Seasonal mixed layer salt budget of the tropical Atlantic Ocean Gregory R. Foltz, Semyon A. Grodsky*, James A. Carton, and Michael J. McPhaden1 Submitted to Journal of Geophysical Research - Oceans April 8, 2003 Department of Meteorology University of Maryland College Park, MD 20742 1 NOAA/Pacific Marine Environmental Laboratory 7600 Sand Point Way NE Seattle, WA 98115 * corresponding author: senya@atmos.umd.edu Abstract This paper addresses the atmospheric and oceanic causes of the seasonal cycle of mixed layer salinity in the tropical Atlantic based on direct observations and model data. Data sets include up to five years (September 1997 - December 2002) of measurements from moored buoys of the Pilot Research Array in the Tropical Atlantic (PIRATA), near-surface drifting buoys, and a numerical ocean model reanalysis. We analyze the mixed layer salt balance at nine PIRATA mooring locations and find that the seasonal cycles of evaporation, precipitation, entrainment, and mean horizontal salt advection all contribute to seasonal mixed layer salinity variability in the northwest (4º - 15ºN along 38ºW). The balance is similarly complex along the equator. Here precipitation decreases eastward (between 35ºW and 10ºW), while freshening from zonal advection increases eastward. Horizontal eddy advection provides an important source of freshening along the equator during boreal summer and fall, when tropical instability waves are present. Meridional advection, combined with entrainment and vertical turbulent diffusion (we suspect), opposes the freshening effects of precipitation, mean zonal advection, and eddy advection, resulting in a weak seasonal cycle of mixed layer salinity. The balance in the southeast (6 - 10ºS along 10ºW) includes significant contributions from mean horizontal advection. Here our estimates are highly uncertain due to a lack of knowledge of horizontal salinity transport. 1. Introduction Salinity affects the density of seawater, spatial gradients of which affect buoyancy, turbulent mixing, and ocean currents. Recent numerical modeling studies indicate that realistic three-dimensional salinity fields are required in order to accurately represent tropical ocean 2 dynamics and thermodynamics (Cooper, 1988; Carton, 1991; Murtugudde and Busalacchi, 1998; Vialard and Delecluse, 1998). In support of these modeling results, a number of observational studies show that changes in mixed layer salinity can dramatically affect currents and temperature in the tropics through the formation of barrier layers (Lukas and Lindstrom, 1991; Roemmich et al., 1994; Pailler et al., 1999). In this study we use in situ, satellite, and model data to determine the oceanic and atmospheric causes of the seasonal cycle of mixed layer salinity in the tropical Atlantic. The flux of moisture at the ocean’s surface is given by the difference between precipitation and evaporation. The annual mean surface moisture flux in the tropical Atlantic reflects the mean position of the Intertropical Convergence Zone (ITCZ) and the subtropical high-pressure systems. In the southern (south of 5S) and northern (north of 10N) tropical Atlantic, annual mean evaporation exceeds precipitation, while in the latitude band of the ITCZ precipitation dominates, with a (zonally averaged) peak of 20 cm mo-1 near 5N (Yoo and Carton, 1990). Seasonal changes in the surface moisture flux result mainly from latitudinal movements of the ITCZ. The seasonal cycle of evaporation is dominated by the annual harmonic throughout most of the tropical Atlantic, with increasing amplitude toward the subtropics. In the northern tropics, evaporation peaks in boreal winter. In this season, the ITCZ is situated close to its southernmost latitude, with increasing northeast trade winds and decreasing relative humidity northward from the equator. In boreal summer and fall, the ITCZ is located near its northernmost latitude (10 12N), resulting in higher relative humidity, lower wind speed, and less evaporation north of 5N. The seasonal cycle of evaporation in the southern tropics is similar in amplitude, but opposite in phase, to that in the north; maximum evaporation occurs in boreal summer, when the 3 southeast trade winds are strong and relative humidity is low. Along the equator in the eastern basin, wind speed and relative humidity change very little on a seasonal basis, resulting in weak seasonal variations of evaporation, while in the west a significant annual harmonic appears, with maximum in late boreal summer. Between the equator and 8N the double passage of the ITCZ results in a significant semiannual harmonic, with highest amplitude in the west (da Silva et al., 1994). The seasonal cycle of precipitation in the tropical Atlantic results from meridional movements of the ITCZ and zonal shifts of convergence within it. In April, a band of high precipitation (> 20 cm mo-1) is situated west of 30W between 5S and 5N, increasing westward toward the coast of South America. Precipitation is also high (> 15 cm mo-1) at this time in the Gulf of Guinea, increasing eastward along the equator toward the African coast. During May through August the zonal band of high rainfall (> 20 cm mo-1) shifts northward and increases in intensity to up to 60 cm mo-1 near the African coast. From September through March, the ITCZ drifts southward from its northernmost latitude (~ 10-12N during August), while the region of high rainfall decreases in intensity and becomes increasingly concentrated in the western basin. As a result, the seasonal cycle of precipitation acquires a significant semiannual harmonic near 5N, with maxima in June and December. In addition to the surface moisture flux, ocean dynamics can affect mixed layer salinity. Near-surface currents in the tropical Atlantic are dominated by the westward South Equatorial Current south of 5N and the eastward North Equatorial Countercurrent centered near 5N (see Fig. 1). The intensity of these zonal currents fluctuates seasonally in response to the seasonal movement of the ITCZ and associated changes in near-surface wind stress. Near the equator, the South Equatorial Current is strongest in boreal summer, with speeds exceeding 50 cm s-1 in mid 4 basin. On and just north of the equator are found strong velocity and temperature fluctuations associated with tropical instability waves, which we anticipate are also important in mixing salinity. Near the western boundary, the South Equatorial Current feeds the North Brazil Current, which flows continuously northward toward the Caribbean during boreal winter and spring. In boreal summer and fall, the North Brazil Current curves back upon itself near 8N, then flows eastward to feed the North Equatorial Countercurrent. In the process, strong eddies form in the western basin between the equator and 10N (Richardson and Reverdin, 1987). These eddies have little effect on sea surface temperature (SST) due to weak gradients of SST in the western basin. However, we anticipate that they may have a significant effect on mixed layer salinity. The annual mean spatial distribution of sea surface salinity (SSS) in the tropical Atlantic (see Fig. 1) to a large extent reflects the annual mean surface moisture flux and river outflow. SSS is highest in the subtropics (> 36 psu), where evaporation exceeds precipitation, and decreases to a minimum near 5N (< 35 psu in the east), where precipitation reaches a maximum (> 17 cm mo-1). In the eastern basin, salinity is low (< 35 psu) in the Gulf of Guinea, where annual mean precipitation and river outflow are high, and increases southwestward toward the subtropics. Although the surface moisture flux contributes significantly to the annual mixed layer salinity budget in the tropical Atlantic, horizontal advection also plays an important role. Indeed, Johnson et al. (2002) found that a substantial portion of the annual mean freshwater flux in the tropical oceans is balanced by oceanic transports within the surface layer (upper 32.5 m). They found large contributions