SUBATOMIC PARTICLES The three main subatomic particles found in atoms are protons, neutrons, and electrons. These particles are compared by mass, charge, and location below. Mass Proton 1 amu Neutron 1 amu Electron 1/1837 amu surrounding the nucleus Charge +1 0 -1 Location In the nucleus In the nucleus In the cloud The actual mass of a proton or a neutron is 1.67 X 10-24 grams. Since this is such a small number, scientists have come up with a relative scale for measuring the mass of protons and neutrons. The units of this scale are called atomic mass units (amu). Originally scientists based this scale on the mass of a hydrogen atom before finally deciding than one atomic mass unit is equal to 1/12 the mass of a carbon atom with 6 protons and 6 neutrons. Electrons have almost no mass in comparison to protons and neutrons and their mass is usually not even considered when calculating the mass of an atom. Atoms are identified by their atomic number (Z). The atomic number of an atom is the same as the number of protons found in the atom. The periodic table is arranged in order of increasing atomic number, beginning with hydrogen (atomic number 1) and moving down the table to larger atoms such as uranium (atomic number 92). If an atom is electrically neutral, the number of protons (+) will equal the number of electrons (-). Therefore, if you know the atomic number of an atom you also know how many protons and electrons are in that atom. All atoms of the same element have the same number of protons since this is what identifies an atom. If you know the atomic number of an atom you can look on the periodic table and find the symbol of that atom. The Mass Number (A) of an atom is the total number of protons and neutrons found in that atom. The mass number of an atom is not found on the periodic table. By knowing the atomic number and the mass number of an atom you can calculate the number of neutrons. #Neutrons = Mass Number - Atomic Number All atoms of the same element must have the same number of protons, but they may vary in their number of neutrons. Atoms of the same element with different numbers of neutrons are called isotopes. All atoms found on the periodic table have two or more isotopes. For example, hydrogen has 3 naturally occuring isotopes. They all have 1 proton but they vary in their number of neutrons from 0 to 2. Isotopes can be shown by writing out the name of the element with the mass number following or by using the symbols shown below. 1 2 3 hydrogen-1 H hydrogen-2 H hydrogen3 H 1 1 1 When using the symbols for isotopes, the atomic number is shown on the bottom beside the symbol and the mass number is shown on top beside the symbol. Hydrogen-1 has zero neutrons and hydrogen-2 has one neutron and hydrogen-3 has two neutrons. They are all different isotopes of hydrogen and only differ by their number of neutrons. Periodic tables show the atomic number of atoms and they also show the atomic mass of atoms. The atomic mass of an atom is the weighted average of the different isotopes of an element. The atomic mass for hydrogen is 1.007 amu. If you look at the mass of the 3 isotopes of hydrogen shown above you would expect the atomic mass to be 2 amu (the average of the 3 isotopes). The reason for the discrepancy is that hydrogen-1 makes up over 99% of all hydrogen atoms and this skews the average closer to 1 amu than the expected 2 amu. The atomic mass of an element is found by multiplying the mass of each isotope by its percentage and then adding them up. Example: There are two common isotopes found for boron atoms, boron-10 and boron11. Boron-10 comprise 19.78% of all boron atoms and the other 80.22% of boron atoms are boron-11. Calculate the atomic mass of boron. boron-10 = 10 amu X 19.78% = 197.8 boron-11 = 11 amu X 80.22% = 882.42 197.2 + 882.42 = 1079.62 /100 = 10.8 amu When calculating atomic mass you can check your answer by comparing it to the atomic mass found on the periodic table. The number on the periodic table should be very close to your answer. Your answer might very slightly because of rare isotopes that may not be included in the percentages when calculating atomic mass.