaters (Concentration in mg/L3; or Technology Code4) Nonwastewaters (Concentration in mg/kg5 unless noted as “mg/L TCLP”; or Technology Code) U209 1,1,2,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane (79-34-5) 0.057 6.0 U210 Tetrachloroethylene Tetrachloroethylene (127-18-4) 0.056 6.0 U211 Carbon tetrachloride Carbon tetrachloride (56-23-5) 0.057 6.0 U213 Tetrahydrofuran Tetrahydrofuran (109-99-9) (WETOX or CHOXD) fb CARBN; or CMBST CMBST Thallium (measured in wastewaters only) (7440-28-0) 1.4 RTHRM; or STABL Thallium (measured in wastewaters only) (7440-28-0) 1.4 RTHRM; or STABL Thallium (measured in wastewaters only) (7440-28-0) 1.4 RTHRM; or STABL Thallium (measured in wastewaters only) (7440-28-0) 1.4 RTHRM; or STABL U214 Thallium(l)acetate U215 Thallium(l)carbonate U216 Thallium(l)chloride U217 Thallium(l)nitrate U218 Thioacetamide Thioacetamide (62-55-5) (WETOX or CHOXD) fb CARBN; or CMBST CMBST U219 Thiourea Thiourea (62-56-6) (WETOX or CMBST 4 - 435 Hazardous Waste Waste Code; Waste Description and Treatment/Regulatory Subcategory 1 Regulated Hazardous Constituent: Common Name; CAS2 Number Wastewaters (Concentration in mg/L3; or Technology Code4) CHOXD) fb CARBN; or CMBST Nonwastewaters (Concentration in mg/kg5 unless noted as “mg/L TCLP”; or Technology Code) 0.080 10 U220 Toluene Toluene (108-88-3) U221 Toluenadiamine Toluenadiamine (25376-45-8) CARBN; or CMBST CMBST U222 o-Toluidine hydrochloride o-Toluidine hydrochloride (636-21-5) (WETOX or CHOXD) fb CARBN; or CMBST CMBST U223 Toluene diisocyanate Toluene diisocyanate (26471-62-5) CARBN; or CMBST CMBST Bromoform (Tribromomethane) (75-252) 0.63 15 U226 1,1,1-Trichlorethane 1,1,1-Trichlorethane (71-55-6) 0.054 6.0 U227 1,1,2-Trichloroethane 1,1,2-Trichloroethane (79-00-5) 0.054 6.0 U228 Trichloroethylene Trichloroethylene (79-01-6) 0.054 6.0 U234 1,3,5-Trinitrobenzene 1,3,5-Trinitrobenzene(99-35-4) (WETOX or CHOXD) fb CARBN; or CMBST U225 Bromoform (Tribromomethane) 4 - 436 Hazardous Waste Waste Code; Waste Description and Treatment/Regulatory Subcategory 1 U235 tris-(2,3-Dibromopropyl)-phosphate Regulated Hazardous Constituent: Common Name; CAS2 Number tris-(2,3-Dibromopropyl)-phosphate (126-72-7) Wastewaters (Concentration in mg/L3; or Technology Code4) CMBST Nonwastewaters (Concentration in mg/kg5 unless noted as “mg/L TCLP”; or Technology Code) 0.11 0.10 U236 Trypan Blue Trypan Blue (72-57-1) (WETOX or CHOXD) fb CARBN; or CMBST CMBST U237 Uracil mustard Uracil mustard (66-75-1) (WETOX or CHOXD) fb CARBN; or CMBST CMBST U238 Urethane (Ethyl carbamate) Urethane (Ethyl carbamate)(51-79-6) (WETOX or CHOXD) fb CARBN; or CMBST CMBST Xylenes-mixed isomers (sum of o-, m-, and p-xylene concentrations) (1330-207) 0.32 30 0.72 10 2,4-D (2,4-Dichlorophenoxyacetic acid) salts and esters 2,4-D (2,4-Dichlorophenoxyacetic acid) (94-75-7) NA (WETOX or CHOXD) fb CARBN; or CMBST CMBST U243 Hexachloropropylene Hexachloropropylene (1888-71-7) 0.035 30 U239 Xylenes U240 2,4-D (2,4-Dichlorophenoxyacetic acid) 4 - 437 Hazardous Waste Waste Code; Waste Description and Treatment/Regulatory Subcategory 1 Regulated Hazardous Constituent: Common Name; CAS2 Number Wastewaters (Concentration in mg/L3; or Technology Code4) Nonwastewaters (Concentration in mg/kg5 unless noted as “mg/L TCLP”; or Technology Code) U244 Thiram Thiram (137-26-8) (WETOX or CHOXD) fb CARBN; or CMBST CMBST U246 Cyanogen bromide Cyanogen bromide (506-68-3) CHOXD; WETOX; or CMBST CHOXD; WETOX; or CMBST U247 Methoxychlor Methoxychlor (72-43-5) 0.25 0.18 U248 Warfarin, & salts, when present at concentrations of 0.3% or less Warfarin (81-81-2) (WETOX or CHOXD) fb CARBN; or CMBST CMBST U249 Zinc phosphide, Zn3P2, when present at concentrations of 10% or less Zinc Phosphide (1314-84-7) CHOXD; CHRED; or CMBST CHOXD; CHRED; or CMBST U271 Benomyl Benomyl (17804-35-2) 0.056 1.4 U278 Bendiocarb Bendiocarb (22781-23-3) 0.056 1.4 U279 Carbaryl Carbaryl (63-25-2) 0.006 0.14 U280 Barban Barban (101-27-9) 0.056 1.4 U328 4 - 438 Hazardous Waste Waste Code; Waste Description and Treatment/Regulatory Subcategory 1 Regulated Hazardous Constituent: Common Name; CAS2 Number Wastewaters (Concentration in mg/L3; or Technology Code4) CMBST; or CHOXD fb (BIODG or CARBN); or BIODG fb CARBN Nonwastewaters (Concentration in mg/kg5 unless noted as “mg/L TCLP”; or Technology Code) CMBST o-Toluidine o-Toluidine (95-53-4) U353 p-Toluidine p-Toluidine (106-49-0) CMBST; or CHOXD fb (BIODG or CARBN); or BIODG fb CARBN CMBST U359 2-Ethoxyethanol 2-Ethoxyethanol (110-80-5) CMBST; or CHOXD fb (BIODG or CARBN); or BIODG fb CARBN CMBST U364 Bendiocarb phenol Bendiocarb phenol (22961-82-6) 0.056 1.4 U367 Carbofuran phenol10 Carbofuran phenol (1563-38-8) 0.056 1.4 U372 Carbendazim Carbendazim (10605-21-7) 0.056 1.4 U373 Propham Propham (122-42-9) 0.056 1.4 U387 4 - 439 Hazardous Waste Waste Code; Waste Description and Treatment/Regulatory Subcategory 1 Regulated Hazardous Constituent: Common Name; CAS2 Number Wastewaters (Concentration in mg/L3; or Technology Code4) 0.042 Nonwastewaters (Concentration in mg/kg5 unless noted as “mg/L TCLP”; or Technology Code) 1.4 Prosulfocarb Prosulfocarb (52888-80-9) U389 Triallate Triallate (2303-17-5) 0.042 1.4 U394 A221310 A2213 (30558-43-1) 0.042 1.4 Diethylene glycol, dicarbamate (595226-1) 0.056 1.4 U404 Triethylamine Triethylamine (121-44-8) 0.081 1.5 U408 2,4,6-Tribromophenol 2,4,6-Tribromophenol (118-79-6) 0.035 7.4 U409 Thiophanate-methyl Thiophanate-methyl (23564-05-8) 0.056 1.4 U410 Thiodicarb Thiodicarb (59669-26-0) 0.019 1.4 U411 Propoxur Propoxur (114-26-1) 0.056 1.4 U395 Diethylene glycol, dicarbamate10 Notes to the table: 1. The waste descriptions provided in this table do not replace waste descriptions in 40 CFR 261. Descriptions of Treatment/ Regulatory Subcategories are provided, as needed, to distinguish between applicability of different standards. 