Petrol. 186-212B; Francis, 2014 PETROLOGY LAB 4: Plutonic Igneous Rocks Plutonic rocks occur in intrusions that have crystallized within the Earth’s crust or at the crustmantle boundary. They are commonly recognized by their coarser grain-size in comparison to volcanic rocks, indicating crystallization at slower cooling rates. Plutonic rocks are classified according to their modal mineralogy: Figure 4.1 1 Petrol. 186-212B; Francis, 2014 Station A - Ultramafic Rocks: The samples at this station are ultramafic rocks, that is they contain over 85 % mafic minerals, and feldspar is either absent or so low in abundance that it can not be seen in hand specimen. If present, feldspar is always an interstitial mineral. Most ultramafic plutonic rocks are at least in part cumulates. They do not represent silicate melts, but rather the accumulation of crystals that have crystallized from a silicate melt in a magma chamber, along the walls of a dyke, etc. Cumulate rocks are generally characterized by their low number of prominent mineral species (1-3) and the common presence of layering in terms of variations in modal mineralogy and sometimes grain-size. Layering in an olivine and chromite cumulate The cumulus minerals represent early crystals that accumulated from a magma to form the framework of the rock and are typically sub-equant in habit. 2 Petrol. 186-212B; Francis, 2014 Inter-cumulus minerals crystallize from the residual trapped liquid between the cumulus crystals. They are typically anhedral and occur as either small crystals interstitial to the larger cumulus minerals, or as large oikocrysts that poikilitically enclose smaller chadocrysts of earlier cumulus minerals. Some cumulate rocks can be recognized in hand specimen by the "flash" of large oikocryst cleavage surfaces containing numerous chadocryst inclusions when the sample is rotated in the light. Olivine chadocrysts in an orthopyroxene oikocryst: Some ultramafic rocks, however, are restites; representing the residual solid left behind after the extraction of partial melts. They commonly display recrystallized granular textures, and lack oikocrysts. They commonly display tectonic textures such as mineral lineations For each rock, identify as many minerals as you can and classify it according to Fig. 4-2. In addition, try to distinguish cumulus minerals from inter-cumulus minerals, and thus the order in which the minerals in the rock crystallised. Orthopyroxene can be recognised by its brownish green to brownish-black colour and prominent woody parting (100). Clinopyroxene is typically green to greenish black, and characterised by a prominent pearly smooth parting (001). Olivine is typically present as equant grains, but its colour can be tricky because it is very susceptible to alteration. When fresh it is light glassy green in colour. If partially altered to serpentine, it is typically black because of the presence of fine-grained magnetite. If oxidised, especially on weathered surfaces, it is commonly reddish brown in colour. Don’t be discouraged if you can’t always identify the minerals. Olivine-rich rocks in which clinopyroxene and/or orthopyroxene cannot be distinguished are best called by the more general name peridotite. In the field, especially if the rock is altered, often all you can say is that the rock is ultramafic. 3 Petrol. 186-212B; Francis, 2014 Station B - Mafic Rocks: All the samples at this station are mafic or ‘gabbroic’ rocks. They contain more than 15%, but less than 60% feldspar. Determine the mineralogy of each of these rocks and classify them according to Figure 4-3. Where possible, distinguish cumulate minerals from intercumulus minerals and try to estimate the order in which the minerals crystallised. If hornblende is present in moderate amounts, then the prefix hormblende is used: hornblende gabbro, hornblende peridotite, etc. Mafic igneous rocks with over 60% hornblende are termed hornblendites The term amphibolite is reserved for amphibole-rich metamorphic rocks. 4 Petrol. 186-212B; Francis, 2014 Station C - Intermediate to Felsic Plutonic Rocks: At this station you will see plutonic rocks with intermediate to felsic whole-rock compositions: diorite, granodiorite, tonalite, monzonite, granite, syenite, and nepheline syenite. Determine their mineral assemblages and use Figure 4-4 to classify the specimens. In which rock types are hornblende or biotite the predominant mafic minerals? Can you see differences in grain size? What can you say about the cooling rate of the samples? The mineralogy of felsic igneous rocks is strongly dependent on silica activity. In silica-saturated rocks, quartz is relatively abundant, whereas in silica-undersaturated rocks quartz does not occur, but feldspathoids are present. Near the silica saturation boundary, syenites typically contain either small quantities of quartz or feldspathoids (but never both), which commonly cannot be detected in hand specimen. The rocks at this station are either silica-saturated granites, silicaundersaturated nepheline syenites or syenites. Classify the specimens according to Figure 4-4 by identify the mineral assemblage present in each specimen. 5 Petrol. 186-212B; Francis, 2014 Station D – Hypersolvus versus Subsolvus Granites Water pressure (PH2O) is an important variable in the crystallization of plutonic rocks and two types of granites with texturally different feldspars can be distinguished depending on the water pressure at which the rock crystallized. In subsolvus granites (water pressures greater 5 kb) two distinct types of feldspar are present, which may have undergone subsequent exsolution. In hypersolvus granites crystallization at relatively low water pressures ( 4kb) results in the formation of a single feldspar that may become perthitic at subsolidus temperatures. Note that both subsolvus and hypersolvus granites require high Na/Ca ratios. Identify the feldspars in the specimens at this station and determine whether these rocks are subsolvus or hypersolvus granites. 