from both horizontal and vertical advection near the equator in the eastern tropical Atlantic and from meridional advection in the northwest, where meridional currents and salinity gradients are strong (see Fig. 1). Observational studies in the tropical 5 Pacific have also stressed the importance of horizontal advection in the mixed layer salinity budget on seasonal to interannual time scales (e.g., Delcroix and Henin, 1991; Cronin and McPhaden, 1998; Delcroix and Picaut, 1998; Henin et al., 1998). Several observational studies have addressed the seasonal cycle of surface salinity in the tropical Atlantic. They have revealed strong seasonal variability near the mouths of major rivers (Amazon and Congo) and important contributions from horizontal advection both in the annual mean and on seasonal time scales. From ship-of-opportunity data, Dessier and Donguy (1994) found that the seasonal cycle of surface salinity is dominated by the annual and semiannual harmonics, with amplitudes that are largest in the far western basin (west of 40W, 0 - 20N) and along the African coast (5N - 15N and 0 - 15S). They show that the seasonal cycle in the western basin is dominated by the annual harmonic and is strongly influenced by advection from the Amazon River. In boreal winter a region of fresh water (< 36 psu) extends northwestward along the coast of South America from the mouth of the Amazon to 15N. In boreal spring, as outflow from the Amazon increases, the fresh pool expands outward from the coast to 45W and northward into the Caribbean. By late boreal summer and fall, coincident with the arrival of the ITCZ and the strengthening of the North Equatorial Countercurrent, a band of fresh water extends eastward across the basin between 4 and 10N. Associated with this fresh pool is a significant barrier layer that is maintained at the surface by eastward advection from the Amazon and at depth by southwestward advection of high-salinity water subducted in the subtropics (Sprintall and Tomczak, 1992; Pailler et al. 1999). The seasonal cycle of surface salinity acquires a significant semiannual harmonic in the central basin between the equator and 5N, with minima corresponding approximately to the northward and southward crossings of the ITCZ. Farther east, SSS again is dominated by the 6 annual harmonic, with a minimum in boreal winter along the African coast (0 - 5S). Here the Congo River reaches maximum outflow in January, nearly four times weaker than that of the Amazon. Southward and westward from the Gulf of Guinea, the minimum in SSS occurs progressively later in the year, occurring in boreal fall near 10S, 10W (Dessier and Donguy, 1994). Based on a limited number of observational studies in the tropical Atlantic, it is clear that evaporation, precipitation, and horizontal advection all contribute to the observed seasonal cycle of mixed layer salinity. In addition, analyses of the mixed layer heat budget suggest that vertical advection and/or turbulent diffusion are also important along the equator (Molinari et al., 1985; Weingartner and Weisberg, 1991; Carton and Zhou, 1997; Foltz et al., 2003). The need to understand the seasonal cycle of mixed layer salinity has been supported by modeling studies, which reveal that mixed layer salinity contributes significantly to upper ocean dynamic height and potentially SST, through the formation of barrier layers. In this study we examine the seasonal mixed layer salinity budget using new comprehensive oceanic and surface meteorological data sets from nine PIRATA mooring locations in the tropical Atlantic. Our study complements an earlier analysis of the mixed layer heat balance using similar data sets at these same mooring sites (Foltz et al., 2003). 2. Data and Methods Following the methodology of Stevenson and Niiler (1983) and Delcroix and Henin (1991), the mixed layer salt balance can be written as S h h v S v S S we vˆ Sˆdz ( E P) S Fh t h 0 7 (1a) h we H hv t (1b) The terms in (1a) represent, from left to right, local salt storage, horizontal advection (separated into monthly mean and eddy terms), entrainment, vertical salinity/velocity covariance, surface moisture flux, and turbulent diffusion at the base of the mixed layer. Entrainment velocity (1b) is associated with a mass flux that crosses an isopycnal surface (H is the Heaviside unit function). Here h is the depth of the mixed layer, S and v are salinity and velocity, respectively, vertically averaged from the surface to a depth of –h, S and v are deviations from their monthly means (the overbar represents a monthy mean), Ŝ and v̂ represent deviations from the vertical average, S S S h , E is evaporation, and P is precipitation. We have found that the vertical salinity/velocity covariance term in (1a) is relatively small (< 0.7 mg m-2 s-1 on a monthly basis) at all locations considered in this study (based on climatological subsurface data from the SODA reanalysis, Carton et al., 2000). We therefore proceed to neglect this term. We also neglect vertical turbulent diffusion (last term on the right), although we anticipate that this term may contribute significantly along the equator, especially in the eastern Atlantic cold tongue, based on studies in the equatorial Pacific (e.g., Hayes et al., 1991; Lien et al., 2002). The PIRATA mooring array (Servain et al., 1998) consists of 12 buoys (see Fig. 1). We focus on nine with record lengths exceeding two years. Deployed in 1997 to study oceanatmosphere interactions, these Next Generation Autonomous Temperature Line Acquisition System (ATLAS) buoys measure subsurface ocean temperature and salinity, rainfall, and surface air temperature, relative humidity, and wind velocity. Ocean temperature is measured at 11 depths between 1 and 500 m with 20 m spacing in the upper 140 m, while salinity is measured only at 1, 20, 40, and 120 m. The 1 m temperature and salinity sensors provide bulk measures of 8 SST and SSS, respectively. Air temperature and relative humidity are measured at a height of 3 m above sea level, while rainfall and wind velocity are measured at 3.5 and 4 m, respectively. The sampling interval is ten minutes for all variables except rainfall, which is sampled at oneminute intervals. The instrument accuracies are: water temperature within 0.01C, salinity within 0.02 psu, wind speed 0.3 m s-1 or 3% (whichever is greater), air temperature 0.2C, relative humidity 3%, and rainfall 0.4 mm hr-1 (Freitag et al., 1994, 1999, 2001; Serra et al., 2001, Lake et al., 2003). Here we use both 10-minute and daily averaged data, which are transmitted in near-real time via satellite by Service Argos. All 10-minute PIRATA data used in this study (precipitation, air temperature, relative humidity, SST, and wind speed) have been analyzed by PMEL for quality control purposes (Freitag et al., 1999). The quantity of 10-minute quality-controlled subsurface temperature and salinity data is low. For these data we use daily averaged values based on real-time data streams, which are available with minimal quality control (H. P. Freitag, personal communication, 2003). We eliminate questionable values based on visual inspection and only when it is clear that a sensor was malfunctioning. Daily salinity measurements required substantial quality control at some locations. Our quality control procedure begins with a subjective identification of uncharacteristic highfrequency oscillations (we believe to result from a significant difference between response times of temperature and conductivity measurements). We next remove data with a significant bias (> 1 psu) with respect to the mean of the remaining time series at that location. Finally, we eliminate data at multiple depth levels if the difference in salinity between the levels begins to rapidly increase with time, which generally indicates instrument drift. The resulting time series are gappy. In order to fill in some of these gaps we use data from an adjacent depth level when 9 the time series at the two levels are visually