The Presence of Water on Mars Amy Duggan and Giuliani Lopez Abstract The presence of water has made Mars a key area of focus. Current observations and climate predictions have lead to the theory that liquid water may have once existed. The observations made by the Mars Exploration Rovers include discovering the presence of minerals such as hematite, which is often an indicator of the presence of past water as well as jarosite and goethite which can only be formed in the presence of water. Other observations made by the Mars Rover included the discovery of shrinkage cracks and cross lamination. Shrinkage cracks are formed when wet sediments dry out while cross laminations are formed by moving water. Both characteristics involve liquid water in their formation. Another Martian discovery was the presence of crystal molds which are made by minerals precipitating out of liquid water. Further evidence for the presence of liquid water came from the predicted climate changes that are said to have taken place in Mars’ past. By tracking periodic glaciations and the axial tilt of the planet, we can calculate the solar luminosity which can give us an approximation of the temperature that Mars experiences. Predictions of past temperature are in the range at which liquid water can be present due to the lack of CO2 ice and the lesser degree of axial tilt. As the climate system on Mars matured, CO2 ice rapidly grew in abundance, decreasing the overall temperature of the planet making it too cold for there to be liquid water present. Mars has been the focus of much study in the last couple of years. We are convinced that there may have once been liquid water on its surface. The possibility of the presence of water suggests that Mars may have once had an environment that could have supported life. Studies so far have provided evidence that supports the theory of water being present. NASA sponsored missions have contributed most of this information. The Mars Lander has uncovered frozen water on the surface of Mars, the Mars Orbiter has surveyed the surface of Mars and there seem to be water formed canyons, and the Mars Rovers have discovered minerals that can only be formed under aquatic conditions. Climate models of Mars have established that the temperature was once much warmer than what it is today showing the possibility for liquid water to exist (Nakamura and Tajika, 2001). The past and present climate of Mars as well as the rock formations and minerals present reveal much about the history of the planet and suggest that Mars may once have had liquid water. Upon examination of the data received from the Mars Exploration Rovers several characteristics were found in the sedimentary rocks that suggest liquid water was involved in their formation. These two characteristics are shrinkage cracks and cross lamination. The shrinkage cracks were discovered by the Olympia outcrops and originally several explanations for their formation existed. It was hypothesized that they could have been formed by the same impact that formed the Erebus crater but the cracks known to be formed by the impact “postdate and overprint” the shrinkage cracks (Grotzinger et al, 2006 pg 1087). Also the shrinkage cracks were found in areas where soft sediment deformation had occurred and in places where plastic deformation had occurred. These observations do not support the hypothesis that the cracks were formed by an impact. The cracks however appear to be nearly identical to the shrinkage cracks found on earth. On earth these cracks are formed by damp sediments drying out and pulling away from each other. For the sediments to originally have been damp it implies that liquid water was present at the time to make them so. Also the Martian shrinkage cracks displayed some prism cracks which are associated with repeated periods of wetness and dryness which could be caused by small rises and falls in the height of the water table. The only logical explanation for the formation of these shrinkage cracks on Mars is an oscillation in the height of the water table and if a water table existed so too did liquid water. The cross lamination in the sedimentary rocks on Mars also leads to this conclusion. On earth, lamination of the “type and scale” (Grotzinger et al, 2006 pg 1085) seen on Mars is not known to be caused by eolian flows or base surges. Also the MI images that were taken of the laminations showed that the layers were an intrinsic part of the rock and not merely a result of weathering. The only other explanation is that they were caused by water. The