Earth’s Clock Absolute Age • Absolute / numerical / chronological age = age measured in years • How to measure time? !Constant process o Ex: Earth’s rotation !A record of the process o Ex: marking days on wall Natural Clocks Tree rings Growth lines Annual layers Nature’s Clock • Radioactivity > age of rocks !Constant rate !Radioactive elements in rocks • Clocks in rocks • Different: ! Elements ! Rocks ! Times Review of Atoms Proton (+) <- Nucleus -> Neutron (no charge) Electron (-) Protium <- 2 isotopes of hydrogen -> Deuterium Isotopes: atoms with = # of protons, !"# of neutrons Isotopes • Uranium ! 238U: 92 protons + 146 neutrons ! 235U: 92 protons + 143 neutrons • Both are unstable: ! Will break apart • Stable isotopes don’t change Radioactive Decay • Def: spontaneous change in nucleus of unstable isotope • General reaction: ! Unstable isotope => Stable isotope + energy ! Parent isotope => Daughter isotope + energy Radioactive Decay (cont.) • Example: ! 238U => 206Pb ! 238U decays to lead ! Loses 10 protons, 22 neutrons Rate of Radioactive Decay • Half-life: time it takes for 50% of parent atoms to decay to daughter atoms ! Measurable o Amount of energy released ! Unchanged by: o Composition o Temperature o Pressure A Representative Calculation • New mineral: ! Contains a radioactive isotope ! Contains no daughter products ! Half-life = 30 yrs • Note: mineral could form by crystallization, metamorphism, or precipitation Halflife Time, years # Parent Atoms # Daughter Atoms 0 0 100%1024 1 30 50% 512 50% 512 2 60 25% 256 75% 768 3 90 12.5% 128 87.5% 896 4 120 6.25% 64 91.75% 960 5 150 3.12% 32 94.86% 992 6 180 1.56% 16 95.42%1008 0% 0 Graphing Radioactive Decay 100 Growth of daughter % of atoms 75 50 Decay of parent 25 0 0 1 2 3 4 Half-lives 5 6 Very Long Half-Lives Parent => Daughter Half-life Minerals 238U => 206Pb 4.5 b.y. zircon 87Rb => 87Sr 48.8 b.y. feldspar => 143Nd 106 b.y. mica 147Sm Shorter Half-Lives Parent => Daughter Half-life 40K 238U 14C Minerals => 40Ar 1.3 b.y. feldspar => 206Pb 700 m.y. zircon => 14N 5,730 y. organic material Which Rocks Give Useful Ages? • Date mineral grains • Good ages if minerals & rock formed at the same time ! Mineral must start with: o Only parent o No daughter Dating Rocks • Igneous rocks ! Very good • Sedimentary rocks - No good! ! Clastic rocks o Dates grain, not when it was deposited, etc. ! Chemical rocks o No radioactive elements Dating Rocks (cont.) • Metamorphic rocks ! Sometimes • Not all rocks datable ! Igneous rocks are best. Combinations • Absolute ages of igneous rocks • Relative ages of others • Estimate age of undatable rocks Volcanic ash, 25 m.y. Lava flow, 40 m.y. Sandstone between 25 & 40 m.y. The Geologic Time Scale Age of Earth = 4.6 b.y. Evolution of Life Humans 2 m.y. Age of Mammals EXTINCTION First birds 65 m.y. Age of Dinosaurs EXTINCTION 245 m.y. Large swamps Amphibians Land plants Fish Trilobites FIRST SHELLS 545 Precambrian (88%) Earliest life Oldest rocks m.y. 3.0 b.y. 4.4 b.y.