Term 2 Final Exam Review Question Answers Pg. 87 #17-24 17. 12,000 g 18. 50. mm 19. 0.128 L 20. 0.081 ms 21. 1011 pg 22. 400 23. 1031 24. 0.9814 g/cm3 Pg. 188, #3, 4, 6, 8, 9, 21-23, 25 3. A 4. D 6. B 8. B 9. C 21. Hydrogen does not truly belong to any family of elements 22. They have one valence electron beyond their inner core that is relatively easy to lose, resulting in an ion with a 1+ charge. 23. The are one electron short of 8 electrons in their outer energy level. As a result, they commonly obtain an extra electron, forming an ion with a 1charge. 25. The increasing number of protons pulls the electrons closer to the nucleus. Pg. 216 #1-9, 28 1. C 6. B 2. D 7. A 3. C 8. C 4. C 9. C 5. D 28. Their outermost electron shells have the stable s2p6 configuration (s2 for helium). Pg. 220 #7-10, 22, 27, 31, 35-39, 43 7. Alpha radiation is a stream of helium nuclei. Beta rays are electrons; gamma rays are high-energy rays, similar to x-rays. 8. Positively charged protons and neutral neutrons are found in the nucleus with a cloud of negativity charged electrons surrounding them. Protons and neutrons have a mass of 1 amu; electrons have a mass of 1/1800 amu. 9. Atomic number = number of protons; mass number = number of protons + number of neutrons. Electric charge indicates gain or loss of electrons. 10. They have the same number of protons and electrons, but different numbers of neutrons 22. In general, larger atoms have lower ionization energies because their electrons are in higher energy levels farther from the nucleus. 27. (a) 80 p+, 121 n0, 78 e(b) 53 p+, 74 n0, 54 e31. 6630Zn 35. (a) Sr = [Kr]5s2 (b) Lu = [Xe]6s24f145d1 36. (a) Ca (b) I 37. (a) S = [Ne]3s23p4 (b) Hg = [Xe]6s24f145d10 38. P, As, Ge 39. I+, I, I43. In3+ = [Kr]4d10 Pg. 252 #1-9, 19. 21-25, 28, 34 1. B 6. C 2. D 7. C 3. B 8. D 4. A 9. C 5. D 19. Atoms tend to gain, lose, or share electrons in order to acquire a full set of valence electrons. It helps us predict the way atoms bond. 21. Cations have a positive charge. Anions have a negative charge. Monatomic ions are one-atom ions. Polyatomic ions are multiple-atom ions. 22. A single bond has one shared pair of electrons, a double bond has two, and a triple bond has three. 23. The charge of the copper ion is different. The Roman numerals show the first to be Cu1+ and the second to be Cu2+. 24. A substance that dissolves in water to produce H+ ions. Like ionic compounds, acids separate into a cation and an anion on water. 25. When the electronegativity of one atom in a bond is significantly different from that of the other atom, a polar bond results. When the atoms have electronegativities that are close of the same, a nonpolar bond results. 28. (a) AgNO3 (d) H2SO4 (b) Mg(OH)2 (e) Pb(C2H3O2)2 (c) CCl4 (f) Fe(NO3)3 34. (a) antimony sulfide (d) carbonic acid (b) iron (II) sulfide (e) silicon dioxide octahydrate (c) sodium oxide (f) calcium sulfate dihydrate Pg. 276 #1-6, 8, 9, 21, 25, 30 1. D 5. A 2. B 6. C 3. B 8. A 4. D 9. A 21. The polarity of a molecule is determined by the shape of the molecule and the type of bond within it. Polar bonds must be present to create the slight positive and negative charges. The shape of the molecule determines whether or not the charges are balanced in the molecule. 