MATERIAL SAFETY DATA SHEET Penn Valley Paint 8000 Bristol Pike Levittown, PA 19057 215-949-0800 24 Hour Emergency Phone Number Chemtel 800-255-3924 SECTION 1: PRODUCT IDENTIFICATION Date Prepared: January 15, 2003 HEALTH FIRE REACTIVITY PPE Product: Code: 1 0 0 X Calbar Metal Siding Paint 18-400 series This form covers all stock colors and bases . Hazard summary (as defined by OSHA Hazard Communication Standard, 29 CFR 1900.1200): Physical Hazards: Health Hazards: None Based on nuisance particulate, ammonia, ethylene glycol, inhalation (TLV/PEL). Based on ammonia, ethylene glycol, acrylic emulsion, irritant (eye, skin, mucous membranes). Based on ethylene glycol, harmful (CNS depression, kidney damage.) Read the entire MSDS for a more thorough evaluation of the hazards. SECTION 2: INGREDIENTS Water Acrylic Polymer Silica Propylene Glycol Ammonia Titanium Dioxide Texanol Ester CAS NUMBER % Wt. 7732-18-5 Proprietary 14808-60-7 57-55-6 7664-41-7 13463-67-7 25265.77.4 10.0-15.0 55.0-60.0 10.0-15.0 2.0-7.0 > 5.0 > 5.0 ACGIH TLV (a) OSHA PEL NR N/E N/E 50 ppm(c) 25 ppm 10 mg/m3 N/E NR N/E N/E 50 ppm(c) 50 ppm 10 mg/m3 N/E Ingredients not precisely identified are proprietary or non hazardous. Values are not product specifications. gt = greater than, lt = less than, ca = approximately, NE = not established, NR = not required, C = ceiling. SECTION 3: PHYSICAL DATA Boiling Point: Vapor Pressure (mmHg at 20 C): Vapor Density (air = 1): pH: Specific gravity: % Volatile by volume: Appearance: Solubility in water: Characteristic odor: No data on this mixture. Approximately 212 °F (water). No data on this mixture. No data on this mixture. 9.5 - 10.0 Approximately 1.10 Approximately 45 Viscous opaque liquid. Color dependent on specific formulation. Dilutable. Slightly sweet, hint of ammonia SECTION 4: FIRE AND EXPLOSION HAZARD DATA Flash point (and method): Auto ignition temperature.: Flammable limits (STP): Extinguishing media: Special fire fighting protective equipment: Unusual fire and explosion hazards: burning yielding oxides of carbon. Non-combustible. Not applicable. Not applicable. Not applicable. Self contained breathing apparatus for fire conditions. Monomer vapors may be evolved at elevated temperatures. Dried polymer films are capable of SECTION 5: REACTIVITY DATA Stability: Incompatibility (Materials to avoid): Hazardous decomposition products: Hazardous polymerization: Stable None None Will not occur. MSDS Metal Siding ~ page two SECTION 6: HEALTH HAZARD ASSESSMENT General: No toxicity information is available on this specific preparation; this health hazard assessment is based on information that is available on its components. Ingestion: The principal toxic effect of this product, when swallowed, is likely to be due to the ethylene glycol content that causes kidney damage. Symptoms of ingestion may include abdominal discomfort and pain, dizziness, malaise, lumbar pain, central nervous system depression and other symptoms related to ethylene glycol ingestion. Severe kidney damage accompanies gross overexposure. Eye contact: This product will probably irritate eyes upon direct contact. The dispersed dusts may cause corneal abrasions. Skin contact: Direct, prolonged contact with skin may cause irritation. Skin absorption: This material is known to be absorbed through the skin and no systematically toxic effects are known via this route. Inhalation: Inhalation of dusts, mists and vapors from this product may irritate the nose, throat and lungs. High vapor concentrations caused by heating in confined spaced without adequate ventilation may result in severe irritation, headache, dizziness, nausea and vomiting. Use appropriate respiratory protection when spraying this product (Section 8). Other effects of overexposure: None known. First Aid Procedures: Skin: Wash thoroughly with soap and water. Eyes: Rinse with plenty of water and consult a physician if burning, redness, itching, pain or other symptoms persist or develop. Ingestion: No specific recommendation. Seek medical attention immediately. Inhalation: Remove subject to fresh air. If respiratory symptoms persist (irritation, cough, nausea, dizziness, ect). consult a physician SECTION 7: SPILL OR LEAK PROCEDURES Steps to be taken in case material is spilled or released: Keep unnecessary people away. Surfaces may be slippery, use caution. Dike and contain spill with inert material (sand, absorbent, earth, etc.). Transfer liquid to containers for recovery or disposal. Transfer solid diking/absorbent material to separate containers for disposal. Keep spills and runoff out of sewers and bodies of water. Disposal Method: Discarded product is a non-hazardous waste under RCRA criteria (40 DFR, part 261). However, even small amounts of emulsion will discolor bodies of water. Reuse uncontaminated material when possible. Landfill or incinerate solids and contaminated diking material in accordance with local, state and federal regulations. Container Disposal: Drain containers completely. Empty containers may retain small amounts of residual product. Observe all hazard precautions when handling empty containers. Puncture or otherwise destroy container and dispose of as non-hazardous waste in accordance with local, state and federal regulations. SECTION 8: SPECIAL PROTECTION INFORMATION TLV or Suggested control Value: No TLV assigned to this mixture. Minimize exposure in accordance with good hygiene practice. Ventilation: Use local exhaust to keep exposures to a minimum. Respiratory protection (specify type): Not normally required under normal conditions of use. If OSHA PEL's for components may be exceeded then use MSHA-NIOSH approved respirator for the applicable hazard. Refer to OSHA standards in 29 CFR, 1910.134. Protective clothing: Use adequate clothing to minimize skin contact. Clean clothing on a regular basis. Eye Protection: Chemical tight goggles or face shield recommended to avoid eye contact. Other Protective Equipment: Provide eyewash station. SECTION 9: SPECIAL PRECAUTIONS OR OTHER COMMENTS Precautions to be taken in handling or storing: Keep from freezing. Product may coagulate. If frozen, thaw slowly at room temperature. Avoid breathing mists, vapors or aerosols. Avoid skin and eye contact. ACGIH CAS IARC LEL MG CU M MM MPPCF MSHA NA ABBREVIATIONS USED: - American Conference of Governmental Industrial Hygienists -Chemical Abstracts Service - International Agency for Research on Cancer -Lower Explosive Limits -Milligram per Cubic Meter -Millimeters -Millions of Particles per Cubic Foot -Mines Safety and Health Administration -Not Applicable N/E NIOSH PEL PPM OSHA RECM TCC / PM TLV UEL -Not Established -National Institute of Occupational Safety and Health -Permissible Exposure Level -Parts per Million -Occupational Safety and Health Administration -Recommended -Tag – Closed Cap / Pensky - Martin -Threshold Limit Values -Upper Explosive Limits DISCLAIMER SECTION. The information contained herein is based on data considered to be accurate. Penn Valley Paint makes no warranties express or implied and assumes no responsibility for the accuracy or completeness of the data. Penn Valley Paint further assumes no responsibility for personal injury or property damage to customers, users, or third parties caused by this material. Such customers or users assume all risks associated with the use of this material. MSDS/MetalSiding03