Chemical Bonding Part 1 Ionic Bonding Unit 4 (Ionic Compounds) Objectives: 1. 2. 3. 4. 5. 6. Using the octet rule, write the symbols for ions of the representative elements. Using the charge, write the correct formula for an ionic compound. Write the formula for a compound containing a polyatomic ion. Given the formula for an ionic compound, write its correct name. Describe the energy levels, sublevels, and orbitals in atoms. Write the arrangement of electrons for atoms using the sublevel blocks on the periodic table. 7. Given the name or symbol of an element, write the electron configuration. 8. Define solute and solvent; describe the formation of a solution. 9. Identify solutes as either electrolytes or non-electrolytes. 10. Define solubility; distinguish between an unsaturated and a saturated solution. 11. Identify an insoluble salt. Vocabulary: Ionic Bond, Ion, Polyatomic Ion, Metals, Nonmetals, Metalloids, Valence, Subscript, Transition Metals, Conductivity, Solubility, Precipitate, Electron Configuration, Orbital, Strong Electrolyte, Weak Electrolyte, Cation, Anion, Lone Pair, Formula 2 COMMON POLYATOMIC IONS Quiz #1 Quiz #2 - acetate C2H3O2 ______________________________________ perchlorate C1O4- chlorate C1O3- chlorite C1O2- CO32- bicarbonate HCO3(hydrogen carbonate) _________________________ permanganate MnO4- hypochlorite C1O_________________________ chromate CrO42dichromate carbonate Cr2O72- oxalate C2O42- cyanide CN- hydroxide OH- ammonium NH4+ Quiz #3 sulfate SO42- sulfite SO32- bisulfate HSO4(hydrogen sulfate) bisulfite HSO3(hydrogen sulfite) ________________________ nitrate NO3NO2____________________________________ nitrite phosphate PO43- 3 4 Crystal Lab PLW 1. Which chemicals do you need to be very careful of? 2. What will happen when you add the acid to the base? 3. How many times do you filter on day one? 4. What do you do with the contents of the filter paper? 5. Why should you be gentle with the alum crystals you form? 6. Ionic salts form crystal lattices at the atomic level. Draw an example of these. 5 6 Crystal Lattice Lab Purpose: The purpose of this lab is to create and examine various crystals. You will be creating alum [potassium aluminum sulfate KA1(SO4)2] and comparing the shape of those crystals to the shape of common table salt and sugar. Safety: YOU MUST WEAR GOGGLES THROUGHOUT THIS LAB!! H2SO4 and KOH are both very dangerous!! Day One-synthesis of alum crystals 1. Get a piece of the aluminum foil provided by your teacher. It should be about 1 gram. 2. Tear the foil into small pieces and put into a 250 mL beaker. 3. Slowly add 25 mL of 3 M KOH. Stir with a stir rod. At first no reaction will seem to take place but WATCH OUT!!!! After a few seconds, a vigorous reaction will proceed. Continue to stir until all of the foil has dissolved. 4. Filter the hot solution using a funnel and flask. Discard the contents of the funnel. 5. Slowly add 35 mL of 3 M H2SO4 to the flask. BE CAREFUL!!! You are adding a concentrated acid to a strong base. It will get HOT!!!!! 6. Filter the solution again and let sit overnight. Crystal will form after some time. Day Two-collection of the crystals 7. Discard the contents of the filter paper. 8. Collect the crystals from the flask by scraping them gently into another filter. 9. Pour 50 mL of a 50/50 alcohol/water mix over them. 10.Gently scrape them into a paper towel to dry them off. Discard the filter paper in the trash and pour all liquids down the drain with lots of water. 11. Examine them under a microscope. Analysis of crystals 12. Obtain some of the small alum crystals. If you don’t have small ones, borrow some from another group 13. Look at the alum crystals underneath the microscope. 14. Obtain some crystals of normal table sale, NaC1 and look at them under the scope. 15. Obtain some crystals of normal sugar, C12H22O11, and look at them under the scope. 