25. (a) Nonpolar. Br2 has no polar bonds (b) Polar. Oxygen is more electronegative than carbon. (c) Polar. Polar bonds exist and two pairs of unshared valence electrons result in a bent shape. (d) Nonpolar. The 6 flourine atoms are grouped evenly around the sulfur atom. (e) Nonpolar. The chlorine atoms are arranged on opposite side of the atom and form a 180 bond angle. (f) Polar. This molecule has a linear shape, but differences in electronegativity between the two atoms cause the molecule to be polar. 30. (a) Bent, sp3 (c) Pyramidal, sp3 (b) Tetrahedral, sp3 (d) Linear, sp3 Pg. 300 #1, 3-8, 24, 25, 39 1. C 6. B 3. C 7. A 4. D 8. B 5. D 24. (a) 4 P + 5 O2 2 P2O5 (b) 2 NaNO3 2 NaNO3 + O2 (c) 2 C8H18 + 25 O2 16 CO2 +18 H2O (d) H2SO4 + 2 NaOH Na2SO4 + 2 H2O 25. (a) Decomposition. A complex substance has decomposed into two simpler substances (b) Double-replacement reaction. Ions form from different compounds have replaced each other. (c) Single-replacement reaction. An uncombined element has replaced an atom in an ionic compound. (d) Direct combination action. Two substances have combined to form a new compound. 39. (a) 2 NH3 N2 + 3 H2, decomposition. (b) 3 Ba(C2H3O2)2 + 2 Na3PO4 Ba3(PO4)2 + 6 NaC2H3O2, doublereplacement. (c) Zn + 2HCl ZnCl2 + H2, single-replacement. (d) 2 Hg + O2 2 HgO, direct combination. Pg. 306 #15-29, 32-41 15. Nitric acid – acid 16. Calcium iodide – ionic compound 17. Iron (III) oxide – ionic compound 18. Dinitrogen tetroxide – molecule 19. Hydroflouric acid – acid 20. Copper (II) phosphate – ionic compound 21. Ammonium chloride – ionic compound 22. Carbon monoxide – molecule 23. Tetrahedral – nonpolar 24. Bent – polar 25. Linear – nonpolar 26. Linear – polar 27. Trigonal planar – polar 28. Trigonal planar – nonpolar 29. Trigonal planar – polar 32. Decomposition: 2 Al(OH)3 Al2O3 + 3H2O 33. Direct combination: 4 Fe + 3 O2 2 Fe2O3 34. Single-replacement 35. Direct combination: 2H2 +O2 2H2O 36. Direct combination: 2Na + Cl2 2NaCl 37. Decomposition 38. Double-replacement 39. Single replacement: 2AgNO3 + Zn Zn(NO3)2 + 2Ag 40. Double-replacement: Al2(SO4)3 + 3BaCl 2AlCl3 + 3BaSO4 41. 2C2H6 +7O2 4CO2 + 6H2O Pg. 342 #1-9 1. A 2. A 3. B 4. D 5. B 6. B 7. A 8. C 9. B Pg. 376 #1-7, 56, 58 1. A 5. D 2. D 6. A 3. B 7. A 4. B 56. 373 L O2 58. (a) 2.64 g Cu (b) Percent yield = Actual yield/expected yield x 100% = 2.51 g Cu/2.64 g Cu x 100% = 95.1% Pg. 412 #11-14 11. (a) 82.3 g (b) 108. L 12. 2.498 mol C 13. 12.6 g Li 14. 3.33 L H2; 1.67 L O2 Pg. 590 #1, 2, 9 1. A solution is a homogeneous mixture of two or more substances in a single state. A solution can be separated into its individual components by distillation or crystallization. 2. Substance dissolved is the solute. (such as salt in seawater) Dissolving agent is the solvent. (water in seawater) 9. Raise the temperature, or stir. Pg. 652 #1, 3, 4, 9 1. Acids—taste sour, conduct electricity, react with metals, turn blue litmus paper red, neutralize bases. Bases—taste bitter, feel slippery, conduct electricity, turn red litmus paper blue, neutralize acids. 3. HCl (acid) + NaOH (base) NaCl (salt) + H2O 4. A strong acid completely dissociates to form H+ ions; a weak acid only partially does so. 9. See Figure 18-25 in your book. Pg. 898 #1, 2, 17, 21 1. Fission—the splitting of the atomic nucleus of a heavy element into two lighter elements. Fusion—light nuclei are combined under thermonuclear conditions to create larger nuclei 2. Gamma radiation is much more energetic than alpha or beta. 17. (a) inorganic – carbon dioxide (d) inorganic – calcium carbonate (b) organic – ethane (e) organic – ethanamine (c) organic – acetic acid 21. C6H12O6 + 6O2 6H2O + 6CO2 Photosynthesis is the opposite reaction