VALDOSTA STATE UNIVERSITY Chemistry Department Summer 2009 Course Prefix and Number: CHEM 1211, Principles of Chemistry I Contact/Credit: 3 lecture/3 credit hours This course is a 3 hr credit course; you need to dedicate 4 hrs per each credit hour, 3 x 4 = 12. Because in summer there is less time than in a regular semester, this is an intensive course where you are expected to dedicate about twice the time (24 hrs): ~5 hours we spend in class, you have 19 hr to study at home, about 4 hr x 5 times / week. Catalog Course Description: This course is an introduction to a quantitative study of the physical and chemical behavior of matter in its several phases and a consideration of modern theories of bonding forces at the molecular level. Atomic and molecular structure, chemical nomenclature, stoichiometry, thermochemistry, the gaseous state, and properties of solutions are discussed. Co-requisites: MATH 1111 (OR MATH 1113) & CHEM 1211L Class Location: BSC 3017 Class Times/Days: M-Th, 12:45 – 2:10 pm Instructor: Telephone Number: (229) 333-5340 email: ldelagarza@valdosta.edu website: www.valdosta.edu/~ldelagarza Dr. de la Garza Office Location: BSC 3080 Office Hrs./Days: M, W: 2:15-2:45 pm Any other time by appointment Required Textbook: CHEMISTRY and CHEMICAL REACTIVITY, Kotz, Treichel, Weaver 7th Ed. Additional required Materials: OWL access code (https://owl1.thomsonlearning.com/), instructions for signing in are in Dr. de la Garza website, register ASAP; calculator. Student Outcomes*: Upon successful completion of this course, the student will be able to: 1- Determine the moles and masses of substances consumed or produced in a chemical reaction by using a balanced chemical equation. 2- Predict the structure of a molecule and its hybridization based on its chemical formula. 3- Determine the number of protons, neutrons and electrons in an atom or ion using the periodic table. 4- Identify changes in physical and chemical properties of the element by using the periodic table. 5- Predict the products of fundamental metathesis and oxidation-reduction reactions. 6- Calculate the enthalpy change of a reaction by using the thermodynamics table. 7- Name inorganic compounds or (exert original text) of a name using IUPAC rules. * Refer to specific student outcomes for each chapter in pages 3-4 of this syllabus. Course Requirements: 1-Partial tests: 3 exams will be administered. Please keep up with the material so you don’t get overwhelmed. Also, the material covered in previous chapters is used later on: study from the beginning and don’t skip material. 2- Final exam: the final exam will be given in two comprehensive exams; one of them is a standard test that will contain general and very basic questions of the covered material. Students who do not take the final exams will fail the course (F), students who make 35% or less on either exam will have a drop in the letter grade (if your final average is 80 = B, but you made 35 or less on the final your final grade will be a C, etc). 3- Homework: 14 required OWL assignments (online - homework tutors) are assigned throughout the semester. You will need to read the book and study before you attempt them. Make sure that you know how to solve these types of problems and the concepts they involve (as the concepts will be included in exams). Please complete them by their due date. Complete instructions on pages 3-4 of this syllabus. 1 4- Quizzes: ~6 quizzes will be given throughout the semester with concepts and topics to be addressed in tests. 5- Participation: collaboration on discussion, answering questions, asking questions, solving problems, etc. is part of everyday class activities. 6- Written report: essay on chemistry, chemistry personalities, and current issues. All reports will be published online and graded by the peers and instructor. Complete instructions on separate handout. Academic Honesty: Academic honesty will be enforced. Any plagiarism, fraud, or cheating will result on a 0 (zero) in the project, homework, test, essay, etc. and it will be reported to the Student Conduct Office in the Dean of Students Office and will be kept on student’s records. Information about policies and procedures at: http://www.valdosta.edu/academic/AcademicHonestyPoliciesandProcedures.shtml Disability Access Statement: Students requesting classroom accommodations or modifications because of a documented disability should contact the Access