HEALTH, SAFETY AND ENVIRONMENT SPECIFICATION
Chemical Management
DOCUMENT ID - SP 1194
REVISION
- 1.1
DATE
- 29/01/2006
HSE – SPECIFICATION
Setting Clear Requirements
Authorised for Issue by the HSE IC 24/06/2002
Document Authorisation
Document Authority
‘dapo Oguntoyinbo
Ref. Ind: CSM
Date: 24/06/02
Document Custodian
GT Tan
Ref. Ind: CSM/2
Date: 24/06/02
Document Author
Abdallah Ruwehy
Ref. Ind: TKM
Date: 24/06/02
The following is a brief summary of the four most recent revisions to this document. Details of all revisions prior
to these are held on file by the Document Custodian.
Version No.
Version 1.0
Date
June 2002
Author
Abdallah Ruwehy
Ref. Ind: TKM
Version 1.1
Jan 2006
Maisoon Riyami
Ref Ind: MSE 21
Scope / Remarks
Supersedes GU 292 Chemical Management Manual.
Now includes relevant information from Chemicals
Management Manual – Volume 1, SP 1008 Use of
Energy, Materials and Resources and OHMG Guidance
Note No. 12.
Supersedes Transport Standards Manual
TOM/03/000/300.m Guide to Hazardous Materials.
Detailed information on disposal of chemicals now
contained in SP 1009 Waste Management.
Revised Chemical Disposal Form
User Notes:
The requirements of this document are mandatory. Non-compliance shall only be authorised by CSM through
STEP-OUT approval.
A controlled copy of the current version of this document is on PDO's EDMS. Before making reference to this
document, it is the user's responsibility to ensure that any hard copy, or electronic copy, is current. For
assistance, contact the Document Custodian.
This document is the property of Petroleum Development Oman, LLC. Neither the whole nor any part of this
document may be disclosed to others or reproduced, stored in a retrieval system, or transmitted in any form by
any means (electronic, mechanical, reprographic recording or otherwise) without prior written consent of the
owner.
Users are encouraged to participate in the ongoing improvement of this document by providing constructive
feedback.
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Contents
GLOSSARY ................................................................................................................ 1
1.0
INTRODUCTION .............................................................................................. 2
1.1
1.2
1.3
1.4
1.5
REGULATORY REQUIREMENTS ..................................................................................... 2
PURPOSE............................................................................................................... 2
DEFINITION ........................................................................................................... 2
SCOPE .................................................................................................................. 2
DELIVERABLES ........................................................................................................ 3
1.6
1.7
1.8
1.9
ROLES AND RESPONSIBILITIES .................................................................................... 3
PERFORMANCE MONITORING ...................................................................................... 4
DISTRIBUTION AND TARGET AUDIENCE ......................................................................... 5
REVIEW AND IMPROVEMENT ....................................................................................... 5
1.5.1
1.5.2
2.0
SELECTION AND PURCHASE OF CHEMICALS .................................................. 6
2.1
2.2
2.3
SELECTION OF CHEMICALS ......................................................................................... 6
CHEMICAL APPROVAL PROCEDURE ............................................................................... 6
CHEMICALS APPROVAL PANEL (CAP) ............................................................................ 7
2.4
2.5
CHEMICAL CUSTODIANS’ REGISTER .............................................................................. 8
PURCHASE OF CHEMICALS .......................................................................................... 8
2.6
PACKAGING AND PACKING OF CHEMICALS ...................................................................... 9
2.7
2.8
2.9
2.10
LABELLING OF CHEMICALS ....................................................................................... 10
CHEMICAL EMERGENCY PLANS .................................................................................. 10
PERSONNEL TRAINING AND AWARENESS ...................................................................... 11
INSPECTION OF CHEMICAL FACILITIES AND STORAGE AREAS ............................................. 12
2.3.1
2.3.2
2.3.3
Composition of the CAP ................................................................................. 7
Frequency of Meetings of the CAP .................................................................. 7
Terms of Reference of the CAP ...................................................................... 7
2.5.1
2.5.2
2.5.3
2.5.4
Third Party Chemicals .................................................................................... 8
Projects ........................................................................................................ 8
Surplus/Redundant Chemicals ........................................................................ 8
Shelf Life ...................................................................................................... 8
2.6.1
2.6.2
Packaging of Chemicals ................................................................................. 9
Packing of Chemicals ..................................................................................... 9
3.0
SP-1194
Records ........................................................................................................ 3
Reports ........................................................................................................ 3
TRANSPORT OF CHEMICALS ......................................................................... 13
3.1
3.2
DOCUMENTATION AND PERMITS ................................................................................ 13
TRANSPORTATION ................................................................................................. 13
3.3
TRANSPORT RESPONSIBILITIES ................................................................................. 14
3.2.1
3.2.2
3.2.3
Safety Equipment ........................................................................................ 13
Loading and Load Restraint ......................................................................... 13
Vehicle Placards .......................................................................................... 13
3.3.1
3.3.2
3.3.3
3.3.4
3.3.5
Operator's (Haulier) Responsibility ............................................................... 14
Driver's Responsibility ................................................................................. 14
Planning ..................................................................................................... 15
Transport from Supplier/Contractor to PDO .................................................. 15
Transport within PDO Operations ................................................................. 16
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4.0
STORAGE OF CHEMICALS ............................................................................. 17
4.1
STORAGE LOCATIONS ............................................................................................. 17
4.1.1
4.1.2
4.1.3
4.1.4
5.0
Bulk Chemicals............................................................................................ 17
Packed Chemicals ....................................................................................... 17
Storage Procedures ..................................................................................... 17
Segregation of Incompatible Chemicals ........................................................ 18
USE AND DISPOSAL OF CHEMICALS ............................................................. 19
5.1
5.2
OPERATING PROCEDURES ........................................................................................ 19
DISPOSAL OF CHEMICALS ........................................................................................ 19
5.2.1
5.2.2
5.2.3
5.2.4
Reuse of Surplus or Damaged Chemicals ...................................................... 19
Recycling of Chemicals ................................................................................ 19
Recycling of Chemical Containers ................................................................. 20
Disposal of Chemical Waste Residues ........................................................... 20
APPENDIX A: SHOC CARD REQUEST FORM (SCRF) ..................................................... 22
APPENDIX B: LIST OF CHEMICALS WHICH ARE PROHIBITED OR REQUIRE A PERMIT .... 23
APPENDIX C: SHOC CARD APPROVAL FORM ............................................................... 38
APPENDIX D: SHOC CARD ........................................................................................ 39
APPENDIX E: CHEMICAL CUSTODIANS' REGISTER ...................................................... 40
APPENDIX F: CONTAINER PACKING & STORAGE GUIDE .............................................. 41
APPENDIX G: HAZARD SYMBOLS ............................................................................... 42
APPENDIX H: MAP OF WESTERN WATER SUPPLY WELL FIELD PROTECTION ZONES ...... 43
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Glossary
CAP
CDAF
CTU
FIFO
MSDS
PSN
ROP
SHOC Cards
SCRF
TREM Card
TU
SP-1194
Chemicals Approval Panel
Chemical Disposal Advice Form
Cargo Transport Unit
First In First Out
Material Safety Data Sheet
Proper Shipping Name
Royal Omani Police
Safe Handling of Chemicals Cards
SHOC Card Request Form
Transport Emergency Card
Transport Unit
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1.0
1.1
Introduction
Regulatory Requirements
Royal Decree No. 46/95: Issuing the Procedures for Handling and Use of Chemicals,
refers to the manufacture, import, export, storage, handling, and use of any chemical
substance. These activities shall comply with the Procedures, Regulations and
Decisions issued for implementation and coordinated by the Minister for the Ministry
of Regional Municipalities, Environment and Water Resources (MRMEWR).
Ministerial Decree 248/97: Issuing the Regulations for the Registration of Chemical
Substances and the Relevant Permits, requires that any hazardous chemical
manufacture, export, transport, storage, handling, use or disposal, shall apply to the
Ministry for a permit. The Department of Chemical Substances shall maintain a list of
hazardous chemicals according to international classifications. This Ministerial Decree
also defines the minimum requirement for the Chemical Safety Data Sheet.
1.2
Purpose
In order to safeguard personnel, facilities and the environment, and to maintain
compliance with Omani law and PDO’s objectives, the use of chemicals must be
controlled and managed effectively.
This Specification outlines the requirements to be followed by PDO staff and
contractors in the selection, purchase, packaging, transport (including the cleaning of
mobile tanks), storage, use and disposal of chemicals.
This Specification works in conjunction with the Safe Handling of Chemicals (SHOC)
Card system. Existing SHOC Cards for approved chemicals are listed on the TKM web
site.
1.3
Definition
In this Specification chemicals are defined as all liquid, gaseous and solid substances,
which are purchased in containers, drums, packages or tankers.
Liquid chemicals include oil products, such as fuels and lubricants, and crude oil in
drums and tankers.
Gaseous chemicals are covered in detail in SP 1005 Emissions to Air.
1.4
Scope
This Specification includes hazardous materials, which are those chemicals classified
as being dangerous to humans and/or the environment.
With every chemical application there is a hazard that must be identified beforehand
so that the risk factor can be measured and managed. This Specification identifies
the responsibilities of those involved in chemical management, with these parties
“managing the risk” at each stage of the chemical lifecycle.
This Specification also covers Contractor requirements for the storage of fuel (Section
4.2). "Fuel" is defined here as petrol or diesel for use in motor vehicles or other
equipment. The Specification does not cover the use of associated gas, aviation fuel,
or clean crude used in power generation activities, air, or drilling activities.
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This Specification does not cover radioactive materials (refer to SP 1170 Naturally
Occurring Radioactive Materials (NORM).
1.5
Deliverables
1.5.1
Records
Records shall be maintained to document the implementation of this Specification.
1.5.2
Reports
The quantities of chemical waste generated, by type and disposal route must be
reported to CSM/2 on a monthly basis as required by SP 1009 Waste Management.
PDO Staff: Any non-compliance with this Specification shall be notified, investigated
and reported per the ‘Non Compliance Report Form’ in CP 122 HSE Management
System Manual, Part 2 Chapter 6.
Contractors: Any non-compliance with this Specification shall be reported to the
Contract Holder.