2. CAS means Chemical Abstract Services. When the waste code and/or regulated constituents are described as a combination of a chemical with its salts and/or esters, the CAS number is given for the parent compound only. 4 - 440 Hazardous Waste Waste Code; Waste Description and Treatment/Regulatory Subcategory 1 Regulated Hazardous Constituent: Common Name; CAS2 Number Wastewaters (Concentration in mg/L3; or Technology Code4) Nonwastewaters (Concentration in mg/kg5 unless noted as “mg/L TCLP”; or Technology Code) 3. Concentration standards for wastewaters are expressed in mg/l and are based on analysis of composite samples. 4. All treatment standards expressed as a Technology Code or combination of Technology Codes are explained in detail in 40 CFR 268.42 Table 1-Technology Codes and Descriptions of Technology-Based Standards. 5. Except for Metals (EP or TCLP) and Cyanides (Total and Amenable) the nonwastewater treatment standards expressed as a concentration were established, in part, based upon incineration in units operated in accordance with the technical requirements of 40 CFR part 264, subpart O or 40 CFR part 265, subpart O, or based upon combustion in fuel substitution units operating in accordance with applicable technical requirements. A facility may comply with these treatment standards according to provisions in 40 CFR 268.40(d). All concentration standards for nonwastewaters are based on analysis of grab samples. 6. Where an alternate treatment standard or set of alternate standards has been indicated, a facility may comply with this alternate standard, but only for the Treatment/Regulatory Subcategory or physical form (i.e., wastewater and/or nonwastewater) specified for that alternate standard. 7. Both Cyanides (Total) and Cyanides (Amenable) for nonwastewaters are to be analyzed using Method 9010 or 9012, found in “Test Methods for Evaluating Solid Waste, Physical/Chemical Methods”, EPA Publication SW-846, as incorporated by reference in 40 CFR 260.11, with a sample size of 10 grams and a distillation time of 1 h and 15 min. 8. These wastes, when rendered nonhazardous and then subsequently managed in CWA, or CWA-equivalent systems are not subject to treatment standards. (See Sec. 148.1(d) and Sec. 268.1(c)(3) and (4)). 9. These wastes, when rendered nonhazardous and then subsequently injected in a Class I SDWA well are not subject to treatment standards. (See Sec. 148.1(d)). 10. The treatment standard for this waste may be satisfied by either meeting the constituent concentrations in this table or by treating the waste by the specified technologies: combustion, as defined by the technology code CMBST at Sec. 268.42 Table 1 of this Part, for nonwastewaters; and, biodegradation as defined by the technology code BIODG, carbon adsorption as defined by the technology code CARBN, chemical oxidation as defined by the technology code CHOXD, or combustion as defined as technology code CMBST at Sec. 268.42 Table 1 of this Part, for wastewaters. 11. For these wastes, the definition of CMBST is limited to: (1) combustion units operating under 40 CFR 266, (2) combustion units permitted under 40 CFR part 264, subpart O, or (3) combustion units operating under 40 CFR 265, subpart O, which have obtained a determination of equivalent treatment under 268.42(b). 12. Disposal of K175 wastes that have complied with all applicable 40 CFR 268.40 treatment standards must also be macroencapsulated in accordance with 40 CFR 268.45 Table 1 unless the waste is placed in: (a) A Subtitle C monofill containing only K175 wastes that meet all applicable 40 CFR 268.40 treatment standards; or 4 - 441 Hazardous Waste Waste Code; Waste Description and Treatment/Regulatory Subcategory 1 Regulated Hazardous Constituent: Common Name; CAS2 Number Wastewaters (Concentration in mg/L3; or Technology Code4) Nonwastewaters (Concentration in mg/kg5 unless noted as “mg/L TCLP”; or Technology Code) (b) A dedicated Subtitle C landfill cell in which all other wastes being co-disposed are at pH6.0. NOTE: NA means not applicable. 