SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006
perform® select H2O2
Version
02.03
Revision Date:
04.01.2016
No Change Service!
Date of last issue: 26.02.2015
Date of first issue: 29.04.2009
SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1 Product identifier
Trade name
: perform® select H2O2
1.2 Relevant identified uses of the substance or mixture and uses advised against
Use of the Sub: Disinfectants and general biocidal products
stance/Mixture
Recommended restrictions
on use
: Restricted to professional users.
1.3 Details of the supplier of the safety data sheet
Producer
: BIOXAL SA - AIR LIQUIDE Group
Route des Varennes - BP 72
71103 Chalon-sur-Saône Cedex
France
Telephone: + 33 (0) 3 85 92 30 00
Telefax: + 33 (0) 3 85 92 30 12
Supplier
: Schülke & Mayr GmbH
Robert-Koch-Str. 2
22851 Norderstedt
Germany
Telephone: +49 (0)40/ 52100-0
Telefax: +49 (0)40/ 52100318
mail@schuelke.com
www.schuelke.com
E-mail address of person
responsible for the
SDS/Contact person
: Application Department HI
+49 (0)40/ 521 00 544
ADHI@schuelke.com
(Schülke & Mayr UK Ltd.: +44-1142543500)
1.4 Emergency telephone number
Emergency telephone num: UK Poisons Emergency number: 0870 600 6266
ber
SECTION 2: Hazards identification
2.1 Classification of the substance or mixture
Classification (REGULATION (EC) No 1272/2008)
Acute toxicity, Category 4
H302: Harmful if swallowed.
Acute toxicity, Category 4
H332: Harmful if inhaled.
Serious eye damage, Category 1
H318: Causes serious eye damage.
2.2 Label elements
Labelling (REGULATION (EC) No 1272/2008)
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SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006
perform® select H2O2
Version
02.03
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Date of last issue: 26.02.2015
Date of first issue: 29.04.2009
Revision Date:
04.01.2016
Hazard pictograms
:
Signal word
:
Danger
Hazard statements
:
H302 + H332
H318
Precautionary statements
:
P220
Further information
: Use biocides safely. Always read the label and product information before use.
Harmful if swallowed or if inhaled
Causes serious eye damage.
Keep/Store away from clothing/ combustible
materials.
P261
Avoid breathing vapours.
P280
Wear protective gloves (e.g. butyl rubber)
/eye protection/face protection.
P301+P312+P330 IF SWALLOWED: Call a POISON
CENTER/doctor if you feel unwell. Rinse
mouth.
P304+P340
IF INHALED: Remove person to fresh air
and keep comfortable for breathing.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for
several minutes. Remove contact lenses, if
present and easy to do. Continue rinsing.
2.3 Other hazards
This substance is not considered to be persistent, bioaccumulating and toxic (PBT).
No special risks known.
SECTION 3: Composition/information on ingredients
3.1 Substances
Hazardous components
Chemical name
Hydrogen peroxide
Index-Number
CAS-No.
EC-No.
Registration number
008-003-00-9
7722-84-1
231-765-0
01-2119485845-22XXXX
Classification
Ox. Liq. 1; H271
Acute Tox. 4; H302
Acute Tox. 4; H332
Skin Corr. 1A; H314
Aquatic Chronic 3;
H412
For explanation of abbreviations see section 16.
SECTION 4: First aid measures
4.1 Description of first aid measures
General advice
: Take off all contaminated clothing immediately.
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Concentration
(% w/w)
30
SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006
perform® select H2O2
Version
02.03
Revision Date:
04.01.2016
If inhaled
In case of skin contact
In case of eye contact
If swallowed
No Change Service!
Date of last issue: 26.02.2015
Date of first issue: 29.04.2009
: Move the victim to fresh air and keep him calm. If breathing is
difficult, give oxygen. Call a physician immediately.
: Wash off immediately with plenty of water for at least 15
minutes. If symptoms persist, call a physician.
: Rinse immediately with plenty of water, also under the eyelids,
for at least 15 minutes. Call a physician immediately. Continue
rinsing eyes during transport to hospital.
: Do NOT induce vomiting. Rinse mouth with water. Immediately give large quantities of water to drink. Call a physician immediately.
