Sedimentary Petrology SEDIMENTARY ROCKS Disintegration Decomposition (Mechanical) (Chemical) Air Water Temperature Frost Chemical changes Abrasion by ice Wind Decay resulting in weathering The decomposition and disintegration of rocks on the earth’s surface usually occur together, but one process is usually predominant. Decomposition is more active in warm, moist, low-lying areas; disintegration occurs mainly in the drier, higher and colder regions of the earth’s surface. DECOMPOSITION: The principal AGENTS of decomposition are water and air. The chief PROCESSES of decomposition are solution, oxidation, hydration and carbonation. Nearly all minerals are acted upon to some extent by water, especially when it contains certain dissolved substances. Some, however, are more susceptible than others and minerals may thus be divided into those which are relatively resistant, such as quartz, muscovite and zircon, and those which are altered with comparative ease, such as the feldspars and most of the ferromagnesian minerals. The process of oxidation involves the alteration of minerals, with the production of oxides. It is especially active with ironbearing minerals, forming the iron oxides haematite and limonite. Hydration is a process by which minerals are altered into substances rich in combined water. Magnesium-bearing minerals, such as olivine, are thus altered into serpentine and talc. (Mg,Fe)2SiO4 Mg6[Si4O10](OH) (olivine) (serpentine) In carbonation, the minerals are altered, with the formation of carbonates. It is especially effective with those minerals containing the alkali metals sodium and potassium, as well as calcium and magnesium. The decomposition of a granite furnishes many different kinds of minerals: Unaltered minerals: Includes quartz and zircon, which form sand grains. Muscovite produces mica grains. http://continue.to/geonotes Insoluble residues: Includes hydrous aluminium silicates, which are fundamental constituents of clays; and iron oxides, which are the colour matters of rocks. Soluble substances: Includes salts of potassium, sodium, calcium, magnesium, iron, etc., and silica. DISINTEGRATION: In high mountains, deserts and snow- or icecovered regions, the process of decomposition is largely in abeyance and disintegration is the dominant mode of breaking down rocks. Disintegration may result from a variety of causes. The great diurnal variations of temperature in deserts and mountainous regions cause strains to be set up in the surface layers of rocks, by which fragments are scaled off. The process is known as exfoliation. The freezing of water in fissures tends to disrupt rocks into angular fragments and much of the weathering in high mountains takes place in this way, the summits being covered with a thick layer of rock debris. The abrasive action of sand carried by wind or water causes the disintegration of rocks in deserts, or in the channels of swift-running, sandladen rivers. Glaciers my pluck and rend boulders from their beds; and by their slow restless movement grind the material they carry against the sides of the containing valleys, with the formation of sand and mud. Most streams issuing from glaciers are heavily laden with materials derived from this action. The pounding of waves may result in much disintegrative action, as is proved by extensive coast erosion. Finally, organic agents often have a marked mechanical effect upon rocks. The roots of plants prise open the fissures or rocks in their search for moisture and nourishment; burrowing animals turn over the soil and subsoil; and man himself, by tilling the ground, deforestation, tunnelling, quarrying, mining and in numerous other ways, helps to disintegrate the rocks. By disintegration, a granite will break up into a coarse sand composed of fragments of quartz, feldspar and micas, mixed with pieces of rock not yet broken down into the component minerals. Many granite areas carry sands of this composition, which are called arkose sands, or, when accumulated, arkose. A basic rock broken up in the same way gives rise to a rock called wacke or greywacke, which is composed of plagioclase feldspar, ferromagnesian minerals and quartz. Disintegration may also produce rough, angular rubble consisting of any kind of rock, which may mantle a mountain-top or accumulate by the action of gravity at the foot of a slope. These accumulations are called talus or scree when unconsolidated, and breccia when consolidated or cemented into a coherent mass. The resultant of the twin processes of decomposition and disintegration is weathering, and the product thereof, in the first place, is the mantle of loose, broken and largely decomposed material, the regolith, which covers the surface of the earth. The finely broke upper layer of the regolith, well aerated and mixed with decayed