7 Alum Lab Analysis AlumFormula: Draw the shape you see under the microscope Table SaltFormula: Draw the shape you see under the microscope SugarFormula: Draw the shape you see under the microscope Questions 1. Which of the above three crystals had repeating, simple shapes of various sizes? 2. Which of the above three crystals had no repeating simple shape? 3. Look at the formulas of the different atoms in the three crystals examined in this lab. Why does it make sense that one should be different? 8 332 CHEMISTRY TEGIF THE EXCITING GAME OF IONIC FORMULAS THE GAME: Use your puzzle pieces to build chemical formulas for Ionic compounds. Write correct formulas and names for the compounds. THE RULES FOR PLAY: 1. For the first round— Player 1 locates and plays the cation(s) Player 2 locates and plays the anion(s) Player 3 checks to be sure the proper number of each type of ion has been played Player 4 records the formula and name of the compound 2. For the second compound, player 1 becomes the recorder, player 2 does cations, player 3 does anions, and player 4 is the checker. 3. The roles continue to rotate for each new compound until all the assigned combinations of ions have formulas and names. THE RULES FOR FORMULAS AND NAMES: 1. The sum of all positive and negative charges in a formula must equal zero. (The total length of the positive puzzle piece side(s) must equal the total length of the negative puzzle piece side(s)). They must form a rectangle. 2. In formulas, positive ion (cations) is written first; negative ions are written second. (Positive puzzle pieces are placed on the left, negative puzzle pieces are placed on the right). 3. If more than one of an ion is needed in a formula, the number of that type of ion is shown as a subscript following the symbol of thee ion. 4. If a polyatomic ion needs a subscript, the formula for the ion must be placed inside parentheses. The subscript follows and is outside of the parentheses. (For example, the 2 nitrate ions in calcium nitrate are shown as Ca(NO3)2.] 5. In names of compounds, the name of the cation comes first; the name of the anion comes second. 6. Names of binary compounds usually end in ―--ide‖. Names of compounds containing three or more elements often end in --ate‖ or --ite‖, although there are some common exceptions like: NH4Br ammonium bromide A1(OH)3 aluminum hydroxide 9 CATION ANION Magnesium Mg2+ Aluminum Nitrate NO3Chloride Iron (II) Hydroxide Iron (II) Nitrate Sodium Sulfate Potassium Phosphate Ammonium Oxide Magnesium Sulfide Iron (II) Sulfate Iron (III) Sulfate Potassium Nitrate Aluminum Sulfate Ammonium Chloride Iron (II) Sulfide Magnesium Chloride Sodium Phosphate FORMULA OF COMPOUND Mg(NO3)2 NAME OF COMPOUND Magnesium Nitrate 10 Naming Ionic Compounds Rules An ionic compound is a compound that contains a cation and an anion. Cation: Anion: The cation is always written first. The cation will be a metal and the anion will be a nonmetal Metals are located on the ____________side of the periodic table. The nonmetals are located on the ____________side of the periodic table. An ionic compound is composed of a metal and a nonmetal. To write an ionic compound, perform the following steps in the order that they are presented. 1. Always write the cation the way it is presented on the periodic table. 2. Determine whether the anion is a polyatomic ion by referring to your polyatomic ion sheet. Polyatomic ion: Examples: 3. If the anion is not a polyatomic ion then write the name of the element from the periodic table and drop the ending, example: sulfur becomes sulf. Add the suffix an ―ide‖ to the anion, example: sulfide. 4. If the anion is a polyatomic ion then write the polyatomic ion as it appears on the reference sheet as your anion. 