1.6
Roles and Responsibilities
Asset Managers
Asset Managers are responsible for ensuring compliance with the requirements for
the storage, use and disposal of chemicals, as outlined in this Specification for the
lifecycle of the chemical under his/her control (see glossary for definition). The Asset
Manager can delegate this authority to a Chemical Custodian.
Chemical Custodians
Chemical Custodians are responsible for chemicals at whatever stage in its life cycle
they are using it (e.g. storage, transportation, use, disposal. Chemical Custodianship
can be passed to another person if the current Chemical Custodian changes job, or
the chemical passes over from an engineering project to an operational use.
The Chemical Custodian shall be identified, by Reference Indicator, against the
chemicals for which they are responsible for, in the Chemical Custodians’ Register
(see Section 2.4 and Appendix E).
The Chemical Custodian shall ensure that all chemicals are accompanied by the
applicable SHOC cards whilst under their custodianship, and that custodianship of the
chemicals is passed on in a timely manner once he is finished with them.
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An example of the people who might be designated Chemical Custodians is shown
below.
Area/Facility/Location
Drilling Rig
Work Over Rig
Laboratories
Production Station
Sewage Treatment Plant
Workshops
Construction Areas
New Projects
Chemical Custodian
Drilling Supervisor
Work Over Supervisor
Laboratory Supervisor
Area Supervisor
Estate Services Supervisor
Workshop Supervisor
Contract Holder
Project Engineer
Note: Supply Supervisors are not considered Chemical Custodians, as they are nonusers. There are existing procedures in place to maintain warehouse/storage areas,
and responsibilities for chemicals under their control are already defined.
Chemical Initiators
Chemical Initiators are responsible for raising the SHOC Card Request Form (refer to
Appendix A). The Chemical Initiator will be the focal point for the chemical
throughout its life-cycle, from selection through to disposal.
Contract Holders
Contract Holders are responsible for communicating this Specification to Contractors,
and for ensuring that the requirements of this Specification are adhered to within the
scope of their contracts.
Contractors
Contractors are responsible for ensuring that activities undertaken within the scope of
their contracts are managed in accordance with the requirements of this
Specification.
1.7
Performance Monitoring
Compliance with this Specification shall be monitored through workplace supervision
and periodic site inspections.
Chemical Performance
All chemical applications must be monitored for effectiveness in terms of cost,
technical efficiency and HSE impact. Continuous improvement should be sought in
reducing costs, quantities and HSE impact.
Waste Chemical Generation
PDO's operating policy is, where possible, to have zero chemical waste. Hence
chemicals must be phased out completely (i.e. all old chemical consumed) before
alternatives are introduced. If a specific requirement for a chemical has ceased then
alternative usage must be sought. It is generally safer to consume the chemical as
per its designed function than to dispose of it into some other process stream.
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1.8
Distribution and Target Audience
This Specification is intended to be used by PDO staff and contractors involved in the
management and use of chemicals.
Distribution of this Specification is controlled by CSM (refer to CP 122 HSE
Management System Manual – Part 2, Chapter 3).
1.9
Review and Improvement
Any user of this document who encounters a mistake or confusing entry is requested
to immediately notify the Document Custodian using the form provided in CP 122
HSE Management System Manual – Part 2, Chapter 3.
This Specification shall be reviewed as necessary by the Document Custodian, but no
less frequently than every four years. Triggers for full or partial review of this
Specification are listed in CP 122 HSE Management System Manual – Part 2, Chapter
8.
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2.0
Selection and Purchase of Chemicals
2.1
Selection of Chemicals
Before a chemical can be selected for a specific application in PDO, a clearly defined
technical justification for the chemical requirement must be made by a Chemical
Initiator using a SHOC Card Request Form (SCRF) (refer to Appendix A).
According to Shell Minimum Environmental Standards, chemical selection should be
based on the ALARP principle. Guidelines for this are pending.
The Chemicals Approval Panel (CAP) must then approve the chemical before a SHOC
Card can be issued. A SHOC Card is only relevant for the chemical application
designated on the SHOC Card Request Form.
All chemicals, even those for trial purposes, require a SHOC Card. If a chemical does
not have a SHOC Card, then the Chemical Approval Procedure (Section 2.2) must be
followed. Existing SHOC Cards for approved chemicals are listed on the TKM web
site.
The list of toxic chemicals that shall not be used in PDO is shown in Appendix B.
2.2
Chemical Approval Procedure
The Chemical Initiator is responsible for raising the SHOC Card Request Form, and
providing the required information, including test results of the chemical’s
compatibility, effectiveness, economical and HSE justification (including the
demonstration of ALARP principle), and a plan to monitor its effectiveness during
use.
The SHOC Card Request Form, and attachments, are then sent to TKL/1, who will
then pass it to the relevant Production Chemistry specialist, or other competent
resources in or outside PDO. After evaluation of the proposal, the application can
either be passed, rejected and/or an alternative proposed.
If passed, TKL/1 will produce a Draft SHOC Card, which will be circulated to CAP
members for approval or rejection on HSE issues using a SHOC Card Approval Form
(Appendix C).
If the chemical is unanimously approved, TKL/1 will issue the SHOC Card (Appendix
D), which must be signed by TKL. The normal timeframe to prepare a SHOC Card is
three weeks (after CAP approval).
If the chemical is rejected by one or more members of the CAP, the Chemical
Initiator has the right to appeal at a specially convened meeting of the CAP.
For an emergency supply of chemicals, a Waiver can be obtained from the duty
Production Chemist (in his capacity as CAP member), who will consult with the other
members of the CAP before issuing.
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2.3
Chemicals Approval Panel (CAP)
2.3.1
Composition of the CAP
The CAP is composed of four permanent members plus 1 part-time member (F),
who will attend the twice per year meetings only.
Person
TKL
TKH
CSM/2
CSM/31
TKC
2.3.2
Position
Member
Secretary
Chairman
Member
Member
Designate
TKC
TKC2
CSM/21
CSM/32
TSP/132
Responsible For
Chemistry
Chemistry
Environmental
Occupational Health and Safety
Purchasing
Frequency of Meetings of the CAP
The CAP formally meets twice per year to carry out reviews as described in the
Terms of Reference below. If there is a requirement for the CAP to meet additionally,
due for example, to hearing appeals on rejected chemicals, then the Chairman will
arrange a special meeting.
2.3.3
Terms of Reference of the CAP
The CAP will:
On an as-required basis


Review the Draft SHOC Cards produced and circulated by TKL/1 and either
approve or reject them. They may decide to approve the SHOC Card subject to
some agreed modification. This is carried out by the individual members, with
no formal meeting of the CAP being required.
Deal with appeals from Chemical Initiators, who have had their chemical(s)
rejected. This will require a special convening of the CAP.
On a twice yearly basis (March and September)



Review compliance issues with this Specification, and as required, propose
revisions of this Specification in order to improve chemical management in PDO.
Review existing SHOC Cards and remove cards for chemicals that are no longer
in use. Make recommendations for improvements, where deficiencies have been
reported.
Review audit action items related to chemical management.
A report will be issued after each 6 monthly review by the CAP to show what action
needs to be taken to achieve 100% compliance with this Specification.
On an annual basis

Review chemical usage statistics to detect significant increases in use above the
expected norm due to, for example, increase in oil or gas production;
Every Three Years

SP-1194
Carry out a Chemicals Management Audit according to the Approved Integrated
Audit and Review Plan.
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2.4
Chemical Custodians’ Register
Details of the chemicals, assigned to each Chemical Custodian shall be entered into
the Chemical Custodians Register (see Appendix E).
Small-scale laboratory chemicals, used by qualified personnel and stored in
laboratories, are excluded from this requirement.
Chemicals stored in warehouses/yards at the Coast and in the Interior, managed by
Logistics Department staff, are also excluded, as they already have their own
recording system in place
2.5
Purchase of Chemicals
A variety of methods are available for purchasing chemicals to be used on the PDO
concession area. Whatever system is used for purchase the over-riding limitation is
"no purchase in the absence of a pre-existing SHOC Card."
The SHOC Card proves that the chemical has passed all screening criteria, and is fit
for purpose for the designated application.
The packaging and packing requirements shall form part of 'Terms & Conditions' of
purchase.
Small-scale laboratory chemicals used by qualified personnel and stored in
laboratories are excluded from this requirement.
PDO’s Supply Procurement Manual.
2.5.1
Third Party Chemicals
In some cases, chemicals are purchased by Third Party (contractors) for use in PDO.
The contract between PDO and the Contractor must include a clause that all chemicals
used in PDO must have a SHOC Card.
It is the responsibility of the Chemical Initiator to ensure that all Third Party chemicals
used in PDO have an approved SHOC Card. Wherever possible and economically
justified any surplus chemicals should be returned to supplier.
2.5.2
Projects
The implementation of a Civil Engineering or Engineering project may require the
purchase and use of chemicals. In these cases, the SCRF will be raised by the
Contract Holder (PDO Project Engineer) at the same time as preparing the HSE
Specification for the Contract as per PR 1171 Contract HSE Management, Part II.
2.5.3
Surplus/Redundant Chemicals
As a general principle, the generation of surplus chemicals should be avoided by
applying careful chemical inventory management. However, such efforts cannot
always be guaranteed to be successful. To avoid generating surplus chemicals the
contract for purchase of chemicals shall contain a clause stating that "Supplier agrees
to accept the return of excess chemicals at any time during the lifetime of the
Contract."
2.5.4
Shelf Life
To ensure that chemicals do not exceed their shelf life, and thus become a potential
waste disposal problem, good management practices, such as applying
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minimum/maximum stock controls and First In First Out (FIFO), shall be followed by
all parties handling chemicals.
2.6
Packaging and Packing of Chemicals
The packaging and packing requirements outlined in this Specification have been set
to:

ensure safe handling, transportation and storage of packaged (and potentially)
dangerous chemicals.

Comply with ROP requirements.

Comply with International Regulations as stipulated by the UN Recommendations
(Orange Book) and/or a current issue of ADR Agreement (European Agreement
for the International Carriage of Dangerous Goods by Road).
People physically engaged in the 'packing' of dangerous goods shall be properly
trained and instructed.
2.6.1
Packaging of Chemicals
It is important that any potential dangerous substances and articles are easily
recognised, hence every chemical shall contain the following information:
2.6.2

Proper Shipping Name (PSN) and the UN Number. PSN may be the chemical name
of the substance (e.g. ACETONE UN 1090) or the chemical group name, or may
be the type of preparation with certain common characteristics (e.g. ADHESIVES
containing flammable liquid UN 1133). However, trade names are not acceptable
as descriptions for dangerous goods.

