KANE INTERNATIONAL CORPORATION MATERIAL SAFETY DATA SHEET KPLASTTM 1022 1. Product Information Product Name: 24 Hour Emergency Number: 800/424-9300 KPLAST™ 1022 2. Composition / Information on Ingredients Chemical Name: CAS No. POLYURETHANE RESIN ETHYL ACETATE ISOPROPANOL REGISTERED 141-78-6 67-63-0 EEC No. % Wt. 200-500-4 200-661-7 70 15 15 3. Hazards Identification CONTAINS VOLATILE SOLVENTS CLASSIFIED HIGHLY FLAMMABLE HMIS: Health (2) Flammability (3) Reactivity (0) Personal Protection (G) Affects Due To: SOLVENT COMPONENTS - Inhalation: HEADACHE, DIZZINESS, DROWSINESS - Skin: IRRITATION, POSSIBLE DERMATITIS WITH FREQUENT CONTACT - Eyes: IRRITATION, POSSIBLE CORNEA DAMAGE WITH LONG TERM EXPOSURE TO FUME - Ingestion: LOW TOXICITY, MAY CAUSE NAUSEA 4. First Aid Measures Inhalation: REMOVE TO OPEN AIR. IF BREATHING DIFFICULT, GIVE OXYGEN AND SEEK MEDICAL ATTENTION Skin: WASH WELL WITH COMMERCIAL CLEANER, THEN SOAP AND WATER Eyes: IRRIGATE WITH COPIOUS AMOUNTS OF WATER FOR 15 MINUTES Ingestion: DO NOT INDUCE VOMITING. SEEK MEDICAL ATTENTION 5. Fire Fighting Measures Extinguishing Measures - Suitable: FOAM, CARBON DIOXIDE, DRY POWDER - Not to be used: WATER JET Hazardous thermal decomposition and combustion products: OXIDES OF CARBON AND NITROGEN. HCN GAS ABOVE 330 C Protective equipment: WEAR SELF CONTAINED BREATHING APPARATUS 411Theodore Fremd Avenue Rye, New York 10580 Tel 813/227-9116 Fax 813/227-9158 Material Safety Data Sheet KPLAST 1022 Page 2 6. Accidental Release Measures Personal precautions: AVOID BREATHING FUMES. EXTINGUISH CIGARETTES/OPEN FLAMES Environmental precaution: DO NOT ALLOW TO ENTER DRAINS OR WATER COURSES Cleaning procedures: ABSORB INTO EARTH, SAND OR OTHER INERT MATERIAL AND PUT INTO CLOSED CONTAINERS Waste Disposal Methods: INCINERATE IN AN APPROVED INCINERATOR OR DISPOSE OF IN A CHEMICAL DUMP ACCORDING TO LOCAL, STATE, AND FEDERAL REGULATIONS 7. Handling and Storage Handling: PROVIDE ELECTRICAL EARTH WHEN TRANSFERRING FROM ONE CONTAINER TO ANOTHER. PROHIBIT SMOKING FROM AREA. ENSURE WORKPLACE IS WELL VENTILATED Storage: AWAY FROM HEAT AND SOURCES OF IGNITION 8. Exposure controls / Personal Protection TWA Exposure Standards Chemical Name ACGIH-TLV OSHA-PEL R-phrases ETHYL ACETATE ISOPROPANOL 400 ppm 200 ppm R 11 R 11 400 ppm 400 ppm Respiratory protection: BREATHING APPARATUS IF WORKPLACE NOT WELL VENTILATED Hand protection: WEAR GLOVES WHICH ARE IMPERVIOUS TO THIS MATERIAL FOR THE DURATION OF ANTICIPATED EXPOSURE IF THERE IS POTENTIAL FOR SKIN CONTACT Eye protection: VISOR OR PROTECTIVE GLASSES Skin protection: BARRIER CREAM RECOMMENDED 9. Physical and Chemical Properties Appearance: PALE YELLOW LIQUID Boiling Point: 77ºC Flammability: HIGHLY FLAMMABLE Odor: FRUITY Viscosity: 5 – 9 ps 10. Stability and Reactivity Stability: Conditions to avoid: Materials to avoid: Hazardous decomposition products: Auto ignition: Flash Point: Wt/Gal: pH: Solubility in water: 427ºC -4°C 8.40 lb/gal N/A INSOLUBLE STABLE SOURCES OF IGNITION STRONG OXIDIZING AGENTS AS DETAILED IN PART 5. IN EVENT OF FIRE 411Theodore Fremd Avenue Rye, New York 