4 - 442 Hazardous Waste 4 - 443 Hazardous Waste 4 - 444 Hazardous Waste Appendix 4-10 Technology Codes and Description of Technology-Based Standards (40 CFR 268.42) Technology code ADGAS Description of technology-based standards Venting of compressed gases into an absorbing or reacting media (i.e., solid or liquid)-- venting can be accomplished through physical release utilizing valves/piping; physical penetration of the container; and/or penetration through detonation. AMLGM Amalgamation of liquid, elemental mercury contaminated with radioactive materials utilizing inorganic reagents such as copper, zinc, nickel, gold, and sulfur that result in a nonliquid, semisolid amalgam and thereby reducing potential emissions of elemental mercury vapors to the air. BIODG Biodegradation of organics or nonorganics (i.e., degradable inorganics that contain the elements of phosphorus, nitrogen, and sulfur) in units operated under either aerobic or anaerobic conditions such that a surrogate compound or indicator parameter has been substantially reduced in concentration in the residuals (e.g., total organic carbon can often be used as an indicator parameter for the biodegradation of many organic constituents that cannot be directly analyzed in wastewater residues). CARBN Carbon adsorption (granulated or powered) of nonmetallic inorganics, organo-metallics, and/or organic constituents, operated such that a surrogate compound or indicator parameter has not undergone breakthrough (e.g., total organic carbon can often be used as an indicator parameter for absorption of many organic constituents that cannot be directly analyzed in wastewater residues). Breakthrough occurs when the carbon has become saturated with the constituent (or indicator parameter) and substantial change in adsorption rate associated with that constituent occurs. CHOXD Chemical or electrolytic oxidation utilizing the following oxidation reagents (or waste reagents) or combinations of reagents: (1) hypochlorite (e.g., bleach); (2) chlorine; (3) chlorine dioxide; (4) ozone or UV (ultraviolet light) assisted ozone; (5) peroxides; (6) persulfates; (7) perchlorates; (8) permangantes; and/or (9) other oxidizing reagents of equivalent efficiency, performed in units operated such that a surrogate compound or indicator parameter has been substantially reduced in concentration in the residuals (e.g., total organic carbon can often be used as an indicator parameter for the oxidation of many organic constituents that cannot be directly analyzed in wastewater residues). Chemical oxidation specifically indicates what is commonly referred to as alkaline chlorination. CHRED Chemical reduction utilizing the following reducing reagents (or waste reagents) or combinations of reagents: (1) sulfur dioxide; (2) sodium, potassium, or alkali salts or sulfides, bisulfites, metabisulfites, and polyethylene glycols (e.g., NaPEG and KPEG); (3) sodium hydrosulfide; (4) ferrous salts; and/or (5) other reducing reagents of equivalent efficiency, performed in units operated such that a surrogate compound or indicator parameter has been substantially reduced in concentration in the residuals (e.g., total organic halogens can often be used as an indicator parameter for the reduction of many halogenated organic constituents that cannot be directly analyzed in wastewater residues). Chemical reduction is commonly used for the reduction of hexavalent chromium to the trivalent state. CMBST Combustion in incinerators, boilers, or industrial furnaces operated in accordance with the applicable requirements of 40 CFR 264, Subpart O, or 40 CFR 266, Subpart H. 4 - 445 Hazardous Waste Technology code DEACT Description of technology-based standards Deactivation to remove the hazardous characteristics of a waste due to its ignitibility, corrosivity, and/or reactivity. FSUBS Fuel substitution in units operated in accordance with applicable technical operating requirements. HLVIT Vitrification of high level mixed radioactive wastes in units in compliance with all applicable radioactive protection requirements under control of the Nuclear Regulatory Commission. IMERC Incineration of wastes containing organics and mercury in units operated in accordance with the technical operating requirements of 40 CFR 264 subpart O and 265 subpart O. All wastewater and nonwastewater residues derived from this process must then comply with the corresponding treatment standards per waste code with consideration of any applicable subcategories (e.g., high or low mercury subcategories). INCIN Incineration in units operated in accordance with the technical operating requirements of 40 CFR 264 subpart O and part 265 subpart O. LLEXT Liquid-liquid extraction (often referred to as solvent extraction) of organics from liquid wastes into an immiscible solvent for which the hazardous constituents have a greater solvent affinity, resulting in an extract high in organics that must undergo either incineration, reuse as a fuel, or other recovery/reuse and a raffinate (extracted liquid waste) proportionately low in organics that must undergo further treatment as specified in the standard. MACRO Macroencapsulation with surface coating materials such as polymeric organic (e.g., resins and plastics) or with a jacket or inert inorganic materials to substantially reduce surface exposure to potential leaching media. Macroencapsulation specifically does not include any material that would be classified as a tank or container according to 40:260.10. NEUTRO Neutralization with the following reagents (or waste reagents) or combination or reagents: (1) acids; (2) bases; or (3) water (including wastewaters) resulting