Before you start Year 12 Chemistry Introduction Why study chemistry? What do Chemists do? Chemistry is a practical subject. It can lead to many different types of careers, or provide the background needed for other careers. What do chemists do? In most jobs a chemist would plan experiments use a range of equipment to analyse materials and samples devise new tests and experiments as new products are developed learn from what other chemists have done, and are doing What sort of jobs need chemistry training? Sources: http://www.chem.ubc.ca/undergraduate/brochure/wherechem.shtml http://www.ltu.edu/arts_sciences/chemistry/what_do_chemists_do.asp Many industries require people with all levels of chemical training, from technician to Ph.D. Here are some examples. Environmental chemist Determines what substances are present in an environmental sample and how they got there. Clinical chemist Works with medical personnel to analyse body tissues and fluids to provide medical doctors with useful diagnostic information. Quality control chemist Analyses raw materials and intermediates as products of an industrial process. This provides information about whether a batch meets specifications and what went wrong in the plant if that batch failed the tests. Chemical technician Develops practical processes for the large-scale manufacture of products, as well as improving the existing manufacturing processes. Technical salesperson Needs a good background in chemistry to sell chemical products to potential customers. Chemistry provides background knowledge for doctors, metallurgists, As background for other careers patent attorneys, and technical writers. Before you start Page 2 Is Year 12 Chemistry the right choice for you? Before going any further, do the pre-test. The chemistry pre-test To help you understand what is expected in Year 12 Chemistry, we would like you to do the pre-test on pages 7 to 9. Do the pre-test. (You can refer to chemistry notes and texts, but the test should not take more than about an hour). Time how long it takes. Correct your answers and work out your score. See what we recommend below. Fill in the questionnaire over the page, and send it in to your teacher. Your pre-test result… What we recommend … If your score was less than 20 40 If you got less than half the pre-test right you will most likely need a lot of time and support to make a success of Year 12 Chemistry. Past experience has shown that students scoring less than 20 out of 40 are not able to continue with this subject because they find it too difficult. We strongly recommend that you contact the Chemistry teachers to discuss your options. If you scored between 20 and 30 you will most likely need revision support throughout the year to develop the skills expected. This means making extra time available for your studies, and perhaps finding a tutor to help you. We suggest that you consider realistically whether you will be able to make the extra study time available. Contact the Chemistry teachers to discuss your options. If your score was between 30 40 and 40 40 If your score was between 20 30 and 40 40 If you scored between 30 and 40 you should be able to cope with most of the skills expected. However, you will also need to make regular study time a part of your weekly schedule. If you have any concerns, contact the DECV, and speak to the Chemistry teachers. It’s only fair to warn you… If you found the pre-test difficult and/or you have enrolled late you will probably find this subject very challenging. To have the best chance of making this year a success, you may wish to consider other options. The quickest way of finding out more is to ring the DECV, and speak to the Year 12 student manager. Phone: (03) 8480 0000, or toll free (in Victoria) 1800 133 511 Before you start SEND Page 3 Why study Year 12 Chemistry? Your name:____________________________________ Your student number:_________ Your pre-test 1. How did