Current Status of Leak Detection System Evaluations Under EPA’s Environmental Technology Verification Program Advanced Monitoring System Center Joe Carvitti and Anne Gregg Battelle Memorial Institute Presented September 21, 2010 22nd National Tanks Conference Presentation Overview • Environmental Technology Verification (ETV) Program Overview • Leak Detection Verification Test Objectives • Automatic Tank Gauging (ATG) Test and Quality Assurance Plan (TQAP) Considerations • ATG TQAP Development • ATG TQAP Implementation 1 EPA ETV Program Overview Advanced Monitoring Systems (AMS) Center • ETV - Voluntary program that provides decision-makers with credible test data on technology performance without comparison or judgment • Credible and fair – Meets EPA and ETV quality system requirements; open and transparent, third-party verification – Peer reviewed process • AMS Center operated by Battelle - Verifies technologies that monitor, sample, and characterize in a variety of matrices – Addresses technology sustainability: recycling, waste streams, etc. – Improves the state of environmental science and data 2 ETV Overview • EPA – Owns the ETV process and guides its use, conducts outreach, technical and quality assurance (QA) support/reviews • Stakeholder-based verification process with support of technical panel and vendor panel – Prioritize technology categories and identify test parameters – Review reports/test plans/protocols – Members include federal, state, academia, and industry • Collaborators – Technology buyers, users, developers, vendors, and “enablers” (consultants, government, regulators, financiers, etc.) – Identify (or provide) sources of funding or in-kind support 3 ETV Verification Process EPA, verification organizations, stakeholders* (*Over 300 active stakeholders) With stakeholders and technical panel, develop test protocols, qualityassurance test plans Conduct technology testing** AND Identify priority technology categories ETV Outreach Identify vendors, collaborators Write verification report www.epa.gov/etv **Vendor reviews and approves test plan before testing begins. 4 AMS Center Facts and Statistics • 149 verified technologies, 37 test/quality assurance plans (TQAP) to date • Stakeholder driven participation in: – Air and water advisory groups – Ad-hoc technical panels (as needed for TQAP development) • Published first international joint ETV verification protocol (ETV Canada) and first international joint ETV verification test with Nordic Water Technology Verification Center (EU/Denmark) 5 Leak Detection Verification Test Objectives • Review current EPA test protocols to identify areas that may be affected by ethanol-blended fuels • Develop an ETV TQAP to be used to verify the performance of underground storage tank leak detection technologies with ethanol-blended fuels • Provide recommendations for updating the protocols to address new fuels 6 ATG TQAP ConsiderationsUnderlying Technical Issues • What are the important principles? – Petroleum and ethanol have very different chemical and physical properties - technologies that operate based on these properties may not function properly in a new environment (examples: density, conductivity, refractive index) – Petroleum and water do NOT mix, so if water enters the tank, it will fall to the bottom immediately. On the other hand, water and ethanol DO mix - so water ingress will not become evident until the fuel “phase separates” - at which point the fuel is unusable. 7 ATG TQAP ConsiderationsPerformance Requirements • ATG requirements are defined in 40 CFR 280, Subpart D – Must be capable of detecting a leak of 0.20 gallon per hour with a probability of (at least) 95%, while operating at a false alarm rate of 5% or less – Must conduct inventory reconciliation (IR) - Measure the height of the liquid to the nearest 1/8 inch - Declare a leak on the basis of the IR if the discrepancy exceeds 1% of the flow-through plus 130 gallons on a monthly basis – Must measure any water in the bottom of the tank at least once a month to the nearest 1/8 inch - Determine the minimum water level that the system can detect - Determine the smallest change in the water level that the system can reliably measure 8 ATG TQAP ConsiderationsExisting and Legacy Equipment Various ATG Technologies Use Different Operating Principles Technology Type Operating Principle Magnetostrictive Probe A wire sensor inside a stainless steel rod detects the presence of a magnetic field, which indicates the height of a float. Ultrasonic Probe A sensor detects sound wave echoes reflected from an interface of water/fuel or fuel/air to calculate the liquid level based on the speed of sound in the media. Mass Buoyancy Probe The buoyancy of a probe is detected on a load cell and compared to the tank geometry to calculate the liquid level. Mass Measurement Probe Mass data is transferred to a load cell and compared to the tank geometry to calculate the liquid level. Capacitance Probe Detection is based on the dielectric property of the stored liquid. Water Level Float (part Buoyancy of float allows the signal generated (e.g., magnetic of the magnetostrictive field) to coincide with the top of the liquid layer based on the technology) liquid density in comparison to float density. 9 ATG TQAP ConsiderationsTechnical and Vendor Panels Technical Panel Name Andrea Barbery Greg Baretta Jim Barnette Mark Barolo Michael Doucette Mike Eck Laura Fisher Jerry Flora Sam Gordji Kevin Henderson Brad Hoffman Steve Howell Curt Johnson Mike Juranty Kevin Keegan Brian Knapp Fran Kremer Ed Kubinsky Bill Moore Kristy Moore Mark Morgan Marcel Moureau Mohamed Mughal Shaheer Muhanna Marcia Poxson Stephen Purpora Bob Renkes Peter Rollo Erik Sirs Tim Smith Willo Smith Jim Weaver Ken Wilcox John Wilson Andrea Zajac Affiliation Office of Underground Storage Tanks (OUST) Engineering Consultant Bureau of Storage Tank Regulation (WI) SIGMA OUST Northeast Tank Services Army Environmental Command UST Leak Prevention Unit (California) JDF Consulting SSG Associates, University of Mississippi Mississippi Department of Environmental Quality Tanknology National Biodiesel Board (NBB), MARC-IV Consulting Inc. Alabama Department of Environmental Management NH Department of Environmental Services Waste Management Divi Tanknology American Petroleum Institute (API) USEPA Office of Research and Development (ORD) Crompco, LLC UT Department of Environmental Quality, Division of Environmental Response and Remediation Renewable Fuels Association (RFA) Petroleum Marketers Association of America (PMAA) Marcel Moreau Associates Army Environmental Command (AEC) Georgia Department of Natural Resources Michigan Dept of Environmental Quality Protanic Petroleum Equipment Institute (PEI) Delaware Natural Resources and Environmental Conservation Region 10 OUST 7-11 USEPA National Exposure Research Laboratory/ORD Ken Wilcox Associates, Inc. (KWA Associates) USEPA Robert S. Kerr Environmental Research Center Michigan Department of Environmental Quality Vendor Panel Name Affiliation Randy Barnes Alert Technologies Ken Cornett Veeder-Root Tom D'Alessandro OMNTEC Mfg., Inc. Howard Dockery Simmons John Levy Pneumercator Company, Inc. Douglas Mann VISTA Leak Detection, Inc. Dan Marston Franklin Fueling Systems Bob Moss Veeder-Root Bill Nelson Franklin Fueling Systems Kent Ried Veeder-Root Lorraine Sabo Franklin Fueling Systems George Thuemling Varec, Inc. Larry Tripp AMETEK APT Jim Walton OPW Fuel Management Systems Greg Young Vaporless Mfg., Inc. 10 ATG TQAP ConsiderationsProspective Scales of Testing • Laboratory scale (100 to <5,000 gal) – At Battelle West Jefferson laboratories • Field scale (1,000s to 10,000s of gal) – Out-of-service (OOS) tanks under or above ground - Controlled conditions - Testing consultant site or private/government-owned OOS tank site – In-service fueling stations, underground tanks - Actual operating conditions - Service stations where the technologies are installed 11 ATG TQAP ConsiderationsOther Technical Questions • Numerous technical questions were discussed in Technical and Vendor Panel meetings – How can volume changes or ingress of miscible materials be evaluated? – Can a three-phase separation occur? How can it be evaluated? – What nominal levels of alcohol blends should be considered? – How does biodiesel impact ATG performance? – Do current simulated leak methods work for blended fuels? – Is fuel temperature a necessary test variable? – What number of tests is needed? – Is the tank tightness QA from the Protocol acceptable? – Should ground water level be monitored? – Should “time to detection” be determined? – Can results be extrapolated to other tank sizes? – Is it necessary to investigate seasonal additives? – Does the test design present any obvious or inherent difficulties or technical limitations? 