in a pH greater than 2 but less than 12.5 as measured in the aqueous residuals. NLDBR No land disposal based on recycling. PRECP Chemical precipitation of metals and other inorganics as insoluble precipitates of oxides, hydroxides, carbonates, sulfates, chlorides, fluorides, or phosphates. The following reagents (or waste reagents) are typically used alone or in combination: (1) lime (i.e., containing oxides and/or hydroxides of calcium and/or magnesium; (2) caustic (i.e., sodium and/or potassium hydroxide; (3) soda ash (i.e., sodium carbonate); (4) sodium sulfide; (5) ferric sulfate or ferric chloride; (6) alum; or (7) sodium sulfate. Additional floculating, coagulation, or similar reagents/processes that enhance sludge dewatering characteristics are not precluded from use. RBERY Thermal recovery of Beryllium. RCGAS Recovery/reuse of compressed gases including techniques such as reprocessing of the gases for reuse/resale; filtering/adsorption of impurities; remixing for direct reuse or resale; and use of the gas as a fuel source. 4 - 446 Hazardous Waste Technology code RCORR Description of technology-based standards Recovery of acids or bases utilizing one or more of the following recovery technologies: (1) distillation (i.e., thermal concentration); (2) ion exchange; (3) resin or solid adsorption; (4) reverse osmosis; and/or (5) incineration for the recovery of acid. Note: this does not preclude the use of other physical phase separation or concentration techniques such as decantation, filtration (including ultrafiltration), and centrifugation, when used in conjunction with the above listed recovery technologies. RLEAD Thermal recovery of lead in secondary lead smelters. RMERC Retorting or roasting in a thermal processing unit capable of volatilizing mercury and subsequently condensing the volatilized mercury for recovery. The retorting or roasting in a thermal unit (or facility) must be subject to one or more of the following: (a) a national emissions standard for hazardous air pollutants (NESHAP) for mercury; (b) a best available control technology (BACT) or a lowest achievable emission rate (LAER) standard for mercury imposed pursuant to a prevention of significant deterioration (PSD) permit; or (c) a state permit that establishes emission limitations (within meaning of section 302 of the Clean Air Act) for mercury. All wastewater and nonwastewater residues derived from this process must then comply with the corresponding treatment standards per waste code with consideration of any applicable subcategories (e.g., high or low mercury subcategories). RMETL Recovery of metals or inorganics utilizing one or more of the following direct physical/ removal technologies: (1) ion exchange; (2) resin or solid (i.e., zeolites) adsorption; (3) reserve osmosis; (40 chelation/solvent extraction; (5) freeze crystallization; (6) ultrafiltration and/or (7) simple precipitation (i.e., crystallization). Note: This does not preclude the use of other physical phase separation or concentration techniques such as decantation, filtration (including ultrafiltration), and centrifugation, when used in conjunction with the above listed recovery technologies. RORGS Recovery of organics utilizing one or more of the following technologies: (1) Distillation; (2) thin film evaporation; (3) steam stripping; (4) carbon adsorption; (5) critical fluid extraction; (6) liquid-liquid extraction; (7) precipitation/crystallization (including freeze crystallization); or (8) chemical phase separation techniques (i.e., addition of acids, bases, demulsifiers, or similar chemicals). Note: This does not preclude the use of other physical phase separation techniques such as a decantation, filtration (including ultrafiltration), and centrifugation, when used in conjunction with the above listed recovery technologies. RTHRM Thermal recovery of metals or inorganics from nonwastewaters in units identified as industrial furnaces according to 40 CFR 60.10 (1), (6), (7), (11), and (12) under the definition of “industrial furnaces”. RZINC Resmelting in high temperature metal recovery units for the purpose of recovery of zinc. STABL Stabilization with the following reagents (or waste reagents) or combinations of reagents: (1) Portland cement; or (2) lime/pozzolans (e.g., fly ash and cement kiln dust). Note: This does not preclude the addition of reagents (e.g., iron slats, silicates, and clays) designed to enhance the set/cure time and/or compressive strength, or to overall reduce the leachability of the metal or inorganic. 