you go in the pre-test? My pre-test score was 2. How long did it take? The pre-test took me ……………… minutes 3. Which of the following best applies to you? 40 My pre-test score was good and I feel confident about studying Year 12 Chemistry I found the pre-test challenging but I wish to continue with Year 12 Chemistry. I realise that I will need to spend extra study time each week to revise the necessary skills. I found the pre-test difficult and I would like to discuss other options. My contact phone is………………………………………………………………………………………… The best time to call is…………………………………………………………………………………… The quickest way to find out more about your options is to ring the DECV, and speak to the Year 12 student manager. Phone: (03) 8480 0000, or toll free (in Victoria) 1800 133 511 Before you start SEND Page 4 Why study Year 12 Chemistry? A bit about you 1. I want to study Chemistry with the DECV because: ……………………………………………………………………………………………………………………………………………………… ……………………………………………………………………………………………………………………………………………………… 2. Have you studied chemistry before? Tick which best applies to you. I have studied Year 11 chemistry previously. I know a bit of chemistry from general science. I have never studied chemistry before. 3. Have you had a break from study? Tick which best applies to you. I am still at school. I am returning to study after a number of months. I am returning to study after a number of years. Something different to the above ……………………………………………………………………………………………………………………………………………………… 4. What it takes to succeed. About a third of the students who enrol in Distance Ed Chemistry drop out. To help you plan ahead it’s important that you realise what is expected before you start. There are three key questions you should ask yourself about your Chemistry studies. 1st. Time: Do you have approximately 6 hours each week, more when there is an assessment task due? Yes No 2nd. Can you schedule study periods for chemistry each week? Yes No 3rd. Lab experiments: Can you attend the DECV for lab work, or inquire locally for lab pracs (for example, at your own school or TAFE)? Yes No If you answered no to any of the above, your chances of success in this subject may be affected. Please contact your chemistry teacher at the DECV to discuss possible options. Phone: (03) 8480 0000, or toll free (in Victoria) 1800 133 511 Before you start Page 5 CHEMISTRY PRETEST UNITS 3 and 4 DATA PAGE Use the data tables below and the periodic table over the page to help you answer the pre-test questions. Table 1: Formulae and charge of selected ions: Cations Na sodium Anions + OH hydroxide + NH4 ammonium Cl chloride Ag+ silver NO3 nitrate Mg2+ magnesium O2 oxide Zn2+ zinc SO42 sulfate Cu2+ copper CO32 carbonate Pb2+ lead PO43 phosphate Table 2: Solubility of ions in water: Ions that are soluble in water Compounds with the following ions are always soluble in water Ammonium NH4+ Sodium Na+ Potassium K+ Nitrate NO3 Compounds with the following ions are mostly soluble in water Chloride Cl except with silver, Ag+, or lead, Pb2+ Sulfate SO42 except with silver, Ag+, or lead, Pb2+ Ions that are not soluble in water Compounds with the following ions are mostly not soluble in water Hydroxide OH Sulfide S2 Carbonate CO32 Phosphate PO43 except with Ammonium NH4+ Sodium Na+ Potassium K+ Table 3: Molar mass of selected elements: Element Molar mass (g per mol) H C O Ne Na Cl Pb 1.0 12.0 16.0 20.1 23.0 35.5 207.2 Table 4: Molar mass of gases STP standard temperature and pressure temperature 0°C, pressure 101.3 kPa One mol of any gas occupies 22.4 litres at STP SLC standard laboratory conditions temperature 25°C, pressure 101.3 kPa One mol of any gas occupies 24.5 litres at SLC Before you start Page 6 CHEMISTRY UNITS 3 and 4 PRETEST QUESTIONS 1. Use the Periodic Table given on the previous page to help you answer the following questions. (a) What is the atomic number of the following elements (i) silver (ii) radon (iii) radium ½ + ½ + ½ = 1½ marks (b) What is the chemical symbol of the following elements (i) gold (ii) silicon (iii) sodium (iv) antimony ½ + ½ + ½ + ½ = 2 marks (c) Identify the element with 13 protons and 13 neutrons. 