Lab: Types of Chemical Reactions - OHS Chemistry PRE-LAB DISCUSSION There are many kinds of chemical reactions and many ways of classifying them. One popular and useful method is to classify reactions into four major types. There are: (1) direct combination, or synthesis; (2) decomposition, or analysis; (3) single replacement; and (4) exchange of ions, or double replacement. Not all chemical reactions can be put into one of these categories. However, many can. See your chapter 8 notes for details about them. All of the types of reactions in this lab may be represented by balanced molecular equations. You will be expected to balance the equations representing the observed equations. 2) PURPOSE Observe some chemical reactions and identify reactants and products of those reactions. Classify the reactions according to type and write balanced equations. EQUIPMENT MATERIALS Burner Crucible tongs Scoopula Test tubes 15x180-mm (7) Test tube holder Test tube rack Evaporating dish Wood splints Fine sandpaper Safety glasses Zinc, mossy (Zn) Copper wire, 5 cm. (Cu) Magnesium ribbon (Mg) Copper (II) carbonate (CuCO3) 6 M hydrochloric acid (HCI) 1 M Copper (II) sulfate (CuSO4) 0.1 M Zinc acetate (Zn(C2H3O2)2) 0.1 M sodium phosphate (Na3PO4) 1 M sodium sulfite (Na2SO3) 3) PROCEDURE: Reaction 1 Use fine sandpaper to clean a 5 cm. piece of copper wire until the wire is shiny. Examine the wire and note its appearance. Using crucible tongs, hold the wire in the hottest part of the burner flame for 1-2 minutes. Observe any changes that occur while the wire is being heated. Remove the wire from the flame and note any changes in appearance caused by the heat. Reaction 2 Place an evaporating dish handy to the base of the burner. Examine a piece of magnesium ribbon. (5 cm.) Using crucible tongs, hold the sample in the burner flame until the magnesium starts to burn. DO NOT LOOK DIRECTLY AT THE FLAME UNLESS VIEWED THROUGH COBALT BLUE GLASS. HOLD THE BURNING MAGNESIUM AWAY FROM YOU AND DIRECTLY OVER THE EVAPORATING DISH. When the ribbon stops burning, put what is left of it in the evaporating dish. Examine this product thoroughly. Reaction 3 Place a scoopula full of copper (II) carbonate (CuCO 3) in a clean, dry test tube (about 2 cm. in the bottom of the tube). Note the appearance of the sample. Using a test tube holder, heat the CuCO3 strongly in the burner flame for about 3 minutes. Turn off the burner and insert a flaming wooden splint in the test tube to test for the presence of carbon dioxide gas. (CO2 will extinguish a fire) Note any change in the appearance of the material in the test tube. Reaction 4 Add about 5 ml of 1 M copper (II) sulfate (CuSO4) solution to a clean, dry test tube. Place a small piece of zinc metal in the solution. Note the appearance of the solution to the same test tube. Put the test tube aside until the end of the period. At that time, observe what has happened, and note any changes in the mixture JLD; 4-14-11 Reaction 5 Stand a clean, dry test tube in a test tube rack. Add about 5 mL of 6 M Hydrochloric acid (HCl) to the tube. CAUTION: HANDLE ACIDS WITH CARE! THEY CAN CAUSE PAINFUL BURNS! Carefully drop a small piece of zinc metal (Zn) into the acid in the test tube. Immediately go on to Reaction 6. Observe and record what happens in Reaction 5. Reaction 6 Using a test tube holder, quickly invert a second test tube over the mouth of the test tube in which the reaction is taking place. Remove the inverted tube after about thirty seconds and quickly insert a burning wooden splint into the mouth of the tube. (A "pop" indicates the presence of hydrogen gas) Note the appearance of the substance in the second test tube. Record all observations. Reaction 7. Add about 2 mL of 0.1 M zinc acetate (Zn (C 2H3O2)2) to a clean, dry test tube. Next, add about 2 mL of 0.1 M sodium phosphate (Na3PO4) solution to the same test tube. Observe what happens and note any changes in the mixture. Reaction 8 Add about 5 mL of sodium sulfite (Na2SO3) solution to a clean, dry test tube. To this solution, add about 1 mL of 6 M HCI. Heat it gently over the Bunsen burner, but do not boil it. Hold test tube at a slight angle aimed away from any people. Observe the odor given off by wafting some of the gas toward your nose. DO NOT DIRECTLY SNIFF THIS GAS! 4) HYPOTHESIS: Using what you know about the various types of chemical reactions, write hypotheses using the IF-THENBECAUSE format to predict the type of the reaction in each step. This means that you will be creating eight separate hypotheses. An example follows: eg. If Na is added to Cl2 then it will be a synthesis reaction because Na is a metal and Cl is a nonmetal. 5) OBSERVATIONS AND DATA Set up a data table in your lab book for observations of each of the above reactions. Allow an entire page for this data table in order that you have plenty of space to make complete observations. Please remember to use a straightedge to construct your table. 6) CALCULATIONS Write and balance an equation for each of the above reactions. Write the word reaction below the balanced molecular equation for that reaction. For example: 2Na(s) + Cl2 (g) → 2 NaCl(s) Sodium metal plus chlorine gas yields solid sodium chloride 7) CONCLUSION: Respond to your hypotheses using a table format to show whether each was supported or not and the data evidence (note the table entries are examples only): Hypothesis 1 2 3 4 Etc… Supported? yes no yes yes Data Evidence Burned producing gas, combining with O2 from air no precipitate formed, instead it bubbled indicating a gas both reactants were solutions and a white AgI ppt formed Pb is replaced by Al which appears as a dark sludge on the Al foil 10) QUESTIONS 1. In this experiment, what method was used to test for the presence of CO 2 gas? 2. What test was used to check for the presence of hydrogen gas? Write a balanced equation to represent this test, 3. Reaction 8 in the Calculations section above is actually represented by the following equation: Na2SO3 (aq) + HCl(aq) NaCl(aq) + H2O(l) + SO2(g) In addition to double replacement, what other reaction type is represented by it? Explain. JLD; 4-14-11