indistinguishable, as frequently occurs in the mixed layer (see Fig. 2). In some cases, even after gap filling, there are not enough data to estimate monthly S and S . In these situations, when there are fewer than 15 daily estimates for a given climatological month (this generally occurs for between two and four months at each location), we use World Ocean Atlas (WOA) 2001 (Boyer et al., 2002) subsurface salinity to estimate S and S since we have found reasonable agreement between WOA 2001 and PIRATA monthly salinity values. With the exception of 1 m and 20 m measurements at 0, 23W and 4N, 38W, seasonal variations of WOA 2001 and PIRATA subsurface salinity are positively correlated at all locations. Highest correlation coefficients (> 0.5 at most depths) occur between 8N and 15N along 38W. Here we also find strong annual mean biases (PIRATA values are lower by up to 0.4 psu except at 15N, where PIRATA are higher by 0.3 psu). We therefore remove the annual means from WOA 2001 salinity data before using them to replace missing PIRATA values (i.e., seasonal variations from WOA 2001 are added to PIRATA annual means). The data records at 0, 10W are among the shortest of all PIRATA mooring records used in this study, yet a seasonal cycle is discernable for all surface variables with the possible exception of wind speed (see Fig. 3). The records at 8N, 38W are somewhat longer and reveal a stronger seasonal cycle for all surface variables. Precipitation is available directly from the moorings. We use ten-minute measurements of precipitation and correct for wind effects following the methodology of Serra et al. (2001). Maximum corrections are in the western basin during months of high rainfall (corrections are ~ 2 mg m-2 s-1 (0.2 mm hr-1)) during May at 4N, 38W and during November at 8N, 38W). We estimate the remaining terms in (1a) from a combination of observational and model data. 10 Evaporation is estimated using the bulk parameterization, E a CeW (q s q) , where E is evaporation rate, a is air density, C e is the transfer coefficient, W is wind speed, q is the water vapor mixing ratio, and q s 0.98q sat Ts is the interfacial water vapor mixing ratio, which is assumed to be proportional to the saturation water vapor mixing ratio (the factor of 0.98 accounts for salinity effects). Tests of this algorithm on data from the Coupled OceanAtmosphere Response Experiment (COARE) in the tropical west Pacific have revealed a bias of 0.16 cm mo-1 (COARE estimates are lower) (Fairall et al., 1996). We use ten-minute measurements of air temperature, SST, wind speed, and relative humidity to estimate evaporation and neglect both cool skin and warm layer effects (see Foltz et al., 2003 for an estimate of their magnitudes). We estimate the mixed layer depth as the depth at which temperature is 0.5C below SST. Throughout most of the tropical Atlantic temperature controls density so that our temperature-based estimates of mixed layer depth agree well with those based on density. An exception is in the northwestern basin, where persistent barrier layers have been observed (Sprintall and Tomczak, 1992; Pailler et al., 1999). We have compared temperature-based (0.5C criterion) and density-based (0.15 criterion, corresponding to a 0.5C criterion if vertical salinity variations are zero) mixed layer depth estimates, based on daily temperature and salinity, and found barrier layers of up to 20 m at 8N, 38W (see Fig. 4). Here the barrier layer is largest during boreal fall, when the low-salinity Amazon plume extends farthest eastward. At all other locations, we found no evidence of significant barrier layer formation (a moderate barrier layer (~ 10 m) is present at 12N, 38W during boreal fall). Unfortunately, the number of simultaneous daily temperature and salinity measurements at most locations is small, and since there are no salinity measurements between 40 and 120 m, mixed layer depth estimates in this 11 range would be uncertain if based on density. In addition, we have found that accounting for the seasonal barrier layer at 8N, 38W results in adjustments of less than 1 mg m-2 s-1 to each term in (1a) (zonal advection and salt storage are the only terms significantly affected). For these reasons, we estimate mixed layer depth from temperature alone. To calculate horizontal salt advection and entrainment velocity we first estimate the seasonal cycle of near-surface (~ 15 m) horizontal velocity following the procedure of Grodsky and Carton (2001). We anticipate that meridional velocity in the mixed layer is primarily the result of Ekman drift (since the meridional component of geostrophic velocity is weak) that decreases with increasing depth. We therefore apply a correction that assumes a linear decrease in meridional velocity from the observed value at 15 m to zero at -h, following Foltz et al. (2003). No correction is applied for h < 15 m since we cannot accurately estimate surface velocity needed for interpolation from 15 m to the surface. This correction leads to annual mean mixed layer salt advection adjustments (with respect to values obtained from constant vertical profiles of meridional velocity) of less than 1.2 mg m-2 s-1 at all locations. However, on a monthly basis, adjustments are more than 2 mg m-2 s-1 at 4N, 38W during August and also at 15N, 38W during January as the result of deep (> 80 m) mixed layers. Along the equator maximum adjustments are in boreal fall (~ 1 mg m-2 s-1). Since we cannot estimate the vertical distribution of zonal velocity (we anticipate that it depends strongly on horizontal pressure gradients, which we cannot calculate), we have not applied a correction to zonal velocity estimates. The climatological monthly velocity is multiplied by reanalysis climatological monthly SSS gradients (Carton et al., 2000) in order to estimate horizontal mixed layer salt advection. We also use divergence of these velocity estimates, as well as estimates of the time derivative of 12 mixed layer depth based on PIRATA subsurface temperature, to calculate we (see (1b)). Horizontal gradients of mixed layer depth are estimated from a monthly climatology based on bathythermograph temperature profiles (White, 1995). In comparison to monthly mean salt advection, eddy advection is more difficult to estimate, since in situ velocity measurements from the PIRATA buoys are not yet available. We anticipate that eddy advection may contribute significantly near the equator based on previous temperature balance analyses. It is known that tropical instability waves heat the equatorial mixed layer during boreal summer and fall (Weisberg and Weingartner, 1988), and we anticipate that they also provide a source of freshening in the presence of a mean southward salinity gradient. Since we are unable to estimate horizontal eddy salt advection directly we begin by estimating eddy temperature advection following the method of Baturin and Niiler (1997) and Swenson and Hansen (1999), which relies on quasi-lagrangian SST and velocity data from drifting buoys and then assume a constant eddy diffusion coefficient Kh for both heat and salt: v T 2T Kh 2 y y (2) v S 2 S Kh 2 y y (3) We further assume that meridional eddy advection dominates zonal eddy advection on the equator due to strong meridional temperature/salinity gradients. Combining (2) and (3) gives: 2 S v S v T y 2 v T S y y 2 T y T 2 y (4) Here S ( T ) is the salinity (temperature) change between the equator and 5N (estimated from the SODA reanalysis). The validity of (4) decreases as T 0. We therefore apply (4) only 13 when T 0.3C and fill missing values using a temporal smoothing based on the annual and semiannual Fourier harmonics. We use (4) to estimate eddy salt advection at the three equatorial mooring locations (see Fig. 1). Although we anticipate that eddy advection may also be important off the equator, especially at 4N, 38W and 8N, 38W where both eddy activity and horizontal salinity gradients are strong during boreal summer and fall, we cannot apply (4) here since zonal