The ‘hazard diamond’ label for the prime hazard and the ‘class number’ shown at
the base.
Packing of Chemicals
The following outlines the procedure for packing chemicals so that they are stored
and/or transported safely.
Segregation of Incompatible Chemicals
Two chemical substances are considered mutually incompatible when their stowage
together may result in undue hazards in case of leakage or spillage, or any other
accident. Such chemicals need to be segregated during transport, storage, use and
disposal.
Segregation is obtained by maintaining certain distances between incompatible
dangerous goods. Intervening spaces between such dangerous goods may be filled
with other cargo, so long as it is compatible with the dangerous substances in
question.
No segregation need be applied between dangerous goods of different classes which
comprise the same substance, but vary only in their water content, e.g. Sodium
Sulphide in classes 4.2 and 8.
Substances of the same class may be stowed together without regard for segregation
required by secondary hazards, provided the substances are compatible.
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Whenever dangerous goods are stowed together, whether or not in the cargo
transport unit, the segregation of such dangerous goods must always be in
accordance with the 'Container Packing and Storage Guide' (see Appendix F)
Packers Responsibilities
Packers must ensure that:
 Hazardous goods packages are in a satisfactory condition.
 Cargo Transport Unit (CTU) is in a satisfactory condition for the loading of the
packages. It must also be clean, dry and in good structural condition with securely
closing doors.
 If dangerous goods form only part of the load, they should be placed near the
doors or in an easily accessible position with the hazard labels visible.
 Packages are properly secured and effectively braced inside the CTU.
2.7
Labelling of Chemicals
For the transport (within and external to PDO), storage and use of chemicals, all
chemicals delivered, stored or used must be clearly and permanently labelled, in
accordance with PDO and international transport regulations, including:






chemical name
CAS and/or UN number
hazard identification
quantity
SHOC number
manufacturer.
These labelling requirements apply to both the outside packaging, and individual
units.
2.8
Chemical Emergency Plans
A contingency plan shall be in place for responding to emergencies involving
accidental spills of chemicals, in accordance with PR 1065 Emergency Response Part
II and Emergency Response Documents Part III. The effectiveness of these plans
shall be tested regularly, through emergency drills and exercises.
All spills and leaks of any chemical must be reported immediately to the PDO
Supervisor responsible for the transportation of the chemicals as indicated in SP 1007
Accidental Releases to Land and Water.
An inventory of the types and quantities of chemical in stock shall be presented to the
local Emergency services every 6 months and upon demand.
Prevention of Spills
When the chemical itself is still found to be in a satisfactory condition, but the
condition of the packaging has deteriorated, or has been damaged to such an extent
that it might not withstand the period until the next inspection, then the chemical
must be re-bagged or re-drummed in new containers.
Personnel Protective Equipment
In general, chemical contact must be avoided. Refer to SHOC Card, Section 15, for
the required protective equipment to be worn for each individual chemical. More
detailed information can be found in SP 1234 Personal Protective Equipment.
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Emergency Equipment
Eye wash units and Safety Showers must be available in all areas where chemicals
are stored and handled. The units shall be of the foot-plate actuated type, located in
close proximity to where the chemicals are stored. The units must be fed with clean
water and protected from direct sunlight to maintain a temperature less than 40oC.
Dangerously hot water shall not be used to feed emergency equipment. The units
must be tested routinely.
Portable eye-wash units are also acceptable, as long as they are well maintained and
stored in a cooled environment. The integrity of the units must be checked
frequently and the water replaced periodically.
Chemical Information
SHOC Cards must be available for all chemicals being stored at a particular location.
The SHOC Cards can also be consulted when dealing with emergencies.
However, it is also recommended that a simpler sheet be displayed at the point where
the chemical is stored. Such signs shall be large (minimum A4), simple to understand,
even by an illiterate person and shall contain the following:
 chemical name
 SHOC number
 relevant hazard symbols
 relevant PPE requirements, and
 first aid measures.
Symbols that can be used for such signs are shown in Appendix G
2.9
Personnel Training and Awareness
All personnel working in chemical use, storage, transportation and handling must have
sufficient understanding of all HSE aspects of the chemicals to enable them to carry
out their work safely, in an environmentally acceptable manner without endangering
their health or the health of others and the health of the environment.
In addition, drivers of vehicles transporting dangerous goods shall be fully trained and
deemed capable of extrapolating information from the TREM card, and competent to
use the provided safety equipment (i.e. fire extinguishers, first aid equipment,
protective clothing etc) effectively. Preference shall be given to drivers who have
literacy in either English or Arabic.
Reference should be made to SP 1157 HSE Training Specification.
obtained from HLD/16.
Advice can be
For storage areas, all staff handling chemicals in operational areas must have
sufficient knowledge to enable them to understand the HSE hazards of chemicals.
Suppliers shall be encouraged to provide this training as part of the chemical supply
contracts.
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2.10
Inspection of Chemical Facilities and Storage Areas
Inspections of Chemical Facilities shall be carried out by the Chemical Custodian, as
per the Unit HSE Plan.
Inspections of Chemical Storage Areas shall be carried out by the Responsible
Supervisor, according to the Unit's HSE plans.
Reference should be made to the GU-441 Guideline for HSE Inspections, and GN-12
Occupational Health Management Guidelines.
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3.0
Transport of Chemicals
This section stipulates the transport requirements particular to chemicals including:
documentation and permits, placarding and labelling of vehicles, transport operators
(haulier) responsibilities, driver responsibilities and the cleaning and gas freeing of
mobile tanks used to transport chemicals.
Chemicals that are defined as Hazardous Materials, and vehicles used to transport
them will require a Royal Oman Police (ROP) Hazardous Materials Permit.
3.1
Documentation and Permits
All shipments of chemicals by road shall be accompanied by individual SHOC Cards,
along with the corresponding Transport Emergency (TREM) Cards (see below)
suitably placed in the cab of the transporting vehicle away from other non-related
documents.
TREM Cards
The TREM (Transport Emergency) Card system aims to minimise the impact of any
accident or emergency that may arise during the carriage of dangerous goods. TREM
Cards contain clear instructions for the carrier of dangerous goods on what is to be
done in case of an emergency, such as spillage or fire.
Each TREM Card has been developed to cater for a group of generic (hazardous)
products constituting generic hazards. It is important, therefore, to consult individual
SHOC Cards for specific details on hazardous goods aboard the transport unit.
A total of fourteen (14) TREM cards have been developed, which represent all hazard
classes with the exception of explosives (ADR class 1) and radioactive materials (ADR
class 7). Refer to SP 2000 Road Transport for the TREM cards.
3.2
Transportation
3.2.1
Safety Equipment
Adequate safety equipment shall be provided to deal with the specific dangers of the
substances being carried, and the driver shall be trained to use it effectively. Such
equipment might include fire extinguishers, first aid equipment, personal protective
clothing, etc.
3.2.2
Loading and Load Restraint
Hazardous substances must be contained, segregated and properly secured in a fit
for purpose four sided boundary so as to avoid movement of the packages during
transportation (refer to Section 2.6.2 for details).
3.2.3
Vehicle Placards
Once the transport unit (TU) has been properly packed with dangerous goods in
packages or in bulk, the TU then needs to be placarded (as per the ROP - 'Directorate
General of Civil Defence' regulations) to indicate that it contains dangerous goods.
For tank containers with tank capacity of over 3000 litres, the tank must be placarded
with the appropriate hazard warning placards (rectangular orange plate/panel); one
on each side of the tank (as far to the front as possible), and one on the back of the
unit.
SP-1194
REVISION 1.0
Page 13
HSE – SPECIFICATION
Setting Clear Requirements
The hazard warning placards must display the following information:
 Relevant hazard symbols
 The hazard identification number.
 The substance identification number (name and the UN number).
 Telephone contact number where specialist advice can be obtained when the
goods are in transit and during emergencies.
On a multiple compartment tank containing two or more dangerous goods, hazard
warning placards shall be placed along each side of the tank at the positions of each
relevant compartment. The hazard warning placards shall display the same
information as above.
For any other cargo transport unit carrying over 500 kg of regulated dangerous
goods, the hazard warning placards shall be placed at least on both sides and the
back of the unit. The hazard warning placards shall display the same information as
above.
3.3
Transport Responsibilities
3.3.1
Operator's (Haulier) Responsibility
Haulier must ensure that:
 The vehicle carrying dangerous goods is suitable for the operation.
 The driver is provided with adequate information in writing about the dangerous
substances on board so that the nature of the hazards and the action to be taken
in an emergency are known.
 The driver is properly trained and fully competent in the transportation of
dangerous goods.
 Loading, unloading, stowage and segregation of dangerous substances are done
properly by suitably trained personnel.
 All necessary precautions against contamination, fire and explosion are taken.
3.3.2
Driver's Responsibility
Driver must ensure that:
 Placards and labels have been applied to the vehicle, and are clean and not
obscured.
 Ensure goods are properly packed and segregated (e.g. toxic goods and food are
not carried in the vehicle, unless food is adequately separated and protected
against contamination).
 All necessary documentation, including emergency instructions, are in place and
in good order.
 All safety equipment is available, well maintained and ready for use.
 The vehicle is never parked unattended unless it is in the designated area.
 Precautions to prevent fire, explosion or any other incident are taken throughout
the carriage.
All drivers of vehicles used for transport of chemicals must have attended the
Chemical Hazard Awareness training course (refer to SP 1157 HSE Training
Specification).
SP-1194
REVISION 1.0
Page 14
HSE – SPECIFICATION
Setting Clear Requirements
3.3.3
Planning
The responsible PDO or Contractor Supervisor shall establish whether any of the
chemicals being handled or transported are of a hazardous nature. This can be
assessed by consulting the SHOC Card and the European Agreement for the
International Carriage of Dangerous Goods by Road. Note that some cargoes are not
hazardous in small quantities, but are hazardous in larger quantities (e.g. industrial
cleaners).
If the chemicals are deemed to be "Hazardous" then the packaging and containers
must meet international minimum safety standards. This will include the clear
labelling of the chemical containers and vehicles, as specified in the European
Agreement for the International Carriage of Dangerous Goods by Road .
