SAFETY DATA SHEET
Click-Solution (DMSO/t-BuOH)
(50-1002-11)
MSDS COVER SHEET
Product Name: Click-Solution
Catalog Number: 50-1002-11
Product Description: DMSO/t-BuOH (3:1)
Glen Research Corporation provides Material Safety Data Sheets (MSDS) based on the hazardous components of each product.
Components and MSDS attached
DMSO
t-BuOH
CAS number 67-68-5
CAS number 75-65-0
MSDS: 50-1002-11, Printing date 06/28/2012
Glen Research Corporation • 22825 Davis Drive, Sterling, VA 20164 • 1-800-327-4536 • 1-800-934-2490 (Fax) • www.glenres.com
Safety Data Sheet
Page 2
Click-Solution (DMSO/t-BuOH)
(50-1002-11)
Material Safety Data Sheet
Narne: Dimethyl sulfoxide; DMSO
Chemical Family: Sulfoxide
Formula: C6H6OS
M.W.: 78.13 g/mol
CAS No.: 67-68-5
Hazardous description: This substance is not classified as dangerous according to Directive 67/548/EEC.
ADRIRID: Not a dangerous goods.
IMDG: Not a dangerous goods.
lATA: Not a dangerous goods.
Section II: Physical Properties
Appearance: Colorless liquid
Vapor Pressure 0.55 hPa at 20°C
Percent Volatile by Volume: n/a
Evaporation Rate (BuAc =1): n/a
Boiling Point: 189°C at 1.013 hPa
Melting point: 18.4°C
Odor: n/a
Vapor Density: n/a
Specific Gravity (H20=1): n/a
Stability: Stable under recommended storage conditions.
Solubility in H20: completely miscible
Water Reactive: n/a
Section III: Reactivity Hazard Data
Storage stability: Stable under recommended storage conditions.
Dangerous reactions: Avoid strong oxidizing agents, strong reducing agents, Phosphorus halides, Acid chlorides.
Dangerous decomposition: Hazardous decomposition products formed under fire conditions. - Carbon oxides, Sulphur Oxides.
Section IV: Fire and Explosion Hazard Data
Means of extinguishing: Use material suitable and appropriate to surrounding fire conditions.
Suitable extinguishing media: Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.
Specie! protective equipment for firefighters: Wear self contained breathing apparatus for fire fighting if necessary.
Section V: Hazardous Ingredients
DMSO
ca 100%
MSDS: 50-1002-11, Printing date 06/28/2012
Glen Research Corporation • 22825 Davis Drive, Sterling, VA 20164 • 1-800-327-4536 • 1-800-934-2490 (Fax) • www.glenres.com
Safety Data Sheet
Page 3
Click-Solution (DMSO/t-BuOH)
(50-1002-11)
Section VI: Toxicity and Health Hazard Data
Potential Health Effects
Inhalation: May be harmful if inhaled. May cause respiratory tract irritation.
Skin: May be harmful if absorbed through skin. May cause skin irritation.
Eyes: May cause eye irritation.
Ingestion: May be harmful if swallowed.
Target Organs: Eyes, Skin,
Additional Information RTECS: PV6210000
Emergency First Aid:
Ingestion: Call poison control center for assistance. Get emergency medical assistance. If conscious, and alert, rinse mouth with water.
Never induce vomiting or give anything by mouth to a victim who is unconscious or having convulsions.
Eye contact: Rinse with copious amounts of water for at least 15 minutes. Get emergency medical assistance.
Skin contact: Flush thoroughly with water for at least 15 minutes. Wash affected skin with soap and water. Remove contaminated
clothes and shoes. Wash clothing before reuse. Get emergency medical assistance.
Inhalation: Immediately remove to fresh air. If not breathing, give artificial respiration. Keep patient warm and at rest. Get emergency
medical assistance.
Section VII: Special Protection
Ventilation: Adequate ventilation is required to control vapors and odor.
