Primary funding is provided by The SPE Foundation through member donations and a contribution from Offshore Europe The Society is grateful to those companies that allow their professionals to serve as lecturers Additional support provided by AIME The linked image cannot be displayed. The file may have been moved, renamed, or deleted. Verify that the link points to the correct file and location. Society of Petroleum Engineers Distinguished Lecturer Program www.spe.org/dl 1 LNG Basics for Petroleum Engineers Michael Choi 2 Present an Overview of LNG Plant • • • • • • Oman LNG Plant • • • Why LNG? Typical Multi-Trains Plant Pre-Treatment Required Unique Auxiliary Facilities Natural Gas Liquefaction Thermodynamics Commercial Liquefaction Processes Equipment for Liquefaction Novel Plant Concepts Concluding Remarks 3 Stranded Gas Looking for Markets • LNG Proved to be Most Economic for Distances >1,500 Mile • Transported in Insulated Tankers @ -162C & 1 atm. • Volume Reduction of 600:1 Supply Demand 4 LNG Process & Equipment ? Big Refrigeration System • • • Compressor/Driver Refrigerant Condenser Evaporator (Process Heat Exchanger) Similar to the AC System in Our Home! 5 Typical 2-Train LNG Plant MakeUp Fuel Gas Gathering Train 1 Gas Inlet Gas Reception 1.7 Bcfd Fuel Inlet Gas Treating NGL Recovery Liquefaction LNG Storage LNG Liquid Train 2 Condensate Stabilization 9 Mtpa (1.2 Bcfd) NGL Fractionation Propane Storage Propane Butane Storage Butane Condensate Storage .73 Mtpa (27 Mbpd) .5 Mtpa (17 Mbpd) Condensate 1.2 Mtpa (34 Mbpd) 6 Typical 2-Train LNG Plant MakeUp Fuel Gas Gathering Train 1 Inlet Gas Reception 1.7 Bcfd Fuel Gas Inlet Gas Treating NGL Recovery Liquefaction LNG Storage LNG Liquid Inlet Gas Reception NGL Recovery Inlet Gas Treating • Pipeline Manifold • forScrub Column/KO • Amine CO NGLafter C3 Pre-Cool 2& Train 2 H2S Removal NGL Fractionation Fractionation • Pig Receivers • Primarily C4+ to Prevent Freezing • <50 ppm & < 4 ppm • Deethanizer • Inlet Separator • LNG Heat Value for US & • Compression Sulfur Recovery Unit ifImportant H2S • Vapor Condensate European Markets • Slug Catcher • Mol Sieve Dehydration* • DepropanizerStabilization & Treating • 1,070 btu/scf Max • < 100 ppb • 95% & 200 psig VP Condensate Stabilization • Need Turbo-Expander for High • Mercury Vapor Removal* • <.5ppm H S & <15ppm S • Multi-Stage Column 2 C3+ Removal • Activated Carbon Adsorber • Debutanizer &Compressor Treating • Vapor • 95% & 70psia psigRVP VP @100F • 10-12 • <.5ppm H2S & <15ppm S • De-Odorized 9 Mtpa (1.2 Bcfd) Propane Storage Propane Butane Storage Butane Condensate Storage .73 Mtpa (27 Mbpd) .5 Mtpa (17 Mbpd) Condensate 1.2 Mtpa (34 Mbpd) 7 180,000 M3 LNG Tank • Full-Containment Tank to Reduce Impound Area & Improve Safety • Approx. 