Safety Data Sheet (91/155/EEC)

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Safety Data Sheet
Material: BaselChemie BW-100
Date of print: 07.12.01 Date of last alteration: 01.10.2001
1 Identification of the substance/preparation and company
1.1 Identification of the substance or preparation:
Commercial Product Name: BW-100
1.2 Company/undertaking identification:
Manufacturer/distributor: BaselChemie Co.,Ltd
Address: Woonsu-Ree450-38, Changhang,SerCheon,ChungNam,Korea 325-906
Telephone: 82-41-956-7273~4
FAX: 82-41-956-7275
Information (Dept. Marketing): 82-16-546-9610
Emergency Number: 82-41-956-7273~4
2 Composition/information on ingredients
2.1 Chemical characterization (preparation):
Chemical characteristics
Polydimethylsilicone
Hazardous ingredients (EU):
CAS-No./ Material Content Warning Label from until Symbol R-Phrases
9016-00-6/ Methanol 0,3 %
3 Hazards identification
3.1 Critical hazards to man and environment:
R-Phrase Description
R10
Flammable.
4 First-aid measures
4.1 General information:
4.2 After inhalation:
Provide fresh air. In cases of sickness seek medical advice (show label if
possible).
4.3 After contact with the skin:
Wash with plenty of water or soap and water; immediately remove all
contaminated clothing. In cases of sickness seek medical advice (show label
if possible).
4.4 After contact with the eyes:
Rinse immediately with plenty of water for 10-15 minutes and seek medical
advice.
4.5 After swallowing:
Drink plenty of water in small portions and induce vomiting. Seek medical
advice immediately and produce the label or packaging.
4.6 Advice for the physician:
In case of contact with water material splits off (also in gastrointestinal
tract) methanol in larger amounts; therefore consider poisoning on methanol
and also observe known period of latency of several days!
5 Fire-fighting measures
5.1 Suitable extinguishing media:
water spray jet , extinguishing powder , foam , carbon dioxide .
5.2 Extinguishing media which must not be used for safety reasons:
5.3 Special exposure hazards arising from the substance or preparation itself, combustion
products resulting gases:
5.4 Special protective equipment for fire fighting:
Use respiratory protection independent of recirculated air.
6 Accidental release measures
6.1 Personal precautions:
Wear personal protective suit (see section 8.3). Avoid inhaling mists and
vapours. Avoid contact with eyes and skin.
6.2 Environmental precautions:
Do not introduce into sewer system or in shore-waters. Dam up escaped liquid
with earth or other suitable material. Retain contaminated
water/extinguishing water. Dispose of in prescribed marked containers.
6.3 Methods for cleaning up:
Remove mechanically and dispose of according to regulations. Absorb with a
liquid binding material such as diatomaceous earth and dispose of according
to regulations.
6.4 Further information:
Eliminate all sources of ignition.
7 Handling and storage
7.1 Handling
Precautions for safe handling:
Ensure adequate ventilation.
Precautions against fire and explosion:
Take precautionary measures against static discharges. Keep away from heat,
open flames, sparks and other sources of ignition. In partly emptied
containers liberation of explosive gases is possible.
7.2 Storage
Conditions for storage rooms and vessels:
Advice for storage of incompatible materials:
Further information for storage:
Keep container tightly closed and store in a well-ventilated place.
8 Exposure controls and personal protection equipment
8.1 Further information for system design and engineering measures:
8.2 Personal protection equipment
General protection and hygiene measures:
Do not eat, drink or smoke when handling. Do not breathe vapours. Avoid
contact with eyes and skin.
Respiratory protection:
gas mask filter A during prolonged exposure .
Hand protection:
PVC gloves , rubber gloves recommended .
Eye protection:
protective goggles recommended .
9 Physical and chemical properties
9.1 Appearance
Form.................................:
Colour...............................:
Odour................................:
9.2 Safety parameters Method
Flash point..........................:
Ignition temperature.................:
Lower explosion point................:
Upper explosion point................:
Vapour pressure......................:
Vapour pressure......................:
Density..............................:
Solubility in water..................:
pH-Value.............................:
Viscosity............................:
liquid
clear/opaque
mild
approx. 81°C (ISO 2719)
> 280 °C (DIN 51794)
unknowm
unknowm
< 50 hPa at 20 °C
< 120 hPa at 50 °C
0.99 g/cm3 at 25 °C (DIN 51757)
virtually insoluble
unknowm
70~80 mPa*s (DIN 51562)
10 Stability and reactivity
10.0 General information:
If stored and handled in accordance with standard industrial practices no
hazardous reactions are known.
10.1 Conditions to avoid:
10.2 Materials to avoid:
Reacts with water to form methanol .
11 Toxicological information
11.0 General information:
Product not investigated.
11.1 Acute toxicity:
Further information:
11.4 Further toxicological information:
Aerosol mist must not be inhaled, as lung damage can be expected. Product(s)
of hydrolysis:
Attention! Product may hydrolyse in gastro-intestinal tract and produce
methanol. According to literature methanol (67-56-1) irritates mucuous
membranes, has skin drying and narcotic effects up to coma or death.
Absorption by the skin is possible. Possibility of damage to heart,kidneys,
liver and optic nerves (blindness) over a period of time.
12 Ecological information
12.1 Information on elimination (persistence and degradability)
Further information:
By hydrolysis: Methanol and silanol- and/or siloxanol-compounds .
12.2 Behaviour in environmental compartiments
Further information:
12.3 Ecotoxicological effects:
No data known.
Effects in sewage treatment plants (bacteria toxicity: respiration-/reproduction inhibition):
Do not introduce large amounts into purification plants.
12.4 Further ecological information
General information:
Do not introduce into waters, sewage or soil.
13 Disposal considerations
13.1 Material
Recommendation:
Dispose of according to regluations by incineration in a special waste
incinerator. Small quantities may be disposed of in a domestic waste
incinerator. Observe local bye-laws.
13.2 Contaminated packaging
Recommendation:
Completely discharge containers (no tear drops, no powder rest, scraped
carefully). Containers may be recycled or re-used. Observe local/national
bye-laws.
14 Transport information
Not -Estabilish
15 Regulatory information
15.1 Warning Label (EU)
- Flammable
R-Phrase Description
R10
Flammable.
S-Phrase Description
S7/9 Keep container tightly closed and in a well ventilated place.
S16 Keep away from sources of ignition - No smoking.
15.2 National regulations:
16 Other information
16.1 Material
The above information describes exclusively the safety requirements of the
product(s) and is based on our present-day knowledge. It does not represent
a guarantee for the properties of the product(s) described in terms of the
legal warranty regulations. Properties of the product are\ to be found in
the respective product leaflet.
n.a. = not applicable, n.s. = not subject to
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