4.2 Most important symptoms and effects, both acute and delayed
Symptoms
: Treat symptomatically.,
4.3 Indication of any immediate medical attention and special treatment needed
Treatment
: For specialist advice physicians should contact the Poisons
Information Service.
SECTION 5: Firefighting measures
5.1 Extinguishing media
Suitable extinguishing media
Unsuitable extinguishing
media
: Water spray jet, Foam, Dry powder, Carbon dioxide (CO2)
: High volume water jet
5.2 Special hazards arising from the substance or mixture
Specific hazards during fire: The product itself does not burn, but it is oxidising., Cool
fighting
closed containers exposed to fire with water spray.
Specific risk from the substance or the product itself,
its combustion products or
evolved gases
5.3 Advice for firefighters
Special protective equipment
for firefighters
: Fire may cause evolution of:, Oxygen, Contact with combustible material may cause fire., Risk of explosion if heated under confinement.
: In the event of fire, wear self-contained breathing apparatus.
Use personal protective equipment.
SECTION 6: Accidental release measures
6.1 Personal precautions, protective equipment and emergency procedures
Personal precautions
: Ensure adequate ventilation. Remove all sources of ignition.
6.2 Environmental precautions
Environmental precautions
: Avoid subsoil penetration. Do not flush into surface water or
sanitary sewer system.
6.3 Methods and material for containment and cleaning up
Methods for cleaning up
: Wipe up with absorbent material (e.g. cloth, fleece).
Unsuitable material for picking up:
Absorbent material, organic
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SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006
perform® select H2O2
Version
02.03
No Change Service!
Date of last issue: 26.02.2015
Date of first issue: 29.04.2009
Revision Date:
04.01.2016
Sawdust
Clean contaminated surface thoroughly.
Flush with water.
6.4 Reference to other sections
see Section 8 + 13
SECTION 7: Handling and storage
7.1 Precautions for safe handling
Advice on safe handling
: Provide sufficient air exchange and/or exhaust in work rooms.
Never return unused material to storage receptacle.
Advice on protection against
: Keep away from sources of ignition - No smoking. Keep away
fire and explosion
from combustible material. May cause or intensify fire; oxidizer.
Hygiene measures
: When using do not eat or drink. Take off all contaminated
clothing immediately. Wash hands before breaks and at the
end of workday.
7.2 Conditions for safe storage, including any incompatibilities
Requirements for storage
: Keep only in the original container. Suitable container and
areas and containers
packaging materials for safe storage Polyethylene PVC Stainless steel Aluminium Teflon (R) Unsuitable materials for containers Metals Iron Copper Store in a receptacle equipped
with a vent. Keep in a bunded area.
Further information on stor: Keep away from heat. Keep away from direct sunlight. Store
age conditions
in cool place. Do not keep the container sealed. Store in upright position only. Recommended storage temperature: 5 30°C
Advice on common storage
: Do not store together with combustible substances.Keep away
from solvents.Do not store together with metals.Keep away
from oxidizing agents, strongly alkaline and strongly acid materials in order to avoid exothermic reactions.
7.3 Specific end use(s)
Specific use(s)
: The product falls under the regulation on biocide products
(EU) 528/2012.
Product type: 2
Product type: 3
Product type: 4
SECTION 8: Exposure controls/personal protection
8.1 Control parameters
Occupational Exposure Limits
Components
CAS-No.
Hydrogen peroxide
7722-84-1
Value type (Form
of exposure)
WEL
WEL
Control parameters
Basis
1 ppm
1,4 mg/m3
2 ppm
2,8 mg/m3
HSE
Derived No Effect Level (DNEL) according to Regulation (EC) No. 1907/2006:
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HSE
SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006
perform® select H2O2
Version
02.03
No Change Service!
Date of last issue: 26.02.2015
Date of first issue: 29.04.2009
Revision Date:
04.01.2016
Substance name
End Use
Exposure routes
Potential health effects
Value
Hydrogen peroxide
Workers
Inhalation
Local effects, Shortterm exposure
3 mg/m3
Workers
Inhalation
Local effects, Longterm exposure
1,4 mg/m3
Consumers
Inhalation
Local effects, Shortterm exposure
1,93 mg/m3
Consumers
Inhalation
Local effects, Longterm exposure
0,21 mg/m3
Predicted No Effect Concentration (PNEC) according to Regulation (EC) No. 1907/2006:
Substance name
Environmental Compartment
Value
Hydrogen peroxide
Fresh water
0,0126 mg/l
Marine water
0,0126 mg/l
Water
0,0138 mg/l
Effects on waste water treatment plants
4,66 mg/l
8.2 Exposure controls
Engineering measures
Ensure that eyewash stations and safety showers are close to the workstation location.