1 mark 2. Butane, C4H10 is commonly used in LPG and lighter fluid. It’s melting and boiling points are shown below. melting point/ freezing (solidification) point boiling (evaporation) point/ condensation point 138 ºC 0.5 ºC Circle the physical state of butane at room temperature, 25 C solid liquid gas at fridge temperature, 4 C solid liquid gas at 5 C solid liquid gas ½ + ½ + ½ = 1½ marks Use the table of ions (Table 1) on the data page to help you answer questions 3 and 4. 3. Identify the ions present in the following ionic compounds and name the compound. (a) MgCl2 (b) Na3PO4 (c) Ag2S 3 marks 4. Work out the chemical formula of the following compounds. (a) Silver hydroxide (b) Magnesium carbonate (c) Zinc nitrate 3 marks 5. Balance the following chemical equations. (a) Mg(s) + N2(g) Mg3N2(s) (b) Ca(S) + O2(g) CaO(s) (c) H2(g) + O2(g) H2O(l) (d) Al (s) + I2 (l) Al2I6(s) 4 marks Before you start Page 7 Pre-test questions continued… 6. Use the solubility table (Table 2) on the data page to determine which of the following ionic compound are soluble. (a) lead sulfate (b) silver chloride (c) ammonium chloride (d) zinc carbonate ½ + ½ + ½ + ½ = 2 marks 7. The compound Cu(NO3)2 dissolves in water by dissociation of ions (a) Identify the ions in the compound. (b) Write the ionic equation of the dissociation reaction. Show the state of each compound or ion. 1 + 2 = 3 marks Refer to the molar mass of elements (Table 3) on the data page to help you answer questions 8, 9 and 10. 8. Find the molar mass of the following compounds (a) H2O (b) NaCl 2 marks 9. Find the mass of 1.3 mol of CH4 1 mark 10. Calculate the number of mol contained in the following samples, rounded to three decimal places. (a) 50 g of lead (b) 62 g of NaCl 2 marks Refer to the molar volume of gases (Table 4) on the data page to help you answer the following question. 11. (a) (b) Work out the volume of 1.4 mol of chlorine (Cl2) at STP Work out the mass of 2.8 L of neon (Ne) gas at SLC 1 + 1 = 2 marks The table below summarises the different types of acid reactions: Reactions of acids 1. acid + metal salt + hydrogen This reaction does not occur with Cu, Hg, or Ag. 2. acid + metal carbonate salt + water + carbon dioxide 3. acid + metal oxide salt + water 4. acid + metal hydroxide salt + water 2 Carbonates contain the CO3 ion The chemical formulae of selected compounds. HCl (aq) Na2CO3 (aq) NaCl (aq) H2O (l) CO2 (g) CuO (s) CuCl2 (aq) H2O (l) H2SO4 (aq) NaOH (aq) Na2SO4 (aq) Before you start Page 8 Pre-test questions continued… 12. Use the summary of acid reactions shown above to predict the products of the following reactions: (a) HCl (aq) + Mg (s) (b) HCl (aq) + Na2CO3 (aq) (c) HCl (aq) + CuO (s) (d) H2SO4 (aq) + NaOH (aq) 1 + 1 + 1 + 1 = 4 marks 13. Are the following reactions oxidation or reduction reactions? (a) Cl2(g) + 2e 2Cl (aq) (b) Pb (s) Pb2+ (aq) + 2e ½ + ½ = 1 mark 14. The reaction Zn(s) + S(s) ZnS (aq) can be written as two half reactions: Zn(s) Zn2+(aq) + 2e and S(s) + 2e S2 (aq) (a) Identify the oxidant in this redox reaction (d) Identify the reductant in this redox reaction ½ + ½ = 1 mark 15. Iron reacts with hydrochloric acid according to the ionic equation Fe(s) + 2H+(aq) Fe2+(aq) + H2(g) (a) What has been oxidised in this reaction? (b) Write a half equation for the oxidation reaction. (d) What has been reduced in this reaction? (e) Write a half equation for the reduction reaction. ½ + 1 + ½ + 1 = 3 marks 16. Hydrogen gas and oxygen gas react to form water according to the reaction 2H2 (g) + O2 (g) 2H2O (l) 10 g of oxygen is reacted in excess hydrogen. (a) How many mol of oxygen was reacted? (b) How many mole of hydrogen is required? (c) Work out the mass of hydrogen reacted. 1 + 1 + 1 = 3 marks END OF PRE-TEST