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MATERIAL SAFETY DATA SHEET
Green Agrosino Ltd
Please read the entire document. This Material Safety Data Sheet contains import environmental,
health and toxicology information for your employees, and anyone who will use, transport, store,
dispose of or handle this product. Please make sure this information is given to them. It also
contains information to help you meet community right-to-know/emergency response reporting
requirement under SARA. Title III and many other laws. If you resell this product, this MSDS
must be given to the buyer or the information contained herein must be incorporated in your
MSDS.
SECTION 1: PRODUCT AND COMPANY INDENTIFICATION
Active Ingredient:
Formulation type:
Chinese Registration Number (S):
SYNONYM (S):
Company Details:
Jixi Agrosino Biotech. Co., Ltd
No. 7, Huayang East Road, Jixi County,
Anhui Province 245300 China
Polyoxin B
Wettable Powder
LS20040731
Polyoxin AL
Emergency telephone number
Telephone No: (0086) 0563 8168891
24 hours Emergency No.: 0086-120
SECTION 2: COMPOSITION/INFORMATION ON INGREDIENTS
Ingredient
Content (w/w)
Exposure Limit
Polyoxin B *
10%
None
Additives
10%
None
Other inert Ingredients**
80%
None
Product Code No.: AS 19396-06-6
9
Chemical type: NA
Packing Group: III
Dangerous Goods Class
/and Subsidiary Risk (ADG):
Hazchem Code :
Poisons Schedule:
USE: It is considered that polyoxin B inhibits fungal cell wall chitin biosynthesis.
SECTION 3: HAZARDS INDENTIFICATION
Emergency overview-caution:
Causes eye irritation.
Avoid contact with eyes, skin and clothing.
Keep out of reach of children.
EMERGENCY TELEPHONE #:
MSDS Number: JAB-008
NDA= No Data Available
Ref.
0086-563-8168891
Issue Date: 08/18/04
NA= Not Applicable
2X
5
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Potential health effects:
Eye and skin: this product is expected to cause brief and minor eye irritation. The
degree of injury will depend on the amount and duration of contact and the speed and
thoroughness of the first aid treatment. The expected adverse health effects resulting
from an exposure may include redness and possible swelling.
Ingestion: this product has been shown to be minimally toxic when ingested. The
degree of injury will depend on the amount of material ingested and the speed and
thoroughness of the first aid treatment.
Inhalation: this product has been shown to be minimally toxic when inhaled. The
degree of injury will depend on the amount of material inhaled and the speed and
thoroughness of the first aid treatment.
SECTION 4: FIRST AID MEASURES
Swallowed: if poisoning occurs contact a doctor or Poisons Information Center. If swallowed DO
NOT induce vomiting. Give a glass of water. Begin artificial respiration if victim is not breathing.
Use mouth to nose rather than mouth to mouth
Eye: Hold eye open and rinse slowly and gently with water for 15-20 minutes. Remove contact
lenses, if present, after the first 5 minutes, then continue rinsing eye. Call a poison control center
or doctor for treatment advice.
Inhaled: Move person to fresh air. If person is not breathing, call an ambulance, then give
artificial respiration, preferably mouth-to-mouth if possible. Call a poison control center or doctor
for treatment advice.
Skin: Take off contaminated clothing. Rinse skin immediately with plenty of water for 15-20
minutes
ADVICE TO DOCTOR
No special antidote is available. if poisoning is suspected apply symptomatic therapy.
SECTION 5: FIRE FIGHTING MEASURES
Flammable Limits in Air (% by volume): Upper:
Lower:
Flash Point:
Method used:
Autoignition Temperature:
LEL/UEL:
NFPA Hazard Classification:
Health:
Flammability:
Reactivity:
Other:
Extinguishing Media:
Special Fire Fighting Procedure:
Hazardous Combustion Products:
EMERGENCY TELEPHONE #:
MSDS Number: JAB-008
NDA= No Data Available
NDA
NDA
NDA
NDA
NDA
NDA
0
0
0
None
Water spray or dry chemical
NDA
NDA
0086-563-8168891
Issue Date: 08/18/04
NA= Not Applicable
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SECTION6.ACCIDENTALRELEASEMEASURES
General and disposal: take all necessary actions to prevent and remedy the adverse
effects of the spill. Ensure that disposal is in compliance with federal requirements
and local disposal regulations. Notify the appropriate authorities immediately.