Personal protective equipment
Eye protection
: Safety glasses with side-shields conforming to EN166
Hand protection
Directive
: The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and the standard EN 374
derived from it.
Remarks
: Prolonged contact: Nitrile rubber gloves e.g. Camatril (>120
Min., layer thickness: 0,40 mm) or butyl rubber gloves e.g.
Butoject (>480 Min., layer thickness: 0,70 mm) made by KCL
or gloves from other manufacturers offering the same protection. Splash protection: disposable nitrile rubber gloves e.g.
Dermatril (layer thickness: 0,11 mm) made by KCL or gloves
from other manufacturers offering the same protection.
Skin and body protection
: Choose body protection according to the amount and concentration of the dangerous substance at the work place.
Wear as appropriate:
Chemical resistant apron
Boots
Respiratory protection
: If the occupational exposure limits cannot be met, in exceptional cases suitable respiratory equipment should be worn
only for a short period of time.
Recommended Filter type:
B:
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SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006
perform® select H2O2
Version
02.03
Revision Date:
04.01.2016
No Change Service!
Date of last issue: 26.02.2015
Date of first issue: 29.04.2009
Inorganic substances in vapour or gaseous form
Suitable mask with particle filter P3 (European Norm 143)
Protective measures
: Avoid contact with skin and eyes.
SECTION 9: Physical and chemical properties
9.1 Information on basic physical and chemical properties
Appearance
: liquid
Colour
: colourless
Odour
: odourless
Odour Threshold
: not determined
pH
: 2 - 4, 20 °C, concentrate
Melting point/freezing point
: -0,4 °C
Decomposition temperature
: No data available
Boiling point/boiling range
: ca. 150 °C
Flash point
: > 60 °C
Other information: The product itself does not burn, but it is
oxidising.
Evaporation rate
: not determined
Flammability (solid, gas)
: Not applicable
Upper explosion limit
: Not applicable
Lower explosion limit
: Not applicable
Vapour pressure
: 23 hPa, ca. 20 °C
Relative vapour density
: not determined
Density
: ca. 1,11 g/cm3, 20 °C
Solubility(ies)
Water solubility
: completely soluble
Partition coefficient: n: No data available
octanol/water
Viscosity
Viscosity, dynamic
: ca. 12,6 mPa*s, 20 °C, Brookfield
Explosive properties
: not determined
Oxidizing properties
: not determined
9.2 Other information
No data available
SECTION 10: Stability and reactivity
10.1 Reactivity
No dangerous reaction known under conditions of normal use.
10.2 Chemical stability
Stable under normal conditions.
10.3 Possibility of hazardous reactions
To avoid thermal decomposition, do not overheat.Decomposes on exposure to light.
10.4 Conditions to avoid
Extremes of temperature and direct sunlight.
10.5 Incompatible materials
Strong acids and strong bases, Reducing agents, Oxidizing agents, Metals, Combustible material,
Acetone
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SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006
perform® select H2O2
Version
02.03
Revision Date:
04.01.2016
No Change Service!
Date of last issue: 26.02.2015
Date of first issue: 29.04.2009
10.6 Hazardous decomposition products
Oxygen
SECTION 11: Toxicological information
11.1 Information on toxicological effects
Acute toxicity
Acute oral toxicity
Acute inhalation toxicity
Acute dermal toxicity
: LD50 (Rat): 1193 - 1270 mg/kg, IUCLID, Regulation (EC) No
1272/2008 on classification, labelling and packaging of substances and mixtures, Annex VI, Table 3.1
: LC0 (Rat): 16,1 mg/l, 4 h, IUCLID, Regulation (EC) No
1272/2008 on classification, labelling and packaging of substances and mixtures, Annex VI, Table 3.1
: LD50 (Rat): 6500 mg/kg
Skin corrosion/irritation
According to the classification criteria of the European Union, the product is not considered as
being a skin irritant.