Respiratory protection: Respiratory protection is not required. Where protection is desired, use multi-purpose combination (US) or
type ABEK (EN 14387) respirator cartridges. Use respirators and components tested and approved under appropriate government
standards such as NIOSH (US) or CEN (EU).
Hand protection: For prolonged or repeated contact use protective gloves.
Skin Protection: Protective rubber gloves and clothing are recommended. The choice of material must be based on chemical
resistance and other user requirements.
Eye Protection: Laboratory safety glasses are minimum protection. Goggles are preferred. Emergency eye wash fountains and safety
showers should be available in the vicinity of any potential exposure. Ground and bond metal containers to minimize sparks.
Section VIII: Spill and Disposal Procedures
Wear protective clothing and use approved respiration equipment. If a spill occurs, protect from ignition. Use water spray to dilute spill to
a non-flammable mixture. Ventilate area of spill. Absorb spilled material in an absorbent recommended for solvent spills and scoop with
a nons parking tool. Remove waste to a safe location for disposal by approved methods. If released to the environment, comply with all
regulatory notification requirements.
Environmental precautions: Do not let product enter drains.
Waste Disposal: Methods for cleaning up: Keep in suitable, closed containers for disposal.
Section IX: Handling and Storage
Handling: Keep away from sources of ignition - No smoking. Take measures to prevent the build up of electrostatic charge.
Storage: Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store under inert gas. hygroscopic
Section X: Other Information
For all other inquiries about this product contact Glen Research at 1-800-327-GLEN or 1-703-437-6191.
The information provided herein is based on sources believed to be reliable as of June 28, 2012 and pertains only to the material
designated. Glen Research Corporation makes no warranty or representation to its completeness, accuracy or currency. This material
is intended for use by persons with the pertinent technical skills and at their discretion and risk. It is the responsibility of the user to
determine the product's suitability for its intended use, the product's safe use and the product's proper disposal. Disposal of hazardous
material may be subject to federal, state or local regulations.
MSDS: 50-1002-11, Printing date 06/28/2012
Glen Research Corporation • 22825 Davis Drive, Sterling, VA 20164 • 1-800-327-4536 • 1-800-934-2490 (Fax) • www.glenres.com
Safety Data Sheet
Click-Solution (DMSO/t-BuOH)
(50-1002-11)
Material Safety Data Sheet
Narne: tert-Butanol; t-BuOH
Synonyms: 2-Methyl-2- propanol; tert-Butyi-alcohol.
Chemical Family: Butanol
Formula: C4H10O
M.W.: : 74.12 g/mol
CAS No.: 75-65-0
Hazardous description: Highly flammable. Harmful by inhalation.
Information concerning particular hazards for human and environment: F; Xn
Classification system: RTECS: E01925000A
ADRIRID
UN-Number: 1120. Class: 3. Packing group: II
Proper shipping name: BUTANOLS
IMDG
UN-Number: 1120. Class: 3. Packing group: II. EMS-No: F-E, S-D
Proper shipping name: BUTANOLS
Marine pollutant: No
lATA
UN-Number: 1120. Class: 3. Packing group: II Proper shipping name: Butanols
Section II: Physical Properties
Appearance: Colorless liquid
Vapor Pressure: 41 hPa at 20°C; 59 hPa at 26°C
Percent Volatile by Volume: n/a
Evaporation Rate (BuAc =1): n/a
Boiling Point: 83 °C
Melting point:: 23 - 26°C
Odor: n/a
Vapor Density: n/a
Specific Gravity (H20=1): n/a
Stability: Stable under recommended storage conditions.
Solubility in H20: completely miscible
Water Reactive: n/a
Section III: Reactivity Hazard Data
Storage stability: stable under recommended storage conditions.
Condition to be avoided: Heat, flames and sparks.
Dangerous reactions: Avoid strong oxidizing agents, Copper, Alkali metals, Aluminum.
Dangerous decomposition: Hazardous decomposition products formed under fire conditions: Carbon Oxides, Peroxides.
Section IV: Fire and Explosion Hazard Data
Fire and explosion hazards: Flash back possible over considerable distance.
