25. Composition stoichemisrty- composition stoichemistry describes the quantitative relationships among elements in compounds. It can be used to determine the number of atom present in a collection of molecules and the masses of each. For example, composition stoichiometry describes the nitrogen to hydrogen (mass) relationship in the compound ammonia: ie., one mole of nitrogren and three moles of hydrogen are in every mole of ammonia. 26. Reaction stoichemistry- describes the quantitative relationships among substances as they participate in chemical reactions. An example is when reaction stoichiometry describes the 1:3:2 ratios of molecules of nitrogen, hydrogen, and ammonia. 27. mole ratio- The coefficients in a balanced equation can be used to write a molar ratio. Molar ratios are conversion factors that can be used to relate: 1. moles of product formed from a certain number of moles of reactant 2. moles of reactant needed to form a certain number of moles of a product. 3. the number of moles of a particular reactant needed to completely react with a certain number of moles of a second reactant. For the following reaction: 4 NH3 (g) + 5 O2 (g) --> 4 NO (g) + 6 H2O (g) the following molar ratios can be written: 4 moles NH3 4 moles NH3 4 moles NH3 5 moles O2 4 moles NO 6 moles H2O 5 moles O2 5 moles O2 4 moles NO 4 moles NO 6 moles H2O 6 moles H2O 28. mole ratio- You need the balanced symbol equation for the reaction. The numbers in front of the formulae show the mole ratios. For example, in the thermal decomposition of calcium carbonate: CaCO3 --> CaO + CO2 The equation is balanced. The mole ratio between CaCO3 and CO2 is 1:1 because there is 1 mole of CaCO3 for every mole of CO2 29. Mole A > mole B Ratio (pg. 360) Example: How many mole of water are made when 16.4 mol of Oxygen are used? First you have to use the 5 Step methods: Given, Find, Plug In, and Solve. And the Bala Given: 16.4 mol of Oxygen Find: moles of water Plug In/ Solve: 16.4 mol O2 1 x 2 mol H2O = 32.8 mol H2O 1 molO2 30- 31. Gram A > gram B Ration (pg. 361 their will be two problems) Example: Calculate the number of grams of NH3 produced by the reaction of 54.0g of hydrogen with an excess of nitrogen. First you have to use the 5 Step methods: Given, Find, Plug In, and Solve. And the Balanced Equa Given: 54.0g H2, 3molH2 (From Balanced Equation), 1 mol H2 (molar mass), and 1 mol NH3= 17.0 (molar mass) Molar Mass: H2 H2: 1.01 x 2= 2.0 Molar Mass: NH3 N: 14.0 x 1= 14.0 H3: 1.01x 3= 3.0 = 17.0 Find: mass of ammonia= gNH3 Plug In/ Solve: 54.0 x 1mol H2 x 2.0 mol NH3 x 17.0 gNH3 = 31g NH3 2.0 gH2 32. Mol A > gram B (pg. 370) 3.0 mol H2 1 mol NH3 Example: What is the maximum number of grams of Cu2S that can be formed when 80.0 g Cu reacts with 25.0 g S? which is limiting? First you have to use the 5 Step methods: Given, Find, Plug In, and Solve. And Convert “givens” to moles: Given: 80gCu, 25.0gS Find: which is limiting 80gCu x 1 molCu 1 63.55gCu 25.0gS x 1molS 1 = 1.26 molCu = 0.78 molS 32.06 Plug In/ Solve: 1.26 molCu x 1molS 1 = 0.63 molS 2molCu Copper Is Limiting 33) Limiting Reactant- The reagent that determines the amount of product that can be formed by a reaction. Example: NH3, the limiting reactant would be hydrogen because it is completely used up. 34) Excess reactant- The reactant that is not completely used up in a reaction. Example: NH3, the excess reactant would be nitrogen because it is not entirely used up. 35) mol A mol B Mole Ratio- A conversion factor derived from the coefficients of a balanced chemical equation interpreted in terms of moles. 1) Find the balanced equation 2) State the given 3) State what you need to find 4) Use the mole-mole calculations to solve (Given x mole ratio= Answer) 36) G A mol B 1) Find the balanaced equation 2) State the given 3) State what you need to find 4) Find the molar mass of the given 5) Use the mole-mole calculations to solve 37) Finding the limiting reactant Limiting Reactant- The reagent that determines the amount of product that can be formed by a reaction. 1) State the two given 2) Find the balanced equation 3) Find the molar mass of each given, you will have two answers 4) Use the statement, “How many of __(have)___ would I need to use up all the _(need)__.” (This will help determine if your answer will be excess or limiting) 5) Use the mole-mole calculations to solve 6) If your answer is more than what you “have” your answer will be excess, therefore the other answer will be stated as “limiting”