Serious eye damage/eye irritation
Regulation (EC) No 1272/2008 on classification, labelling and packaging of substances and mixtures, Annex VI, Table 3.1, Causes serious eye damage.
Respiratory or skin sensitisation
Did not cause sensitisation on laboratory animals.Guinea pig
Germ cell mutagenicity
Genotoxicity in vitro
Genotoxicity in vivo
Germ cell mutagenicity- Assessment
: Ames test, negative
: in vivo assay, not mutagenic
: Not mutagenic in Ames Test
Carcinogenicity
Carcinogenicity - Assessment
: Animal testing did not show any carcinogenic effects.
Reproductive toxicity
Reproductive toxicity - Assessment
: Animal testing did not show any effects on fertility.
STOT - single exposure
No data available
STOT - repeated exposure
No data available
Repeated dose toxicity
Rat, NOAEL: 26 mg/kg, Oral, 3 months, No adverse effect has been observed in chronic toxicity
tests.
Rat, NOAEL: 0,0029 mg/l, inhalation (vapour), OECD Test Guideline 407
Aspiration toxicity
No data available
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SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006
perform® select H2O2
Version
02.03
Revision Date:
04.01.2016
No Change Service!
Date of last issue: 26.02.2015
Date of first issue: 29.04.2009
SECTION 12: Ecological information
12.1 Toxicity
Toxicity to fish
Toxicity to daphnia and other
aquatic invertebrates
Toxicity to algae
: LC50 (Pimephales promelas (fathead minnow)): 16,4 mg/l, 96
h, IUCLID
: EC50 (Daphnia magna (Water flea)): 7,7 mg/l, 24 h, IUCLID
: IC50 (Chlorella vulgaris (Fresh water algae)): 2,5 mg/l, 72 h,
IUCLID
12.2 Persistence and degradability
Biodegradability
: Totally biodegradable, OECD Test Guideline 301
12.3 Bioaccumulative potential
Bioaccumulation
: Does not bioaccumulate.
12.4 Mobility in soil
Mobility
: Water Hydrolyses readily.
12.5 Results of PBT and vPvB assessment
Assessment
: This substance is not considered to be persistent, bioaccumulating and toxic (PBT).
12.6 Other adverse effects
Additional ecological information
: none
SECTION 13: Disposal considerations
13.1 Waste treatment methods
Product
Contaminated packaging
Waste key for the unused
product
Waste key for the unused
product(Group)
: Dispose of the product according to the defined EWC (European Waste Code) No. Dispose of as hazardous waste in
compliance with local and national regulations.
: Take empty packaging to the recycling plant.
: EWC 160903
: peroxides, e.g. hydrogen peroxide
SECTION 14: Transport information
14.1 UN number
ADR
: UN 2014
IMDG
: UN 2014
IATA
: UN 2014
14.2 UN proper shipping name
ADR
: HYDROGEN PEROXIDE, AQUEOUS SOLUTION
IMDG
: HYDROGEN PEROXIDE, AQUEOUS SOLUTION
IATA
: Hydrogen peroxide, aqueous solution
14.3 Transport hazard class(es)
ADR
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: 5.1 (8, 11)
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SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006
perform® select H2O2
Version
02.03
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Date of last issue: 26.02.2015
Date of first issue: 29.04.2009
Revision Date:
04.01.2016
IMDG
: 5.1 (8, 11)
IATA
: 5.1 (8, 11)
14.4 Packing group
ADR
Packing group
Classification Code
Hazard Identification Number
Labels
Tunnel restriction code
:
:
:
:
:
IMDG
Packing group
Labels
EmS Code
: II
: 5.1 (8, 11)
: F-H, S-Q
IATA
Packing instruction (cargo
aircraft)
Packing group
Labels
II
OC1
58
5.1 (8, 11)
E
: 554
: II
: Oxidizer, Corrosive, above
14.5 Environmental hazards
ADR
Environmentally hazardous
: no
IMDG
Marine pollutant
: no
14.6 Special precautions for user
For personal protection see section 8.
14.7 Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable for product as supplied.