organic matter, is the soil. http://continue.to/geonotes TRANSPORTATION: The soluble or insoluble material supplied by weathering is either accumulated in place or is transported and deposited elsewhere. The agents of transport are rivers, waves, oceans currents, wind, and glaciers. The loess of China is believed to be simply an extensive deposit of wind-blown dust derived from the Asian deserts. Wind is by far the most efficient agent of rounding, and grains which have suffered long transport by wind show almost perfect spherical forms. Ice transport, however, permits very little rounding. Wind, again, is the most efficient sorted of grains, and deposits carried by wind are often characterised by their homogeneity. In ice transport, however, there is little or no sorting of materials, and on melting or retreat of the ice, it is dumped down into an unassorted and heterogeneous mixture of rock flour, grains, pebbles and boulders of all sizes. DEPOSITION: The ultimate destination of transported material, whether carried by water, wind or ice, is the sea, but it may be temporarily deposited on the land, and the deposits thus formed may persist for several geological periods before they resume their march to the sea. This leads to a distinction between continental and marine deposits. Deposition may be either mechanical or chemical, according to whether it affects the mechanically transported insoluble material or the substances carried in solution. The material carried in suspension or in other ways by water, wind and ice is deposited when the transporting medium is overloaded, when its velocity is checked, or when it suffers a chemical or physical change. Very extensive deposits of clay, silt and sand thus occur in the lower parts of river systems and also where rivers debauch into the sea(in deltas). The settlement of material entering the sea is aided not only by decrease in velocity of the river current, but also by admixture of salt water, which promotes a physical change (flocculation) favourable to the deposition of suspended material. The soluble material derived from weathering may be deposited either on land or in water, directly by physicochemical processes such as precipitation, or indirectly by the agency of organisms. http://continue.to/geonotes Sedimentary Rocks MINERALOGICAL, TEXTURAL AND STRUCTURAL CHARACTERS: Mineral composition: The minerals of sedimentary rocks fall into two classes: Insoluble residues of rock decomposition: This includes the groups of: Clay minerals such as kaolinite, halloysite, etc. Micaceous minerals, including the hydromicas and chlorite. Aluminium hydroxides like bauxite, gibbsite, etc. Ferric oxides and hydroxides. Comparatively durable minerals from pre-existing rocks. These include: Quartz (most abundant) Accessory minerals like zircon, rutile, tourmaline, garnet, kyanite, magnetite, etc. Mineral composition also depends upon the nature of the rocks forming the gathering round of the material. If the country rock consists mainly of some mineralogically uniform rock such as quartzite or a granite poor in ferromagnesian minerals and accessory minerals, the composition of the sediment resulting from its denudation will be simpler than that resulting from the waste of a lithologically or mineralogically heterogeneous region. The duration and nature of the transport is also a factor in determining the mineral composition. Long, continued drifting of particles separates them according to mass and surface area, and therefore according to composition. Wind is a particularly efficient sorter of sand grains. In deserts, mica flakes and dust are blown far away, and the remaining sands are sifted and redistributed until there is an approach to mineral uniformity. Long, continued transport in rivers or along shores may be almost equally effective in producing clean, graded and uniform deposits. Transportation tends to destroy the softer, more cleavable and brittle mineral grains, and thus produces greater mineral uniformity in the final material. Those constituents, such as boulders, pebbles or mineral grains which have been formed elsewhere and have been brought into a sediment from outside are termed allogenic (originating elsewhere); those constituents which have been formed de novo/in situ are called authigenic (formed in place or on the spot). TEXTURES OF SEDIMENTARY ROCKS: Textures of sedimentary rocks are defined by at least six factors: Origin Of Grains: A sedimentary rock may be partially or wholly composed of clastic(allogenic) grains, or chemically or http://continue.to/geonotes organically evolved(authigenic) components, giving it contrasting textures. Thus, rocks rich in clastic grains of any size, shape and composition are said to show clastic textures and these form the two principle types of sedimentary