shape, texture and size of the trough cross lamination suggest that they were caused by shallow water moving at moderate velocities. The presence of both cross lamination and shrinkage cracks on Mars is highly supportive evidence that water was once present (Grotzinger et al, 2006). Other observations made by the Mars Exploration Rovers that support the theory that water was once present included possible crystal molds. Sulfate rich rocks with their surfaces “crisscrossed by tiny gashes” (Squyres 2005 pg 310) were found by the Opportunity Rover on the Meridiani Planum. The tiny gashes looked like those formed from crystal molds. On earth crystal molds form when minerals precipitate out of water that is saturating a rock and crystallize pushing aside or replacing the rock that is already there. When conditions change the softer crystals are eroded away faster than the surrounding rock leaving indentations in the rock where they once were resulting in the scratched appearance of the rock (Squyres 2005). These crystal molds could also explain something else about Mars. Studies of MgSO4·11H2O have shown that it could be the crystal that made the molds. If this is true a third of the crystals by volume were composed of water. It is also possible that the release of water from MgSO4·11H2O resulted in the some of the outflow channels on Mars (Peterson et al, 2006). The Mars Exploration Rovers have helped explore the geology of Mars in much greater depth than was possible with only satellite pictures. One of the instruments in the payload, the Mossbauer spectrometer was particularly useful in determining the identity of minerals present on Mars. Three minerals in particular that the Mossbauer spectrometer was able to identify were hematite, jarosite, and goethite (Squyres 2005). The presence of all three of these mineral helps substantiate the theory of water once being present on Mars. Hematite is an indicator of water because it can precipitate out of water and be deposited in layers. Although it can be formed in others ways and does not provide solid proof of water the hematite found on Mars is a strong suggestion that it might have been there (Hematite, 2007). Also important was the fact that the hematite on Mars was found in tiny spherules. These spherules were at first hypothesized to be either accretionary lapilli, beads of glass, or concretions. The fact that the hematite spherules were made of a different material than the surrounding basaltic sand disproved the lapilli hypothisis (Squyres2005) and the distribution and the presence of interlocking spherules makes it unlikely that they could be anything other than concretions (Minerals in Mars 'Berries' Adds to Water Story 2004). For the hematite spherules to be concretions they would have to have been formed by water percolating through rocks and depositing hematite in layers around an initial point of precipitation. This theory for how the spherules formed involves the actions of liquid water and thus strengths the argument for the possibility of past water. Two other minerals discovered on Mars, jarosite and goethite, provide more substantial evidence for the presence of water. Both jarosite, a sulfate salt, and goethite, an oxyhydroxide, actually have water in their crystal structure. Therefore water must be present when they are being formed (Squyres 2005). The climate system on Mars is said to undergo drastic changes in temperature due to Jupiter’s gravitational interference on Mars’ angle of tilt about its axis. (Kerr, 2003a). These stages are brought forth every 100,000 years or so as the angle at which the planet tilts fluctuates between 25.2°, which is the current axial tilt of the planet, and 15° which is the estimated axial tilt that Mars used to experience several hundred thousand years ago. (Kerr, 2003a). This change in axial tilt does not increase the amount of light or heat that Mars’ surface experiences but it amplifies the diurnal and seasonal changes in temperature that Mars experiences. These seasonal changes in the past would have allowed for a steady temperature state in which liquid water could exist. Even though there was a presence of water, it was exclusive to the equator where the C02 pressure was highest. This offers an alternative to labeling Mars as a once liquid water-rich planet. We do not have to go to the extent and say that liquid water was abundant on early Mars, but only that it was present. As the climate system of Mars matured the change in tilt allowed for the accumulation of CO2 ice through positive feedback. This