CanadaColorsandChemicalsLimited
152KennedyRoadSouth
Brampton,Ontario
Canada
L6W3G4
GeneralInquiryNumber:(905)459Ͳ1232
MaterialSafetyDataSheet
Attached
Operations Center
MK MONOMERS LLC
905 Brickell Bay Drive Miami, FL 33131
300 Rike Drive *
Millstone Twp., NJ,
08535
Magnakron.com
Info@magnakron.com
732-928-5800
Fax 609-448-4980
SAFETY DATA SHEET
1.
Identification
CAS #
Product use
Recommended Restrictions
Synonym(s)
Chemical formula
Manufacturer
24 Hour Emergency
response Information
Chemtrec number
2.
Hazards identification
GHS classification
Physical Hazards
Health hazards
Environmental hazards
3.
4.
Composition/information on ingredients
Components
Maleic Anhydride
First aid measures
First aid procedures
Inhalation
Maleic Anhydride (KRONTRO-MA)
108-31-6
Not available
Thisproductisdistributedby
Not available
CanadaColorsandChemicalsLimited
(905) 459-1232
GeneralInquiry:(416)449Ͳ7750
Toxilic anhydride
24HourEmergency:(416)444Ͳ2112
C4H2O3
CCC:ProductCode:______________________
Magna-Kron Corp.
."-&*$"/):%3*%&#3*26&55&4
CCC:ProductName:______________________________________
640 Herman Road, Suite 1
Jackson, NJ 08527
732-928-5800
Info@magnakron.com
Chemtrec: 1-800-424-9300
CCN620540
Very hazardous in case of ingestion. Hazardous in case of skin
contact (irritant, permeator), of eye contact (irritant), of inhalation.
Corrosive to eyes and skin. The amount of tissue damage depends
on length of contact. Eye contact can result in corneal damage or
blindness. Skin contact can produce inflammation and blistering.
Inhalation of dust will produce irritation to gastro-intestinal or
respiratory tract, characterized by burning, sneezing and coughing.
Severe over-exposure can produce lung damage, choking,
unconsciousness or death.
Very hazardous in case of ingestion.
Hazardous in case of skin contact (irritant, permeator), of eye
contact (irritant), of inhalation.
The substance is toxic to lungs, mucous membranes.
Repeated or prolonged exposure to the substance can produce
target organs damage. Repeated exposure of the
eyes to a low level of dust can produce eye irritation. Repeated
skin exposure can produce local skin destruction,
or dermatitis. Repeated inhalation of dust can produce varying
degree of respiratory irritation or lung damage.
Not available
CAS #
108-31-6
Percent
100%
Allow the victim to rest in a well-ventilated area. Seek immediate
medical attention. Serious Inhalation: Evacuate the victim to a
safe area as soon as possible. Loosen tight clothing such as a
collar, tie, belt or waistband. If breathing is difficult, administer
oxygen. If the victim is not breathing, perform mouth-to-mouth
resuscitation. WARNING: It may be hazardous to the person
1|5
Material name: Maleic Anhydride
Revision date: 10/1/2014
MK MONOMERS LLC
905 Brickell Bay Drive Miami, FL 33131
Magnakron.com
Info@magnakron.com
Operations Center
300 Rike Drive *
Millstone Twp., NJ,
08535
732-928-5800
Fax 609-448-4980
Skin
Eye
Ingestion
Notes to physician
5.
Fire-fighter measures
Suitable extinguishing media
Specific hazards arising from
the chemical
Protective equipment and
precautions for firefighters
6.
7.
Accidental release measures
Personal precautions
Environmental precautions
Methods for containment
Methods for cleaning up
providing aid to give mouth-to-mouth resuscitation when the
inhaled material is toxic, infectious or corrosive. Seek immediate
medical attention.