4 - 447 Hazardous Waste Technology code SSTRP Description of technology-based standards Steam stripping of organics from liquid wastes utilizing direct application of steam to the wastes operated such that liquid and vapor flow rates, as well as, temperature and pressure ranges have been optimized, monitored, and maintained. These operating parameters are dependent upon the design parameters of the unit, such as the number of separation stages and the internal column design, thus resulting in a condensed extract high in organics that must undergo incineration, reuse as a fuel, or other recovery/reuse and an extract wastewater that must undergo further treatment as specified in the standard. WETOX Wet air oxidation performed in units such that a surrogate compound or indicator parameter has been substantially reduced in concentration in the residuals (e.g., total organic carbon can often be used as an indicator for the oxidation of many organic constituents that cannot be directly analyzed in wastewater residues). WTRRX Controlled reaction with water for highly reactive inorganic or organic chemicals with precautionary controls for protection of workers from potential violent reactions as well as precautionary controls for potential emissions of toxic/ignitable levels of gases released during the reaction. Note 1: When a combination of these technologies (i.e., a treatment train) is specified as a single treatment standard, the order of application is specified in 40 CFR 268.42, Table 2 by the five letter technology code that must be applied first, then the designation “fb” (abbreviation for “followed by”), then the five letter technology code for the technology that must be applied next, and so on. Note 2: When more than one technology (or treatment train) is specified as alternative treatment standards, the five letter technology codes (or the treatment trains) are separated by a semicolon (;), with the last technology preceded by the word “or”. This indicates that any one of these BDAT technologies or treatment trains can be used for compliance with the standard. 4 - 448 Hazardous Waste Appendix 4-11 Maximum Concentrations of Constituents for Groundwater Protection (40 CFR 264.94, Table 1) Constituent Arsenic Barium Cadmium Chromium Lead Mercury Selenium Silver Endrin Lindane Methoxychlor 2,4,5-TP Silvex Toxaphene 2,4-D Maximum Concentration (mg3) 0.05 1.0 0.01 0.05 0.05 0.002 0.01 0.05 0.0002 0.004 0.01 0.01 0.005 0.1 4 - 449 Hazardous Waste 4 - 450 Hazardous Waste Appendix 4-12 Groundwater Monitoring List1 (40 CFR 264, Appendix IX) Common name2 CAS RN3 CAS index name4 Suggeste d methods PQL (g/L)6 5 Acenaphthene 83-32-9 Acenaphthylene, 1,2-dihydro- 8100 200 Acenaphthylene 208-968 Acenaphthylene 8270 8100 10 200 Acetone Acetophenone Acetonitrile; methyl cyanide 2-Acetylaminofluorene; 2AAF Acrolein 67-64-1 98-86-2 75-05-8 53-96-3 2-Propanone Ethanone, 1-phenylAcetonitrile Acetamide, N-9H-fluoren-2-yl- 8270 8240 8270 8015 8270 10 100 10 100 10 107-028 2-Propenal 8030 5 Acrylonitrile 107-131 2-Propenenitrile 8240 8030 5 5 Aldrin 309-002 1,4:5,8-Dimethanonaphthalene, 1, 2, 3, 4, 10, 10hexachloro- 1, 4, 4a, 5, 8, 8a-hexahydro- (1, 4, 4a, 5, 8, 8a)1-Propene, 3-chloro- 8240 8080 5 .05 8270 8010 10 5 Allyl chloride 107-051 4-Aminobiphenyl Aniline Anthracene 92-67-1 62-53-3 120-127 [1,1’-Biphenyl]- 4-amine Benzenamine Anthracene 8240 8270 8270 8100 100 10 10 200 Antimony (Total) Antimony 8270 6010 10 300 7040 2000 7041 8270 30 10 6010 500 7060 10 7061 6010 20 20 7080 1000 Aramite Arsenic Barium 140-578 (Total) (Total) Sulfurous acid, 2-chloroethyl 2-[4-(1,1dimethylethyl)phenoxy]-1methyllethl ester Arsenic Varium 4 - 451 Hazardous Waste Common name2 CAS RN3 CAS index name4 Suggeste d methods PQL (g/L)6 5 Benzene 71-43-2 Benzene 8020 2 Benzo[a]anthracene; Benzanthracene 56-55-3 Bena[a]anthracene 8240 8100 5 200 Benzo[b]fluoranthene 205-992 Benz[e]acephenanthrylene 8270 8100 10 200 Benzo[k]fluoranthene 207-089 Benxo[k]fluoranthene 8270 8100 10 200 Benzo[ghi]perylene 191-242 Benzo[ghi]perylene 8270 8100 10 200 Benzo[a]pyrene 50-32-8 Benzo[a]pyrene 8270 8100 10 200 Benzyl alcohol 100-516 (Total) Benzenemethanol 8270 8270 10 20 Berylium 6010 3 7090 50 7091 8080 2 0.05 8250 8080 10 0.05 8250 8080 40 0.1 8250 8080 30 0.05 Berylium alpha-BNC 319-846 Cyclohexane, 1, 2, 3, 4, 5, 6-hexachloro-,(1, 2, 3, 4, 5, 6)- beta-BHC 319-857 Cyclohexane, 1, 2, 3, 4, 5, 6-hexachloro-, (1, 2, 3, 4, 5, 6)- delta-BHC 319-688 Cyclohexane, 1, 2, 3, 4, 5, 6-hexachloro-,(1, 2, 3, 4, 5, 6)- gamma-BHC; Lindane 58-89-9 Cyclohexane, 1, 2, 3, 4, 5, 6-hexachloro-,(1, 2, 3, 4, 5, 6)- Bis(2-chloroethoxy)methane 111-911 111-444 108-601 Ethane, 1,1’-[methylenebis (oxy)]bis [2-chloro- 8250 8270 10 10 Ethane, 1,1’-oxybis[2-chloro- 8270 10 Propane, 2,2’-oxybis[1-chloro 8010 100 117-817 1,2-Benzenedicarboxylic acid, bis(2-ethylhexyl) ester 8270 8060 10 20 75-27-4 Methane, bromodichloro- 8270 8010 10 1 8240 5 Bis (2-chloroethyl)ether Bis(2-chloro-1-methylethyl) ether; 2,2’Dichlorodiisopropyl ether Bis(2-ehtylhexyl) phthalate Bromodichloromethane 4 - 452 Hazardous Waste Common name2 CAS RN3 CAS index name4 Suggeste d methods PQL (g/L)6 5 Bromoform; Tribromomehane 75-25-2 Methane, tribromo- 8010 2 4-Bromophenyl phenyl ether 101-553 85-68-7 Benzene, 1-bromo-4-phenoxy- 8240 8270 5 10 8060 5 (Total) Cadmium 8270 6010 10 40 7130 50 7131 8240 8010 1 5 1 8240 8080 5 0.1 Butyl benzyl phthalate; Benzyl butyl phthalate Cadmium 1,2-Benzenedicarboxylic phenylmethyl ester acid, butyl Carbon disulfide Carbon tetrachloride 75-15-0 56-23-5 Carbon disulfide Methane, tetrachloro- Chlordane 57-74-9 4,7-Methano-1H-indene, 1, 2, 4, 5, 6, 7, 8, 8octachloro-2, 3, 3a, 4, 7, 7a-hexahydro- p-Chloroaniline 106-478 108-907 Benzenamine, 4-chloro- 8250 8270 10 20 Benzene, chloro- 8010 2 8020 2 8240 8270 5 10 8040 5 Chlorobenzene