Notes #1 Introduction to Chemical Reactions Name Date________ Block____ Chemical reactions involve the rearrangement of atoms and ions to form new substances. Chemical reactions involve chemical changes. Substances that exist before a chemical reaction are called reactants. The substances that exist after the chemical reaction are called the products. There are a few criteria used to determine whether a chemical reaction has occurred. These include the formation of one or more new substances (that did not exist before the reaction), an energy change (example: energy that is released as heat and/or visible light, or energy that is absorbed); a change in color. A) A new substance has been formed. 1) a gas is formed but none of the reactants had been a gas; Ex.: you would observe bubbles rising in a mixture of liquids or a vapor condensing in the cooler air above two liquids that you had mixed or a vapor is observed above a heated solid that is releasing a gas; 2) a solid is formed but none of the reactants had been a solid; Ex.: you mix two clear colorless liquids and an opaque yellow solution forms, and upon standing, a yellow solid settles to the bottom of the test tube and a clear colorless liquid remains on top; 3) a liquid is formed but none of the reactants had been a liquid; Ex.: a solid is placed in a small open dish and a liquid is observed to form around the solid; or two gases react and a liquid forms. B) There is an energy change. 1) no heat is added but the temperature of the reactants increases or decreasesas the reaction progresses; 2) the reactants are not refrigerated but the temperature of the reactants decreases as the reaction progresses; 3) visible light energy is given off by the reactants as the reaction progresses; Be VERY careful here –often we raise the temperature of the reactants to start the reaction by heating the reactants. (The particles of the reactants must have enough kinetic energy for the reaction to occur.) The addition of heat to start a reaction is not the same as the heat given off by the reaction once it has started. Ex.: you heat charcoal until it starts “burning” (that is, reacting with the oxygen in the air) on its own; then you remove the “addition of heat” such as the match, electric starter, etc. The reaction of the carbon with the oxygen in the air continues and releases enough heat energy to keep the reaction going (until one of the reactants - charcoal or oxygen - is used up) and sometimes visible light is also given off. If you did not “help” the reaction get started, it might take many years for the reaction to go to completion to produce carbon dioxide gas and water vapor. Any heat release from this “unaided” reaction would occur so slowly so you would not be aware that the reaction was actually exothermic. 1 C) There is a change in color. You have only the colors of the visible light spectrum, the intermediate colors of the visible spectrum and white, black, gray and silver (actually tints of black), gold, copper, brown, from which to choose. SHADES of a color mean that the observed color is DARKER than the pure color; TINTS of a color mean that the observed color is lighter than the pure color. Names of colors that are used to describe substances are given below. If two colors are hyphenated, the first color is the more dominant color observed. red red-orange orange-red orange orange-yellow yellow yellow-green green-yellow green green-blue blue-green blue blue-violet gray (usually dull) violet-blue silver (usually shiny) violet gold (usually shiny) white copper (usually shiny) black brown (includes: cream, tan, and beige) Deeper or darker shades of red and lighter or paler tints of red are still red. You should always include “dark” or “light” if the adjective applies to an observed color. “Deep” and “pale” refer to the color intensity (also called color saturation). Deep is NOT the same as Dark; light is not the same as pale. A dark red solution may appear to be a pale red if the original solution is diluted by the addition of water or other colorless solvent, or if viewed in a much smaller amount such only a few drops. Only a change from one color listed above to another is an actual color change. IF YOU HAVE DIFFICULTY DISTINGUISHING BETWEEN COLORS, ASK FOR HELP. IF YOU ARE COLOR-BLIND, LET ME KNOW. Remember: CLEAR means that you can see through it. CLEAR is NOT a color! True solutions and some solids (such as gem-quality crystals) may have a color and still be clear. NOTE: Changes in physical state (solid ↔ liquid ↔ gas) are not always indications of chemical reactions. Ice is water in the solid state H2O(s); water vapor is water in the gas state, H2O(g). Bubbles may be observed rising from within a liquid if the liquid is being heated and: a) there had been gas dissolved in the liquid (carbonated beverages contain CO2 gas dissolved in water; tap water and water obtained from oceans, rivers, lakes, streams, etc., contain dissolved O2 gas as well as other atmospheric gases); b) the liquid itself is undergoing a change in physical state from liquid to gas at its boiling point.. A gas may be said to be a new substance if the reactants were both solids and there was no evidence of melting, or one or both of the reactants were liquids and bubbles are observed rising from within the solution and there is no addition of heat. Remember: you must be aware of the conditions under which the reactants are put together. 2