eddy advection may contribute significantly. Our analysis procedure begins with the formation of monthly mean climatological cycles of h, S, S , E and P. We use these PIRATA-based estimates, along with the climatological velocity, salinity gradients, and eddy advection estimates described previously, to estimate each term in (1a). Since we are interested primarily in the seasonal cycle, we eliminate high-frequency variability by fitting each term to annual and semiannual harmonics using least squares (Fourier) analysis. We use the standard deviation from each harmonic fit as an estimate of the uncertainty associated with each term in (1). These error estimates account for high-frequency variability (period < 6 months) that our data cannot accurately reproduce. We also anticipate errors resulting from the combination of missing PIRATA data and interannual variability. In particular, it is possible for climatologies of different PIRATA variables to incorporate data from different time periods (see Fig. 3). For this reason we display the number of daily PIRATA measurements that go into each climatological monthly estimate at each location. Monthly estimates of each term in (1) use a maximum of about 150 individual daily measurements (since most PIRATA moorings have been operational for about five years). Low counts (<< 150) indicate high uncertainty. 3. Results 14 In this section we examine the balance of terms in (1a) at nine PIRATA mooring locations (see Fig. 1). a) 15N, 38W and 12N, 38W At these sites, both surface fluxes and ocean dynamics contribute significantly to seasonal salt storage (Fig. 5). Seasonal variability of the surface moisture flux is connected to the seasonal movement of the ITCZ. Rainfall is significant during August – October, when the ITCZ is near its northernmost position, while evaporation at this time is at a minimum. As a result, surface salinity decreases at both locations during late boreal summer and early fall. In boreal winter strong northeast trade winds and low relative humidity lead to high rates of evaporation, causing surface salinity to increase at 12N. At 15N, ocean dynamics counteract the effects of evaporation, leading to weak freshening. Meridional advection has a strong seasonal cycle at both 12N and 15N (Fig. 6). Meridional velocity reaches a maximum during boreal winter, when the westward northeast trade winds and resultant northward Ekman drift are strong. Seasonal variations of S / y result from meridional movements of the zonal subtropical surface salinity front. At 15N, the northward surface salinity gradient reaches a maximum in boreal winter, when evaporation rates are high to the north and rainfall is abundant to the south. At this time, strong northward velocity combines with the strong northward salinity gradient, providing a significant source of freshening at 15N. The seasonal cycle of meridional advection at 12N is weaker, although seasonal variations of meridional velocity and S / y here are actually larger. The maximum northward gradient occurs in boreal fall at 12N, coincident with strong eastward advection of the Amazon freshwater plume to the south. Although the phase of the seasonal cycle of meridional advection is similar at 12N and 15N, due to similar seasonal cycles of meridional velocity, the annual 15 mean and seasonal amplitude at 12N are significantly lower since meridional velocity and S / y are in quadrature. In comparison to meridional advection, the seasonal cycle of zonal advection is weak (see Fig. 6) due to weaker zonal gradients of surface salinity. Seasonal changes in zonal advection at both locations reflect seasonal variations of S / x . Entrainment undergoes significant seasonal changes at 15N. The mixed layer deepens rapidly from 40 m in September to 80 m in January without compensating horizontal mass convergence. The resultant entrainment velocity (~ 0.7 m dy-1), combined with a large S (~ 0.3 psu), tends to an increase mixed layer salinity. Entrainment is negligible during July through September, when mixed layer depth decreases and S is close to zero. Entrainment velocity at 12N is similar, both in phase and amplitude, to that at 15N, but S is significantly weaker at 12N, resulting in much weaker entrainment at this location. During March through July mixed layer salinity increases at 15N, while the sum of terms results in a slightly negative tendency. The large discrepancy indicates a missing source of salt that most likely results from an overestimate of meridional advection. Horizontal salinity gradients provide the largest source of uncertainty at most locations we consider in this study, since we must rely on a combination of poorly sampled observations and a numerical model. Estimates of meridional SSS gradients at 15N are particularly difficult to make due to its close proximity to the strong zonal subtropical salinity front. Small errors in the meridional placement of this front result in large errors in meridional advection estimates. b) 8N, 38W and 4N, 38W We next consider the mixed layer salinity balance at two locations farther south and within the latitudinal range of the ITCZ (8N, 38W and 4N, 38W). As expected, precipitation here is more significant, in terms of both annual mean and seasonal variations (Fig. 7). Rainfall 16 at 8N is dominated by the annual harmonic, with a maximum in September when the ITCZ is farthest north. At 4N a significant semiannual harmonic appears, associated with the double passage of the ITCZ in June and December. Seasonal variations of evaporation at these locations are weaker than those to the north (12N and 15N) due to in phase relationships between wind speed and relative humidity (relative humidity is low when wind speed is low at 4N and 8N, in contrast to the out of phase relationship at 12N and 15N). Although precipitation is the most important factor affecting seasonal mixed layer salinity variability at both 4N and 8N, ocean dynamics also play an important role. The seasonal cycles of both meridional and zonal advection differ substantially between 8N and 4N (see Fig. 8). Seasonal variations of S / y at 8N are out of phase with those of meridional velocity. S / y is northward throughout the year, and is strongest during May – September, when rainfall is well developed to the south, while V is significant only during boreal winter. As a result, meridional advection provides only minor freshening during boreal spring. S / y and V also vary out of phase at 4N. Here S / y is southward throughout the year, reaching a maximum in August, when both the ITCZ and the Amazon freshwater plume are situated to the north. At this time, meridional velocity also reaches a maximum at 4N, resulting in strong northward salt advection during boreal summer and fall. Zonal advection also contributes significantly at 4N and 8N (see Fig. 8). In contrast to the conditions at 12N and 15N, the seasonal cycle of zonal velocity at both 4N and 8N is the dominant factor controlling seasonal variability of zonal advection. At 8N zonal advection is limited to August – October, when the eastward velocity of the North Equatorial Countercurrent reaches a maximum. At 4N S / x is small and westward throughout the year, while U 17 alternates between strong westward flow during the first half of the year (associated with the South Equatorial Current) and eastward flow during the latter half (due to the North Equatorial Countercurrent). A strong annual harmonic results at 4N, with zonal advection freshening the mixed layer during boreal spring and increasing salinity during boreal fall. Entrainment at 4N is strongest during boreal spring, when zonal mass divergence within the mixed layer is strong, while at 8N meridional mass convergence balances mixed layer deepening in boreal winter, resulting in zero entrainment throughout the year. At both locations, discrepancies between the sum of terms and local salt storage rate indicate that all terms have not been properly represented. At both 8N and 4N we