Chlorobenzilate p-Chloro-m-cresol 510-156 59-50-7 Benaeneacetic acid, 4-chloro--(4chlorophenyl)--hydroxy-, ethyl ester Phenol, 4-chloro-3-methyl- Chloroethane; Ethyl chloride 75-00-3 Ethane, chloro- 8270 8010 20 5 Chloroform 67-66-3 Methane, trichloro- 8240 8010 10 0.5 2-Chloronaphthalene 91-58-7 Naphthalene, 2-chloro- 8240 8120 5 10 2-Chlorophenol 95-57-8 Phenol, 2-chloro- 8270 8040 10 5 4-Chlorophenyl phenyl ether 700572-3 126-998 Benzene, 1-chloro-4-phenoxy- 8270 8270 10 10 1,3-Butadiende, 2-chloro- 8010 50 8240 5 Chloroprene 4 - 453 Hazardous Waste Common name2 CAS RN3 CAS index name4 Suggeste d methods PQL (g/L)6 5 Chromium (Total) Chromium 6010 70 7190 500 Chrysene 218-019 Chrysene 7191 8100 10 200 Cobalt (Total) Cobalt 8270 6010 10 70 7200 500 Copper (Total) Copper 7201 6010 10 60 m-Cresol 108-394 95-48-7 106-445 57-12-5 94-75-7 Phenol, 3-methyl- 7210 8270 200 10 Phenol, 2-methylPhenol, 4-methyl- 8270 8270 10 10 Cyanide Acetic Acid, (2,4-dichlorophenoxy)- 9010 9150 a 10 72-54-8 Benzene chloro- 1,1’-(2,2-dichloroethylidene) bis[4- 8080 0.1 4,4’-DDE 72-55-9 Benzene, chloro- 1,1’-(dichloroethenylidene) bis[4- 8270 8080 10 0.05 4,4’-DDT 50-29-3 Benzene, 1,1’-(2,2,2-trichloroethylidene) bis[4chloro- 8270 8080 10 0.1 Diallate 230316-4 53-70-3 Carbamothioic acid, bis(1-methylethyl)-, S- (2,3dichloro-2- propenyl) ester Dibenz[a,h]anthracene 8270 8270 10 10 8100 200 132-649 124-481 Dibenzofuran 8270 8270 10 10 Methane, dibromochloro- 8010 1 96-12-8 Propane, 1,2-dibromo-3-chloro- 8240 8010 5 100 8240 5 8270 8010 10 10 8240 5 0-Cresol p-Cresol Cyanide 2,4-D; 2,4Dichlorophenoxyacetic acid 4,4’-DDD Dibebz[a,h]anthracene Dibenzofuran Dibromochloromethane; Chlorodibromomethane 1,2-Dibromo-3chloropropane; DBCP 1,2-Dibromoethane; Ethylene dibromide 106-934 Ethane, 1,2-dibromo- 4 - 454 Hazardous Waste Common name2 CAS RN3 CAS index name4 Suggeste d methods PQL (g/L)6 5 Di-n-butyl phthalate 84-74-2 1,2-Benzenedicarboxylic acid, dibutyl ester 8060 5 0-Dichlorobenzene 95-50-1 Benxene, 1,2-dichloro- 8270 8010 10 2 8020 5 8120 10 8270 8010 10 5 8020 5 8120 10 8270 8010 10 2 8020 5 8120 15 m-Dichlorobenzene p-Dichlorobenzene 541-731 106-467 benzene, 1,3-dichloro- Benzene, 1,4-dichloro- [1,1’-Biphenyl]-4,4’-diamine, 3,3’-dichloro2-Butene, 1,4-dichloro-, (E) 8270 8270 8240 10 20 5 Dichlorodifluoromethane 91-94-1 110-576 75-71-8 Methane, dichlorodifluoro- 8010 10 1,1-Dichloroethane 75-34-3 Ethane, 1,1-dichloro- 8240 8010 5 1 1,2-Dichloroethane; Ethylene dichloride 107-062 Ethane, 1,2-dichloro 8240 8010 5 0.5 1,1-Dichloroethylene; Vinylidene chloride 75-35-4 Ethane, 1,1-dichloro- 8240 8010 5 1 trans-1,2-Dichloroethylene 156-605 Ethane, 1,2-dichloro-, (E)- 8240 8010 5 1 2,4-Dichlorophenol 120-832 Phenol, 2,4-dichloro- 8240 8040 5 5 2,6-Dichlorophenol 1,2-Dichloropropane 87-65-0 78-87-5 Phenol, 2,6-dichloroPropane, 1,2-dichloro- 8270 8270 8010 10 10 0.5 8240 5 3,3’-Dichlorobenzidine trans-1,4-Dichloro-2-butene 4 - 455 Hazardous Waste Common name2 CAS RN3 CAS index name4 Suggeste d methods PQL (g/L)6 5 cis-1,3-Dichloropropene 1006101-5 1-Propene, 1,3-dichloro-, (Z) 8010 20 trans-1,3-dichloropropene 1006102-6 1-Propene, 1,3-dichloro-, (E) 8240 8010 5 5 Dieldrin 60-57-1 8240 8080 5 0.05 Diethyl phthalate 84-66-2 2,7:3,6-Dimethanonaphth [2,3-b]oxirene, 3, 4, 5, 6, 9, 9- hexachloro- 1a, 2, 2a, 3, 6, 6a, 7, 7aoctahydro, (1a, 2, 2a, 3, 6, 6a, 7, 7a)1,2-Benzenedicarboxylic acid, diethyl ester 8270 8060 10 5 O,O-Diethyl O-2-pyrazinyl phosphorothioate; Thionazin Dimethoate 297-972 60-51-5 8270 8270 10 10 8270 10 p(Dimethylamino)azobenzene 7,12Dimethylbenz[a]anthracene 3,3’-Dimtheylbenzidine 60-11-7 Phosphorothioic acid, O,O-diethyl O-pyrazinyl ester Phosphorodithioic acid, O,O-dimethyl S-[2(methylamino)-2- oxoethyl] ester Benaenamine, N,N-demethyl-4-(phenylazo)- 8270 10 57-97-6 Benz[a]anthracene, 7,12-demithyl- 8270 10 119-937 122-098 105-679 [1,1’-Biphenyl]-4,4’-diamine, 3,3’-dimethyl- 8270 10 Benzeneethanamine, -dimethyl- 8270 10 Phenol, 2,4-dimethyl- 8040 5 Dimethyl phthalate 131-113 1,2-Benzenedicarboxylic acid, dimethyl ester 8270 8060 10 5 m-Dinitrobenzene 4,6-Dinitro-o-cresol 99-65-0 534-521 Benzene, 1,3-dinitroPhenol, 2-methyl-4,6-dinitro- 8270 8270 8040 10 10 150 2,4-Dinitrophenol 51-28-5 Phenol, 2,4-dinitro- 8270 8040 50 150 2,4-Dinitroltoluene 121-142 Benzene, 1-methyl-2,4-dinitro- 8270 8090 50 0.2 2,6-Dinitrotoluene 606-202 Benzene, 2-methyl-1,3-dinitro- 8270 8090 10 0.1 Dinoseb; DNBP; 2-sec-Butyl4,6-dinitrophenol 88-85-7 Phenol, 2-(1-methylpropyl)-4,6-dinitro- 8270 8150 10 1 Di-n-octyl phthalate 117-840 1,2-Benzenedicarboxylic acid, dioctyl ester 8270 8060 10 30 8270 10 alpha, alphaDimehtylphenethylamine 2,4-Dimethylphenol 4 - 456 Hazardous Waste Common name2 CAS RN3 CAS index name4 Suggeste d methods PQL (g/L)6 5 1,4-Dioxane 123-911 122-394 298-044 1,4-Dioxane 8015 150 Benzenamine, N-phenyl- 8270 10 8140 2 Endosulfan I 959-988 8270 8080 10 0.1 Endosulfan II 3321365-9 8250 8080 10 0.05 Endosulfan sulfate 103107-8 8080 0.5 Endrin 72-20-8 6,9-Methano-2,4,3-benzodioxathiepin, 6, 7, 8, 9, 10, 10-hezachloro-1, 5, 5a, 6, 9, 9a-hexahydro-, 3-oxide, (3, 5a, 6, 9, 9a)6,9-Methano-2,4,3-benzodioxathiepin, 6, 7, 8, 9, 10, 10-hezachloro-1, 5, 5a, 6, 9, 