10580 Tel 813/227-9116 Fax 813/227-9158 Material Safety Data Sheet KPLAST 1022 Page 3 11. Toxicological Information Ethyl Acetate Isopropanol LD50 Oral: Rat LC50 Inhalation: Rat LD50 Dermal: Rabbit 5,620 mg/kg 5,045 mg/kg 45,000 mg/m3 (2 hr) 16,000 ppm (8 hr) 180,000 mg/kg 12,800 mg/kg 12. Ecological Information Mobility: VISCOUS LIQUID, WILL SINK BELOW SURFACE OF WATER ONCE SOLVENT HAS EVAPORATED Persistence and degradability: POLYMER CONSIDERED TO BE SLOWLY BIO DEGRADABLE Bioaccumulative potential: NOT THOUGHT LIKELY TO BE BIO - ACCUMULATIVE Aquatic / Ecotoxicity: RESIN IS NON TOXIC, AQUATIC TOXICITY OF SOLVENTS IS LOW WGK RATING : 1 (BASED ON SOLVENTS) Ethyl Acetate Isopropanol LC50: 220 mg/l (96 hr) Fish: Fathead Minnow LC50: 100,000 mg/l (96 hr) Fish: Fathead Minnow 13. Disposal Considerations Methods of Disposal: ABSORB INTO INERT MATERIAL AND PUT INTO DRUMS DISPOSE OF IN ACCORDANCE WITH LOCAL REGULATIONS Danger(s): PRESENCE OF SOLVENTS IN WASTE AND EMPTY DRUMS MEANS THAT CONTAINERS SHOULD BE STILL LABELLED "HIGHLY FLAMMABLE" 14. Transport Information Special Precautions: Classification: - UN number: 1866 - ADR / RID: 3.5 (C) - Marine pollutant: NOT - Shipping name: RESIN SOLUTION FLAMMABLE - Packaging Group: - ICAO / IATA: - IMDG - code: - Stow away from foodstuffs: II 3 (II) 3278 NO 411Theodore Fremd Avenue Rye, New York 10580 Tel 813/227-9116 Fax 813/227-9158 Material Safety Data Sheet KPLAST 1022 Page 4 15. Regulatory Information CAS number: REGISTERED EEC number: N / A Labeling: FLAMMABLE LIQUID Risk Phrase: R 11 Safety Phrase: S7-16-23-29-33 SARA TITLE III INFORMATION This product contains the following chemicals subject to the reporting requirements of Section 313 of the Emergency Planning and Community Response Act of 1986 and of 40 CFR 372. This information must be included in all MSDSs that are copied and distributed for this material. Component CAS # WT% N/A SARA Section 311 and 312 hazard classification(s) for this product are listed below: Immediate (acute) health hazard Delayed (chronic) health hazard Fire hazard CERCLA INFORMATION Under EPA-CERCLA releases to air, land, or water which exceed the reportable quantity must be reported to the National Response Center (800-424-8802). The reportable quantity for this product is > 33,333 pounds based on the presence of Ethyl Acetate. 16. Other Information Although data in this MSDS is based on information of this moment and are believed reliable, we cannot assume responsibility for the use thereof, nor do we accept any liability for loss or damage directly or indirectly caused by our product. It is the users responsibility to check safety, quality and all other properties of this product prior to use, particularly where use is other than as recommended in our Technical Data sheet. This is to certify that all chemical substances in this shipment comply with all applicable rules under TSCA and that we are not offering a chemical substance for entry in violation of TSCA or any applicable rule there under. May 2013 411Theodore Fremd Avenue Rye, New York 10580 Tel 813/227-9116 Fax 813/227-9158