textures. Size OF Grains: The grain size in sedimentary rocks varies within wide limits. Individual grains of less than 0.002mm or more than 250mm may form a part or whole of these rocks. Accordingly, rocks are divided into fine grained (grain size < 1mm), medium grained (grain size between 1mm and 5mm) and course grained (grain size > 5mm). The type of weathering, the nature of the parent rock and the duration of transport are some of the factors that cause a variation in the grain size of the sediments. HOLMES’ CLASSIFICATION OF SEDIMENTARY FRAGMENTS: GRADE Boulders Cobbles Pebbles Gravel Very Coarse Sand Coarse Sand Medium Sand Fine Sand Silt Dust, Mud & Clay SIZE RANGE >200mm 200mm - 50mm 50mm - 10mm 10mm - 2mm 2mm - 1mm 1mm - 0.5mm 0.5mm - 0.25mm 0.25mm - 0.10mm 0.10mm - 0.01mm <0.01mm MAIN GROUP RUDYTES GRAVEL SAND SILT CLAY WENTWORTH-UDDEN SCALE (SI): SIZE RANGE > 265mm 64mm - 256mm 4mm - 64mm 2mm - 4mm 1/16mm - 2mm ½56mm - 1/16mm < 1/256mm PARTICLE Boulder Cobble Pebble Gravel Sand Silt Clay Shape Of Grains: Individual outlines of sediments are generally of considerable significance in defining the textural characteristics. These grains may be round, smooth and spherical, or angular or rough. Roundness and sphericity are the indications of a greater amount of abrasion and generally of a large amount of transportation in the clastic rocks. Packing of the Grains: Sediments may be open-packed or closepacked. The density of the packing is generally related to the pressure, either from above (because of overlying strata) or from the sides (because of compressive forces originating during mountain-building periods). http://continue.to/geonotes Fabric of the Grains: A given sedimentary rock may contain many elongated particles. Their orientation, which is studied in terms of their long axis, is of great textural importance. If all or most of the elongated particles are arranged in such a way that their long axes lie in the same direction, the rock is said to show a high degree of preferred orientation. The direction of preferred orientation is commonly related to the direction of the current flow of the medium of transport. Crystallisation Trends: In sedimentary rocks of chemical origin, textures are usually defined on the basis of degree and nature of crystallisation of the component grains. Rocks may show perfectly interlocking grains, giving rise to crystalline granular textures, or they may be composed of noncrystalline, colloidal particles, when textures are termed amorphous. STRUCTURES OF SEDIMENTARY ROCKS: The term structure includes some large-scale features of the sedimentary rocks that have been imposed on them during their formation. These can be best studied under three headings: Mechanical Structures Chemical Structures Organic Structures Mechanical Structures: They include those structures that have developed because of some physical processes operating at the time of deposition of the sediments. These include: Stratification: By stratification is understood a layered arrangement in a sedimentary rock and this may be very prominent or only mildly displayed. The different layers may be of similar or dissimilar colour, grain size and composition. These layers, also known as beds or strata if more than 1 cm thick, are separated from each other by planes of weakness - the bedding planes. When the bedding planes are very close to each other, or, in other words, the beds are very thin (generally <1cm thick), the term lamination is used instead of stratification, and the layers are known as laminae. Lamination is a characteristic feature of very fine-grained rocks like shale. Cross Bedding: Changes in velocity and direction of the currents of the transporting agent result in an irregular type of stratification, variously called false bedding, current bedding or cross bedding. The cross-bedding is described as tabular when successive sets have essentially parallel top and bottom surfaces. It is termed as lenticular when layers show extreme irregularity in their shape and disposition; each layer or set of beds may be intersected by other lying at different angles. The cross-bedding is known as wedge-shaped when the structure is highly complex; the http://continue.to/geonotes laminae of different beds dip in different direction and at different angles. Tabular Bedding Lenticular Bedding Wedge-Shaped Bedding Graded Bedding: In some stratified rocks, the component sediments in each layer appear to be characteristically sorted and arranged according to their grain size, i.e. the coarsest being towards the bottom and the finest towards the top of each of the two layers. Such an individual layer is said to be graded and if a number of such graded beds occur one above the another, as invariable is the case, the structure is termed as graded