5. Look at the cation. If the cation is a transition metal then a roman numeral needs to be inserted. The Roman numeral refers to the charge, super script, that the cation has. 11 WRITING FORMULAS (CRISS-CROSS METHOD) Name ______________ Write the formulas of the compounds produced from the listed ions. CICO3-2 OHSO4-2 PO4-3 NO3Na+ NH4+ K+ Ca+2 Mg+2 Zn+2 Fe+3 AI+3 Co+3 Fe+2 H+ 12 Chemistry S-332 Name _________________ Ionic Compounds – Worksheet #1 Chemical formulas and names Elements Charge of each Formula Name 1. Ca, Br 2. Li, O 3. Ag, I 4. O, Ca 5. Zn, Cl 6. Cs, S 7. O, Al 8. Ba, N 9. P, Sr 10.S, Mg Name Charge of each Formula 1. Francium Fluoride 2. Rubidium Oxide 3. Magnesium Chloride 4. Silver Sulfide 5. Strontium Selenide 13 Chemistry S-332 Name _______________ Ionic Formulas – Worksheet # 2 (transition metals) Name Charge of each Formula Charge of each Name 1. Vanadium (III) Oxide 2. Nickel (II) Bromide 3. Copper (II) Oxide 4. Potassium Nitride 5. Sliver Chloride 6. Lead (IV) Sulfide 7. Gold (III) Bromide 8. Manganese (I) Nitride 9. Barium Fluoride 10.Magnesium Iodide Formula 1. Cu3N2 2. CoCl 3. Fe2O 4. Cs3N 5. CaS 14 Chemistry S-332 Name _______________ Ionic Formulas – Worksheet #3 (polyatomic ions) Name Charge of each Formula Charge of each Name 1. Magnesium Sulfate 2. Barium Chlorate 3. Sodium Nitrate 4. Copper (II) Phosphide 5. Iron (II) Oxide 6. Aluminum Chromate 7. Sliver Bisulfate 8. Sodium Bicarbonate 9. Calcium Carbonate 10. Iron (II) Nitride Formula 1. CuSO4 2. KMnO4 3. CsNO3 4. Mg(OH)2 5. HNO3 15 Chemistry S-332 Name _______________ Ionic Formulas – Worksheet #4 Formulas Charge Name NaBr MgO CuS FeCl VI4 NiF3 Ca3N2 Zn3P2 Al2S3 BaCl2 Name Charge Formula Copper (I) Sulfide Iron (III) Oxide Vanadium (VI) Phosphide Chromium (IV) Bromide Sliver Nitride Potassium Chloride Nickel (II) Phosphide Manganese (VI) Nitride 16 Name the following ionic compounds. 1. CuSO4 2. KC1 3. BaBr2 4. Na3PO4 5. Zn(OH)2 6. NaC1 7. LiBr 8. CaC12 9. A1PO4 10. KC2H3O2 11. NH4NO3 12. ZnC12 13. CaO 14. AgC1 15. CrBr3 16. FeSO4 17. FeC13 18. FeBr 17 18 Name ____________________ Solubility Lab PLW 1. How much of the solid are you to put into the test tube? Draw this. 2. How much water are you to put into the test tube? Draw this. 3. Why would it be important to shake the tube for at least 2 minutes? 4. How can you tell if a substance has dissolved in water? 5. What would be some evidence of a substance that has NOT dissolved in water? 6. Draw a picture of how an ionic crystal is arranged on the atomic level. 19 20 Name ______________________ Solubility Purpose: To investigate the solubility in water of several ionic substances in an effort to generate a set of ionic solubility rules. Safety: Goggles and Aprons must be worn. Procedure: 1. At your lab table should be test tubes and two different chemicals. 2. Using the scoopula, add a very small amount of the chemical to the test tube. You should use just enough to cover the bottom rounded portion of the tube. Using too much will give poor results. 3. Add water until the tube is about ¾ full. 4. Place a stopper on the tube and shake vigorously for at least 2 minutes. 5. Examine each tube and decide if the solid chemical was soluble and dissolved or was insoluble and did not dissolve. 6. Discard the contents of the tube down the drain with lots of water and clean out the tube. 7. Rotate around the room until all 14 chemicals have been tested. 8. Return to your original table and clean it up. 9. Using your results, try to come up with a generalized set of rules which govern ionic solubility. Tube Compound 1 Calcium Chloride 2 Sodium Phosphate 3 Aluminum Oxide 4 Aluminum Nitrate 5 Calcium Carbonate 6 Calcium Phosphate 7 Sodium Carbonate 8 Potassium Bromide 9 Cobalt Carbonate 10 Zinc Nitrate 11 Magnesium Oxide 12 Ammonium Sulfate 13 Copper (II)Carbonate 14 Potassium Chromate Formula Soluble? 21 Name _______________________ Date ______________ Per, _____ Solubility Lab Analysis 1. List all of the salts that were soluble. 