9a-hexahydro-, 3-oxide, (3, 5a, 6, 9, 9a)6,9-Methano-2,4,3-benzodioxathiepin, 6, 7, 8, 9, 10, 10-hezachloro-1, 5, 5a, 6, 9, 9a-hexahydro-, 3, 3-dioxide 2,7:3,6-Dimethanonaphth[2,3-b]oxirene, 3, 4, 5, 6, 9, 9- hexachloro- 1a, 2, 2a, 3, 6, 6a, 7, 7aoctahydro-, (1a, 2, 2a, 3, 6, 6a, 7, 7a)1,2,4-Methenocyclopenta[cd]pentalene-5carboxaldehyde, 2, 2a, 3, 3, 4, 7hexachlorodecahydro-, (1, 2, 2a, 4, 4a, 5, 6a, 6b, 7R*)Benzene, ethyl- 8270 8080 10 0.1 8250 10 8080 0.2 8270 10 8020 2 8240 8015 8250 8270 8270 8270 8270 5 10 5 10 10 10 10 8100 8270 8100 8270 8080 8270 8080 8270 200 10 200 10 0.05 10 1 10 8120 8270 8120 8270 8120 8270 0.5 10 5 10 5 10 Diphenylamine Disulfoton Endrin aldehyde 742193-4 Phosphorodithiuic acid, (ethylthio)ethyl]ester O,O-diethyl Ethylbenzene 100-414 Ethyl methacrylate 97-63-2 2-Propenoic acid, 2-methyl-, ethyl ester Ethyl methanesulfonate Famphur 62-50-0 52-85-7 Methanesulfonic acid, ethyl ester Phosphorothioic acid, [(dimethylamino)sulfonyl]phenyl]dimethyl ester Fluoranthene Fluoranthene Fluorene 206-440 86-73-7 Heptachlor 76-44-8 Heptachlor epoxide 102457-3 Hexachlorobenzene Hexachlorobutadiene 118-741 87-68-3 Hexachlorocyclopentadiene 77-47-4 O, S-[2- O-[4O- 9H-Fluorene 4,7-Methano-1H-indene, 1,4,5,6,7,8,8heptachloro-3a, 4, 7, 7a- tetrahydro2,5-Methano-2H-indeno[1,2-b]oxirene, 2,3,4,5,6,7,7-heptachloro-1a, 1b, 5, 5a, 6, 6a,hexahydro-, (1a, 1b, 2, 5, 5a, 6, 6a) Benzene, hexachloro1,3-Butadiene, 1,1,2,3,4,4-hexachloro1,3-Cyclopentadiene, 1,2,3,4,5,5-hexachloro- 4 - 457 Hazardous Waste Common name2 CAS RN3 CAS index name4 Suggeste d methods PQL (g/L)6 5 Hexachloroethane 67-72-1 Ethane, hexachloro- Hexachlorophene Hexachloropropene 70-30-4 188871-7 591-786 193-395 78-83-1 465-736 2-Hexanone Indeno(1,2,3-cd)pyrene Isobutyl alcohol Isodrin Isophorone 78-59-1 Isosafrole 120-581 143-500 Kapone Phenol, 2,2’-methylenebis[3,4,6-trichloro1-Propene, 1,1,2,3,3,3-hexachloro- 8120 8270 8270 8270 0.5 10 10 10 2-Hexanone 8240 50 Indeno[1,2,3-cd]pyrene 8100 8270 8015 8015 8270 200 10 50 50 10 8090 8270 8270 60 10 10 8270 8270 10 10 6010 7240 7241 7470 8015 8240 8270 40 1000 10 2 5 5 10 8080 8270 8010 8240 8010 8240 8270 8010 8240 8010 8240 8015 8240 8010 8240 8015 8240 8270 8270 8140 8270 2 10 20 10 1 10 10 15 5 5 5 10 100 40 5 2 5 10 10 0.5 10 1-Propanol, 2-methyl1,4,5,8-Dimethanonaphthalene, 1,2,3,4,10,10hexachloro- 1,4,4a,5,8,8a hexahydro-(1, 4, 4a, 5, 8, 8a)2-Cyclohexen-1-one, 3,5,5-trimethyl1,3-Benzodioxole, 5-(1-propenyl)1,3,4-Metheno-2H-cyclobuta-[cd]pentalen-2one, 1,1a,3,3a,4,5,5,5a,5b,6decachlorooctahydroLead Lead (Total) Mercury Methacrylonitrile Methapyrilene (Total) 126-987 91-80-5 Methoxychlor 72-43-5 Methyl bromide; Bromomethane Methyl chloride; Chloromethane 3-Methylcholanthrene Methylene bromide; Dibromomethane Methylene chloride; Dibromomethane Methyl ethyl ketone; MEK 74-83-9 1,2,Ethanediamine, N,N-dimethyl-N’-2pyridinyl- N’-(2-thienylmethyl)Benzene, 1,1’-(2,2,2,trichloroethylidene)bis[4methoxyMethane, bromo- 74-87-3 Methane, chloro- 56-49-5 74-95-3 Benz[j]aceanthrylene, 1,2-dihydro-3-methylMethane, dibromo- 75-09-2 Methane, dichloro- 78-93-3 2-Butanone Methyl iodide; Iodomethane 74-88-4 Methane, iodo- Methyl methacrylate 80-62-6 2-Propenoic acid, 2-methyl-, methyl ester Methyl methanesulfonate 2-Methylnaphthalene Methyl parathion; Parathion methyl 66-27-3 91-57-6 298-000 Methanesulfonic acid, methyl ester Naphthalene, 2-methylPhosphorothioic acid, O,O-dimethyl nirtophenyl) ester Mercury 2-Propenenetrile, 2-methyl- O-(4- 4 - 458 Hazardous Waste Common name2 CAS RN3 CAS index name4 Suggeste d methods PQL (g/L)6 5 4-Methyl-2-pentanone; Methyl isobutyl ketone Naphthalene 108-101 91-20-3 2-Pentanone, 4-methyl- 1,4-Naphthoquinone 130-154 134-327 91-59-8 (Total) Benaenamine, 2-nitroBenzenamine, 3-nitroBenzenamine, 4-nitro- Nitrobenzene 88-74-4 99-09-2 100-016 98-95-3 o-Nitrophenol 88-75-5 Phenol, 2-nitro- p-Nitrophenol 100-027 56-57-5 924-163 55-18-5 62-75-9 86-30-6 621-647 1059595-6 59-89-2 100-754 930-552 99-55-8 56-38-2 Phenol, 4-nitro- 1-Naphthylamine 2-Naphthylamine Nickel o-Nitroaniline m-Nitroaniline p-Nitroaniline 4-Nitroquinoline 1-oxide N-Nitrosodi-n-butylamine N-Nitrododiethylamine N-Nitrosodimethylamine N-Nitrosodiphenylamine N-Nitrosodipropylamine; Din-propylnitrosamine N-Nitrosomethylethylamine N-Nitrosomorpholine N-Nitrosopiperidine N-Nitrosopyrrolidine 5-Nitro-o-toluidine Parathion Polychlorinated biphenyls; PCBs Polychlorinated dibenzo-pdioxins; PCDDs Polychlorinated dibenzofurans; PCDFs Pentachlorobenzene Pentachloroethane See Note 7 See Note 8 See Note 8 608-935 76-01-7 Pentachloronitrobenzene 82-68-8 1,4-Naphthalenedione 8015 8240 8100 8270 8270 5 50 200 10 10 1-Naphthalenamine 8270 10 2-Naphthalenamine Nickel 8270 6010 7520 8270 8270 8270 10 50 400 50 50 50 Quinoline, 4-nitro-, 1-oxide 1-Butanamine, N-butyl-N-nitroso- 8090 8270 8040 8270 8040 8270 8270 8270 40 10 5 10 10 50 10 10 ethanamine, N-ethyl-N-nitrosoMethanamine, N-methyl-N-nitrosoBenzenamine, N-nitroso-N-phenyl1-Propanamine, N-nitroso-N-propyl- 8270 8270 8270 8270 10 10 10 10 Ethanamine, N-methyl-N-nitroso- 8270 10 Morpholine, 4-nitrosoPiperidine, 1-nitroso- 8270 8270 10 10 Pyrrolidine, 1-nitroso- 8270 10 Benzenamine, 