bedding. Normally, such beds are the result of sedimentation in bodies of standing water where there are seasonal variations in the process. http://continue.to/geonotes Mud Cracks: They are features of common observation in those sedimentary masses of fine grain size that have been exposed to drying under sub-aerial (i.e. under the influence of sun rays) conditions. Rain Prints: They are the marks left on the top surface of loose sediments by rain water. Ripple marks: They are symmetrical or asymmetrical undulations that may be seen on some sedimentary deposits. These are essentially the product of wind or wave action during the deposition of sediments in a shallow water environment. Chemical Structures: These include those types that result during the segregation of the surfaces through chemical processes. Some important chemical sedimentary structures are: Concretionary Structure: Concretions are rounded, nodular, or irregularly shaped material present in some rock masses. Their chemical and mineralogical composition is generally different from the enclosing rock. Oolitic & Pisolitic Structures: The presence of small, more or less spherical particles (ranging from 0.1mm to 1mm), called oolites, give rise to the oolitic structure. Sometimes these particles are of bigger size (>2mm) and are termed pisolites; the structure is termed pisolitic. Limestones and bauxites show both structures. Nodular Structure: This structure is exhibited generally by limestones and s characterised by the development of irregularly shaped nodules of chert, iron oxides, iron carbonates and clay ironstone. Sometimes, these nodules show an elongation or flattening parallel to the bedding planes. Geode structure: A geode is actually a hollow shell, the interior or which is lines with inwardly projecting crystals. Generally, the outer shell is made of chalcedony and the inner encrustations are of quartz crystals. The formation of a geode requires the presence of an original cavity. Organic Structures: They include those structural features that have been imposed, directly or indirectly, by the organisms on sedimentary rocks. The rock is described as fossiliferous if it contains remains of some organisms. Limestones are sometimes highly fossiliferous. Another kind of structure which is produced by some kinds of algae is termed stromatolitic. CLASSIFICATION OF SEDIMENTARY ROCKS: Sedimentary rocks have been variously classified on the basis of their mineralogical composition, environment of deposition, mode of formation and textural/structural features. In the http://continue.to/geonotes classification, all sedimentary rocks are grouped under two divisions: Clastic (Detrital) Non-Clastic (Chemical) CLASTIC(MECHANICALLY FORMED)ROCKS: Clastic rocks include all those sedimentary rocks that have been formed from preexisting rocks through the mechanical action of denuding agents like wind, water, glaciers, etc. Their formation is achieved through the processes of erosion, deposition and lithification of the sediments. The clastic rocks are further subdivided into the following three classes on the basis of average grain size of the sediments: Rudites/Rudaceous rocks/Psephites: These include coarsegrained clastic rocks of heterogeneous composition. The average grain size of the sediments of rudites is always more than 2mm. In other words, they may composed of boulders(>200mm), cobbles(200mm-50mm), pebbles(50mm-10mm) and gravel(10mm-2mm) that are generally held together by cementing material. For example, breccia and conglomerate. Arenites/Arenaceous rocks/Psammites: They include mediumgrained clastic rocks. These are made up of sediments of grain size between 2mm and 1/16mm. Most commonly the grains are siliceous in composition; sandstones, greywackes, arkose and quartzite are some common examples. Lutites/Argillaceous rocks/Pelites: These are the finest grained clastic rocks which are made up of sediments with average grain size less that 1/256mm. They include common rocks such as shale, mudstone, claystone, etc. Clastic rocks with particles of grain size between 1/16mm and 1/256mm are also grouped under lutites, although they are generally described as silt rocks. Siltstone is a common example. NON-CLASTIC (CHEMICALLY FORMED) ROCKS: These include sedimentary rocks that have been formed through precipitation/evaporation of natural solutions. These also include the sedimentary rocks of organic origin in which the process of formation has been distinctly biochemical in nature. Non-detrital rocks are generally homogeneous in character, with interlocking crystalline texture and are formed mostly at the site of deposition. They are further divided into two main classes, namely the precipitates and the organic rocks. Precipitates: The group includes sedimentary rocks that have been formed as