Incompatible chemicals (see SHOC Card, Section 8 for details) shall not be
transported together on the same vehicle.
A police escort must be requested for all bulk chemical loads that pass through
Western Water Supply Well Field Protection Zones. A map of the Western Water
Supply Well Field Protection Zones is included in Appendix H.
In case of transportation of chemicals by air, the "Dangerous Goods Regulations"
[IATA] and "Technical Instructions for the Transport of Dangerous Goods by Air"
[ICAO] shall be consulted.
In case of transportation of chemicals by sea, the "International Maritime Dangerous
Goods Code" [IMO] shall be consulted.
3.3.4
Transport from Supplier/Contractor to PDO
Chemicals supplied to PDO by a Supplier/Contractor remain the responsibility of the
Supplier/Contractor, until the signing of the delivery ticket. All transportation, up to
the stage of signing of the delivery ticket, is also the responsibility of the
Supplier/Contractor.
Receiving PDO personnel shall ensure that chemicals delivered to PDO are supplied in
accordance with the requirements specified in the order.
Packaging (drums, bags, pallets, boxes, shrink wrapping, etc.) shall be inspected
carefully by the receiving PDO representative. If defects are found which are
considered to be not in line with minimal HSE requirements (e.g. damaged or leaking
containers) the material shall not be accepted and shall be sent back to the supplier
for corrective action, after making the damaged container safe.
Upon receipt of bulk delivery of chemicals, the delivery truck and the receiving storage
vessel shall be inspected for damage before off-loading takes place. Any damage to
the delivery truck or storage vessel shall be reported immediately by the receiving
PDO representative to the appropriate PDO and Contractor supervisors.
To prevent delivery into wrong storage vessels, competent personnel shall be
available during the off-loading.
SP-1194
REVISION 1.0
Page 15
HSE – SPECIFICATION
Setting Clear Requirements
3.3.5
Transport within PDO Operations
TREM cards are required for all chemicals to be transported within PDO. The TREM
Card shall be carried by the driver during transport. The TREM card details shall also
be included in the ‘Journey Management Plan’ (refer to Appendix III of SP 2000 Road
Transport), so that in the event of an emergency the Emergency Response Team
know how to deal with the situation.
SP-1194
REVISION 1.0
Page 16
HSE – SPECIFICATION
Setting Clear Requirements
4.0
Storage of Chemicals
4.1
Storage Locations
4.1.1
Bulk Chemicals
Tanks containing chemical liquids shall be spaced and positioned such that they
present no danger to personnel and surrounding installations. They shall be clearly
identified, placed on an impermeable base, and surrounded by protective bunding
that will contain any spillage and prevent leakage beyond the base, in accordance
with PDO-ERD-09-02.
4.1.2
Packed Chemicals
All chemicals must have secure packages (drums, bags, sacks, etc.) to prevent
spoilage as a result of outside contamination or spillages. Chemicals in permanent
locations shall be stored on hard standing and provided with containment, such that
accidental spillage will not result in pollution of the soil. Chemicals stored in
temporary locations, such as drilling sites, are excluded from this requirement, but
shall have some form of containment in case of spillage.
Hazardous chemicals shall be protected from the elements (i.e. sun, rain, storm, etc.).
Incompatible chemicals (see SHOC Card, Section 8 for details) shall not be stored
together such that potential dangerous reactions could take place, even if the storage
is temporary.
Redundant chemicals and/or chemicals awaiting disposal shall be stored in separate
storage areas. Such areas shall be clearly signposted, constructed and maintained in
the same way as the normal storage areas, as indicated above.
4.1.3
Storage Procedures
All storage of chemicals shall be organised such that the "first in/first out" (FIFO)
principle (i.e. older stock to be consumed first) is adhered to. This requires good
housekeeping of the storage area and accessibility of the material to be taken first.
Regular inspections of the chemicals being stored (packaging as well as product) must
take place to ensure that:


no leakage of the chemical will occur in the period until the next inspection and;
the chemical is still fit for purpose over the period until the next inspection.
If the chemical has been in storage for a long period of time and no off-take has
taken place over the past year(s), further storage of the chemical should be
questioned. The following steps shall then be taken:

The Chemical Initiator, together with the Specialist Production Chemist (TKC/
TKL) shall establish whether the chemical could be used at another location in
PDO.
If yes, the chemical must be consumed at this alternative location to prevent
deterioration. If it has a different use, then it shall be screened prior to being used at
the new location.
SP-1194
REVISION 1.0
Page 17
HSE – SPECIFICATION
Setting Clear Requirements
If not, proceed according to the Specifications for reuse, recycle and/or disposal as
outlined in SP 1009 Waste Management.
4.1.4
Segregation of Incompatible Chemicals
Segregation of dangerous goods while in storage shall be in accordance with section
2.6.2 above.
Every dangerous substance or article while in storage must be accompanied by a
SHOC Card. SHOC card must be clearly displayed for each chemical at its storage
location.
SP-1194
REVISION 1.0
Page 18
HSE – SPECIFICATION
Setting Clear Requirements
5.0
Use and Disposal of Chemicals
The use of chemicals in an operations environment requires special handling
techniques and equipment, specific training and knowledge to ensure that all HSE
precautions are taken. As outlined in Section 1.6 the Chemical Custodian is
responsible for all activities concerning the use of chemicals.
5.1
Operating Procedures
All production and drilling locations, and any other location where chemicals are used,
shall include details of chemical handling in their operating procedures, as outlined in
this Specification.
5.2
Disposal of Chemicals
If, despite the application of best chemical management practices described above,
damaged, unwanted or surplus chemicals are still generated then the following is to
be in order to minimise the amount of chemical waste for disposal:
Reuse
Recycle
Residue
5.2.1
Includes return to Supplier
Return to the process
Must be disposed of with minimum impact
Reuse of Surplus or Damaged Chemicals
Surplus Chemicals
An approved alternative use of the chemical shall be sought in the first instance,
preferably with the same application. If the use is different from that specified on the
SHOC Card, then a revised SHOC Card is required before the chemical can be used
(refer to Section 2).
Another alternative is to return the chemical to the Supplier, according to the standard
requirement in contracts between PDO and Suppliers. In cases where this is not
practicable (e.g. overseas Supplier) or the Supplier will not accept them, then the
waste will have to be disposed of according to Section 5.2.
Damaged Chemicals
If chemicals are damaged on PDO premises and are not surplus, then they shall be
cleaned (and any damaged components removed) and repackaged to requirements
agreed to with the Chemical Custodian, so that they can be used in the process for
which they were obtained.
If chemicals are damaged before or during delivery by the Supplier, then they shall
not be accepted.
If the damaged chemicals are surplus to requirements, then the chemical shall be
repackaged as per Section 2.6.
5.2.2
Recycling of Chemicals
The scope for recycling of chemicals is limited as most chemicals, once they have
been used, end up in a product or waste stream and cannot be extracted.
SP-1194
REVISION 1.0
Page 19
HSE – SPECIFICATION
Setting Clear Requirements
An exception is chemicals used in formulating drilling muds, when the mud is
recycled for the next well. Another example is the recycling of waste lubricating oil.
The Chemical Custodian shall consult with an HSE Advisor to seek opportunities to
recycle chemical waste or its packaging.
5.2.3
Recycling of Chemical Containers
Non-hazardous and hazardous chemical containers (including plastic and metal
drums) shall be emptied, cleaned and punctured by the user/waste generator and
transported with the SHOC card of the chemical to a waste facility capable of
accepting hazardous and/or non hazardous waste (refer to SP 1009 Waste
Management).
Metal drums can either be recycled for their metal content, or reused by the Supplier
for refilling with the same product. Likewise plastic containers can also be recycled.
All containers not being recycled or reused by the Supplier shall be punctured by the
User. This is to prevent the containers being put to an incorrect use, such as storage
of potable water.
5.2.4
Disposal of Chemical Waste Residues
Only those chemicals which cannot be reused or recycled shall be considered for
waste disposal and are called Chemical Waste Residues for the purpose of this
Specification.
The Chemical Waste Residues shall be contained in leak-proof, secure containers,
which are labelled and accompanied by a:
 completed Chemical Disposal Advice Form (refer to SP 1009 Waste Management)
 TREM Card
The Transporters of Chemical Waste Residues shall be licensed to carry hazardous
waste and the disposal site must be licensed to receive such waste.
The chemical Waste Residues shall be disposed of according to SP 1009 Waste
Management. The table below provides an overview of the steps that shall be taken
to ensure that the Chemical Waste Residues are disposed of in the most appropriate
manner.
SP-1194
Waste
stream
Halons & CFC’s
Crude oil
compatible?
-
Water
compatible?
-
Liquid
chemical
wastes
Liquid
chemical
wastes
Liquid
chemical
wastes
Solid chemical
wastes
yes
no
no
yes
No
no
-
-
REVISION 1.0
Page 20
Disposal method
Store until disposal method is
available
Discharge to crude oil product
stream after treatment if required
Discharge to production water
stream to reservoir or non-potable
aquifer after treatment if required
Discharge at Liquid Waste Chemical
Disposal Pit after treatment if
required
Dispose of in lined solid chemical
waste disposal pit
HSE – SPECIFICATION
Setting Clear Requirements
Write-off of Redundant Chemicals
The Chemical Custodian, together with the Chemical Initiator, are responsible for
ensuring that all redundant chemicals are properly written-off.
TKC shall be informed if the chemical is to be withdrawn so that the SHOC Card can
also be withdrawn.
SP-1194
REVISION 1.0
Page 21
HSE – SPECIFICATION
Setting Clear Requirements
Appendix A: SHOC Card Request Form (SCRF)
To be completed by Chemical Initiator/PDO Contract Holder
From: ..................................
Date: ..............
Tel no.
Ref Indicator
...........
...........
To: TKC
To be completed by Chemical Initiator
1. Name of Chemical: ...............................................................
2. Supplier: .......................................................
3. Anticipated use t/annum: .....................4. Type of container .............................................
5 What will the chemical be used for, compared to not using it? ...............................................................
6. New/Replacement chemical? (Strike out as applicable).
7. SHOC Number of old chemical (where applicable) ..............
8. Is this chemical really required? Please supply answers to the following questions as attachments (1-4) to
this form:
8(a) If a replacement chemical, what is its advantage over existing chemical? (Att. 1)
8(b) What benefits does the chemical give over not using it? (Att. 2)
8(c) Is the chemical effective? Please supply supporting evidence from field trial in Att.3.