If the chemical got onto the clothed portion of the body, remove
the contaminated clothes as quickly as possible, protecting your
own hands and body. Place the victim under a deluge shower. If
the chemical got on the victim's exposed skin, such as the hands:
Gently and thoroughly wash the contaminated skin with running
water and non-abrasive soap. Be particularly careful to clean folds,
crevices, creases and groin. Cold water may be used. If irritation
persists, seek medical attention. Wash contaminated clothing
before reusing. Serious Skin Contact: Wash with a disinfectant
soap and cover the contaminated skin with an anti-bacterial cream.
Seek immediate medical attention.
Check for and remove any contact lenses. Immediately flush eyes
with running water for at least 15 minutes, keeping eyelids open.
Cold water may be used. Do not use an eye ointment. Seek medical
attention.
Do not induce vomiting. Examine the lips and mouth to ascertain
whether the tissues are damaged, a possible indication that the
toxic material was ingested; the absence of such signs, however, is
not conclusive. Loosen tight clothing such as a collar, tie, belt or
waistband. If the victim is not breathing, perform mouth-to-mouth
resuscitation. Seek immediate medical attention.
Not available
SMALL FIRE: Use DRY chemical powder.
LARGE FIRE: Use water spray, fog or foam. Do not use water jet.
Combustible when exposed to heat or flame. Material in
powder form, capable of creating a dust explosion.
When heated to decomposition it emits acrid smoke and irritating
fumes.
Wear positive-pressure self-contained breathing
precautions for firefighters apparatus (SCBA) and protective
firefighting clothing (includes firefighting helmet, coat, trousers,
boots, and gloves).
Small Spill: Use appropriate tools to put the spilled solid in a
convenient waste disposal container. Large Spill: Corrosive solid.
Stop leak if without risk. Do not get water inside container. Do not
touch spilled material. Use water spray to reduce vapors. Prevent
entry into sewers, basements or confined areas; dike if needed.
Eliminate all ignition sources. Call for assistance on disposal. Be
careful that the product is not present at a concentration level
above TLV. Check TLV on the MSDS and with local authorities.
Handling and storage
2|5
Material name: Maleic Anhydride
Revision date: 10/1/2014
Operations Center
MK MONOMERS LLC
905 Brickell Bay Drive Miami, FL 33131
300 Rike Drive *
Millstone Twp., NJ,
08535
Magnakron.com
Info@magnakron.com
732-928-5800
Fax 609-448-4980
Handling
Storage
8.
Exposure controls / personal protection
Recommended monitoring
procedures
Exposure Limits
Personal protective equipment
Eye/face protection
Skin protection
Respiratory protection
Hand protection
9.
Physical and chemical properties
Appearance
Physical state
Color
Odor
pH
Melting point/Freezing point
Boiling point
Flash point
Evaporation rate
Flammability limits in air, lower
% by volume
Flammability limits in are, upper
% by volume
Vapor pressure
Vapor density
Relative density
Solubility
Octanol/H2O coeff
Auto-ignition temperature
Decomposition temperature
Viscosity
Keep container dry. Keep away from heat. Keep away from
sources of ignition. Empty containers pose a fire risk, evaporate the
residue under a fume hood. Ground all equipment containing
material. Do not ingest. Do not breathe dust. Never add water to
this product Wear suitable protective clothing In case of
insufficient ventilation, wear suitable respiratory equipment If
ingested, seek medical advice immediately and show the container
or the label. Avoid contact with skin and eyes Keep away from
incompatibles such as oxidizing agents, reducing agents, acids,
moisture.
Keep container dry. Keep in a cool place. Ground all equipment
containing material. Corrosive materials should be stored in a
separate safety storage cabinet or room.
Use process enclosures, local exhaust ventilation, or other
engineering controls to keep airborne levels below recommended
exposure limits. If user operations generate dust, fume or mist, use
ventilation to keep exposure to airborne contaminants below the
exposure limit.
TWA: 0.25 (ppm) from ACGIH (TLV)
TWA: 1 (mg/m3) from ACGIH
Consult local authorities for acceptable exposure limits.
Splash goggles
Synthetic apron
Vapor and dust respirator. Be sure to use an approved/certified
respirator or equivalent
Gloves
Crystals
Solid
White
Not available
7 [Neutral.]