a result of chemical processes like crystallisation, precipitation and evaporation from aqueous solutions carrying the weathered material dissolved in them. On the basis of chemical composition, the precipitates are further divided into: Siliceous deposits: Here silica is the chief constituent. Some forms of silica like chalcedony, opal, etc. are slightly soluble in water and may be deposited in various http://continue.to/geonotes forms, forming siliceous deposits. E.g. flint, jasper, chert. Carbonate deposits: They include sedimentary rocks of carbonate composition, chief among which are carbonates of calcium and magnesium that form widespread deposits of limestone and dolomite. Ferruginous deposits: These include sedimentary rocks of ferruginous composition and chemical origin. Generally, they are composed of oxides and hydroxides of the metal, though carbonates and silicates are also formed. The socalled bog iron ores are chemically precipitated hydroxides or iron. Phosphatic deposits: Common example of phosphatic deposits are rock phosphates that have formed from sea water rich in phosphoric acid. Similarly, other rocks like limestones and shales may be rich in phosphate content. Evaporites: They are the chemically formed sedimentary rocks in which evaporation is the process involved. These include some of the very important sedimentary deposits of economic value like gypsum, rock salt, anhydrite, calcium carbonate, borate, rock sulphur and nitrate. The deposits have formed from bodies of sea water that were detached from the ocean because of any reason and were then concentrated to the point of saturation and subsequent precipitation under continued evaporation. Organic deposits: Those sedimentary deposits in the formation of which organisms (both plants and animals) have played a prominent part are grouped under this heading. The organisms might have contributed directly or indirectly. Thus rocks in which the bulk of the material is supplied by organisms (as, for instance, coal and some limestones) are simply the refined remains of some plants and animals respectively. Indirect contribution is made in a different way; some types of bacteria may help or even be solely responsible from precipitating the rock components from solutions. Organic deposits are further distinguished into the following types on the basis of their chemical composition: Carbonate rocks: These are formed by gradual accumulation of shells and skeletons of sea animals like foraminifera, corals, crinoids and crustacea. Some types of limestone are purely organic in origin. Carbonaceous rocks: These are the sedimentary deposits rich in carbon. In these, the raw material have mostly been supplied by plants of various groups. Most important of such deposits are coals of various types. Phosphatic deposits: Guano is an example of the phosphatic deposits of organic origin. The guano deposits are actually accumulations of phosphatic excreta of certain birds that inhabit certain islands and live mainly on fish. http://continue.to/geonotes Ferruginous deposits: These include some iron deposits in the precipitation of which certain types of bacteria are believed to have taken active part. Miscellaneous deposits: Some sedimentary rocks have a complex mode of formation, and thus cannot be easily grouped under any of the above headings of non-clastic rocks. It is customary to describe them separately. Some of these are clearly of residual nature, i.e. they were formed by the decomposition of pre-existing rocks involving their alteration into new types. Examples of such deposits are bauxite and laterite. TABULAR CLASSIFICATION OF SEDIMENTARY ROCKS COMPOSITION Siliceous Argillaceous Calcareous Carbonaceous Ferruginous Miscellaneous CLASTIC ROCKS RUDITES (>2mm) a)Breccia b)Conglomerate ARENTES Sandstone LUTITES (21/256mm) Shale Clay Siltstone Marls Calcareous conglomerates and sandstones Carbonaceous shale Ferruginous sandstones - NON-CLASTIC ROCKS 1. Flint ORGANIC ROCKS Radiolarian earth RESIDUAL ROCKS 2.Chert 3.Siliceous Sinter Diatomaceous earth - - - Limestones Kankar Travertine COALS: Lignite Bituminous coal Anthracite Bog iron ore SALTS: Gypsum Anhydrite Rock salt Caliche Phosphate rocks Limestone Chalk Some iron ores Phosphate rocks Guano CLASTIC ROCKS: http://continue.to/geonotes Terra Rosa - Bauxite Laterite RUDYTES: Breccia: Breccia is a mechanically formed sedimentary rock which consists of angular fragments of heterogeneous composition embedded in a fine matrix of cement. The fragments are generally greater than 2mm in diameter. They are of various types: Basal Breccia: This is formed by sea water advancing over a cherty region. Fault Breccia: This rock is formed by the cementation of fragments formed due to the braking of rocks by the process of faulting. Also called crush