CE 527 Solid Waste Management Materials Recovery (Chapter 9 and 12 of textbook) Dr. S.K. Ong 1. Materials Recovery Facilities (MRF) - are defined as a centralized operation where commingled and/or source separated recyclables are processed mechanically or manually. - prepare the recyclables to meet market specifications for sale Relatively new in the solid waste management field - first MRF was established in Groton, Connecticut in the late 1970s (USEPA, 1991), still operating but does not accept paper or plastic stream - in 1990, there are about 104 MRFs identified (US EPA, 1991) Separation of waste materials is a necessary operation of materials recovery. There are generally two types of MRF: - MRFs for source separated wastes, e.g., curbside programs - MRFs for commingled MSW- waste separated manually or mechanically on site into various groups Advantages of MRF - allows recyclable materials from a municipality or region to be pooled and processed uniformly to meet buyers' specification, provide the needed volume and constant source of materials and to maximize recycling and recovery of materials - collection needs are usually simplified as separation are done at the MRF - instead of several compartment as for curb side recycling, a single or two compartments will be needed - collection time and costs reduced - increased participation by generators - reduce MSW going to landfills Disadvantages - may discourage generators from reducing waste - high start up cost 2. Engineering Consideration Design of MRF requires the estimation of quantities of materials that can be recovered and the appropriate design loading rates. Loading rates (tons/day) are used to select and size equipment properly. 3. Typical Process Flow Diagram - consists of unit operations and facilities to achieve a specified waste generation goal or goals - typical flow diagrams for source separation see Figure 2 – 5 and 6-34 (notes), Fig. 9 – 28 (book) Will discuss several unit operations within the processing facility. They are: 1 4. Size Reduction - reduce size of materials so that the materials can be handled efficiently by conventional processing and materials handling equipment - breaks and expose materials so that they can be separated and recovered - shredded materials/waste burns more readily increasing its value as a fuel - size reduction equipment developed originally for mining industry where the materials is for homogeneous feed - terms typically used are shredding, milling and grinding Type of Equipment - _________________________(horizontal shaft or vertical shaft) - central rotor with pinned radial hammers that are free to swing - horizontal hammer mill comes with a discharged grate below the rotor which determines the size of the product - vertical hammer mills moves materials by gravity down the sides of the housing with larger clearances between the housing at the top of the mill and progressively narrows towards the bottom (sometimes they are called grinders) - widely used for refuse shredding - high maintenance for rebuilding and replacing hammers _______________________ - have two counter-rotating blades or knives that cut and shear the waste - low speed devices - excellent for plastics, tin cans and ductile materials ______________________ - solid waste and water added - cutting blade and rotor converts materials to pulp - solids content of slurry is 2.5 to 3.5% range. - hydropulper common for materials separation in paper recycling and as a front end for biogasification of materials 4.1 Selection of Hammer mills - most hammer mills selection is conducted through trial runs - models have been developed to predict final particles size distribution for a given input. But because of the heterogeneous nature of SW, most of the models are very specific and cannot be universally applied (see Savage et al., 1986. Unit Operations Models for Solid Waste Processing, Noyes Publication) The most widely used particle size descriptor is the Rosin-Rammler model, first proposed in 1933. The equation is a generalized expression for sigmoidal curves. Y = 1 – exp(-x/xo)n Where n = constant, xo is the characteristic particle size defined as the size at which 63.2% (1 – 1/e = 0.632) of the particles (by weight) are smaller. The linear form is written as log [ ln (1/1-Y)] = n [log x – log xo] - two important parameters are used, mass loading (ton/hr) and power requirements - Hammermills are highly ineffieicnet with only 0.1 % to 2.0% of the energy supplied appearing as increased surface energy of the product solids. - Power requirements for shredding can be modeled using empirical relationships or form manufacturers' literature - common equations include: 2 dE CL n dL where E is the energy required per ton/hour of materials processed (hp. hr/ton) L is the particle size C and n are constants The equation assumes that the energy needed to achieve a small size change of dL in a unit mass of materials is inversely proportional to the size of the particle L If n = 1, then integrating dE CL 1 dL E = C log(L1/L2) where (L1/L2) is the size reduction ratio, E is the work done to reduce the size from L 1 to L2. This is also known as the _______________________ If n = 2, we have E = C (1/L2 - 1/L1) _________________________ Rittinger's law agrees better with rough grinding operations Kick's Law - better approximation for fine grinding For n = 1.5, the general equation becomes the Bond Law where it is assumed that the work done in crushing and grinding is directly proportional to the total length of new cracks formed in the materials being reduced in size. E Ei LF Lp LF 100 Lp 1 1 E 10 E i Lp LF where E = specific work (kWh/ton) required