Spills on land
Containment: avoid runoff into storm sewers and ditches which lead to waterways.
Contained spilled liquids with dry absorbents.
Cleanup: clean up spill immediately. Absorb spill with inert material, then place in a
chemical waste container. Wash area with soap and water. Pick up wash liquid with
additional absorbent and place in a chemical waste container.
Spills in water:
Containment: this active ingredient is water soluble. Stop or reduce contamination of
any water. Isolate contaminated water.
Cleanup: remove contaminated water for treatment or disposal.
SECTION 7. HANDLING AND STORAGE
Handling: keep pesticide in original container. Do not store or transport near food or
feed. Do not contaminate food or feed. Do not put concentrate into food or drink
containers. Do not dilute concentrate in food or drink containers.
Storage: store in a cool, dry place, out of direct sunlight.
SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
ALWAYS READ AND FOLLOW THE LABEL INSTRUCTIONS AND WARNING
EXPOSURE STANDARDS
No exposure standards have been set for the components of this product .The manufacturer of the
liquid aromatic hydrocarbon solvent recommends and occupational exposure limit of 100mg/L of
air (8 hour time weighted average)
Exposure Potential: Swallowing is unlikely under normal conditions of usage, Skin uptake and
inhalation of diluted form is less toxic by all exposure routes.
Re-entry Period: Do not enter treated areas without protective clothing until spray has dried.
ENGINEEDRING CONTROLS
No special requirements. Product is used outdoors.
FLAMMABILITY
This product is NON-FLAMMABLE and NOT explosive. Product is NOT combustible.
PERSONAL PROTECTION
Harmful if swallowed. Will irritate the eyes and skin. Avoid contact with eyes and skin. Do not
inhale spray mist. When opening the container and preparing spray wear elbow-length PVC
gloves and face shield or goggles .if product gets in eyes, wash it out immediately with water.
Wash hands after use. After each day’s use, wash gloves and face shield or goggles and
contaminated clothing.
EMERGENCY TELEPHONE #:
MSDS Number: JAB-008
NDA= No Data Available
0086-563-8168891
Issue Date: 08/18/04
NA= Not Applicable
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SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES
PHYSICAL DESCRIPTION /PROPERTIES
Appearance: Yellow-Brown Powder
Odor:
Non-specific
Melting Point: Min 188 oC (decomp.)
Boiling Point: No data available
Specific Gravity/Density: 1.01 g/ml @ 20oC
PH: 2-4
Solubility in water: Insoluble in water
Vapor Pressure: No data available
SECTION 10: STABILITY AND REACTIVITY
Flammability:
non-flammable
Volatility:
not available
Explosive properties:
not explosive
Ignition temperature: 390℃(airborne dust)
Thermal sensitivity:
themally not sensitive
Self-heating properties
Behaviour in water:
Oxidising properties:
Corrosiveness:
not self-heating
Easily soluble
not oxidising
non-corrosive
SECTION 11. TOXICOLOGICAL INFORMATION
ACUTE:
Toxicity:
this product is slightly hazardous (WHO hazard Class IV)
LOW TOXICITY
Swallowed: Tests on rals indicate a low toxicity following single doses of the undiluted product
(LD50> 2000mg/kg)
Dermal:
LOW TOXICITY
Absorption: Tests on rats indicate a low toxicity due to shin contact with the undiluted product.
(LD50 >2000mg/kg)
Inhaled:
NO DATA
Tests on rats using a comparable wettable powder formulation indicate a low toxicity
due to inhalation of the undiluted product.
(LC50 (6 h) > 10mg/l) air.