anticipate that horizontal eddy advection may account for at least part the large discrepancies present during August through December at 8N and throughout the year at 4N. c) Along the equator We next consider the salt balance at three locations along the equator (35W, 23W, and 10W). In contrast to the conditions at the off-equatorial sites (4 - 15N along 38W) here we find that seasonal variations of mixed layer salinity are low, while rainfall is limited to the first half of the year, when the ITCZ is closest to the equator (see Fig. 9). Precipitation is lowest in the eastern basin (0, 10W), where the ITCZ fails to reach the equator during boreal winter and spring. In comparison to precipitation, evaporation is relatively constant throughout the year, since both relative humidity and wind speed vary weakly on a seasonal basis. In contrast to the surface moisture flux, which decreases in magnitude eastward along the equator, horizontal advection increases from 35W to 10W (see Fig. 10). Seasonal variability of horizontal advection is closely tied to the seasonal cycle of horizontal velocity. At all equatorial locations, both northward velocity and meridional advection reach their peaks during boreal fall, 18 when the southeast trade winds are strongest. Seasonal variations of both meridional velocity and meridional advection are weakest at 10W, where V is northward throughout the year and varies in phase with S / y (V is strongest in boreal fall, when southward S / y is weakest). At 23W the combination of a weaker seasonal cycle of S / y and stronger variations of V results in a stronger seasonal cycle of meridional advection. Seasonal variations of S / y are again strong at 35W. Here the southward SSS gradient peaks in boreal fall, when the Amazon plume extends farthest eastward and precipitation is high to the north. Although V and S / y vary out of phase at 35W (tending to increase the amplitude of the seasonal cycle), the annual mean southward surface salinity gradient here is much weaker than at 23W, leading to similar seasonal cycles of meridional advection. Whereas meridional advection tends to increase mixed layer salinity along the equator, zonal advection provides a source of freshening. At all equatorial locations, seasonal variations in the intensity of the westward South Equatorial Current have a large impact on the seasonal cycle of zonal mixed layer salinity advection. At 35W westward velocity is strongest during boreal fall, and S / x is very weak throughout the year (see Fig. 10). As a result, zonal advection is important only during the second half of the year and has weak annual mean and seasonal variations. At 23W zonal advection is more significant as a result of a stronger westward surface salinity gradient. Here westward velocity reaches maxima in boreal summer and winter, producing a seasonal cycle with a strong semiannual harmonic. The annual mean and seasonal cycles of both zonal velocity and S / x reach a maximum at 10W. Here the westward surface salinity gradient peaks in boreal winter, when rainfall and Congo River outflow freshen the mixed layer to the east. The amplitude of the seasonal cycle of U here is almost twice that at 23W, resulting in a very strong seasonal cycle of zonal advection at 10W. 19 Meridional eddy advection opposes the effects of meridional advection, contributing a source of freshening at the three equatorial locations during late boreal summer. At this time the mean southward surface salinity gradient is strong at all locations and tropical instability waves are well developed in the central and eastern basin. Entrainment tends to increase mixed layer salinity at 35W, where horizontal mass divergence peaks in boreal spring and fall, but is much weaker throughout the year at 23W and 10W. The sum of terms at 35W results in a period of strong freshening during February through May, when the sum of evaporation, entrainment, and eddy advection fails to balance precipitation. During this time the actual mixed layer tendency is less negative or even positive, indicating that we have either neglected or misrepresented the magnitude one or more terms in the balance. One possible explanation is that we have underestimated entrainment during this time period. Weingartner and Weisberg (1991) analyzed one year of in situ upper ocean horizontal velocity data near the equator at 28W and found strong upwelling near the base of the mixed layer during mid-April through mid-May. It is thus possible that the coarse horizontal resolution of our mean velocity data (2-lat x 3-lon) has led to an underestimate of horizontal mass divergence and associated entrainment velocity. Additional entrainment of ~ 3 to 5 mg m-2 s-1 (equivalent to an entrainment velocity of ~ 2.5 to 4.3 m dy-1) is required to explain the discrepancy during February – May at 35W. It therefore seems unlikely, based on the upwelling estimates of Weingartner and Weisberg (1991), that unresolved entrainment alone could account for the additional increase in mixed layer salinity needed at 0, 35W. Another possibility is that vertical turbulent diffusion is important at 35W (we have completely neglected this term). The largest discrepancy between the sum of terms and salt storage occurs during February through May, when the mixed layer at 35W is shallowest (~ 35 20 to 45 m). At this time velocity is weak near the surface, but is strong and eastward below the mixed layer (based on climatological data from the SODA reanalysis, Carton et al., 2000). Using the turbulent diffusion parameterization of Pacanowski and Philander (1981) with U / z = 0.012 s-1, T / z = 0.1 C m-1 (based on PIRATA subsurface temperature), and S / z = 0.02 psu m-1 (assuming the PIRATA-based S is distributed over 10 m) leads to a maximum increase in salt content of ~ 0.5 mg m-2 s-1 during boreal spring. It therefore seems unlikely that the discrepancy during boreal spring at 0, 35W can be accounted for by turbulent diffusion alone. In contrast, the discrepancy between the sum of terms and salt storage during October – December at 35W requires an additional source of freshening that cannot be provided by entrainment or turbulent diffusion. One possibility is that we have underestimated horizontal eddy advection (these estimates are very uncertain on the equator due to a lack of near-surface drifter data). It is also possible that we have overestimated entrainment, since Weingartner and Weisberg (1991) found that upwelling was most significant during boreal spring near 28W. The sum of terms at 0, 23W indicates excess freshening of 2 to 4 mg m-2 s-1 during January – May and an excess increase in mixed layer salinity of ~ 3 mg m-2 s-1 during September – November. Explanations for the excess freshening include an underestimate of entrainment and failure to account for vertical turbulent diffusion. An additional entrainment velocity of ~ 1.7 to 3.4 m dy-1 is required during January – May to balance the excess freshening predicted by the sum of terms. On the other hand, vertical turbulent diffusion accounts for no more than ~ 0.5 mg m-2 s-1, with a peak in boreal spring. It therefore seems, as was the case at 35W, that unresolved entrainment accounts for the bulk of the excess freshening at 0, 23W. The excess increase in salt content during the end of the year is possibly due to an underestimate of horizontal eddy 21 advection (these estimates are highly uncertain due to a lack of drifter data and the indirect method used). The sum of terms at 0, 10W predicts excess freshening during April – August, with a peak of ~ 5 mg m-2 s-1 in June. If unresolved entrainment alone were to account for this discrepancy, an entrainment velocity of more than 4 m dy-1 would be required. We therefore anticipate that vertical turbulent diffusion plays an important role at 0, 10W during May – June. At this time the mixed layer is very shallow (< 20 m) and near-surface westward velocity approaches 1 m s-1. Assuming U / z = 0.022 s-1, vertical turbulent diffusion accounts