2. What aspect do all of ions above have in common? 3. List all of the salts that were insoluble 4. What aspect do all of the ions above have in common? 5. Finish the following statement: An ionic salt will most likely be soluble in water and dissolve if… 22 Name ________________________ Conductivity Lab Purpose: To investigate the conductivity in water of several ionic substances. Safety: Goggles and Aprons must be worn. Procedure: 1. At your lab table should be 250 mL beakers and two different chemicals. 2. Add a medium scoop of one chemical to a 250 mL beaker. 3. Add about 200 mL of water to the beaker with the chemical 4. Using a clean stirring rod, stir the beaker vigorously for about a minute. 5. Dip the conductivity probes into the beaker and see if the light goes on. 6. Dump the contents of the beaker down the drain with lots of water and clean out the beaker. 7. Clean the probes with a beaker of clean water and dry them off. 8. Rotate around the room so that all 14 chemicals are tested. 9. Return to your original table and clean it up. Tube Compound 1 Calcium Chloride 2 Sodium Phosphate 3 Aluminum Oxide 4 Aluminum Nitrate 5 Calcium Carbonate 6 Calcium Phosphate 7 Sodium Carbonate 8 Potassium Bromide 9 Cobalt Carbonate 10 Zinc Nitrate 11 Magnesium Oxide 12 Ammonium Sulfate 13 Copper (II)Carbonate 14 Potassium Chromate Formula Conducts? 23 Name ________________________ Conductivity Lab Analysis 1. When an ionic substance dissolves in water, what happens to the crystal structure of the ions? 2. Compare the results of this lab to the results of the solubility lab. What trend do you notice? 3. Explain the results of this lab in terms of ionic bonding and solubility in water. Why do the results seen in the lab make sense? Why does it make sense that the ones that conducted electricity did so? 24 PLW Precipitate Lab 1. What is an aqueous solution? 2. 3. What ions are in an aqueous solution of sodium chloride? 4. Draw a picture of the ions present in each aqueous solution CaCl2(aq) K2SO4(aq) 5. What is a precipitate and how does it form? 6. Write the formula for the following compounds: a) sodium carbonate_________________ b) sodium chloride__________________ c) copper (II) nitrate_________________ d) sodium phosphate_________________ e) zinc nitrate______________________ f) magnesium nitrate_________________ 7. Step H of the lab asks you to observe if a precipitate will form in the spot plate. What are some observations that will indicate that a precipitate has formed? 8. A set of students conducted an experiment very similar to your Precipitate Lab. Several aqueous solutions were combined to test for a precipitate. The data table below shows the results of each test. . Aqueous Solutions Li2SO4 Fe(ClO3)2 Cu2CrO4 Al(NO3)3 Na2CO3 BaI2 White ppt NR White ppt NR Red ppt NR Geen ppt NR Blue ppt a. Which two ionic compounds form a red precipitate when combined together? b. When Na2CO3 is combined with Cu2CrO4, what is the result? c. What happens when the solution BaI2 is combined with the solution Li2SO4 ? 25 26 Precipitates Lab Purpose: In this lab you will be using the solubility rules to predict whether combinations of solutions will form precipitates. Background: Write the formulas for each of the following chemicals. a) sodium carbonate ______________________ b) sodium chloride ______________________ c) copper (II) nitrate ______________________ d) sodium phosphate ______________________ e) zinc nitrate ______________________ f) magnesium nitrate ______________________ Procedure: a) Obtain and CLEAN six test tubes and one spot plate. Be sure to rinse each with a little DI water. b) Mark each test tube with one of the above chemicals names. c) Pour enough of each solution into the proper test tube so that the tube is about ¼ full. d) Examine the grid on the next page. e) You will notice that the top and left side row and column are left blank. Fill the chemical formulas above into the top row and the left column. (Put them into correct order, a-f) f) For each blank space on the chart, find the two chemicals which intersect there. g) Combine 4-5 drops of each chemical in a well of a spot plate. h) Observe if a precipitate forms or not. If a precipitate is formed, write PPT. If no reaction occurs, write NR. i) Dispose of the excess chemicals. Spot plates should be filtered and excess solutions in test tubes should be rinsed down the sink one at a time with lots of water. 