12 ATG TQAP DevelopmentKey Variables and Parameters Variables and Performance Parameter Selection for Evaluation is Critical to Test Outcome Performance Parameters Accuracy False alarm (fuel leak detection only) Sensitivity Precision Phase separation (water ingress detection only) Operational data Dependent Variables Fuel leak detection Water ingress detection Independent Variables Fuel type (ethanol content) Fuel leak rate Fuel height in tank Fuel temperature Water ingress method/rate 13 ATG TQAP DevelopmentDesign Overview • • • • Four sets of experiments Bench scale preliminary experiments Baseline experiments with pure gasoline Water ingress – 3 variables - Fuel type / alcohol content (5 levels) Temperature (3 levels) Fuel height (3 levels) Ingress method/rate (3 levels) • Fuel leak – 4 variables - Fuel type / alcohol content (5 levels) Temperature (3 levels) Fuel height (3 levels) Fuel leak rate (3 levels) 14 ATG TQAP DevelopmentProspective Variables • Water ingress method and rate • Fuel alcohol content – E0, E10, E17, E27, E85 – In fuel dump/quick; well mixed • Fuel leak rate – Through fill pipe or large hole/quick or semiconstant stream • Fuel height – Through a small hole in the tank/slow and constant; least mixed • Temperature of fuel – 0.0, 0.1, 0.2, gal/hour – 20-25%, 50%, 90-95% full – Initial temperature (Ti) – Ti plus 5º F – Ti plus 10º F 15 ATG TQAP DevelopmentAnticipated Test Facilities Battelle’s West Jefferson, OH Facility can Support ETV Testing JS-20 XP rated support Building JS-10 Blast rated test Building 16 ATG TQAP DevelopmentStatistical Fuel Leak Test Matrix Fuel Leak Rate, gallons per hour Fuel Height in Tank (j) Ti 20-25% full Starting Fuel Ethanol Content, percent E10 0.0 0.1 0.2 Temperature, F Temperature, F Temperature , F Ti+5 Ti+10 Initial Ti+5 Ti+10 Initial Ti+5 Ti+10 DUPE 50% full DUPE 90-95% full 20-25% full E17 DUPE 50% full 90-95% full DUPE 20-25% full E27 50% full DUPE 90-95% full DUPE 20-25% full E85 DUPE 50% full 90-95% full DUPE 17 ATG TQAP DevelopmentStatistical Water Ingress Test Matrix Water Ingress Method/rate Fuel Height in Tank (j) Instantaneous Ingress Ingress Over 1-hour Period Ingress over 2-hour Period Temperature, F Temperature, F Temperature, F Ti 20-25% full Starting Fuel Ethanol Content, percent E10 Ti+5 Ti+10 Ti Ti+5 Ti+10 Ti Ti+5 Ti+10 DUPE 50% full DUPE DUPE 90-95% full 20-25% full E17 DUPE 50% full 90-95% full DUPE DUPE DUPE 20-25% full E27 50% full DUPE DUPE 90-95% full DUPE 20-25% full E85 50% full DUPE DUPE 90-95% full 18 Verification Test ImplementationGeneral Test Schedule • Activity and Tentative Schedule – Vendor recruitment and commitments (SeptemberOctober) – Final TQAP approval by vendors and EPA (December) – Testing preparations (October-December) – Testing (January-March 2011) – Data analysis and reporting (April-June 2011) 19 Verification Test ImplementationLogistical Issues • Logistical issues are also being considered – Where/how should we blend the fuel? – How will the fuel be disposed/used after testing is completed? – How will randomization be accomplished? – Must other test facilities be identified? 20 www.epa.gov/etv Contact: John McKernan USEPA 26 W. Martin Luther King Dr. Cincinnati, OH 45268 Email: McKernan.John@epa.gov Phone: 513-569-7415 Amy Dindal, Program Manager Battelle Memorial Institute Email: DindalA@battelle.org Phone: (561) 422-0113 Joe Carvitti, UST LD Project Manager Battelle Memorial Institute Email: CarvittiJ@battelle.org Phone: (614) 424-4843 Tim Smith USEPA, OUST Email: Smith.TimR@epamail.epa.gov Phone: (703) 603-7158 21 21