8(d) Is the chemical economically justified? Please give details of alternatives, including no use in Att. 4.
9. Where will chemical finish up? Air..............% Water..............% Oil ...............%,
other .............. %, ( please specify) ...............
10. Please attach completed SHOC Questionnaire (yes/no) &/or MSDS (yes/no) ( Strike out as appropriate) as
Att. 5.
11. Please supply plan for monitoring effectiveness of chemical during use in Att.6.
Signed: ........................................ Telephone Number: ..................................
To be completed by TKL
The chemical is approved/rejected (Strike out as appropriate).
Signed: ....................................... (TKL )
Date ............................ (Fill in as appropriate).
Distribution: Chemical Initiator/Contract Holder TKC
Note: The presence of an approved SHOC card does not remove the obligation for taskspecific HEMP / Job Hazard Analysis.
SP-1194
REVISION 1.0
Page 22
HSE – SPECIFICATION
Setting Clear Requirements
Appendix B: List of Chemicals which are prohibited or require a Permit
Chemicals listed below require an environmental permit from the Department of Chemicals,
of the Ministry of Regional Municipalities, Environment and Water (MRMEWR). In some
cases, their use is banned either by the Ministry (marked ‘Yes‘) or PDO (in red). This list is
not inclusive of all possible banned chemicals.
Any chemical that is considered to be a known or suspect carcinogen (as defined by the
ACGIH) will be banned from use in PDO (however, the chemical may be present in some
work areas as a byproduct, e.g., benzene which can be found in small amounts in crude oil).
Also, chemicals that are acutely toxic at low doses will also be banned (e.g., phosgene).
In all cases, the final PDO authority for determining whether or not a specific chemical may
be used resides with the Chemical Approvals Panel (CAP) chaired by CSM/2.
No.
Common name
1.
1,1,1-Trichloroethane
2.
1,1,2-Trichloroethane
3.
1,2,4-Trichlorobenzene
4. 1,2-Dibroboethane (EDB)
5.
1,2-Dichloroethylene
6.
1,2-Diphenylhydrazine
7.
1,3-Butadiene
8.
1-Chloronaphthalene
9.
2,3,4,5-Tetrachlphenol
10.
2,4,5-T
11.
2,4,5-Trichlorophenol
12.
2,4,6-Trichlorophenol
13.
2,4-D
14.
2,4-Diaminoanisole
15.
2,4-Diaminotoluene
16.
2,4-Dichlorophenol
17.
2,4-Dinitrophenol
18.
2,6-Dichlorophenol
19.
2-Butanone
20.
2-Chloronaphthalene
21. 2-Ethoxyethanolacetate
22.
2-Hexanone
23.
2-Naphthylamine
24.
2-Nitropropane
25.
2-Propanol
26.
3,3'-Dichlorobenzidine
27.
3,4-Diaminotoluene
28.
3,5-Dinitro-o-cresol
29.
4,4'-Diaminodiphenyl
Oxide
30.
4-Aminobiphenyl
31.
4-Chloro-o-toluidine
Hydrochloride
SP-1194
REVISION 1.0
CAS No.
Number
71-36-3
79-00-5
120-3-2
106-93-4
540-59-0
122-66-7
106-99-0
90-13-1
4901-51-3
93-76-5
95-95-4
88-06-2
94-75-7
615-05-4
95-80-7
120-33-2
51-28-5
87-65-0
78-93-3
91-58-7
111-15-9
591-78-6
91-59-3
79-46-9
67-63-0
91-94-1
496-72-0
497-56-3
101-80-4
92-67-1
3165-93-3
Prohibited Restricted
Page 23
Yes
usage
Pesticide
PDO
Yes
PDO
Pesticide
HSE – SPECIFICATION
Setting Clear Requirements
32.
Acephate
33.
Acetaldehyde
34.
Acetanilide
35.
Acetic Acid
36.
Acetone
37.
Acetonitrile
38.
Acetyl Bromide
39.
Acetylene
40. Acetylene Tetrachloride
41.
Acridine
42.
Acrolein
43.
Acrylamide
44.
Acrylic Acid
45.
Acrylnitril
46.
Acrylonitrile
47.
Adipic Acid
48.
Aflatoxcin M1
49.
Aflatoxin B1
50.
Aflatoxin B2
51.
Aflatoxin G1
52.
Aflatoxins
53.
Alachlor
54.
Aldicarb
55.
Aldoxycarb
56.
Aldrin
57. Alkylbenzenesulfonic Acid
58.
Allethrin
59.
Allyl Alcohol
60.
Allyl Chloride
61.
alpha-HCH
62.
Aluminium
63.
Aluminium Carbide
64.
Aluminium Chloride
65.
Aluminium Nitrate
66.
Aluminium Oxide
67.
Aluminium Sulphate
68.
Aluminum Hydroxide
69.
Aluminum Phosphide
70.
Amidithion
71.
Aminocarb
72.
Amiton
73.
Ammonia
74.
Ammonium Acetate
75.
Ammonium Chloride
76.
Ammonium Hydroxide
77.
Ammonium Nitrate
78.
Ammonium Persulfate
79.
Ammonium Sulfate
SP-1194
REVISION 1.0
30560-19-1
75-07-0
103-84-4
64-19-7
67-64-1
75-05-8
506-96-7
74-86-2
79-34-5
260-94-6
107-02-8
79-06-1
79-10-7
107-13-1
124-04-9
6795-23-9
1162-65-8
7220-81-7
1165-39-5
1402-68-2
15972-60-8
116-06-3
1646-88-4
309-00-2
42615-29-2
584-79-2
107-18-6
107-05-1
319-84-6
7429-90-5
12656-43-8
7446-70-0
13473-90-0
1344-28-1
10043-01-3
21645-51-2
20859-73-8
919-76-6
2032-59-9
78-53-5
7664-41-7
631-61-8
12125-02-9
1336-21-6
6484-52-2
7727-54-0
7783-20-2
Page 24
Yes
Pesticide
Yes
Pesticide
Yes
Pesticide
Yes
Pesticide
Yes
Pesticide
Yes
Pesticide
HSE – SPECIFICATION
Setting Clear Requirements
80.
Ammonium Vanadate
81.
Ammonium982. Hudroperfluorononanate
Aniline
83.
Anthracene
84.
Antimony
85.
Antu
86.
Aramite
87.
Aroclor 5460
88.
Arsenic
89.
Arsenic Acid
90.
Arsenic Pentoxide
91.
Arsenic Trioxide
92.
Arsenic Trisulfide
93.
Arsine
94.
Asbestos
95.
Asphalt
96.
Asulam
97.
Atrazine
98.
Azinphos-ethyl
99.
Azinphos-methyl
100.
Azothoate
101.
Barban
102.
Barium
103.
Barium Carbonate
104.
Barium Chlorate
105.
Barium Chloride
106.
Barium Nitrate
107. Barium Poly Sulphate
108.
Bendiocarb
109.
Benfluralin
110.
Benomyl
111.
Benzaldehyde
112.
Benzene
113. Benzene Sulfonic Acid
114.
Benzo(a)anthracene
115.
Benzo(a)pyrene
116.
Benzoic Acid
117.
Benzoquinone
118.
Beryllium
119.
beta-HCH
120.
BHC
121.
Binapacryl
122.
Bioresmethrin
123.
Biphenyl
124.
Bis(2chloroisopropyl)ether
125. Bis(2-ethylhexyl)phthalate
126. Bis(chloromethyl) ether
127.
Bomyl
SP-1194
REVISION 1.0
7803-55-6
1868-86-6
62-53-3
120-12-7
7440-06-0
86-88-4
140-57-8
11126-42-4
7440-38-2
7778-39-4
1303-28-2
1327-53-3
1303-33-9
7784-42-1
1332-21-4
8052-42-4
3337-71-1
1912-24-9
2642-71-9
86-50-0
5834-96-8
101-27-9
7440-39-3
513-77-9
13477-00-4
10361-37-2
10022-31-8
50864-67-0
22781-23-3
1861-40-1
17804-35-2
100-52-7
71-43-2
98-11-3
56-55-3
50-32-8
65-85-0
106-51-4
7440-41-7
319-85-7
58-89-9
485-31-4
28434-01-7
92-52-4
108-60-1
117-81-7
542-88-1
Page 25
Yes
Yes
Yes
Yes
Yes
Yes
Yes
PDO
Pesticide
Pesticide
Pesticide
Pesticide
Pesticide
Pesticide
Yes
Yes
Pesticide
Pesticide
Yes
Yes
Pesticide
Yes
PDO
PDO
PDO
PDO
Yes
Pesticide
PDO
Yes
Pesticide
HSE – SPECIFICATION
Setting Clear Requirements
128.
129.
130.
131.
132.
133.
134.
135.
136.
137.
138.
139.
140.
141.
142.
143.
144.
145.
146.
147.
148.
149.
150.
151.
152.
153.
154.
155.
156.
157.
158.
159.
160.
161.
162.
163.
164.
165.
166.
167.
168.
169.
170.
171.
172.
173.
174.
175.
SP-1194
Brodifacoum
Bromacil
Bromadiolone
Bromides
Bromine
Bromoform
Bromophos - ethyl
Bromophos Ethyl
Butyl Benzyl Phthalate
Butyl Cellosolve
Butylate
Cacodylic Acid
Cadmium
Cadmium Acetate
Cadmium Chloride
Cadmium Oxide
Cadmium Sulphate
Calcium Arsenate
Calcium Chlorate
Calcium Chromate
Calcium Cyanide
Calcium Naphthanate
Caprolactam
Captafol
Captan
Carbaryl
Carbendazim
Carbofuran
Carbon
Carbon Disulfide
Carbon Monoxide
Carbon Tetrachloride
Carbophenothion
Carboxin
Cartap
Cellosolve
Chloramben
Chlorbenside
Chlordane
Chlordimeform
Chlorfenethol
Chlorfenviophos
Chlorine
Chlormephos
Chlorobenzene
Chlorobenzilate
Chlorodecone
Chlorodifluoromethane
REVISION 1.0
56073-10-0
314-40-9
28772-56-7
24959-67-9
7726-95-6
75-25-2
2104-96-3
4824-78-6
85-68-7
111-76-2
2008-41-5
75-60-5
7440-43-9
543-90-8
10108-64-2
1306-19-0
10124-36-4
7778-44-1
10137-47-3
13765-19-0
592-01-8
105-60-2
2425-06-1
133-06-2
63-25-2
10605-21-7
1563-66-2
7440-44-0
75-15-0
630-08-0
56-23-5
786-19-6
5234-68-4
15263-52-2
110-80-5
133-90-4
103-17-3
57-74-9
6164-98-3
80-06-8
470-90-6
7782-50-5
24934-91-6
108-90-7
510-15-6
143-50-0
75-45-6
Page 26
Yes
Rodenticide
Yes
Pesticide
Yes
Pesticide
Yes
Yes
Yes
Yes
Yes
Yes
Pesticide
Pesticide
Pesticide
Pesticide
Pesticide
Pesticide
Yes
Pesticide
Yes
Pesticide
Yes
Pesticide
Yes
Pesticide
Yes
Pesticide
Yes
Yes
Pesticide
Pesticide
Yes
Nesticide
&Nemticide
Yes
Pesticide
HSE – SPECIFICATION
Setting Clear Requirements
176.