Flash Point: 11°C - closed cup.
Means of extinguishing: Use material suitable and appropriate to surrounding fire conditions. Extinguishing media: For small
(incipient) fires, use media such as "alcohol" foam, dry chemical, or carbon dioxide.
For large fires, apply water from as far as possible. Use very large quantities (flooding) of water applied as a mist or spray; solid
streams of water may be ineffective. Cool all affected containers with flooding quantities of water.
MSDS: 50-1002-11, Printing date 06/28/2012
Glen Research Corporation • 22825 Davis Drive, Sterling, VA 20164 • 1-800-327-4536 • 1-800-934-2490 (Fax) • www.glenres.com
Page 4
Safety Data Sheet
Page 5
Click-Solution (DMSO/t-BuOH)
(50-1002-11)
Fire fighting procedures: Wear self contained breathing apparatus for fire fighting if necessary.
Further information: In case of fire: Evacuate area. Fight fire remotely due to the risk of explosion. Use water spray to cool unopened
containers.
Section V: Hazardous Ingredients
t-BuOH, ca 100%
Section VI: Toxicity and Health Hazard Data
Potential Health Effects
Inhalation: May be harmful if inhaled. May cause respiratory tract irritation.
Skin: May be harmful if absorbed through skin. May cause skin irritation.
Signs and Symptoms of Exposure: drying, cracking of the skin, skin irritation.
Eyes: May cause eye irritation.
Ingestion: May be harmful if swallowed.
Target: Organs Central Nervous System, Kidney, Liver, Bladder, Thyroid.
Additional Information: RTECS: E01925000
Emergency First Aid:
Ingestion: Call poison control center for assistance. Get emergency medical assistance. If conscious, and alert, rinse mouth with
water. Never induce vomiting or give anything by mouth to a victim who is unconscious or having convulsions.
Eye contact: Rinse with copious amounts of water for at least 15 minutes. Get emergency medical assistance.
Skin contact: Flush thoroughly with water for at least 15 minutes. Wash affected skin with soap and water. Remove contaminated
clothes and shoes. Wash clothing before reuse. Get emergency medical assistance.
Inhalation: Immediately remove to fresh air. If not breathing, give artificial respiration. Keep patient warm and at rest. Get emergency
medical assistance.
Section VII: Special Protection
Personal protective equipment: The usual precautionary measures are to be adhered to when handling chemicals. Choose body
protection according to the amount and concentration of the dangerous substance at the work place.
Respiratory protection: Where risk assessment shows air-purifying respirators are appropriate use a full-face respirator with
multipurpose combination (US) or type ABEK (EN 14387) respirator cartridges as a backup to engineering controls. If the respirator is
the sole means of protection, use a full-face
Supplied air respirator. Use respirators and components tested and approved under appropriate government standards such as NIOSH
(US) or CEN (EU).
Protection of hands: The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and the standard
EN 374 derived from it. Handle with gloves.
Eye protection: Laboratory safety glasses
Hygiene measures: Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end
of workday.
Section VIII: Spill and Disposal Procedures
Avoid all direct contact.
Respiratory protection: Use personal protective equipment. Avoid breathing vapors, mist or gas. Ensure adequate ventilation.
Remove all sources of ignition. Evacuate personnel to safe areas. Beware of vapors accumulating to form explosive concentrations.
Vapors can accumulate in low areas (EU).
Protective gloves: Impermeable
Eye protection: Laboratory safety glasses Other protective equipment: Normal laboratory apparel
Measures for environmental protection: Prevent further leakage or spillage if safe to do so. Do not let product enter drains.
Measures for cleaning/collection if a spill occurs: Contain spillage, and then collect with non-combustible absorbent material, (e.g.
sand, earth, diatomaceous earth, vermiculite) and place in container for disposal according to local/national regulations.
.
MSDS: 50-1002-11, Printing date 06/28/2012
Glen Research Corporation • 22825 Davis Drive, Sterling, VA 20164 • 1-800-327-4536 • 1-800-934-2490 (Fax) • www.glenres.com