27 Precipitates Lab (Continued) Data: Write the names of the chemicals at the top and along the left. If a precipitate forms, write PPT. If no reaction occurs, write NR. a b X X X X X X X X X X X d d e f Ionic Formulas a b c d e f X X X X X X X X X X Analysis: Based on the above data, can you determine the rules which govern the formations of precipitates? Think back to the solubility rules for ionic compounds. Conclusion: Write out a situation which summarizes the rules on the formation of precipitates. 28 Name _______________________ Precipitates prediction worksheet Use the following data to determine whether a ppt will form. Indicate the formula of the ppt. 1. Calcium Nitrate 2. Sodium Phosphate 4. Lithium Chromate 5. Iron (lll) Nitrate Ions to be mixed 2 1 2 3 4 5 1 x x x x x 3 x x x x 3. Sodium Carbonate 4 x x x 5 x x x 29 30 Name __________________________ Date _______________ Per. ________ Chemical Bonding Unit Review 1. Identify each as an element or a compound: Ca H2 O CH4 H2SO4 CaCO3 N2 Fe NaC1 2. What charge will each element have as an ion? Nitrogen ________________ Lithium _____________ Barium ________________ Fluorine ____________ 3. How many valence electrons does each of the following elements have? Hydrogen ________________ Calcium ____________ Neon ________________ Sulfur ____________ 4. Which elements are chemically stable and why are they inert (non-reactive)? 5. For each of the species listed below, list the number of protons, neutrons, and electrons in each atom or ion. 23 Na+1 p : _____ no: _____ e-: _____ + 79 Br p : _____ no: _____ e-: _____ + 35 C1-1 p : _____ no: _____ e-: _____ + 84 Kr p : _____ no: _____ e-: _____ + 6. Complete the statement by circling the correct words: Ionic bonds form due to charge attractions from the (sharing of electrons /transfer of electrons) between a (metal and a non-metal /2 non-metals /2 metals). 7. Write the names of the following ionic compounds: Fe2O3 ____________________ Ca3(PO4)2 ___________________________ NH4NO3 ______________________________ Pb12 __________________ 31 Name ________________________ Date _____________ Per. _______ 8. It is noticed that neither solid calcium chloride nor calcium oxide will conduct electricity. However when calcium chloride is added to water, the resulting solution conducts electricity. Calcium oxide, though, continues to be non-conductive even when added to water. Explain this phenomenon. 9. Circle which of the following ionic solids will dissolve in water. Na3PO4 CaCO3 K2SO4 A1(NO2)3 10. Circle which of the following ionic solids will conduct electricity in water. A12(Cr2O7)2 LiC1 BaSO4 Pb(NO3)2 11. Below are listed chemical formulae for groups of two solutions. Circle which groupings would form a precipitate. For each grouping, write the formula of the precipitate formed (if any) and list any ions that are still left in the solution. A NaC1 Cu(NO3)2 B Ba(OH)2 Li2SO4 C K2CO3 FeBr3 D A1(NO3)3 K2CrO4 PPT ___________ ____________ _____________ ____________ IONS LEFT__________ ____________ _____________ ____________ 12. Rank the following ionic solids in order of expected increasing melting points: A1PO4 NaC1 MgF2 CaO Mg3(PO4)2 13. Below are listed some lattice energies for various ionic compounds: BeO 1200 CaO 500 SrO 300 Predict the lattice energy for magnesium oxide:________________________ What difference in the formulae of the crystals above could account for the changes in lattice energy? 