Office for Students with Disabilities located in Room 1115 Nevins Hall. The phone numbers are 245-2498 (voice) and 219-1348 (TTY). Any needs must be discussed with the professor at the beginning of the term. Attendance: Lecture attendance is required. Students are to be seated when lecture begins. In accordance with VSU policy, 20% or more absences can result in a course grade of F. It is responsibility of the student to drop a course they choose not to attend. NO food allowed during the lecture. CELL phones and pagers must be OFF during lecture. No hats allowed during examinations. Evaluation of Performance: 42% = Three partial exams (14% each exam) 20% = Final exam (two parts will be averaged) 12% = Written report 14% = OWL Homework (1% each chapter) 6% = Participation 6% = Quizzes 100 + up to 10 extra points (for 80% OWL extra point problems) Grading Scale: Grade A B C D F Numerical Points 90 and higher 80-89 70-79 60-69 59 and lower Course Outline and Tentative Schedule (subject to change): Week of June 8 June 15 June 22 June 29 July 6 July 13 July 20 July 27 Lecture Assignments due (OWL Chapters)___ Basic Concepts & Tools / Interchapter p. 338 Ch 1, Tools due Mon Jun 15 Atoms, Molec & Ions / Chem Reactions Ch 2 due Wed Jun 17, 3 due Mon Jun22 Chem Reactions / Stoichiometry Ch 4 due Tue Jun 30 Stoichiometry / Energy Ch 5 due Mon Jul 6 Structure of Atoms / Periodic Trends Ch 6 due Fr Jul 10, 7 due Tue Jul 14 Bonding & Structure / Hybrid & Molecular Orb Ch 8, 9 due Mon Jul 20 Ch 10** due Th Jul 23 Gases / Intermolecular Forces & Liquids Ch 11, 12 due Mon Jul 27 Solids / Solutions Ch 13, 14 due Wed Jul 29 ** Chapter 10 is recommended reading / OWL hmk required. Please keep up with the material, if you need HELP please see me in office hours or by appointment (and please honor your appointments). Laboratory time is an important part of your practice. Attend to the laboratory experiments for a different way to learn the material. Very important labs for class will be posted on my website. Student Success Center has tutors available: http://www.valdosta.edu/ssc/ 2 Exam dates EXAM I will be given on Tuesday June 23, 2009 (chapters 1, Tools, 2 and part of 3) EXAM II will be given on Wednesday July 8, 2009 (chapters 3, 4, 5) EXAM III will be given on Tuesday July 21, 2009 (chapters 6, 7, 8, 9) FINAL EXAM Part 1 will be given on Wednesday July 29, 2009 (comprehensive) Part 2 will be given on Thursday July 30, 2009 at 2 to 4 pm (comprehensive). Make up exams or quizzes will NOT be given. * Any emergency needs to be informed to the Office of Students Affairs (phone: 333-5359). Important dates: Wed Jun 10 - First day of classes Thursday Jul 2 – Midterm (last day to drop the course) Monday Jul 6 - No classes Wed Jul 29 - Last day of classes, final exam (chapters 1 to 14) Thursday Jul 30 - Final exam (standardized examination – cumulative) Instructions for Take-home assignments on OWL: Fourteen (14) OWL assignments are assigned throughout the semester. Only the “End of Chapter Questions – Homework Tutors” are required, the other OWL exercises are for extra-points or optional. Submit your answer on the OWL web-site for the corresponding homework tutors before the due date. Due times might change; check your OWL website continuously. START WORKING ON PROBLEMS AS THE MATERIAL IS COVERED, DO NOT WAIT UNTIL LAST DAY TO SUBMIT ANSWERS! Below are the SAME or SIMILAR required questions for each chapter with their textbook number, so in case you do not have online access at home, you can work on the problems and then submit your answers before the due date using a school computer (not guaranteed and in extreme situations you may submit your written work for credit). Chapter 1: Basic Concepts (7 exercises) Study questions Ed 7: on page 20: 2, 4, 6, 8, 10, 19, 37 Let’s Review: Tools (10 exercises) Study questions Ed 7: on page 43: 3, 10, 14, 16, 18, 20, 32, 34, 40, 60 Chapter 2: Atoms and Elements (26 exercises) Study questions Ed 7 on page 100: # 2, 4, 5, 8, 10, 15, 21, 23, 29, 33, 35, 36, 41, 43, 49, 51, 53, 55, 57, 59, 61, 67, 71, 76, 105, 141 Chapter 3: Chemical Reactions (24 exercises) Study questions Ed 7 on page 152: # 2, 4, 9, 11, 13, 15, 19, 21, 26, 28, 33, 34, 37, 39, 41, 44, 45, 46, 48, 52, 63, 68, 73, 76 Specific objectives: Upon successful completion of this section, the student will be able to: 12345678- Use the Kinetic Molecular Theory to describe the physical states of