for up to 2.5 mg m-2 s-1 during May – June at 0, 10W. Thus, in contrast to the situations along the equator at 23W and 35W, here it appears that turbulent diffusion probably plays a major role. d) 6S, 10W and 10S, 10W The seasonal mixed layer salt balance south of the equator (along 10W) is highly uncertain (see Fig. 11). Much of this uncertainty is due to poor estimates of horizontal surface salinity gradients and hence horizontal advection. The number of in situ surface salinity measurements assimilated into the SODA reanalysis (used to estimate horizontal gradients) at these locations is low in comparison to most of the other locations considered in this study. For example, at 6S, 10W there are no surface salinity measurements during eight months of the year. As a result, discrepancies between the sum of terms and salt storage are significant (~ 2 to 5 mg m-2 s-1) throughout most of the year at both 6S and 10S. At 6S, 10W the surface moisture flux is dominated by evaporation. Precipitation is nearly zero throughout the year, while evaporation peaks in early boreal summer, when the southeast trade winds are strong and relative humidity is low. In contrast to the conditions along the equator and along 38W, where S < 0 throughout the year, here S > 0 (salinity decreases 22 with depth in the mixed layer) during the second half of the year. As a result, entrainment freshens the mixed layer during July – December due to a combination of zonal and meridional mass divergence. In contrast, entrainment increases SSS during April – June, when S < 0 and the mixed layer deepens from 40 to 60 m without compensating horizontal mass convergence. Our results show that both meridional velocity and the meridional SSS gradient are southward throughout the year at 6S, 10W, indicating that meridional advection provides a year-round source of freshening. Zonal advection seems to be weaker in the annual mean, with a seasonal amplitude that is similar to that of meridional advection. As discussed previously, our estimates of horizontal advection at this location are highly uncertain. Error bars associated with these terms are possibly twice as large as the signal, due to poorly known horizontal SSS gradients. With the exception of entrainment, the balance at 10S, 10W seems to be similar to that at 6S. Evaporation peaks during boreal summer, while meridional advection provides a yearround source of freshening. Entrainment here is much less important than at 6S due to smaller S at 10S. 4. Summary This paper examines the mixed layer salt budget in the tropical Atlantic, based on measurements from nine PIRATA moorings and a variety of other in situ, satellite, and model data, in an attempt to explain seasonal cycle of SSS. This study is similar in spirit to that of Cronin and McPhaden (1998) in the western equatorial Pacific, which uses in situ near-surface atmospheric and subsurface oceanographic measurements to directly estimate as many terms as possible in the mixed layer salt budget. Our main results are as follows: 23 At 15ºN, 38ºW and 12ºN, 38ºW changes in mixed layer salinity are balanced primarily by precipitation, evaporation, and meridional advection, with the exception that entrainment contributes significantly during boreal winter at 15ºN (due to a rapidly increasing mixed layer depth and large S ). We anticipate that uncertainty in our estimate of the meridional SSS gradient may be responsible for the excess freshening during boreal spring at 15ºN. The mixed layer salt balances at 8ºN, 38ºW and 4ºN, 38ºW include significant contributions from precipitation and horizontal advection. Horizontal advection (both zonal and meridional components) is most important at 4ºN, while entrainment is additionally important at this location during boreal spring. We expect that unresolved horizontal eddy salt advection may be at least partially responsible for discrepancies between the sum of terms and salt storage at both locations. The mixed layer salt budgets along the equator (0º, 10ºW; 0º, 23ºW; and 0º, 35ºW) represent a balance of precipitation, horizontal advection (both mean and eddy), and entrainment. Contributions from zonal advection increase eastward from 35ºW to 10ºW, while precipitation decreases eastward. Horizontal eddy advection provides a significant source of freshening at all locations during boreal summer and fall, while entrainment contributes significantly only at 35ºW. We believe that unresolved entrainment and vertical turbulent diffusion may explain 24 most of the excess freshening at all locations and that uncertainties in our estimates of horizontal eddy advection may be the cause of excess increases in mixed layer salinity during boreal fall. The mixed layer salinity balance in the eastern equatorial Atlantic (6ºS, 10ºW and 10ºS, 10ºW) includes contributions from evaporation, entrainment, and horizontal advection. Large discrepancies between the sum of terms and salt storage at both locations indicate that our estimates of horizontal SSS gradients contain a high degree of uncertainty. This study provides the first comprehensive observation-based analysis of the mixed layer salt budget in the tropical Atlantic. On the equator we have found many similarities with the mixed layer heat balance (Foltz et al., 2003). In both cases horizontal mean and eddy advection contribute significantly, and we suspect that unresolved entrainment and vertical turbulent diffusion account for anomalous heating/freshening. We find that the salt balance contains large contributions from mean horizontal advection at all off-equatorial locations, and we anticipate that many of the discrepancies between the sum of terms and salt storage along 38ºW are due to unresolved eddy salt advection. This is in contrast to the mixed layer heat balance, where off the equator horizontal advection makes minimal contributions and eddy advection is insignificant. In comparison to the heat advection estimates of Foltz et al. (2003), our estimates of mean horizontal salt advection are highly uncertain. Additional uncertainties arise because the seasonal cycle of horizontal SSS gradients in the tropical Atlantic is very poorly known (due to a lack of in situ and satellite observations) in comparison to that of SST. 25 As a result, our estimates of horizontal SSS gradients, and hence mean horizontal salt advection, are uncertain. Not surprisingly, the largest errors in our analysis are at the two locations in the southern hemisphere (6ºS, 10ºW and 10ºS, 10ºW), where the seasonal cycle of SSS and its gradient are poorly known. There are generally less than 100 total surface salinity observations (summed over the entire historical record from WOA 2001) in each 2-lat 3-lon box along 10W. In contrast, there are more than 400 observations along the equator between 23W and 35W. We therefore expect that discrepancies at 6ºS, 10ºW and 10ºS, 10ºW are associated with uncertainties in our estimates of horizontal salt advection. We have also found large discrepancies north of the equator, particularly at 4ºN, 38ºW and 8ºN, 38ºW. We expect that unresolved horizontal eddy advection may account for most of these discrepancies. We have found that the sum of terms at 15ºN results in excess freshening (up to 2.5 mg m-2 s-1) during boreal spring and summer. At this time the meridional SSS gradient is strong, and we anticipate that errors in the placement of this zonal front may account for the discrepancies at this location. In this region there are generally less than 100 total surface salinity observations. Along the equator disagreements between the sum of terms and salt storage are related to uncertainties in our estimates of horizontal eddy salt advection as well as unresolved entrainment and vertical turbulent diffusion. At 0º, 23ºW and 0º, 35ºW the sum of terms results in excess freshening during the first half of the year. We anticipate that these discrepancies are mainly due to unresolved entrainment (due to the 2º-latitude resolution of our velocity