Chloroform
177.
Chlorophacinone
178.
Chloropicrin
179.
Chloroprene
180.
Chlorothal
181.
Chlorothalonil
182.
Chloroxuran
183.
Chlorpropham
184.
Chlorpyrifos
185.
Chlorpyrifos-methyl
186.
Chlorthiamide
187.
Chlorthiphos
188.
Cholrmequat
189.
Chromic Acid
190.
Chromic Acid
191.
Chromioum
192. Chromium (III) Chloride,
Hexahydrate
193.
Chromium
Nitrate
194.
Chromium(VI)
195.
Coal Tar Oil
196.
Cobalt
197.
Copper
198. Copper Arsenate (basic)
199.
Copper Cyanide
200.
Copper Naphthenate
201.
Copper Oxychloride
202.
Coumachlor
203.
Coumaphos
204.
Coumarin
205.
Coumatetralyl
206.
Cresol
207.
Crimidine
208.
Crocidlite
209.
Crotoxyphos
210.
Crufomate
211.
Cryofluorane
212.
Cupric Sulfate
213.
Cuprous
214.
Cyanide
215.
Cyclhexamid
216.
Cyclheximide
217.
Cycloate
218.
Cyclohexanon
219.
Cyhexatin
220.
Cypermethrin
221.
D.D,+Chloropicrin
222.
Dalapon
223.
Dalapon Sodium
SP-1194
REVISION 1.0
67-66-3
3691-35-8
76-06-2
126-99-8
1861-32-1
1879-45-6
1982-47-4
101-21-3
2921-88-2
5598-13-0
1918-13-4
Yes
Pesticide
Yes
Yes
999-81-5
1333-82-0
7738-94-5
7440-47-3
10060-12-5
13548-38-4
18540-29-9
8001-58-9
7440-48-4
7440-50-8
16102-92-4
544-92-3
1338-02-9
1332-40-7
81-82-3
56-72-4
91-64-5
5836-29-3
1319-77-3
535-89-7
12001-28-4
7700-17-6
299-86-5
76-14-2
7758-98-7
1317-39-1
57-12-5
66-81-9
1134-23-2
108-94-1
13121-70-5
52315-07-8
Pesticide
PDO
Yes
Pestiside
Yes
Yes
Rodenticide
Industrial
Yes
Yes
Pesticide
Fungicides
Yes
Insecticide
Yes
75-99-0
127-20-8
Page 27
Pesticide
Pesticide
HSE – SPECIFICATION
Setting Clear Requirements
224.
DBCP
225.
DDD
226.
DDT
227.
Delmethrin
228.
Demeton
229.
Demeton-S-methyl
230.
Desmedipham
231.
Diallate
232.
Diaminotoluenes
233.
Diazinon
234.
Dibam
235.
Dibromethan
236.
Dibutyl Pthalate
237.
Dicamba
238.
Dichlofenthion
239.
Dichloropropane
240.
Dichloropropene
241.
Dichlorothane
242.
Dichlorvos
243.
Dicofol
244.
Dicrotophos
245.
Dieldrin
246.
Diethyl Phthalate
247.
Diethylene Glycol
248.
Diethylenetriamine
249.
Diflubenzuran
250.
Diisobutyl Ketone
251.
Dime Fox
252.
Dimethoate
253.
Dimethyl Phthalate
254.
Dimethylamine
255.
DimethylSulfate
256.
Dimetilan
257.
Dinitrogen Tetroxide
258.
Dinobuton
259.
Dinocap
260.
Dinoseb Acetate
261. Dinozeb & Dinozeb salts
262.
Dioxacarb
263.
Dioxathion
264.
Dioxins
265.
Diphemamid
266.
Diphenylamine
267.
Diquat Dibromide
268.
Diquat Dichloride
269.
Disodium Arsenate
270.
Disodium Arsenate
Heptahyrate
271.
Disulfiram
SP-1194
REVISION 1.0
96-12-8
72-54-8
50-29-3
52918-63-5
8065-48-3
919-86-8
13684-56-5
2303-16-4
25376-45-8
333-41-5
128-04-1
106-93-4
84-74-2
1918-00-9
97-17-6
26638-19-7
26952-23-8
1300-21-6
62-73-7
115-32-2
141-66-2
60-57-1
84-66-2
111-46-6
110-40-0
35367-38-5
108-83-3
115-26-4
60-51-5
131-11-3
124-40-3
77-78-1
644-64-4
10544-72-6
933-21-7
39300-08-7
2813-95-8
88-85-7
6988-21-2
78-34-2
1746-01-6
957-51-7
122-39-4
85-00-7
4032-26-2
7778-43-0
10048-95-0
97-77-8
Page 28
Yes
Pesticide
Yes
Pesticide
Yes
Yes
Insecticide
Pesticide
Yes
Pesticide
Yes
Yes
Yes
Pesticide
Pesticide
Pesticide
Yes
Yes
Pesticide
Yes
Pesticide
Yes
Pesticide
Yes
Pesticide
Yes
Yes
Pesticide
Pesticide
HSE – SPECIFICATION
Setting Clear Requirements
272.
273.
274.
275.
276.
277.
278.
279.
280.
281.
282.
283.
284.
285.
286.
287.
288.
289.
290.
291.
292.
293.
294.
295.
296.
297.
298.
299.
300.
301.
302.
303.
304.
305.
306.
307.
308.
309.
310.
311.
312.
313.
314.
315.
316.
317.
318.
319.
SP-1194
Disulfoton
Dithianon
Diuron
DNOC
Dodecylbenzene
Dodine
Drazoxolon
Edifenphos
Endosulfan
Endothal
Endrin
Epichlorohydrin
EPN
Eptam
Erbon
Ethephone
Ethiofencarb
Ethion
Ethoprophos
Ethyl Acetate
Ethyl Acrylate
Ethyl Chloride
Ethyl Ether
Ethyl Mercaptan
Ethylamine
Ethylbenzene
Ethylene Dibromide
Ethylene Dichloride
Ethylene Oxide
Ethylene Thiourea
Etrimfos
Fenamiphos
Fenasal
Fenchlorphos
Fenitrothion
Fensulfothion
Fenthion
Fentin Acetate
Fentin Hedroxide
Fenuron
Fenvalerate
Ferbam
Ferric Chloride
Ferrous Sulfate
Flourine Compounds
Fluoranthene
Fluoride
Fluorine
REVISION 1.0
298-04-4
3347-22-6
330-54-1
534-52-1
123-01-3
2439-10-3
5707-69-7
17109-49-8
115-29-7
145-73-3
72-20-8
106-89-8
2104-64-5
759-94-4
136-25-4
16672-87-0
29973-13-5
563-21-1
13194-48-4
141-78-6
140-88-5
75-00-3
60-29-7
75-08-1
75-04-7
100-41-4
106-93-4
107-06-2
75-21-8
96-45-7
38260-54-7
22224-92-6
50-65-7
299-84-3
122-14-5
115-90-2
55-38-9
900-95-8
76-87-9
101-42-8
51630-58-1
14484-64-1
7705-08-0
7782-63-0
206-44-0
16984-48-8
7782-41-4
Page 29
Yes
Pesticide
Yes
Pesticide
Yes
Pesticide
Yes
Pesticide
Yes
Pesticide
Yes
Pesticide
Yes
Pesticide
Yes
Pesticide
Yes
Pesticide
Yes
Pesticide
Yes
Pesticide
Yes
Yes
Pesticide
Pesticide
HSE – SPECIFICATION
Setting Clear Requirements
320.
Fluroacetamide
640-19-7
321.
Folpet
133-07-3
322.
Fonofos
944-22-9
323.
Formaldehyde
50-00-0
324.
Formamide
75-12-7
325.
Formetanate
22259-30-9
326.
Formic Acid
64-18-6
327.
Formothion
2540-82-1
328.
Fosthietan
21548-32-3
329.
Freon 11
75-69-4
330.
Freon 12
75-71-8
331.
Furans
110-00-9
332.
Furfural
98-01-1
333.
Furfuryl Alcohol
98-00-0
334.
Glyphosate
1071-83-6
335.
HCB
118-74-1
336.
HCH
608-73-1
337.
Hedrogen Cyanide
74-90-8
338.
Heptachlor
76-44-8
339.
Heptachlor Epoxide
1024-57-3
340.
Heptenophos
23560-59-0
341.
HETP
342.
Hexachlorobenzene
118-74-1
343. Hexachlorobutadiene
87-68-3
344. Hexachlorocyclopentadien
77-47-4
e
345.
Hexachloroethane
67-72-1
346. Hexachloronaphthalene
1335-87-1
347.
Hexachlorophen
70-30-4
348.
Hexone
108-10-1
349.
Hydrazine
302-01-2
350.
Hydrochloric Acid
7647-01-0
351.
Hydrogen Fluoride
7664-39-3
352.
Hydrogen Peroxide
7722-84-1
353.
Hydrogen Sulfide
7783-06-4
354.
Hydroquinone
123-31-9
355.
Idofenphos
18181-70-9
356.
Ioxynil
1689-83-4
357.
Isobemzan
297-78-9
358.
Isobenzan
297-78-9
359.
Isobutanol
78-83-1
360.
Isodrin
465-73-6
361.
Isofenophos
25311-71-1
362.
Isophorone
78-59-1
363.
Isoprene
78-79-5
364.
Isoprocarb
2631-40-5
365.
