Table of Contents The table of contents entry discrete plasmonic nanostructures comprising: 2, 3, 4 and 5 closely-spaced 15 nm gold nanoparticles are seen as discreet bands on the gel image. The absorption visible spectra on the right panel show that the magnitude of the red shift is directly proportional to the number of particles in the plasmonic structure. TOC Keyword: Gold nanoparticles, nanomaterials, Surface plasmon resonance shift, TEM. Shay Halamish, Gennady Eidelshtein and Alexander Kotlyar* Plasmon-coupled Nanostructures Comprising Finite Number of Gold Particles 1 Plasmon-coupled Nanostructures Comprising Finite Number of Gold Particles Shay Halamish, Gennady Eidelshtein and Alexander Kotlyar* Department of Biochemistry and Molecular Biology, George S. Wise Faculty of life Sciences and The Center of Nanoscience and Nanotechnology, Tel Aviv University, Ramat Aviv 69978, Israel * E-mail address- s2shak@post.tau.ac.il Telephone- +972-3-640-7138 Fax- +972-3-640-6834 SUPPORTING INFORMATION Fig. S1 Time-dependent absorption changes of AuNPs suspension induced by Tris-Acetate. To 15 nm citrate-protected AuNPs (bottom curve) Tris-Acetate (pH 7.4) was added to a final concentration of 4.5 mM and the spectra were recorded 0.7, 2.3, 4, 6, 8 and 10 min after Tris addition. 2 Fig. S2 TEM images (left panels) and corresponding population histograms (right panels) of nanoparticle fractions electroeluted from lanes 1, 2, 3, 4 and 5 of Figure 1b. 3 Fig. S3. Representative HRTEM images showing that the particles in the clusters are very closely spaced and the distance between adjacent nanoparticles does not exceed 1 nm. 4