Irritation :
Eye:
Positive (rabbits)
Skin:
Negative (rabbits)
Sensitization: (based on tests using a comparable wettable powder formulation on guinea pigs)
Skin:
Negative (rabbits)
The sensitizing potential of the hydrocarbon is not know
EMERGENCY TELEPHONE #:
MSDS Number: JAB-008
NDA= No Data Available
0086-563-8168891
Issue Date: 08/18/04
NA= Not Applicable
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SUBCHRONIC
Toxicity: Oral (mice, rats) = 10,000 mg/Kg/day
Chronic/Carcinogenicity (maximum inactive dose): Chronic exposures to low level amounts of
this material are not carcinogenic.
Oral (mice)=4,200mg/kg/day
Oral (rats)=2,500mg/kg/day
Teratology/Development Toxicity: None observed (rabbits, mice)
Mutagenicity: Negative
SECTION 12. ECOLOGICAL INFORMATION
Fish LC50 (96h) for carp﹥100mg/l. Japanese killifish unaffected by 100mg/l for 72h.
Daphnia LC50 (3h) for D.pulex ﹥40mg/l. Algae Eb C50 (72h) for Selenastrum capricornutum ﹥
100mg/l. Other aquatic spp. LC50 (3h) for moina macrocopa ﹥4mg/l.
SECTION 13. DISPOSAL CONSIDERATION
SPILL AND DISPOSAL:
In case of spillage it is important to take all steps necessary to:
(1) Avoid eye and skin contact
(2) Avoid contamination of waterways.
Procedure for spill:
(1) Keep all bystanders away.
(2) Wear goggles, half face-piece respirator with combined dust and vapour cartridge, full-length
clothing and PVC gloves.
(3) Reposition any leaking containers so as to minimize further leakage.
(4) Dam and absorb spill with an absorbent material (e.g. stand or soil)
(5) Shovel the absorbed material will depend upon the extent of the spill
(6) Dispose of the absorbed material will depend upon the extent of the spill.
For quantities up to 50L of product bury in a secure landfill site.
For quantities great than 50L seek advice from the manufacturer (use emergency contact
number below) before attempting disposal. Contain in a secure location until disposal method is
established.
(7) Decontaminate the spill area with detergent and water and rinse with the smallest volume of
water practicable.
Dispose of empty, use containers by:
(a) Triple rinsing or preferably pressure rinsing containers with water, add the rinsing to the
spray tank.. DO NOT dispose of undiluted chemicals on site.
(b) If recycling, replace cap and return clean containers to recycler or designated collection
point.
(c) If not recycling, break, crush or puncture and bury empty containers in a local authority
landfill. If no landfill is available, bury the containers below 500 mm in a disposal pit
specifically marked and set up for this purpose clear of waterways, desirable vegetation
and tree roots.
EMERGENCY TELEPHONE #:
MSDS Number: JAB-008
NDA= No Data Available
0086-563-8168891
Issue Date: 08/18/04
NA= Not Applicable
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SECTION 14. TRANSPORT INFORMATION
UN NUMBER: NOT REGULATED
ADR/IRD:
NOT REGULATED
IMDG/IMO: NOT REGULATED
AIR/IATA:
NOT REGULATED
SECTION 15: REGULATORY INFORMATION
HAZARD CLASSES:
Acute health effects: YES
Delayed (chronic) health effect: YES
Fire hazard: NO
Sudden release of pressure hazard: NO
Reactivity hazard: NA
SECTION 16: OTHER INFORMATION
Reason for issue:
New MSDS
JAB MSDS Prepared by:
Dean Zheng, Jixi Agrosino Biotech. Co., Ltd
Approval date:
08/18/04
Supersedes date:
NA
MSDS number:
JAB-008
The information in this MSDSA is based on data available to us of the revision data given herein,
and believed to be correct.
EMERGENCY TELEPHONE #:
MSDS Number: JAB-008
NDA= No Data Available
0086-563-8168891
Issue Date: 08/18/04
NA= Not Applicable