Isopropylamine
75-31-0
366.
Kelevan
4234-79-1
367.
Kepon
143-50-0
SP-1194
REVISION 1.0
Page 30
Yes
Pesticide
Yes
PDO
Pesticide
Yes
Pesticide
Yes
Yes
Yes
Pesticide
Yes
Yes
Pesticide
Pesticide
Yes
Yes
Pesticide
Pesticide
Yes
Pesticide
Yes
Pesticide
Yes
Yes
Pesticide
Pesticide
HSE – SPECIFICATION
Setting Clear Requirements
368.
369.
370.
371.
372.
373.
374.
375.
376.
377.
378.
379.
380.
381.
382.
383.
384.
385.
386.
387.
388.
389.
390.
391.
392.
393.
394.
395.
396.
397.
398.
399.
400.
401.
402.
403.
404.
405.
406.
407.
408.
409.
410.
411.
412.
413.
414.
415.
SP-1194
Lead
Lead (II) Nitrate
Lead Arsenate
Lead Carbonate
Lead Chloride
Lead chromate
Lead Dioxide
Lead Naphthenate
Lead Phosphate
Lead Subacetate
Lead Sulfate
Lead(II) Acetate
Lenacil
Leptophos
Lindane
Linuron
Lithium Fluoride
m-Chlorophenol
m-Cresol
m-Nitrophenol
m-Phenylenediamine
m-Xylene
Magnesium Phosphide
Malaoxon
Malathion
Maleic Anhyride
Mancozeb
Maneb
Manganese
MCPA, 2-butoxyethyl
ester
Mecarbam
Menazon
Mephosfolan
Mercaptophos
Mercuric Chloride
Mercuric Oxide
Mercurous chloride
Mercury
Mercury (II) Acetate
Mercury (II) Nitrate
Mercury (II) Thiocynate
Metaldehyde
Metham-sodium
Methamidophos
Methanol
Methazole
Methidathion
Methiocarb
REVISION 1.0
7439-92-1
10099-74-8
7645-25-2
598-63-0
7758-95-4
7758-97-6
1309-60-0
61790-14-5
7446-27-7
1335-32-6
7446-14-2
301-04-2
2164-08-1
21609-90-5
58-89-9
330-55-2
7789-24-4
108-43-0
108-39-4
553-84-7
108-45-2
108-38-3
12057-74-8
1634-78-2
121-75-5
108-31-6
8018-01-7
12427-38-2
7439-96-5
19480-43-4
2595-54-2
78-57-9
950-10-7
8065-48-3
7487-94-7
21908-53-2
7546-30-7
7439-97-6
1600-27-7
10045-94-0
592-85-8
108-62-3
137-42-8
10265-92-6
67-56-1
20354-26-1
950-37-8
2032-65-7
Page 31
Yes
Yes
Yes
Yes
Yes
Yes
Yes
Yes
Yes
Yes
Yes
Yes
Pesticide
Pesticide
Pesticide
Pesticide
Pesticide
Pesticide
Pesticide
Industrial
Pesticide
Pesticide
Pesticide
Pesticide
Yes
Yes
Pesticide
Pesicide
Yes
Pesticide
Yes
Pesticide
Yes
Yes
Yes
Yes
Yes
Yes
Pesticide
Pesticide
Pesticide
Pesticide
Pesticide
Pesticide
Yes
Pesticide
HSE – SPECIFICATION
Setting Clear Requirements
416.
417.
418.
419.
420.
421.
422.
423.
424.
425.
426.
427.
428.
429.
430.
431.
432.
433.
434.
435.
436.
437.
438.
439.
440.
441.
442.
443.
444.
445.
446.
447.
448.
449.
450.
451.
452.
453.
454.
455.
456.
457.
458.
459.
460.
461.
462.
463.
SP-1194
Methomyl
16752-77-5
Methoxychlor
72-43-5
Methyl Bromide
74-83-9
Methyl Cellosolve Acetate
109-49-6
Methyl Chloromethyl
107-30-2
MethylEther
Isocyanate
624-83-9
Methyl Mercury
22967-92-6
Methylene Chloride
75-09-2
Metiram
9006-42-2
Metobromuron
30-60-89-7
Mevinphos
7786-34-7
Mexacarbate
315-18-4
Mirex
2385-85-5
Molinate
2212-67-1
Monocrotophos
6923-22-4
Monolinuron
1746-81-2
Monuron
150-68-5
Morfam Quat
7411-47-4
Morpholine
110-91-3
MSPA
94-74-6
N,N-Dially
37764-25-3
Dichloroacrtamide
N,N-Dimethyl-p99-98-9
phenylenediamine
N,N-Dimethylformamide
68-12-2
n-Butanol
71-36-3
n-Butyl Phthalate
84-74-2
N-Dimethylnitrosamine
62-38-4
n-Hexane
110-49-6
N-Nitrosodiethylamine
55-18-5
N-Nitrosodiphenylamine
86-30-6
N-Nitrosodipropylamine
621-64-7
n-Propanol
71-23-8
Nabam
142-59-6
Naphtha
8030-30-6
Naptalam Sodium
132-67-2
Nated
300-76-5
Nickel
7440-02-0
Nickel Carbonyl
13463-39-3
Nicotine
54-11-5
Nicotine Sulfate
65-30-5
Nitrates
14797-55-8
Nitric Acid
7697-37-2
Nitric Oxide
10102-43-9
Nitrobenzene
98-95-3
Nitrofen
1836-75-5
Nitrogen Dioxide
10102-44-0
Nitroglycerine
55-63-0
Nitromethane
75-52-5
Norbormid
991-42-4
REVISION 1.0
Page 32
Yes
Pesticide
Yes
Pesticide
Yes
Pesticide
Yes
Pesticide
Yes
Yes
Pesticide
Yes
Pesticide
PDO
Yes
Pesticide
HSE – SPECIFICATION
Setting Clear Requirements
464.
O-Chlorophenol
465.
O-Cresol0
466.
o-Dianisidine
467.
o-Nitrophenol
468.
O-Phenylenediamine
469.
o-Tolidine
470.
O-Xylene
471. Octachlor Naphthalene
472.
Omethoate
473.
Oxamyl
474.
Oxydemeton-methyl
475.
Ozone
476.
p-Chlorophenol
477.
p-Cresol
478.
p-Dichlorobenzene
479.
p-Dioxane
480.
p-Nitrophenol
481.
p-Phenylenediamine
482.
p-Xylene
483.
Paraoxon
484.
Paraoxon-methyl
485.
Paraquat Dichloride
486.
Paraquat Ion
487.
Parathion
488.
Parthion-methyl
489. PBB (Firemaster FF1)
490. PBB(Firemaster BP-6)
491.
PCB's
492.
PCB's
493.
PCB's(21%)
494.
PCB's(42%chlorin)
495.
PCB's(54%)
496.
PCB's(60%)
497.
PCT(aroclor 5442)
498.
Pebulate
499.
Penta
500.
Pentachloroethane
501. Pentachloronaphthalene
502.
Pentachlorophenol
503.
Perchloric Acid
504.
Permethrin
505.
Perthane
506.
Phenmedipham
507.
Phenol
508.
Phenthoate
509.
Phenyl Ether
510.
Phenyl Hydrazine
511.
Phenyl Mercaptan
SP-1194
REVISION 1.0
95-57-8
95-46-7
119-90-4
88-75-5
95-54-5
119-93-7
95-47-6
2234-13-1
1113-02-6
23135-22-0
301-12-2
10028-15-6
106-48-9
106-44-5
106-46-7
123-91-1
100-02-7
106-50-3
106-42-3
311-45-5
950-35-6
1910-42-5
4685-14-7
56-38-2
298-00-0
67774-32-7
59536-65-1
61788-33-8
1336-36-3
11104-28-2
53469-21-9
11097-69-1
11096-82-5
12642-23-8
1114-71-2
76-01-7
1321-64-8
87-86-5
7601-90-3
52645-53-1
72-56-0
13684-63-4
108-95-2
2597-03-7
101-84-8
100-63-0
108-98-5
Page 33
Yes
Pesticide
Yes
Yes
Yes
Yes
Yes
Yes
Yes
Yes
Yes
Yes
Yes
Yes
Yes
Pesticide
Pesticide
Pesticide
Yes
Pesticide
Yes
Pesticide
Industrial
Industrial
Industrial
Industrial
Industrial
Pesticide
HSE – SPECIFICATION
Setting Clear Requirements
512. Phenylmercuric Acetate
513.
Phorate
514.
Phosalone
515.
Phosfolan
516.
Phosgene
517.
Phosmet
518.
Phosphamidon
519.
Phosphine
520.
Phosphoric Acid
521.
Phosphorous
522.
Phoxim
523.
Picloram
524.
Picric Acid
525.
Piperonyl Butoxide
526.
Pirimicarb
527.
Pirimiphos-ethyl
528.
Pirimiphos-methyl
529.
Pival
530.
Platinum
531. Polybrominatedbiphenyls
532.
Polychlortrpene
533.
Polyethylene
534.
Polystyrene
535.
Polyvinyl Chloride
536.
Potassium Chromate
537. Potassium Dichromate
538. Potassium Hydroxide
539. Potassium Permanganate
540.
Profenofos
541.
Promecarb
542.
Propachlor
543.
Propane
544.
Propham
545.
Propinep
546.
Propionitrile
547.
Propoxur
548.
Propylene Dichloride
549.
Propylene Oxide
550.
Prothiofos
551.
Prothoate
552.
Pyrazophos
553.
Pyrene
554.
Pyrethrin I
555.
Pyrethrin II
556.
Pyrethrum
557.
Pyridine
558.
Pyrocatechol
559.
Pyrogallol
SP-1194
REVISION 1.0
62-38-4
298-02-2
2310-17-0
947-02-4
75-44-5
732-11-6
13171-21-6
7803-51-2
7664-38-2
7723-14-0
14816-18-3
1918- 02-1
88-39-1
51-03-6
23103-98-2
23505-41-1
29232-93-7
83-26-1
7440-06-4
59080-40-9,
27858-07-7,
13654-09-6
9002-88-4
9003-53-6
9002-86-2
7789-00-6
7778-50-9
1310-50-3
7722-64-7
41198-08-7
2631-37-0
1918-16-7
74-98-6
122-42-9
12071-83-9
107-12-0
114-26-1
78-87-5
75-56-9
34643-46-4
2275-18-5
13457-18-6
129-00-0
121-21-1
121-29-9
8003-34-7
110-86-1
120-80-9
87-66-1
Page 34
Yes
Yes
PDO
Pesticide
Yes
Pesticide
Yes
Yes
Pesticide
Pesticide
Yes
Pesticide
HSE – SPECIFICATION
Setting Clear Requirements
560.