breccia. Sometimes other tectonic processes like folding and intrusion may also produce breccias; all these types are commonly known termed as fault/tectonic breccias. Agglomeratic Breccia: They are those rudaceous rocks in which the angular fragments are of volcanic origin. Conglomerate: These are sedimentary rocks of clastic nature and consist of rounded pebbles, gravel, boulders etc. cemented together. The consequent fragments range in size from 2mm and above, and their roundness is indicative of the fact that they have undergone a good deal of transport by water whereby their original angularities have been removed. The rounded fragments may be of any composition; they may be mineral or rock fragments. Similarly, the cementing material may be siliceous or calcareous in composition, or a mixture of these. Various types of conglomerates are: Volcanic conglomerates: The fragments are of volcanic origin (but have undergone transport before deposition). Basal conglomerates: The fragments were deposited by sea waves during their advance over a subsiding land mass. Glacial conglomerate: The fragments are of glacial origin. ARENITES: Sandstone: These are mechanically formed sedimentary rocks which result from compaction and consolidation of sand beds. The component grains are generally of a diameter between 2mm and 1/16mm. Silica is always the dominant constituent in sandstone. The types of sandstone are: Siliceous sandstone: The cementing material or matrix is siliceous in character. Calcareous sandstone: The matrix is made up of carbonates of Ca, Mg, etc. Argillaceous sandstone: They are generally soft in nature, the matrix is clayey in character. Ferruginous sandstone: they contain cementing material of ferruginous composition. On the basis of mineralogical composition, the following types are commonly recognised: http://continue.to/geonotes Arkoses: These are sandstone exceptionally rich in feldspars. These are assumed to have been derived from granitic parent rocks. Greywackes: These are impure sandstones of grey appearance and contain quartz, feldspars and bits of rocks like granites, feldsite, shales, etc. Flagstones: These are sandstones rich in mica. Sometimes mica flakes are present in parallel or sub-parallel positions, resulting in the stone becoming weak in these directions. Freestones: They are massive sandstones that contain no or very little divisional planes, assuming on the whole a compact character. LUTITES: Shale: This is a fine-grained sedimentary rock of argillaceous(clayey) composition. Shales are generally characterised by a distinct fissility (property of easy partition) parallel to he bedding and are made up of fine clay particles of 1/256mm diameter. They are composed of minute particles of uncertain composition; clayey minerals like illite, montmorillonite and kaolin are generally present. Montmorillonite and kaolin are invariable the chief constituents. The types of shale are: Calcareous shale: They contain certain carbonates. Carbonaceous shale: These rocks are rich in organic matter, especially carbon and are generally black. Alum shales: They are rich in iron sulphide (pyrites) or sulphate. Oil shale: They are carbonaceous shales that yield oil on destructive distillation. NON-CLASTIC/CHEMICAL/NON-DETRITAL ROCKS: CARBONATE ROCKS: Limestone: Limestones are very important and widespread sedimentary rocks that have formed from chemical as well as organic processes. Pure limestones are chiefly composed of calcite, whereas in common limestones, impurities like clays, feldspars, quartz and pyrite may be present in considerable amounts. Magnesium carbonate is generally a common impurity. In some limestones, the magnesium carbonates predominate, and he rock is called DOLOMITE. The various types of limestone are: Chalk: It is he purest form of limestone, characterised by fine-grained, earthy texture. The common colour is white; some chalks may be exceptionally rich in the remains of very small organisms like foraminifera. http://continue.to/geonotes Argillaceous Limestones: They are those in which clay is present in considerable proportions. When carbonate and clay are present in equal proportions, the rock is called MARL. Shell/Fossiliferous Limestone: The remains of some organisms are preserved as fossils in the rock. When the limestone is composed largely of shells and shell fragments, it is called COQUINA. Lithographic Limestones: They are compact, homogeneous and extremely fine-grained calcareous rocks. Kankar: It is a nodular or concretionary form of carbonate formed by evaporation of subsoil water (rich in CACO3) just near the surface. Calc-sinter: It is a carbonate-rich deposit formed by precipitation from carbonate-rich spring waters. These deposits are also known as travertine or calc-tuff. http://continue.to/geonotes