to reduce a unit weight of material with 80% finer than some diameter LF in micrometers, to a product with 80% finer than some diameter Lp in micrometers. Ei is the Bond Work Index, a factor that is a function of the materials processes. or Work Indices for common industrial materials are tabulated below Materials Coal Glass Granite Slag Refuse Paper Aluminum cans Work Index (kWh/ton) The rotor of shredders are usually expressed as WR2 where W is the mass of the rotor assembly and R the radius of the hammermill tips. A wide range of WR2 is offered by manufacturers from about 50,000 to 150,000 lb-ft2. Typically a shredder for MSW has a width/diameter ratio greater than 1.0, a hammer weight of 150 lb, arotor inertia of 35,000 lb-ft2, a hammer tip speed of 14,000 ft/min. As a rule of thumb a MSW shredder must be designed for at least 15 kWh/ton/ 3 4.2 Environmental Issues - Noise: A 3 ton/hr hammer mill produces 95 - 100 dBA (normal grinding sound) plus high impact noises. OSHA requirements limit noise levels to 90 dBA over am 8-hour working day - Dust: possible vector for transmission of pathogens and microorganisms. OSHA standards - 15 mg/m3 of total dust over an 8-hour period. Dust level can be 7 to 13 times higher than OSHA standards. Plate counts near hammer mills may have 20 times more bacterial count than ambient which contains about 880 organisms/m3 of air. - Explosion: from breakage of aerosol cans 5. Size Separation - hand sorting - air separation - screening - magnetic separation - inertial separation - flotation - optical sorting (based on color) - electrostatic separation Separation of a mixture of materials into two or more portions by means of one or more screening surfaces or separation devices usually with a go or no go screen 5.1 Performance Characteristics Performance of size separation equipment can be evaluated in terms of - recovery - purity - efficiency For illustration purposes, if the waste stream has two components, X and Y. Assume input mass a Xo and Yo. After separation, there are two streams: X stream one with more X - X1 and Y1 and Y stream with more Y - X2 and Y2 (see diagram) X1, Y1 Xo, Yo Screen X stream X2, Y2 Y stream 4 Parameter Recovery X Y Comments Possible to have 100% recovery of X but yet have 100% of Y in X stream. Some manufacturer use a different expression called Overall Recovery: X Y1 100 OR X1 1 X 0 Y0 Purity Efficiency Another representation is Worrell's Equation X Y E ( x , y ) 1 2 100 X o Y0 Both expressions are rational of perfect separation occurs, i.e. X1 = X0, Y2 = Yo, then efficiency is equal to 100%. 5.2 Most common Screens for Separating MSW - Rotary Drum or Trommel - inclined cylinder mounted in rollers with holes/slots in the side -roll at slow speed of 10 to 15 rpm - works by allowing refuse in the screen to tumble around until the smaller pieces find themselves next to the apertures and fall through - can visualize tumbling motion as consisting of three types: - cascading - cataracting - centrifuging - cascading - the charge is lifted up by the circular motion of the screen and then tumbles down on top of the layer heading upward - cataracting - speed sufficiently great to actually fling the material into the air where it drops along a parabolic trajectory back to the bottom of the screen. Greatest turbulence is achieved and machine should achieve good efficiency for materials separation. - centrifuging - materials adhere to the drum and does not drop off, low recovery Efficieny of trommel is dependent on: rotational speed, diameter, length, angle of inclination, feed rate, particle shape, particle distribution, screen sizes or slots - Trommels are defined by a critical speed. - assume a particle within the trommel located at angle from the vertical - the forces acting on the particle are - centrifugal force, C; - weight of the particle, W, - the opposing forces are W1 = W cos If C > W1 centrifuging, solid adheres 5 If C < W1 If C = W1 particle will fall off, cascading or cataracting then separation occurs and the particle will leave the surface of the trommel at a given velocity - cataracting Therefore C = W cos C = W (r 2)/g where r = radius (cm) = rotational velocity (rad/s) g = acceleration due to gravity (cm/s) W cos = W (r 2)/g or cos = (r 2)/g substitute = 2 n where n is the speed of the screen in rev/s cos = 4 2 n2 r /g Critical point or last chance for the particle to separate and float in the air is when = 0 or cos = 1 Then 1 = 4 2 n2 r /g or nc = ( g/(42r)1/2 = (1/2 )(g/r)1/2 This is the critical speed, nc. Rotational speed varies from 50 to 80% of the critical speed (approximately 10 to 18 rev/min) See Figures for effects of speed, angle of trommel Diameter of screen needed is given by various empirical equations 11 .36 Q m D 0.5 d b FK v g tan Q D 7.66 where Q = capacity tons/hr = specific gravity of material D = diameter of drum (ins) 0.4 Qm = trommel capacity (lb/s) db = bulk specifc weight of MSW (lb/ft3) = trommel inclination Kv = velocity correction factor (1.35 - 1.85 depending on ) F = fillage factor (0.25 - 0.33) g = 32.2 ft/s 6. Air Classification - separate the light, mostly organic materials from the heavy (mostly inorganic such as glass) - basic premise - the light materials will be caught in an upward current of air and carried by the air while the heavier fraction will drop down - the light fraction is then separated from the air using a cyclone separator (see Figures for typical types of air classifier) - can be a vertical column or one with a zigzag column with 60 or 90 o turns - creates turbulence at the corners, causing further separation or breaking of clumps - See Results - Figures attached. 6