Quintozene
561.
Resmethrin
562.
Resorcinol
563.
Resorcinol Diglycidyl
Ether
564.
Rotenon
565.
Schradan
566.
sec-Butanol
567.
sec-Butylamine
568.
Selenium
569.
Selenium (IV) oxide
570.
Selenium Disulfide
571. Selenium Hexafluoride
572. Selenium Oxychloride
573.
Siduron
574.
Silicon Fluride
575.
Silicon Tetrachloride
576.
Simazine
577.
Sodium
578. Alkylbenzenesulfonate
Sodium Arsenite
579.
Sodium Chromate
580.
Sodium Cyanide
581.
Sodium Dichromate
582.
Sodium Flouride
583. Sodium Fluoroacetate
584.
Sodium Hydroxide
585.
Sodium MCPA
586.
Sodium Nitrate
587.
Sodium Nitrite
588. Sodium Orthophosphate
589.
Sodium Salicylate
590.
Sodium Selenate
591. Sodium Trichloroactate
592.
Streptomycin
593.
Stroban
594.
Strychnine
595.
Strychnine Sulfate
596.
Styrene
597.
Sulfallate
598.
Sulfami Acid
599.
Sulfonamide
600.
Sulfotepp
601.
Sulfprofos
602.
Sulfur
603.
Sulfur Dioxide
604.
Sulfuric Acid
605.
Sulphur Trioxide
606.
TCDD
607.
Tecnazene
SP-1194
REVISION 1.0
82-86-8
10453-86-8
108-46-3
101-90-6
83-79-4
152-16-9
78-92-2
13952-84-6
7782-49-2
7446-08-4
7488-56-4
7783-79-1
7791-23-3
1982-49-6
7783-61-1
10026-04-7
122-34-9
68411-30-3
7784-46-5
7775-11-3
143-33-9
10588-01-9
7681-49-4
62-74-8
1310-73-2
3653-48-3
7631-99-4
7632-00-0
7601-54-9
54-21-7
13410-01-0
650-51-1
57-92-1
8001-50-1
57-24-9
60-41-3
100-42-5
95-06-7
5329-14-6
63-74-1
3689-24-5
35400-43-2
7704-34-9
7446-09-5
766493-9
7446-11-9
1746-01-6
117-18-0
Page 35
Yes
Pesticide
Yes
Pesticide
Yes
Yes
Yes
Yes
Yes
Pesticide
Pesticide
Pesticide
Pesticide
Pesticide
Yes
Pesticide
Yes
Pesticide
Yes
Pesticide
Yes
Pesticide
HSE – SPECIFICATION
Setting Clear Requirements
608.
Tellurium
609.
Temephos
610.
TEPP
611.
Terbufos G
612.
tert-Butanol
613.
Tetrachloroethyiene
614.
Tetrachlorvinphos
615.
Tetracycline
616.
Tetradifon
617.
Tetraethyl Lead
618.
Tetramethrin
619.
Tetramethyl Lead
620.
Thalium Chloride
621.
Thalium Sulphate
622.
Thallium
623.
Thiabendazole
624.
Thiofanox
625.
Thiometon
626.
Thionazin
627.
Thionyl Chloride
628.
Thiram
629.
Tin
630.
Titanium
631.
Titanium Dioxide
632. Titanium Tetrachloride
633.
Titanium Trichloride
634.
Toluene
635. Toluene Diisocyanate
636. Toluene-2,6-Diisocyanate
637. Toluene-2-2-Diisocyanate
638.
Toxaphene
639.
Triallate
640.
Triamiphos
641.
Triazophos
642.
Tributyl Phosphate
643.
Trichlorfon
644.
Trichloronate
645.
Trichothecin
646.
Tricloroethylene
647.
Trifluralin
648.
Triforine
649.
Trinitrotoluene
650.
Triphenyl Phosphate
651. Tris(2,3-dibromopropyl)
phosphate
652.
Turpentine
653.
Urea
654.
Valeraldehyde
655.
Vamidothion
SP-1194
REVISION 1.0
13494-80-9
3383-96-8
107-49-3
13071-79-9
75-65-0
127-18-4
22248-79-9
60-54-8
119-29-0
78-00-2
7696-12-0
75-74-1
7791-12-0
10031-59-1
7440-28-0
148-79-8
39196-18-4
640-15-3
297-97-2
7719-09-7
137-26-8
7440-31-5
7440-32-6
13463-67-7
7550-45-0
7705-07-9
108-88-3
26471-62-5
91-08-7
584-84-9
8001-58-9
2303-17-5
1031-47-6
24017-47-8
126-73-8
52-68-6
327-98-0
6379-69-7
79-01-6
1582-09-8
26644-46-2
118-96-7
115-86-6
126-72-7
8006-64-2
57-13-6
110-62-3
2275-23-2
Page 36
Yes
Yes
Pesticide
Pesticide
Yes
Pesticide
Yes
Yes
Pesticide
Yes
Pesticide
HSE – SPECIFICATION
Setting Clear Requirements
656.
Vanadium
657.
Vanadium Penoxide
658. Vanadium Tetrachloride
659.
Vanadium Trioxide
660.
Vernolate
661.
Vinyl Chloride
662.
Vinylidene Chloride
663.
Warfarin
664.
White Spirit
665.
Xylidine
666.
Zinc
667.
Zinc Chloride
668.
Zinc Cyanide
669.
Zinc Oxide
670.
Zinc Phosphide
671.
Zineb
672.
Ziram
SP-1194
REVISION 1.0
7440-62-2
1314-62-1
7632-51-1
1314-34-7
1929-77-7
75-01-4
75-35-4
81-81-2
8052-41-3
1300-73-8
7440-66-6
7646-85-7
557-21-1
1314-13-2
1314-84-7
12122-67-7
137-30-4
Page 37
PDO
HSE – SPECIFICATION
Setting Clear Requirements
Appendix C: SHOC Card Approval Form
Petroleum Development Oman
Memorandum
From:
Ref:
To:
Date:
SHOC Approval Form
Sheet for approval (MSDS sheets are also included for reference).
Details are as follows.
Chemical name
Chemical description/usage
Supplier
TMM sheet processing details
Date
Name/Ref. Ind.
Requested by
Received by
TMM sheet prepared by
Approved by
(BPC/1)
Sent to CSM/21- CSM/31
Approved by (*) CSM/21
(CSM/21)
Approved by (*) CSM/31
(CSM/31)
Returned from CSM/21- CSM/31
Corrections made
Final approval
(BPC/1)
(*) provided that the corrections as indicated on the TMM sheet are incorporated.
You are requested to review the attached sheet and make comments as you feel necessary.
If the use of the chemical is acceptable to you, please sign in the box beside ‘Approved by’. I
will then incorporate the changes indicated, get BPC/1 approval and issue a new sheet in the
next TMM update.
BPC/103
cc. BPC/1
SP-1194
REVISION 1.0
Page 38
HSE – SPECIFICATION
Setting Clear Requirements
Appendix D: SHOC Card
Date of issue:
1. Other names:
2. MESC:
4. Composition:
3. Supplier
5. Appearance and odour
6. Usage
7. Physical properties (at 25oC, 1013 mbar)
density (kg/m3):
boiling point (degr. C):
melting point (degr. C):
flashpoint (degr. C):
autoignition temp (degr. C):
flamability limits (% v/v):
rel. vapour density(air=1):
vapour pressure (mbar):
kinematic viscosity (mm2/s):
solubility in water (kg/m3):
pH:
Particle size (micron):
8. Important characteristics
incompatibilities:
occupational exposure limit TLV (ACGIH):
9. Safety hazards
10. Safety precautions
Stability:
:
11. Fire extinguishing agents
12. Fire fighting precautions
13. Health hazards
14. First aid
skin:
:
eyes:
:
ingestion:
:
Fire:
:
inhalation:
:
15. Personal protection
normal usage:
spill control/clean up:
16. Environmental hazards
17. Environmental precautions
18. Spillage mitigation (see also 15)
19. Disposal options
Preferred:
Acceptable:
THE DISPOSAL OPTION TAKEN MUST BE ACCEPTABLE WITHIN THE REQUIREMENTS OF OPERATIVE LEGISLATION
20. Storage
21. Packing and labelling
UN number:
22. Supplementary information
Health:
Safety:
Environment:
SP-1194
REVISION 1.0
Page 39
Label:
HSE – SPECIFICATION
Setting Clear Requirements
Appendix E: Chemical Custodians' Register
Business Unit:........... Area: ...................................................................
Name of Chemical
SP-1194
REVISION 1.0
Designated
Use/Location
Page 40
Date
Sheet: ..../of .....
SHOC Number
Chemical Custodian
HSE – SPECIFICATION
Setting Clear Requirements
Appendix F: Container Packing & Storage Guide
2.2
2.3
3
4.1
4.2
4.3
5.1
5.2
6.1
6.2
8
8
6.2
6.1
5.2
5.1
4.3
4.2
4.1
3
2.3
2.2
2.1
2.1
No segregation
necessary
complete
2.1 - Flammable gases
2.2 - Non toxic, non flammable gases
2.3 - Poisonous gases
3 - Flammable liquids
4.1 - Flammable solids
4.2 - Spontaneously combustible substances
Document Ref. TOM/03/000.a2 - 1
SP-1194
REVISION 1.0
Separate by a complete
compartment
Separate bywith
a a distance
greater than 2m apart
Separate by at least
2m apart
4.3 - Substances dangerous when wet
5.1 - Oxidising substances
5.2 - Organic paroxides
6.1 - Poisons
6.2 - Infectious substances
8 - corrosives
(pack-gd.ppt)
Page 41
Issued: 03-09-97
HSE – SPECIFICATION
Setting Clear Requirements
Appendix G: Hazard Symbols
Hazards
Protection
First Aid
SP-1194
REVISION 1.0
Page 42
HSE – SPECIFICATION
Setting Clear Requirements
Appendix H: Map of Western Water Supply Well Field Protection Zones
SP-1194
REVISION 1.0
Page 43