Name Period Date Practice: Predicting Relative Properties Use your periodic table and references to determine these answers. DON’T look up actual numbers, but predict the largest or smallest based on an elements position in the periodic table. The primary reference to use is The Periodic Table: Electron Shells Affect Trends. 1. For each set of atoms tell which atom has the biggest atomic radius: Largest? Lithium Calcium Krypton Polonium 2. Carbon Beryllium Zinc Sulfur Nitrogen Radium Calcium Oxygen Fluorine Magnesium Bromine Tellurium ➜ ➜ ➜ ➜ Li Ra Ca Po For each set of atoms tell which atom has the highest electronegativity Highest EN? Chlorine Boron Nitrogen Lithium Sulfur Indium Oxygen Calcium Aluminum Aluminum Fluorine Francium Magnesium Gallium Calcium Silicon ➜ ➜ ➜ ➜ Cl B F Si 3. For each set of atoms tell which atom has the lowest ionization energy Lowest IE? Nitrogen Iodine Lithium Aluminum Fluorine Bromine Beryllium Silicon Oxygen Fluorine Boron Phosphorus Carbon Chlorine Carbon Sulfur ➜ ➜ ➜ ➜ C I Li Al 4. Which would be larger the ionic radius or the atomic radius? a. Calcium’s Atomic Radius or its Ionic Radius? Calcium’s atomic radius would be larger because it loses an entire shell when it makes a +2 ion b. Fluorine’s Atomic Radius or its Ionic Radius Fluorine’s ion is larger because it has gained an electron and stuffed into an existing shell to make F–1 c. Bromine’s Atomic Radius or its Ionic Radius The ion is larger (it has gained an electron) to make Br–1 d. Potassium’s Atomic Radius or its Ionic Radius The K atom is larger because it has a whole extra shell vs. its ion which has lost the outer shell. Practice: Explaining Trends 3 10/6/14 5. For the following pairs of atoms determine which is larger, draw a picture, and explain why: a. Carbon or Oxygen Carbon is larger; it has fewer protons than oxygen for the same number of shells. The extra protons of oxygen are able to pull the same number of shells closer in. b. Magnesium or Calcium Calcium is larger. It has one more outer layer of electrons than Magnesium. a column, added shells win out over the extra protons to make the size relatively larger. Going down c. Lithium or Bromine Not a very good question because there are two competing trends. Lithium ends up being larger because it pulls very weakly on its few electrons, but bromine has many more shells so its too hard for me to ask this one on a quiz. 6. For each pair of atoms determine which can steal an electron easier (higher electronegativity), draw a picture, and explain why: a. Oxygen and Fluorine Fluorine steals better because its outer shell has been pulled in toward the protons into a closer area. It’s easier for F’s protons to “get at” passing electrons. b. Sodium and Potassium Sodium is smaller, so its easier for it to steal an electron than K. Neither atom does this much, though, because they generally lose electrons. c. Boron and Calcium Boron has more protons per/shell and it has fewer shells. Both of these features work together to make it more likely to grab an electron vs. Ca. 7. For each pair of atoms determine which can lose an electron easier (lower ionization energy), draw a picture, and explain why: a. Hydrogen and Helium Hydrogen can lose its lone electron easier. It has one less proton than Helium, for the same number of shells so it pulls a less effectively. Again, the atom with fewer protons/shell within a period holds its electrons with less pull. b. Boron and Aluminum Aluminum can lose its electrons easier from the outer shell because it has MORE Shells. This factor causes those valence electrons to be much farther out and easier to lose. 8. Which is bigger the ion or the atom (be sure to draw a picture and explain why). a. Sodium atom or ion The sodium ATOM is larger. It has one more shell than a sodium ion b. Chlorine atom or ion The chlorine ION is larger. It has one more electron in the same number of shells so those electrons are able to roam out a little farther. Practice: Explaining Trends 4 10/6/14