75M Dia x 40M H • Insulated for <.05%/D of Boil-off • Total Capacity Based on Tanker Size (135,000 M3) • Plus 4+-Days Production • Top Entry In-Tank Pumps 8 Inside the Tanks Single-Stage Multi-Stage Tank with Pump Caissons 9 LNG Loading System • • • • 16 Chiksan Type 3+1 – LNG Arms • 3,500 M3/Hr/Ea. • 10,500 M3/Hr • 140K M3 Tanker 4+1 – Systems • 14,000 M3/Hr • Qmax & Qflex • 200K+ M3 1 – Vapor Return 10 Cost of Refrigeration Methane or Nitrogen Cost/Btu Removed Ethylene -162C Propane Temperature Air/Water 25C 11 Natural Gas Liquefaction Processes 25C Gas Cooling Condensation Temperature Min. DT Liquid Sub-cooling -162C ΔH (Enthalpy - Heat Removed) 12 Cascade LNG Process Most Straight Forward of All Processes Kenai Plant Continuous Operation 1969 CoP License, Plant Build by Bechtel 80F Propane Refrig. 1st Stage Temperature • • • CoP Optimized Cascade Refrigerant Cycle 2nd Stage 3th Stage 1st Stage Ethylene Refrig 2nd Stage 1st Stage -260F Methane Refrig. 2nd Stage . 3th Stage ΔH (Enthalpy - Heat Removed) Kenai, Alaska 13 C3 Precooled – Mixed Refrigerant Process Most Widely Used Licensed by APCI 1st Plant in Algeria Operating Since 1972 Plants Built by KBR, Chiyoda, JGC, FW 80F Propane Refrig. 1st Stage Temperature • • • Propane PreCooled Mixed Refrigerant Cycle 2nd Stage 3th Stage Mixed Refrigerant -260F ΔH (Enthalpy - Heat Removed) QatarGas LNG Plant 14 APCI AP-X Process • • • • Largest Train Capacity @ 8 Mtpa Overcome Spiral Wound MCHE Limit First Unit Started in 2009 (QG-II) No Plants Outside of Qatar APCI Supplies • • • • Process Design Cold Boxes Spiral Wound Exchanger Turbo-Expanders 15 All Processes Use Similar Equipment • • • • • GE MS7001 FB Gas Turbine Most New Plants Use Large Gas Turbine (& Combined Cycle) to Drive Refrigerant Compressors Some Older & Smaller Trains Have Steam Turbine Drives Many Peak Shaving Plants on Electric Drives Use Large Process Type Centrifugal Compressors Main Difference is in the Cryogenic Heat Exchangers 16 Main Cryogenic Heat Exchanger Use by Mixed Refrigerant Process Air Products & Chemicals & Linde: Spiral Wound Ex. • Max. Diameter: 5,030mm • Height: ~55m • Stainless Steel Core • 25mm Aluminum Tubing • Externally Insulated • Chill & Liquefy Gas – From –34ºC to –152ºC – At 55 to 69 Barg 17 APCI s MR Main Cryogenic Heat Exchanger (MCHE) Spiral Wound Design 18 Heat Exchanger for Cascade Process Plate Fin Exchanger Cold Box Configuration • Many Manufacturers • Use Extensively in Air Separation • Cascade & Other LNG Processes 19 Advances in LNG Plants Onshore Conventional Design Near-shore GBS Design Offshore Steel or Concrete Floater 20 Conclusions • LNG Liquefaction Process Same as AC System in Our Home • Pre-Treatment Facilities Can Dwarf Liquefaction System – Mole Sieve Dehydration & Mercury Removal Required – Gas Treating & NGL Extraction May be Needed – Stabilized Condensate & Fractionated NGL Add Value • LNG Exchangers, Storage & Loading Systems Are Unique • Commercial Liquefaction Processes Well Proven, Robust & Can be Optimized for Plant Size, Gas Composition, Sales & Commercial Needs • Novel Near-Shore & Offshore Floating Concepts Are Developed 21 LNG ? 22 Your Feedback is Important Enter your section in the DL Evaluation Contest by completing the evaluation form for this presentation : Click on: Section Evaluation Society of Petroleum Engineers Distinguished Lecturer Program www.spe.org/dl 23 http://research.spe.org/se.ashx?s=705E3F13128DC9C5