2-methyl-5-nitroPhosphorothioic acid, O,O-diethyl-O-(4nitrophenyl) ester 1,1’-Biphenyl, chloro derivatives 8270 8270 10 10 8080 50 Dibenzo[b,e][1,4]dioxin, chloro derivatives 8280 0.01 Bibenzo[b,e][1,4] dioxin, chloro derivatives 8280 0.01 Benzene, pentachloro- 8270 10 Ethane, pentachloro- 8240 8270 8270 5 10 10 Naphthalene Benzene, nitro- Benzene, pentachloronitro- 4 - 459 Hazardous Waste Common name2 CAS RN3 CAS index name4 Suggeste d methods PQL (g/L)6 5 Pentachlorophenol 87-86-5 Phenol, pentachloro- Phenacetin Phenanthrene 62-44-2 85-01-8 Acetamide, N-(4-ethoxyphenyl) Phenanthrene Phenol Phenol Safrole Selenium 108-952 106-503 298-022 109-068 2395058-5 107-122 129-000 110-861 94-59-7 (Total) Silver (Total) Silver Silvex; 2,4,5-TP Styrene 93-72-1 100-425 1849625-8 93-76-5 Propanoic acid, 2-(2,4,5-trichlorophenoxy)Benzene, ethenyl- p-Phenylenediamine Phorate 2-Picoline Pronamide Propionitrile; Ethyl cyanide Pyrene Pyridine Sulfide 2,4,5-T; 2,4,5Trichlorophenoxyacetic acid 2,3,7,8-TCDD; 2,3,7,8Tetrachlorodibenzo-p- dioxin 1,2,4,5-Tetrachlorobenzene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethylene; Perchloroethylene; Tetrachloroethene 2,3,4,6-Tetrachlorophenol Tetraethyl dithiopyrophosphate; Sulfotepp Thallium 8040 8270 8270 8100 8270 8040 8270 8270 5 50 10 200 10 1 10 10 8140 8270 8240 8270 8270 2 10 5 10 10 Sulfide 8015 8240 8100 8270 8240 8270 8270 6010 7740 7741 6010 7760 8150 8020 8240 9030 60 5 200 10 5 10 10 750 20 20 70 100 2 1 5 10,000 Acetic acid, (2,4,5- trichlorophenoxy)- 8150 2 174601-6 95-94-3 630-206 79-34-6 Dibenzo[b,e][1,4]dioxin, 2,3,7,8-tetrachloro- 8280 0.005 Benzene, 1,2,4,5-tetrachloroEthane, 1,1,1,2-tetrachloro- 127-184 Ethene, tetrachloro- 8270 8010 8240 8010 8240 8010 8240 10 5 5 0.5 5 10 10 58-90-2 368924-5 Phenol, 2,3,4,5-tetrachloroThiodiphosphoric acid tetraethyl ester 8270 8270 10 10 (Total) Thallium 6010 7840 7841 400 1000 10 1,4-Benzenediamine Phosphorodithioic acid, [(ethylthio)methyl]ester Pyridine, 2-mehtylBenzamide, propynyl)Propanenitrile O,O-diethyl S- 3,5-dichloro-N-(1,1-dimethyl-2- Pyrene Pyridine 1,3-Benzodioxole, 5-(2-propenyl)Selenium Ethane, 1,1,2,2-tetrachloro- ([(HO)2P(S)]2O), 4 - 460 Hazardous Waste Common name2 CAS RN3 CAS index name4 Suggeste d methods PQL (g/L)6 5 Tin Toluene Benzene, 1,2,4-trichloro- 7870 8020 8240 8270 8080 8250 8270 8000 2 5 10 2 10 10 Ethane, 1,1,1-trichloro- 8240 5 79-00-5 Ethane, 1,1,2-trichloro- Trichloroethylene; Trichloroethene Trichlorofluoromethane 79-01-6 Ethene, trichloro- 75-69-4 Methane, trichlorofluoro- 2,4,5-Trichlorophenol 2,4,6-Trichlorophenol 95-95-4 88-06-2 Phenol, 2,4,5-trichloroPhenol, 2,4,6-trichloro- 1,2,3-Trichloropropane 96-18-4 Propane, 1,2,3-trichloro- O,O,O-Triethyl phosphorothioate sym-Trinitrobenzene Vanadium 126-681 99-35-4 (Total) Phosphorothioic acid, O,O,O-triethyl ester 8010 8240 8010 8240 8010 8240 8270 8040 8270 8010 8240 8270 0.2 5 1 5 10 5 10 5 10 10 5 10 Vinyl acetate 108-054 75-01-4 Acetic acid, ethenyl ester 8270 6010 7910 7911 8240 10 80 2000 40 5 o-Toluidine Toxaphene 1,2,4-Trichlorobenzene 1,1,1-Trichloroethane; Methylchloroform 1,1,2-Trichloroethane Vinyl chloride (Total) 108-883 95-53-4 800135-2 120-821 71-55-6 Tin Benzene, methylBenzenamine, 2-methylToxaphene Benzene, 1,3,5-trinitroVanadium Ethene, chloro- 8010 2 8240 10 Xylene (total) 1330Benzene, dimethyl8020 5 20-7 8240 5 Zinc (Total) Zinc 6010 20 7950 50 1The regulatory requirements pertain only to the list of substances; the right hand columns (Methods and PQL) are given for informational pur poses only. See also footnotes 5 and 6. 2Common names are those widely used in government regulations, scientific publications, and commerce; synonyms exist for many chemicals. 3Chemical Abstracts Service registry number. Where “Total” is entered, all species in the ground water that contain this element are included. 4CAS index names are those used in the 9th Cumulative Index. 5Suggested Methods refer to analytical procedure numbers used in EPA Report SW-846 “Test Methods for Evaluating Solid Waste”, third edition,. Analytical details can be found in SW-846 and in documentation on file at the agency. The packed column gas chromotography methods 8010, 8020, 8030, 8040, 8060, 8080, 8090, 810, 8120, 8140, 8150, 8240, and 8250 were promulgated methods through Updates III of SW-846 and, as of Update III, the AGency has replaced these methods with “capillary column GC methods”, as the suggested methods. CAUTION: The methods listed are representative SW-846 procedures and may not always be the most suitable method(s) for monitoring an analyte under the regulations. 4 - 461 Hazardous Waste 4 - 462 Hazardous Waste Appendix 4-13 Interim Primary Drinking Water Standards (40 CFR 265, Appendix III) Parameter Arsenic Barium Cadmium Chromium Fluoride Lead Mercury Nitrate (as N) Selenium Silver Endrin Lindane Methoxychlor Toxaphene 2,4-D 2,4,5-TP Silver Radium Gross alpha Gross beta Turbidity Coliform bacteria Maximum level (mg/L) 0.05 1.0 0.01 0.05 1.4 - 2.4 0.05 0.002 10 0.01 0.05 0.0002 0.004 0.01 0.005 0.1 0.01 5 pCi/1 15 pCi/1 4 mrem/yr 1/TU 1/100 mL (NOTE: Turbidity is only applicable to surface water supplies.) 4 - 463 Hazardous Waste 4 - 464 Hazardous Waste