CE 3100 Electrically Conductive Adhesive For Solder Replacement With Superior Contact Resistance Key Feature Stable electrical conductivity Screen or stencil print Cures through solder reflow Lead free Benefit Reliable SMD assemblies on all traditional printed circuit board metal finishes Fine-pitch printing capability Compatible with existing SMT assembly lines No lead, lead reclamation, or flux residue cleaning required Product Description : CE 3100 is a one component, thermosetting, electrically conductive adhesive that is a lead-free alternative to solder for surface mount device (SMD) interconnect formation. CE 3100 will cure completely following a typical eutectic solder reflow cycle, with no postcure required. CE 3100 can run on existing SMT lines – no new equipment is needed. CE 3100 uses new, propriatary oxide-reducing technology to provide breakthrough electrical junction stability and reliability on all common metal solderable surface finishes. CE 3100 also provides fine-pitch capability using standard SMT solder-paste screen and stencil print equipment. This material’s lower surface tension versus solder means no bridging on fine-pitch assembly patterns. CE 3100 cures completely in a typical solder eutectic reflow cycle, with no postcure needed. As a result, CE 3100 is highly compatible with existing SMT assembly processes. This breakthrough product allows for an environmentally favourable and simplified SMT process by eliminating lead, lead reclamation, solder paste residues, flux residue cleaning, and high temperature reflow cycles. CE 3100 is intrinsically clean. This means no significant VOC’s, no residuals and high SIR. The low Coefficient of Thermal Expansion (CTE) of CE 3100 results in exceptional thermomechanical junction reliability versus solder. Applications : CE 3100 adhesive is capable of fine pitch resolution (500 µm) when printed using either a stainless steel mesh screen or a metal mask stencil. It is also syringe dispensable. This exceptionally stable adhesive may be used with thick film and all traditional printed circuit board metallisations. Instructions For Use : Thoroughly read the information concerning health and safety contained in this bulletin before using. Observe all precautionary statements that appear on the product label and/or contained in individual Material Safety Data Sheets (MSDS). . When CE 3100 is stored at low temperatures, it must be allowed to return to room temperature before use. Please refer to the “Cure Schedule” below. Technical Data Page 1 of 3 CE 3100 Page 2 of 3 Properties Of Uncured Material : Property Chemistry Appearance Brookfield Cone and Plate Viscosity Test Method Unit Visual 5 rpm # CP-51 Shear Thinning Pa.s NA Typical Value Epoxy Silver paste 30 – 75 2,5 Cure Schedule : CE 3100 may be cured in a reflow oven, with a typical reflow cycle or lower temperature modified cycle. Alternatively, it may also be cured in a convection oven. Because the CE 3100 solder alternative material cures completely during a typical reflow cycle, no postcure operation is required. Recommended Cure Condition Cure Condition Cure Option 1 Cure Option 2 Cure Temperature (°C) 150 130 150 Cure Time (min) Oven 3 6 10 Reflow Reflow Convection Properties Of Material After Application : Property Glass Transition Temperature (Tg) Coefficient Of Linear Thermal Expansion (CTE) Below Tg Above Tg Volume Resistivity At 25°C Modulus At 25°C At 150°C Extractable Ionic Content Chloride Sodium Potassium Tensile Lap Shear Strength Europe Nijverheidsstraat 7 B-2260 Westerlo Belgium % +(32)-(0) 14 57 56 11 Fax: +(32)-(0) 14 58 55 30 Test Method TMA (10°C / min) TMA (10°C / min) ASTM-D-257 DMA (3°C / min ; 1 Hz Frequency ; 40 µ Amplitude) TP-91 ASTM-D-1002 North America 46 Manning Road Billerica, MA 01821 % 800-832-4929 % (978) 436-9700 Fax: (978) 436-9701 Unit Typical Value °C 69 ppm ppm Ohm.cm 51 148 0,0001 GPa GPa 6,3 0,2 ppm ppm ppm MPa 79,0 <1 none detected 7 Asia-Pacific 100 Kaneda, Atsugi-shi Kanagawa-ken, 243-0807 Japan % (81) 462-258-880 Fax: (81) 462-221-347 NATIONAL STARCH MAKES NO REPRESENTATIONS OR WARRANTIES, EXPRESS OR IMPLIED, CONCERNING THE SUITABILITY OF THESE MATERIALS FOR USE IN IMPLANTATION IN THE HUMAN BODY, OR FOR ANY OTHER USE. These materials are not designed or manufactured for use in implantation in the human body. National Starch has not performed clinical testing of these materials for implantation. National Starch has neither sought, nor received, approval from the FDA for the use of these materials in implantation in the human body. No representative of ours has any authority to waive or change the foregoing provisions but, subject to such provisions, our engineers are available to assist purchasers in adapting our products to their needs and to the circumstances prevailing in their business. Nothing contained herein shall be construed to imply the non-existence of any relevant patents or to constitute a permission, inducement or recommendation to practice any invention covered by any patent, without authority from the owner of this patent. We also expect purchasers to use our products in accordance with the guiding principles of the Chemical Manufacturers Association’s Responsible Care program. © 2000 National Starch & Chemical Company CE 3100 Electrically Conductive Adhesive For Solder Replacement With Superior Contact Resistance Performance And Reliability Data : Property Contact Resistance On : Tin/Lead Initial And After 85% RH/85°C Contact Resistance On : OSP Coated Copper Initial And After 85% RH/85°C Contact Resistance On : Tin Test Method Unit Typical Value 6 Mil Print On Daisy Chain Pattern Without Resistors Ohm Initial : 0,1261 Chain average 0,0063 Individual pad % Change From Initial Reading Ohm @ 500 h : -5 @ 1000 h : 6 Initial : 0,0708 Chain average 0,0035 Individual pad % Change From Initial Reading Ohm @ 500 h : -11 @ 1000 h : -4 Initial : 1,0324 Chain average 0,0516 Individual pad % Change From Initial Reading @ 500 h : -64 @ 1000 h : -78 6 Mil Print On Daisy Chain Pattern Without Resistors 6 Mil Print On Daisy Chain Pattern Without Resistors Initial And After 85% RH/85°C Storage And Handling : The shelf life of CE 3100 is 12 months at –40°C or 6 months at –10°C. For best results, store in original, tightly covered containers. Storage in a cool, clean and dry area is recommended. Usable shelf life may vary depending on method of application and storage conditions. Storage Temperature (°C) -10 -40 Usable Shelf Life (months) 6 12 Health & Safety : Attention Specification Writers : It is recommended to consult the Emerson & Cuming product literature, including material safety data sheets, prior to using Emerson & Cuming products. These may be obtained from your local sales office. The technical information contained herein is consistent with the properties of this material but should not be used in the preparation of specifications, as it is intended for reference only. For assistance in preparing specifications, please contact your local Emerson & Cuming office for details. Please contact Emerson & Cuming Quality Assurance for test method details. (CE 3100 was formerly called AMICON CE 3100) (AMICON is a registered trademark of The Millipore Corporation) E08/06/2000-GL Technical Data Page 3 of 3