6 Petrol. 186-212B; Francis, 2014 Station E – Granites by Source Type: The tectonic environment of granite formation can be determined by analyzing the composition of the granitic rocks. S-type granites are generated during partial melting processes (anatexis) in the continental crust. Their precursor rocks are aluminous metasediments and therefore S-type granites are typically rich in muscovite and may contain alumino-silicates (kyanite, sillimanite), and/or garnet. Biotite may also be present. S-type granites are typically peraluminous in composition. I-type granites originate from mantle-derived magmas or due to partial melting of mafic igneous rocks. They typically contain hornblende and/or biotite as mafic minerals. A-type granites (anorogenic) are relatively rare and not associated with regional metamorphism or convergent plate tectonics. Their protolith is granulitic lower crust and they are generated in an extensional within-plate tectonic regime. A-type granites are typically peralkaline in composition, containing sodic amphibole or pyroxene as their accessory mafic mineral, and typically do not contain mica. The samples at this station represent a mix of S and I type granites. See if you can distinguish them on the basis of the mineralogy. 7 Petrol. 186-212B; Francis, 2014 Characterisitics of Granitoid Suites Feature Rock Types : Mafic Minerals: A -Type I - Type S - Type granite tonalite to granite granodiorite to granite hornblende biotite muscovite biotite Na-amphibole Na-pyroxene Accessories: fluorite topaz tourmaline Oxide: ilmenite magnetite ilmenite Feldspar : perthite hypersolvus K-spar and plag subsolvus K-spar and plag subsolvus (Na+K)/Al: garnet Al-silicates cordierite corundum >1 per-alkaline <1 << 1 (Na+K+Ca×2)/Al: >> 1 >1 meta-aluminous <1 per-aluminous Restite/ Enclaves: few amphibolite biotite-cordierite sillimanite-garnet gneiss Source Regions: granulitic lower crust with halogen volatile flux mafic igneous rocks or mantle-derived magmas (M) sedimentary rocks Tectonic Setting: extensional within-plate compressional volcanic arcs, extensional interpolate compressional continental collisions 8 Petrol. 186-212B; Francis, 2014 Station F: Porphyry Dykes High level dykes and sills are typically finegrained and commonly difficult to distinguish from the massive portions of thick flows without their field context. If contacts are exposed, sills can be distinguished from flows by the presence of symmetric finer-grained quenched margins, as opposed to the thick upper quench and thin lower quench zones of flows. Cross cutting field relationships are indicative of dykes. High-level dykes are commonly porphyritic with larger phenocrysts of crystals that grew before emplacement enclosed in a finer grained matrix that reflects rapid cooling at the shallow site of emplacement. Felsic Dykes: Quartz feldspar porphyry rhyolite dykes (QFP dykes) are especially important as they are commonly associated with porphyry copper and gold mineralization in volcanic terranes. Without field context, it may be difficult to decide if a quartz-feldspar-phyric felsic rock is a dyke or the massive portion of a lava flow. Often it is best to indicate the phenocryst assemblage in a prefix, and simply call the rock a felsite, eg feldspar-phyric felsite. The presence of quartz phenocrysts is indicative of a rhyolitic composition. Mafic to Intermediate Dykes: Fine-grained mafic dykes that are aphyric or contain phenocrysts of feldspar are commonly simply referred to as basaltic or diabase dykes, or even more generally as mafic or intermediate dykes. If the phenocyrst assemblage does not contain plagioclase, but does contain amphibole, mica, and/or clinopyroxene and olivine, then mafic dykes are likely to be lamprophyres. Lamprophyre dykes commonly have compositions similar to alkaline basalts. If feldspar is absent in the matrix, then the term ultramafic lamprophyre is used. In the field, lamprophyre dykes are best named using a prefix indicating the types of phenocrysts present, eg. hornblendephyric lamprophyre dyke. The presence of hydrous phenocrysts such as hornblende or phlogopite is diagnostic of lamprophyres and the fact that the rock was a high level intrusion rather than a volcanic flow. Water escapes in mafic lavas at the surface, and thus amphibole is typically not stable. The phenocrysts of thin porphyritic mafic dykes are commonly concentrated towards the centre of the dyke by flow differentiation. 9 Petrol. 186-212B; Francis, 2014 Kimberlite: Kimberlite is an ultramafic rock (no feldspar) that is commonly rich in olivine megacrysts. There are many types of kimberlite, ranging from olivine-rich dykes with dark fine-grained matices (hypabyssal facies), which resemble ultramafic lamprophyres in hand specimen, to polymictic beccias that contain fragments of both the mantle (olivine-rich xenoliths) and the crustal rocks they intrude (diatreme facies). Kimberlite dykes are best distinguished from lamprophrye dykes by the presence of purple-red garnet and brown phlogopite megacrysts. Kimberlite dykes are rare, but their importance comes from the fact that they are the host rocks for diamonds. pyropic garnet & phlogopite 10