estimates). At 0º, 10ºW excess freshening is ~ 4 - 5 mg m-2 s-1 during May – July. Here we anticipate that vertical turbulent diffusion contributes significantly (up to 2.5 mg m-2 s-1) in response to a shallow mixed layer (< 20 m) and strong westward surface currents (~ 1 m s-1). Discrepancies during boreal fall 26 at 0º, 23ºW and 0º, 35ºW, requiring an additional source of freshening, are most likely due to underestimates of horizontal eddy advection. These estimates are highly uncertain due to a lack of drifter data on the equator and the indirect method used. Despite these limitations and the relatively short mooring records, we have been able to show that horizontal advection is an important component of the mixed layer salt balance at all nine locations we considered. To complete our understanding at seasonal periods additional work is needed to quantify the roles of horizontal advection, entrainment, and vertical turbulent diffusion. In particular, the addition of current meters to the PIRATA buoys would provide better knowledge of both mean and eddy advection. In addition, satellite-based measurements of surface salinity from the NASA Aquarius mission will greatly improve estimates of horizontal salt advection. Though subject to considerable uncertainties because of data limitations, our results nonetheless provide a basis for evaluating interannual and decadal variability, which are both linked to the annual cycle. Acknowledgements References Baturin, N.G., and P.P. Niiler, Effects of instability waves in the mixed layer of the equatorial Pacific, J. Geophys. Res., 102, 27,771-93, 1997. Boyer, T.P., Stephens, C., J.I. Antonov, M.E. Conkright, R.A. Locarnini, T.D. O'Brien, and H.E. Garcia, World Ocean Atlas 2001, Volume 2: Salinity. S. Levitus, Ed., NOAA Atlas NESDIS 50, U.S. Government Printing Office, Wash., D.C., 165 pp., 2002. 27 Carton, J.A., Effect of seasonal surface freshwater flux on sea surface temperature in the tropical Atlantic Ocean, J. Geophys. Res., 96, 12,593-12,598, 1991. Carton, J. A., and Z.X. Zhou, Annual cycle of sea surface temperature in the tropical Atlantic ocean, J. Geophys. Res., 102, 27,813-27,824, 1997. Carton, J.A., G. Chepurin, X.H. Cao, and B. Giese, A Simple Ocean Data Assimilation analysis of the global upper ocean 1950-95. Part I: Methodology, J. Phys. Oceanogr., 30, 294-309, 2000. Cooper, N.S., The effect of salinity on tropical ocean models, J. Phys. Oceanogr., 18, 697-707, 1988. Cronin, M.F., and M.J. McPhaden, Upper ocean salinity balance in the western equatorial Pacific, J. Geophys. Res., 103, 27,567-87, 1998. da Silva, A., A.C. Young, and S. Levitus, Atlas of Surface Marine Data 1994, Volume 1: Algorithms and Procedures. NOAA Atlas NESDIS 6, U.S. Department of Commerce, Washington, D.C., 1994. Delcroix, T., and C. Henin, Seasonal and interannual variations of sea surface salinity in the tropical Pacific Ocean, J. Geophys. Res., 96, 22,135-22,150, 1991. Delcroix, T., and J. Picaut, Zonal displacement of the western equatorial Pacific “fresh pool,” J. Geophys. Res., 103, 1087-1098, 1998. Dessier, A., and J.R. Donguy, The sea surface salinity in the tropical Atlantic between 10S and 30N – seasonal and interannual variations (1977-1989), Deep Sea Res. I, 41, 81-100, 1994 Fairall, C.W., E.F. Bradley, D.P. Rogers, J.B. Edson, G.S. Young, Bulk parameterization of airsea fluxes for TOGA COARE. J. Geophys. Res., 101, 3747-3764, 1996. 28 Foltz, G.R., S.A. Grodsky, J.A. Carton, and M.J. McPhaden, Seasonal mixed layer heat budget of the tropical Atlantic Ocean, accepted in J. Geophys. Res., 2002JC001584, 2003. Freitag, H.P., Y. Feng, L.J. Mangum, M.P. McPhaden, J. Neander, and L.D. Stratton, Calibration procedures and instrumental accuracy estimates of TAO temperature, relative humidity and radiation measurements. NOAA Tech. Memo. ERL PMEL-104, 32 pp., 1994. Freitag, H.P., M.E. McCarty, C. Nosse, R. Lukas, M.J. McPhaden, and M.F. Cronin, COARE Seacat data: Calibrations and quality control procedures. NOAA Tech. Memo. ERL PMEL115, 89 pp., 1999. Freitag, H.P., M. O'Haleck, G.C. Thomas, and M.J. McPhaden, Calibration procedures and instrumental accuracies for ATLAS wind measurements. NOAA. Tech. Memo. OAR PMEL119, NOAA/Pacific Marine Environmental Laboratory, Seattle, Washington, 20 pp., 2001. Grodsky, S.A., and J.A. Carton, Intense surface currents in the tropical Pacific during 19961998, J. Geophys. Res., 106, 16673-16684, 2001. Hayes, S.P., P. Chang, and M.J. McPhaden, Variability of the sea surface temperature in the eastern equatorial Pacific during 1986-1988, J. Geophys. Res., 96, 10553-10566, 1991. Henin, C., Y. du Penhoat, and M. Ioualalen, Observations of sea surface salinity in the western Pacific fresh pool: Large-scale changes in 1992-1995, J. Geophys. Res., 103, 7523-7536, 1998. Johnson, E.S., G.S.E. Lagerloef, J.T. Gunn, and F. Bonjean, Salinity advection in the tropical oceans compared to atmospheric freshwater forcing: a trial balance, J. Geophys. Res., 107, art. no. 8014, 2002. 29 Lake, B. J., S.M. Noor, H.P. Freitag, and M.J. McPhaden, Calibration procedures and instrumental accuracy estimates for ATLAS air temperature and relative humidity measurements, NOAA Tech. Memo., in press, 2003. Lien, R.-C., E.A. D’Asaro, and M.J. McPhaden, Internal waves and turbulence in the upper central equatorial Pacific: lagrangian and eulerian observations, J. Phys. Oceanogr., 32, 2619-2639, 2002. Lukas, R., and E. Lindstrom, The mixed layer of the western equatorial Pacific Ocean, J. Geophys. Res., 96, suppl. S, 3343-3357, 1991. Molinari, R. L., J. F. Festa, and E. Marmolejo, Evolution of sea surface temperature in the tropical Atlantic Ocean during FGGE, 1979, 2. Oceanographic fields and heat balance of the mixed layer, J. Mar. Res., 43, 67-81, 1985. Murtugudde R., and A.J. Busalacchi, Salinity effects in a tropical ocean model, J. Geophys. Res., 103, 3283-3300, 1998. Pacanowski, R.C., and S.G.H. Philander, Parameterization of vertical mixing in numerical models of tropical oceans, J. Phys. Oceanogr., 11, 1443-1451, 1981. Pailler, K., B. Bourles, and Y. Gouriou, The barrier layer in the western tropical Atlantic Ocean, Geophys. Res. Lett., 26, 2069-2072, 1999. Richardson, P.L., and G. Reverdin, Seasonal cycle of velocity in the Atlantic North Equatorial Countercurrent as measured by surface drifters, current meters, and ship drifts, J. Geophys. Res., 92, 3691-3708, 1987. Roemmich, D., M. Morris, W.R. Young, and J.R. Donguy, Fresh equatorial jets, J. Phys. Oceanogr., 24, 540-558, 1994. 30 Serra, Y.L., P. A'Hearn, H.P. Freitag, and M.J. McPhaden, ATLAS self-siphoning rain gauge error estimates. J. Atmos. Ocean. Tech., 18, 1989-2002, 2001. Servain, J., A.J. Busalacchi, M.J. McPhaden, A.D. Moura, G. Reverdin, M. Vianna, and S.E. Zebiak, A Pilot Research Moored Array in the Tropical Atlantic (PIRATA), Bull. Amer. Meteorol. Soc., 79, 2019-2031, 1998. Sprintall, J., and M. Tomczak, Evidence of the barrier layer in the surface layer of the tropics, J. Geophys. Res., 97, 7305-7316, 1992. Stevenson, J.W., and P.P. Niiler, Upper ocean heat budget during the Hawaii-to-Tahiti shuttle experiment, J. Phys. Oceanogr., 13, 1894-1907, 1983. Swenson, M.S., and D.V. Hansen, Tropical Pacific ocean mixed layer heat budget: The Pacific cold tongue, J. Phys. Oceanogr., 29, 69-81, 1999. Vialard, J., and P. Delecluse, An OGCM study for the TOGA decade. Part I: Role of salinity in the physics of the western Pacific fresh pool, J. Phys. Oceanogr., 28, 1071-1088, 1998. Weisberg, R. H., and T. J. Weingartner, Instability waves in the equatorial Atlantic Ocean, J. Phys. Oceanogr., 18, 1641-1657, 1988. Weingartner, T. J., and R. H. Weisberg, On the annual cycle of equatorial upwelling in the central Atlantic Ocean, J. Phys. Oceanogr., 21, 68-82, 1991. White, W. B., Design of a global observing system for gyre-scale upper ocean temperature variability, Progress in Oceanogr., 36, Pergamon, 169-217, 1995. Yoo, J.-M., and J.A. Carton, Annual and interannual variation of the freshwater budget in the tropical Atlantic Ocean and the Caribbean Sea, J. Phys. Oceanogr., 20, 831-845, 1990. 