Establishing Equilibrium Objective: Students will establish a system at equilibrium. Materials: (2) 25 mL graduated cylinders, 2 straws w/different diameters, food coloring, safety glasses Procedure: 1) Label one graduated cylinder “reactants” and the other “products”. Label one straw “forward” and the other “reverse”. 2) Add a few drops of food coloring to the reactant cylinder. Then fill the cylinder with water to the 25.0 mL mark. 3) Place the forward straw into the reactant cylinder so that it touches the bottom. Place the reverse straw in the empty product cylinder. 4) Put your finger over the top of the forward straw so that the liquid is trapped in the straw. Transfer the colored water in the straw to the product cylinder. 5) Now put your finger over the reverse straw and transfer colored liquid from the product cylinder to the reactant cylinder. 6) Record the volume of each cylinder in the data table on the next page. Each time you transfer liquid from the reactant cylinder to the product cylinder and back from the product cylinder to the reactant cylinder constitutes one transfer. 7) Repeat steps 4, 5, and 6 until the volumes in the cylinders remain constant for at least 5 readings. 8) Repeat the entire experiment, but this time begin with 25.0 mL of colored water in the product cylinder and nothing in the reactant cylinder. Use the same straws for the forward and reverse reactions. ©2011 University of Illinois Board of Trustees • http://islcs.ncsa.illinois.edu/copyright Data Table Trial 1 Transfer 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 Reactant mL Product mL Trial 2 Transfer 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 Reactant mL Product mL Analysis and Conclusion 1) Did you use the large straw for the forward or reverse reaction? 2) At equilibrium, was there a greater volume of products or reactants? 3) What was the effect on equilibrium volumes when you started with no reactants and 25.0 mL of products? 4) Using Excel prepare a graph for that shows your results for both trials by plotting the transfer number on the x-axis and the volumes for both reactants and products on the y-axis. This lab is a modification from Prentice Hall’s Connections to Our Changing World. ©2011 University of Illinois Board of Trustees • http://islcs.ncsa.illinois.edu/copyright