CLASS: M.Sc. CHEMISTRY 15N/367 St. JOSEPH’S COLLEGE (AUTONOMOUS) TIRUCHIRAPPALLI – 620 002 SEMESTER EXAMINATIONS – NOVEMBER 2015 TIME: 40 Minutes. MAXIMUM MARKS: 30 SEM SET PAPER CODE TITLE OF THE PAPER I 2015 14 PCH 1102 ORGANIC CHEMISTRY - I SECTION - A Answer all the questions: Choose the correct answer: 1. What do you understand by the 3D pictorial representations of the wave functions of the electrons? a) c) 2. 3. 4. 5. 30 X 1 = 30 orbitals eigen values b) d) eigen functions both A & B Identify the propable shape of the 3dz2 orbital. a) b) c) d) none Identify the hybridization and geometry at the carbonyl group in acetone. a) sp2, tetrahedral b) sp2, linear c) sp2, trigonal planar d) sp3, square pyramidal Identify the most polar molecule in the given list. a) Ph-OH b) Ph-NO2 c) p-C6H4Cl2 d) C6H5Br Choose the correct order of decreasing strength of +I groups. a) O- > COO- > CR3 > CH2R > CH3 b) NR3+ > SR2+ > NH3+> NO2 > SO2R c) COOH > F > Cl > Br > OAr d) O- < COO- < CR3 < CH2R < CH3 6. 7. 8. 9. 10. 11. 12. 13. 14. What term does signify the instantaneous-dipole-induced-dipole interactions operating between non-polar molecules? a) Hydrogen bonding b) dipole-dipole interaction c) van der Waals interactions d) all the three A, B & C Identify the isomerism exhibited by the given compound – CH3CH=C(Br)CH2CH3 (3-bromopent-2-ene) a) Z-E isomerism b) cis-trans isomerism c) optical isomerism d) none How many stereoisomers are possible to exist for aldotetrose? a) 9 b) 10 c) 8 d) 4 What do you understand by the term 'diastereomers'? a) non-superimposable mirror-image isomers b) non-superimposable non-mirror-image isomers c) superimposable mirror-image isomers d) none What is not true about axial chirality? a) Two pairs of vertices in the elongatedtetrahedron b) absence Cn, i, s, Sn symmetry c) asymmetric carbon d) chiral axis What kind of chirality is shown by the 'ansa' compounds? a) carbon chirality b) axial chirality c) planar chirality d) all the three A, B & C Which of the following is true about (S)-enantiomer? a) it rotates the plane of polarized light to the right b) it rotates the plane of polarized light to the left c) it's the mirror-image of the corresponding R-enantiomer d) it has the highest priority order group on the left The Huckel’s 4n+2 rule is applicable to a) alicyclic compounds b) aromatic compounds c) cyclic compounds d) polycyclic compounds Which of the following is the same as the tropylium ion? a) cyclopropenyl anion b) cyclopentadienyl cation c) cycloheptatrienyl anion d) cycloheptatrienyl cation 15. 16. 17. 18. 19. 20. 21. 22. 23. How many spin states do exist for the carbene intermediate a) singlet b) triplet c) doublet d) both A and B Pinacol-pinacolone rearrangement takes place through the formation of the intermediate a) carbaninon b) carbocation c) carbene d) nitrene How many resonance structures are there for naphthalene other than the Dewar's structures? a) 5 b) 4 c) 3 d) 2 The order of stability of carbonimu ion is a) Secondary > tertiary > primary b) Primary> secondary > tertiary c) Tertiary > secondary > primary d) None of these In a homolytic bond fission, which of the following is formed? a) carbonium ion b) carbanion c) free-radical d) none Exchange of an atom in the substrate for one of its heavier isotope leads to a) decrease in rate b) increase in rate c) iostope effect d) both A & C The rate of a overall reaction is determined by the rate of a) fast step b) slow step c) equilibrium step d) none In an organic reaction, the leaving group goes with an unshared pair of electrons is called a) nucleofuge b) nucleophile c) electrofuge d) electrophile What is the impact of anchimeric assistance on the rate of a reaction? a) rate, enhanced b) rate, retarded c) product yield, enhanced d) none 24. 25. 26. 27. 28. 29. 30. A reaction will be ______ if the energy of the products is less than the energy of the reactants. a) endothermic b) exothermic c) isothermic d) none Identify the type of reaction, given: R-X + Z: ------> R-Z + Xa) nucleophilic substitution b) electrophilic substitution c) diradical substitution d) none We have a set of substrates and nucleophiles: a. RI b. RNMe3+ c. OH- d. NMe3 e. H2S predict the possible combinations of reactions a) a + c, a + d, b + c, b + e b) a + c, a + e, b + c, b + c c) a + e, a + d, b + c, b + e d) a + c, a + e, b + c, b + d Identify the exact stereochemical implication of the given reaction.(+)-malic acid + SOCl2 ------> (+)-chlorosuccinic acid a) SNi reaction b) retention of configuration c) internal nucleophile d) all the three A, B & C Why does norbornenyl tosylate substrate reacts faster than the norbonyl tosylate in the solvolytic reaction? a) easy formation of non-classical carbonium ion b) anchimetic assistance by the pi-bond c) favourable geometry d) all the three – A, B & C One of the modern methods of studying free radicals, formed during the course of a reaction is a) I.R spectra b) U.V spectra c) CIDNP d) Microwave spectra What is the electrphile in the haloform reaction? a) H+ b) OHc) CH3+ d) X+ *********************