N o r t h E a st I n d ep en d e nt S c h o o l D i st ric t Chemistry Unit 5: Gases, Liquids, Solids Clarifying Statements May, 2006 In this unit, students will study the characteristics of the common phases of matter; namely solids, liquids, and gases. In order to effectively investigate these characteristics, the students must have a basic understanding of the kinetic molecular theory. This theory explains the properties of matter in terms of the “energy of the particles and the forces that act between the particles”. (Modern Chemistry HRW, p 303). By the end of this unit, students will be able to compare and contrast the states of matter in terms of kinetic energy, general properties (such as surface tension of liquids and diffusion of gases), and attractive forces between molecules (intermolecular forces). Gases The kinetic-molecular theory, as it is applied to ideal gases, accounts for the following properties: expansion, low density, compressibility, diffusion, effusion, and fluidity (Modern Chemistry HRW, p. 304-305). Students must be able to identify, describe, and explain these properties of gases. Students must recognize the “variables that influence the behavior of gases” (TEKS 7) such as pressure, temperature, volume, and number of particles. Students should know that barometers and manometers are used to measure pressure in millimeters of mercury and that atmospheres, torrs, and pascals are also units of pressure. Student should understand the relationship between the temperature scales of Kelvin and Celsius. This relationship is based on the fact that absolute zero, the lowest possible temperature, is equivalent to 0 Kelvin or –273C. Students should also understand that the term standard temperature and pressure (STP) describes a system at 0C and 1 atm. This information is important as it will be used by students in future calculations. Clarifying statements are intended to deepen teachers’ understanding of science concepts and serve as a guide for instructional design. They are not intended to serve as student instructional materials. This publication is the property of North East Independent School District. Duplication in whole or in part, outside of NEISD, is prohibited without express written permission from NEISD. 1 N o r t h E a st I n d ep en d e nt S c h o o l D i st ric t Chemistry Unit 5: Gases, Liquids, Solids Clarifying Statements May, 2006 Students must also understand how gas laws are mathematical models of the following relationships: pressure and volume (Boyle’s Law), volume and temperature (Charles’s Law), and pressure and temperature (Gay-Lussac’s Law). The following graphs are representations of these relationships. Dalton’s law of partial pressure enables scientists to accurately measure gases by water displacement. Students must be able to use this law in order to calculate pressure of a gas collected over water. Students must also be able to use the combined gas law to calculate the effect of varying the conditions of a gas. The ideal gas law establishes the relationship between pressure, volume, temperature, and the number of moles of a gas. Students must be able to use the ideal gas law in order to calculate property values of a gas at STP. Liquids The kinetic-molecular theory, as it is applied to liquids, accounts for the following properties: fluidity, indefinite shape, definite volume, high density, ability to diffuse, relative incompressibility, and surface tension (Modern Chemistry HRW, p. 363-364). Solids The kinetic-molecular theory, as applied to solids, accounts for the following properties: definite shape, definite volume, definite melting point, very high density, incompressibility, and very low rate of diffusion. (Modern Chemistry HRW, p. 368-369). Clarifying statements are intended to deepen teachers’ understanding of science concepts and serve as a guide for instructional design. They are not intended to serve as student instructional materials. This publication is the property of North East Independent School District. Duplication in whole or in part, outside of NEISD, is prohibited without express written permission from NEISD. 2 N o r t h E a st I n d ep en d e nt S c h o o l D i st ric t Chemistry Unit 5: Gases, Liquids, Solids Clarifying Statements May, 2006 Phase Changes At this point, students should be able to compare and contrast the general properties of solids and liquids. They should also be familiar with phase change terms such as evaporation, condensation, sublimation, etc. As matter changes states, it either absorbs or releases heat energy. Students must know that heat is absorbed as a solid becomes a liquid, as well as when a liquid becomes a gas. Conversely, they should also know that heat is released when a gas becomes a liquid and when a liquid becomes a solid. If time permits, teachers may wish to study equilibrium and Le Chatelier’s principle in order to further explain the energy changes that occur as matter changes state. Students must be able interpret phase diagrams (such as the following), that depict the effect of pressure and temperature on phase states. They should also be able to understand the significance of the triple point and critical point. Finally, students must be able to explain the concept of equilibrium vapor pressure; and be able to describe boiling, freezing, and melting in terms of kinetic energy, temperature, and pressure. Throughout this unit, students will have many opportunities to analyze data tables and graphs. Students will also continue to strengthen their measuring techniques and general lab skills, as well as improve their knowledge of significant figures and the metric system. Clarifying statements are intended to deepen teachers’ understanding of science concepts and serve as a guide for instructional design. They are not intended to serve as student instructional materials. This publication is the property of North East Independent School District. Duplication in whole or in part, outside of NEISD, is prohibited without express written permission from NEISD. 3