Polar Covalent Bonds

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2.4 Polar Covalent Bonds

1. Unequal Sharing

LO: I know what is meant by a polar covalent bond.

If the atoms forming a covalent bond are the same they will have an equal pull on the shared pair of electrons.

This type of bond is a pure covalent bond.

However, in hydrogen fluoride the fluorine atom has a stronger pull than the hydrogen atom on the shared pair of electrons.

This means that the electrons are closer to the fluorine atom than the hydrogen atom. slightly positive end (

+)

H F slightly negative end (

-)

This is shown by an arrow on the covalent bond pointing towards the fluorine atom.

The bond is said to have a permanent dipole with a positive pole at the hydrogen end and a negative pole at the fluorine end.

This type of bond is a polar covalent bond.

2. How Strong an Attraction?

LO: I know what is meant by electronegativity.

Electronegativity is a measure of the attraction an atom which is involved in a covalent bond has for the shared electrons of the bond.

2.2

1.0

1.2

2.5

2.2

3.5 4.0

3.0

0.8 2.1

2.8

2.6

0.8

Electronegativity:

 increases across a period.

 decreases down a group.

In a polar covalent bond the atom with the:

 highest electronegativity will be slightly negative.

 lowest electronegativity will be slightly positive.

The greater the difference in electronegativity the more polar the bond.

So, will be

H Br H I than

3. Polar Molecules

LO: I understand how molecules can be polar.

A polar molecule is a molecule which has a permanent slightly positive charge on one side and a permanent slightly negative charge on the other.

Water is a polar molecule.

It has a slightly positive side and a slightly negative side.

Polar liquids can be detected by passing a fine stream past a charged rod:

 Polar liquids will be attracted to the charged rod.

 Non-polar liquids will flow straight past.

Examples:

Liquid Polarity

Water

Paraffin

Alcohol

White Spirit

Polar

Non-polar

Polar

Non-polar

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