52.8°C (127°F)
202°C (395.6°F)
CLOSED CUP: 103.33°C (218°F)
Not available
1.4%
7.1%
Not applicable
3.4 (Air = 1)
Not available
Soluble in cold water, hot water.
Very slightly soluble in methanol.
Not available
476.67°C (890°F)
Not available
Not available
3|5
Material name: Maleic Anhydride
Revision date: 10/1/2014
Operations Center
MK MONOMERS LLC
905 Brickell Bay Drive Miami, FL 33131
300 Rike Drive *
Millstone Twp., NJ,
08535
Magnakron.com
Info@magnakron.com
732-928-5800
Fax 609-448-4980
Specific Gravity
10. Stability and reactivity
Chemical stability
Possibility of hazardous
reactions
Conditions to avoid
Materials to avoid
Hazardous Decomposition
products
11. Toxicological Information
Routes of entry
Toxicity to Animals
Chronic Effects on Humans
Other Toxic Effects on Humans
Special remarks on chronic
effects on humans
Special Remarks on other
toxic effects on humans
1.48 (Water = 1)
The product is stable
May decompose on exposure to moist air or water
Not available
Reactive with oxidizing agents, reducing agents, acids, moisture.
Slightly reactive to reactive with metals, alkalis.
Not available
Dermal contact. Eye contact. Inhalation. Ingestion
Acute oral toxicity (LD50): 481 mg/kg [Rat.].
Acute dermal toxicity (LD50): 2620 mg/kg [Rabbit.].
The substance is toxic to lungs, mucous membranes.
Very hazardous in case of ingestion.
Hazardous in case of skin contact (irritant, permeator), of
inhalation.
Exposure will cause asthma, dermatitis and pulmonary oedema;
effects may be delayed. Tumorigen.
Sternutator
12. Ecological Information
Not available
13. Disposal Considerations
Disposal instructions
Contaminated packaging
Not available
Not available
14. Transport Information
DOT Classification
Identification
CLASS 8: Corrosive solid.
Maleic anhydride : UN2215 PG: III
15. Regulatory Information
US federal regulations
Pennsylvania RTK: Maleic anhydride
Massachusetts RTK: Maleic anhydride
TSCA 8(b) inventory: Maleic anhydride
SARA 313 toxic chemical notification and release reporting:
Maleic anhydride
CERCLA (Superfund) reportable quantity
Hazardous substances.: Maleic anhydride
Superfund Amendments and Reauthorization Act of 1986 (SARA)
Hazard categories
Not available
Section 302 extremely
Not available
hazardous substances
Section 311 hazardous
Not available
chemical
16. Other Information
Other regulations
OSHA: Hazardous by definition of Hazard Communication
Standard (29 CFR 1910.1200)
4|5
Material name: Maleic Anhydride
Revision date: 10/1/2014
Operations Center
MK MONOMERS LLC
905 Brickell Bay Drive Miami, FL 33131
300 Rike Drive *
Millstone Twp., NJ,
08535
Magnakron.com
Info@magnakron.com
732-928-5800
Fax 609-448-4980
WHMIS (Canada)
HMIS® ratings
CLASS D-1B: Material causing immediate and serious toxic
effects (TOXIC).
CLASS D-2A: Material causing other toxic effects (VERY
TOXIC).
CLASS E: Corrosive solid.
Health Hazard: 3
Fire Hazard: 1
Reactivity: 2
Personal Protection: j
3
NFPA ratings
Disclaimer
Issue date
J
2
Health: 3
Flammability: 1
Reactivity: 1
3
Protective equipment
1
1
1
Gloves.
Synthetic apron.
Vapor and dust respirator. Be sure to use an approved/certified
respirator or equivalent. Wear appropriate
respirator when ventilation is inadequate.
Splash goggles.
The information provided herein is for sole purpose of reference
only. Magnakron Corporation makes no warranty, express,
implied or otherwise, as to the product’s fitness for any particular
use or merchantability.
10/1/2014
5|5
Material name: Maleic Anhydride
Revision date: 10/1/2014