AVAT (ARMAN) TAHERPOUR
1,2,*
, SEPEHR TABAN
3 and AKO YARI
1
1
Department of Organic Chemistry, Faculty of Chemistry, Razi University, P.O.Box: 67149-
67346, Kermanshah, Iran
2
Medical Biology Research Center, Kermanshah University of Medical Sciences, Kermanshah,
Iran
3
Chemistry Department, Science Faculty, Islamic Azad University, Arak Branch, P.O.Box 38135-
567, Arak, Iran e-mail: avatarman.taherpour@gmail.com
Table of contents:
S1: The
1
H-nmr spectrum aromatic patterns of phenylacetylene (1) and 1-Phenylacethylene (2) as the product.
S2: The GC and Mass spectrum of 1-Phenylacethylene (2) synthesized by the one-pot solvent free catalytic dimerization of phenylacetylene (1) and Cu/C in room temperature.
S3: The copper component on Cu/C catalyst due to EDS analysis.
S4: Another SEM image of copper-impregnated Carbone (Cu/C) catalyst in scale of 10µm.
Some of the information about the
1
H-NMR and GC-Mass spectra of phenyl-acetylene ( 1 ), 1phenylnaphtalene ( 2 ) and the one of the SEM of Cu/C catalyst was shown in the supplementary information. The
1
H-NMR shows the changes of the spectrum of phenyl-acetylene ( 1 ) and 1phenylnaphtalene ( 2 ). See S1. S2 shows the GC and Mass spectrum of 1-Phenylacethylene (2) synthesized by the one-pot solvent free catalytic dimerization of phenylacetylene (1) and Cu/C in room temperature. See S1 and S2. In S3 has shown the copper component on Cu/C catalyst due to
EDS analysis. One of the SEM pictures was shown in the supplementary information. See S4. The
SEM image has demonstrated the copper-impregnated Carbone (Cu/C) catalyst in scale of 10µm.

S1: The
1
H-nmr spectrum aromatic patterns of phenylacetylene (1) and 1-Phenylacethylene (2) as the product.

S2: The GC and Mass spectrum of 1-Phenylacethylene (2) synthesized by the one-pot solvent free catalytic dimerization of phenylacetylene (1) and Cu/C in room temperature.

S3: The copper component on Cu/C catalyst due to EDS analysis.

S4: Another SEM image of copper-impregnated Carbone (Cu/C) catalyst in scale of
10µm.