Soybean Methyl Esters

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INDUSTRY BULLETIN

SOYBEAN METHYL ESTERS

Since the enactment of the Clean Air Act of 1990, many conventional chlorinated fluorocarbon and petroleum industrial solvents have been regulated out of traditional market applications. Methyl Soyate, a soybean-oilbased methyl ester, is gaining market acceptance as an excellent solvent replacement alternative in applications such as parts cleaning and degreasing, paint and adhesive removal, mold releases agents and asphalt cleanup.

What is methyl soyate?

Methyl Soyate is also known as soybean oil methyl esters and soy methyl ester. It is made by the esterification of soybean oil. Soy oil is heated and reacted with methanol in the presence of a catalyst. The reaction causes the separation of soy oil into methyl ester and glycerin. Following the separation, the glycerin goes to storage where it will eventually be shipped to processors utilizing it in cosmetics and health aids. The methyl ester goes through a water-wash process; water adheres to any impurities, causing the impurities to be filtered from the methyl ester. The methyl ester is then dried through a vacuum drying system.

Why are soybean methyl esters important to Meyer Laboratory?

As a solvent, soybean methyl ester has important environmental and safety related properties that make it attractive for many industrial applications.

Soybean methyl esters are lower in toxicity than most other solvents, is readily biodegradable, has a very high flash point, is VOC free or has a low level of VOC’s, <50 g/liter and they decrease the risk of fire and exposure for workers during use and storage.

The principle regulated air pollutant affecting the printing ink industry is Volatile Organic Compounds (VOC).

In the printing industry, the current processes use are lithography/offset (43%), gravure (23%), flexography

(21%), letterpress (4%), screen printing (3%) and desktop publishing (6%). In the future (weeks, months, years), ninety-four percent of the printing market will need to reduce the VOC level in their facilities. Meyer

Laboratory’s – NPS will meet the EPA’s requirement of being VOC free. Test Method 24 requires that a product have less than 70 g/liter to be considered VOC free.

What are the benefits of soybean methyl esters? The benefits include: 100% Biodegradable-

Easy and inexpensive to recycle-Renewable- made from soybeans-Low VOC-Zero Vapor Pressure-High boiling point-High solvency power for resins, polymers and dyes-Great penetration characteristics-Stable in solvent formulations-EPA approved SNAP solvent-Not a ODC- Ozone Depleting Chemical-Not a HAP-

Hazardous Air Pollutant-Not SARA reportable-Non carcinogenic-Non corrosive.

Solvent Properties

Product Kb Value

Soybean Methyl Esters 58

Mineral Sprits 35

Tolune 105

Naphtha 35

% VOCs Flash Point

< 50 g/liter >360

100 107

100

100

41

58

d-Limonene 56 95 121

Trichloroethylene 129 100 None

Methylene Chloride 136 100 None

Elevated temperatures and agitation can enhance soybean methyl ester’s cleaning, rinsability and accelerate evaporation, which is characteristically slow.

Kb Value (Kauri-butanol) is the relative measure of solvency. The higher the KB Value the quicker the product will degrease and the faster the evaporation rate.

HAZARDOUS CHEMICAL

Methylene Chloride

Trichloroethylene

1,1,1, Trichloroethane

Benzene

Toluene

Xylene

Perchloroethylene

NPS-Non Petroleum Solvent

Mineral Spirits

Naphtha

Kerosene

Stoddard Solvent

MEK

Acetone

NOTES: 1.

Carcinogenic 2.

Flammable 3.

Toxic

4.

Non-Biodegradable

5.

Ozone Depleting

6. Biodegradable, Not a ODC, Not a HAP, Non Carcinogenic

Kb VALUE (solvency)

136

129

124

107

105

98

92

58

37

35

34

33

N/A

N/A

NOTES

1,3,4

3,4

3,4,5

1,2,3,4

2,3,4

2,3,4

3,4

6

4

2,3,4

4

3,4

2,3,4

2,3,4

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