explains why the 95% of Marsʼ atmosphere and most of Marsʼ surface is made of either liquid or ice CO2. (Byrne and Ingresoll, 2003). The surface CO2 ice reflected the Sunʼs light and in turn made the planet cooler, eventually leading to the lack of liquid water. Even though the temperature has long been estimated to be far below the area in which liquid water can exist, there have been rare occasions that suggest liquid water may still be running on Marsʼ surface. Photographic evidence shows the minor alterations of craters and gullies that seem to be formed by erosion. (Reports Detail Rover Discoveries of Wet Martian History, 2004). This implies that our understanding of the climate system on Mars may not be as complete as we think and that there may still be subtle traces of liquid water scattered along Marsʼ surface although if this were so, the amount would be incredibly low because Mars lacks both the precipitation rates and oceans that drive Earthʼs climate system. (Albee, 2003). An error in past and present understandings of Mars’ surface has been in identifying CO2 ice and H2O ice properly. There are vast areas of CO2 ice caps that are believed to cover the majority of H2O ice on Mars. Thermal identification of frozen H2O has been observed to have problems identifying items through dust particles and thick sheets of CO2 ice which throws off the estimates of H20 ice on Mars. (Titus et al, 2003). The importance in these miscalculations is that CO2 determines the atmospheric pressure of Mars, surface which can affect the levels of H2O present. (Byrne and Ingresoll, 2003). However, if we assume that current atmospheric conditions where CO2 ice and CO2 gas are the highest in abundance are the reason for no liquid H2O, we can predict that atmospheric conditions were at one point optimal for the presence of liquid H2O before the process of CO2 ice sheet positive feedback occurred. Although no liquid water has yet been found the body of evidence supporting this theory is extensive. The evidence shows that liquid water is the most probable cause for the formation of the shrinkage cracks, cross lamination, crystal molds and hematite spherules. This evidence coupled with the probability of a warmer mars derived from climate models suggests the presence of liquid water. The evidence of water has lead to a deeper understanding of Mars’ past, increase present interest in Mars and may pave the way for future discoveries. Currently there are hypotheses working off the theory that liquid water was present which suggest that there may be bacteria on Mars and that in the past Mars may have had an environment capable of supporting life. References Albee, A.L., The unearthly landscapes of Mars, Scientific American, Vol 288, No. 6, 4453, 2003. Byrne, B. and Ingersoll, A.P., A sublimation model for martian south polar ice features. Science, p 1051-1054, 2003. Grotzinger J. et al “The Geological Society of America” Sedimentary textures formed by aqueous process, Erebus crater, Meridiani Planum, Mar. http://www.gsajournals.org/perlserv/ ?request= get-document&doi=10.1130%2FG22985A.1 (9-20-08) Kerr, R.A., Iceball Mars?, Science, 234-237, 2003. Peterson, R., and Wang R., Crystal molds on Mars; melting of a possible new mineral species to create Martian chaotic terrain Geology, Vol. 34. No. 11, 957-960 November 2006 Nakamura, T., Tajika, E., Stability and evolution of the climate system on Mars, Earth Planets Space, 53, 851-859,2001. “NASA” A Patch of Spherules on Mars 2-16-04 http://apod.gsfc.nasa.gov/apod/ap040216.html (10- 18-08) “NASA” Mars exploration Rover Mission 8-17-02 http://mars.jpl.nasa.gov/mer/fido/sol18-image1.html (10-11-08) “NASA” Hematite 7-12-07 http://www.jpl.nasa.gov/releases/2004/88.cfm (10-11-08) “NASA” Minerals in Mars 'Berries' Adds to Water Story 2004 www.jpl.nasa.gov/releases/2004/88.cfm (10-11-08) Squyres S. Roving Mars: Spirit, Opportunity, and the Exploration of the Red Planet. Hyperion 2006. Titus, N.T., Kieffer, H.H., Christensen, P.R., Exposed water ice discovered near the South Pole of Mars, Science, 1048-1052, 2003. Webster G. Savage D. “NASA” Reports Detail Rover Discoveries of Wet Martian History, 2004 12-2-04 http://www.nasa.gov/centers/jpl/news/mer-120204.html (9-23-08) Image A is of trough cross-lamination found on Mars. Image B is an example of trough cross-lamination found on Earth (Grotzinger et al, 2006). This is an image of the hematite spherules found on taken by the rover Opportunity (A patch of Spherules on Mars, 2004). Shrinkage cracks on Mars (Mars Exploration Rover Mission).