Chapter 2: Chemical Reactions Section 1: Observing Chemical Changes How can matter and changes in matter be described? In terms of two kinds of propertiesphysical properties and chemical properties Changes in matter can be described in terms of physical or chemical changes What is a physical property? A characteristic of a substance that can be observed without changing the substance into another substance Examples: ice melting, color, hardness, texture, shine, etc. What is a chemical property? A characteristic of a substance that describes its ability to change into other substances Examples: burning magnesium, rusting What is the difference between a physical and a chemical reaction? A change in matter that produces one or more new substances is a chemical change, or chemical reaction Physical change examples: braiding your hair, squashing a marshmallow Chemical change examples: burning of gasoline, burning a marshmallow How can you tell when a chemical reaction occurs? Chemical changes occur when bonds break and new bonds form Chemical reactions involve two main kinds of changes that you can observe-formation of new substances and changes in energy What are some changes in properties that indicate a chemical change? Precipitate – a solid that forms from a solution during a chemical reaction Color change may indicate a chemical reaction Gas production – bubbles How do you categorize changes in energy? Endothermic – A reaction in which energy is absorbed – Examples: baking soda and vinegar gets cooler when combined Exothermic – A reaction that releases energy in the form of heat – Examples: burning of airplane fuel Section 2: Describing chemical reactions What information does a chemical equation contain? Chemical equations use chemical formulas and other symbols instead of words to summarize a reaction Reactants – substances you have at the beginning Products – new substances produced when the reaction is complete What does the principle of conservation of mass state? That in a chemical reaction, the total mass of the reactants must equal the total mass of the products Matter is neither created nor destroyed What does open or closed system mean? Open system – matter can enter from or escape to the surroundings Closed system – matter is not allowed to enter or leave What must a balanced chemical equation show? The same number of each type of atom on both sides of the equation Represents the conservation of mass Coefficients – a number placed in front of a chemical formula in an equation that tells you how many atoms or molecules of a reactant or product take place in the reaction How do you balance chemical equations? Count the # of atoms of each element in the reactants & products ID element that is not equal on both sides Add coefficient to the front of the formula that will make the # = on both sides for that element Sample Problems Sample Problem: Reactants Products 1 Zn 1 Zn 1H 2H 1 Br 2 Br Zn + HBr H2 + ZnBr2 Multiply HBr x 2 to correct (balance) Reactants Products Zn + 2HBr H2 + ZnBr2 1 Zn 1 Zn 2H 2H 2 Br 2 Br Try these!! 2Na + Cl2 2NaCl Ca + Cl2 CaCl2 2H2O 2H2 + O2 N2 + 3 H2 2NH3 2Al2O3 4 Al + 3 O2 P4 + 3 O2 P4O6 3Fe + 4H2O Fe3O4 + 4 H2 What are the three categories of chemical reactions? Synthesis Decomposition Replacement What is a synthesis reaction? When two or more substances combine to make a more complex substance –A + B AB –2H2 + O2 2H2O Example: hydrogen and oxygen to make water What is a Decomposition reaction? Breaking down compounds into simpler products –AB A + B –2H2O2 2H2O + O2 Example: Hydrogen peroxide decomposes into water and oxygen gas What is a replacement reaction? When one element replaces another in a compound, or when two elements in different compounds trade places Example: copper metal obtained by heating copper oxide with carbon Single (one element replaces another) –AB + C AC + B –Zn + 2HCl ZnCl2 + H2 or double (elements appear to trade places with another compound) –AB + CD AC + BD –NaCl + AgF NaF +AgCl Section 3: Controlling Chemical Reactions How is activation energy related to chemical reactions? The minimum amount of energy needed to start a chemical reaction All chemical reactions need a certain amount of activation energy to get started What factors affect the rate of a chemical reaction? Surface area – the greater the surface area that faster the reaction (ex. Chewing) Temperature – raising the temperature causes particles to move faster and therefore have more energy; they also come into contact more often; lowering temperature slows things down Concentration – amount of substance in a given volume; increased concentration-increased reaction Catalysts – increases the rate of a reaction by decreasing the energy needed to start – Enzymes: biological catalysts Inhibitors – material used to decrease the rate of reaction (ex. preservatives in food)