SECTION 15: Regulatory information
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
Legislation on the control of
: Directive 96/82/EC does not apply
major-accident hazards involving dangerous substances
Volatile organic compounds
: none, Directive 2010/75/EC on the limitation of emissions of
volatile organic compounds
Other regulations
: Take note of Directive 98/24/EC on the protection of the
health and safety of workers from the risks related to chemical
agents at work.Take note of Directive 2000/39/EC establishing
a first list of indicative occupational exposure limit values.Regulation (EU) No 528/2012 of the European Parliament
and of the Council of 22 May 2012 concerning the making
available on the market and use of biocidal products
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SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006
perform® select H2O2
Version
02.03
No Change Service!
Date of last issue: 26.02.2015
Date of first issue: 29.04.2009
Revision Date:
04.01.2016
15.2 Chemical safety assessment
A Chemical Safety Assessment is not required for this substance.
SECTION 16: Other information
Full text of H-Statements
H271
H302
H314
H332
H412
:
:
:
:
:
Full text of other abbreviations
Acute Tox.
:
Aquatic Chronic
:
Ox. Liq.
:
Skin Corr.
:
May cause fire or explosion; strong oxidizer.
Harmful if swallowed.
Causes severe skin burns and eye damage.
Harmful if inhaled.
Harmful to aquatic life with long lasting effects.
Acute toxicity
Chronic aquatic toxicity
Oxidizing liquids
Skin corrosion
ADN - European Agreement concerning the International Carriage of Dangerous Goods by Inland
Waterways; ADR - European Agreement concerning the International Carriage of Dangerous
Goods by Road; AICS - Australian Inventory of Chemical Substances; ASTM - American Society
for the Testing of Materials; bw - Body weight; CLP - Classification Labelling Packaging Regulation; Regulation (EC) No 1272/2008; CMR - Carcinogen, Mutagen or Reproductive Toxicant; DIN
- Standard of the German Institute for Standardisation; DSL - Domestic Substances List (Canada); ECHA - European Chemicals Agency; EC-Number - European Community number; ECx Concentration associated with x% response; ELx - Loading rate associated with x% response;
EmS - Emergency Schedule; ENCS - Existing and New Chemical Substances (Japan); ErCx Concentration associated with x% growth rate response; GHS - Globally Harmonized System;
GLP - Good Laboratory Practice; IARC - International Agency for Research on Cancer; IATA - International Air Transport Association; IBC - International Code for the Construction and Equipment of Ships carrying Dangerous Chemicals in Bulk; IC50 - Half maximal inhibitory concentration; ICAO - International Civil Aviation Organization; IECSC - Inventory of Existing Chemical
Substances in China; IMDG - International Maritime Dangerous Goods; IMO - International Maritime Organization; ISHL - Industrial Safety and Health Law (Japan); ISO - International Organisation for Standardization; KECI - Korea Existing Chemicals Inventory; LC50 - Lethal Concentration
to 50 % of a test population; LD50 - Lethal Dose to 50% of a test population (Median Lethal
Dose); MARPOL - International Convention for the Prevention of Pollution from Ships; n.o.s. - Not
Otherwise Specified; NO(A)EC - No Observed (Adverse) Effect Concentration; NO(A)EL - No
Observed (Adverse) Effect Level; NOELR - No Observable Effect Loading Rate; NZIoC - New
Zealand Inventory of Chemicals; OECD - Organization for Economic Co-operation and Development; OPPTS - Office of Chemical Safety and Pollution Prevention; PBT - Persistent, Bioaccumulative and Toxic substance; PICCS - Philippines Inventory of Chemicals and Chemical Substances; (Q)SAR - (Quantitative) Structure Activity Relationship; REACH - Regulation (EC) No
1907/2006 of the European Parliament and of the Council concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals; RID - Regulations concerning the International
Carriage of Dangerous Goods by Rail; SADT - Self-Accelerating Decomposition Temperature;
SDS - Safety Data Sheet; TCSI - Taiwan Chemical Substance Inventory; TRGS - Technical Rule
for Hazardous Substances; TSCA - Toxic Substances Control Act (United States); UN - United
Nations; vPvB - Very Persistent and Very Bioaccumulative
Further information
Changes compared with the previous edition!!!
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SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006
perform® select H2O2
Version
02.03
Revision Date:
04.01.2016
No Change Service!
Date of last issue: 26.02.2015
Date of first issue: 29.04.2009
The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not
to be considered a warranty or quality specification. The information relates only to the specific
material designated and may not be valid for such material used in combination with any other
materials or in any process, unless specified in the text.
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