matter; Perform density calculations; Recognize between intensive and extensive properties; Recognize between accuracy and precision; Use the periodic table to find elements; Recognize ionic vs. molecular compounds; Recognize polyatomic ions; Give the names and symbols of elements and names and formulas of compounds; 9101112131415- Perform calculations with isotopes and atomic weight; Perform % mass composition calculations; Explain how soluble ionic compounds are dissolved in water; Recognize soluble vs. insoluble compounds; Write net ionic equations; Classify reactions by their type (precipitation, acid-base, gas evolution, redox); Find the oxidation number of atoms in given compounds. Chapter 4: Stoichiometry (18 exercises) Study questions Ed 7 on page 195: # 2, 5, 8, 12, 16, 19, 29, 37, 39, 41, 46, 47, 54, 55, 62, 67, 71, 106 Chapter 5: Energy (14 exercises) Study questions Ed 7 on page 242: # 8, 10, 12, 18, 20, 21, 24, 28, 30, 34, 44, 46, 54, 79 3 Specific objectives: Upon successful completion of this section, the 1- Perform molarity calculations; 62- Use the mole concept to perform stoichiometric and limiting reactant calculations. 783- Explain the difference between temperature and heat; 4- Perform heat and specific heat calculations; 5- Draw heat vs. T diagrams; student will be able to: Use the First Law of Thermodynamics to classify chemical reactions in exothermic vs. endothermic reactions; Know what is a State Function; Perform enthalpy (H) calculations using the Hess’s Law and using standard enthalpy of formation values. Chapter 6: Atomic Structure (15 exercises) Study questions Ed 7 on page 297: # 1, 3, 9, 18, 28, 32, 34, 36, 40, 44, 51, 60, 62, 67, 78. Chapter 7: Electron Configuration (16 exercises) Study questions Ed 7 on page 332: # 2, 6, 11, 18, 20, 24, 26, 28, 30, 32, 40, 41, 44, 56, 59, 64. Chapter 8: Bonding (16 exercises) Study questions Ed 7 on page 395: # 6, 10, 12, 14, 18, 27, 28, 29, 34, 38, 42, 47, 50, 53, 56, 86. Chapter 9: Molecular Orbitals (10 exercises) Study questions Ed 7 on page 434: # 3, 4, 11, 12, 14, 22, 23, 34, 44, 54. Chapter 10: Carbon Compounds (2 exercises) Study questions Ed 7 on page 488: # 51, 95. Specific objectives: Upon successful completion of this section, the student will be able to: 1- Perform frequency/wavelength calculations; 10- Identify different types of bonds; 2- Know the electromagnetic spectrum; 11- Use the periodic table to predict properties 3- Identify quantum numbers and give their applying periodic trends; meaning; 12- Classify substances as polar or nonpolar; 4- Know the types of orbitals and how they are 13- Perform enthalpy calculations using bond represented by quantum numbers; strength data; 5- Find valance electrons of atoms; 14- Give the hybridization of the center atom in 6- Write electronic configurations of atoms and simple molecules or ions based on MO; ions or find the atom or ion form the 15- Use the Law of Conservation of Matter to electronic configuration; balance chemical equations, specially 7- Explain the periodic trends: AR, IE, EA and the combustion reactions; relations between them; 16- Identify the types of organic groups; 8- Use the periodic table to predict properties 17- Know the properties of carbohydrates and applying periodic trends. polymers. 9- Draw Lewis dot structures and give the electronic and molecular geometry of simple molecules or ions using VSEPR theory; Chapter 11: Gases (12 exercises) Study questions Ed 7 on page 546: # 1, 6, 12, 18, 22, 24, 32, 34, 39, 41, 45, 65. Chapter 12: Intermolecular Forces & Liquids (12 exercises) Study questions Ed 7 on page 581: # 2, 4, 6, 8, 14, 17, 18, 20, 25, 28, 39, 41. Chapter 13: Solids (6 exercises) Study questions Ed 7 on page 581: # 11, 13, 14, 20, 22, 26. Chapter 14: Solutions (10 exercises) Study questions Ed 7 on page 648: # 6, 13, 28, 32, 41, 53, 58, 60, 93, 96. Specific objectives: Upon successful completion of this section, the student will be able to: 1- Explain the KMT of gases; 6- Classify substances as solids, liquids, or gas; 2- Perform calculations using gas laws 7- Classify solids by their type; equations; 3- Describe properties of gases; 8- Draw simple unit cells; 4- Identify the types of intermolecular forces 9- Perform molality calculations; present in various chemicals; 10- Perform calculations for the colligative 5- Describe properties of liquids (especially properties and their applications. water); 4