31 Figure captions Figure 1 Locations of the PIRATA moored buoys (solid and open circles). Solid circles indicate buoys used in this study. Background contours and arrows are climatological annual mean near-surface salinity from the SODA reanalysis (Carton et al., 2000) and near-surface ocean velocity (Grodsky and Carton, 2001). Bold contour lines represent 1 psu intervals. Figure 2 Example of the quality control and gap filling procedure for PIRATA subsurface salinity records. Original PIRATA 1 m (top) and 20 m (middle) salinity, and the final 1 m salinity record (bottom) after quality control and gap filling. Questionable data during 1998, early 2001, and early 2002 in the original 1 m time series have been removed, and gaps in the 1 m record in 2002 have been filled with data from 20 m. Figure 3 Daily PIRATA near-surface atmospheric and oceanic measurements at (left) 0, 10W and (right) 8N, 38W during 1998 – 2002. Solid gray lines represent monthly mean World Ocean Atlas 2001 climatological surface salinity, TRMM Microwave Imager rainfall, QuikSCAT near-surface wind speed, and NCEP/NCAR Reanalysis relative humidity. Figure 4 Mixed layer depth at 8N, 38W calculated from PIRATA subsurface temperature (0.5 C criterion) and from PIRATA subsurface temperature and salinity (0.15 ). Note the significant barrier layer during boreal summer and fall. Figure 5 Left panels show individual contributions to the salt balance equation (1) in the form of evaporation, precipitation, entrainment, and mean zonal and meridional heat advection. Plots in lefthand panels show least squares fits of mean + annual and semiannual harmonics to monthly data. Righthand panels show the sum of the terms in the lefthand panel and the actual mixed layer salt storage rate. Shading and cross-hatching in righthand panels indicate error estimates based on standard deviations of monthly data from least squares harmonic fits. Bars in righthand panels indicate number of days in each month for which all PIRATA-based terms in the lefthand panel are available (maximum of ~ 150 days for each month, corresponding to ~ 5 years of data: September 1997 – December 2002). Figure 6 Zonal and meridional climatological near-surface ocean velocity and surface salinity gradients at 15N, 38W and 12N, 38W. Figure 7 As in Figure 5, but for 8N, 38W and 4N, 38W. Figure 8 As in Figure 6, but for 8N, 38W and 4N, 38W. Figure 9 As in Figure 5, but for locations along the equator. Horizontal eddy salt advection (defined as total advection minus climatological monthly advection) is included in the left panels. Figure 10 As in Figure 6, but for locations along the equator. Figure 11 As in Figure 5, but for 6S, 10W and 10S, 10W. 32 Table 1 Amplitude and phase of annual and semiannual cosine harmonics (with respect to Jan. 1) and annual mean of terms in the mixed layer salt balance at 15N, 38W and 12N, 38W. Underlined terms are those that explain the largest amount of variance at each location. Annual mean (mg m-2 s-1) 15ºN 38ºW Evaporation Precipitation Entrainment Zonal adv. Meridional adv. Salt storage Mixed layer depth 12ºN 38ºW Evaporation Precipitation Entrainment Zonal adv. Meridional adv. Salt storage Mixed layer depth Annual amplitude (mg m-2 s-1) Annual phase (months) Semiannual amplitude (mg m-2 s-1) Semiannual phase (months) 2.0 -0.5 0.5 -0.5 -2.0 0.0 60 m 0.5 1.0 1.0 0.5 1.0 1.0 20 m 2 3 0 9 8 5 3 0.0 0.5 0.5 0.5 0.5 1.0 10 m 0 6 0 6 4 5 1 2.0 -1.0 0.0 0.5 -1.0 0.5 40 m 0.5 1.5 0.0 0.5 0.5 2.0 20 m 2 3 0 0 8 3 4 0.5 0.5 0.0 0.5 0.5 1.0 0m 2 1 0 0 1 3 2 Table 2 As in Table 1, but for 8N, 38W and 4N, 38W. Annual mean (mg m-2 s-1) 8ºN 38ºW Evaporation Precipitation Entrainment Zonal adv. Meridional adv. Salt storage Mixed layer depth 4ºN 38ºW Evaporation Precipitation Entrainment Zonal adv. Meridional adv. Salt storage Mixed layer depth Annual amplitude (mg m-2 s-1) Annual phase (months) Semiannual amplitude (mg m-2 s-1) Semiannual phase (months) 2.0 -3.5 0.0 0.0 -0.5 0.0 40 m 0.5 4.0 0.0 1.0 0.5 3.5 20 m 2 3 3 3 10 1 4 0.0 0.5 0.0 1.0 0.0 1.5 0m 2 3 2 6 1 5 3 1.0 -4.0 0.5 0.0 1.5 0.0 70 m 0.0 2.5 1.0 1.0 1.5 3.0 30 m 10 9 4 10 9 7 11 0.0 1.5 0.0 0.0 0.5 2.0 10 m 2 2 3 5 1 1 2 33 Table 3 As in Table 1, but for the three equatorial locations. Annual mean (mg m-2 s-1) 0º 35ºW Evaporation Precipitation Entrainment Zonal adv. Meridional adv. Eddy adv. Salt storage Mixed layer depth 0º 23ºW Evaporation Precipitation Entrainment Zonal adv. Meridional adv. Eddy adv. Salt storage Mixed layer depth 0º 10ºW Evaporation Precipitation Entrainment Zonal adv. Meridional adv. Eddy adv. Salt storage Mixed layer depth Annual amplitude (mg m-2 s-1) Annual phase (months) Semiannual amplitude (mg m-2 s-1) Semiannual phase (months) 1.5 -2.5 1.0 -0.5 0.5 -0.5 0.0 60 m 0.5 3.0 0.5 1.0 1.0 1.0 0.5 20 m 9 10 10 4 9 2 9 10 0.0 1.0 1.0 0.0 0.0 1.5 1.0 0m 1 0 4 6 4 6 5 2 1.0 -1.5 0.5 -1.0 1.0 -0.5 0.0 30 m 0.5 2.0 0.5 0.0 1.0 0.5 1.0 10 m 8 10 10 2 10 4 1 10 0.0 1.0 0.0 1.0 0.5 1.5 1.0 0m 4 1 1 3 3 5 4 1 1.0 -0.5 0.5 -2.5 1.5 -1.0 0.0 20 m 0.5 1.0 0.5 1.0 0.5 1.5 1.5 10 m 2 9 3 11 11 4 6 11 0.0 0.5 0.5 2.0 0.5 0.5 1.0 0m 4 0 2 3 4 5 3 4 34 Table 4 As in Table 1, but for 6S, 10W and 10S, 10W. Annual mean (mg m-2 s-1) 6ºS 10ºW Evaporation Precipitation Entrainment Zonal adv. Meridional adv. Salt storage Mixed layer depth 10ºS 10ºW Evaporation Precipitation Entrainment Zonal adv. Meridional adv. Salt storage Mixed layer depth Annual amplitude (mg m-2 s-1) Annual phase (months) Semiannual amplitude (mg m-2 s-1) Semiannual phase (months) 2.0 0.0 0.0 0.0 -1.5 0.5 50 m 0.5 0.0 1.0 0.5 0.5 1.5 10 m 6 11 3 0 0 10 9 0.0 0.0 0.5 0.5 0.5 3.0 10 m 5 1 4 4 1 0 6 2.0 0.0 0.0 0.0 -1.0 0.0 50 m 0.5 0.0 0.0 0.5 0.5 1.5 20 m 7 10 4 0 2 0 9 0.0 0.0 0.0 0.0 0.0 1.5 0m 1 0 0 3 0 3 1 35 Title: map.eps Creator: gxeps $Rev is ion: 1.1.1.1 $ Prev iew : This EPS picture w as not s av ed w ith a preview inc luded in it. Comment: This EPS picture w ill print to a Pos tSc ript printer, but not to other ty pes of printers. Figure 1 36 Title: /homes/metogra1/gregory f/SALT/FIGS/qc.eps Creator: MATLAB, The Mathw orks , Inc . Preview : This EPS picture w as not saved w ith a preview included in it. Comment: This EPS picture w ill print to a PostScript printer, but not to other ty pes of printers . Figure 2 37 Title: /homes/metogra1/gregoryf/SALT/FIGS/raw .eps Creator: MATLAB, The Mathw orks, Inc. 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Comment: This EPS picture w ill print to a Pos tSc ript printer, but not to other ty pes of printers. Figure 6 41 Title: /homes/metogra1/gregoryf/SALT/FIGS/s w .eps Creator: MATLAB, The Mathw orks, Inc. Prev iew : This EPS picture w as not s av ed w ith a preview inc luded in it. Comment: This EPS picture w ill print to a Pos tSc ript printer, but not to other ty pes of printers. Figure 7 42 Title: /homes/metogra1/gregory f/SALT/FIGS/adv _s w .eps Creator: MATLAB, The Mathw orks , Inc . Preview : This EPS picture w as not saved w ith a preview included in it. Comment: This EPS picture w ill print to a PostScript printer, but not to other ty pes of printers . Figure 8 43 Title: /homes/metogra1/gregoryf/SALT/FIGS/eq.eps Creator: MATLAB, The Mathw orks, Inc. Prev iew : This EPS picture w as not s av ed w ith a preview inc luded in it. Comment: This EPS picture w ill print to a Pos tSc ript printer, but not to other ty pes of printers. Figure 9 44 Title: /homes/metogra1/gregory f/SALT/FIGS/adv _eq.eps Creator: MATLAB, The Mathw orks , Inc . Preview : This EPS picture w as not saved w ith a preview included in it. Comment: This EPS picture w ill print to a PostScript printer, but not to other ty pes of printers . Figure 10 45 Title: /homes/metogra1/gregory f/SALT/FIGS/s e.eps Creator: MATLAB, The Mathw orks , Inc . Preview : This EPS picture w as not saved w ith a preview included in it. Comment: This EPS picture w ill print to a PostScript printer, but not to other ty pes of printers . Figure 11 46