14. Define ion: 32 Camp Electron To: Potential summer camp employees of Camp Electron From: Miss Daisy, Head Camp Director Concerning: Assignment of campers to cabins and bunks. What is Camp Electron? Camp Electron is a place for electrons, much like yourselves, to come in for the summer and experience arts and crafts, swimming, nature hikes, horseback riding, and to learn wilderness survival skills. When is Camp Electron? Camp Electron takes place each week through out the summer for electrons only. Yes, we understand there are protons and neutrons out there too, but it seems that these electrons are so tiny that they feel neglected. They often seem to go unnoticed in comparison to the giant protons and neutrons. Where is Camp Electron? Camp Electron is located in the woods north of Oshkosh, Wisconsin. It is near Peshtigo, Wisconsin. It was built back in 1968. Why are you receiving this information? Normally, Camp Electron retires many of its previous workers, but it seems to be in a crunch for this upcoming summer. We’re in need of camp employees. This memo is to explain to you the paper work that is needed at Camp Electron in the event that you may be interested in applying for a job. It is necessary for you to have knowledge on how to assign electrons to their-cabins and their bunks. Applications will be available at the end of class. 33 Please observe the following camp rules and regulations. A short explanation of the camp layout is provided. 1. Each cabin at Camp Electron is numbered and lettered: 1s, 2s, 2p, 3s and so on. 2. The circles following the cabin designations represent the bunks in each cabin. 3. Two campers (electrons) may sleep in each bunk. 4. We had a mudslide a few years back and moved some of the cabins from the original locations. Due to our limited budget (and somewhat lazy maintenance staff) the cabin numbers have not been changed. Please don’t let this upset you. Just assigned the campers (electrons) to their bunks using the following rules. a. Each new camper (electron) is assigned to the lowest cabin on the hill in the lowest level that still has bunk space available. The lowest cabin is the one that is closest to the bottom of the map. Again, we know the cabin numbers are messed up. Cabin 3d is really higher than cabin 4s. Cabin 4d really is higher than cabin 5s and so. A cabin is full when all of its bunks (circles) contain two campers (electrons). b. Please remember-NO MORE THAN TWO CAMPERS IN A BUNK. We don’t want to crowd them too much. c. Don’t assign two campers (electrons) to the same bunk in a cabin until all of the bunks in that cabin contain one camper. Look at the 3d, for example. Each bunk (circle) must be assigned one camper before you start pairing campers up. Don’t crowd the campers before you have to. We hope that you will consider a potential job as a camp counselor this upcoming summer. Since the landslide we’ve been having trouble keeping camp counselors for more than one summer. The cabin numbering system 34 seems to be the main problem, but we’re sure that you can handle the job based on your teacher’s recommendations. Good luck and we hope to see you this summer! Electron summer Camp Cabins and Bunks 7p O O O 6d OOOOO 5f OOOOOOO 7s O ___________________ _____________________________________________________________Level 7____ 6p O O O OOOOO 5d 4f OOOOOOO 6s O______________________ _____________________________________________________________Level 6___ 5p O O O 4d OOOOO 5s O _______ _____________________________________________________________Level 5____ 4p O O O 3d OOOOO 4s O_______ _____________________________________________________________Level 4____ 3p O O O 3s O __ _____________________________________________________________Level 3____ 2p O O O 2s O ___ _____________________________________________________________Level 2____ 1s O_________________________________________________________ Level 1____ 35 36 Camp Electron Weekly Bunk Assignment Summer 2010 To test your ability to assign campers (electrons) to their appropriate bunks within the camp, below you will find the numbers for the first 14 weeks of this past summer. With a partner, practice assigning campers (electrons) to the bunks within the cabins and then share your results with the class. Remember, each camper (electron) is assigned to the lowest cabin on the hill in the lowest level bunk available. No one is assigned the top bunk until all the bottom bunks are filled and no more campers (electrons) to a bunk. Week # 1 # of Campers N-7 Bunk Assignment Head Office notation 1s2 2s2 2p3 1s 2s 2 P-15 3 F-9 4 Cu-29 5 Mg-12 6 C-6 7 K-19 8 Fe-26 9 O-8 2p 37 10 Cl-17 11 Ne-10 12 Ca-20 13 Al-13 14 Zn-30 38 Electron Configuration What elements correspond to each of the following electron configurations? 1. 1s2 2s2 2p4 2. 1s2 2s2 3. 1s2 2s2 2p6 3s2 3p3 4. 1s2 2s2 2p6 3s2 3p6 4s2 3d5 5. 1s2 2s2 2p6 3s2 3p6 4s1 6. 1s2 2s2 2p6 3s2 3p6 4s2 3d10 4p6 5s2 4d3 7. 1s2 2s2 2p6 3s2 3p6 4s2 3d10 4p65s2 4d10 5p6 6s2 8. 1s2 2s2 2p6 3s2 3p6 4s2 3d10 4p4 Write the electron configuration found in each of the following atoms. 1. oxygen 11. aluminum 2. chlorine 12. chromium 3. titanium 13. scandium 4. beryllium 14. phosphorous 5. cobalt 15. zinc 6. calcium 16. bromine 7. strontium 17. potassium 8. nickel 18. vanadium 9. silicon 19. gallium 10. rubidium 20. selenium 39 Electron Configuration Practice 1. Sn 2. Ge+2 3. Te+2 4. Te-2 5, Which is more stable # 3 or # 4? Why? 6. Ne 7. Mg+2 8. Mg-2 9. Co+ 10. Co11. Mo+3 12. Mo+ 13. Mo 14. Cs 15. Er 16. Hg 17. At+ 18. At19. Which is more stable #17 or # 18? 20. What element has a +2 charge and has configuration of 1s22s22p3? 21. What element has a -2 charge and has configuration of 1s2s22p3? 22. What element has a -3 charge and has configuration of [Kr] 5s24d7? 23. Os-3 24. U 40 Electron Configuration Battleship® The idea for adapting the Battleship® game to Chemistry comes from Justin Field of Oregon at ChemEd ’01; Battleship® are games by the MiltonBradley Company. First some practice so you can hope to WIN! Element Configuration Ti 1s22s22p63s23p64s23d2 Short Cut Configuration [Ar] 4s23d2 Valence Electrons 4s23d2 Be 1s22s22p63s23p64s1 5s24d105p4 Ce 3s23p6 1s22s22p63s23p64s2 3d104p65s24d105p6 6s24f145d106p67s25f7 [Kr] 5d24d4 41 Game Rules: 1. You will work with a partner to play Battleship®. The goal is to determine where your partner’s ships are on their periodic table. 2. First you need to privately ―hide‖ your six ships on the periodic table by highlighting them with a marker. The ship sizes are: a. TWO ships are three spaces b. TWO ships are four spaces c. TWO ships are five spaces The ships may be placed on the periodic table horizontally (along a period) of vertically (along a family). 3. Fold the periodic table and place in a standing textbook for privacy. 4. You and your partner will take turns guessing the ―coordinates‖ of the hidden ―ships‖. You will guess by……… a. First, Student A may guess 3s23p4. You may state either full configuration, short cut configuration or valence electrons. It is best to use different configurations each time to practice all different types. b. Student B will confirm the element saying, Sulfur. After confirmation Student B will say ―HIT‖ (If they hit your battleship) or ―MISS‖. c. Both students must keep track of all guesses in the following table. 5. The game ends when all of one players ships are sunk or after time is called. 42 Electron Configuration Battleship® Player Guess Example: [Ne] 3s23p4 Reply Sulfur Hit Miss X A 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 18 20 B 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 43 Ionic Bonding Notes 44 Ionic Bonding Notes 45